CN108946893A - A kind of process units for stalk flocculant - Google Patents
A kind of process units for stalk flocculant Download PDFInfo
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- CN108946893A CN108946893A CN201810813829.1A CN201810813829A CN108946893A CN 108946893 A CN108946893 A CN 108946893A CN 201810813829 A CN201810813829 A CN 201810813829A CN 108946893 A CN108946893 A CN 108946893A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5263—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
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Abstract
A kind of process units for stalk flocculant, medicament mixing apparatus inside are equipped with cellular reactor and steam injection pipe, pass through piping connection between medicament mixing apparatus and Turbulent Flow processor top；Mobile gas transmission station includes mobile loading plate and aeration pump；Turbulent Flow processor includes the turbulent flow shell of upper end opening, turbulent flow shell lower end is equipped with spoil disposal and drain line, the spray pipe network being made of more spraying pipelines is successively arranged in inner cavity, promote reactor group by multiple Turbulent Flows at Turbulent Flow promote the aeration tube of reaction mechanism and annular, be additionally provided with temperature detector and liquidometer in turbulent flow shell；Spraying pipeline lower part is connected with nozzle, and spray pipe network is connect by inlet pipe with external water pump；Turbulent Flow promotees reactor surface and is equipped with a large amount of through-holes, and inside promotees reaction filler equipped with matchmaker；Aeration tube top is equipped with solarization air cap；The air delivering pipeline at aeration pump gas outlet is connected to be connected to aeration tube.The device can be conducive to the quick preparation of stalk flocculant.
Description
Technical field
The invention belongs to flocculant production technical fields, and in particular to a kind of process units for stalk flocculant.
Background technique
Flocculant is prepared using waste straw, can be used for sewage treatment, the effective ingredient in stalk is cellulose and lignin,
It is swollen in the presence of catalyst n aOH, and is reacted with cationic etherifying agent, generating cation must property flocculant.Staff is making
It when standby medicament, needs for various medical fluids and drug to be mixed, is adjusted to uniformly, medicament mixing could be made so sufficiently,
And then the biggish drug effect of competence exertion.It is in the prior art usually that medicament is drawn into mixer, then by the medicine in mixer
Liquid injects in surge tank, while needing mixed medicament to be put into a surge tank simultaneously for a variety of, and mechanical stirring reaches mixing
The purpose of medicament.But in such operation, the uniformity of medicament mixing is not ensured that, and mechanical agitation process is easy to make
At spilling for medicament, medicament is caused to waste.
Summary of the invention
In view of the above existing problems in the prior art, the present invention provides a kind of process units for stalk flocculant, should
Apparatus structure is simple, and manufacturing cost is low, can be conducive to the quick preparation of stalk flocculant, with stronger generalization.
To achieve the goals above, the present invention provides an a kind of process units for stalk flocculant, including passes through branch
The job platform that frame one vacantly installs further includes medicament mixing apparatus, mobile gas transmission station and control system, the job platform
Side Turbulent Flow processor has vacantly been installed by bracket two, the medicament mixing apparatus is located at operation by fixed prop up of pedestal
The lower part of platform；
The medicament mixing apparatus includes medicament mixing shell, and the intracorporal middle part of the medicament mixed shell and lower part are solid respectively
Surely cellular reactor and vapor injection line are provided with, the bottom of medicament mixing shell is fixedly connected with to be connected to its inner cavity
Confection discharge pipe, the top of medicament mixing shell are fixedly connected with the medicament filling line being connected to its inner cavity and addition
Agent charging line is further fixedly arranged on temperature sensor in medicament mixed shell body；The section of the cellular reactor is honeycomb
Shape, and up and down, it is made of the standpipe of more honeycomb arrangements；The vapor injection line is annular in shape, upper surface
The through-hole being connected to its inner cavity is provided with throughout ground, the steam supply pipe road for connecting vapor injection line is pierced by medicament mixing shell
It is connect afterwards with external high steam pipeline；The outlet end of the confection discharge pipe passes through pressure pump and is fixedly connected on
The liquid feeding end of the side addition pipeline on Turbulent Flow processor top is fixedly connected, and adding tube road is provided with solenoid valve A；It is described to add
Pipeline, confection discharge pipe, medicament filling line, additive charging line and steam supply pipe road is added to be respectively arranged with
Solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E；
The movable type gas transmission station is arranged in the lower part of Turbulent Flow processor, mobile gas transmission station include mobile loading plate,
Two pairs of movable pulleys for being rotatably connected to mobile loading plate lower part, connect the aeration pump for being securely fitted in mobile loading plate top
Connect gas flowmeter and air delivering pipeline at aeration pump gas outlet, the gas valve being arranged on air delivering pipeline；
The Turbulent Flow processor includes the turbulent flow shell of upper end opening, the sludge pipe for being fixedly connected on turbulent flow shell lower end
Road and drain line, are fixedly connected in turbulent flow housing cavity the spray pipe network for being fixedly connected on turbulent flow housing cavity middle and upper part
The Turbulent Flow rush reaction mechanism at middle part, is fixed at turbulent flow shell at the aeration tube for being fixedly connected on turbulent flow housing cavity middle and lower part
The temperature detector and liquidometer in internal portion；
The spray pipe network is made of more interconnected spraying pipelines, and the lower part of every spraying pipeline is respectively connected with edge
Multiple nozzles being connected to its inner cavity of its length direction distribution, the inlet pipe being fixedly connected with spray pipe network liquid feeding end is by rapids
The upper end of stream shell is pierced by and connect with the water outlet of external water pump, and liquid inlet electromagnetic valve, the rapids are connected in inlet pipe
Fluidised form promotees reaction mechanism and promotees reactor group at the Turbulent Flow promotees reactor in circle by several Turbulent Flows being distributed in display
Columnar hollow structure, surface irregularity is simultaneously equipped with the through-hole being largely connected to its inner cavity, internal to promote reaction equipped with matchmaker
Filler, in a ring, upper part is provided with the solarization air cap being connected to its inner cavity to the aeration tube；The outlet side of air delivering pipeline passes through rapids
Input end after stream shell with aeration tube；
It is connected separately with mud valve and liquid valve on the mud line and drain line, mud line and drain line
Liquid feeding end is located at the bottom and middle part of turbulent flow shell；
Solenoid valve A, aeration pump, gas flowmeter, gas valve, temperature detector, liquidometer, water pump, liquid inlet electromagnetic valve, go out
Slurry valve, liquid valve, temperature sensor, solenoid valve B, solenoid valve C and solenoid valve D are connect with control system.
In the technical scheme, medicament, additive are filled into medicament mixing from medicament injection pipe, additive filler pipe respectively
In equipment, the sprayed high-temperature steam of steam injection pipe promotes medicament react in cellular inside reactor, after from mixing medicine
The discharge of agent delivery pipe.By the side of Turbulent Flow processor be provided with addition pipeline, confection delivery pipe and its connect
Logical medicament mixing apparatus can easily realize that confection is injected into Turbulent Flow processor；Make Turbulent Flow processor top
Spray pipe network is set, can be easy to implement being rapidly injected for clear water, and the setting of more spraying pipelines and multiple nozzles, it can make advantageous
In the rapid dispersion that clear water is added, so as to convenient for the confection of injection carry out it is good contact, so as to improve mixing
Effect, and can be shortened incorporation time.The setting of aeration tube can evenly and rapidly be added convenient for fresh air, and can be with the liquid of whereabouts
Body uniformly comes into full contact with, so as to effectively improve the mixed effect of mixed liquor.In matrix it is arranged in inside Turbulent Flow processor
Turbulent Flow promote reactor, inside equipped with matchmaker promote reaction filler, so as to promote confection abundant reaction.Temperature inspection
Survey device can and liquidometer can in Turbulent Flow processor temperature and liquid level be measured in real time, it is mixed in order to effectively supervise
Conjunction progress.The apparatus structure is simple, and manufacturing cost is low, convenient operating maintenance, can easily realize and be wadded a quilt with cotton using stalk
The preparation of solidifying agent, with stronger generalization.
Further, it is cleaned for the ease of the inside to medicament mixing apparatus, the medicament mixing apparatus further includes solid
Surely the washing pipeline of medicament mixing housing tip, the one end and washing water pump of washing pipeline in medicament mixing hull outside are connected to
Water outlet connection, fixed connect in one end and the lotus spray-head that cellular reactor top is arranged in of medicament mixing enclosure interior
It connects；Solenoid valve F is provided on the washing pipeline；Solenoid valve F is connect with control system.The lower part squit hole face of lotus spray-head
Cellular reactor, when needing to clean, lotus spray-head spray high pressure water to cellular reactor carry out high-pressure wash.
As a preference, the water outlet of the drain line is connected to external collecting tank.
As a preference, the movable plate is the galvanized sheet of rectangle.
As a preference, the aeration pump quantity is two.
As a preference, the lower end of the turbulent flow shell is funnel-shaped；The spraying pipeline quantity is no less than 6.
As a preference, the job platform is made of stainless steel plate of the thickness between 1cm~1.5cm, in operation
Platform periphery is provided with safety barrier, and the safety barrier height is connected on the job platform between 80cm~120cm
Ladder.
Further, degradation rate is high in order to obtain, the longer cellular reactor of service life, the cellular reactor
It is composed of the following components by ratio of weight and the number of copies:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4-
Four 136.2~245.1 parts of chlorozincate (2:1) of [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4), 3- methyl mercapto fourth
132.6~149.7 parts of acetoacetic ester, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- third
Alkenyl) -4,1- phenylene] Oxymethylene] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer 138.4~
199.1 parts, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia benzene oxygen
Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of base-Isosorbide-5-Nitrae-phenylene imino group] 133.5~175.9 parts, first
135.1~175.6 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate,
124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of methyl ethyl ketoxime sealing end, 7- methyl-octanoic 123.2~
166.8 parts, 132.6~177.2 parts of hexyl formate, 142.1~186.1 parts of polyurethane resin, mass concentration be 132mg/L~
165.7~219.5 parts of the phosphoric acid cetyl ester sylvite of 399mg/L.
Further, degradation rate is high in order to obtain, the longer cellular reactor of service life, the cellular reactor
The production method is as follows:
Step 1: in more kettle reactors, distilled water and 3- methyl undecanonitrile is added, starts the stirring in more kettle reactors
Machine, setting speed are 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, rise to temperature
149.0 DEG C~150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) four is added
Chlorozincate (2:1) stirs evenly, and carries out reaction 126.3~137.5 minutes, and 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.1m3/ min~
166.7m3The fluorine gas of/min 126.3~137.5 minutes；Golden yellow leuco compound is added in more kettle reactors later, then
Seal steam heat exchanger in the more kettle reactors of secondary starting makes temperature rise to 166.2 DEG C~199.1 DEG C, and heat preservation 126.6~
137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bis-epoxies are added
The polymer of the dimethyl silicone polymer of ethane and hydrogen sealing end, the pH value for adjusting solution in more kettle reactors is 4.2~8.9, is protected
Temperature 126.2~366.2 minutes；
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication
After 0.132~1.199 hour；Pb nanoparticles are added in another more kettle reactor, addition mass concentration is 136mg/L
[Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of~366mg/L
(dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors
Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8
×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes；It is quiet to stop reaction later
It sets 6.66 × 10~12.1 × 10 minutes, removes impurity；Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension
Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732
×103Rpm~
9.23×103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, after grinding
Cross 0.732 × 103~1.23 × 103Mesh, it is spare；
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionising radiation spoke after mixing
According to the energy of ionizing radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time is
135.2~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change；By alkali formula cupric phosphate and lead
Nanoparticle mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, setting temperature
134.6 DEG C~180.2 DEG C of degree starts the blender in more kettle reactors, and revolving speed is 126rpm~521rpm, and pH is adjusted to 4.1
Between~8.1, it is dehydrated 135.1~149.1 minutes, it is spare；
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L~366mg/L blocks, cocurrent adds to the 1st
In more kettle reactors of step, flow acceleration is 271mL/min~999mL/min；Start more kettle reaction mechanical stirrers, setting speed
For 140rpm~180rpm；Stirring 4~8 minutes；7- methyl-octanoic is added, the seal steam heat in more kettle reactors is started
Exchanger is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/
Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes；More kettle reaction mechanical stirrers are again started up, revolving speed is
135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points
Clock；
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts more kettle reactions
Seal steam heat exchanger in device sets temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, it is added
Polyurethane resin reacts 126.2~137.1 minutes；Phosphoric acid cetyl ester sylvite is added later, starts in more kettle reactors
Seal steam heat exchanger, sets temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, pH adjust to 4.2~8.2 it
Between, pressure is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to
126.2 DEG C~137.1 DEG C discharge into molding press to get to cellular reactor；
The partial size of the Pb nanoparticles is 140 μm~150 μm.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention；
Fig. 2 is the structural schematic diagram of Turbulent Flow processor in the present invention；
Fig. 3 is the structural schematic diagram of Chinese medicine mixing apparatus of the present invention；
Fig. 4 is the structural schematic diagram of mobile gas transmission station in the present invention；
Fig. 5 be in the present invention cellular reactor material corrosion resistant erosion degree with the curve graph for using time change.
In figure: 1, ladder, 2, job platform, 3, medicament mixing apparatus, 3-1, confection discharge pipe, 3-2, steam spray
Penetrate pipeline, 3-3, cellular reactor, 3-4, additive charging line, 3-5, medicament filling line, 3-6, washing pipeline, 3-7,
Temperature sensor, 3-8, pedestal, 3-9, medicament mixing shell, 3-10, steam supply pipe road, 4, addition pipeline, 5, at Turbulent Flow
Device is managed, 5-1, liquid inlet electromagnetic valve, 5-2, spraying pipeline, 5-3, Turbulent Flow promote reactor, 5-4, mud valve, 5-5, liquid valve, 5-
6, temperature detector, 5-7, liquidometer, 5-8, aeration tube, 5-9, mud line, 5-10, drain line, 5-11, turbulent flow shell,
6, mobile gas transmission station, 6-1, movable pulley, 6-2, mobile loading plate, 6-3, aeration pump, 6-4, gas flowmeter, 6-5, gas transmission
Valve, 6-6, air delivering pipeline, 7, control system.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
As shown in Figures 1 to 4, a kind of process units for stalk flocculant, including what is vacantly installed by bracket one
Job platform 2, further includes medicament mixing apparatus 3, mobile gas transmission station 6 and control system 7, and the side of the job platform 2 is logical
It crosses bracket two and has vacantly installed Turbulent Flow processor 5, the medicament mixing apparatus 3 is located at operation horizontal by the fixed branch of pedestal 3-8
The lower part of platform 2；
The medicament mixing apparatus 3 includes medicament mixing shell 3-9, and the middle part in the medicament mixing shell 3-9 is under
Portion is fixedly installed cellular reactor 3-3 and vapor injection line 3-2 respectively, and the bottom of medicament mixing shell 3-9 is fixed to be connected
It is connected to the confection discharge pipe 3-1 being connected to its inner cavity, the top of medicament mixing shell 3-9 is fixedly connected with and its inner cavity
Temperature biography is further fixedly arranged in the medicament filling line 3-5 and additive charging line 3-4 of connection, medicament mixing shell 3-9
Sensor 3-7；The section of the cellular reactor 3-3 is honeycomb, and up and down, by the standpipe of more honeycomb arrangements
Composition；The vapor injection line 3-2 is annular in shape, and upper surface is provided with the through-hole being connected to its inner cavity throughout ground, connection
The steam supply pipe road 3-10 of vapor injection line 3-2 connects after being pierced by medicament mixing shell 3-9 with external high steam pipeline
It connects；The steam of high temperature can be equably ejected to the cellular reactor 3-3 on top by the setting of vapor injection line 3-2,
To promote the reaction of medicament；The outlet end of the confection discharge pipe 3-1 is by pressure pump and is fixedly connected on Turbulent Flow
The liquid feeding end of the side addition pipeline 4 on 5 top of processor is fixedly connected, and is added and is provided with solenoid valve A on pipeline 4；The addition
Pipeline 4, confection discharge pipe 3-1, medicament filling line 3-5, additive charging line 3-4 and steam supply pipe road 3-10
On be respectively arranged with solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E；Medicament, additive are infused from medicament respectively
Enter pipe 3-5, medicament injection pipe 3-5 is filled into medicament mixing apparatus 3, the sprayed high-temperature steam promotion medicine of steam injection pipe 3-2
Agent in cellular reactor 3-3 internal-response, after be discharged from confection delivery pipe 3-1；
The lower part of Turbulent Flow processor 5 is arranged in the movable type gas transmission station 6, and mobile gas transmission station 6 includes mobile carrying
Plate 6-2, two couples of movable pulley 6-1 for being rotatably connected to the lower part mobile loading plate 6-2, it is securely fitted in mobile loading plate 6-2
The aeration pump 6-3 on top, it is connected to gas flowmeter 6-4 and air delivering pipeline 6-6 at the gas outlet aeration pump 6-3, is arranged in gas transmission
Gas valve 6-5 on pipeline 6-6；Brake gear can be set on movable pulley 6-1, be also provided with for driving its rotation
Driving motor.
The Turbulent Flow processor 5 includes the turbulent flow shell 5-11 of upper end opening, is fixedly connected under turbulent flow shell 5-11
The mud line 5-9 and drain line 5-10 at end, the spray pipe network for being fixedly connected on the turbulent flow inner cavity shell 5-11 middle and upper part, fixation
Under being connected to the Turbulent Flow rush reaction mechanism at middle part in the inner cavity turbulent flow shell 5-11, being fixedly connected in the inner cavity turbulent flow shell 5-11
The aeration tube 5-8 in portion, the temperature detector 5-6 and liquidometer 5-7 being fixed inside turbulent flow shell 5-11；
The spray pipe network is made of more interconnected spraying pipeline 5-2, and the lower part of every spraying pipeline 5-2 connects
It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end
Road 5-13 is pierced by by the upper end of turbulent flow shell 5-11 and is connect with the water outlet of external water pump, is connected on inlet pipe 5-13
Liquid inlet electromagnetic valve 5-1, the Turbulent Flow promote reaction mechanism and promote reactor 5-3 group by several Turbulent Flows being distributed in display
Promote the cylindrical hollow structure of reactor 5-3 at, the Turbulent Flow, surface irregularity and being equipped with largely connects with its inner cavity
Logical through-hole, internal to promote reaction filler equipped with matchmaker, in a ring, upper part is provided with to be connected to the aeration tube 5-8 with its inner cavity
Solarization air cap；Input end of the outlet side of air delivering pipeline 6-6 after turbulent flow shell 5-11 with aeration tube 5-8；
Mud valve 5-4 and liquid valve 5-5, sludge pipe are connected separately on the mud line 5-9 and drain line 5-10
The liquid feeding end of road 5-9 and drain line 5-10 are located at the bottom and middle part of turbulent flow shell 5-11, drain line 5-10 into
Liquid end promotees reactor 5-3 lower end 4cm~6cm apart from Turbulent Flow；
Solenoid valve A, aeration pump 6-3, gas flowmeter 6-4, gas valve 6-5, temperature detector 5-6, liquidometer 5-7, water
Pump, liquid inlet electromagnetic valve 5-1, mud valve 5-4, liquid valve 5-5, temperature sensor 3-7, solenoid valve B, solenoid valve C and solenoid valve D are equal
It is connect with control system 7.
The medicament mixing apparatus 3 further includes the washing pipeline 3-6 for being fixedly connected on the top medicament mixing shell 3-9, is washed
The one end of pipeline 3-6 outside medicament mixing shell 3-9 is washed to connect with the water outlet of washing water pump, in medicament mixing shell 3-9
Internal one end is fixedly connected with the lotus spray-head that the top cellular reactor 3-3 is arranged in；It is arranged on the washing pipeline 3-6
There is solenoid valve F；Solenoid valve F is connect with control system 7.
The temperature detector 5-6 is mounted on turbulent flow shell 5-11 inner sidewall, apart from the upper end turbulent flow shell 5-11
Distance is between 15cm~25cm；The liquidometer 5-7 is set on inner wall, and liquidometer 5-7 is apart from the bottom end turbulent flow shell 5-11
Distance between 40cm~60cm.
The water outlet of the drain line 5-10 is connected to external collecting tank.
The movable plate 6-2 is the galvanized sheet of rectangle.
The aeration pump 6-3 quantity is two.
The lower end of the turbulent flow shell 5-11 is funnel-shaped；The spraying pipeline 5-2 quantity is no less than 6.
The job platform 2 is made of stainless steel plate of the thickness between 1cm~1.5cm, is arranged on 2 periphery of job platform
There is safety barrier, the safety barrier height is connected with ladder 1 on the job platform 2 between 80cm~120cm.
Further, degradation rate is high in order to obtain, service life longer cellular reactor 3-3, described cellular anti-
Answer device 3-3 composed of the following components by ratio of weight and the number of copies:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4-
Four 136.2~245.1 parts of chlorozincate (2:1) of [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4), 3- methyl mercapto fourth
132.6~149.7 parts of acetoacetic ester, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- third
Alkenyl) -4,1- phenylene] Oxymethylene] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer 138.4~
199.1 parts, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia benzene oxygen
Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of base-Isosorbide-5-Nitrae-phenylene imino group] 133.5~175.9 parts, first
135.1~175.6 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate,
124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of methyl ethyl ketoxime sealing end, 7- methyl-octanoic 123.2~
166.8 parts, 132.6~177.2 parts of hexyl formate, 142.1~186.1 parts of polyurethane resin, mass concentration be 132mg/L~
165.7~219.5 parts of the phosphoric acid cetyl ester sylvite of 399mg/L.
Further, degradation rate is high in order to obtain, service life longer cellular reactor 3-3, described cellular anti-
Answer device 3-3 the production method is as follows:
Step 1: in more kettle reactors, distilled water and 3- methyl undecanonitrile is added, starts the stirring in more kettle reactors
Machine, setting speed are 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, rise to temperature
149.0 DEG C~150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) four is added
Chlorozincate (2:1) stirs evenly, and carries out reaction 126.3~137.5 minutes, and 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes；It is added in more kettle reactors later golden yellow hidden
Colour solid, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation
126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added
Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2
~8.9, keep the temperature 126.2~366.2 minutes；
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication
After 0.132~1.199 hour；Pb nanoparticles are added in another more kettle reactor, addition mass concentration is 136mg/L
[Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of~366mg/L
(dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors
Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8
×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes；It is quiet to stop reaction later
It sets 6.66 × 10~12.1 × 10 minutes, removes impurity；Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension
Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732
×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding
0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare；
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionising radiation spoke after mixing
According to the energy of ionizing radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time is
135.2~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change；By alkali formula cupric phosphate and lead
Nanoparticle mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, setting temperature
134.6 DEG C~180.2 DEG C of degree starts the blender in more kettle reactors, and revolving speed is 126rpm~521rpm, and pH is adjusted to 4.1
Between~8.1, it is dehydrated 135.1~149.1 minutes, it is spare；
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L~366mg/L blocks, cocurrent adds to the 1st
In more kettle reactors of step, flow acceleration is 271mL/min~999mL/min；Start more kettle reaction mechanical stirrers, setting speed
For 140rpm~180rpm；Stirring 4~8 minutes；7- methyl-octanoic is added, the seal steam heat in more kettle reactors is started
Exchanger is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/
Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes；More kettle reaction mechanical stirrers are again started up, revolving speed is
135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points
Clock；
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts more kettle reactions
Seal steam heat exchanger in device sets temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, it is added
Polyurethane resin reacts 126.2~137.1 minutes；Phosphoric acid cetyl ester sylvite is added later, starts in more kettle reactors
Seal steam heat exchanger, sets temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, pH adjust to 4.2~8.2 it
Between, pressure is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to
126.2 DEG C~137.1 DEG C discharge into molding press to get to cellular reactor 3-3；
The partial size of the Pb nanoparticles is 140 μm~150 μm.
Following embodiment further illustrates the contents of the present invention, and as cellular reactor 3-3, it is of the invention important
Component increases the service life of integral device due to its presence, it is played for the safety of integral device, even running
Key effect.For this purpose, by it is following be embodiment, further verify cellular reactor 3-3 of the present invention, shown
The physical characteristic higher than other related patents.
Embodiment 1
Cellular reactor 3-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 133.3 parts of 341.0 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles
Blender in reactor, setting speed 134rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter
To 149.0 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added
136.2 parts of salt (2:1) stirs evenly, and carries out reaction 126.3 minutes, and 132.6 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.1m3The fluorine gas of/min 126.3 minutes；135.2 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up
Seal steam heat exchanger in more kettle reactors makes temperature rise to 166.2 DEG C, keeps the temperature 126.6 minutes, and 2,2'- [(1- is added
Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl
138.4 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 4.2, keeps the temperature 126.2 minutes；
Step 2: separately taking 140.9 parts of Pb nanoparticles, by Pb nanoparticles power be 6.66KW under ultrasonication
After 0.132 hour；Pb nanoparticles are added in another more kettle reactor, the polymerization that mass concentration is 136mg/L is added
[Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group
Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 133.5 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors
Device makes solution temperature at 46 DEG C, starts the blender in more kettle reactors, and with 4 × 102The speed of rpm stirs, and adjusts pH value
4.4, insulated and stirred 132 minutes；Stop reaction later and stand 6.66 × 10 minutes, removes impurity；Formaldehyde is added in suspension
With 135.1 parts of polymer of binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value forms sediment distillation washing 1.4
It is de-, by centrifuge in revolving speed 4.732 × 103Solid content is obtained under rpm, 2.95 × 102It is dry at a temperature of DEG C, mistake after grinding
0.732×103Mesh, it is spare；
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate 135.6 and step 2 to handle, after mixing using ionization spoke
Irradiation is penetrated, the energy of ionizing radiation is 123.2MeV, dosage 171.2kGy, irradiation time are 135.2 minutes, obtaining property
The alkali formula cupric phosphate and Pb nanoparticles mixture that shape changes；Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another more
In kettle reactor, starts the seal steam heat exchanger in more kettle reactors, 134.6 DEG C of set temperature, start more kettle reactors
In blender, revolving speed 126rpm, pH are adjusted to 4.1, are dehydrated 135.1 minutes, spare；
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 124.4 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L blocks, cocurrent adds to step 1
More kettle reactors in, flow acceleration 271mL/min；Start more kettle reaction mechanical stirrers, setting speed 140rpm；Stirring
4 minutes；123.2 parts of 7- methyl-octanoic are added, starts the seal steam heat exchanger in more kettle reactors, is warming up to 170.7
DEG C, pH is adjusted to 4.7, and being passed through fluorine gas ventilatory capacity is 125.293m3/ min, heat preservation stand 160.0 minutes；It is anti-to be again started up more kettles
Mechanical stirrer is answered, revolving speed 135rpm is added 132.6 parts of hexyl formate, and pH is made to be adjusted to 4.7, and heat preservation stands 159.3 points
Clock；
Step 5: starting the blender in more kettle reactors, and setting speed 132rpm starts the vapour in more kettle reactors
Gland steam heat exchanger sets temperature in more kettle reactors as 1.581 × 102DEG C, 142.1 parts of polyurethane resin are added, instead
It answers 126.2 minutes；165.7 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 132mg/L is added later, starts more kettle reactions
Seal steam heat exchanger in device, sets temperature in more kettle reactors as 210.6 DEG C, and pH is adjusted to 4.2, and pressure is
1.32MPa, reaction time are 0.4 hour；Be depressurized to later gauge pressure be 0MPa, be cooled to 126.2 DEG C discharge into molding press to get
To cellular reactor 3-3；The partial size of the Pb nanoparticles is 140 μm.
Embodiment 2
Cellular reactor 3-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 175.5 parts of 566.2 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles
Blender in reactor, setting speed 180rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter
To 150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added
245.1 parts of salt (2:1) stirs evenly, and carries out reaction 137.5 minutes, and 149.7 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 166.7m3The fluorine gas of/min 137.5 minutes；192.9 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up
Seal steam heat exchanger in more kettle reactors makes temperature rise to 199.1 DEG C, keeps the temperature 137.7 minutes, and 2,2'- [(1- is added
Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl
199.1 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 8.9, keeps the temperature 366.2 minutes；
Step 2: separately taking 195.2 parts of Pb nanoparticles, by Pb nanoparticles power be 12.1KW under ultrasonication
1.199 after hour；Pb nanoparticles are added in another more kettle reactor, the polymerization that mass concentration is 366mg/L is added
[Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group
Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 175.9 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors
Device makes solution temperature between 86 DEG C, starts the blender in more kettle reactors, and with 8 × 102The speed of rpm stirs, adjustment
PH value is 8.8, insulated and stirred 199 minutes；Stop reaction later and stand 12.1 × 10 minutes, removes impurity；Suspension is added
175.6 parts of polymer of formaldehyde and binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value form sediment distillation 2.8
Water elution, by centrifuge in revolving speed 9.23 × 103Solid content is obtained under rpm, 3.419 × 102It is dry at a temperature of DEG C, grinding
1.23 × 10 are crossed afterwards3Mesh, it is spare；
Step 3: Pb nanoparticles after 158.1 parts of alkali formula cupric phosphate and step 2 processing are separately taken, after mixing using ionization
Radiation, the energy of ionizing radiation is 151.8MeV, dosage 211.8kGy, irradiation time are 160.8 minutes, is obtained
The alkali formula cupric phosphate and Pb nanoparticles mixture that character changes；Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another
In more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, 180.2 DEG C of set temperature, start more kettle reactions
Blender in device, revolving speed 521rpm, pH are adjusted to 8.1, are dehydrated 149.1 minutes, spare；
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 366mg/L blocks, cocurrent adds to step 1
More kettle reactors in, flow acceleration 999mL/min；Start more kettle reaction mechanical stirrers, setting speed 180rpm；Stirring
8 minutes；166.8 parts of 7- methyl-octanoic are added, starts the seal steam heat exchanger in more kettle reactors, is warming up to 207.5
DEG C, pH is adjusted to 8.5, and being passed through fluorine gas ventilatory capacity is 166.410m3/ min, heat preservation stand 190.2 minutes；It is anti-to be again started up more kettles
Mechanical stirrer is answered, revolving speed 180rpm is added 177.2 parts of hexyl formate, and pH is made to be adjusted to 8.5, and heat preservation stands 199.5 points
Clock；
Step 5: starting the blender in more kettle reactors, and setting speed 199rpm starts the vapour in more kettle reactors
Gland steam heat exchanger sets temperature in more kettle reactors as 2.462 × 102DEG C, 186.1 parts of polyurethane resin are added, instead
It answers 137.1 minutes；219.5 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 399mg/L is added later, starts more kettle reactions
Seal steam heat exchanger in device, sets temperature in more kettle reactors as 266.7 DEG C, and pH is adjusted to 8.2, and pressure is
1.33MPa, reaction time are 0.9 hour；Be depressurized to later gauge pressure be 0MPa, be cooled to 137.1 DEG C discharge into molding press to get
To cellular reactor 3-3；The partial size of the Pb nanoparticles is 150 μm.
Embodiment 3
Cellular reactor 3-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 133.9 parts of 341.9 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles
Blender in reactor, setting speed 134rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter
To 149.9 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added
136.9 parts of salt (2:1) stirs evenly, and carries out reaction 126.9 minutes, and 132.9 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.9m3The fluorine gas of/min 126.9 minutes；135.9 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up
Seal steam heat exchanger in more kettle reactors makes temperature rise to 166.9 DEG C, keeps the temperature 126.9 minutes, and 2,2'- [(1- is added
Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl
138.9 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 4.9, keeps the temperature 126.9 minutes；
Step 2: separately taking 140.9 parts of Pb nanoparticles, by Pb nanoparticles power be 6.669KW under ultrasonication
After 0.1329 hour；Pb nanoparticles are added in another more kettle reactor, it is the poly- of 136.9mg/L that mass concentration, which is added,
Close [Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group
Base) carbon-based imino group
Isosorbide-5-Nitrae-Asia benzene] 133.9 parts of dispersion Pb nanoparticles, start the seal steam heat exchanger in more kettle reactors, makes
Solution temperature starts the blender in more kettle reactors at 46.9 DEG C, and with 4.9 × 102The speed of rpm stirs, and adjusts pH value
4.9, insulated and stirred 132.9 minutes；Stop reaction later and stand 6.66 × 10 minutes, removes impurity；First is added in suspension
135.9 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value form sediment distilled water 1.9
Elution, by centrifuge in revolving speed 4.732 × 103Solid content is obtained under rpm, 2.95 × 102It is dry at a temperature of DEG C, after grinding
Cross 0.732 × 103Mesh, it is spare；
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate 135.9 and step 2 to handle, after mixing using ionization spoke
Irradiation is penetrated, the energy of ionizing radiation is 123.9MeV, dosage 171.9kGy, irradiation time are 135.9 minutes, obtaining property
The alkali formula cupric phosphate and Pb nanoparticles mixture that shape changes；Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another more
In kettle reactor, starts the seal steam heat exchanger in more kettle reactors, 134.9 DEG C of set temperature, start more kettle reactors
In blender, revolving speed 126rpm, pH are adjusted to 4.9, are dehydrated 135.9 minutes, spare；
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 124.9 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136.9mg/L blocks, cocurrent adds to the 1st
In more kettle reactors of step, flow acceleration 271.9mL/min；Start more kettle reaction mechanical stirrers, setting speed 140rpm；
Stirring 4.9 minutes；123.9 parts of 7- methyl-octanoic are added, the seal steam heat exchanger in more kettle reactors is started, is heated up
To 170.9 DEG C, pH is adjusted to 4.9, and being passed through fluorine gas ventilatory capacity is 125.9m3/ min, heat preservation stand 160.9 minutes；It is again started up
More kettles react mechanical stirrer, and revolving speed 135rpm is added 132.9 parts of hexyl formate, and pH is made to be adjusted to 4.9, and heat preservation is stood
159.9 minute；
Step 5: starting the blender in more kettle reactors, and setting speed 132rpm starts the vapour in more kettle reactors
Gland steam heat exchanger sets temperature in more kettle reactors as 1.581 × 102DEG C, 142.9 parts of polyurethane resin are added, instead
It answers 126.9 minutes；165.7 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 132mg/L is added later, starts more kettle reactions
Seal steam heat exchanger in device, sets temperature in more kettle reactors as 210.9 DEG C, and pH is adjusted to 4.9, and pressure is
1.32MPa, reaction time are 0.41 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 126.9 DEG C and discharges into molding press, i.e.,
Obtain cellular reactor 3-3；The partial size of the Pb nanoparticles is 140 μm.
Reference examples
Reference examples are tested for the property test using the cellular reactor of certain commercially available brand.
Embodiment 4
Examples 1 to 3 and reference examples cellular reactor 3-3 obtained are tested for the property test, test terminates
Afterwards to parameters such as compression strength enhancing rate, resistance to deformation strength enhancing rate, partition service life enhancing rate, impact resistance enhancing rates
It is analyzed.Data analysis is as shown in table 1.
As seen from Table 1, cellular reactor 3-3 of the present invention, obviously higher than existing in Specifications
The product of technology production.
In addition, as shown in figure 5, the production that Examples 1 to 3 in Specifications, is substantially produced better than the prior art
Product.
Working method of one of the present invention for the process units of stalk flocculant, this method includes following step
It is rapid:
Step 1: solenoid valve E, solenoid valve C and solenoid valve D are controlled by control system 7 and opened, steam supply pipe road is passed through
3-10 feeds steam, is separately added into medicament, additive by medicament injection pipe 3-5, medicament injection pipe 3-5, mixes into medicament
Liquid in shell 3-9 accelerates reaction, after reaction evenly into cellular reactor 3-3 under the action of steam
Mixed liquor is discharged by confection discharge pipe 3-1；
Step 2 is added smashed waste straw powder by the upper open end of turbulent flow shell 5-11, passes through control system
7 open liquid inlet electromagnetic valve 5-1, are fed clear water using pressure pump, and the spray of the even action by spraying pipeline 5-2 and nozzle
It is spread across in Turbulent Flow processor 5, starts the aeration pump 6- on mobile gas transmission station 6 after 15min, then through control system 7
3, the gas valve 6-5 on air delivering pipeline 6-6 is opened simultaneously, fresh air is fed by Turbulent Flow processor 5 by aeration tube 5-8,
Increase the oxygen content in Turbulent Flow processor 5, after 10min, the solenoid valve on addition pipeline 4 is opened by control system 7
A adds confection into Turbulent Flow processor 5, and after the reaction of setting time, sediment is discharged through mud line 5-9,
Flocculant obtained is transported to collecting tank through drain line 5-10；
Step 3: Turbulent Flow promotees matchmaker's rush reaction filler inside reactor 5-3 and is catalyzed to the confection of entrance, temperature
Spend the temperature in detector 5-6 real-time monitoring Turbulent Flow processor 5；When detecting that temperature is higher than default value T, temperature inspection
It surveys device 5-6 and electric signal is fed back into control system 7, control system 7 controls coupled alarm and sounds an alarm, with notice
Operator takes cooling measure；
Step 4: liquidometer 5-7 real-time monitoring Turbulent Flow promotees the liquid level of mixing liquid in reactor 5-3；As liquidometer 5-7
When detecting that clear water liquid level is higher than default value M, signal is fed back to control system 7 by liquidometer 5-7, and control system 7 is opened
Mixing liquid is discharged by drain line 5-10 by liquid valve 5-5；
Step 5: the conveying capacity of the gas flowmeter 6-4 real-time monitoring air on mobile gas transmission station 6；Work as gas flowmeter
When 6-4 detects conveying capacity lower than default value P, feedback signal is sent to control system 7 by gas flowmeter 6-4, control
System 7 improves aeration pump 6-3 revolving speed, while increasing gas valve 6-5 aperture, to guarantee the conveying capacity of gas.
Claims (10)
1. a kind of process units for stalk flocculant, including the job platform (2) vacantly installed by bracket one, feature
It is, further includes medicament mixing apparatus (3), mobile gas transmission station (6) and control system (7), the side of the job platform (2)
Turbulent Flow processor (5) are vacantly installed by bracket two, the medicament mixing apparatus (3) is installed by pedestal (3-8) fixation
In the lower part of job platform (2)；
The medicament mixing apparatus (3) includes medicament mixing shell (3-9), the middle part in the medicament mixing shell (3-9) and
Lower part is fixedly installed cellular reactor (3-3) and vapor injection line (3-2), the bottom of medicament mixing shell (3-9) respectively
Portion is fixedly connected with the confection discharge pipe (3-1) being connected to its inner cavity, and the top of medicament mixing shell (3-9) is fixed to be connected
It is connected to the medicament filling line (3-5) and additive charging line (3-4) being connected to its inner cavity, medicament mixing shell (3-9) is interior
It is further fixedly arranged on temperature sensor (3-7)；The section of the cellular reactor (3-3) is honeycomb, and up and down,
It is made of the standpipe of more honeycomb arrangements；The vapor injection line (3-2) is annular in shape, and upper surface is provided with throughout ground
The steam supply pipe road (3-10) of the through-hole being connected to its inner cavity, connection vapor injection line (3-2) is pierced by medicament mixing shell
(3-9) is connect with external high steam pipeline afterwards；The outlet end of the confection discharge pipe (3-1) by pressure pump with
The liquid feeding end for being fixedly connected on side addition pipeline (4) on Turbulent Flow processor (5) top is fixedly connected, in addition pipeline (4)
It is provided with solenoid valve A；The addition pipeline (4), confection discharge pipe (3-1), medicament filling line (3-5), additive
Solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D are respectively arranged on charging line (3-4) and steam supply pipe road (3-10)
With solenoid valve E；
The movable type gas transmission station (6) is arranged in the lower part of Turbulent Flow processor (5), and mobile gas transmission station (6) includes that movement is held
Support plate (6-2), two pairs of movable pulleys (6-1) for being rotatably connected to the lower part mobile loading plate (6-2) are securely fitted in mobile hold
The aeration pump (6-3) on the top support plate (6-2) is connected to gas flowmeter (6-4) and air delivering pipeline at the gas outlet aeration pump (6-3)
(6-6), the gas valve (6-5) being arranged on air delivering pipeline (6-6)；
The Turbulent Flow processor (5) includes the turbulent flow shell (5-11) of upper end opening, is fixedly connected on turbulent flow shell (5-11)
The mud line (5-9) and drain line (5-10) of lower end, the spray for being fixedly connected on the inner cavity middle and upper part turbulent flow shell (5-11)
Pipe network, the Turbulent Flow for being fixedly connected on middle part in the inner cavity turbulent flow shell (5-11) promote reaction mechanism, are fixedly connected on turbulent flow shell
The aeration tube (5-8) of the inner cavity middle and lower part (5-11), be fixed at the internal temperature detector (5-6) of turbulent flow shell (5-11) and
Liquidometer (5-7)；
The spray pipe network is made of more interconnected spraying pipelines (5-2), and the lower part of every spraying pipeline (5-2) connects
It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end
Road (5-13) is pierced by by the upper end of turbulent flow shell (5-11) and is connect with the water outlet of external water pump, in inlet pipe (5-13)
It is connected with liquid inlet electromagnetic valve (5-1), the Turbulent Flow promotees reaction mechanism and promotees reaction by several Turbulent Flows being distributed in display
Device (5-3) composition, the Turbulent Flow promote reactor (5-3) cylindrical hollow structure, and surface irregularity is simultaneously equipped with a large amount of
The through-hole being connected to its inner cavity, it is internal to promote reaction filler equipped with matchmaker, the aeration tube (5-8) in a ring, upper part setting
There is the solarization air cap being connected to its inner cavity；The outlet side of air delivering pipeline (6-6) pass through turbulent flow shell (5-11) afterwards with aeration tube (5-8)
Input end；
It is connected separately with mud valve (5-4) and liquid valve (5-5) on the mud line (5-9) and drain line (5-10), arranges
Mud pipeline (5-9) and the liquid feeding end of drain line (5-10) are located at the bottom and middle part of turbulent flow shell (5-11)；
Solenoid valve A, aeration pump (6-3), gas flowmeter (6-4), gas valve (6-5), temperature detector (5-6), liquidometer (5-
7), water pump, liquid inlet electromagnetic valve (5-1), mud valve (5-4), liquid valve (5-5), temperature sensor (3-7), solenoid valve B, electromagnetism
Valve C and solenoid valve D is connect with control system (7).
2. a kind of process units for stalk flocculant according to claim 1, which is characterized in that the medicament mixing
Equipment (3) further includes the washing pipeline (3-6) for being fixedly connected on the top medicament mixing shell (3-9), and washing pipeline (3-6) is in medicine
The external one end of agent mixing shell (3-9) is connected with the water outlet of washing water pump, in the internal one end of medicament mixing shell (3-9)
Lotus spray-head with setting on the top cellular reactor (3-3) is fixedly connected；Electromagnetism is provided on the washing pipeline (3-6)
Valve F；Solenoid valve F is connect with control system (7).
3. a kind of process units for stalk flocculant according to claim 1 or 2, which is characterized in that the drain
The water outlet of pipeline (5-10) is connected to external collecting tank.
4. a kind of process units for stalk flocculant according to claim 3, which is characterized in that the movable plate
(6-2) is the galvanized sheet of rectangle.
5. a kind of process units for stalk flocculant according to claim 4, which is characterized in that the aeration pump
(6-3) quantity is two.
6. a kind of process units for stalk flocculant according to claim 5, which is characterized in that the turbulent flow shell
The lower end of (5-11) is funnel-shaped；Spraying pipeline (5-2) quantity is no less than 6.
7. a kind of process units for stalk flocculant according to claim 6, which is characterized in that the job platform
(2) stainless steel plate by thickness between 1cm~1.5cm is made, and job platform (2) periphery is provided with safety barrier, described
Safety barrier height is connected with ladder (1) on the job platform (2) between 80cm~120cm.
8. a kind of process units for stalk flocculant according to claim 7, which is characterized in that described cellular anti-
Answer device (3-3) composed of the following components by ratio of weight and the number of copies:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4- [(4- first
Base -2- nitrobenzophenone) azo] four 136.2~245.1 parts of chlorozincate (2:1) of benzene diazonium (T-4), 3- methylmercapto butyric acid ethyl ester
132.6~149.7 parts, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic)-
4,1- phenylenes] Oxymethylene] 138.4~199.1 parts of polymer of dimethyl silicone polymer of bisoxirane and hydrogen sealing end,
140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia phenoxy group-Isosorbide-5-Nitrae-Asia
Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of phenylimino] 133.5~175.9 parts, formaldehyde and dinonyl
135.1~175.6 parts of the polymer of phenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate, methyl ethyl ketoxime envelope
124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) at end, 123.2~166.8 parts of 7- methyl-octanoic, formic acid
132.6~177.2 parts of own ester, 142.1~186.1 parts of polyurethane resin, mass concentration is the phosphoric acid of 132mg/L~399mg/L
165.7~219.5 parts of cetyl ester sylvite.
9. a kind of process units for stalk flocculant according to claim 8, which is characterized in that described cellular anti-
Answer device (3-3) the production method is as follows:
Step 1: in more kettle reactors, being added distilled water and 3- methyl undecanonitrile, start the blender in more kettle reactors, if
Determine revolving speed be 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, make temperature rise to 149.0 DEG C~
150.2 DEG C, four chlorozincate of 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) is added
(2:1) is stirred evenly, and carries out reaction 126.3~137.5 minutes, 3- methylmercapto butyric acid ethyl ester is added, being passed through flow is
125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes；Golden yellow procrypsis is added in more kettle reactors later
Body, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation
126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added
Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2
~8.9, keep the temperature 126.2~366.2 minutes；
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication 0.132
After~1.199 hours；Pb nanoparticles are added in another more kettle reactor, addition mass concentration be 136mg/L~
[Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of 366mg/L
(dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors
Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8
×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes；It is quiet to stop reaction later
It sets 6.66 × 10~12.1 × 10 minutes, removes impurity；Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension
Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732
×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding
0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare；
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionizing radiation, electricity after mixing
Energy from radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time 135.2
~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change；Alkali formula cupric phosphate and lead nanometer is micro-
Grain mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, set temperature 134.6
DEG C~180.2 DEG C, start the blender in more kettle reactors, revolving speed is 126rpm~521rpm, pH be adjusted to 4.1~8.1 it
Between, it is dehydrated 135.1~149.1 minutes, it is spare；
Step 4: the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes, adding to mass concentration is
In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of the methyl ethyl ketoxime sealing end of 136mg/L~366mg/L, cocurrent adds to step 1
In more kettle reactors, flow acceleration is 271mL/min~999mL/min；Start more kettle reaction mechanical stirrers, setting speed is
140rpm~180rpm；Stirring 4~8 minutes；7- methyl-octanoic is added, the seal steam heat started in more kettle reactors is handed over
Parallel operation is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/
Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes；More kettle reaction mechanical stirrers are again started up, revolving speed is
135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points
Clock；
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts in more kettle reactors
Seal steam heat exchanger, set temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, poly- ammonia is added
Ester resin reacts 126.2~137.1 minutes；Phosphoric acid cetyl ester sylvite is added later, starts the packing in more kettle reactors
Steam heat-exchanger sets the temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, and pH is adjusted between 4.2~8.2, pressure
Power is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 126.2
DEG C~137.1 DEG C discharge into molding press to get to cellular reactor (3-3).
10. a kind of process units for stalk flocculant according to claim 9, which is characterized in that the lead nanometer
The partial size of particle is 140 μm~150 μm.
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| CN109940037A (en) * | 2019-03-05 | 2019-06-28 | 徐州工程学院 | A kind of contaminated soil remediation agent production equipment |
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|---|---|---|---|---|
| CN109940037A (en) * | 2019-03-05 | 2019-06-28 | 徐州工程学院 | A kind of contaminated soil remediation agent production equipment |
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