CN109232750A - A kind of production equipment for cornstarch - Google Patents

A kind of production equipment for cornstarch Download PDF

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Publication number
CN109232750A
CN109232750A CN201810812314.XA CN201810812314A CN109232750A CN 109232750 A CN109232750 A CN 109232750A CN 201810812314 A CN201810812314 A CN 201810812314A CN 109232750 A CN109232750 A CN 109232750A
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China
Prior art keywords
shell
turbulent flow
pipeline
parts
kettle
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CN201810812314.XA
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Chinese (zh)
Inventor
梁峙
梁骁
马捷
韩宝平
刘喜坤
许旭
张明胜
陈兴祥
董平
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Xuzhou University of Technology
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Xuzhou University of Technology
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Publication of CN109232750A publication Critical patent/CN109232750A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B31/00Preparation of derivatives of starch
    • C08B31/003Crosslinking of starch
    • C08B31/006Crosslinking of derivatives of starch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B31/00Preparation of derivatives of starch
    • C08B31/02Esters
    • C08B31/04Esters of organic acids, e.g. alkenyl-succinated starch

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

A kind of production equipment for cornstarch, medicament mixing apparatus inside are equipped with cellular reactor and steam injection pipe, pass through piping connection between medicament mixing apparatus and Turbulent Flow processor top;The turbulent flow shell of Turbulent Flow processor is equipped with spoil disposal and drain line, and the aeration tube of spray pipe network, Turbulent Flow adsorbing mechanism and annular is successively arranged in inner cavity;Spray pipe network is connect by pipeline with external water pump;Turbulent Flow adsorbing mechanism surface is equipped with a large amount of through-holes, and inside is equipped with adsorption stuffing;Aeration tube top is equipped with solarization air cap, and is connected to the aeration pump being arranged on mobile gas transmission station;Raw material conveying device is equipped with the conveyer belt being obliquely installed driven by drive roll and driven roller, is provided with material containing case on conveyer belt, the lower end of raw material conveying device is provided with loading hopper, and upper end is provided with discharging hopper.The device can have the convenient production for realizing composite modified starch, and structure is simple, at low cost, can improve production efficiency.

Description

A kind of production equipment for cornstarch
Technical field
The invention belongs to starch preparation technical fields, and in particular to a kind of production equipment for cornstarch.
Background technique
Cornstarch is also known as corn starch, the white flaxen powder of micro-strip.It is wide by consumer as the raw material of industry It is general required, corn be not only in the king or cereal crops of feed purposes it is most wide, can development be most, dosage is maximum The raw material of industry.Starch is produced by raw material of corn, can be obtained that chemical analysis is best, the minimum product of cost, added value is more than jade Tens times of initial value of rice, is widely used in the industries such as papermaking, food, weaving, medicine.To improve the performance of starch, expanding it using model It encloses, using physics, chemistry or enzymatic treatment, new functional group is introduced on starch molecule or changes starch molecule size and starch Particle properties to change the natural characteristic of starch, and then can obtain converted starch, and converted starch can be applicable in some special applications Demand.The device structure of existing production converted starch is complicated, and manufacturing cost is high, inconvenient, the cornstarch matter produced It is poor to measure, and production efficiency is low.
Summary of the invention
In view of the above existing problems in the prior art, the present invention provides a kind of production equipment for cornstarch, the dresses It is simple to set structure, manufacturing cost is low, and it is easy to operate, the quality of production of converted starch can be improved, and the production effect of starch can be improved Rate.
To achieve the goals above, the present invention provides a kind of production equipment for cornstarch, including passes through bracket one The job platform vacantly installed further includes medicament mixing apparatus, mobile gas transmission station, control system and raw material conveying device, institute The side for stating job platform has vacantly installed Turbulent Flow processor by bracket two, and the medicament mixing apparatus is fixed by pedestal Branch is located at the lower part of job platform;
The medicament mixing apparatus includes the medicament mixing shell of upper end opening, the intracorporal middle part of medicament mixed shell and Lower part is fixedly installed cellular reactor and vapor injection line respectively, and the bottom of medicament mixing shell is fixedly connected with and it The confection discharge pipe of inner cavity connection, the top of medicament mixing shell are fixedly connected with the medicament injection being connected to its inner cavity Pipeline and additive charging line are further fixedly arranged on temperature sensor in medicament mixed shell body;The cellular reactor Section is honeycomb, and up and down, is made of the standpipe of more honeycomb arrangements;The vapor injection line is in annulus Shape, upper surface are provided with the through-hole being connected to its inner cavity throughout ground, and the steam supply pipe road for connecting vapor injection line is pierced by It is connect after medicament mixing shell with external high steam pipeline;The outlet end of the confection discharge pipe passes through pressure pump The liquid feeding end for adding pipeline with the side for being fixedly connected on Turbulent Flow processor top is fixedly connected, and adding tube road is provided with electricity Magnet valve A;The addition pipeline, confection discharge pipe, medicament filling line, additive charging line and steam supply pipe road On be respectively arranged with solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E;
The movable type gas transmission station is arranged in the lower part of Turbulent Flow processor, mobile gas transmission station include mobile loading plate, Two pairs of movable pulleys for being rotatably connected to mobile loading plate lower part, connect the aeration pump for being securely fitted in mobile loading plate top Connect gas flowmeter and air delivering pipeline at aeration pump gas outlet, the gas valve being arranged on air delivering pipeline;
The Turbulent Flow processor includes the turbulent flow shell of upper end opening, is fixedly connected on turbulent flow housing cavity middle and upper part Spray pipe network is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part in turbulent flow housing cavity, is fixedly connected on turbulent flow housing cavity The aeration tube of middle and lower part, the temperature detector and liquidometer for being fixed at turbulent flow enclosure interior;
The spray pipe network is made of more interconnected spraying pipelines, and the lower part of every spraying pipeline is respectively connected with edge Multiple nozzles being connected to its inner cavity of its length direction distribution, the inlet pipe being fixedly connected with spray pipe network liquid feeding end is by rapids The upper end of stream shell is pierced by and connect with the water outlet of external water pump, and liquid inlet electromagnetic valve, the rapids are connected in inlet pipe Fluidised form adsorbing mechanism promotees reactor group at it is in cylinder that the Turbulent Flow, which promotees reactor, by several Turbulent Flows being distributed in display Shape hollow structure, surface irregularity is simultaneously equipped with the through-hole being largely connected to its inner cavity, internal that adsorption stuffing, institute are housed State aeration tube in a ring, upper part is provided with the solarization air cap being connected to its inner cavity;The outlet side of air delivering pipeline passes through turbulent flow shell Afterwards with the input end of aeration tube;
The lower part of the turbulent flow shell is precipitation section funnel-shaped, and the precipitation section is fixedly connected with and its inner cavity respectively The drain line and starch of connection outer row pipeline are connected separately with out starch control in the outer row pipeline of the starch and drain line The liquid feeding end of valve and liquid valve, the outer row pipeline of starch and drain line is located at the bottom and middle part of precipitation section;
The raw material conveying device is located at the side of job platform, and raw material conveying device includes being obliquely installed in box-type The conveying shell of structure and the rack of support conveying shell, the conveying enclosure interior are provided with conveyer belt, drive roll, driven Roller, the first bend pulley, second bend pulley, block roller and pressure roller, driven roller arranged side by side and the first bend pulley point The left part and right part of conveying shell upper end are not rotatably connected to by the short axle of its front and rear sides, arranged side by side second changes The short axle for passing through its front and rear sides respectively to roller and drive roll is rotatably connected to left part and the right side of conveying shell lower end Portion, and the short axle of drive roll side is pierced by the output after conveying shell with the feed drive motor for being fixed on conveying hull outside Axis connection, the conveyer belt are wound around the outside of driven roller, the first bend pulley, drive roll and second bend pulley, gear The lower part of the first bend pulley is correspondingly arranged in the first bend pulley for roller, to cooperate the first bend pulley to realize conveyer belt The changed course on top, pressure roller and second bend pulley are arranged in correspondence in the lower part of second bend pulley, with cooperation the second changed course rolling Cylinder realizes the changed course of conveyer belt lower part;The lower end and upper end for conveying shell are respectively arranged with the feed hopper communicated with its chamber and go out Expect hopper, center outer surface is connected with several circumferential equally distributed material containing casees to conveyer belt in the front-back direction, and material containing case is separate Conveyer belt it is open at one end;The conveying shell is extended obliquely upward by ground, and the lower end for the hopper that discharges extend into medicament and mixes Close the upper open end inner upper of shell;
Solenoid valve A, aeration pump, gas flowmeter, gas valve, temperature detector, liquidometer, water pump, liquid inlet electromagnetic valve, go out Starch control valve, liquid valve, temperature sensor, solenoid valve B, solenoid valve C, solenoid valve D, solenoid valve E and feed drive motor are equal It is connect with control system.
In the technical scheme, cornstarch is added into material containing case by the feed hopper of raw material conveying device, conveyed During driving motor drives conveyer belt, the material containing case equipped with raw material is driven to move obliquely upward, the material containing case equipped with raw material The raw material that can be flipped after driven roller, and then be stored in material containing case originally can be fallen by the hopper that discharges, and It into the upper open end of medicament mixing apparatus, first passes through medicament injection pipe and acetic anhydride is added into medicament mixing apparatus, to carry out Phosphorus oxychloride after a certain period of time, then by additive filler pipe is filled into medicament mixing apparatus by acetylization reaction, reaction, with Cross-linking reaction is carried out, so as to be denaturalized cornstarch, the sprayed high-temperature steam of steam injection pipe can guarantee that acetylation is anti- Should be with reaction temperature when cross-linking reaction, the mixed liquor containing composite modified starch leads under the action of kinetic pump after reaction It crosses confection discharge pipe and addition pipeline is filled into Turbulent Flow processor, make Turbulent Flow processor top that spray tube is set Net, can be easy to implement the rapidly and uniformly injection of clear water, and the setting of more spraying pipelines and multiple nozzles, can make to be conducive to plus Enter the rapid dispersion of clear water, so as to be convenient for being diluted to the mixed liquor containing composite modified starch, passes through the process energy Unreacted acetic anhydride and phosphorus oxychloride are melted into clear water, and then are conducive to the precipitating of composite modified starch.Aeration tube is set Setting can evenly and rapidly be added convenient for fresh air, and can uniformly come into full contact with the liquid of whereabouts and form bubble, and bubble exists It can help to that clear water preferably melts acetic anhydride and phosphorus oxychloride is melted when rupture.In matrix it is arranged in inside Turbulent Flow processor Turbulent Flow absorber, inside is equipped with adsorption stuffing, circulates the effective absorption of row so as to Dichlorodiphenyl Acetate acid anhydride and phosphorus oxychloride, into And the quality of composite modified starch obtained can be improved.Temperature detector energy and liquidometer can be to the temperature in Turbulent Flow processor It is measured in real time with liquid level, in order to effectively monitor the processing progress to composite modified starch.After standing a period of time, Composite modified starch obtained can precipitate, and fall into the lower part of precipitation section shell, be arranged the mixed liquor on top by drain line Out, it then arranges row pipeline by starch composite modified starch is discharged.The apparatus structure is simple, and manufacturing cost is low, Operation and Maintenance side Just, being made for composite modified starch, and its quality that can improve composite modified starch can easily be realized, and production effect can be improved Rate.
Further, it is cleaned for the ease of the inside to medicament mixing apparatus, the medicament mixing apparatus further includes solid Surely the washing pipeline of medicament mixing housing tip, the one end and washing water pump of washing pipeline in medicament mixing hull outside are connected to Water outlet connection, fixed connect in one end and the lotus spray-head that cellular reactor top is arranged in of medicament mixing enclosure interior It connects;Solenoid valve F is provided on the washing pipeline;Solenoid valve F is connect with control system.The lower part squit hole face of lotus spray-head Cellular reactor, when needing to clean, lotus spray-head spray high pressure water to cellular reactor carry out high-pressure wash.
As a preference, the water outlet of the drain line is connected to external collecting tank.
As a preference, the control system is mounted on job platform.
As a preference, the aeration pump quantity is two.
As a preference, the precipitation section shell is square cone structure;The spraying pipeline quantity is no less than 6.
As a preference, the job platform is made of stainless steel plate of the thickness between 1cm~1.5cm, in operation Platform periphery is provided with safety barrier, and the safety barrier height is connected on the job platform between 80cm~120cm Ladder.
Further, the longer conveyer belt of good corrosion resistance, service life in order to obtain, the conveyer belt is by ratio of weight and the number of copies It is composed of the following components:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4- Four 136.2~245.1 parts of chlorozincate (2:1) of [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4), 3- methyl mercapto fourth 132.6~149.7 parts of acetoacetic ester, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- third Alkenyl) -4,1- phenylene] Oxymethylene] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer 138.4~ 199.1 parts, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia benzene oxygen Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of base-Isosorbide-5-Nitrae-phenylene imino group] 133.5~175.9 parts, first 135.1~175.6 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate, 124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of methyl ethyl ketoxime sealing end, 7- methyl-octanoic 123.2~ 166.8 parts, 132.6~177.2 parts of hexyl formate, 142.1~186.1 parts of polyurethane resin, mass concentration be 132mg/L~ 165.7~219.5 parts of the phosphoric acid cetyl ester sylvite of 399mg/L.
Further, the longer conveyer belt of good corrosion resistance, service life in order to obtain, the production method of the conveyer belt is such as Under:
Step 1: in more kettle reactors, distilled water and 3- methyl undecanonitrile is added, starts the stirring in more kettle reactors Machine, setting speed are 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, rise to temperature 149.0 DEG C~150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) four is added Chlorozincate (2:1) stirs evenly, and carries out reaction 126.3~137.5 minutes, and 3- methylmercapto butyric acid ethyl ester is added, is passed through flow For 125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes;It is added in more kettle reactors later golden yellow hidden Colour solid, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation 126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2 ~8.9, keep the temperature 126.2~366.2 minutes;
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication After 0.132~1.199 hour;Pb nanoparticles are added in another more kettle reactor, addition mass concentration is 136mg/L [Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of~366mg/L (dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8 ×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes;It is quiet to stop reaction later It sets 6.66 × 10~12.1 × 10 minutes, removes impurity;Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732 ×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding 0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionising radiation spoke after mixing According to the energy of ionizing radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time is 135.2~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change;By alkali formula cupric phosphate and lead Nanoparticle mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, setting temperature 134.6 DEG C~180.2 DEG C of degree starts the blender in more kettle reactors, and revolving speed is 126rpm~521rpm, and pH is adjusted to 4.1 Between~8.1, it is dehydrated 135.1~149.1 minutes, it is spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L~366mg/L blocks, cocurrent adds to the 1st In more kettle reactors of step, flow acceleration is 271mL/min~999mL/min;Start more kettle reaction mechanical stirrers, setting speed For 140rpm~180rpm;Stirring 4~8 minutes;7- methyl-octanoic is added, the seal steam heat in more kettle reactors is started Exchanger is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/ Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes;More kettle reaction mechanical stirrers are again started up, revolving speed is 135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points Clock;
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts more kettle reactions Seal steam heat exchanger in device sets temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, it is added Polyurethane resin reacts 126.2~137.1 minutes;Phosphoric acid cetyl ester sylvite is added later, starts in more kettle reactors Seal steam heat exchanger, sets temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, pH adjust to 4.2~8.2 it Between, pressure is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to 126.2 DEG C~137.1 DEG C discharge into molding press to get to conveyer belt;
The partial size of the Pb nanoparticles is 140 μm~150 μm.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention;
Fig. 2 is the structural schematic diagram of Turbulent Flow processor in the present invention;
Fig. 3 is the structural schematic diagram of Chinese medicine mixing apparatus of the present invention;
Fig. 4 is the structural schematic diagram of mobile gas transmission station in the present invention;
Fig. 5 is the structural schematic diagram of raw material conveying device in the present invention;
Fig. 6 is the service life of conveyer belt in the present invention with the curve graph for using time change.
In figure: 1, ladder, 2, job platform, 3, medicament mixing apparatus, 3-1, confection discharge pipe, 3-2, steam spray Penetrate pipeline, 3-3, cellular reactor, 3-4, additive charging line, 3-5, medicament filling line, 3-6, washing pipeline, 3-7, Temperature sensor, 3-8, pedestal, 3-9, medicament mixing shell, 3-10, steam supply pipe road, 4, addition pipeline, 5, at Turbulent Flow Device is managed, 5-1, liquid inlet electromagnetic valve, 5-2, spraying pipeline, 5-3, Turbulent Flow promote reactor, 5-4, precipitation section, 5-5, liquid valve, 5- 6, temperature detector, 5-7, liquidometer, 5-8, aeration tube, the outer row pipeline of 5-9, starch, 5-10, drain line, 5-11, turbulent flow shell Body, 5-12, out starch control valve, 6, mobile gas transmission station, 6-1, movable pulley, 6-2, mobile loading plate, 6-3, aeration pump, 6-4, Gas flowmeter, 6-5, gas valve, 6-6, air delivering pipeline, 7, control system, 9-1, conveying shell, 9-2, rack, 9-3, conveying Band, 9-4, drive roll, 9-5, driven roller, 9-6, the first bend pulley, 9-7, second bend pulley, 9-8, block roller, 9-9, Pressure roller, 9-10, feed hopper, 9-11, discharging hopper, 9-12, material containing case.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
As shown in Figures 1 to 5, a kind of production equipment for cornstarch, including the work vacantly installed by bracket one Industry platform 2 further includes medicament mixing apparatus 3, mobile gas transmission station 6, control system 7 and raw material conveying device 9, the operation horizontal The side of platform 2 has vacantly installed Turbulent Flow processor 5 by bracket two, and the medicament mixing apparatus 3 passes through the fixed branch of pedestal 3-8 It is located at the lower part of job platform 2;
The medicament mixing apparatus 3 includes in medicament mixing the shell 3-9, the medicament mixing shell 3-9 of upper end opening Middle part and lower part be fixedly installed cellular reactor 3-3 and vapor injection line 3-2 respectively, medicament mixing shell 3-9's Bottom is fixedly connected with the confection discharge pipe 3-1 being connected to its inner cavity, and the top of medicament mixing shell 3-9 is fixedly connected There are the medicament filling line 3-5 being connected to its inner cavity and additive charging line 3-4, also fixation is set in medicament mixing shell 3-9 It is equipped with temperature sensor 3-7;The section of the cellular reactor 3-3 is honeycomb, and up and down, by more honeycombs The standpipe of arrangement forms;The vapor injection line 3-2 is annular in shape, and upper surface is provided with throughout ground to be connected to its inner cavity Through-hole, the steam supply pipe road 3-10 of connection vapor injection line 3-2 steam after being pierced by medicament mixing shell 3-9 with external high pressure The connection of steam pipe road;By the setting of vapor injection line 3-2 high temperature can be equably ejected to the cellular reactor 3-3 on top Steam, to promote the reaction of medicament;The outlet end of the confection discharge pipe 3-1 passes through pressure pump and is fixedly connected on The liquid feeding end of the side addition pipeline 4 on 5 top of Turbulent Flow processor is fixedly connected, and is added and is provided with solenoid valve A on pipeline 4;Institute State addition pipeline 4, confection discharge pipe 3-1, medicament filling line 3-5, additive charging line 3-4 and steam supply pipe Solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E are respectively arranged on the 3-10 of road;Medicament, additive respectively from Medicament injection pipe 3-5, medicament injection pipe 3-5 are filled into medicament mixing apparatus 3, the sprayed high-temperature steam of steam injection pipe 3-2 Promote medicament in cellular reactor 3-3 internal-response, after be discharged from confection delivery pipe 3-1;
The lower part of Turbulent Flow processor 5 is arranged in the movable type gas transmission station 6, and mobile gas transmission station 6 includes mobile carrying Plate 6-2, two couples of movable pulley 6-1 for being rotatably connected to the lower part mobile loading plate 6-2, it is securely fitted in mobile loading plate 6-2 The aeration pump 6-3 on top, it is connected to gas flowmeter 6-4 and air delivering pipeline 6-6 at the gas outlet aeration pump 6-3, is arranged in gas transmission Gas valve 6-5 on pipeline 6-6;Brake gear can be set on movable pulley 6-1, be also provided with for driving its rotation Driving motor.
The Turbulent Flow processor 5 includes the turbulent flow shell 5-11 of upper end opening, is fixedly connected in turbulent flow shell 5-11 The spray pipe network of chamber middle and upper part is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part in the inner cavity turbulent flow shell 5-11, is fixedly connected Aeration tube 5-8, the temperature detector 5-6 that is fixed inside turbulent flow shell 5-11 in the turbulent flow inner cavity shell 5-11 middle and lower part With liquidometer 5-7;
The spray pipe network is made of more interconnected spraying pipeline 5-2, and the lower part of every spraying pipeline 5-2 connects It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end Road 5-13 is pierced by by the upper end of turbulent flow shell 5-11 and is connect with the water outlet of external water pump, is connected on inlet pipe 5-13 Liquid inlet electromagnetic valve 5-1, the Turbulent Flow adsorbing mechanism promote reactor 5-3 by several Turbulent Flows being distributed in display and form, The Turbulent Flow promotees the cylindrical hollow structure of reactor 5-3, and surface irregularity and being equipped with largely is connected to its inner cavity Through-hole, internal that adsorption stuffing is housed, in a ring, upper part is provided with the aeration being connected to its inner cavity to the aeration tube 5-8 Hole;Input end of the outlet side of air delivering pipeline 6-6 after turbulent flow shell 5-11 with aeration tube 5-8;
The lower part of the turbulent flow shell 5-11 is precipitation section 5-4 funnel-shaped, and the precipitation section 5-4 is respectively fixedly connected with There are row pipeline 5-9 outside the drain line 5-10 and starch being connected to its inner cavity, the outer row pipeline 5-9 and drain line 5- of the starch Starch control valve 5-12 and liquid valve 5-5, the feed liquor of starch outer row pipeline 5-9 and drain line 5-10 are connected separately with out on 10 End is located at the bottom and middle part of precipitation section 5-4;
The raw material conveying device 9 is located at the side of job platform 2, and raw material conveying device 9 includes being obliquely installed in case The rack 9-2, the conveying shell 9-1 of the conveying shell 9-1 and support conveying shell 9-1 of body formula structure are internally provided with conveying Band 9-3, drive roll 9-4, driven roller 9-5, the first bend pulley 9-6, second bend pulley 9-7, block roller 9-8 and pressure roller 9- The short axle that 9, driven roller 9-5 arranged side by side and the first bend pulley 9-6 pass through its front and rear sides respectively is rotatably coupled Left part and right part in the conveying upper end shell 9-1, second bend pulley 9-7 arranged side by side and drive roll 9-4 pass through respectively The short axle of its front and rear sides is rotatably connected to the left part and right part of the conveying lower end shell 9-1, and drive roll 9-4 side Short axle is pierced by the output axis connection after conveying shell 9-1 with the feed drive motor being fixed on outside conveying shell 9-1, described defeated The outside that driven roller 9-5, the first bend pulley 9-6, drive roll 9-4 and second bend pulley 9-7 are wound around with 9-3 is sent, The lower part of the first bend pulley 9-6 is correspondingly arranged in the first bend pulley 9-6 by block roller 9-8, with cooperation the first changed course rolling Cylinder 9-6 realizes the changed course on the top conveyer belt 9-3, and pressure roller 9-9 and second bend pulley 9-7 are arranged in correspondence in second bend pulley The lower part of 9-7, to cooperate second bend pulley 9-7 to realize the changed course of the lower part conveyer belt 9-3;Convey the lower end of shell 9-1 and upper End is respectively arranged with the feed hopper 9-10 communicated with its chamber and the hopper 9-11 that discharges, and conveyer belt 9-3 is in the front-back direction outside middle part Surface is connected with several circumferential equally distributed material containing case 9-12, and material containing case 9-12 is open at one end far from conveyer belt 9-3's;Institute It states conveying shell 9-1 to be extended obliquely upward by ground, and the lower end for the hopper 9-11 that discharges extend into the upper of medicament mixing shell 3-9 Open end inner upper;
Solenoid valve A, aeration pump 6-3, gas flowmeter 6-4, gas valve 6-5, temperature detector 5-6, liquidometer 5-7, water Pump, goes out starch control valve 5-12, liquid valve 5-5, temperature sensor 3-7, solenoid valve B, solenoid valve C, electricity at liquid inlet electromagnetic valve 5-1 Magnet valve D, solenoid valve E and feed drive motor are connect with control system 7.
The control system 7 is mounted on job platform 2.
The medicament mixing apparatus 3 further includes the washing pipeline 3-6 for being fixedly connected on the top medicament mixing shell 3-9, is washed The one end of pipeline 3-6 outside medicament mixing shell 3-9 is washed to connect with the water outlet of washing water pump, in medicament mixing shell 3-9 Internal one end is fixedly connected with the lotus spray-head that the top cellular reactor 3-3 is arranged in;It is arranged on the washing pipeline 3-6 There is solenoid valve F;Solenoid valve F is connect with control system 7.
The temperature detector 5-6 is mounted on turbulent flow shell 5-11 inner sidewall, apart from the upper end turbulent flow shell 5-11 Distance is between 15cm~25cm;The liquidometer 5-7 is set on inner wall, and liquidometer 5-7 is apart from the bottom end turbulent flow shell 5-11 Distance between 40cm~60cm.
The water outlet of the drain line 5-10 is connected to external collecting tank.
The movable plate 6-2 is the galvanized sheet of rectangle.
The aeration pump 6-3 quantity is two.
The precipitation section shell 5-4-5 is square cone structure;The spraying pipeline 5-2 quantity is no less than 6.
The job platform 2 is made of stainless steel plate of the thickness between 1cm~1.5cm, is arranged on 2 periphery of job platform There is safety barrier, the safety barrier height is connected with ladder 1 on the job platform 2 between 80cm~120cm.
Further, the longer conveyer belt 9-3 of good corrosion resistance, service life in order to obtain, the conveyer belt 9-3 is by weight Portion rate is composed of the following components:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4- Four 136.2~245.1 parts of chlorozincate (2:1) of [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4), 3- methyl mercapto fourth 132.6~149.7 parts of acetoacetic ester, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- third Alkenyl) -4,1- phenylene] Oxymethylene] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer 138.4~ 199.1 parts, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia benzene oxygen Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of base-Isosorbide-5-Nitrae-phenylene imino group] 133.5~175.9 parts, first 135.1~175.6 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate, 124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of methyl ethyl ketoxime sealing end, 7- methyl-octanoic 123.2~ 166.8 parts, 132.6~177.2 parts of hexyl formate, 142.1~186.1 parts of polyurethane resin, mass concentration be 132mg/L~ 165.7~219.5 parts of the phosphoric acid cetyl ester sylvite of 399mg/L.
Further, the longer conveyer belt 9-3 of good corrosion resistance, service life in order to obtain, the production of the conveyer belt 9-3 Method is as follows:
Step 1: in more kettle reactors, distilled water and 3- methyl undecanonitrile is added, starts the stirring in more kettle reactors Machine, setting speed are 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, rise to temperature 149.0 DEG C~150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) four is added Chlorozincate (2:1) stirs evenly, and carries out reaction 126.3~137.5 minutes, and 3- methylmercapto butyric acid ethyl ester is added, is passed through flow For 125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes;It is added in more kettle reactors later golden yellow hidden Colour solid, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation 126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2 ~8.9, keep the temperature 126.2~366.2 minutes;
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication After 0.132~1.199 hour;Pb nanoparticles are added in another more kettle reactor, addition mass concentration is 136mg/L [Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of~366mg/L (dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8 ×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes;It is quiet to stop reaction later It sets 6.66 × 10~12.1 × 10 minutes, removes impurity;Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732 ×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding 0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionising radiation spoke after mixing According to the energy of ionizing radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time is 135.2~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change;By alkali formula cupric phosphate and lead Nanoparticle mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, setting temperature 134.6 DEG C~180.2 DEG C of degree starts the blender in more kettle reactors, and revolving speed is 126rpm~521rpm, and pH is adjusted to 4.1 Between~8.1, it is dehydrated 135.1~149.1 minutes, it is spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L~366mg/L blocks, cocurrent adds to the 1st In more kettle reactors of step, flow acceleration is 271mL/min~999mL/min;Start more kettle reaction mechanical stirrers, setting speed For 140rpm~180rpm;Stirring 4~8 minutes;7- methyl-octanoic is added, the seal steam heat in more kettle reactors is started Exchanger is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/ Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes;More kettle reaction mechanical stirrers are again started up, revolving speed is 135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points Clock;
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts more kettle reactions Seal steam heat exchanger in device sets temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, it is added Polyurethane resin reacts 126.2~137.1 minutes;Phosphoric acid cetyl ester sylvite is added later, starts in more kettle reactors Seal steam heat exchanger, sets temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, pH adjust to 4.2~8.2 it Between, pressure is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to 126.2 DEG C~137.1 DEG C discharge into molding press to get to conveyer belt 9-3;
The partial size of the Pb nanoparticles is 140 μm~150 μm.
Following embodiment further illustrates the contents of the present invention, and as conveyer belt 9-3, it is significant components of the invention, Due to its presence, the service life of integral device is increased, it plays crucial work for the safety of integral device, even running With.For this purpose, by it is following be embodiment, further verify conveyer belt 9-3 of the present invention, shown be higher than other phases Close the physical characteristic of patent.
Embodiment 1
Conveyer belt 9-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 133.3 parts of 341.0 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles Blender in reactor, setting speed 134rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter To 149.0 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added 136.2 parts of salt (2:1) stirs evenly, and carries out reaction 126.3 minutes, and 132.6 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow For 125.1m3The fluorine gas of/min 126.3 minutes;135.2 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up Seal steam heat exchanger in more kettle reactors makes temperature rise to 166.2 DEG C, keeps the temperature 126.6 minutes, and 2,2'- [(1- is added Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl 138.4 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 4.2, keeps the temperature 126.2 minutes;
Step 2: separately taking 140.9 parts of Pb nanoparticles, by Pb nanoparticles power be 6.66KW under ultrasonication After 0.132 hour;Pb nanoparticles are added in another more kettle reactor, the polymerization that mass concentration is 136mg/L is added [Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 133.5 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors Device makes solution temperature at 46 DEG C, starts the blender in more kettle reactors, and with 4 × 102The speed of rpm stirs, and adjusts pH value 4.4, insulated and stirred 132 minutes;Stop reaction later and stand 6.66 × 10 minutes, removes impurity;Formaldehyde is added in suspension With 135.1 parts of polymer of binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value forms sediment distillation washing 1.4 It is de-, by centrifuge in revolving speed 4.732 × 103Solid content is obtained under rpm, 2.95 × 102It is dry at a temperature of DEG C, mistake after grinding 0.732×103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate 135.6 and step 2 to handle, after mixing using ionization spoke Irradiation is penetrated, the energy of ionizing radiation is 123.2MeV, dosage 171.2kGy, irradiation time are 135.2 minutes, obtaining property The alkali formula cupric phosphate and Pb nanoparticles mixture that shape changes;Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another more In kettle reactor, starts the seal steam heat exchanger in more kettle reactors, 134.6 DEG C of set temperature, start more kettle reactors In blender, revolving speed 126rpm, pH are adjusted to 4.1, are dehydrated 135.1 minutes, spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes In 124.4 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L blocks, cocurrent adds to step 1 More kettle reactors in, flow acceleration 271mL/min;Start more kettle reaction mechanical stirrers, setting speed 140rpm;Stirring 4 minutes;123.2 parts of 7- methyl-octanoic are added, starts the seal steam heat exchanger in more kettle reactors, is warming up to 170.7 DEG C, pH is adjusted to 4.7, and being passed through fluorine gas ventilatory capacity is 125.293m3/ min, heat preservation stand 160.0 minutes;It is anti-to be again started up more kettles Mechanical stirrer is answered, revolving speed 135rpm is added 132.6 parts of hexyl formate, and pH is made to be adjusted to 4.7, and heat preservation stands 159.3 points Clock;
Step 5: starting the blender in more kettle reactors, and setting speed 132rpm starts the vapour in more kettle reactors Gland steam heat exchanger sets temperature in more kettle reactors as 1.581 × 102DEG C, 142.1 parts of polyurethane resin are added, instead It answers 126.2 minutes;165.7 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 132mg/L is added later, starts more kettle reactions Seal steam heat exchanger in device, sets temperature in more kettle reactors as 210.6 DEG C, and pH is adjusted to 4.2, and pressure is 1.32MPa, reaction time are 0.4 hour;Be depressurized to later gauge pressure be 0MPa, be cooled to 126.2 DEG C discharge into molding press to get To conveyer belt 9-3;The partial size of the Pb nanoparticles is 140 μm.
Embodiment 2
Conveyer belt 9-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 175.5 parts of 566.2 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles Blender in reactor, setting speed 180rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter To 150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added 245.1 parts of salt (2:1) stirs evenly, and carries out reaction 137.5 minutes, and 149.7 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow For 166.7m3The fluorine gas of/min 137.5 minutes;192.9 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up Seal steam heat exchanger in more kettle reactors makes temperature rise to 199.1 DEG C, keeps the temperature 137.7 minutes, and 2,2'- [(1- is added Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl 199.1 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 8.9, keeps the temperature 366.2 minutes;
Step 2: separately taking 195.2 parts of Pb nanoparticles, by Pb nanoparticles power be 12.1KW under ultrasonication 1.199 after hour;Pb nanoparticles are added in another more kettle reactor, the polymerization that mass concentration is 366mg/L is added [Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 175.9 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors Device makes solution temperature between 86 DEG C, starts the blender in more kettle reactors, and with 8 × 102The speed of rpm stirs, adjustment PH value is 8.8, insulated and stirred 199 minutes;Stop reaction later and stand 12.1 × 10 minutes, removes impurity;Suspension is added 175.6 parts of polymer of formaldehyde and binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value form sediment distillation 2.8 Water elution, by centrifuge in revolving speed 9.23 × 103Solid content is obtained under rpm, 3.419 × 102It is dry at a temperature of DEG C, grinding 1.23 × 10 are crossed afterwards3Mesh, it is spare;
Step 3: Pb nanoparticles after 158.1 parts of alkali formula cupric phosphate and step 2 processing are separately taken, after mixing using ionization Radiation, the energy of ionizing radiation is 151.8MeV, dosage 211.8kGy, irradiation time are 160.8 minutes, is obtained The alkali formula cupric phosphate and Pb nanoparticles mixture that character changes;Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another In more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, 180.2 DEG C of set temperature, start more kettle reactions Blender in device, revolving speed 521rpm, pH are adjusted to 8.1, are dehydrated 149.1 minutes, spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes In 160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 366mg/L blocks, cocurrent adds to step 1 More kettle reactors in, flow acceleration 999mL/min;Start more kettle reaction mechanical stirrers, setting speed 180rpm;Stirring 8 minutes;166.8 parts of 7- methyl-octanoic are added, starts the seal steam heat exchanger in more kettle reactors, is warming up to 207.5 DEG C, pH is adjusted to 8.5, and being passed through fluorine gas ventilatory capacity is 166.410m3/ min, heat preservation stand 190.2 minutes;It is anti-to be again started up more kettles Mechanical stirrer is answered, revolving speed 180rpm is added 177.2 parts of hexyl formate, and pH is made to be adjusted to 8.5, and heat preservation stands 199.5 points Clock;
Step 5: starting the blender in more kettle reactors, and setting speed 199rpm starts the vapour in more kettle reactors Gland steam heat exchanger sets temperature in more kettle reactors as 2.462 × 102DEG C, 186.1 parts of polyurethane resin are added, instead It answers 137.1 minutes;219.5 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 399mg/L is added later, starts more kettle reactions Seal steam heat exchanger in device, sets temperature in more kettle reactors as 266.7 DEG C, and pH is adjusted to 8.2, and pressure is 1.33MPa, reaction time are 0.9 hour;Be depressurized to later gauge pressure be 0MPa, be cooled to 137.1 DEG C discharge into molding press to get To conveyer belt 9-3;The partial size of the Pb nanoparticles is 150 μm.
Embodiment 3
Conveyer belt 9-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 133.9 parts of 341.9 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles Blender in reactor, setting speed 134rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter To 149.9 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added 136.9 parts of salt (2:1) stirs evenly, and carries out reaction 126.9 minutes, and 132.9 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow For 125.9m3The fluorine gas of/min 126.9 minutes;135.9 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up Seal steam heat exchanger in more kettle reactors makes temperature rise to 166.9 DEG C, keeps the temperature 126.9 minutes, and 2,2'- [(1- is added Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl 138.9 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 4.9, keeps the temperature 126.9 minutes;
Step 2: separately taking 140.9 parts of Pb nanoparticles, by Pb nanoparticles power be 6.669KW under ultrasonication After 0.1329 hour;Pb nanoparticles are added in another more kettle reactor, it is the poly- of 136.9mg/L that mass concentration, which is added, Close [Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group Base) carbon-based imino group
Isosorbide-5-Nitrae-Asia benzene] 133.9 parts of dispersion Pb nanoparticles, start the seal steam heat exchanger in more kettle reactors, makes Solution temperature starts the blender in more kettle reactors at 46.9 DEG C, and with 4.9 × 102The speed of rpm stirs, and adjusts pH value 4.9, insulated and stirred 132.9 minutes;Stop reaction later and stand 6.66 × 10 minutes, removes impurity;First is added in suspension 135.9 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value form sediment distilled water 1.9 Elution, by centrifuge in revolving speed 4.732 × 103Solid content is obtained under rpm, 2.95 × 102It is dry at a temperature of DEG C, after grinding Cross 0.732 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate 135.9 and step 2 to handle, after mixing using ionization spoke Irradiation is penetrated, the energy of ionizing radiation is 123.9MeV, dosage 171.9kGy, irradiation time are 135.9 minutes, obtaining property The alkali formula cupric phosphate and Pb nanoparticles mixture that shape changes;Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another more In kettle reactor, starts the seal steam heat exchanger in more kettle reactors, 134.9 DEG C of set temperature, start more kettle reactors In blender, revolving speed 126rpm, pH are adjusted to 4.9, are dehydrated 135.9 minutes, spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes In 124.9 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136.9mg/L blocks, cocurrent adds to the 1st In more kettle reactors of step, flow acceleration 271.9mL/min;Start more kettle reaction mechanical stirrers, setting speed 140rpm; Stirring 4.9 minutes;123.9 parts of 7- methyl-octanoic are added, the seal steam heat exchanger in more kettle reactors is started, is heated up To 170.9 DEG C, pH is adjusted to 4.9, and being passed through fluorine gas ventilatory capacity is 125.9m3/ min, heat preservation stand 160.9 minutes;It is again started up More kettles react mechanical stirrer, and revolving speed 135rpm is added 132.9 parts of hexyl formate, and pH is made to be adjusted to 4.9, and heat preservation is stood 159.9 minute;
Step 5: starting the blender in more kettle reactors, and setting speed 132rpm starts the vapour in more kettle reactors Gland steam heat exchanger sets temperature in more kettle reactors as 1.581 × 102DEG C, 142.9 parts of polyurethane resin are added, instead It answers 126.9 minutes;165.7 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 132mg/L is added later, starts more kettle reactions Seal steam heat exchanger in device, sets temperature in more kettle reactors as 210.9 DEG C, and pH is adjusted to 4.9, and pressure is 1.32MPa, reaction time are 0.41 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to 126.9 DEG C and discharges into molding press, i.e., Obtain conveyer belt 9-3;The partial size of the Pb nanoparticles is 140 μm.
Reference examples
Reference examples are tested for the property test using the conveyer belt of certain commercially available brand.
Embodiment 4
Examples 1 to 3 and reference examples conveyer belt 9-3 obtained are tested for the property test, fought after test The parameters such as Compressive Strength enhancing rate, resistance to deformation strength enhancing rate, partition service life enhancing rate, impact resistance enhancing rate are divided Analysis.Data analysis is as shown in table 1.
As seen from Table 1, conveyer belt 9-3 of the present invention is raw obviously higher than the prior art in Specifications The product of production.
In addition, as shown in fig. 6, the production that Examples 1 to 3 in Specifications, is substantially produced better than the prior art Product.
Working method of one of the present invention for the production equipment of cornstarch, this method includes following step It is rapid:
Step 1: the work of feed drive motor is controlled by control system 7, and solenoid valve E and solenoid valve C is opened, in benefit While entering medicament mixing apparatus with raw material conveying device conveying cornstarch, steam supply pipe road 3-10 feeds steam, together When, medicament injection pipe 3-5 feeds acetic anhydride, to can be carried out acetylization reaction, after reacting setting time, then is added by additive It infuses pipe 3-4 and phosphorus oxychloride is added, meanwhile, continue the supply of steam, then carry out cross-linking reaction, forms sediment to be made containing complex denaturation The mixed liquor of powder;
Mixing liquid in medicament mixing shell 3-9 is fed Turbulent Flow processing equipment 5 by control kinetic pump by step 2 In, liquid inlet electromagnetic valve 5-1 is opened by control system 7, will be fed containing clear water using pressure pump, and pass through spraying pipeline 5-2 With being sprayed onto Turbulent Flow processor 5 for the even action of nozzle, start movable type after 15min, then through control system 7 Aeration pump 6-3 on gas transmission station 6 opens simultaneously the gas valve 6-5 on air delivering pipeline 6-6, by aeration tube 5-8 by fresh air Turbulent Flow processor 5 is fed, so as to be convenient for uniformly diluting the progress of the mixed liquor containing composite modified starch, by this Unreacted acetic anhydride and phosphorus oxychloride can be melted into clear water by process, and then be conducive to the precipitating of composite modified starch.Precipitating Composite modified starch afterwards imports the bottom of precipitation section 5-4, mixed liquor is discharged by drain line 5-10, then pass through sediment Composite modified starch obtained is discharged through row pipeline 5-9 outside starch;
Step 3: the adsorption stuffing in Turbulent Flow absorber 5-3 can inhale unreacted acetic anhydride and phosphorus oxychloride It is attached, in the process, the temperature in temperature detector 5-6 real-time monitoring Turbulent Flow processor 5;It is when detecting that temperature is higher than When system setting value T, electric signal is fed back to control system 7 by temperature detector 5-6, and control system 7 controls coupled report Alert device sounds an alarm, to notify operator to take cooling measure;
Step 4: liquidometer 5-7 real-time monitoring Turbulent Flow promotees the liquid level of mixing liquid in reactor 5-3;As liquidometer 5-7 When detecting that clear water liquid level is higher than default value M, signal is fed back to control system 7 by liquidometer 5-7, and control system 7 is opened Internal liquid is discharged in time by drain line 5-10 by liquid valve 5-5;
Step 5: the conveying capacity of the gas flowmeter 6-4 real-time monitoring air on mobile gas transmission station 6;Work as gas flowmeter When 6-4 detects conveying capacity lower than default value P, feedback signal is sent to control system 7 by gas flowmeter 6-4, control System 7 improves aeration pump 6-3 revolving speed, while increasing gas valve 6-5 aperture, to guarantee the supply of gas.

Claims (10)

1. a kind of production equipment for cornstarch, including the job platform (2) vacantly installed by bracket one, feature exists In further including medicament mixing apparatus (3), mobile gas transmission station (6), control system (7) and raw material conveying device (9), the work The side of industry platform (2) has vacantly been installed Turbulent Flow processor (5) by bracket two, and the medicament mixing apparatus (3) passes through base The fixed branch of seat (3-8) is located at the lower part of job platform (2);
The medicament mixing apparatus (3) includes the medicament mixing shell (3-9) of upper end opening, the medicament mixing shell (3-9) Interior middle part and lower part is fixedly installed cellular reactor (3-3) and vapor injection line (3-2), medicament mixing shell respectively The bottom of (3-9) is fixedly connected with the confection discharge pipe (3-1) being connected to its inner cavity, medicament mixing shell (3-9) Top is fixedly connected with the medicament filling line (3-5) and additive charging line (3-4) being connected to its inner cavity, medicament mixed shell Temperature sensor (3-7) is further fixedly arranged in body (3-9);The section of the cellular reactor (3-3) is honeycomb, and on Lower perforation, is made of the standpipe of more honeycomb arrangements;The vapor injection line (3-2) is annular in shape, upper surface time It is provided with to cloth the through-hole being connected to its inner cavity, the steam supply pipe road (3-10) of connection vapor injection line (3-2) is pierced by medicine Agent mixing shell (3-9) is connect with external high steam pipeline afterwards;The outlet end of the confection discharge pipe (3-1) is logical Excess pressure pumps the liquid feeding end for adding pipeline (4) with the side for being fixedly connected on Turbulent Flow processor (5) top and is fixedly connected, and adds Pipeline is provided with solenoid valve A on (4);The addition pipeline (4), confection discharge pipe (3-1), medicament filling line (3- 5) solenoid valve A, solenoid valve B, solenoid valve, are respectively arranged on additive charging line (3-4) and steam supply pipe road (3-10) C, solenoid valve D and solenoid valve E;
The movable type gas transmission station (6) is arranged in the lower part of Turbulent Flow processor (5), and mobile gas transmission station (6) includes that movement is held Support plate (6-2), two pairs of movable pulleys (6-1) for being rotatably connected to the lower part mobile loading plate (6-2) are securely fitted in mobile hold The aeration pump (6-3) on the top support plate (6-2) is connected to gas flowmeter (6-4) and air delivering pipeline at the gas outlet aeration pump (6-3) (6-6), the gas valve (6-5) being arranged on air delivering pipeline (6-6);
The Turbulent Flow processor (5) includes the turbulent flow shell (5-11) of upper end opening, is fixedly connected on turbulent flow shell (5-11) The spray pipe network of inner cavity middle and upper part is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part, fixation in the inner cavity turbulent flow shell (5-11) It is connected to the aeration tube (5-8) of the inner cavity middle and lower part turbulent flow shell (5-11), is fixed at the internal temperature of turbulent flow shell (5-11) Spend detector (5-6) and liquidometer (5-7);
The spray pipe network is made of more interconnected spraying pipelines (5-2), and the lower part of every spraying pipeline (5-2) connects It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end Road (5-13) is pierced by by the upper end of turbulent flow shell (5-11) and is connect with the water outlet of external water pump, in inlet pipe (5-13) It is connected with liquid inlet electromagnetic valve (5-1), the Turbulent Flow adsorbing mechanism promotees reactor by several Turbulent Flows being distributed in display (5-3) composition, the Turbulent Flow promote reactor (5-3) cylindrical hollow structure, and surface irregularity is simultaneously equipped with a large amount of The through-hole being connected to its inner cavity, internal that adsorption stuffing is housed, in a ring, upper part is provided with and it for the aeration tube (5-8) The solarization air cap of inner cavity connection;The outlet side of air delivering pipeline (6-6) passes through turbulent flow shell (5-11) import with aeration tube (5-8) afterwards End;
The lower part of the turbulent flow shell (5-11) is precipitation section (5-4) funnel-shaped, and the precipitation section (5-4) is fixed respectively to be connected It is connected to the drain line (5-10) being connected to its inner cavity and the outer row pipeline (5-9) of starch, the outer row pipeline (5-9) of the starch and row Starch control valve (5-12) and liquid valve (5-5), the outer row pipeline (5-9) of starch and row are connected separately with out on liquid pipeline (5-10) The liquid feeding end of liquid pipeline (5-10) is located at the bottom and middle part of precipitation section (5-4);
The raw material conveying device (9) is located at the side of job platform (2), raw material conveying device (9) include be obliquely installed be in The conveying shell (9-1) of box typed structure and the rack (9-2) of support conveying shell (9-1), the conveying shell (9-1) are internal It is provided with conveyer belt (9-3), drive roll (9-4), driven roller (9-5), the first bend pulley (9-6), second bend pulley (9-7), block roller (9-8) and pressure roller (9-9), driven roller arranged side by side (9-5) and the first bend pulley (9-6) pass through respectively The short axle of its front and rear sides is rotatably connected to the left part and right part of conveying upper end shell (9-1), and arranged side by side second changes Conveying shell (9-1) is rotatably connected to by the short axle of its front and rear sides respectively to roller (9-7) and drive roll (9-4) The left part and right part of lower end, and the short axle of the side drive roll (9-4) be pierced by conveying shell (9-1) afterwards be fixed on conveying shell The output axis connection of (9-1) external feed drive motor, the conveyer belt (9-3) are wound around driven roller (9-5), first change To the outside of roller (9-6), drive roll (9-4) and second bend pulley (9-7), block roller (9-8) and the first bend pulley (9- 6) lower part of the first bend pulley (9-6) is correspondingly set, to cooperate the first bend pulley (9-6) to realize conveyer belt (9- 3) changed course on top, pressure roller (9-9) and second bend pulley (9-7) are arranged in correspondence in the lower part of second bend pulley (9-7), To cooperate second bend pulley (9-7) to realize the changed course of the lower part conveyer belt (9-3);Convey the lower end and upper end point of shell (9-1) Be not provided with the feed hopper (9-10) communicated with its chamber and discharging hopper (9-11), conveyer belt (9-3) in the front-back direction middle part Outer surface is connected with several circumferential equally distributed material containing casees (9-12), material containing case (9-12) far from conveyer belt (9-3) one End opening;The conveying shell (9-1) is extended obliquely upward by ground, and the lower end of discharging hopper (9-11) extend into medicament and mixes Close the upper open end inner upper of shell (3-9);
Solenoid valve A, aeration pump (6-3), gas flowmeter (6-4), gas valve (6-5), temperature detector (5-6), liquidometer (5- 7), water pump, liquid inlet electromagnetic valve (5-1), out starch control valve (5-12), liquid valve (5-5), temperature sensor (3-7), solenoid valve B, solenoid valve C, solenoid valve D, solenoid valve E and feed drive motor are connect with control system (7).
2. a kind of production equipment for cornstarch according to claim 1, which is characterized in that the medicament mixing is set Standby (3) further include the washing pipeline (3-6) for being fixedly connected on the top medicament mixing shell (3-9), and washing pipeline (3-6) is in medicament Mix the external one end shell (3-9) and the connection of the water outlet of washing water pump, in the internal one end of medicament mixing shell (3-9) and The lotus spray-head on the top cellular reactor (3-3) is arranged to be fixedly connected;Solenoid valve is provided on the washing pipeline (3-6) F;Solenoid valve F is connect with control system (7).
3. a kind of production equipment for cornstarch according to claim 1 or 2, which is characterized in that the drain pipe The water outlet on road (5-10) is connected to external collecting tank.
4. a kind of production equipment for cornstarch according to claim 3, which is characterized in that the control system (7) it is mounted on job platform (2).
5. a kind of production equipment for cornstarch according to claim 4, which is characterized in that the aeration pump (6- 3) quantity is two.
6. a kind of production equipment for cornstarch according to claim 5, which is characterized in that the precipitation section shell (5-4-5) is square cone structure;Spraying pipeline (5-2) quantity is no less than 6.
7. a kind of production equipment for cornstarch according to claim 6, which is characterized in that the job platform (2) stainless steel plate by thickness between 1cm~1.5cm is made, and job platform (2) periphery is provided with safety barrier, described Safety barrier height is connected with ladder (1) on the job platform (2) between 80cm~120cm.
8. a kind of production equipment for cornstarch according to claim 7, which is characterized in that the conveyer belt (9- 3) composed of the following components by ratio of weight and the number of copies:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4- [(4- first Base -2- nitrobenzophenone) azo] four 136.2~245.1 parts of chlorozincate (2:1) of benzene diazonium (T-4), 3- methylmercapto butyric acid ethyl ester 132.6~149.7 parts, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic)- 4,1- phenylenes] Oxymethylene] 138.4~199.1 parts of polymer of dimethyl silicone polymer of bisoxirane and hydrogen sealing end, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia phenoxy group-Isosorbide-5-Nitrae-Asia Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of phenylimino] 133.5~175.9 parts, formaldehyde and dinonyl 135.1~175.6 parts of the polymer of phenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate, methyl ethyl ketoxime envelope 124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) at end, 123.2~166.8 parts of 7- methyl-octanoic, formic acid 132.6~177.2 parts of own ester, 142.1~186.1 parts of polyurethane resin, mass concentration is the phosphoric acid of 132mg/L~399mg/L 165.7~219.5 parts of cetyl ester sylvite.
9. a kind of production equipment for cornstarch according to claim 8, which is characterized in that the conveyer belt (9- 3) the production method is as follows:
Step 1: in more kettle reactors, being added distilled water and 3- methyl undecanonitrile, start the blender in more kettle reactors, if Determine revolving speed be 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, make temperature rise to 149.0 DEG C~ 150.2 DEG C, four chlorozincate of 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) is added (2:1) is stirred evenly, and carries out reaction 126.3~137.5 minutes, 3- methylmercapto butyric acid ethyl ester is added, being passed through flow is 125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes;Golden yellow procrypsis is added in more kettle reactors later Body, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation 126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2 ~8.9, keep the temperature 126.2~366.2 minutes;
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication 0.132 After~1.199 hours;Pb nanoparticles are added in another more kettle reactor, addition mass concentration be 136mg/L~ [Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of 366mg/L (dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8 ×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes;It is quiet to stop reaction later It sets 6.66 × 10~12.1 × 10 minutes, removes impurity;Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732 ×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding 0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionizing radiation, electricity after mixing Energy from radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time 135.2 ~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change;Alkali formula cupric phosphate and lead nanometer is micro- Grain mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, set temperature 134.6 DEG C~180.2 DEG C, start the blender in more kettle reactors, revolving speed is 126rpm~521rpm, pH be adjusted to 4.1~8.1 it Between, it is dehydrated 135.1~149.1 minutes, it is spare;
Step 4: the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes, adding to mass concentration is In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of the methyl ethyl ketoxime sealing end of 136mg/L~366mg/L, cocurrent adds to step 1 In more kettle reactors, flow acceleration is 271mL/min~999mL/min;Start more kettle reaction mechanical stirrers, setting speed is 140rpm~180rpm;Stirring 4~8 minutes;7- methyl-octanoic is added, the seal steam heat started in more kettle reactors is handed over Parallel operation is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/ Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes;More kettle reaction mechanical stirrers are again started up, revolving speed is 135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points Clock;
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts in more kettle reactors Seal steam heat exchanger, set temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, poly- ammonia is added Ester resin reacts 126.2~137.1 minutes;Phosphoric acid cetyl ester sylvite is added later, starts the packing in more kettle reactors Steam heat-exchanger sets the temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, and pH is adjusted between 4.2~8.2, pressure Power is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to 126.2 DEG C~137.1 DEG C discharge into molding press to get to conveyer belt (9-3).
10. a kind of production equipment for cornstarch according to claim 9, which is characterized in that the lead nanometer is micro- The partial size of grain is 140 μm~150 μm.
CN201810812314.XA 2018-07-23 2018-07-23 A kind of production equipment for cornstarch Withdrawn CN109232750A (en)

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CN111495500A (en) * 2020-04-20 2020-08-07 孙睿 Method for compacting raw materials of enhanced rubber hose

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