CN109267421A - A kind of coating fluid reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas - Google Patents

A kind of coating fluid reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas Download PDF

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Publication number
CN109267421A
CN109267421A CN201810850752.5A CN201810850752A CN109267421A CN 109267421 A CN109267421 A CN 109267421A CN 201810850752 A CN201810850752 A CN 201810850752A CN 109267421 A CN109267421 A CN 109267421A
Authority
CN
China
Prior art keywords
coating fluid
filter stick
paper filter
flue gas
stick type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810850752.5A
Other languages
Chinese (zh)
Inventor
雷强
景延秋
徐坚强
李常军
熊斌
张学伟
宁尚辉
罗柱石
向金友
杨懿德
杨洋
易蔓
李林秋
王林
喻保华
梁鑫
喻泰阁
喻洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Hengjing Environmental Technology Co Ltd
Henan Agricultural University
Original Assignee
Henan Hengjing Environmental Technology Co Ltd
Henan Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Hengjing Environmental Technology Co Ltd, Henan Agricultural University filed Critical Henan Hengjing Environmental Technology Co Ltd
Priority to CN201810850752.5A priority Critical patent/CN109267421A/en
Publication of CN109267421A publication Critical patent/CN109267421A/en
Withdrawn legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The present invention provides a kind of coating fluid for reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas, by being with water, carboxymethyl cellulose, Tween-80, sodium carboxymethylcellulose, calgon, melon rubber, paraben esters and its fatty acid ester compounded object of sodium salt, higher alcohols.It is an advantage of the invention that the use of the coating fluid can be effectively reduced the releasing content of coke tar in paper filter stick type cigarette mainstream flue gas, and Sensory Quality of Cigarette is not influenced, furthermore the coating fluid is raw materials used from a wealth of sources, environmentally protective, low in cost.

Description

A kind of coating fluid reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas
Technical field
The invention belongs to technical field of cigarettes, are to provide one kind specifically for reducing paper filter stick type cigarette mainstream flue gas The coating fluid of middle releasing content of coke tar.
Background technique
Paper filter stick is born in the twenties in last century, due to many originals such as being limited by cigarette filter rod industry technology is horizontal Cause, cigarette paper filter stick are never widely used.But paper filter stick is there is also some disadvantages, such as " paper taste " heavier, Flue gas is dry, generates heat collapses, to rejection effect difference of the harmful components such as tar in flue gas etc..As reducing tar and reducing harm is held by society Continuous concern, the burst size for reducing tar in cigarette smoke seem even more important.The reduction about tar in paper filter stick has perhaps at present More researchs are matched after being mixed such as 5671757 patent of US using 25%~50%Lyocell fiber and 50%~75% wood pulp cellulose It is copied into filter rod body paper, is remarkably improved the filter efficiency of traditionally on paper filter rod, the especially filtering to tar harmful components Effect.Training show et al. is contained by the way that a certain amount of cellulose diacetate fibers are added in pure wood pulp cellulose, using wet papermaking and Line dry method embossing technique develops a kind of fibrous paper (CAP body paper) and filter stick (CAPF filter stick) containing cellulose acetate, with vinegar fibre Filter stick is compared, and using CAPF filter stick, coke tar in cigarette reduces 15%-41%, and tar also has certain reduction, the volume of CAPF filter stick Cigarette aesthetic quality is close with the aesthetic quality of vinegar fibre filter stick cigarette.It is modified in conclusion current research concentrates on body paper, Dosage is larger, higher cost.In addition paper filter stick is also poor to tar rejection effect.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of coating fluid for paper filter stick, the coatings The use of liquid can be effectively reduced the releasing content of coke tar in paper filter stick type cigarette mainstream flue gas, and the raw materials used source of the coating fluid Extensively, environmentally protective, low in cost.The purpose of the present invention is be achieved through the following technical solutions to obtain: one kind is for reducing paper The coating fluid of releasing content of coke tar in filter stick type cigarette mainstream flue gas, by following weight ratio at being grouped as: water 30-90%, carboxylic first Base cellulose is 10-40%, Tween-80 5-20%, sodium carboxymethylcellulose 1-15%, calgon 1-10%, melon rubber 0 .1-10%, fatty acid ester compounded 0 .1-5% of object of 0 .1-5% of paraben esters and its sodium salt, higher alcohols.The coating fluid is by carboxylic Methylcellulose, Tween-80, sodium carboxymethylcellulose, calgon, melon rubber, paraben esters and its sodium salt, high-carbon alcohol ester Fat acid esters compound sequentially adds to be prepared in water.The Tween-80 is wetting agent.
The solid content of coating fluid of the invention is about 10%-70%(weight), pH value is about 6.5-8, and viscosity is about 50- 500cps(25 DEG C), and there is good coating performance.
Coating fluid of the invention is generally carried out in coating stage, and coating weight is generally 10-30g/m2.
It is an advantage of the invention that the use of the coating fluid can be effectively reduced the coke in paper filter stick type cigarette mainstream flue gas Oily burst size, and Sensory Quality of Cigarette is not influenced, furthermore the coating fluid is raw materials used from a wealth of sources, environmentally protective, low in cost.
Below with reference to embodiment, invention is described further in this to specific embodiment, but the scope of the invention is not limited to These embodiments.
Embodiment 1 is by 20g carboxymethyl cellulose, 5g Tween-80,5g sodium carboxymethylcellulose, 3g calgon, 3g melon Youngster's glue, 2g paraben esters and its sodium salt, the fatty acid ester compounded object of 3g higher alcohols are added sequentially in 70g water, are within stirring 1 hour It can.It is 28 .3% that gained, which is coated with fluid solid content, and brookfield viscosity is 120cps(25 DEG C).
Embodiment 2 is by 30g carboxymethyl cellulose, 6g Tween-80,4g sodium carboxymethylcellulose, 4g calgon, 6g melon Youngster's glue, 4g paraben esters and its sodium salt, the fatty acid ester compounded object of 1g higher alcohols are added sequentially in 52g water, are within stirring 1 hour It can.It is 45 .6% that gained, which is coated with fluid solid content, and brookfield viscosity is 360cps(25 DEG C).Embodiment 3 is by 35g carboxymethyl Cellulose, 12g Tween-80,9g sodium carboxymethylcellulose, calgon 1-10%, 9g melon rubber, 2g paraben esters and its sodium Salt, the fatty acid ester compounded object of 5g higher alcohols are added sequentially in 47g water, are stirred 1 hour.It is 48 that gained, which is coated with fluid solid content, .2%, brookfield viscosity is 455cps(25 DEG C).
3 kinds of coating fluids that above-described embodiment 1- embodiment 3 is prepared application example are successively coated respectively, wherein Coating weight is respectively 11 .8g/m2,11 .9 g/m2,12 .2 g/m2, and paper filter then is respectively prepared with mouth rod forming machine Stick, and cigarette, at cigarette, sample cigarette is denoted as 1#, 2#, 3# respectively.In addition, respectively and normally by aforementioned three obtained kind paper filter stick Vinegar fibre filter stick carried out respectively according to the ratio of 15mm+10mm compound, obtain three kinds of composite filters, then distinguish again cigarette at Cigarette, sample cigarette are denoted as 4#, 5#, 6# respectively.In addition, by uncoated paper filter stick cigarette at cigarette, and rolled up as 1-3# sample The control sample of cigarette;Uncoated paper filter stick is subjected to binary that is compound, and will obtaining according to the ratio of aforementioned 15mm+10mm Control sample of the composite filter cigarette at cigarette, as 4-6# sample cigarette.In temperature (22 ± 1) DEG C, phase before cigarette test used To balancing 48 hours under the conditions of humidity (60 ± 2) %, then through weight (± 0 .02g of average weight) and resistance to suction (average resistance to suction ± It 49Pa) sorts, chooses standard compliant test cigarette.Cigarette smoking test is carried out on smoking machine according to standard aspiration condition, And carry out the detection of releasing content of coke tar respectively according to standard YC/T 255-2008 and GB/T 19609-2004.Each sample three A Duplicate Samples, the results are shown in Table 1.
1 cigarette sample releasing content of coke tar test result of table
Cigarette sample title Tar (mg) Tar reduced rate (%)
Paper filter stick compares cigarette sample 13.3 /
Paper vinegar binary composite tip stick control sample 13.6 /
1# paper filter stick cigarette sample 11.3 15
2# paper filter stick cigarette sample 11.5 13.5
3# paper filter stick cigarette sample 10.9 18
4# paper vinegar binary composite tip stick sample 11.8 11.2
5# paper vinegar binary composite tip stick sample 12.1 9
6# paper vinegar binary composite tip stick sample 10.6 20.3
As can be seen from Table 1, compared with paper filter stick compares cigarette sample, 3# paper filter stick cigarette sample tar reduced rate is reached as high as 18%.It can thus be seen that the use of coating fluid of the present invention can be effectively reduced the coke in paper filter stick type cigarette mainstream flue gas Oily burst size.And smoking result show test Sensory Quality of Cigarette with compare cigarette without significant difference.

Claims (4)

1. a kind of coating fluid for reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas, which is characterized in that by following Weight ratio at being grouped as: water 30-90%, carboxymethyl cellulose 10-40%, Tween-80 5-20%, carboxymethyl cellulose Sodium 1-15%, calgon 1-10%, 0 .1-5% of 0 .1-10% of melon rubber, paraben esters and its sodium salt, high-carbon polyol fatty acid 0 .1-5% of ester complexes.
2. the used coating fluid for reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas according to claim 1, special Sign is, by carboxymethyl cellulose, Tween-80 (wetting agent), sodium carboxymethylcellulose, calgon, melon rubber, nipalgin Ester and its fatty acid ester compounded object of sodium salt, higher alcohols sequentially add to be prepared in water.
3. the used coating fluid for reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas according to claim 1, special Sign is that the solid content of coating fluid is about 10%-70%(weight), pH value is about 6.5-8, and viscosity is about 50-500cps(25 DEG C), And there is good coating performance.
4. the used coating fluid for reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas according to claim 1, special Sign is that coating fluid of the invention is generally carried out in coating stage, and coating weight is generally 10-30g/m2
CN201810850752.5A 2018-07-29 2018-07-29 A kind of coating fluid reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas Withdrawn CN109267421A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810850752.5A CN109267421A (en) 2018-07-29 2018-07-29 A kind of coating fluid reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas

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CN201810850752.5A CN109267421A (en) 2018-07-29 2018-07-29 A kind of coating fluid reducing releasing content of coke tar in paper filter stick type cigarette mainstream flue gas

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1933744A (en) * 2004-02-19 2007-03-21 三荣源有限公司 Nicotine-reducing agent and nicotine reduction method
CN101914869A (en) * 2010-07-28 2010-12-15 玉溪思润印刷有限公司 Porous-starch-containing water-based paint for cigarette wrapping paper
CN101914872A (en) * 2010-07-28 2010-12-15 玉溪思润印刷有限公司 Chitosan-contained waterborne coating for cigarette wrapping paper
CN102326864A (en) * 2011-07-02 2012-01-25 云南瑞升烟草技术(集团)有限公司 Filter material and application of same in cigarettes
CN102423132A (en) * 2011-08-15 2012-04-25 武汉力诚生物科技有限公司 Plant polysaccharide cigarette filter tip and preparation method thereof
CN102691234A (en) * 2012-06-06 2012-09-26 云南瑞升烟草技术(集团)有限公司 Papery filter material with high tensile strength for cigarettes and preparation method thereof
CN102972860A (en) * 2012-12-21 2013-03-20 吉林烟草工业有限责任公司 Tobacco sheet and production method thereof
CN103462211A (en) * 2013-09-13 2013-12-25 安徽中烟工业有限责任公司 Ignitable smoking tobacco substitute capable of reducing tar yield and hazardous substance content of cigarettes and preparation method thereof
CN104323422A (en) * 2014-08-27 2015-02-04 南京市荣达树脂有限公司 Cigarette filter additive containing super oil absorption resin and preparation method of cigarette filter additive
CN105266196A (en) * 2015-10-13 2016-01-27 江苏长泰药业有限公司 Application of pyruvic acid compound in cigarette filter tip preparation as additive for reducing inhalation amount of harmful substances in smoke
CN108047840A (en) * 2017-12-21 2018-05-18 中国烟草总公司郑州烟草研究院 The liquid coating material of phenol release amount in a kind of filter stick type cigarette mainstream flue gas for reducing paper

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1933744A (en) * 2004-02-19 2007-03-21 三荣源有限公司 Nicotine-reducing agent and nicotine reduction method
CN101914869A (en) * 2010-07-28 2010-12-15 玉溪思润印刷有限公司 Porous-starch-containing water-based paint for cigarette wrapping paper
CN101914872A (en) * 2010-07-28 2010-12-15 玉溪思润印刷有限公司 Chitosan-contained waterborne coating for cigarette wrapping paper
CN102326864A (en) * 2011-07-02 2012-01-25 云南瑞升烟草技术(集团)有限公司 Filter material and application of same in cigarettes
CN102423132A (en) * 2011-08-15 2012-04-25 武汉力诚生物科技有限公司 Plant polysaccharide cigarette filter tip and preparation method thereof
CN102691234A (en) * 2012-06-06 2012-09-26 云南瑞升烟草技术(集团)有限公司 Papery filter material with high tensile strength for cigarettes and preparation method thereof
CN102972860A (en) * 2012-12-21 2013-03-20 吉林烟草工业有限责任公司 Tobacco sheet and production method thereof
CN103462211A (en) * 2013-09-13 2013-12-25 安徽中烟工业有限责任公司 Ignitable smoking tobacco substitute capable of reducing tar yield and hazardous substance content of cigarettes and preparation method thereof
CN104323422A (en) * 2014-08-27 2015-02-04 南京市荣达树脂有限公司 Cigarette filter additive containing super oil absorption resin and preparation method of cigarette filter additive
CN105266196A (en) * 2015-10-13 2016-01-27 江苏长泰药业有限公司 Application of pyruvic acid compound in cigarette filter tip preparation as additive for reducing inhalation amount of harmful substances in smoke
CN108047840A (en) * 2017-12-21 2018-05-18 中国烟草总公司郑州烟草研究院 The liquid coating material of phenol release amount in a kind of filter stick type cigarette mainstream flue gas for reducing paper

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Application publication date: 20190125