CN108947007A - One kind being percolated liquid processing device for residents in rural community - Google Patents
One kind being percolated liquid processing device for residents in rural community Download PDFInfo
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- CN108947007A CN108947007A CN201810813804.1A CN201810813804A CN108947007A CN 108947007 A CN108947007 A CN 108947007A CN 201810813804 A CN201810813804 A CN 201810813804A CN 108947007 A CN108947007 A CN 108947007A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5281—Installations for water purification using chemical agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/06—Contaminated groundwater or leachate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/22—O2
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/38—Gas flow rate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/42—Liquid level
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
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Abstract
One kind being percolated liquid processing device for residents in rural community, and cellular reactor and steam injection pipe are equipped with inside medicament mixing apparatus, is equipped with heating tube in multiple standpipes of cellular reactor;Pass through piping connection between medicament mixing apparatus and Turbulent Flow processor top;The turbulent flow shell of Turbulent Flow processor is equipped with spoil disposal and drain line, and spray pipe network, Turbulent Flow adsorbing mechanism and aeration tube are successively arranged in inner cavity;Spray pipe network is connect by pipeline with external water pump;Reaction sphere is housed, and equipped with source resonance device and supercharging impeller inside Turbulent Flow adsorbing mechanism, is equipped with resonance head and vibrating arm in active resonance device, is equipped with dither in resonance head;Aeration tube top is equipped with solarization air cap;Dispersal unit in turbulent flow shell is made of two aluminium polychloride dispersion pipes;Current stabilization buffer cell is made of multiple macromolecule current stabilization sieves;Current stabilization shakes unit and shakes monomer composition by multiple current stabilizations.The device can effectively be handled residents in rural community percolate.
Description
Technical field
The invention belongs to technical field of sewage, and in particular to one kind is for residents in rural community percolate processing dress
It sets.
Background technique
Important component of the water as human living space provides good freshwater resources for the mankind.But with
China's environmental pollution is on the rise, and water pollution problems is also increasingly severeer.
During residents in rural community processing, more leachate can be generated, during processing, is often directed to
Fixed part in rural garbage is handled, this part of contaminated water is exhausted directly in river mostly without processing, this is to river
Stream produces serious pollution, and domestic residents in rural community percolate generally uses merely at the method for sedimentation basin at present
Reason, also has a small number of producers to be handled by the way of flocculation sedimentation.But the existing dress to residents in rural community percolate
It sets that structure is complicated, manufacturing cost is high, is unfavorable for the convenient processing to residents in rural community percolate.
Summary of the invention
In view of the above existing problems in the prior art, the present invention provides one kind for residents in rural community percolate processing dress
It sets, the apparatus structure is simple, and manufacturing cost is low, it can be conducive to quickly and effectively administer residents in rural community percolate,
It is with stronger generalization.
To achieve the goals above, the present invention provides an one kind and is percolated liquid processing device for residents in rural community, including
The job platform vacantly installed by bracket one further includes medicament mixing apparatus, mobile gas transmission station and control system, the work
The side of industry platform has vacantly installed Turbulent Flow processor by bracket two, and the medicament mixing apparatus is installed by pedestal fixation
In the lower part of job platform;
The medicament mixing apparatus includes medicament mixing shell, and the intracorporal middle part of the medicament mixed shell and lower part are solid respectively
Surely cellular reactor and vapor injection line are provided with, the bottom of medicament mixing shell is fixedly connected with to be connected to its inner cavity
Confection discharge pipe, the top of medicament mixing shell are fixedly connected with the medicament filling line being connected to its inner cavity and addition
Agent charging line is further fixedly arranged on temperature sensor in medicament mixed shell body;The section of the cellular reactor is honeycomb
Shape, and up and down, is made of the standpipe of more honeycomb arrangements, and the standpipe includes that hexagon shell, upper and lower ends are logical
That crosses that annular slab is fixedly connected on hexagon housing cavity center leads note pipe, positioned at hexagon enclosure interior and spiral is wound around
The heating tube outside note pipe is led, the power supply line of heating tube connects after sequentially passing through hexagon shell medicament mixing shell with control system
It connects;The vapor injection line is annular in shape, and upper surface is provided with the through-hole being connected to its inner cavity, connection steam spray throughout ground
The steam supply pipe road for penetrating pipeline is pierced by after medicament mixing shell to be connect with external high steam pipeline;The confection row
The outlet end for putting pipeline is solid by the liquid feeding end of pressure pump and the side addition pipeline for being fixedly connected on Turbulent Flow processor top
Fixed connection, adding tube road are provided with solenoid valve A;The addition pipeline, medicament filling line, adds confection discharge pipe
Agent charging line and steam supply pipe road is added to be respectively arranged with solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve
E;
The movable type gas transmission station is arranged in the lower part of Turbulent Flow processor, mobile gas transmission station include mobile loading plate,
Two pairs of movable pulleys for being rotatably connected to mobile loading plate lower part, connect the aeration pump for being securely fitted in mobile loading plate top
Connect gas flowmeter and air delivering pipeline at aeration pump gas outlet, the gas valve being arranged on air delivering pipeline;
The Turbulent Flow processor includes the turbulent flow shell of upper end opening, is fixedly connected on turbulent flow housing cavity middle and upper part
Spray pipe network is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part in turbulent flow housing cavity, is fixedly connected on turbulent flow housing cavity
The aeration tube of middle and lower part, the temperature detector and liquidometer for being fixed at turbulent flow enclosure interior;
The spray pipe network is made of more interconnected spraying pipelines, and the lower part of every spraying pipeline is respectively connected with edge
Multiple nozzles being connected to its inner cavity of its length direction distribution, the inlet pipe being fixedly connected with spray pipe network liquid feeding end is by rapids
The upper end of stream shell is pierced by and connect with the water outlet of external water pump, and liquid inlet electromagnetic valve, the rapids are connected in inlet pipe
Fluidised form adsorbing mechanism promotees reactor group at it includes enclosing that the Turbulent Flow, which promotees reactor, by several Turbulent Flows being distributed in display
It is coiled into the reaction sphere grid of tubular construction, the supercharging impeller for being rotatablely arranged at reaction sphere grid intracavity bottom and fixed setting
Active resonance device in reaction sphere grid inner cavity lower part;The supercharging impeller promotees the waterproof of reactor lower part by being located at Turbulent Flow
Motor driven rotation;On active resonance device top, support has a large amount of reaction sphere, and the outer diameter of reaction sphere is greater than reaction sphere grid
Gap and active resonance device mesh diameter;A large amount of reaction sphere is full of the upper space of entire reaction sphere grid;Anti-
Ball grid is answered to be internally provided with temperature sensing device;It is additionally provided with spray equipment on reaction sphere grid top, spray equipment includes ring
The sodium dimethyl dithiocarbamate medicament pipe of shape is circumferentially uniformly fixedly connected on sodium dimethyl dithiocarbamate medicament
Multiple sodium dimethyl dithiocarbamate spray heads of pipe lower part are connected to sodium dimethyldithiocar-bamate (SDDC) medicament tube cavity
Spray supervisor connect with external pressure pump;The active resonance device includes tubular grid shell up and down, respectively
Two resonance strainers being fixedly connected at tubular grid shell upper open end and lower open end, the setting of tubular grid interior of shell
Have multiple resonant elements, each resonant element by multiple resonance heads equally distributed along its length, the adjacent resonance head of connection it
Between multiple drive rods composition, tubular grid shell is arranged by more upright bars being circumferentially uniformly arranged and longitudinal gap and fixed connected
Connect the lantern ring composition more upright bar peripheries;The resonance head is internally provided with dither, and drive rod is cavity structure, high
The power supply line of frequency vibration device is pierced by turbulent flow shell after being pierced by by drive rod again and connect with control system;The aeration tube in a ring,
Upper part is provided with the solarization air cap being connected to its inner cavity;Import of the outlet side of air delivering pipeline after turbulent flow shell with aeration tube
End;
The lower part of the turbulent flow shell is precipitation section funnel-shaped, and the precipitation section includes precipitation section shell, and heavy
Shallow lake portion enclosure interior is successively fixedly installed dispersal unit, current stabilization buffer cell, current stabilization concussion unit from top to bottom;The dispersion
Unit two aluminium polychloride dispersion pipes in rectangular ring arranged side by side and is evenly connected at each gather in parallel by left and right
Close multiple nozzles composition of aluminium chloride dispersion pipe lower part;The current stabilization buffer cell is steady by the multiple macromolecules being longitudinally stacked
Flow sieve composition;The current stabilization concussion unit is by from left to right successively multiple current stabilizations of equidistant intervals arrangement shake monomer group
At the current stabilization concussion monomer is by being fixedly connected on two electric and magnetic oscillation sticks of precipitation section housing bottom and being fixedly connected on two
The current stabilization wing plate of electric and magnetic oscillation stick upper end forms, and the vertical section of the current stabilization wing plate is in the W type toppled over;The precipitation section shell
Middle part and lower end are respectively fixedly connected with the drain line being connected to its inner cavity and mud line, the mud line and drain pipe
Road is connected separately with mud valve and liquid valve, and the liquid feeding end of mud line and drain line is located at the bottom of precipitation section shell
Portion and middle part;Storage tank and middle storage tank water pump in the outside of precipitation section shell is provided with store aluminium polychloride in middle storage tank
The liquid feeding end of solution, middle storage tank water pump is connected to by pipeline with the perforation of the bottom of middle storage tank inner cavity, the outlet end of middle storage tank water pump
It is connected to respectively by pipeline with the inner cavity of two aluminium polychloride dispersion pipes;
Solenoid valve A, aeration pump, gas flowmeter, gas valve, temperature detector, liquidometer, water pump, liquid inlet electromagnetic valve, go out
Slurry valve, liquid valve, temperature sensor, solenoid valve B, solenoid valve C, solenoid valve D, electric and magnetic oscillation stick, middle storage tank water pump, anti-water power
Machine, temperature sensing device and pressure pump are connect with control system.
In the technical scheme, medicament, additive are filled into medicament mixing from medicament injection pipe, additive filler pipe respectively
In equipment, the sprayed high-temperature steam of steam injection pipe promotes medicament to react generation inorganic flocculating agent in cellular inside reactor,
After be discharged from confection delivery pipe, the diversion pipe in multiple standpipes is able to achieve the shunting of whereabouts liquid, and passes through heating
The heating of pipe promotes the formation efficiency of inorganic flocculating agent.By the side of Turbulent Flow processor be provided with addition pipeline,
The medicament mixing apparatus that confection delivery pipe communicates therewith can easily realize that inorganic flocculating agent is injected into Turbulent Flow processor
In, it is quickly settled in order to effectively facilitate the waste in sewage;Make Turbulent Flow processor top that spray pipe network is set, can be convenient for
The rapidly and uniformly injection of realization sewage, and the setting of more spraying pipelines and multiple nozzles, can make to be conducive to that sewage is added
Rapid dispersion, so as to convenient for the inorganic flocculating agent of injection carry out it is good contact, so as to improve flocculating effect, and can contract
Short flocculation time.The setting of aeration tube can evenly and rapidly be added convenient for fresh air, and can be uniformly abundant with the liquid of whereabouts
Contact, so as to effectively kill the anaerobe detested in sewage, meanwhile, the air of entrance can also be in the process contacted with water phase
In, the carbon tetrachloride in abundant thawing water, and be discharged into air by the upper open end of turbulent flow shell.Rapids in matrix is set
Turbulent Flow absorber inside fluidised form processor, inside are equipped with reaction sphere, and sodium dimethyl dithiocarbamate spray head can be so as to
It is sprayed in external sodium dimethyl dithiocarbamate to be atomized, the effect of to improve sewage treatment drug, in reaction sphere
Under effect, the microorganism in sewage can effectively be adsorbed, and adsorbed microorganism can be promoted to be decomposed, thus
Further increase the treatment effect of sewage.It will do it high-frequency vibration, Jin Erhui after the energization of resonance head in active resonance device
To enter tubular grid shell in solution activation, and can make its quickly through.Supercharging impeller can be under the driving of waterproof machine
The turbulent flow rotation for realizing discharge water, can be further improved the treatment effect of sewage, temperature sensing device can monitor near reaction sphere
Temperature, thus can help to understand absorption progress;Temperature detector energy and liquidometer can be to the temperature in Turbulent Flow processor
It is measured in real time with liquid level, in order to effectively monitor the processing progress to sewage.When sewage falls into precipitation section shell,
With middle storage tank water pump supply with regard to aluminium polychloride dispersion pipe spray aluminium polychloride meet with to sewage carry out degerming, deodorization and
Decoloration, then under the buffer function of macromolecule current stabilization sieve, falls into the lower part of precipitation section shell;Current stabilization wing plate is in electric and magnetic oscillation
Horizontal concussion is carried out under the drive of stick, meanwhile, the horizontal concussion of certain amplitude can also occur for electric and magnetic oscillation stick itself, so as to add
Fast flocculation reaction, when current stabilization wing plate, electric and magnetic oscillation stick stop working, organic matter flocculation precipitating is simultaneously arranged from the sludge pipe of bottom
Out, clear water is discharged from the drain line at middle part;The apparatus structure is simple, and manufacturing cost is low, convenient operating maintenance, can be easily real
It is now handled using to river pollution water, with stronger generalization.
Further, it is cleaned for the ease of the inside to medicament mixing apparatus, the medicament mixing apparatus further includes solid
Surely the washing pipeline of medicament mixing housing tip, the one end and washing water pump of washing pipeline in medicament mixing hull outside are connected to
Water outlet connection, fixed connect in one end and the lotus spray-head that cellular reactor top is arranged in of medicament mixing enclosure interior
It connects;Solenoid valve F is provided on the washing pipeline;Solenoid valve F is connect with control system.The lower part squit hole face of lotus spray-head
Cellular reactor, when needing to clean, lotus spray-head spray high pressure water to cellular reactor carry out high-pressure wash.
As a preference, the water outlet of the drain line is connected to external collecting tank.
As a preference, the mesh aperture of the current stabilization sieve is 5mm~16mm;The quantity of current stabilization sieve is 10;
The quantity of the current stabilization concussion monomer is 10, and the distance between adjacent current stabilization concussion monomer is 2cm~6cm;The same current stabilization
It is distributed with shaking two electric and magnetic oscillation stick front-rear directions among monomer, and at a distance of 10cm~60cm.
As a preference, the aeration pump quantity is two.
As a preference, the precipitation section shell is square cone structure;The spraying pipeline quantity is no less than 6.
As a preference, the job platform is made of stainless steel plate of the thickness between 1cm~1.5cm, in operation
Platform periphery is provided with safety barrier, and the safety barrier height is connected on the job platform between 80cm~120cm
Ladder.
Further, the longer heating tube of good corrosion resistance, service life in order to obtain, the heating tube is by ratio of weight and the number of copies
It is composed of the following components:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4-
Four 136.2~245.1 parts of chlorozincate (2:1) of [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4), 3- methyl mercapto fourth
132.6~149.7 parts of acetoacetic ester, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- third
Alkenyl) -4,1- phenylene] Oxymethylene] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer 138.4~
199.1 parts, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia benzene oxygen
Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of base-Isosorbide-5-Nitrae-phenylene imino group] 133.5~175.9 parts, first
135.1~175.6 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate,
124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of methyl ethyl ketoxime sealing end, 7- methyl-octanoic 123.2~
166.8 parts, 132.6~177.2 parts of hexyl formate, 142.1~186.1 parts of polyurethane resin, mass concentration be 132mg/L~
165.7~219.5 parts of the phosphoric acid cetyl ester sylvite of 399mg/L.
Further, the longer heating tube of good corrosion resistance, service life in order to obtain, the production method of the heating tube is such as
Under:
Step 1: in more kettle reactors, distilled water and 3- methyl undecanonitrile is added, starts the stirring in more kettle reactors
Machine, setting speed are 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, rise to temperature
149.0 DEG C~150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) four is added
Chlorozincate (2:1) stirs evenly, and carries out reaction 126.3~137.5 minutes, and 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes;It is added in more kettle reactors later golden yellow hidden
Colour solid, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation
126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added
Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2
~8.9, keep the temperature 126.2~366.2 minutes;
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication
After 0.132~1.199 hour;Pb nanoparticles are added in another more kettle reactor, addition mass concentration is 136mg/L
[Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of~366mg/L
(dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors
Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8
×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes;It is quiet to stop reaction later
It sets 6.66 × 10~12.1 × 10 minutes, removes impurity;Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension
Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732
×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding
0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionising radiation spoke after mixing
According to the energy of ionizing radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time is
135.2~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change;By alkali formula cupric phosphate and lead
Nanoparticle mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, setting temperature
134.6 DEG C~180.2 DEG C of degree starts the blender in more kettle reactors, and revolving speed is 126rpm~521rpm, and pH is adjusted to 4.1
Between~8.1, it is dehydrated 135.1~149.1 minutes, it is spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L~366mg/L blocks, cocurrent adds to the 1st
In more kettle reactors of step, flow acceleration is 271mL/min~999mL/min;Start more kettle reaction mechanical stirrers, setting speed
For 140rpm~180rpm;Stirring 4~8 minutes;7- methyl-octanoic is added, the seal steam heat in more kettle reactors is started
Exchanger is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/
Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes;More kettle reaction mechanical stirrers are again started up, revolving speed is
135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points
Clock;
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts more kettle reactions
Seal steam heat exchanger in device sets temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, it is added
Polyurethane resin reacts 126.2~137.1 minutes;Phosphoric acid cetyl ester sylvite is added later, starts in more kettle reactors
Seal steam heat exchanger, sets temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, pH adjust to 4.2~8.2 it
Between, pressure is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to
126.2 DEG C~137.1 DEG C discharge into molding press to get to heating tube;
The partial size of the Pb nanoparticles is 140 μm~150 μm.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention;
Fig. 2 is the structural schematic diagram of Chinese medicine mixing apparatus of the present invention;
Fig. 3 is the structural schematic diagram of neutral tube of the present invention;
Fig. 4 is the structural schematic diagram of Turbulent Flow processor in the present invention;
Fig. 5 is the structural schematic diagram that Turbulent Flow promotees reactor in the present invention;
Fig. 6 is the structural schematic diagram of active resonance device in the present invention;
Fig. 7 is the structural schematic diagram of precipitation section in the present invention;
Fig. 8 is the structural schematic diagram of mobile gas transmission station in the present invention;
Fig. 9 be in the present invention heating tube corrosion resistant erosion degree with using time changing curve figure.
In figure: 1, ladder, 2, job platform, 3, medicament mixing apparatus, 3-1, confection discharge pipe, 3-2, steam spray
Pipeline, 3-3, cellular reactor are penetrated, 3-3-2,3-3-1, annular slab lead note pipe, 3-3-3, heating tube, 3-3-4, hexagon shell
Body, 3-4, additive charging line, 3-5, medicament filling line, 3-6, washing pipeline, 3-7, temperature sensor, 3-8, pedestal,
3-9, medicament mixing shell, 3-10, steam supply pipe road, 4, addition pipeline, 5, Turbulent Flow processor, 5-1, liquid inlet electromagnetic valve,
5-2, spraying pipeline, 5-3, Turbulent Flow promote reactor, 5-3-1, supercharging impeller, 5-3-2, active resonance device, 5-3-2-1, cylinder
Shape grid shell, 5-3-2-2, drive rod, 5-3-2-3, resonance strainer, 5-3-2-4, upright bar, 5-3-2-5, resonance head, 5-3-2-
6, lantern ring, 5-3-3, reaction sphere grid, 5-3-4, reaction sphere, 5-3-5, temperature sensing device, 5-3-6, multiple dimethyl disulfide
For carbamic acid sodium spray head, 5-3-7, sodium dimethyldithiocar-bamate (SDDC) medicament pipe, 5-4, precipitation section, 5-4-1, electric and magnetic oscillation
Stick, 5-4-2, current stabilization wing plate, 5-4-3, macromolecule current stabilization sieve, 5-4-4, aluminium polychloride dispersion pipe, 5-4-5, precipitation section shell
Body, 5-4-6, middle storage tank, 5-4-7, middle storage tank water pump, 5-5, liquid valve, 5-6, temperature detector, 5-7, liquidometer, 5-8, exposure
Tracheae, 5-9, mud line, 5-10, drain line, 5-11, turbulent flow shell, 5-12, mud valve, 6, mobile gas transmission station, 6-1,
Movable pulley, 6-2, mobile loading plate, 6-3, aeration pump, 6-4, gas flowmeter, 6-5, gas valve, 6-6, air delivering pipeline, 7, control
System processed.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
As shown in Figures 1 to 8, a kind of to be percolated liquid processing device for residents in rural community including hanging by bracket one
The job platform 2 installed, further includes medicament mixing apparatus 3, mobile gas transmission station 6 and control system 7, the job platform 2
Side has vacantly installed Turbulent Flow processor 5 by bracket two, and the medicament mixing apparatus 3 is located at by the fixed branch of pedestal 3-8
The lower part of job platform 2;
The medicament mixing apparatus 3 includes medicament mixing shell 3-9, and the middle part in the medicament mixing shell 3-9 is under
Portion is fixedly installed cellular reactor 3-3 and vapor injection line 3-2 respectively, and the bottom of medicament mixing shell 3-9 is fixed to be connected
It is connected to the confection discharge pipe 3-1 being connected to its inner cavity, the top of medicament mixing shell 3-9 is fixedly connected with and its inner cavity
Temperature biography is further fixedly arranged in the medicament filling line 3-5 and additive charging line 3-4 of connection, medicament mixing shell 3-9
Sensor 3-7;The section of the cellular reactor 3-3 is honeycomb, and up and down, by the standpipe of more honeycomb arrangements
Composition, the standpipe include that hexagon shell 3-3-4, upper and lower ends by annular slab 3-3-1 are fixedly connected on hexagon shell
3-3-4 lumen centers lead note pipe 3-3-2, inside hexagon shell 3-3-4 and being wound around for spiral is led outside note pipe 3-3-2
The heating tube 3-3-3 in portion, the power supply line of heating tube 3-3-3 sequentially pass through after hexagon shell 3-3-4 medicament mixing shell 3-9 with
Control system 7 connects;The vapor injection line 3-2 is annular in shape, and upper surface is provided with throughout ground to be connected to its inner cavity
Through-hole, the steam supply pipe road 3-10 of connection vapor injection line 3-2 steam after being pierced by medicament mixing shell 3-9 with external high pressure
The connection of steam pipe road;By the setting of vapor injection line 3-2 high temperature can be equably ejected to the cellular reactor 3-3 on top
Steam, to promote the reaction of medicament;The outlet end of the confection discharge pipe 3-1 passes through pressure pump and is fixedly connected on
The liquid feeding end of the side addition pipeline 4 on 5 top of Turbulent Flow processor is fixedly connected, and is added and is provided with solenoid valve A on pipeline 4;Institute
State addition pipeline 4, confection discharge pipe 3-1, medicament filling line 3-5, additive charging line 3-4 and steam supply pipe
Solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E are respectively arranged on the 3-10 of road;Medicament, additive respectively from
Medicament injection pipe 3-5, medicament injection pipe 3-5 are filled into medicament mixing apparatus 3, the sprayed high-temperature steam of steam injection pipe 3-2
Promote medicament in cellular reactor 3-3 internal-response, after be discharged from confection delivery pipe 3-1;
The lower part of Turbulent Flow processor 5 is arranged in the movable type gas transmission station 6, and mobile gas transmission station 6 includes mobile carrying
Plate 6-2, two couples of movable pulley 6-1 for being rotatably connected to the lower part mobile loading plate 6-2, it is securely fitted in mobile loading plate 6-2
The aeration pump 6-3 on top, it is connected to gas flowmeter 6-4 and air delivering pipeline 6-6 at the gas outlet aeration pump 6-3, is arranged in gas transmission
Gas valve 6-5 on pipeline 6-6;Brake gear can be set on movable pulley 6-1, be also provided with for driving its rotation
Driving motor.
The Turbulent Flow processor 5 includes the turbulent flow shell 5-11 of upper end opening, is fixedly connected in turbulent flow shell 5-11
The spray pipe network of chamber middle and upper part is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part in the inner cavity turbulent flow shell 5-11, is fixedly connected
Aeration tube 5-8, the temperature detector 5-6 that is fixed inside turbulent flow shell 5-11 in the turbulent flow inner cavity shell 5-11 middle and lower part
With liquidometer 5-7;
The spray pipe network is made of more interconnected spraying pipeline 5-2, and the lower part of every spraying pipeline 5-2 connects
It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end
Road 5-13 is pierced by by the upper end of turbulent flow shell 5-11 and is connect with the water outlet of external water pump, is connected on inlet pipe 5-13
Liquid inlet electromagnetic valve 5-1, the Turbulent Flow adsorbing mechanism promote reactor 5-3 by several Turbulent Flows being distributed in display and form,
The Turbulent Flow adsorbing mechanism promotees reactor 5-3 by several Turbulent Flows being distributed in display and forms, and the Turbulent Flow promotees anti-
Device 5-3 is answered to include the reaction sphere grid 5-3-3 for being surrounded by tubular construction, be rotatablely arranged at the inner cavity reaction sphere grid 5-3-3
The supercharging impeller 5-3-1 of the bottom and active resonance device 5-3-2 for being fixed at the reaction sphere inner cavity grid 5-3-3 lower part;Institute
State the waterproof machine driving rotation that supercharging impeller 5-3-1 promotees the lower part reactor 5-3 by being located at Turbulent Flow;In active resonance device 5-
The top 3-2 support has a large amount of reaction sphere 5-3-4, and the outer diameter of reaction sphere 5-3-4 is greater than the gap of reaction sphere grid 5-3-3 and has
The mesh diameter of source resonance device 5-3-2;A large amount of reaction sphere 5-3-4 is full of the upper space of entire reaction sphere grid 5-3-3;
Temperature sensing device 5-3-5 is internally provided in reaction sphere grid 5-3-3;Spray is additionally provided on the top reaction sphere grid 5-3-3
Device, spray equipment include the sodium dimethyl dithiocarbamate medicament pipe 5-3-7 of annular, are circumferentially uniformly fixedly connected on two
Multiple sodium dimethyl dithiocarbamate spray head 5-3-6 of the lower part sodium dimethyldithiocar-bamate (SDDC) medicament pipe 5-3-7, with first
The spray supervisor of the base nabam medicament inner cavity pipe 5-3-7 connection connect with external pressure pump;It is described active
Resonance device 5-3-2 includes tubular grid shell 5-3-2-1 up and down, is respectively fixedly connected in tubular grid shell 5-3-
Two resonance strainer 5-3-2-3 at 2-1 upper open end and lower open end, tubular grid shell 5-3-2-1 are internally provided with more
A resonant element, each resonant element is by multiple resonance head 5-3-2-5 equally distributed along its length, the adjacent resonance head of connection
Multiple drive rod 5-3-2-2 composition between 5-3-2-5, tubular grid shell 5-3-2-1 are vertical by more be circumferentially uniformly arranged
Bar 5-3-2-4 and longitudinal gap setting and the lantern ring 5-3-2-6 composition for being fixedly connected on the more peripheries upright bar 5-3-2-4;It is described
Resonance head 5-3-2-5 is internally provided with dither, and drive rod 5-3-2-2 is cavity structure, the power supply line of dither
Turbulent flow shell 5-11 is pierced by after being pierced by by drive rod 5-3-2-2 again to connect with control system 7, the mesh of resonance strainer 5-3-2-3
Aperture is 5mm~20mm;In a ring, upper part is provided with the solarization air cap being connected to its inner cavity to the aeration tube 5-8;Air delivering pipeline
Input end of the outlet side of 6-6 after turbulent flow shell 5-11 with aeration tube 5-8;
The lower part of the turbulent flow shell 5-11 is that precipitation section 5-4, the precipitation section 5-4 funnel-shaped include precipitation section shell
Body 5-4-5, and it is successively fixedly installed inside precipitation section shell 5-4-5 dispersal unit, current stabilization buffer cell, steady from top to bottom
Stream concussion unit;Two aluminium polychloride dispersion pipe 5- in rectangular ring that the dispersal unit is arranged side by side in parallel by left and right
4-4 and the multiple nozzles composition for being evenly connected at each lower part aluminium polychloride dispersion pipe 5-4-4;The current stabilization buffer cell
It is made of the multiple macromolecule current stabilization sieve 5-4-3 being longitudinally stacked;Current stabilization concussion unit is by from left to right successively etc.
Multiple current stabilizations of distance interval arrangement shake monomer composition, and the current stabilization concussion monomer is by being fixedly connected on precipitation section shell 5-4-
Two electric and magnetic oscillation stick 5-4-1 of the 5 bottom ends and current stabilization wing plate 5-4-2 for being fixedly connected on two upper ends electric and magnetic oscillation stick 5-4-1
Composition, the vertical section of the current stabilization wing plate 5-4-2 are in the W type toppled over;The middle part of the precipitation section shell 5-4-5 and lower end difference
It is fixedly connected with the drain line 5-10 being connected to its inner cavity and mud line 5-9, the mud line 5-9 and drain line 5-
It is connected separately with mud valve 5-12 and liquid valve 5-5 on 10, the liquid feeding end of mud line 5-9 and drain line 5-10 are located at
The bottom and middle part of precipitation section shell 5-4-5, the liquid feeding end of drain line 5-10 is located at current stabilization buffer cell and current stabilization concussion is single
Between member;Storage tank 5-4-6 and middle storage tank water pump 5-4-7, middle storage tank 5-4-6 in the outside of precipitation section shell 5-4-5 is provided with
In store polymeric aluminum chlorides solution, the liquid feeding end of middle storage tank water pump 5-4-7 passes through the bottom of pipeline and the inner cavity middle storage tank 5-4-6
Perforation connection, the outlet end of middle storage tank water pump 5-4-7 pass through the inner cavity of pipeline and two aluminium polychloride dispersion pipe 5-4-4 respectively
Connection;The mesh aperture of the current stabilization sieve 5-4-3 is 5mm~16mm;The quantity of current stabilization sieve 5-4-3 is 10;It is described steady
The quantity of stream concussion monomer is 10, and the distance between adjacent current stabilization concussion monomer is 2cm~6cm;The same current stabilization concussion is single
It is distributed to two electric and magnetic oscillation stick 5-4-1 front-rear directions among body, and at a distance of 10cm~60cm.Sewage is from precipitation section shell 5-
The top 4-5 enters, and meets with the aluminium polychloride dispersion pipe 5-4-4 aluminium polychloride sprayed, and in macromolecule current stabilization sieve 5-
Under the buffer function of 4-3, the lower part of precipitation section shell 5-4-5 is fallen into;At this time in current stabilization wing plate 5-4-2 in electric and magnetic oscillation stick 5-4-
Horizontal concussion is carried out under 1 drive, meanwhile, the horizontal concussion of certain amplitude can also occur for electric and magnetic oscillation stick 5-4-1 itself, thus
It can accelerate flocculation reaction, when current stabilization wing plate 5-4-2, electric and magnetic oscillation stick 5-4-1 stop working, the organic matter flocculation precipitating and bottom of from
The sludge pipe 5-9 in portion is discharged, and clear water is discharged from the drain line 5-10 at middle part;
Solenoid valve A, aeration pump 6-3, gas flowmeter 6-4, gas valve 6-5, temperature detector 5-6, liquidometer 5-7, water
Pump, liquid inlet electromagnetic valve 5-1, mud valve 5-12, liquid valve 5-5, temperature sensor 3-7, solenoid valve B, solenoid valve C, solenoid valve D,
Electric and magnetic oscillation stick 5-4-1, middle storage tank water pump 5-4-7, waterproof machine, temperature sensing device 5-3-5 and pressure pump with control
System 7 connects.
The medicament mixing apparatus 3 further includes the washing pipeline 3-6 for being fixedly connected on the top medicament mixing shell 3-9, is washed
The one end of pipeline 3-6 outside medicament mixing shell 3-9 is washed to connect with the water outlet of washing water pump, in medicament mixing shell 3-9
Internal one end is fixedly connected with the lotus spray-head that the top cellular reactor 3-3 is arranged in;It is arranged on the washing pipeline 3-6
There is solenoid valve F;Solenoid valve F is connect with control system 7.
The temperature detector 5-6 is mounted on turbulent flow shell 5-11 inner sidewall, apart from the upper end turbulent flow shell 5-11
Distance is between 15cm~25cm;The liquidometer 5-7 is set on inner wall, and liquidometer 5-7 is apart from the bottom end turbulent flow shell 5-11
Distance between 40cm~60cm.
The water outlet of the drain line 5-10 is connected to external collecting tank.
The movable plate 6-2 is the galvanized sheet of rectangle.
The aeration pump 6-3 quantity is two.
The precipitation section shell 5-4-5 is square cone structure;The spraying pipeline 5-2 quantity is no less than 6.
The job platform 2 is made of stainless steel plate of the thickness between 1cm~1.5cm, is arranged on 2 periphery of job platform
There is safety barrier, the safety barrier height is connected with ladder 1 on the job platform 2 between 80cm~120cm.
Further, the longer heating tube 3-3-3 of good corrosion resistance, service life, the heating tube 3-3-3 are pressed in order to obtain
Weight fraction ratio is composed of the following components:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4-
Four 136.2~245.1 parts of chlorozincate (2:1) of [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4), 3- methyl mercapto fourth
132.6~149.7 parts of acetoacetic ester, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- third
Alkenyl) -4,1- phenylene] Oxymethylene] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer 138.4~
199.1 parts, 140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia benzene oxygen
Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of base-Isosorbide-5-Nitrae-phenylene imino group] 133.5~175.9 parts, first
135.1~175.6 parts of polymer of aldehyde and binonylphenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate,
124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of methyl ethyl ketoxime sealing end, 7- methyl-octanoic 123.2~
166.8 parts, 132.6~177.2 parts of hexyl formate, 142.1~186.1 parts of polyurethane resin, mass concentration be 132mg/L~
165.7~219.5 parts of the phosphoric acid cetyl ester sylvite of 399mg/L.
Further, the longer heating tube 3-3-3 of good corrosion resistance, service life in order to obtain, the heating tube 3-3-3's
The production method is as follows:
Step 1: in more kettle reactors, distilled water and 3- methyl undecanonitrile is added, starts the stirring in more kettle reactors
Machine, setting speed are 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, rise to temperature
149.0 DEG C~150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) four is added
Chlorozincate (2:1) stirs evenly, and carries out reaction 126.3~137.5 minutes, and 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes;It is added in more kettle reactors later golden yellow hidden
Colour solid, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation
126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added
Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2
~8.9, keep the temperature 126.2~366.2 minutes;
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication
After 0.132~1.199 hour;Pb nanoparticles are added in another more kettle reactor, addition mass concentration is 136mg/L
[Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of~366mg/L
(dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors
Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8
×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes;It is quiet to stop reaction later
It sets 6.66 × 10~12.1 × 10 minutes, removes impurity;Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension
Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732
×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding
0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionising radiation spoke after mixing
According to the energy of ionizing radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time is
135.2~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change;By alkali formula cupric phosphate and lead
Nanoparticle mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, setting temperature
134.6 DEG C~180.2 DEG C of degree starts the blender in more kettle reactors, and revolving speed is 126rpm~521rpm, and pH is adjusted to 4.1
Between~8.1, it is dehydrated 135.1~149.1 minutes, it is spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L~366mg/L blocks, cocurrent adds to the 1st
In more kettle reactors of step, flow acceleration is 271mL/min~999mL/min;Start more kettle reaction mechanical stirrers, setting speed
For 140rpm~180rpm;Stirring 4~8 minutes;7- methyl-octanoic is added, the seal steam heat in more kettle reactors is started
Exchanger is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/
Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes;More kettle reaction mechanical stirrers are again started up, revolving speed is
135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points
Clock;
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts more kettle reactions
Seal steam heat exchanger in device sets temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, it is added
Polyurethane resin reacts 126.2~137.1 minutes;Phosphoric acid cetyl ester sylvite is added later, starts in more kettle reactors
Seal steam heat exchanger, sets temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, pH adjust to 4.2~8.2 it
Between, pressure is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to
126.2 DEG C~137.1 DEG C discharge into molding press to get to heating tube 3-3-3;
The partial size of the Pb nanoparticles is 140 μm~150 μm.
Following embodiment further illustrates the contents of the present invention, and as heating tube 3-3-3, it is important set of the invention
Part increases the service life of integral device due to its presence, it plays pass for the safety of integral device, even running
Key effect.For this purpose, by it is following be embodiment, further verify heating tube 3-3-3 of the present invention, what is shown is higher than
The physical characteristic of other related patents.
Embodiment 1
Heating tube 3-3-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 133.3 parts of 341.0 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles
Blender in reactor, setting speed 134rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter
To 149.0 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added
136.2 parts of salt (2:1) stirs evenly, and carries out reaction 126.3 minutes, and 132.6 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.1m3The fluorine gas of/min 126.3 minutes;135.2 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up
Seal steam heat exchanger in more kettle reactors makes temperature rise to 166.2 DEG C, keeps the temperature 126.6 minutes, and 2,2'- [(1- is added
Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl
138.4 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 4.2, keeps the temperature 126.2 minutes;
Step 2: separately taking 140.9 parts of Pb nanoparticles, by Pb nanoparticles power be 6.66KW under ultrasonication
After 0.132 hour;Pb nanoparticles are added in another more kettle reactor, the polymerization that mass concentration is 136mg/L is added
[Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group
Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 133.5 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors
Device makes solution temperature at 46 DEG C, starts the blender in more kettle reactors, and with 4 × 102The speed of rpm stirs, and adjusts pH value
4.4, insulated and stirred 132 minutes;Stop reaction later and stand 6.66 × 10 minutes, removes impurity;Formaldehyde is added in suspension
With 135.1 parts of polymer of binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value forms sediment distillation washing 1.4
It is de-, by centrifuge in revolving speed 4.732 × 103Solid content is obtained under rpm, 2.95 × 102It is dry at a temperature of DEG C, mistake after grinding
0.732×103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate 135.6 and step 2 to handle, after mixing using ionization spoke
Irradiation is penetrated, the energy of ionizing radiation is 123.2MeV, dosage 171.2kGy, irradiation time are 135.2 minutes, obtaining property
The alkali formula cupric phosphate and Pb nanoparticles mixture that shape changes;Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another more
In kettle reactor, starts the seal steam heat exchanger in more kettle reactors, 134.6 DEG C of set temperature, start more kettle reactors
In blender, revolving speed 126rpm, pH are adjusted to 4.1, are dehydrated 135.1 minutes, spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 124.4 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136mg/L blocks, cocurrent adds to step 1
More kettle reactors in, flow acceleration 271mL/min;Start more kettle reaction mechanical stirrers, setting speed 140rpm;Stirring
4 minutes;123.2 parts of 7- methyl-octanoic are added, starts the seal steam heat exchanger in more kettle reactors, is warming up to 170.7
DEG C, pH is adjusted to 4.7, and being passed through fluorine gas ventilatory capacity is 125.293m3/ min, heat preservation stand 160.0 minutes;It is anti-to be again started up more kettles
Mechanical stirrer is answered, revolving speed 135rpm is added 132.6 parts of hexyl formate, and pH is made to be adjusted to 4.7, and heat preservation stands 159.3 points
Clock;
Step 5: starting the blender in more kettle reactors, and setting speed 132rpm starts the vapour in more kettle reactors
Gland steam heat exchanger sets temperature in more kettle reactors as 1.581 × 102DEG C, 142.1 parts of polyurethane resin are added, instead
It answers 126.2 minutes;165.7 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 132mg/L is added later, starts more kettle reactions
Seal steam heat exchanger in device, sets temperature in more kettle reactors as 210.6 DEG C, and pH is adjusted to 4.2, and pressure is
1.32MPa, reaction time are 0.4 hour;Be depressurized to later gauge pressure be 0MPa, be cooled to 126.2 DEG C discharge into molding press to get
To heating tube 3-3-3;The partial size of the Pb nanoparticles is 140 μm.
Embodiment 2
Heating tube 3-3-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 175.5 parts of 566.2 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles
Blender in reactor, setting speed 180rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter
To 150.2 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added
245.1 parts of salt (2:1) stirs evenly, and carries out reaction 137.5 minutes, and 149.7 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 166.7m3The fluorine gas of/min 137.5 minutes;192.9 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up
Seal steam heat exchanger in more kettle reactors makes temperature rise to 199.1 DEG C, keeps the temperature 137.7 minutes, and 2,2'- [(1- is added
Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl
199.1 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 8.9, keeps the temperature 366.2 minutes;
Step 2: separately taking 195.2 parts of Pb nanoparticles, by Pb nanoparticles power be 12.1KW under ultrasonication
1.199 after hour;Pb nanoparticles are added in another more kettle reactor, the polymerization that mass concentration is 366mg/L is added
[Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group
Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 175.9 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors
Device makes solution temperature between 86 DEG C, starts the blender in more kettle reactors, and with 8 × 102The speed of rpm stirs, adjustment
PH value is 8.8, insulated and stirred 199 minutes;Stop reaction later and stand 12.1 × 10 minutes, removes impurity;Suspension is added
175.6 parts of polymer of formaldehyde and binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value form sediment distillation 2.8
Water elution, by centrifuge in revolving speed 9.23 × 103Solid content is obtained under rpm, 3.419 × 102It is dry at a temperature of DEG C, grinding
1.23 × 10 are crossed afterwards3Mesh, it is spare;
Step 3: Pb nanoparticles after 158.1 parts of alkali formula cupric phosphate and step 2 processing are separately taken, after mixing using ionization
Radiation, the energy of ionizing radiation is 151.8MeV, dosage 211.8kGy, irradiation time are 160.8 minutes, is obtained
The alkali formula cupric phosphate and Pb nanoparticles mixture that character changes;Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another
In more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, 180.2 DEG C of set temperature, start more kettle reactions
Blender in device, revolving speed 521rpm, pH are adjusted to 8.1, are dehydrated 149.1 minutes, spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 366mg/L blocks, cocurrent adds to step 1
More kettle reactors in, flow acceleration 999mL/min;Start more kettle reaction mechanical stirrers, setting speed 180rpm;Stirring
8 minutes;166.8 parts of 7- methyl-octanoic are added, starts the seal steam heat exchanger in more kettle reactors, is warming up to 207.5
DEG C, pH is adjusted to 8.5, and being passed through fluorine gas ventilatory capacity is 166.410m3/ min, heat preservation stand 190.2 minutes;It is anti-to be again started up more kettles
Mechanical stirrer is answered, revolving speed 180rpm is added 177.2 parts of hexyl formate, and pH is made to be adjusted to 8.5, and heat preservation stands 199.5 points
Clock;
Step 5: starting the blender in more kettle reactors, and setting speed 199rpm starts the vapour in more kettle reactors
Gland steam heat exchanger sets temperature in more kettle reactors as 2.462 × 102DEG C, 186.1 parts of polyurethane resin are added, instead
It answers 137.1 minutes;219.5 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 399mg/L is added later, starts more kettle reactions
Seal steam heat exchanger in device, sets temperature in more kettle reactors as 266.7 DEG C, and pH is adjusted to 8.2, and pressure is
1.33MPa, reaction time are 0.9 hour;Be depressurized to later gauge pressure be 0MPa, be cooled to 137.1 DEG C discharge into molding press to get
To heating tube 3-3-3;The partial size of the Pb nanoparticles is 150 μm.
Embodiment 3
Heating tube 3-3-3 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in more kettle reactors, 133.9 parts of 341.9 parts of distilled water and 3- methyl undecanonitrile is added, starts more kettles
Blender in reactor, setting speed 134rpm start the seal steam heat exchanger in more kettle reactors, make temperature liter
To 149.9 DEG C, 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) tetrachloro zincic acid is added
136.9 parts of salt (2:1) stirs evenly, and carries out reaction 126.9 minutes, and 132.9 parts of 3- methylmercapto butyric acid ethyl ester is added, is passed through flow
For 125.9m3The fluorine gas of/min 126.9 minutes;135.9 parts of golden yellow leuco compound is added in more kettle reactors later, is again started up
Seal steam heat exchanger in more kettle reactors makes temperature rise to 166.9 DEG C, keeps the temperature 126.9 minutes, and 2,2'- [(1- is added
Methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] Oxymethylene] bisoxiranes and hydrogen sealing end poly dimethyl
138.9 parts of the polymer of siloxanes, the pH value for adjusting solution in more kettle reactors is 4.9, keeps the temperature 126.9 minutes;
Step 2: separately taking 140.9 parts of Pb nanoparticles, by Pb nanoparticles power be 6.669KW under ultrasonication
After 0.1329 hour;Pb nanoparticles are added in another more kettle reactor, it is the poly- of 136.9mg/L that mass concentration, which is added,
Close [Oxy-1, carbon-based (the dicarboxyl cyclobutane two of the Asia 4- benzene (the 1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group
Base) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] 133.9 parts of dispersion Pb nanoparticles, start the seal steam heat exchange in more kettle reactors
Device makes solution temperature at 46.9 DEG C, starts the blender in more kettle reactors, and with 4.9 × 102The speed of rpm stirs, adjustment
PH value is 4.9, insulated and stirred 132.9 minutes;Stop reaction later and stand 6.66 × 10 minutes, removes impurity;By suspension plus
Enter 135.9 parts of polymer of formaldehyde and binonylphenol, nonyl phenol and ethylene oxide, adjustment pH value forms sediment and steam 1.9
Distilled water elution, by centrifuge in revolving speed 4.732 × 103Solid content is obtained under rpm, 2.95 × 102It is dry at a temperature of DEG C, it grinds
0.732 × 10 is crossed after mill3Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate 135.9 and step 2 to handle, after mixing using ionization spoke
Irradiation is penetrated, the energy of ionizing radiation is 123.9MeV, dosage 171.9kGy, irradiation time are 135.9 minutes, obtaining property
The alkali formula cupric phosphate and Pb nanoparticles mixture that shape changes;Alkali formula cupric phosphate and Pb nanoparticles mixture are placed in another more
In kettle reactor, starts the seal steam heat exchanger in more kettle reactors, 134.9 DEG C of set temperature, start more kettle reactors
In blender, revolving speed 126rpm, pH are adjusted to 4.9, are dehydrated 135.9 minutes, spare;
Step 4: it is dense to add to quality for the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes
In 124.9 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) that the methyl ethyl ketoxime that degree is 136.9mg/L blocks, cocurrent adds to the 1st
In more kettle reactors of step, flow acceleration 271.9mL/min;Start more kettle reaction mechanical stirrers, setting speed 140rpm;
Stirring 4.9 minutes;123.9 parts of 7- methyl-octanoic are added, the seal steam heat exchanger in more kettle reactors is started, is heated up
To 170.9 DEG C, pH is adjusted to 4.9, and being passed through fluorine gas ventilatory capacity is 125.9m3/ min, heat preservation stand 160.9 minutes;It is again started up
More kettles react mechanical stirrer, and revolving speed 135rpm is added 132.9 parts of hexyl formate, and pH is made to be adjusted to 4.9, and heat preservation is stood
159.9 minute;
Step 5: starting the blender in more kettle reactors, and setting speed 132rpm starts the vapour in more kettle reactors
Gland steam heat exchanger sets temperature in more kettle reactors as 1.581 × 102DEG C, 142.9 parts of polyurethane resin are added, instead
It answers 126.9 minutes;165.7 parts of the phosphoric acid cetyl ester sylvite that mass concentration is 132mg/L is added later, starts more kettle reactions
Seal steam heat exchanger in device, sets temperature in more kettle reactors as 210.9 DEG C, and pH is adjusted to 4.9, and pressure is
1.32MPa, reaction time are 0.41 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to 126.9 DEG C and discharges into molding press, i.e.,
Obtain heating tube 3-3-3;The partial size of the Pb nanoparticles is 140 μm.
Reference examples
Reference examples are tested for the property test using the heating tube of certain commercially available brand.
Embodiment 4
Examples 1 to 3 and reference examples heating tube 3-3-3 obtained are tested for the property test, it is right after test
The parameters such as compression strength enhancing rate, resistance to deformation strength enhancing rate, partition service life enhancing rate, impact resistance enhancing rate carry out
Analysis.Data analysis is as shown in table 1.
As seen from Table 1, heating tube 3-3-3 of the present invention, obviously higher than the prior art in Specifications
The product of production.
In addition, as shown in figure 9, the production that Examples 1 to 3 in Specifications, is substantially produced better than the prior art
Product.
Working method of one of the present invention for residents in rural community diafiltration liquid processing device, this method includes following
Several steps:
Step 1: heating heating tube 3-3-3 by control system 7, controls solenoid valve E, electricity by control system 7
Magnet valve C and solenoid valve D is opened, and is fed steam by steam supply pipe road 3-10, is passed through medicament injection pipe 3-5, medicament injection pipe
3-5 is separately added into medicament, additive, into the liquid in medicament mixing shell 3-9 evenly into cellular reactor 3-3
In, liquid is dispersed by diversion pipe 3-3-2 in multiple standpipes, then accelerates instead under the double action of heating tube 3-3-3 and steam
It answers, the effect and efficiency of reaction can be effectively improved, the inorganic flocculating agent generated after reaction is arranged by confection discharge pipe 3-1
Out;
Step 2 is opened liquid inlet electromagnetic valve 5-1 by control system 7, is fed underground engineering waste water using pressure pump, and
By being sprayed onto Turbulent Flow processor 5 for the even action of spraying pipeline 5-2 and nozzle, after 15min, then pass through control
System 7 starts aeration pump 6-3, waterproof machine on mobile gas transmission station 6, opens simultaneously the gas valve 6- on air delivering pipeline 6-6
5, fresh air is fed by Turbulent Flow processor 5 by aeration tube 5-8, increases the oxygen content in Turbulent Flow processor 5, to kill
Anaerobe opens the solenoid valve A on addition pipeline 4 by control system 7, to Turbulent Flow processor 5 after 10min
Interior addition inorganic flocculating agent is adequately reacted with sewage, when sewage is fallen into precipitation section shell 5-4-5, control system 7
Storage tank water pump 5-4-7 and electric and magnetic oscillation stick 5-4-1 in starting feeds aluminium polychloride by aluminium polychloride dispersion pipe 5-4-4
To carry out degerming, deodorization and decoloration to sewage, control electric and magnetic oscillation stick 5-4-1 drives current stabilization wing plate 5-4-2 to produce in the horizontal direction
The concussion of raw certain amplitude, double buffering of the sewage of whereabouts in macromolecule current stabilization sieve 5-4-3 and current stabilization wing plate 5-4-2 act on
Lower adequately to react with inorganic flocculating agent, sediment falls into the lower part of precipitation section shell 5-4-5;By the reaction of setting time
Afterwards, the sediment after flocculation is discharged through mud line 5-9, and the clear water near current stabilization wing plate 5-4-2 is discharged from drain line 5-10
Swallow enters collecting tank;
In this process, control system 7 controls external transfer pump for sodium dimethyl dithiocarbamate from dimethyl two
Thiocarbamic acid sodium spray head 5-3-6 atomization sprays, and mixes, is reacting with the top reactor 5-3 inflow solution is promoted from Turbulent Flow
It is reacted under ball 5-3-4 effect, improves agent efficacy;Meanwhile positioned at the supercharging impeller 5-3-1 of bottom be solution pressurization, most
Whole solution promotees tetra- wall through-hole of reactor 5-3 from Turbulent Flow and sprays;Temperature sensing device 5-3-5 is prior art products, FY-45-
6F type reaction rate sensor is produced by Shanghai continental rise Electromechanical Technology Co., Ltd;
Step 3: the reaction sphere 5-4-3 on Turbulent Flow absorber 5-3 inhales the microorganism in the sewage of entrance
Degradation is echoed, in the process, the temperature in temperature detector 5-6 real-time monitoring Turbulent Flow processor 5;When detecting temperature height
When default value T, electric signal is fed back to control system 7 by temperature detector 5-6, and control system 7 controls coupled
Alarm sound an alarm, to notify operator to take cooling measure;
Step 4: the power supply of active resonance device 5-3-2 medium-high frequency vibrator, resonance head 5-3- are connected by control system 7
2-5 and drive rod 5-3-2-2 generates vibration by a relatively large margin together, and acts on tubular grid shell 5-3-2-1 upper open end
With the resonance strainer 5-3-2-3 of lower open end, promote mixing liquid activation while, moreover it is possible to make liquid quickly through;
Step 5: liquidometer 5-7 real-time monitoring Turbulent Flow promotees the liquid level of mixing liquid in reactor 5-3;As liquidometer 5-7
When detecting that clear water liquid level is higher than default value M, signal is fed back to control system 7 by liquidometer 5-7, and control system 7 is opened
Liquid valve 5-5, by drain line 5-10, by treated, clear water is discharged in time;
Step 6: the conveying capacity of the gas flowmeter 6-4 real-time monitoring air on mobile gas transmission station 6;Work as gas flowmeter
When 6-4 detects conveying capacity lower than default value P, feedback signal is sent to control system 7 by gas flowmeter 6-4, control
System 7 improves aeration pump 6-3 revolving speed, while increasing gas valve 6-5 aperture, to guarantee the supply of gas.
Claims (10)
1. one kind is percolated liquid processing device for residents in rural community, the job platform (2) vacantly installed including passing through bracket one,
It is characterized in that, further including medicament mixing apparatus (3), mobile gas transmission station (6) and control system (7), the job platform (2)
Side vacantly installed Turbulent Flow processor (5) by bracket two, the medicament mixing apparatus (3) is consolidated by pedestal (3-8)
Fixed branch is located at the lower part of job platform (2);
The medicament mixing apparatus (3) includes medicament mixing shell (3-9), the middle part in the medicament mixing shell (3-9) and
Lower part is fixedly installed cellular reactor (3-3) and vapor injection line (3-2), the bottom of medicament mixing shell (3-9) respectively
Portion is fixedly connected with the confection discharge pipe (3-1) being connected to its inner cavity, and the top of medicament mixing shell (3-9) is fixed to be connected
It is connected to the medicament filling line (3-5) and additive charging line (3-4) being connected to its inner cavity, medicament mixing shell (3-9) is interior
It is further fixedly arranged on temperature sensor (3-7);The section of the cellular reactor (3-3) is honeycomb, and up and down,
It is made of the standpipe of more honeycomb arrangements, the standpipe includes that hexagon shell (3-3-4), upper and lower ends pass through annular slab
(3-3-1) is fixedly connected on leading note pipe (3-3-2), being located at hexagon shell (3-3- for hexagon shell (3-3-4) lumen centers
4) internal and spiral be wound around leads the external heating tube (3-3-3) of note pipe (3-3-2), the power supply line of heating tube (3-3-3) according to
Secondary hexagon shell (3-3-4) the medicament mixing shell (3-9) that passes through is connect with control system (7) afterwards;The vapor injection line
(3-2) is annular in shape, and upper surface is provided with the through-hole being connected to its inner cavity throughout ground, connection vapor injection line (3-2)
Steam supply pipe road (3-10) is pierced by medicament mixing shell (3-9) and connect afterwards with external high steam pipeline;The mixing medicine
The outlet end of agent discharge pipe (3-1) passes through pressure pump and the side adding tube for being fixedly connected on Turbulent Flow processor (5) top
The liquid feeding end on road (4) is fixedly connected, and is provided with solenoid valve A in addition pipeline (4);The addition pipeline (4), confection discharge
Pipeline (3-1), medicament filling line (3-5) are respectively set on additive charging line (3-4) and steam supply pipe road (3-10)
There are solenoid valve A, solenoid valve B, solenoid valve C, solenoid valve D and solenoid valve E;
The movable type gas transmission station (6) is arranged in the lower part of Turbulent Flow processor (5), and mobile gas transmission station (6) includes that movement is held
Support plate (6-2), two pairs of movable pulleys (6-1) for being rotatably connected to the lower part mobile loading plate (6-2) are securely fitted in mobile hold
The aeration pump (6-3) on the top support plate (6-2) is connected to gas flowmeter (6-4) and air delivering pipeline at the gas outlet aeration pump (6-3)
(6-6), the gas valve (6-5) being arranged on air delivering pipeline (6-6);
The Turbulent Flow processor (5) includes the turbulent flow shell (5-11) of upper end opening, is fixedly connected on turbulent flow shell (5-11)
The spray pipe network of inner cavity middle and upper part is fixedly connected on the Turbulent Flow adsorbing mechanism at middle part, fixation in the inner cavity turbulent flow shell (5-11)
It is connected to the aeration tube (5-8) of the inner cavity middle and lower part turbulent flow shell (5-11), is fixed at the internal temperature of turbulent flow shell (5-11)
Spend detector (5-6) and liquidometer (5-7);
The spray pipe network is made of more interconnected spraying pipelines (5-2), and the lower part of every spraying pipeline (5-2) connects
It is connected to multiple nozzles being connected to its inner cavity distributed along its length, the inlet tube being fixedly connected with spray pipe network liquid feeding end
Road (5-13) is pierced by by the upper end of turbulent flow shell (5-11) and is connect with the water outlet of external water pump, in inlet pipe (5-13)
It is connected with liquid inlet electromagnetic valve (5-1), the Turbulent Flow adsorbing mechanism promotees reactor by several Turbulent Flows being distributed in display
(5-3) composition, the Turbulent Flow promote reactor (5-3) and include the reaction sphere grid (5-3-3) for being surrounded by tubular construction, can be rotated
Ground is set to the supercharging impeller (5-3-1) of reaction sphere grid (5-3-3) intracavity bottom and is fixed at reaction sphere grid (5-3-
3) the active resonance device (5-3-2) of inner cavity lower part;The supercharging impeller (5-3-1) promotees reactor (5-3) by being located at Turbulent Flow
The waterproof machine of lower part drives rotation;On the top active resonance device (5-3-2), support has a large amount of reaction sphere (5-3-4), instead
Answer the mesh diameter of gap of the outer diameter of ball (5-3-4) greater than reaction sphere grid (5-3-3) and active resonance device (5-3-2);
A large amount of reaction sphere (5-3-4) is full of the upper space of entire reaction sphere grid (5-3-3);In reaction sphere grid (5-3-3)
Portion is provided with temperature sensing device (5-3-5);Spray equipment, spray equipment packet are additionally provided on the top reaction sphere grid (5-3-3)
It includes the sodium dimethyl dithiocarbamate medicament pipe (5-3-7) of annular, be circumferentially uniformly fixedly connected on dimethyl disulfide for ammonia
Multiple sodium dimethyl dithiocarbamate spray heads (5-3-6) of the lower part base sodium formate medicament pipe (5-3-7) are thio with methyl two
The spray supervisor of the carbamic acid sodium medicament pipe inner cavity (5-3-7) connection connect with external pressure pump;The active resonance dress
(5-3-2) is set to include tubular grid shell (5-3-2-1) up and down, be respectively fixedly connected in tubular grid shell (5-3-
2-1) two resonance strainers (5-3-2-3) at upper open end and lower open end, setting inside tubular grid shell (5-3-2-1)
There are multiple resonant elements, each resonant element is adjacent by multiple resonance heads (5-3-2-5) equally distributed along its length, connection
Multiple drive rods (5-3-2-2) composition between resonance head (5-3-2-5), tubular grid shell (5-3-2-1) is by circumferential uniform
More upright bars (5-3-2-4) being arranged and longitudinal gap setting and the lantern ring for being fixedly connected on more upright bar (5-3-2-4) peripheries
(5-3-2-6) composition;The resonance head (5-3-2-5) is internally provided with dither, and drive rod (5-3-2-2) is cavity knot
Structure, the power supply line of dither are pierced by turbulent flow shell (5-11) and control system (7) after being pierced by by drive rod (5-3-2-2) again
Connection;In a ring, upper part is provided with the solarization air cap being connected to its inner cavity to the aeration tube (5-8);Air delivering pipeline (6-6) goes out
Gas end passes through turbulent flow shell (5-11) input end with aeration tube (5-8) afterwards;
The lower part of the turbulent flow shell (5-11) is precipitation section (5-4) funnel-shaped, and the precipitation section (5-4) includes precipitation section
Shell (5-4-5), and successively it is fixedly installed dispersal unit, current stabilization buffering from top to bottom inside precipitation section shell (5-4-5)
Unit, current stabilization shake unit;Two aluminium polychlorides in rectangular ring that the dispersal unit is arranged side by side in parallel by left and right
Dispersion pipe (5-4-4) and the multiple nozzles composition for being evenly connected at each aluminium polychloride dispersion pipe (5-4-4) lower part;It is described
Current stabilization buffer cell is made of the multiple macromolecule current stabilization sieves (5-4-3) being longitudinally stacked;Current stabilization concussion unit by
From left to right successively multiple current stabilizations of equidistant intervals arrangement shake monomer composition, and the current stabilization concussion monomer is by being fixedly connected on
Two electric and magnetic oscillation sticks (5-4-1) of the bottom end precipitation section shell (5-4-5) and it is fixedly connected on two electric and magnetic oscillation sticks (5-4-1)
The current stabilization wing plate (5-4-2) of upper end forms, and the vertical section of the current stabilization wing plate (5-4-2) is in the W type toppled over;The precipitation section shell
The middle part and lower end of body (5-4-5) are respectively fixedly connected with the drain line (5-10) being connected to its inner cavity and mud line (5-
9) it, is connected separately with mud valve (5-12) and liquid valve (5-5) in the mud line (5-9) and drain line (5-10), is arranged
Mud pipeline (5-9) and the liquid feeding end of drain line (5-10) are located at the bottom and middle part of precipitation section shell (5-4-5);Heavy
The outside of shallow lake portion shell (5-4-5) is provided with middle storage tank (5-4-6) and middle storage tank water pump (5-4-7), storage in middle storage tank (5-4-6)
There is polymeric aluminum chlorides solution, the liquid feeding end of middle storage tank water pump (5-4-7) passes through the bottom of pipeline and the inner cavity middle storage tank (5-4-6)
Perforation connection, the outlet end of middle storage tank water pump (5-4-7) pass through pipeline and two aluminium polychloride dispersion pipes (5-4-4) respectively
Inner cavity connection;
Solenoid valve A, aeration pump (6-3), gas flowmeter (6-4), gas valve (6-5), temperature detector (5-6), liquidometer (5-
7), water pump, liquid inlet electromagnetic valve (5-1), mud valve (5-12), liquid valve (5-5), temperature sensor (3-7), solenoid valve B, electromagnetism
Valve C, solenoid valve D, electric and magnetic oscillation stick (5-4-1), middle storage tank water pump (5-4-7), waterproof machine, temperature sensing device (5-3-5)
It is connect with control system (7) with pressure pump.
2. according to claim 1 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that the medicine
Agent mixing apparatus (3) further includes the washing pipeline (3-6) for being fixedly connected on the top medicament mixing shell (3-9), washing pipeline (3-
6) in the external one end of medicament mixing shell (3-9) with the connection of the water outlet of washing water pump, in medicament mixing shell (3-9) inside
One end be fixedly connected with lotus spray-head on the top cellular reactor (3-3) is arranged;It is arranged on the washing pipeline (3-6)
There is solenoid valve F;Solenoid valve F is connect with control system (7).
3. according to claim 1 or 2 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that institute
The water outlet for stating drain line (5-10) is connected to external collecting tank.
4. according to claim 3 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that described steady
The mesh aperture for flowing sieve (5-4-3) is 5mm~16mm;The quantity of current stabilization sieve (5-4-3) is 10;The current stabilization concussion is single
The quantity of body is 10, and the distance between adjacent current stabilization concussion monomer is 2cm~6cm;Among the same current stabilization concussion monomer
It is distributed to two electric and magnetic oscillation stick (5-4-1) front-rear directions, and at a distance of 10cm~60cm.
5. according to claim 4 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that the exposure
Air pump (6-3) quantity is two.
6. according to claim 5 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that described heavy
Shallow lake portion shell (5-4-5) is square cone structure;Spraying pipeline (5-2) quantity is no less than 6.
7. according to claim 6 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that the work
Industry platform (2) is made of stainless steel plate of the thickness between 1cm~1.5cm, and job platform (2) periphery is provided with safety protective
Column, the safety barrier height are connected with ladder (1) on the job platform (2) between 80cm~120cm.
8. according to claim 7 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that described to add
Heat pipe (3-3-3) is composed of the following components by ratio of weight and the number of copies:
341.0~566.2 parts of distilled water, 133.3~175.5 parts of 3- methyl undecanonitrile, 2- methoxyl group -5- methyl -4- [(4- first
Base -2- nitrobenzophenone) azo] four 136.2~245.1 parts of chlorozincate (2:1) of benzene diazonium (T-4), 3- methylmercapto butyric acid ethyl ester
132.6~149.7 parts, 135.2~192.9 parts of golden yellow leuco compound, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic)-
4,1- phenylenes] Oxymethylene] 138.4~199.1 parts of polymer of dimethyl silicone polymer of bisoxirane and hydrogen sealing end,
140.9~195.2 parts of Pb nanoparticles, it polymerize [Oxy-1, the Asia 4- benzene (1- methyl ethylidene)-Isosorbide-5-Nitrae-Asia phenoxy group-Isosorbide-5-Nitrae-Asia
Carbon-based (the dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene of phenylimino] 133.5~175.9 parts, formaldehyde and dinonyl
135.1~175.6 parts of the polymer of phenol, nonyl phenol and ethylene oxide, 135.6~158.1 parts of alkali formula cupric phosphate, methyl ethyl ketoxime envelope
124.4~160.8 parts of 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) at end, 123.2~166.8 parts of 7- methyl-octanoic, formic acid
132.6~177.2 parts of own ester, 142.1~186.1 parts of polyurethane resin, mass concentration is the phosphoric acid of 132mg/L~399mg/L
165.7~219.5 parts of cetyl ester sylvite.
9. according to claim 8 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that described to add
Heat pipe (3-3-3) the production method is as follows:
Step 1: in more kettle reactors, being added distilled water and 3- methyl undecanonitrile, start the blender in more kettle reactors, if
Determine revolving speed be 134rpm~180rpm, start the seal steam heat exchanger in more kettle reactors, make temperature rise to 149.0 DEG C~
150.2 DEG C, four chlorozincate of 2- methoxyl group -5- methyl -4- [(4- methyl -2- nitrobenzophenone) azo] benzene diazonium (T-4) is added
(2:1) is stirred evenly, and carries out reaction 126.3~137.5 minutes, 3- methylmercapto butyric acid ethyl ester is added, being passed through flow is
125.1m3/ min~166.7m3The fluorine gas of/min 126.3~137.5 minutes;Golden yellow procrypsis is added in more kettle reactors later
Body, the seal steam heat exchanger being again started up in more kettle reactors make temperature rise to 166.2 DEG C~199.1 DEG C, heat preservation
126.6~137.7 minutes, 2,2'- [(1- methyl ethylidene) bis- [[2- (2- acrylic) -4,1- phenylene] oxygen methylenes are added
Base] bisoxirane and hydrogen sealing end dimethyl silicone polymer polymer, adjust solution in more kettle reactors pH value be 4.2
~8.9, keep the temperature 126.2~366.2 minutes;
Step 2: separately taking Pb nanoparticles, by Pb nanoparticles power be 6.66KW~12.1KW under ultrasonication 0.132
After~1.199 hours;Pb nanoparticles are added in another more kettle reactor, addition mass concentration be 136mg/L~
[Oxy-1, the Asia 4- benzene (1- methyl ethylidene) Asia -1,4- phenoxy group -1,4- phenylene imino group are carbon-based for the polymerization of 366mg/L
(dicarboxyl cyclobutane diyl) carbon-based imino group-Isosorbide-5-Nitrae-Asia benzene] dispersion Pb nanoparticles, start the seal steam in more kettle reactors
Heat exchanger makes solution temperature between 46 DEG C~86 DEG C, starts the blender in more kettle reactors, and with 4 × 102Rpm~8
×102The speed of rpm stirs, and adjusts pH value between 4.4~8.8, and insulated and stirred 132~199 minutes;It is quiet to stop reaction later
It sets 6.66 × 10~12.1 × 10 minutes, removes impurity;Formaldehyde and binonylphenol, nonyl phenol and ethylene oxide is added in suspension
Polymer, adjust pH value between 1.4~2.8, formed sediment with distillation water elution, by centrifuge in revolving speed 4.732
×103Rpm~9.23 × 103Solid content is obtained under rpm, 2.95 × 102DEG C~3.419 × 102It is dry at a temperature of DEG C, grinding
0.732 × 10 is crossed afterwards3~1.23 × 103Mesh, it is spare;
Step 3: Pb nanoparticles after separately taking alkali formula cupric phosphate and step 2 to handle use ionizing radiation, electricity after mixing
Energy from radiation is 123.2MeV~151.8MeV, dosage is 171.2kGy~211.8kGy, irradiation time 135.2
~160.8 minutes, obtain the alkali formula cupric phosphate and Pb nanoparticles mixture of character change;Alkali formula cupric phosphate and lead nanometer is micro-
Grain mixture is placed in another more kettle reactors, starts the seal steam heat exchanger in more kettle reactors, set temperature 134.6
DEG C~180.2 DEG C, start the blender in more kettle reactors, revolving speed is 126rpm~521rpm, pH be adjusted to 4.1~8.1 it
Between, it is dehydrated 135.1~149.1 minutes, it is spare;
Step 4: the alkali formula cupric phosphate and Pb nanoparticles mixture that the character that step 3 is obtained changes, adding to mass concentration is
In 1, the 1'- di-2-ethylhexylphosphine oxide (isocyanato- benzene) of the methyl ethyl ketoxime sealing end of 136mg/L~366mg/L, cocurrent adds to step 1
In more kettle reactors, flow acceleration is 271mL/min~999mL/min;Start more kettle reaction mechanical stirrers, setting speed is
140rpm~180rpm;Stirring 4~8 minutes;7- methyl-octanoic is added, the seal steam heat started in more kettle reactors is handed over
Parallel operation is warming up to 170.7 DEG C~207.5 DEG C, and pH is adjusted between 4.7~8.5, and being passed through fluorine gas ventilatory capacity is 125.293m3/
Min~166.410m3/ min, heat preservation stand 160.0~190.2 minutes;More kettle reaction mechanical stirrers are again started up, revolving speed is
135rpm~180rpm is added hexyl formate, and pH is adjusted between 4.7~8.5, and heat preservation stands 159.3~199.5 points
Clock;
Step 5: starting the blender in more kettle reactors, and setting speed is 132rpm~199rpm, starts in more kettle reactors
Seal steam heat exchanger, set temperature in more kettle reactors as 1.581 × 102DEG C~2.462 × 102DEG C, poly- ammonia is added
Ester resin reacts 126.2~137.1 minutes;Phosphoric acid cetyl ester sylvite is added later, starts the packing in more kettle reactors
Steam heat-exchanger sets the temperature in more kettle reactors as 210.6 DEG C~266.7 DEG C, and pH is adjusted between 4.2~8.2, pressure
Power is 1.32MPa~1.33MPa, and the reaction time is 0.4~0.9 hour;Being depressurized to gauge pressure later is 0MPa, is cooled to 126.2
DEG C~137.1 DEG C discharge into molding press to get to heating tube (3-3-3).
10. according to claim 9 a kind of for residents in rural community diafiltration liquid processing device, which is characterized in that described
The partial size of Pb nanoparticles is 140 μm~150 μm.
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