CN107721077A

CN107721077A - A kind of underground engineering wastewater treatment integrating device and operating method

Info

Publication number: CN107721077A
Application number: CN201711077819.8A
Authority: CN
Inventors: 梁峙; 梁骁; 马捷
Original assignee: Xuzhou University of Technology
Current assignee: Xuzhou University of Technology
Priority date: 2017-11-06
Filing date: 2017-11-06
Publication date: 2018-02-23

Abstract

A kind of underground engineering wastewater treatment integrating device and operating method, device：Deodorization agent set includes deodorization tank and intelligent controller, and deodorization tank is internally provided with preprocessor, primary nanometer purification membrane, mixes agitator and two level nanometer purification membrane；The enclosure interior of preprocessor is fixedly installed the first dispersion plate, steam ring, the second dispersion plate and supporting plate successively from top to bottom, and activated carbon is filled between the second dispersion plate and supporting plate；Agitating vane is between primary nanometer purification membrane and two level nanometer purification membrane.Method：Control the electrically-controlled valve opened inside water inlet to intake by intelligent controller, sewage is pre-processed by preprocessor；The deodorant of addition is carried out by mixing stirring by the mixing agitator in deodorization jar again.The device can effectively handle caused foul gas in sewage disposal process.The operating method can effectively improve the eradicating efficacy to foul gas in sewage, the harm for being avoided that the pollution of environment and being brought to people's health.

Description

A kind of underground engineering wastewater treatment integrating device and operating method

Technical field

The present invention relates to sewage deodorizing equipment technical field, and in particular to a kind of underground engineering wastewater treatment integrating device and Operating method.

Background technology

With the quickening of Urbanization Process In China, municipal sewage treatment facility is further perfect, the meaning of sewage treatment facility It is to reduce pollution, environmental protection.The sewage treatment facility fixation urban operating mechanism widely distributed as urban core region, is being transported Substantial amounts of foul gas can be produced during row.Stench refers to that all can stimulate the olfactory organ of people, causes people's discomfort Feel, damage the smell of living environment and health.Peculiar smell in city can produce to environmental quality and people's lives can not The influence of ignorance.With people's environmental consciousness and to quality of life requirement raising, to caused by peculiar smell be discontented with and complaint amount not Disconnected increase, odor treatment increasingly cause country and relevant department to pay attention to.

Chinese city sewage composition is complicated, no matter sanitary sewage or trade effluent, in transport and processing procedure Substantial amounts of foul gas will necessarily be produced.Sewage disposal device is in day-to-day operation, because the actions such as stirring promote current turbulence, And then original in sewage and caused odorant pollutant is promoted to outside quick release, form odor polluting source.Odor pollution The irritant smell of thing, unhappy outer except making one to produce, to breathing, digesting, circulating, neural and internal system can all produce damage Evil.Common odor pollutant mainly has 3 classes：(1) sulfur-containing compound, including H2S, methyl sulfide, methyl mercaptan etc.；(2) nitrogen-containing compound, Including NH3, indoles, dimethylamine etc.；(3) carbon containing, hydrogen, oxygen compound, lower alcohol, aliphatic acid, aldehyde etc..Typically, odorant pollutant Mostly complex form, each component intensity are relevant with pollutant kind, concentration.Sewage treatment plant's foul smell situation is carried out both at home and abroad big Amount investigation and analysis, the results showed that main odorant pollutant is H2S, NH3 in foul smell, wherein, content is most, concentration is maximum is NH3, it is secondly H2S, methyl sulfide etc.；Determine that people experience degree, methyl mercaptan is maximum, next to that H2S, methyl sulfide and NH3.

Existing sewage disposal device has no effective treatment measures to caused foul gas in running.

The content of the invention

In view of the above-mentioned problems of the prior art, the present invention provides a kind of underground engineering wastewater treatment integrating device, should Device can effectively handle caused foul gas in sewage disposal process, be avoided that and brought because foul gas discharges to environment Pollution and the harm that is brought to people's health.

To achieve these goals, the present invention provides a kind of underground engineering wastewater treatment integrating device, including floor-type support Frame and fixed branch are located at the deodorization agent set inside floor-type support frame, and the deodorization agent set includes deodorization tank and intelligence is controlled Device processed, water inlet, deodorant adding mouth, pressure-reducing valve, temperature-sensing valve, odor unit are disposed with the tank skin of the deodorization tank and is visited Device and delivery port are surveyed, deodorization tank is internally provided with preprocessor, primary nanometer purification membrane, mixes agitator and the purification of two level nanometer Film, wherein water inlet and delivery port are located at the upper and lower part of deodorization tank, primary nanometer purification membrane and two level nanometer purification respectively Film is set respectively close to deodorization tank top and bottomland；The inside of the water inlet and delivery port is equipped with electrically-controlled valve, described to remove Closure is provided with above smelly dose of adding mouth；The preprocessor is fixedly connected in the upper space of primary nanometer purification membrane, in advance The case top of processor and bottom are respectively arranged with inlet and liquid outlet, and the enclosure interior of preprocessor is from top to bottom successively The first dispersion plate, steam ring, the second dispersion plate and supporting plate are fixedly installed, is filled between the second dispersion plate and supporting plate Activated carbon；The inlet is connected by pipeline with water inlet；First dispersion plate, the second dispersion plate and supporting plate spread all over its table Face it is provided with some through holes；The through hole of supporting plate is less than the particle diameter of activated carbon；Steam ring is the annulus line of closure, and it is horizontal Ground is set, and is uniformly provided with several steam jets connected with its inner chamber thereon, is occurred with the high steam of outside Device connection steam enter pipe through deodorization tank tank skin and preprocessor housing after with steam ring through connection；The mixing is stirred Dynamic device includes agitation main shaft, is fixedly installed on the stirring motor on deodorization tank arc top and is securely fitted in the agitation of agitation main shaft bottom Impeller, the top for stirring main shaft extend to the outer surface on deodorization tank arc top and are connected with stirring motor；The agitating vane is located at Between primary nanometer purification membrane and two level nanometer purification membrane；Electrically-controlled valve, stirring motor, pressure-reducing valve, temperature-sensing valve and odor unit are visited Device is surveyed to be connected with intelligent controller polygon control survey respectively.

In the technical scheme, enter back into deodorization tank and can significantly carry after first passing through the processing of preprocessor by making sewage High sewage treating efficiency, the first dispersion plate in preprocessor can make sewage spilling uniformly, gently, steam ring energy Sewage is carried out to be heated rapidly to 30 DEG C~40 DEG C, the pending solution after heating is gently entered activated carbon by the second dispersion plate Layer, activated carbon adsorb to the aerobic microbiological in sewage and organic matter, and are provided with machine thing degraded place for aerobic microbiological；From And the treatment effect to sewage can be effectively improved.The sewage aerobic microorganism treated by preprocessor and organic matter are significantly Reduce, so as to significantly decrease the stink of sewage.The treated sewage of preprocessor enters behind deodorization tank inside by primary The processing of nanometer purification membrane can carry out purified treatment to most sulfur-containing compound in sewage and nitrogen-containing compound, further disappear Except the stink of sewage；Deodorant will be added by mixing agitator again to be sufficiently mixed with pending sewage, can be entered One step reduces the stink of sewage；Added the sewage of deodorant again can be to the sulfur-containing compound of residual by two level nanometer purification membrane And nitrogen-containing compound carries out double purification processing, the water body after processing flows out through delivery port.In deodorisation process, pressure-reducing valve, temperature Control valve and odor unit detector difference the moment monitoring deodorization tank inside pressure, temperature and odor unit situation, when accordingly finger When marking below standard, pressure-reducing valve, temperature-sensing valve and odor unit detector send signal, intelligent controller control to intelligent controller respectively System processed is automatically adjusted to relevant parameter, can further improve treatment effeciency.The device can effectively handle dirt Caused foul gas in water treatment procedure, it is avoided that the pollution brought by foul gas discharge to environment and gives people's body The harm that health care belt comes.

Further, in order to improve treatment effeciency and treatment effect to sewage deodorizing, the preprocessor is also included by the The top of one dispersion plate penetrates the catalyst jet pipe of the inner space of preprocessor and the air supply device outside deodorization tank；Institute State catalyst jet pipe outer end pass the tank skin of deodorization tank after be connected with catalyst tank, the inner end downward bending of catalyst jet pipe is worn Nozzle is equipped with after crossing the first dispersion plate；The K2SO424H2O catalyst of fog-like body can equably be sprayed by catalyst jet pipe Enter and the sewage with disperseing by the first dispersion plate is sufficiently mixed；

The air outlet of the air supply device and one end of airduct are connected, and the other end of airduct is penetrated after deodorization tank by liquid outlet It is deep into the inside of preprocessor housing and through supporting plate inside active carbon layer；The housing sidewall top of preprocessor is set It is equipped with air outlet；

Viable bacteria atomizer is equipped with the side close to air supply device inside the airduct, the viable bacteria atomizer includes water Level land be fixed on the horn cover inside airduct, the surge chamber being fixedly connected on the left of the small openend of horn cover, be fixedly connected on it is slow Rush the motor of room left end and the bacterium solution pump outside horn cover；

The horn cover left end opening diameter is less than right-end openings diameter, during the position of horn cover internal axis line is provided with Pony axle, the left end of hollow axle are extended to inside surge chamber right-hand member and are rotatably coupled by bearing and surge chamber, loudspeaker The internal both ends of cover are each provided with a hollow support ring being fixedly connected by hollow cross with hollow axle, two hollow branch Be provided with the cylindroid hollow tube of multiple circular hollow axles arrangements between pushing out ring, the both ends of cylindroid hollow tube and two it is hollow Support ring insertion ground connection, the hollow pipe surface of cylindroid, which sets group, the bacterium solution shower nozzle largely connected with its inner chamber；

The output shaft of the motor stretches into the inner end of hollow axle and the more connecting rods by radially arranging through surge chamber It is fixedly connected with hollow axle；

The outlet end of the bacterium solution pump is connected by pipeline with the inner chamber of surge chamber, and the liquid feeding end of bacterium solution pump is pre- by passing The extension tube attached of processor and deodorization tank connects with outside bacterium solution culture tank；

Motor and bacterium solution pump are connected with intelligent controller polygon control survey respectively.Air supply device survey by outside fresh air and Aerobic bacteria after the atomization that viable bacteria atomizer provides is transported to activated carbon, to provide oxygen for growth of aerobic microorganisms.

Further, be also associated with for the ease of detecting the treatment effect of different phase, on the housing of the preprocessor with The detection pipe of its inner chamber connection, the outer end of detection pipe are connected with the control being connected with intelligent controller polygon control survey after passing deodorization tank Valve processed.

Further, in order to detect the rotating speed of stirring main shaft, the top of the agitation main shaft is provided with reductor revolution speed sensing Device, reductor speed probe are connected with intelligent controller polygon control survey.

Further, in order to which practical operation is more convenient, the floor-type support frame is welded by transverse channel steels, vertical channel-section steel and reinforcement Connect and assemble, floor-type support frame top is provided with aerial fixed station, and the aerial fixed station is welded and fixed with floor-type support frame, empty Middle fixed station surface is provided with anti-slip tank；Described halfpace one end of ascending a height is welded in the side of aerial fixed station, and the other end is consolidated with screw Due to ground, halfpace side of ascending a height is provided with safety barrier, and the safety barrier is welded and fixed with halfpace of ascending a height, safety barrier height Not less than 1.2m；The deodorization agent set bottom is positioned over floor-type support frame surface, and deodorization agent set waist is through in the air Circular groove among fixed station；The intelligent controller is positioned at halfpace side of ascending a height.

Further, in order to survey raising treatment effect, the inlet is inverted broadening formation structure, and the air outlet is set Put in the oblique side wall of broadening formation；The steam jet quantity is 10~20；The airduct is L-type bend pipe structure；Institute It is the cylinder-like structure with arc closure to state deodorization tank.

Further, it is described to stir in order to obtain the mixing agitator that stirring efficiency is high, has preferable deodorization acceleration capacity Movable vane wheel is matched in parts by weight by following components to be formed：

4- acetoxy-3s-acetoxy-methyl-α-(N- benzyl-N- tert-butylaminos)-acetophenone hydro-chloride 50~270 Part, alpha-brominated 30~240 parts of -4- methoxyacetophenones, the base butyric acid of alpha-cyano -3- phenoxy benzyls 2- (4- chlorphenyls) -3- four 100~300 parts of ester, (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- bis- chloro- 1 (4- ethoxyl phenenyls) cyclopropane-carboxylic acid 60 ~370 parts, 4- benzyloxies-α-{ [2- (4- anisyls) ethyl] amino } 50~260 parts of propiophenone, 2- [(the chloro- 2- nitros of 4- Phenyl) azo] 140~430 parts of-N- (4- ethoxyl phenenyls) -3- oxos butyramide, concentration is 90ppm~130ppm inclined chlorine 30~120 parts of the fluoro- 3- phenoxy groups benzyl esters of chrysanthemumic acid alpha-cyano -4-, (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- bis- chloroethenes Alkenyl) 50~350 parts of cyclopropane-carboxylic acid-a- cyano group -3- phenoxy group -4- fluoro-methylbenzyl esters, [(the chloro- 4- fluoroanilinos of 3-) methylene] third 80~330 parts of diethyl adipate, 70~310 parts of crosslinking agent, 40~130 parts of 4- Trifluoromethoxyphen-ls isocyanates, 4- (3,5- Dimethoxy phenyl) 250~430 parts of -3-butenoic acid ethyl ester, 3,5- 40~70 parts of diaminourea -4- chlorobenzoic acids isobutyl esters, ((4- ammonia The fluoro- 2- pyridines of two chloro- 6- of base -3,5-) epoxide) 140~330 parts of-acetic acid.

Further, in order to obtain the more preferable agitator arm of performance, the crosslinking agent is 2- cyano group -3- phenoxy benzyl -2, 2,3,3- tetramethyl-rings cyclopropanecarboxylic acid ester, 3,4- dichlorophenyl carbamic acids -2- [3- butyl -4- (2,2- dicyanoethenyls) -3- Toluidino] ethyl ester, any one in 2- cyano group -2- (3 '-chloro- 2 '-nitrobenzophenone) tert-butyl acetate.

Further, it is described to stir in order to obtain the mixing agitator that stirring efficiency is high, has preferable deodorization acceleration capacity Movable vane wheel is prepared by following steps：

1st step：300~450 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 1.45 μ S/cm~4.37 is added in a kettle, is opened Agitator in dynamic reactor, rotating speed be 120rpm~230rpm, startup heat pump, make reactor temperature rise to 70 DEG C~ 110℃；Successively plus 4- acetoxy-3s-acetoxy-methyl-α-(N- benzyl-N- tert-butylaminos)-acetophenone hydro-chloride, α- Bromo -4- methoxyacetophenones, the base butyrates of alpha-cyano -3- phenoxy benzyls 2- (4- chlorphenyls) -3- four, stir to completely molten Solution, regulation pH value are 3.1~8.4, agitator speed are adjusted into 120rpm~210rpm, temperature is 110 DEG C~240 DEG C, esterification Reaction 9~17 hours；

2nd step：Take (4- ethoxyl phenenyls) cyclopropane carboxylic acids of (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- two chloro- 1 Acid, 4- benzyloxies-α-{ [2- (4- anisyls) ethyl] amino } propiophenone are crushed, and powder diameter is 30~70 mesh；Add 2- [(the chloro- 2- nitrobenzophenones of 4-) azo]-N- (4- ethoxyl phenenyls) -3- oxos butyramide 1 is well mixed, is laid in pallet Interior, tiling thickness is 20mm~60mm, uses the alpha ray that dosage is 3.2MeV~5.7MeV for 3.0kGy~8.3kGy, energy Irradiation 22~46 minutes, and the β x ray irradiation xs 94~131 minutes of Isodose；

3rd step：The mixed-powder handled through the 2nd step is dissolved in the inclined fluoro- 3- phenoxy groups benzyl esters of chlorine chrysanthemumic acid alpha-cyano -4-, is added Enter reactor, agitator speed is 70rpm~520rpm, and temperature is 120 DEG C~260 DEG C, and starting vavuum pump makes the true of reactor Reciprocal of duty cycle reaches -0.20MPa~-0.50MPa, keeps this state response 3~14 hours；Pressure release is simultaneously passed through nitrogen, makes in reactor Pressure is 1.15MPa~5.55MPa, and insulation stands 3~10 hours；Agitator speed is promoted to 70rpm~200rpm, while instead Kettle pressure release is answered to 0MPa；Sequentially add (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane carboxylic acid After acid-a- cyano group -3- phenoxy group -4- fluoro-methylbenzyl esters, [(the chloro- 4- fluoroanilinos of 3-) methylene] diethyl malonate are completely dissolved, Add crosslinking agent to be stirred so that the hydrophilic lipophilic balance of reactor solution is 2.0~7.0, and it is small that insulation stands 8~16 When；

4th step：When agitator speed is 52rpm~240rpm, sequentially add 4- Trifluoromethoxyphen-ls isocyanates, 4- (3,5- dimethoxy phenyls) -3-butenoic acid ethyl ester, 3,5- diaminourea -4- chlorobenzoic acids isobutyl ester, ((4- amino -3,5- two The chloro- fluoro- 2- pyridines of 6-) epoxide)-acetic acid, reactor pressure is lifted, reaches 4.20MPa~7.50MPa, temperature is 110 DEG C ~250 DEG C, polymerisation 5~15 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to 20 DEG C~30 DEG C, Discharging, enters molding press and can be prepared by agitating vane.

A kind of operating method of underground engineering wastewater treatment integrating device, comprises the following steps：

1st step：The electrically-controlled valve opened inside water inlet is controlled by intelligent controller, makes water with 13m3/h~37m3/h's Flow velocity enters preprocessor；First dispersion plate makes sewage uniformly, gently fall into the middle part of preprocessor, meanwhile, catalyst jet pipe The catalyst of fog-like body is equably sprayed in the middle part of preprocessor, steam ring by external high pressure steam spray to whereabouts sewage and The mixed liquor of catalyst, rapidly to be heated to the mixed liquor of sewage and catalyst；After the guiding of second dispersion plate is heated Mixed liquor through uniformly, gently enter preprocessor bottom；Activated carbon is inhaled to the aerobic microbiological in mixed liquor and organic matter It is attached, and it is provided with machine thing degraded place for aerobic microbiological；Air supply device work passes through airduct by the fresh air of outside and work Aerobic bacteria after the atomization that bacterium atomizer provides is transported to active carbon layer, to provide oxygen for growth of aerobic microorganisms；After processing Sewage by liquid outlet discharge；

2nd step：Sewage after preprocessor is handled enters in deodorization tank, and sewage rate in deodorization tank firstly flows through primary Nanometer purification membrane, primary nanometer purification membrane carry out purified treatment to most sulfur-containing compound in sewage and nitrogen-containing compound；

3rd step：The closure above deodorant adding mouth is opened, quantitative deodorant, while intelligence are launched into sewage Controller control starts motor, and stirring motor drives agitating vane to carry out uniform speed rotation, increases the odor removal efficient of deodorant, In the process, the rotating speed size of reductor speed probe moment monitoring agitating vane；

4th step：Sewage through deodorant deodorization it is backward under continue to flow through two level nanometer purification membrane, two level nanometer purification membrane is to dirt The sulfur-containing compound and nitrogen-containing compound remained in water carries out double purification processing, and the water body after processing flows out through delivery port；

5th step：In deodorisation process, in pressure-reducing valve, temperature-sensing valve and odor unit detector difference moment monitoring deodorization tank Pressure, temperature and the odor unit situation in portion, when corresponding index is below standard, pressure-reducing valve, temperature-sensing valve and odor unit detector Signal is sent to intelligent controller respectively, intelligent controller control system is automatically adjusted to relevant parameter.

The operating method can effectively improve the eradicating efficacy to foul gas in sewage, be avoided that because foul gas discharges And the pollution brought to environment and the harm brought to people's health.

Brief description of the drawings

Fig. 1 is the structural representation in the present invention；

Fig. 2 is the structural representation of deodorization agent set in the present invention；

Fig. 3 is the structural representation that agitator is mixed in the present invention；

Fig. 4 is the structural representation of preprocessor in the present invention；

Fig. 5 is the structural representation of viable bacteria atomizer in the present invention；

Fig. 6 is agitating vane material and the curve map of deodorizing capability enhancing rate in the present invention.

In figure：1st, floor stand supports, and 2, aerial fixed station, 3, anti-slip tank, 4, halfpace of ascending a height, 5, safety barrier, 6, deodorization Agent set, 6-1, deodorization tank, 6-2, water inlet, 6-3, agitator is mixed, 6-3-1, stirring motor, 6-3-2, stirs main shaft, 6-3-3, agitating vane, 6-3-4, reductor speed probe, 6-4, primary nanometer purification membrane, 6-5, two level nanometer purification membrane, 6-6, deodorant adding mouth, 6-7, pressure-reducing valve, 6-8, temperature-sensing valve, 6-9, odor unit detector, 6-10, delivery port are 6-11, pre- Processor, 6-11-1, inlet, 6-11-2, the first dispersion plate, 6-11-3, steam ring, 6-11-4, activated carbon, 6-11-5, hold Supporting plate, 6-11-6, liquid outlet, 6-11-7, airduct, 6-11-8, air supply device, 6-11-9, steam enter pipe, 6-11-10, detection Pipe, 6-11-11, catalyst jet pipe, 6-11-12, viable bacteria atomizer, 6-11-12-1, motor, 6-11-12-2, surge chamber, 6- 11-12-3, hollow axle, 6-11-12-4, cylindroid hollow tube, 6-11-12-5, bacterium solution shower nozzle, 6-11-12-6, middle maltese cross Frame, 6-11-12-7, hollow support ring, 6-11-12-8, horn cover, 6-11-12-9, bacterium solution pump, 6-11-12-10, extension tube attached, 6-11-13, air outlet, 6-11-14, the second dispersion plate, 7, intelligent controller.

Embodiment

The invention will be further described below.

As depicted in figs. 1 and 2, a kind of underground engineering wastewater treatment integrating device, including floor-type support frame 1 and fixation install Deodorization agent set 6 inside floor-type support frame 1, the deodorization agent set 6 include deodorization tank 6-1 and intelligent controller 7, Be disposed with the tank skin of the deodorization tank 6-1 water inlet 6-2, deodorant adding mouth 6-6, pressure-reducing valve 6-7, temperature-sensing valve 6-8, Odor unit detector 6-9 and delivery port 6-10, deodorization tank 6-1 are internally provided with preprocessor 6-11, primary nanometer purification membrane 6-4, mixing agitator 6-3 and two level nanometer purification membrane 6-5, wherein water inlet 6-2 and delivery port 6-10 are located at deodorization tank respectively 6-1 upper and lower part, primary nanometer purification membrane 6-4 and two level nanometer purification membrane 6-5 are respectively close at the top of deodorization tank 6-1 and bottom Set to portion；Primary nanometer purification membrane 6-4 and two level nanometer purification membrane 6-5 are made by nano material；The water inlet 6-2 and Delivery port 6-10 inside is equipped with electrically-controlled valve, and closure is provided with above the deodorant adding mouth 6-6；

As shown in figure 4, the preprocessor 6-11 is fixedly connected in primary nanometer purification membrane 6-4 upper space, in advance Processor 6-11 case top and bottom are respectively arranged with inlet 6-11-1 and liquid outlet 6-11-6, and liquid outlet 6-11-6 will In solution injection deodorization agent set 6 after processing；Preprocessor 6-11 enclosure interior is fixedly installed successively from top to bottom First dispersion plate 6-11-2, steam ring 6-11-3, the second dispersion plate 6-11-14 and supporting plate 6-11-5, in the second dispersion plate 6- Activated carbon 6-11-4 is filled between 11-14 and supporting plate 6-11-5；The inlet 6-11-1 passes through pipeline and water inlet 6-2 Connection；First dispersion plate 6-11-2, the second dispersion plate 6-11-14 and supporting plate 6-11-5 spread all over its be outwardly provided with it is some Through hole；Supporting plate 6-11-5 through hole is less than activated carbon 6-11-4 particle diameter；First dispersion plate 6-11-2 and the second dispersion plate 6- 11-14 be used for pending solution buffering, make pending solution uniformly, gently enter next procedure；Activated carbon 6-11-4 inhales Attached aerobic microbiological and organic matter, and it is provided with machine thing degraded place for aerobic microbiological；Supporting plate 6-11-5 can prevent activity Charcoal falls, is lost in；

Steam ring 6-11-3 is the annulus line of closure, and it is flatly set, and is uniformly provided with several thereon Enter pipe 6-11-9 with the steam that the high pressure steam generator of outside connects with the steam jet that its inner chamber connects and pass through deodorization tank 6-1 Tank skin and preprocessor 6-11 housing after with steam ring 6-11-3 through connections；Steam ring 6-11-3 is mainly used in wait to locate Manage solution and heat 30 DEG C~40 DEG C；

As shown in figure 3, the mixing agitator 6-3 includes agitation main shaft 6-3-2, is fixedly installed on deodorization tank 6-1 arcs top Stirring motor 6-3-1 and be securely fitted in the agitating vane 6-3-3 of agitation main shaft 6-3-2 bottoms, agitation main shaft 6-3-2's is upper Portion extends to the outer surface on deodorization tank 6-1 arcs top and is connected with stirring motor 6-3-1；Primary nanometer purification membrane 6-4 stirs corresponding Dynamic main shaft 6-3-2 position is reserved with the through hole passed through for agitation main shaft 6-3-2, and the agitating vane 6-3-3 receives positioned at primary Between rice purification membrane 6-4 and two level nanometer purification membrane 6-5；Agitating vane 6-3-3 is interference fitted with agitation main shaft 6-3-2；In order to Enable the weight of primary nanometer purification membrane 6-4 and two level nanometer purification membrane 6-5 carrying residual waters, in primary nanometer purification membrane 6-4 The support framework being fixedly connected with deodorization tank 6-1 inwalls is provided with two level nanometer purification membrane 6-5 lower surfaces.

Electrically-controlled valve, stirring motor 6-3-1, pressure-reducing valve 6-7, temperature-sensing valve 6-8 and odor unit detector 6-9 respectively with intelligence The polygon control survey of controller 7 connects.

As shown in figure 4, the preprocessor 6-11 also includes penetrating preprocessor by the first dispersion plate 6-11-2 top The catalyst jet pipe 6-11-11 of the 6-11 inner space and air supply device 6-11-8 outside deodorization tank 6-1；The catalysis Agent jet pipe 6-11-11 outer end is connected after passing deodorization tank 6-1 tank skin with catalyst tank, in catalyst jet pipe 6-11-11 End downward bending is equipped with nozzle after passing through the first dispersion plate 6-11-2；K is housed in catalyst tank₂SO₄·24H₂O；Nozzle is used for Catalyst is equably sprayed inside preprocessor 6-11 with fog-like body；

The air outlet of the air supply device 6-11-8 is connected with airduct 6-11-7 one end, and the airduct 6-11-7 other end is worn The inside of preprocessor 6-11 housings is entered by liquid outlet 6-11-6 after entering deodorization tank 6-1 and is deep into through supporting plate 6-11-5 Inside activated carbon 6-11-4 layers；The fresh air conveying of outside is aerobic micro- life to activated carbon 6-11-4 layers by airduct 6-11-7 Thing growth provides oxygen；Preprocessor 6-11 housing sidewall top is provided with air outlet 6-11-13；

As shown in figure 5, it is being equipped with viable bacteria atomization close to air supply device 6-11-8 side inside the airduct 6-11-7 Device 6-11-12, the viable bacteria atomizer 6-11-12 include being horizontally fixed on the horn cover 6-11-12- inside airduct 6-11-7 8th, it is fixedly connected on the surge chamber 6-11-12-2 on the left of the small openends of horn cover 6-11-12-8, is fixedly connected on surge chamber 6- The motor 6-11-12-1 of the 11-12-2 left ends and bacterium solution pump 6-11-12-9 outside horn cover 6-11-12-8；Surge chamber 6- 11-12-2 is hollow columnar structures；Bacterium solution pump 6-11-12-9 is located at horn cover 6-11-12-8 left hand externals, and is located at motor 6-11-12-1 lower section.Bacterium solution pump 6-11-12-9 forms vaporific ejection by bacterium solution shower nozzle 6-11-12-5 for aerobic bacteria and provided Power.

The horn cover 6-11-12-8 penetrates in round table-like and both ends open, and its left end opening diameter is less than right-end openings Diameter, the position of horn cover 6-11-12-8 internal axis lines are provided with hollow axle 6-11-12-3, hollow axle 6-11-12-3 Left end extend to inside surge chamber 6-11-12-2 right-hand members and be rotatably coupled by bearing and surge chamber 6-11-12-2, loudspeaker Cover 6-11-12-8 inside both ends are each provided with one and consolidated by hollow cross 6-11-12-6 and hollow axle 6-11-12-3 Surely the hollow support ring 6-11-12-7 connected, two hollow support ring 6-11-12-7 size adapt to horn cover 6- respectively The internal diameter at 11-12-8 both ends, to ensure to rotate in inside horn cover 6-11-12-8 around hollow axle 6-11-12-3；Two The cylindroid hollow tube 6- of multiple circular hollow axle 6-11-12-3 arrangements is provided between individual hollow support ring 6-11-12-7 11-12-4, multiple cylindroid hollow tube 6-11-12-4 equably arrange around horn cover 6-11-12-8 axial line, cylindroid Hollow tube 6-11-12-4 both ends are connected with penetrating with two hollow support ring 6-11-12-7, cylindroid hollow tube 6-11-12- 4 surfaces, which set group, the bacterium solution shower nozzle 6-11-12-5 largely connected with its inner chamber；Bacterium solution shower nozzle 6-11-12-5 is used for aerobic bacteria Nebulize ejection.

The output shaft of the motor 6-11-12-1 is stretched into hollow axle 6-11-12-3 through surge chamber 6-11-12-2 Hold and the more connecting rods by radially arranging are fixedly connected with hollow axle 6-11-12-3；Motor 6-11-12-1 power line Electrically connected through airduct 6-11-7 with outside city；Motor 6-11-12-1 drives hollow cross by hollow axle 6-11-12-3 6-11-12-6 and cylindroid hollow tube 6-11-12-4 are rotated in horn cover 6-11-12-8；Surge chamber 6-11-12-2 with it is hollow Rotating shaft 6-11-12-3 is connected, and hollow axle 6-11-12-3 passes through hollow cross 6-11-12-6 and cylindroid hollow tube 6-11- 12-4 is connected；

The outlet end of the bacterium solution pump 6-11-12-9 is connected by pipeline with surge chamber 6-11-12-2 inner chamber, bacterium solution pump 6-11-12-9 liquid feeding end passes through the extension tube attached 6-11-12-10 for passing preprocessor 6-11 and deodorization tank 6-1 and outside bacterium solution Culture tank connects；Viable bacteria atomizer 6-11-12 by air supply device 6-11-8 is delivered to activated carbon 6-11-4 after aerobic bacteria is atomized Layer is internal.

Motor 6-11-12-1 and bacterium solution pump 6-11-12-9 are connected with the polygon control survey of intelligent controller 7 respectively.

The detection pipe 6-11-10, detection pipe 6- connected with its inner chamber is also associated with the housing of the preprocessor 6-11 11-10 outer end is connected with the control valve being connected with the polygon control survey of intelligent controller 7, detection pipe 6-11- after passing deodorization tank 6-1 10 can easily obtain detection solution.

The top of the agitation main shaft 6-3-2 is provided with reductor speed probe 6-3-4, reductor speed probe 6- 3-4 is connected with the polygon control survey of intelligent controller 7.

The floor-type support frame 1 is formed by transverse channel steels, vertical channel-section steel and reinforcement welding assembly, on floor-type support frame 1 Portion is provided with aerial fixed station 2, and the aerial fixed station 2 is welded and fixed with floor-type support frame 1, and the aerial surface of fixed station 2 is provided with anti- Chute 3；Described one end of halfpace 4 of ascending a height is welded in the side of aerial fixed station 2, and the other end is screwed in ground, step ladder The side of platform 4 is provided with safety barrier 5, and the safety barrier 5 is welded and fixed with halfpace 4 of ascending a height, and the height of safety barrier 5 is not less than 1.2m；The bottom of deodorization agent set 6 is positioned over the surface of floor-type support frame 1, and the waist of deodorization agent set 6 is fixed through aerial Circular groove among platform 2；The intelligent controller 7 is positioned at the side of halfpace 4 of ascending a height.

The inlet 6-11-1 is inverted broadening formation structure, and the air outlet 6-11-13 is arranged on broadening formation Oblique side wall on；The steam jet quantity is 10~20；The airduct 6-11-7 is L-type bend pipe structure；The deodorization Tank 6-1 is the cylinder-like structure with arc closure.

Sewage treating efficiency can be significantly improved in deodorization tank by making sewage first pass through to enter back into after the processing of preprocessor, The first dispersion plate in preprocessor can make sewage uniformly, spilling gently, and catalyst jet pipe can be by fog-like body K2SO424H2O catalyst equably spray into and with by the first dispersion plate disperse sewage sufficiently mixed, steam Ring sprays to external high pressure steam in the sewage of whereabouts and the mixed liquor of catalyst, is promoting being sufficiently mixed for sewage and catalyst On the basis of, moreover it is possible to mixed liquor be heated rapidly to 30 DEG C~40 DEG C, the second dispersion plate is by the pending solution after heating Gentle to enter active carbon layer, activated carbon adsorbs to the aerobic microbiological in mixed liquor and organic matter, and is provided for aerobic microbiological Organic matter degradation place；Aerobic bacteria after the atomization that air supply device provides the fresh air of outside and viable bacteria atomizer is transported to Activated carbon, survey and provide oxygen for growth of aerobic microorganisms, the treatment effect to sewage can be effectively improved.Handled by preprocessor The sewage aerobic microorganism crossed and organic matter are greatly reduced, so as to significantly decrease the stink of sewage.Preprocessor processing The processing that the sewage crossed enters behind deodorization tank inside by primary nanometer purification membrane can be to most sulfur-containing compound in sewage And nitrogen-containing compound carries out purified treatment, the stink of sewage is further obviated；Again deodorization will be added by mixing agitator Agent is sufficiently mixed with pending sewage, can further reduce the stink of sewage；The sewage of deodorant was added to pass through two again Level nanometer purification membrane can carry out double purification processing to the sulfur-containing compound and nitrogen-containing compound of residual, the water body warp after processing Delivery port flows out.In deodorisation process, inside pressure-reducing valve, temperature-sensing valve and odor unit detector difference moment monitoring deodorization tank Pressure, temperature and odor unit situation, when corresponding index is below standard, pressure-reducing valve, temperature-sensing valve and odor unit detector difference Signal is sent to intelligent controller, intelligent controller control system is automatically adjusted to relevant parameter, can be further Improve treatment effeciency.The device can effectively handle caused foul gas in sewage disposal process, be avoided that because of foul gas Discharge and the pollution brought to environment and the harm brought to people's health.

In order to obtain stirring efficiency height, the mixing agitator with preferable deodorization acceleration capacity, the agitating vane 6-3-3 is matched and formed in parts by weight by following components：

In order to obtain the more preferable agitator arm 6-3-3 of performance, the crosslinking agent is 2- cyano group -3- phenoxy benzyls -2,2, 3,3- tetramethyl-rings cyclopropanecarboxylic acid ester, 3,4- dichlorophenyl carbamic acids -2- [3- butyl -4- (2,2- dicyanoethenyls) -3- first Phenylamino] ethyl ester, any one in 2- cyano group -2- (3 '-chloro- 2 '-nitrobenzophenone) tert-butyl acetate.

In order to obtain stirring efficiency height, the mixing agitator with preferable deodorization acceleration capacity, the agitating vane 6-3-3 is prepared by following steps：

4th step：When agitator speed is 52rpm~240rpm, sequentially add 4- Trifluoromethoxyphen-ls isocyanates, 4- (3,5- dimethoxy phenyls) -3-butenoic acid ethyl ester, 3,5- diaminourea -4- chlorobenzoic acids isobutyl ester, ((4- amino -3,5- two The chloro- fluoro- 2- pyridines of 6-) epoxide)-acetic acid, reactor pressure is lifted, reaches 4.20MPa~7.50MPa, temperature is 110 DEG C ~250 DEG C, polymerisation 5~15 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to 20 DEG C~30 DEG C, Discharging, enters molding press and can be prepared by agitating vane 6-3-3.

1st step：The electrically-controlled valve opened inside water inlet 6-2 is controlled by intelligent controller 7, make water with 13m3/h~ 37m3/h flow velocity enters preprocessor 6-11；First dispersion plate 6-11-2 make sewage uniformly, gently fall into preprocessor 6- 11 middle parts, meanwhile, the catalyst of fog-like body is equably sprayed in the middle part of preprocessor 6-11 by catalyst jet pipe 6-11-11, is steamed Vapour ring 6-11-3 sprays to external high pressure steam in the sewage of whereabouts and the mixed liquor of catalyst, with rapidly to sewage and catalyst Mixed liquor heated；Second dispersion plate 6-11-14 guiding be heated after mixed liquor through uniformly, gently enter pretreatment Device 6-11 bottoms；Activated carbon 6-11-4 adsorbs to the aerobic microbiological in mixed liquor and organic matter, and is provided for aerobic microbiological Organic matter degradation place；Air supply device work passes through airduct 6-11-7 by the fresh air and viable bacteria atomizer 6-11-12 of outside Aerobic bacteria after the atomization of offer is transported to activated carbon 6-11-4 layers, to provide oxygen for growth of aerobic microorganisms；After processing Sewage is discharged by liquid outlet 6-11-6；

2nd step：Sewage after preprocessor 6-11 processing enters in deodorization tank 6-1, sewage rate in deodorization tank 6-1 Primary nanometer purification membrane 6- is firstly flowed through through 4, primary nanometer purification membrane 6-4 is to most sulfur-containing compound and nitrogen in sewage Compound carries out purified treatment；

3rd step：The closure above deodorant adding mouth 6-6 is opened, quantitative deodorant, while intelligence are launched into sewage The energy control of controller 7 starts motor 6-3-1, and stirring motor 6-3-1 drives agitating vane 6-3-3 to carry out uniform speed rotation, increasing Add the odor removal efficient of deodorant, in the process, the reductor speed probe 6-3-4 moment monitors turning for agitating vane 6-3-3 Fast size；

4th step：Sewage through deodorant deodorization it is backward under continue to flow through two level nanometer purification membrane 6-5, two level nanometer purification membrane 6-5 carries out double purification processing to the sulfur-containing compound and nitrogen-containing compound that are remained in sewage, and the water body after processing is through delivery port 6-10 flows out；

5th step：In deodorisation process, pressure-reducing valve 6-7, temperature-sensing valve 6-8 and odor unit detector 6-9 difference moment monitoring Pressure, temperature and odor unit situation inside deodorization tank 6-1, when corresponding index is below standard, pressure-reducing valve 6-7, temperature-sensing valve 6-8 And odor unit detector 6-9 sends signal to intelligent controller 7 respectively, the control system of intelligent controller 7 is entered to relevant parameter Row automatically adjusts.

A kind of underground engineering wastewater treatment integrating device novel and reasonable structure of the present invention, odor removal efficient is high, is applicable Wide scope.

It is the embodiment of agitating vane 6-3-3 of the present invention manufacturing process below, embodiment is in order to furtherly Bright present disclosure, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, it is right The modification and replacement that the inventive method, step or condition are made, belong to the scope of the present invention.

Unless otherwise specified, the conventional meanses that technological means used in embodiment is well known to those skilled in the art.

Embodiment 1

Agitating vane 6-3-3 of the present invention, and fraction meter by weight are manufactured according to following steps：

1st step：300 parts of the ultra-pure water that electrical conductivity is 1.45 μ S/cm is added in a kettle, is started in reactor and is stirred Device, rotating speed 120rpm, start heat pump, reactor temperature is risen to 70 DEG C；Successively plus 4- acetoxy-3s-acetyl oxygen Ylmethyl-α-(N- benzyl-N- tert-butylaminos) 50 parts of-acetophenone hydro-chloride, 30 parts of alpha-brominated -4- methoxyacetophenones, α - 100 parts of four base butyrates of cyano group -3- phenoxy benzyls 2- (4- chlorphenyls) -3-, to being completely dissolved, regulation pH value is 3.1 for stirring, Agitator speed is adjusted to 120rpm, temperature is 110 DEG C, esterification 9 hours；

2nd step：Take (4- ethoxyl phenenyls) cyclopropane carboxylic acids of (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- two chloro- 1 60 parts of acid, 4- benzyloxies-α-{ [2- (4- anisyls) ethyl] amino } 50 parts of propiophenone are crushed, powder diameter 30 Mesh；Add 140 parts of 2- [(the chloro- 2- nitrobenzophenones of 4-) azo]-N- (4- ethoxyl phenenyls) -3- oxos butyramide well mixed, put down It is laid in pallet, tiling thickness is 20mm, and the alpha ray for using dosage to be 3.2MeV for 3.0kGy, energy irradiates 22 minutes, and The β x ray irradiation xs of Isodose 94 minutes；

3rd step：The mixed-powder handled through the 2nd step is dissolved in the inclined fluoro- 3- benzene of chlorine chrysanthemumic acid alpha-cyano -4- that concentration is 90ppm In 30 parts of epoxide benzyl ester, reactor, agitator speed 70rpm are added, temperature is 120 DEG C, and starting vavuum pump makes reactor Vacuum reaches -0.20MPa, keeps this state response 3 hours；Pressure release is simultaneously passed through nitrogen, makes the reacting kettle inner pressure be 1.15MPa, insulation stand 3 hours；Agitator speed is promoted to 70rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane-carboxylic acid-a- cyano group -3- phenoxy group -4- fluoro-methylbenzyl esters 50 After part, [(the chloro- 4- fluoroanilinos of 3-) methylene] 80 parts of diethyl malonate are completely dissolved, it is mixed to add 70 parts of stirrings of crosslinking agent Close so that the hydrophilic lipophilic balance of reactor solution is 2.0, and insulation stands 8 hours；

4th step：When agitator speed is 52rpm, 40 parts of 4- Trifluoromethoxyphen-ls isocyanates, 4- are sequentially added 250 parts of (3,5- dimethoxy phenyls) -3-butenoic acid ethyl ester, 40 parts of 3,5- diaminourea -4- chlorobenzoic acids isobutyl ester, ((4- amino - 3, the 5- bis- chloro- fluoro- 2- pyridines of 6-) epoxide) 140 parts of-acetic acid, reactor pressure is lifted, reaches 4.20MPa, temperature 110 DEG C, polymerisation 5 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 20 DEG C is cooled to, discharging, enters molding press i.e. Agitating vane 6-3-3 can be made；

The crosslinking agent is 2- cyano group -3- phenoxy benzyl -2,2,3,3- tetramethyl-ring cyclopropanecarboxylic acid esters.

Embodiment 2

1st step：450 parts of the ultra-pure water that electrical conductivity is 4.37 μ S/cm is added in a kettle, is started in reactor and is stirred Device, rotating speed 230rpm, start heat pump, reactor temperature is risen to 110 DEG C；Successively plus 4- acetoxy-3s-acetyl Epoxide methyl-α-(N- benzyl-N- tert-butylaminos) 270 parts of-acetophenone hydro-chloride, alpha-brominated -4- methoxyacetophenones 240 Part, 300 parts of four base butyrates of alpha-cyano -3- phenoxy benzyls 2- (4- chlorphenyls) -3-, stirring adjust pH value to being completely dissolved For 8.4, agitator speed is adjusted to 210rpm, temperature is 240 DEG C, esterification 17 hours；

2nd step：Take (4- ethoxyl phenenyls) cyclopropane carboxylic acids of (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- two chloro- 1 370 parts of acid, 4- benzyloxies-α-{ [2- (4- anisyls) ethyl] amino } 260 parts of propiophenone are crushed, powder diameter 70 Mesh；Add 430 parts of 2- [(the chloro- 2- nitrobenzophenones of 4-) azo]-N- (4- ethoxyl phenenyls) -3- oxos butyramide well mixed, put down It is laid in pallet, tiling thickness is 60mm, and the alpha ray for using dosage to be 5.7MeV for 8.3kGy, energy irradiates 46 minutes, and The β x ray irradiation xs of Isodose 131 minutes；

3rd step：The mixed-powder handled through the 2nd step is dissolved in the inclined fluoro- 3- benzene of chlorine chrysanthemumic acid alpha-cyano -4- that concentration is 130ppm In 120 parts of epoxide benzyl ester, reactor, agitator speed 520rpm are added, temperature is 260 DEG C, and starting vavuum pump makes reactor Vacuum reach -0.50MPa, keep this state response 14 hours；Pressure release is simultaneously passed through nitrogen, makes the reacting kettle inner pressure be 5.55MPa, insulation stand 10 hours；Agitator speed is promoted to 200rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane-carboxylic acid-a- cyano group -3- phenoxy group -4- fluorine benzyls After 350 parts of ester, [(the chloro- 4- fluoroanilinos of 3-) methylene] 330 parts of diethyl malonate are completely dissolved, 310 parts of crosslinking agent is added It is stirred so that the hydrophilic lipophilic balance of reactor solution is 7.0, and insulation stands 16 hours；

4th step：When agitator speed is 240rpm, 130 parts of 4- Trifluoromethoxyphen-ls isocyanates, 4- are sequentially added 430 parts of (3,5- dimethoxy phenyls) -3-butenoic acid ethyl ester, 70 parts of 3,5- diaminourea -4- chlorobenzoic acids isobutyl ester, ((4- amino - 3, the 5- bis- chloro- fluoro- 2- pyridines of 6-) epoxide) 330 parts of-acetic acid, reactor pressure is lifted, reaches 7.50MPa, temperature 250 DEG C, polymerisation 15 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 30 DEG C is cooled to, discharging, enters molding press i.e. Agitating vane 6-3-3 can be made；

The crosslinking agent is 2- cyano group -2- (3 '-chloro- 2 '-nitrobenzophenone) tert-butyl acetate.

Embodiment 3

1st step：350 parts of the ultra-pure water that electrical conductivity is 2.37 μ S/cm is added in a kettle, is started in reactor and is stirred Device, rotating speed 170rpm, start heat pump, reactor temperature is risen to 90 DEG C；Successively plus 4- acetoxy-3s-acetyl oxygen Ylmethyl-α-(N- benzyl-N- tert-butylaminos) 130 parts of-acetophenone hydro-chloride, 140 parts of alpha-brominated -4- methoxyacetophenones, 200 parts of four base butyrates of alpha-cyano -3- phenoxy benzyls 2- (4- chlorphenyls) -3-, to being completely dissolved, adjusting pH value is for stirring 6.4, agitator speed is adjusted to 170rpm, temperature is 140 DEG C, esterification 12 hours；

2nd step：Take (4- ethoxyl phenenyls) cyclopropane carboxylic acids of (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- two chloro- 1 170 parts of acid, 4- benzyloxies-α-{ [2- (4- anisyls) ethyl] amino } 160 parts of propiophenone are crushed, powder diameter 50 Mesh；Add 230 parts of 2- [(the chloro- 2- nitrobenzophenones of 4-) azo]-N- (4- ethoxyl phenenyls) -3- oxos butyramide well mixed, put down It is laid in pallet, tiling thickness is 30mm, and the alpha ray for using dosage to be 4.7MeV for 4.3kGy, energy irradiates 36 minutes, and The β x ray irradiation xs of Isodose 101 minutes；

3rd step：The mixed-powder handled through the 2nd step is dissolved in the inclined fluoro- 3- benzene of chlorine chrysanthemumic acid alpha-cyano -4- that concentration is 110ppm In 70 parts of epoxide benzyl ester, reactor, agitator speed 320rpm are added, temperature is 160 DEG C, and starting vavuum pump makes reactor Vacuum reaches -0.40MPa, keeps this state response 11 hours；Pressure release is simultaneously passed through nitrogen, makes the reacting kettle inner pressure be 3.55MPa, insulation stand 7.2 hours；Agitator speed is promoted to 100rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane-carboxylic acid-a- cyano group -3- phenoxy group -4- fluorine benzyls After 250 parts of ester, [(the chloro- 4- fluoroanilinos of 3-) methylene] 230 parts of diethyl malonate are completely dissolved, 210 parts of crosslinking agent is added It is stirred so that the hydrophilic lipophilic balance of reactor solution is 5.0, and insulation stands 11 hours；

4th step：When agitator speed is 140rpm, 110 parts of 4- Trifluoromethoxyphen-ls isocyanates, 4- are sequentially added 330 parts of (3,5- dimethoxy phenyls) -3-butenoic acid ethyl ester, 50 parts of 3,5- diaminourea -4- chlorobenzoic acids isobutyl ester, ((4- amino - 3, the 5- bis- chloro- fluoro- 2- pyridines of 6-) epoxide) 230 parts of-acetic acid, reactor pressure is lifted, reaches 6.50MPa, temperature 150 DEG C, polymerisation 10 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 25 DEG C is cooled to, discharging, enters molding press i.e. Agitating vane 6-3-3 can be made；

The crosslinking agent is 3,4- dichlorophenyl carbamic acids -2- [3- butyl -4- (2,2- dicyanoethenyls) -3- first Phenylamino] ethyl ester.Reference examples

Reference examples are used for the service condition of municipal sewage deodorisation process for the agitating vane of certain commercially available brand.

Embodiment 4

The agitating vane described in agitating vane 6-3-3 and reference examples that embodiment 1~3 is prepared is used for municipal sewage The service condition of deodorisation process is contrasted, and is lifted with mixing speed enhancing rate, deodorization acceleration capacity enhancing rate, damping performance Rate, spiral disturbance capability improving rate are that technical indicator is counted, as a result as shown in table 1：

Table 1:Agitating vane described in embodiment 1~3 and reference examples is used for the service condition of municipal sewage deodorisation process The contrast of parameters

Table 1 is used for the service condition of municipal sewage deodorisation process for the agitating vane described in embodiment 1~3 and reference examples The comparing result of parameters, as seen from Table 1, agitating vane 6-3-3 of the present invention, it mixes speed enhancing rate, deodorization Acceleration capacity enhancing rate, damping performance enhancing rate, spiral disturbance capability improving rate are above the product of prior art production.

In addition, as shown in fig. 6, it is agitating vane 6-3-3 materials of the present invention and deodorizing capability enhancing rate graph of a relation. Find out in figure, agitating vane 6-3-3 materials are evenly distributed used in embodiment 1~3, and deodoriging properties are high；Institute of the present invention is shown in figure The agitating vane 6-3-3 stated, its deodorizing capability enhancing rate are significantly better than existing product.

Claims

1. a kind of underground engineering wastewater treatment integrating device, including floor-type support frame (1) and fixed branch are located at floor-type support frame (1) Internal deodorization agent set (6), it is characterised in that the deodorization agent set (6) includes deodorization tank (6-1) and intelligent control Device (7), water inlet (6-2), deodorant adding mouth (6-6), pressure-reducing valve are disposed with the tank skin of the deodorization tank (6-1) (6-7), temperature-sensing valve (6-8), odor unit detector (6-9) and delivery port (6-10), deodorization tank (6-1) are internally provided with pre- place Manage device (6-11), primary nanometer purification membrane (6-4), mix agitator (6-3) and two level nanometer purification membrane (6-5), wherein intaking Mouth (6-2) and delivery port (6-10) are located at the upper and lower part of deodorization tank (6-1), primary nanometer purification membrane (6-4) and two respectively Level nanometer purification membrane (6-5) is set respectively close to ground at the top and bottom of deodorization tank (6-1)；The water inlet (6-2) and delivery port The inside of (6-10) is equipped with electrically-controlled valve, and closure is provided with above the deodorant adding mouth (6-6)；

The preprocessor (6-11) is fixedly connected in the upper space of primary nanometer purification membrane (6-4), preprocessor (6- 11) case top and bottom is respectively arranged with inlet (6-11-1) and liquid outlet (6-11-6), preprocessor (6-11) Enclosure interior is fixedly installed the first dispersion plate (6-11-2), steam ring (6-11-3), the second dispersion plate (6- successively from top to bottom 11-14) with supporting plate (6-11-5), activated carbon is filled between the second dispersion plate (6-11-14) and supporting plate (6-11-5) (6-11-4)；The inlet (6-11-1) is connected by pipeline with water inlet (6-2)；First dispersion plate (6-11-2), second Dispersion plate (6-11-14) and supporting plate (6-11-5) spread all over it and are outwardly provided with some through holes；Supporting plate (6-11-5) Through hole is less than the particle diameter of activated carbon (6-11-4)；

Steam ring (6-11-3) for closure annulus line, it is flatly set, be uniformly provided with thereon several with The steam jet of its inner chamber connection, the steam connected with the high pressure steam generator of outside enter pipe (6-11-9) and pass through deodorization tank After the housing of the tank skin and preprocessor (6-11) of (6-1) with steam ring (6-11-3) through connection；

The agitator (6-3) that mixes includes agitation main shaft (6-3-2), is fixedly installed on the agitation electricity on deodorization tank (6-1) arc top Machine (6-3-1) and the agitating vane (6-3-3) for being securely fitted in agitation main shaft (6-3-2) bottom, stir the upper of main shaft (6-3-2) Portion extends to the outer surface on deodorization tank (6-1) arc top and is connected with stirring motor (6-3-1)；Agitating vane (6-3-3) position Between primary nanometer purification membrane (6-4) and two level nanometer purification membrane (6-5)；

Electrically-controlled valve, stirring motor (6-3-1), pressure-reducing valve (6-7), temperature-sensing valve (6-8) and odor unit detector (6-9) respectively with Intelligent controller (7) polygon control survey connects.

A kind of 2. underground engineering wastewater treatment integrating device according to claim 1, it is characterised in that the preprocessor The catalyst for the inner space that (6-11) also includes penetrating preprocessor (6-11) by the top of the first dispersion plate (6-11-2) sprays Manage (6-11-11) and positioned at the outside air supply device (6-11-8) of deodorization tank (6-1)；The catalyst jet pipe (6-11-11) Outer end is connected after passing deodorization tank (6-1) tank skin with catalyst tank, and the inner end downward bending of catalyst jet pipe (6-11-11) is worn Nozzle is equipped with after crossing the first dispersion plate (6-11-2)；

The air outlet of the air supply device (6-11-8) is connected with one end of airduct (6-11-7), the other end of airduct (6-11-7) The inside of preprocessor (6-11) housing is entered by liquid outlet (6-11-6) after penetrating deodorization tank (6-1) and passes through supporting plate (6- 11-5) it is deep into inside activated carbon (6-11-4) layer；The housing sidewall top of preprocessor (6-11) is provided with air outlet (6- 11-13)；

The internal side close to air supply device (6-11-8) of the airduct (6-11-7) is equipped with viable bacteria atomizer (6-11- 12), the viable bacteria atomizer (6-11-12) includes being horizontally fixed on the internal horn cover (6-11-12- of airduct (6-11-7) 8), it is fixedly connected on the surge chamber (6-11-12-2) on the left of horn cover (6-11-12-8) small openend, is fixedly connected on buffering The motor (6-11-12-1) of room (6-11-12-2) left end and the bacterium solution pump (6-11- positioned at horn cover (6-11-12-8) outside 12-9)；

Horn cover (6-11-12-8) the left end opening diameter is less than right-end openings diameter, horn cover (6-11-12-8) inner shaft The position of heart line is provided with hollow axle (6-11-12-3), and the left end of hollow axle (6-11-12-3) extends to surge chamber (6- 11-12-2) it is rotatably coupled inside right-hand member and by bearing and surge chamber (6-11-12-2), in horn cover (6-11-12-8) Portion both ends are each provided with one and are fixedly connected with hollow axle (6-11-12-3) by hollow cross (6-11-12-6) Empty support ring (6-11-12-7), multiple circular hollow axle (6-11- are provided between two hollow support rings (6-11-12-7) 12-3) the cylindroid hollow tube (6-11-12-4) of arrangement, the both ends of cylindroid hollow tube (6-11-12-4) and two hollow branch Pushing out ring (6-11-12-7) insertion ground connection, cylindroid hollow tube (6-11-12-4) surface, which sets group, what is largely connected with its inner chamber Bacterium solution shower nozzle (6-11-12-5)；

The output shaft of the motor (6-11-12-1) stretches into hollow axle (6-11-12-3) through surge chamber (6-11-12-2) The inner end and more connecting rods by radially arranging are fixedly connected with hollow axle (6-11-12-3)；

The outlet end of the bacterium solution pump (6-11-12-9) is connected by pipeline with the inner chamber of surge chamber (6-11-12-2), bacterium solution pump The liquid feeding end of (6-11-12-9) by pass the extension tube attached (6-11-12-10) of preprocessor (6-11) and deodorization tank (6-1) with Outside bacterium solution culture tank connection；

Motor (6-11-12-1) and bacterium solution pump (6-11-12-9) are connected with intelligent controller (7) polygon control survey respectively.

A kind of 3. underground engineering wastewater treatment integrating device according to claim 1 or 2, it is characterised in that the pre- place The detection pipe (6-11-10) connected with its inner chamber, the outer end of detection pipe (6-11-10) are also associated with the housing of reason device (6-11) The control valve being connected with intelligent controller (7) polygon control survey is connected with after passing deodorization tank (6-1).

A kind of 4. underground engineering wastewater treatment integrating device according to claim 3, it is characterised in that the agitation main shaft The top of (6-3-2) is provided with reductor speed probe (6-3-4), reductor speed probe (6-3-4) and intelligent control Device (7) polygon control survey connects.

A kind of 5. underground engineering wastewater treatment integrating device according to any one of claim 4, it is characterised in that it is described fall Ground support frame (1) is formed by transverse channel steels, vertical channel-section steel and reinforcement welding assembly, and floor-type support frame (1) top is provided with aerial Fixed station (2), the aerial fixed station (2) are welded and fixed with floor-type support frame (1), and aerial fixed station (2) surface is provided with anti-skidding Groove (3)；Described halfpace of ascending a height (4) one end is welded in the side of aerial fixed station (2), and the other end is screwed in ground, stepped on High halfpace (4) side is provided with safety barrier (5), and the safety barrier (5) is welded and fixed with halfpace of ascending a height (4), safety barrier (5) Highly it is not less than 1.2m；Deodorization agent set (6) bottom is positioned over floor-type support frame (1) surface, deodorization agent set (6) Waist passes through the circular groove among aerial fixed station (2)；The intelligent controller (7) is positioned at halfpace (4) side of ascending a height.

A kind of 6. underground engineering wastewater treatment integrating device according to claim 5, it is characterised in that the inlet (6-11-1) is inverted broadening formation structure, and the air outlet (6-11-13) is arranged in the oblique side wall of broadening formation；Institute Steam jet quantity is stated as 10~20；The airduct (6-11-7) is L-type bend pipe structure；The deodorization tank (6-1) be with The cylinder-like structure of arc closure.

A kind of 7. underground engineering wastewater treatment integrating device according to claim 1, it is characterised in that the agitating vane (6-3-3) is matched in parts by weight by following components to be formed：

4- acetoxy-3s-acetoxy-methyl-α-(N- benzyl-N- tert-butylaminos) 50~270 parts of-acetophenone hydro-chloride, Alpha-brominated 30~240 parts of -4- methoxyacetophenones, the base butyrates of alpha-cyano -3- phenoxy benzyls 2- (4- chlorphenyls) -3- four 100~300 parts, (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- bis- chloro- 1 (4- ethoxyl phenenyls) cyclopropane-carboxylic acid 60~ 370 parts, 4- benzyloxies-α-{ [2- (4- anisyls) ethyl] amino } 50~260 parts of propiophenone, 2- [(the chloro- 2- nitrobenzene of 4- Base) azo] 140~430 parts of-N- (4- ethoxyl phenenyls) -3- oxos butyramide, concentration is 90ppm~130ppm inclined chlorine chrysanthemum Sour fluoro- 30~120 parts of the 3- phenoxy groups benzyl esters of alpha-cyano -4-, (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- dichloroethylene Base) 50~350 parts of cyclopropane-carboxylic acid-a- cyano group -3- phenoxy group -4- fluoro-methylbenzyl esters, [(the chloro- 4- fluoroanilinos of 3-) methylene] the third two 80~330 parts of diethyl phthalate, 70~310 parts of crosslinking agent, 40~130 parts of 4- Trifluoromethoxyphen-ls isocyanates, 4- (3,5- bis- Anisyl) 250~430 parts of -3-butenoic acid ethyl ester, 3,5- 40~70 parts of diaminourea -4- chlorobenzoic acids isobutyl esters, ((4- ammonia The fluoro- 2- pyridines of two chloro- 6- of base -3,5-) epoxide) 140~330 parts of-acetic acid.

8. a kind of underground engineering wastewater treatment integrating device stated according to claim 7, it is characterised in that the crosslinking agent is 2- Cyano group -3- phenoxy benzyl -2,2,3,3- tetramethyl-rings cyclopropanecarboxylic acid ester, 3,4- dichlorophenyl carbamic acids -2- [3- butyl -4- (2,2- dicyanoethenyls) -3- toluidinos] ethyl ester, in 2- cyano group -2- (3 '-chloro- 2 '-nitrobenzophenone) tert-butyl acetate Any one.

A kind of 9. underground engineering wastewater treatment integrating device stated according to claim 8, it is characterised in that the agitating vane (6-3-3) is prepared by following steps：

1st step：300~450 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 1.45 μ S/cm~4.37 is added in a kettle, is started anti- Agitator in kettle is answered, rotating speed is 120rpm~230rpm, starts heat pump, reactor temperature is risen to 70 DEG C~110 DEG C； Successively plus 4- acetoxy-3s-acetoxy-methyl-α-(N- benzyl-N- tert-butylaminos)-acetophenone hydro-chloride, it is alpha-brominated- 4- methoxyacetophenones, the base butyrates of alpha-cyano -3- phenoxy benzyls 2- (4- chlorphenyls) -3- four, stirring are adjusted to being completely dissolved It is 3.1~8.4 to save pH value, agitator speed is adjusted into 120rpm~210rpm, temperature is 110 DEG C~240 DEG C, esterification 9 ~17 hours；

2nd step：Take (4- ethoxyl phenenyls) cyclopropane-carboxylic acids of (RS)-alpha-cyano -3- benzyloxy phenoxies base-(RS) -2,2- two chloro- 1,4- Benzyloxy-α-{ [2- (4- anisyls) ethyl] amino } propiophenone is crushed, and powder diameter is 30~70 mesh；Add 2- [(4- Chloro- 2- nitrobenzophenones) azo]-N- (4- ethoxyl phenenyls) -3- oxos butyramide 1 is well mixed, and it is laid in pallet, tiles Thickness is 20mm~60mm, use dosage for 3.0kGy~8.3kGy, energy be 3.2MeV~5.7MeV alpha ray irradiation 22~ 46 minutes, and the β x ray irradiation xs 94~131 minutes of Isodose；

3rd step：The mixed-powder handled through the 2nd step is dissolved in the inclined fluoro- 3- phenoxy groups benzyl esters of chlorine chrysanthemumic acid alpha-cyano -4-, is added anti- Kettle is answered, agitator speed is 70rpm~520rpm, and temperature is 120 DEG C~260 DEG C, and starting vavuum pump makes the vacuum of reactor Reach -0.20MPa~-0.50MPa, keep this state response 3~14 hours；Pressure release is simultaneously passed through nitrogen, makes reacting kettle inner pressure For 1.15MPa~5.55MPa, insulation stands 3~10 hours；Agitator speed is promoted to 70rpm~200rpm, simultaneous reactions kettle Pressure release is to 0MPa；Sequentially add (1R, S)-suitable, trans -2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane-carboxylic acid-a- After cyano group -3- phenoxy group -4- fluoro-methylbenzyl esters, [(the chloro- 4- fluoroanilinos of 3-) methylene] diethyl malonate are completely dissolved, add and hand over Connection agent is stirred so that the hydrophilic lipophilic balance of reactor solution is 2.0~7.0, and insulation stands 8~16 hours；

4th step：When agitator speed is 52rpm~240rpm, 4- Trifluoromethoxyphen-ls isocyanates, 4- are sequentially added (3,5- dimethoxy phenyls) -3-butenoic acid ethyl ester, 3,5- diaminourea -4- chlorobenzoic acids isobutyl ester, ((4- amino -3,5- two is chloro- The fluoro- 2- pyridines of 6-) epoxide)-acetic acid, reactor pressure is lifted, reaches 4.20MPa~7.50MPa, temperature is 110 DEG C~ 250 DEG C, polymerisation 5~15 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 20 DEG C~30 DEG C is cooled to, goes out Material, enters molding press and can be prepared by agitating vane (6-3-3).

10. a kind of operating method of underground engineering wastewater treatment integrating device, it is characterised in that comprise the following steps：

1st step：Controlled by intelligent controller (7) and open the internal electrically-controlled valve of water inlet (6-2), make water with 13m3/h~ 37m3/h flow velocity enters preprocessor (6-11)；First dispersion plate (6-11-2) make sewage uniformly, gently fall into pretreatment In the middle part of device (6-11), meanwhile, the catalyst of fog-like body is equably sprayed at preprocessor (6- by catalyst jet pipe (6-11-11) 11) middle part, steam ring (6-11-3) sprays to external high pressure steam in the sewage of whereabouts and the mixed liquor of catalyst, with rapidly right The mixed liquor of sewage and catalyst is heated；Mixed liquor after second dispersion plate (6-11-14) guiding is heated is through uniform, flat Enter preprocessor (6-11) bottom slowly；Activated carbon (6-11-4) adsorbs to the aerobic microbiological in mixed liquor and organic matter, And it is provided with machine thing degraded place for aerobic microbiological；Air supply device (6-11-8) work passes through airduct (6-11-7) by outside Aerobic bacteria after the atomization that fresh air and viable bacteria atomizer (6-11-12) provide is transported to activated carbon (6-11-4) layer, thinks Growth of aerobic microorganisms provides oxygen；Sewage after processing is discharged by liquid outlet (6-11-6)；

2nd step：Sewage after preprocessor (6-11) processing enters in deodorization tank (6-1), and sewage is in deodorization tank (6-1) Rate firstly flows through primary nanometer purification membrane (6- is through 4), primary nanometer purification membrane (6-4) to most sulfur-containing compound in sewage and Nitrogen-containing compound carries out purified treatment；

3rd step：The closure above deodorant adding mouth (6-6) is opened, quantitative deodorant, while intelligence are launched into sewage Controller (7) control starts motor (6-3-1), and stirring motor (6-3-1) drives agitating vane (6-3-3) to carry out at the uniform velocity rotation fortune It is dynamic, increase the odor removal efficient of deodorant, in the process, reductor speed probe (6-3-4) moment monitoring agitating vane (6- Rotating speed size 3-3)；

4th step：Sewage through deodorant deodorization it is backward under continue to flow through two level nanometer purification membrane (6-5), two level nanometer purification membrane (6- 5) double purification processing is carried out to the sulfur-containing compound and nitrogen-containing compound that are remained in sewage, the water body after processing is through delivery port (6-10) flows out；

5th step：In deodorisation process, the moment supervises respectively for pressure-reducing valve (6-7), temperature-sensing valve (6-8) and odor unit detector (6-9) Deodorization tank (6-1) internal pressure, temperature and odor unit situation are controlled, when corresponding index is below standard, pressure-reducing valve (6-7), temperature Control valve (6-8) and odor unit detector (6-9) and send signal, intelligent controller (7) control system to intelligent controller (7) respectively System is automatically adjusted to relevant parameter.