CN109206953A - A kind of conch meal simulated ecological and preparation method thereof - Google Patents
A kind of conch meal simulated ecological and preparation method thereof Download PDFInfo
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- CN109206953A CN109206953A CN201810360307.0A CN201810360307A CN109206953A CN 109206953 A CN109206953 A CN 109206953A CN 201810360307 A CN201810360307 A CN 201810360307A CN 109206953 A CN109206953 A CN 109206953A
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- conch meal
- simulated ecological
- organobentonite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to simulated ecological technical fields, and a kind of conch meal simulated ecological is disclosed, the raw material including following parts by weight proportion: 40-60 parts of fluorinated acrylic ester, 30-50 parts of silicon rubber, 4-8 parts of bioantifouling agent, 20-40 parts of filler, 1-3 parts of organobentonite, 1-3 parts of polyethylene wax, 4-15 parts of propylene glycol and 5-10 parts of conch meal.Pass through the addition of conch meal, there are few difference for the absorption property and diatom ooze of conch meal ecologic coating, but its specific gravity is smaller than diatom ooze, so workability is more preferably, with more the visual effect that texture is soft and smooth, shell powder paint not only itself does not contain harmful substance, the finishing pollutions such as the formaldehyde in air can also be adsorbed, smoke can also be removed, the life peculiar smells such as peculiar smell of pet and toilet, it is known that containing many calcium in shell, and its main component is exactly calcium in good shell, calcium has good anti-static ability again, therefore the anti-static ability of good shell powder paint is ability very strong and there are also adjusting air humidity.
Description
Technical field
The present invention relates to simulated ecological technical field, specially a kind of conch meal simulated ecological and preparation method thereof.
Background technique
Bionical antifouling paint is a kind of completely new antifouling concept, it is to find antifouling high score from biological attachment mechanism
Sub- material is such as imitated by the sink conditions to some biologies, assigns coating with special surface property, such as low-surface-energy
With microphase-separated etc., keep its easy to attach or attachment loosely, biomimetic material refer to mimic biology various features or characteristic and
The material of development, the people that usually structure law of the operational mode and biomaterial of copying life system is manufactured and designed
Work material is known as biomimetic material, and branch of the bionics in material science is known as Researches on Biomimetic Materials, it refers to from molecular level
The design feature and structure-activity relationship of biomaterial are studied, and then develops similar or newly sets up schools better than one of protozoa material
Section, is the intersection of the subjects such as chemistry, materialogy, biology and physics, and Bionic Design will not only simulate the knot of biological object
Structure will more simulate its function, and material science, life science, bionics are combined, for pushing the development of material science to have
It is of great importance, natural evolution makes biomaterial have macroscopical, thin sight and microstructure most reasonable, optimize, and has
There are adaptivity and self-healing capability, is all best in the comprehensive performances such as specific strength, specific stiffness and toughness.
With popularizing for conch meal technology, the application field of conch meal is also more and more extensive, and conch meal is initially used in
Beauty industry and food additives gradually expand to finishing field, the absorption property and diatom ooze of conch meal ecologic coating later
There are few difference, but its specific gravity is smaller than diatom ooze, so workability is more preferably, with more the visual effect that texture is soft and smooth, now
Common coating requires to spend the manpower and material resources of aniseed in terms of construction and the maintenance in later period, and the research and development of simulated ecological improve
Also become present mainstream.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of conch meal simulated ecological and preparation method thereof, has adsorptivity
The advantages of big and saving resource, solves now common coating and requires to spend aniseed in terms of construction and the maintenance in later period
Manpower and material resources the problem of.
(2) technical solution
To realize that above-mentioned adsorptivity is big and saves the purpose of resource, the invention provides the following technical scheme: a kind of conch meal is bionical
Coating, the raw material including following parts by weight proportion: 40-60 parts of fluorinated acrylic ester, 30-50 parts of silicon rubber, bioantifouling agent
4-8 parts, 20-40 parts of filler, 1-3 parts of organobentonite, 1-3 parts of polyethylene wax, 4-15 parts of propylene glycol and 5-10 parts of conch meal.
Preferably, the raw material including following parts by weight proportion: 40 parts of fluorinated acrylic ester, 30 parts of silicon rubber, biology are anti-
4 parts of dirty agent, 20 parts of filler, 1 part of organobentonite, 1 part of polyethylene wax, 4 parts of propylene glycol and 5 parts of conch meal.
Preferably, the raw material including following parts by weight proportion: 50 parts of fluorinated acrylic ester, 40 parts of silicon rubber, biology are anti-
6 parts of dirty agent, 30 parts of filler, 2 parts of organobentonite, 2 parts of polyethylene wax, 10 parts of propylene glycol and 8 parts of conch meal.
Preferably, the raw material including following parts by weight proportion: 60 parts of fluorinated acrylic ester, 50 parts of silicon rubber, biology are anti-
8 parts of dirty agent, 40 parts of filler, 3 parts of organobentonite, 3 parts of polyethylene wax, 15 parts of propylene glycol and 10 parts of conch meal.
Another technical problem to be solved by the present invention is that a kind of conch meal simulated ecological and preparation method thereof is provided, including with
Lower step:
1) 40-60 parts of fluorinated acrylic ester, 30-50 parts of silicon rubber, 4-8 parts of bioantifouling agent are first taken, double roller refining glue is added together
Machine is heated to 50 DEG C one 60 DEG C, rolls repeatedly and be smelt mixture color chips, then letting nitrogen in and deoxidizing, is gradually heated to 75-85 DEG C, places
For a period of time, then by mixture color chips it being implanted into reaction kettle, is heated to 40 DEG C one 80 DEG C, stirring to whole dissolutions stands 10 minutes,
It stays with spare;
2) it is stood in step 1) ten minutes later, filler 20-40 parts, 1-3 parts of organobentonite is added into reaction kettle, then opens
Dynamic reaction kettle persistently stirs 30 minutes, and revolving speed control is turned left the right side 100, then turns down revolving speed to 50 turns, mixing time 10 minutes,
20 minutes are stood, it is spare;
3) after time of repose reaches in step 2, polyethylene wax 1-3 parts of addition, 4-15 parts of propylene glycol and shellfish into reaction kettle
5-10 parts of shell powder, wherein the sequences of conch meal 5-10 parts of additions be placed on finally, and by the normal work of reaction kettle, until completely
Mixing, it is spare after standing 1 hour;
4) mixture completed will be stood in step 3) be heated to 50 DEG C in a kettle, continuous continual 30 points of stirring
Conch meal simulated ecological can be obtained in clock.
(3) beneficial effect
Compared with prior art, the present invention provides a kind of conch meal simulated ecologicals and preparation method thereof, have following beneficial to effect
Fruit:
The conch meal simulated ecological and preparation method thereof, by the addition of conch meal, the absorption property of conch meal ecologic coating with
There are few difference for diatom ooze, but its specific gravity is smaller than diatom ooze, so workability is more preferably, imitate with more the soft and smooth vision of texture
Fruit, shell powder paint not only itself do not contain harmful substance, moreover it is possible to adsorb the finishing pollutions such as the formaldehyde in air, moreover it is possible to remove cigarette
The life peculiar smells such as taste, peculiar smell of pet and toilet, it is known that contain many calcium in shell, and its in good shell is led
Wanting ingredient is exactly calcium, and calcium has good anti-static ability again, therefore the anti-static ability of good shell powder paint is very
Ability strong and there are also adjusting air humidity, shell powder paint is very environment protection health, does not contain any nocuousness not only
Substance also can effectively purifying formaldehyde and purify the air of a room, and shell powder paint can also play the role of adjusting air humidity,
It can effectively absorb the moisture of new house ornamentation environment, to facilitate the health of guarantee human body, shell powder paint also has extremely strong
Anti-static ability, ash not easy to stick solves common painting now if surface has only need to gently brush lightly out when dust
Material requires the problem of spending the manpower and material resources of aniseed in terms of construction and the maintenance in later period.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
Embodiment one:
A kind of conch meal simulated ecological, the raw material including following parts by weight proportion: 40 parts of fluorinated acrylic ester, silicon rubber 30
Part, 4 parts of bioantifouling agent, 20 parts of filler, 1 part of organobentonite, 1 part of polyethylene wax, 4 parts of propylene glycol and 5 parts of conch meal.
A kind of conch meal simulated ecological and preparation method thereof, comprising the following steps:
1) 40 parts of fluorinated acrylic ester, 30 parts of silicon rubber, 4 parts of bioantifouling agent are first taken, twin-screw extruder is added together, is heated to
It 50 DEG C, rolls repeatedly and is smelt mixture color chips, then letting nitrogen in and deoxidizing, be gradually heated to 75 DEG C, place a period of time, then by mixture
Color chips is implanted into reaction kettle, is heated to 40 DEG C, and stirring to whole dissolutions stands 10 minutes, stays with spare;
2) it is stood in step 1) ten minutes later, 20 parts of filler, 1 part of organobentonite is added into reaction kettle, then starting is anti-
Kettle is answered, is persistently stirred 30 minutes, revolving speed control is turned left the right side 100, then turns down revolving speed to 50 turns, mixing time 10 minutes, is stood
It is 20 minutes, spare;
3) after time of repose reaches in step 2, polyethylene wax 1-3 parts of addition, 4 parts of propylene glycol and shell into reaction kettle
5 parts of powder, wherein the sequences of conch meal 5-10 parts of additions be placed on finally, and by the normal work of reaction kettle, until be thoroughly mixed,
It is spare after standing 1 hour;
4) mixture completed will be stood in step 3) be heated to 50 DEG C in a kettle, continuous continual 30 points of stirring
Conch meal simulated ecological can be obtained in clock.
Embodiment two:
A kind of conch meal simulated ecological, the raw material including following parts by weight proportion: the raw material including following parts by weight proportion:
50 parts of fluorinated acrylic ester, 40 parts of silicon rubber, 6 parts of bioantifouling agent, 30 parts of filler, 2 parts of organobentonite, 2 parts of polyethylene wax,
10 parts and 8 parts of conch meal of propylene glycol.
A kind of conch meal simulated ecological and preparation method thereof, comprising the following steps:
1) 50 parts of fluorinated acrylic ester, 40 parts of silicon rubber, 6 parts of bioantifouling agent are first taken, twin-screw extruder is added together, is heated to
It 55 DEG C, rolls repeatedly and is smelt mixture color chips, then letting nitrogen in and deoxidizing, be gradually heated to 80 DEG C, place a period of time, then by mixture
Color chips is implanted into reaction kettle, is heated to 60 DEG C, and stirring to whole dissolutions stands 10 minutes, stays with spare;
2) it is stood in step 1) ten minutes later, 30 parts of filler, 2 parts of organobentonite is added into reaction kettle, then starting is anti-
Kettle is answered, is persistently stirred 30 minutes, revolving speed control is turned left the right side 100, then turns down revolving speed to 50 turns, mixing time 10 minutes, is stood
It is 20 minutes, spare;
3) after time of repose reaches in step 2,2 parts of polyethylene wax, 10 parts of propylene glycol and conch meal are added into reaction kettle
8 parts, wherein the sequence of 8 parts of conch meal additions is placed on finally, and standing 1 up to being thoroughly mixed by the normal work of reaction kettle
It is spare after hour;
4) mixture completed will be stood in step 3) be heated to 50 DEG C in a kettle, continuous continual 30 points of stirring
Conch meal simulated ecological can be obtained in clock.
Embodiment three:
A kind of conch meal simulated ecological, the raw material including following parts by weight proportion: 60 parts of fluorinated acrylic ester, silicon rubber 50
Part, 8 parts of bioantifouling agent, 40 parts of filler, 3 parts of organobentonite, 3 parts of polyethylene wax, 15 parts of propylene glycol and 10 parts of conch meal.
A kind of conch meal simulated ecological and preparation method thereof, comprising the following steps:
1) 60 parts of fluorinated acrylic ester, 50 parts of silicon rubber, 8 parts of bioantifouling agent are first taken, twin-screw extruder is added together, is heated to
It 60 DEG C, rolls repeatedly and is smelt mixture color chips, then letting nitrogen in and deoxidizing, be gradually heated to 85 DEG C, place a period of time, then by mixture
Color chips is implanted into reaction kettle, is heated to 80 DEG C, and stirring to whole dissolutions stands 10 minutes, stays with spare;
2) it is stood in step 1) ten minutes later, 40 parts of filler, 3 parts of organobentonite is added into reaction kettle, then starting is anti-
Kettle is answered, is persistently stirred 30 minutes, revolving speed control is turned left the right side 100, then turns down revolving speed to 50 turns, mixing time 10 minutes, is stood
It is 20 minutes, spare;
3) after time of repose reaches in step 2,3 parts of polyethylene wax, 15 parts of propylene glycol and conch meal are added into reaction kettle
10 parts, wherein the sequences of 10 parts of conch meal additions be placed on finally, and by the normal work of reaction kettle, it is quiet until be thoroughly mixed
It is spare after setting 1 hour;
4) mixture completed will be stood in step 3) be heated to 50 DEG C in a kettle, continuous continual 30 points of stirring
Conch meal simulated ecological can be obtained in clock.
The beneficial effects of the present invention are:
By the addition of conch meal, there are few difference for the absorption property and diatom ooze of conch meal ecologic coating, but its specific gravity compares diatom
Mud is smaller, so workability is more preferably, with more the visual effect that texture is soft and smooth, shell powder paint not only itself does not contain nocuousness
Substance, moreover it is possible to adsorb the finishing pollutions such as the formaldehyde in air, moreover it is possible to the life peculiar smells such as smoke, peculiar smell of pet and toilet are removed,
It is known that contain many calcium in shell, and its main component is exactly calcium in good shell, calcium has anti-well again
Electrostatic capacity, therefore the anti-static ability of good shell powder paint is energy very strong and there are also adjusting air humidity
Power, shell powder paint are that very environment protection health also being capable of effectively purifying formaldehyde and purification not only without containing any harmful substance
Room air, shell powder paint can also play the role of adjusting air humidity, it can effectively absorb the wet of new house ornamentation environment
Gas, to facilitate the health of guarantee human body, shell powder paint also has extremely strong anti-static ability, ash not easy to stick, if table
Face has and only need to gently brush lightly out when dust, solves now common coating in terms of construction and the maintenance in later period all
The problem of needing to spend the manpower and material resources of aniseed.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (5)
1. a kind of conch meal simulated ecological, which is characterized in that the raw material including following parts by weight proportion: fluorinated acrylic ester
40-60 parts, 30-50 parts of silicon rubber, 4-8 parts of bioantifouling agent, 20-40 parts of filler, 1-3 parts of organobentonite, polyethylene wax 1-3
Part, 4-15 parts of propylene glycol and 5-10 parts of conch meal.
2. a kind of conch meal simulated ecological according to claim 1, which is characterized in that including following parts by weight proportion
Raw material: 40 parts of fluorinated acrylic ester, 30 parts of silicon rubber, 4 parts of bioantifouling agent, 20 parts of filler, 1 part of organobentonite, polyethylene
1 part of wax, 4 parts of propylene glycol and 5 parts of conch meal.
3. a kind of conch meal simulated ecological according to claim 1, which is characterized in that including following parts by weight proportion
Raw material: 50 parts of fluorinated acrylic ester, 40 parts of silicon rubber, 6 parts of bioantifouling agent, 30 parts of filler, 2 parts of organobentonite, polyethylene
2 parts of wax, 10 parts of propylene glycol and 8 parts of conch meal.
4. a kind of conch meal simulated ecological according to claim 1, which is characterized in that including following parts by weight proportion
Raw material: 60 parts of fluorinated acrylic ester, 50 parts of silicon rubber, 8 parts of bioantifouling agent, 40 parts of filler, 3 parts of organobentonite, polyethylene
3 parts of wax, 15 parts of propylene glycol and 10 parts of conch meal.
5. a kind of conch meal simulated ecological and preparation method thereof, which comprises the following steps:
1) 40-60 parts of fluorinated acrylic ester, 30-50 parts of silicon rubber, 4-8 parts of bioantifouling agent are first taken, double roller refining glue is added together
Machine is heated to 50 DEG C one 60 DEG C, rolls repeatedly and be smelt mixture color chips, then letting nitrogen in and deoxidizing, is gradually heated to 75-85 DEG C, places
For a period of time, then by mixture color chips it being implanted into reaction kettle, is heated to 40 DEG C one 80 DEG C, stirring to whole dissolutions stands 10 minutes,
It stays with spare;
2) it is stood in step 1) ten minutes later, filler 20-40 parts, 1-3 parts of organobentonite is added into reaction kettle, then opens
Dynamic reaction kettle persistently stirs 30 minutes, and revolving speed control is turned left the right side 100, then turns down revolving speed to 50 turns, mixing time 10 minutes,
20 minutes are stood, it is spare;
3) after time of repose reaches in step 2, polyethylene wax 1-3 parts of addition, 4-15 parts of propylene glycol and shellfish into reaction kettle
5-10 parts of shell powder, wherein the sequences of conch meal 5-10 parts of additions be placed on finally, and by the normal work of reaction kettle, until completely
Mixing, it is spare after standing 1 hour;
4) mixture completed will be stood in step 3) be heated to 50 DEG C in a kettle, continuous continual 30 points of stirring
Conch meal simulated ecological can be obtained in clock.
Priority Applications (1)
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CN201810360307.0A CN109206953A (en) | 2018-04-20 | 2018-04-20 | A kind of conch meal simulated ecological and preparation method thereof |
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CN201810360307.0A CN109206953A (en) | 2018-04-20 | 2018-04-20 | A kind of conch meal simulated ecological and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110183026A (en) * | 2019-05-10 | 2019-08-30 | 金华市景和科技有限公司 | Plant culture and rainwater-collecting integrated apparatus |
Citations (3)
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CN103694754A (en) * | 2013-12-12 | 2014-04-02 | 青岛海洋新材料科技有限公司 | Bionic marine antifouling paint |
CN104164112A (en) * | 2014-08-21 | 2014-11-26 | 青岛优维奥信息技术有限公司 | Bionic marine antifouling paint |
CN107459933A (en) * | 2017-08-25 | 2017-12-12 | 秦皇岛美博士新型材料科技有限公司 | A kind of liquid shell powder paint and preparation method thereof |
-
2018
- 2018-04-20 CN CN201810360307.0A patent/CN109206953A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103694754A (en) * | 2013-12-12 | 2014-04-02 | 青岛海洋新材料科技有限公司 | Bionic marine antifouling paint |
CN104164112A (en) * | 2014-08-21 | 2014-11-26 | 青岛优维奥信息技术有限公司 | Bionic marine antifouling paint |
CN107459933A (en) * | 2017-08-25 | 2017-12-12 | 秦皇岛美博士新型材料科技有限公司 | A kind of liquid shell powder paint and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110183026A (en) * | 2019-05-10 | 2019-08-30 | 金华市景和科技有限公司 | Plant culture and rainwater-collecting integrated apparatus |
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