CN109199888B - Novel water with functions of beautifying and makeup removing and preparation method thereof - Google Patents
Novel water with functions of beautifying and makeup removing and preparation method thereof Download PDFInfo
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- CN109199888B CN109199888B CN201811358066.2A CN201811358066A CN109199888B CN 109199888 B CN109199888 B CN 109199888B CN 201811358066 A CN201811358066 A CN 201811358066A CN 109199888 B CN109199888 B CN 109199888B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 189
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 100
- 239000011707 mineral Substances 0.000 claims abstract description 100
- 230000035622 drinking Effects 0.000 claims abstract description 26
- 239000008213 purified water Substances 0.000 claims abstract description 26
- 230000000694 effects Effects 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims description 139
- 238000003756 stirring Methods 0.000 claims description 89
- 238000000498 ball milling Methods 0.000 claims description 79
- 239000004575 stone Substances 0.000 claims description 78
- 239000000919 ceramic Substances 0.000 claims description 54
- 238000002156 mixing Methods 0.000 claims description 49
- 238000010438 heat treatment Methods 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 40
- 238000005245 sintering Methods 0.000 claims description 39
- 238000001035 drying Methods 0.000 claims description 34
- 238000005406 washing Methods 0.000 claims description 33
- 239000000853 adhesive Substances 0.000 claims description 32
- 230000001070 adhesive effect Effects 0.000 claims description 32
- 239000002244 precipitate Substances 0.000 claims description 28
- 238000004321 preservation Methods 0.000 claims description 28
- 239000002002 slurry Substances 0.000 claims description 28
- 239000012798 spherical particle Substances 0.000 claims description 28
- 238000000227 grinding Methods 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 22
- 229910044991 metal oxide Inorganic materials 0.000 claims description 22
- 150000004706 metal oxides Chemical class 0.000 claims description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- 238000001816 cooling Methods 0.000 claims description 20
- 238000001914 filtration Methods 0.000 claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 17
- 239000003607 modifier Substances 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 230000004913 activation Effects 0.000 claims description 13
- 241000237536 Mytilus edulis Species 0.000 claims description 12
- 235000020638 mussel Nutrition 0.000 claims description 12
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 11
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 11
- 238000002791 soaking Methods 0.000 claims description 11
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 10
- 238000010298 pulverizing process Methods 0.000 claims description 10
- 239000000661 sodium alginate Substances 0.000 claims description 10
- 235000010413 sodium alginate Nutrition 0.000 claims description 10
- 229940005550 sodium alginate Drugs 0.000 claims description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 10
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 10
- 239000002352 surface water Substances 0.000 claims description 10
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 229910052746 lanthanum Inorganic materials 0.000 claims description 9
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical group [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 108700004121 sarkosyl Proteins 0.000 claims description 6
- 230000003796 beauty Effects 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- 241000237509 Patinopecten sp. Species 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 235000020637 scallop Nutrition 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- 239000000126 substance Substances 0.000 abstract description 12
- 150000002632 lipids Chemical class 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 4
- 241000700605 Viruses Species 0.000 abstract description 4
- 235000016709 nutrition Nutrition 0.000 abstract description 4
- 230000035764 nutrition Effects 0.000 abstract description 4
- 239000012466 permeate Substances 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 238000007873 sieving Methods 0.000 description 23
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 22
- 239000000243 solution Substances 0.000 description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 19
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 18
- 239000011268 mixed slurry Substances 0.000 description 16
- 239000002537 cosmetic Substances 0.000 description 15
- 239000004744 fabric Substances 0.000 description 15
- 239000011812 mixed powder Substances 0.000 description 15
- 238000012545 processing Methods 0.000 description 15
- 235000001014 amino acid Nutrition 0.000 description 12
- 150000001413 amino acids Chemical class 0.000 description 12
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 9
- 229910001961 silver nitrate Inorganic materials 0.000 description 9
- 229910052613 tourmaline Inorganic materials 0.000 description 9
- 229940070527 tourmaline Drugs 0.000 description 9
- 239000011032 tourmaline Substances 0.000 description 9
- 239000011787 zinc oxide Substances 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- 229910052656 albite Inorganic materials 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- 239000012065 filter cake Substances 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 125000004430 oxygen atom Chemical group O* 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 4
- 206010000496 acne Diseases 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 208000002874 Acne Vulgaris Diseases 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002354 daily effect Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- 229910052624 sepiolite Inorganic materials 0.000 description 2
- 230000005808 skin problem Effects 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 208000020154 Acnes Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241001143502 Hippocastanaceae Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical group CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 239000001140 aloe barbadensis leaf extract Substances 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036074 healthy skin Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000001225 nuclear magnetic resonance method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- -1 sodium carboxylate Chemical class 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Zoology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses water with novel beautifying and makeup removing functions and a preparation method thereof, wherein the preparation method of the water with the novel beautifying and makeup removing functions comprises the following steps: (1) taking purified water for drinking; (2) and (5) activating the mineral balls. The novel water with the functions of beautifying and makeup removing and the preparation method thereof activate the water through the mineral balls, the obtained water is small molecular group water, the permeability and the dissolving power are stronger, the water can deeply permeate the skin, the nutrition, the moisture and the like necessary for a human body are conveyed into cells, the harmful substances such as bacteria, viruses, oily molecules such as makeup and the like and lipid and the like deposited in the cells can be better dissolved and discharged out of the body to achieve the aim of beautifying, and the water is rich in mineral components, so that the pH value of the water is changed from weak acidity to weak alkalinity, the oily molecules such as makeup and the like and the lipid and the like can be effectively removed, the makeup removing effect is good, and the novel water with the functions of beautifying and makeup removing is prepared from drinking purified water as a raw material without adding any chemical medicine and can not cause secondary damage to the skin.
Description
Technical Field
The invention relates to the technical field of daily chemicals, in particular to novel water with functions of beautifying and removing makeup and a preparation method thereof.
Background
The makeup can make people beautiful and give people a new feeling. In life, dressing for girls is a necessary course. This is a good way to show the beauty and charm of oneself. The makeup remover is a cosmetic product for removing makeup. At present, more and more women can apply various cosmetics on the face, the makeup is almost a daily necessary work of modern women, but the cosmetics have certain damage to the skin, the cosmetics are difficult to clean with clear water, the cosmetics left on the face can block pores and influence the normal metabolism of the skin, the normal physiological function of the skin is hindered to generate various skin diseases, the skin aging is accelerated, the makeup on the face must be removed every day and night, and if the makeup is not completely removed, the pores can be blocked when the cosmetics remain on the face, so that the serious result is easy to generate.
The makeup remover is particularly important for the cosmetics full of Linglan. The makeup remover on the market is mainly divided into two types, namely the makeup remover and the makeup remover oil. The components of the cleansing oil mainly comprise vegetable oil, mineral oil, synthetic ester and surfactant. The makeup removing oil mainly utilizes the characteristic of similarity and intermiscibility between grease, takes the oil as a solvent, dissolves color makeup or dirt on the face, and has high-efficiency and thorough makeup removing effect. However, the skin feel is thick and greasy when the skin care product is used, and pores can be blocked once the skin care product is not cleaned in time, so that skin problems such as acne and comedo are caused. The cleansing water is composed of surfactant and chemical solvent (benzyl alcohol) capable of dissolving oil and fat as main raw materials, and most of the cleansing water adopts artificially synthesized chemicals such as alcohol, perfume, pigment, etc., and the cleansing water has great irritation and damage to skin after long-term use. If the skin is not removed completely, pores can be blocked for a long time, and a series of skin problems such as large pores, blackheads, acnes and the like are caused. Therefore, more and more people make up at present, more people abuse and more people do not understand the makeup, and as a result, the face is covered with acne at a gentle age, so that the face skin is damaged, and a large number of people suffer from cosmetology.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the novel water with the functions of beautifying and removing makeup and the preparation method thereof, and the obtained novel water with the functions of beautifying and removing makeup is small molecular group water. Since water molecules have polarity (water molecules are polar molecules), water molecules are angular, hydrogen atoms are positioned at the ends of the water molecules and oxygen atoms are positioned at the vertices of the water molecules, and since oxygen has higher electronegativity than hydrogen, the charge on the side of the oxygen atoms in the water molecules is biased to negative, and molecules with such a charge difference are called dipoles. The charge difference causes water molecules to attract each other (the positively charged regions are attracted by the negatively charged regions), and simultaneously causes the water molecules to attract each other with other polar molecules, so that the water molecules are easy to pollute and hook. The terahertz balls can provide energy, and shock breaks interaction force-van der waals force between molecules. The low-frequency energy vibrates water molecules to enable the molecular weight of water to be 500 daltons, and the high-frequency energy enables the molecular weight of water to be 700 daltons and the water becomes small-molecule water. The micromolecule water has stronger penetrability and dissolubility, can deeply permeate the skin, can convey necessary nutrition, moisture and the like of a human body into cells, can better dissolve and discharge harmful substances such as bacteria, viruses, cosmetics and the like and lipid and the like deposited in the cells out of the body to achieve the aim of beautifying, is rich in mineral components, enables the pH value of water to be changed from weak acidity to weak alkalinity, can effectively remove cosmetics and other oily molecules and lipids, and has good makeup removing effect.
The purpose of the invention is realized by the following technical scheme:
a preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: (5-30), soaking for 2-4 hours, and filtering to obtain the novel water with the functions of beautifying and removing makeup.
The mineral balls are terahertz ceramic mineral balls and/or MPH + ceramic mineral balls.
Preferably, the mineral balls are terahertz ceramic mineral balls and MPH + ceramic mineral balls according to the mass ratio of (1-5): (1-5).
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.2-2 parts of adhesive into 10-20 parts of water, stirring for 10-20 minutes at 75-85 ℃ at 300 revolutions/minute of 100-;
(2) drying the spherical particles at 40-50 ℃ for 2-4 hours, then placing the spherical particles into a sintering furnace, heating to 400 ℃ at 8-12 ℃/min, carrying out heat preservation sintering for 20-30 minutes, heating to 750 ℃ at 15-25 ℃/min, carrying out heat preservation sintering for 20-30 minutes, heating to 1100 ℃ at 15-25 ℃/min, carrying out heat preservation sintering for 1-3 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is one or a mixture of sodium alginate, polyvinyl alcohol and sodium carboxymethylcellulose.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.1-1mm coarse powder;
(2) mixing 5-10 parts of shell coarse powder and 20-30 parts of 3-8 wt% sodium carbonate aqueous solution, stirring for 40-60 minutes at 100-;
(3) putting the shell coarse powder without the cuticle obtained in the step (2) into a ball milling tank for ball milling, adding 5-10 parts of ethanol as a ball milling medium, performing ball milling at the rotation speed of 400 and 600 revolutions per minute, and performing ball milling for 16-28 hours to obtain ball milling slurry;
(4) heating the ball milling slurry to 60-80 ℃, stirring at 60-80 ℃ for 1-3 hours at 300 revolutions per minute of 100-.
Preferably, the pretreated shell powder is prepared by the following method, wherein the parts are all parts by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.1-1mm coarse powder;
(2) mixing 5-10 parts of shell coarse powder and 20-30 parts of 3-8 wt% sodium carbonate aqueous solution, stirring for 40-60 minutes at 100-;
(3) putting the shell coarse powder without the horny layer obtained in the step (2) and 0.01-0.05 part of lanthanum titanate into a ball milling tank for ball milling, adding 5-10 parts of ethanol as a ball milling medium, wherein the ball milling rotation speed is 400-600 rpm, adding 1-5 parts of 8-12 wt% modifier aqueous solution after ball milling for 15-25 hours, and continuing ball milling for 1-3 hours to obtain ball milling slurry;
(4) heating the ball milling slurry to 60-80 ℃, stirring for 1-3 hours at 60-80 ℃ at 100-.
The shell is one or more of mussel shell, scallop shell, oyster shell, and flower shell.
The modifier is N-lauroyl sarcosine sodium and/or octanoic acid decanoyl acyl oat amino acid sodium.
Preferably, the modifier is a mixture of N-sodium lauroyl sarcosinate and sodium caprylocamphor aminoacid, and the mass ratio of the N-sodium lauroyl sarcosinate to the sodium caprylocamphor aminoacid is 1: (1-5).
The modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 5-10 parts of medical stone powder and 80-120 parts of 3-5 wt% hydrochloric acid, stirring at 40-50 ℃ for 20-40 minutes at 60-100 rpm, centrifuging at 4000-6000 rpm for 20-30 minutes, washing the obtained precipitate with water until no Cl is detected in the washing liquid by using 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 200-300 ℃ at the speed of 8-12 ℃/min, preserving the heat for 3-4 hours at the temperature of 200-300 ℃, naturally cooling to room temperature along with the furnace, and grinding to obtain the thermally modified medical stone;
(3) mixing 4-8 parts of thermally modified medical stone with 40-60 parts of water, adding 0.05-0.2 part of sodium hexametaphosphate, stirring at 60-80 ℃ for 10-20 minutes at 60-100 revolutions per minute, adding 0.01 part of metal oxide, stirring at 60-80 ℃ for 5-10 minutes at 60-100 revolutions per minute, stirring at 20-30 ℃ for 20-30 minutes, standing for 40-60 minutes, separating the core at 5000 revolutions per minute for 20-30 minutes, washing the lower-layer precipitate with 40-60 parts of water for 1-3 times, and drying at 80-100 ℃ for 4-8 hours to obtain the modified medical stone powder.
The metal oxide is one of cerium oxide, zirconium oxide and titanium oxide.
Preferably, the metal oxide is cerium oxide.
A novel water with skin caring and makeup removing effects is prepared by the above method.
The water molecule is formed by two hydrogen atoms and one oxygen atom which are linked together through an atomic chemical bond. The water molecules are angular, with the hydrogen atoms at the ends and the oxygen atoms at the vertices. Since oxygen has a higher electronegativity than hydrogen, the charge on the oxygen atom side of the molecule is biased negative. The difference in charge causes the water molecules to attract each other, so the water molecules have polarity. In addition, a hydrogen atom in one water molecule also has a bond, called a hydrogen bond, with an oxygen atom in an adjacent water molecule, which is not an atomic chemical bond but a molecular bond between water molecules. The hydrogen bond is longer, the bond energy is smaller, and the breakage is easy to damage. Due to the action of hydrogen bonds, association between water molecules occurs, and large molecular groups are formed and exist in nature.
The terahertz ceramic mineral ball is prepared by compositely processing ores with natural energy and has the function of naturally releasing terahertz waves. Terahertz waves (THz), also known as "vital rays", are a type of "light" energy, which refers to electromagnetic waves having a wavelength between 3 μm and 1000 μm, a frequency of 0.1-10THz, between microwave and infrared. Belongs to one of far infrared rays. The terahertz ceramic mineral ball emits terahertz waves, and can provide energy to vibrate and break the interaction force between molecules, namely van der Waals force. The low-frequency energy vibrates water molecules to enable the molecular weight of water to be 500 daltons, and the high-frequency energy enables the molecular weight of water to be 700 daltons and the water becomes small-molecule water. The small molecular group water has stronger penetrability and dissolubility, can deeply permeate into the skin, transmits the necessary nutrition and moisture of the human body into cells, and can better dissolve and discharge the harmful substances such as bacteria, viruses, cosmetics and other oily molecules and lipids deposited in the cells out of the body to achieve the purpose of beautifying.
The MPH + ceramic mineral sphere is made and processed by adopting mineral materials such as natural shells and the like by applying the latest 'micropore slow release' technology and a multi-temperature roasting process, contains various minerals beneficial to a human body, and can carry out hydrolysis reaction on water, so that the pH of the water is changed from weak acidity (pH value of 6-6.8) to an alkaline environment with weak alkalinity (pH value of 7.5-9.5). As the cosmetics such as color cosmetics mainly comprise esters and compounds such as glycerin, propylene glycol, methyl hydroxybenzoate, phenoxyethanol, acrylic acid (esters) and aloe barbadensis leaf extract, the group (-COO-) formed by combining organic matters with hydroxyl (-OH) and carboxyl (-COOH) is hydrolyzed in alkaline water to generate sodium carboxylate and alcohol, and the cosmetics are easy to dissolve in water and wipe.
Through the combined action of the two, the effects of good beautifying and makeup removing can be achieved.
The terahertz ceramic mineral ball prepared by the invention has an obvious effect of releasing far infrared rays, and can fully activate water to become small molecular group water. And natural waste shell powder is adopted, the shell powder is pretreated to prepare the MPH + ceramic mineral spheres, and the shell powder releases carbon dioxide in the sintering process to enable the ceramics to form a pore structure, so that the slow release effect of the MPH + ceramic mineral spheres is realized. Carry out the ball-milling and modify to shell powder, make it form small particle and with other raw materials misce benes, be favorable to forming even and tiny pore structure, promote the activation effect of MPH + ceramic mineral ball to water, and then promote the dissolving capacity and the infiltration ability of the water of novel beautiful face and make up removal function, make the water of novel beautiful face and make up removal function have good beautiful face and make up removal effect.
The terahertz ceramic mineral ball and the MPH + ceramic mineral ball can be placed in a conventional press type cosmetic bottle, the bottle is filled with water, and the water is fully activated by the terahertz ceramic mineral ball and the MPH + ceramic mineral ball and then sprayed out in a spray form through pressing.
Specifically, the mineral balls can be placed in the filter element shell 1, and the end face shell cover plate 2 is firmly welded by ultrasonic waves. The end surfaces of the shell 1 and the shell cover plate 2 are respectively provided with water through holes with equal diameters, the shell 1 filled with the mineral ceramic balls is placed in a spraying bottle 3, the drinking purified water is poured into the spraying bottle 3 and is soaked for 2-4 hours, and the novel water with the functions of beautifying and removing makeup is obtained. The user can adopt various modes to beautify and remove makeup, and can directly spray the water-replenishing water-removing mask on the positions needing makeup removal, such as water replenishing, whitening and the like, or spray the water-replenishing mask on the mask due to the activation of pure water. Or spraying the cleansing agent on a cleansing cotton for cleansing.
The novel water with the functions of beautifying and makeup removal and the preparation method thereof activate the water through the mineral balls, the obtained novel water with the functions of beautifying and makeup removal is small molecular group water, the permeability and the dissolving power are stronger, the novel water can deeply permeate into the skin, the nutrition, the moisture and the like required by a human body are conveyed into cells, the harmful substances such as bacteria, viruses, makeup and the like deposited in the cells can be better dissolved and discharged out of the body to achieve the aim of beautifying, and the novel water is rich in mineral components, so that the pH value of the water is changed from weak acidity to weak alkalinity, the oily molecules and the lipids such as the makeup and the like can be effectively removed, the makeup removal effect is good, and the novel water with the functions of beautifying and makeup removal is prepared from drinking purified water without adding any chemical medicine, and cannot cause secondary damage to the skin.
Detailed Description
In the present invention, all the equipment and materials are commercially available or commonly used in the art, and the methods in the following examples are conventional in the art unless otherwise specified.
The terahertz ceramic mineral ball can be a commercially available terahertz ceramic mineral ball or a self-made terahertz ceramic mineral ball, and in the embodiment, the terahertz ceramic mineral ball is prepared by the following method, wherein the parts are in parts by weight: mixing 35 parts of tourmaline, 25 parts of medical stone, 20 parts of sepiolite, 15 parts of kaolinite, 3 parts of titanium oxide and 2 parts of zirconium oxide according to parts by weight, stirring for 30 minutes at 800 revolutions per minute to obtain mixed powder, adding 15 parts of water, stirring for 2 hours at 800 revolutions per minute to obtain mixed slurry, processing the mixed slurry into spherical particles with the diameter of 4mm by a ball rolling machine, drying the spherical particles for 3 hours at 45 ℃, putting the spherical particles into a sintering furnace, heating to 1050 ℃ at 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the terahertz ceramic mineral ball.
Sepiolite, purchased from a processing plant for constantly-spreading mineral products in lingshou county, 800 mesh.
Kaolinite, purchased from waukang non-metallic mineral processing plant in anyun county, 800 mesh.
Albite, purchased from Jinshou county gold mine processing factory, 800 mesh.
Mussel is commercially available mussel, and is cleaned after meat and impurities are removed to obtain mussel shells.
Medical stone powder, purchased from Shunzhize mineral processing factory of Lingshou county, 800 mesh.
Zeolite powder, 800 mesh, was purchased from clinoptilolite powder produced by Shunzui mineral processing plants in Lingshou county.
Tourmaline powder, purchased from Shunzui mineral processing factory of Lingshou county, 800 mesh.
Zinc oxide, CAS No.: 1314-13-2, nano zinc oxide purchased from Jiangsu Tiansu New Material Co., Ltd, model: TZP-50 with primary particle size of 30 nm.
Sodium alginate, CAS No.: 9005-38-3, purchased from Hippocastanaceae Biotech Co.
Lanthanum titanate, a lanthanum titanate crystal produced by Kaisan electro-optic Material Co., Ltd.
Sodium lauroyl sarcosinate, CAS No.: 137-16-6, purchased from Tianjin Xiansi Biotechnology Ltd, was diluted with water to a 10 wt% aqueous solution of sodium lauroylsarcosine for further use.
The sodium decanoyl octanoyl oat amino acid is prepared by diluting aqueous solution of the sodium decanoyl octanoyl oat amino acid obtained in the application No. 201410784026 in the example 3 with water to 10 wt% aqueous solution of the sodium decanoyl octanoyl oat amino acid for later use.
Cerium oxide, CAS number: 1306-38-3, available from Shanghai Nippon Denyuki nanotechnology Co., granularity: 50 nm.
Zirconia, CAS number: 1314-23-4, purchased from shanghai yunrong nanotechnology co, granularity: 50 nm.
Titanium oxide, CAS No.: 1317-80-2, available from shanghai sey nanotechnology co, granularity: 50 nm.
The ball mill is a bedroom planetary ball mill with model PBM-40 produced by crystallizing industrial and mechanical Co, in which a zirconia ball milling tank and zirconia balls with diameter of 6mm are used for ball milling.
Example 1
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mineral ceramic balls are arranged in the filter element shell 1, and the end surface shell cover plate 2 is firmly welded by ultrasonic waves. The end surfaces of the shell 1 and the shell cover plate 2 are respectively provided with water through holes with equal diameter distribution, the shell 1 filled with the mineral ceramic balls is placed in the spraying bottle 3, the drinking purified water obtained in the step (1) is poured into the spraying bottle 3, and the water with the novel beautifying and makeup removing functions is obtained after soaking for 3 hours.
Example 2
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral ball is a terahertz ceramic mineral ball.
Example 3
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral balls are MPH + ceramic mineral balls.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller machine;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the cuticle obtained in the step (2) into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material ball ratio of 1:3, and performing ball milling for 22 hours to obtain ball milling slurry;
(4) and drying the ball-milling slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
Example 4
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral sphere MPH + ceramic mineral sphere.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of modified medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the cuticle obtained in the step (2) into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material ball ratio of 1:3, and performing ball milling for 22 hours to obtain ball milling slurry;
(4) and drying the ball-milling slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
The modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 4 wt%100 parts of hydrochloric acid were mixed, and the mixture was stirred at 45 ℃ at 80 rpm for 30 minutes, centrifuged at 5000 rpm for 30 minutes, and the obtained precipitate was washed with water until no Cl was detected in the wash with 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is cerium oxide.
Example 5
Essentially the same as example 4, except that:
the modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 100 parts of 4 wt% hydrochloric acid, stirring at 45 deg.C at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl in the washing solution is detected by 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is zirconia.
Example 6
Essentially the same as example 4, except that:
the modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 100 parts of 4 wt% hydrochloric acid, stirring at 45 deg.C at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl in the washing solution is detected by 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is titanium oxide.
Example 7
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral balls are MPH + ceramic mineral balls.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of modified medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the cuticle obtained in the step (2) and 0.03 part of lanthanum titanate into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material-ball ratio of 1:3, and performing ball milling for 22 hours to obtain ball milling slurry;
(4) and drying the ball-milling slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
The modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing medical stone powder 8 weight parts with100 parts of 4 wt% hydrochloric acid, followed by stirring at 45 ℃ at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl is detected in the washing solution with 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is cerium oxide.
Example 8
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral balls are MPH + ceramic mineral balls.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of modified medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the horny layer obtained in the step (2) and 0.03 part of lanthanum titanate into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material-ball ratio of 1:3, adding 3 parts of 10 wt% modifier aqueous solution after ball milling for 20 hours, and continuing ball milling for 2 hours to obtain ball milling slurry;
(4) heating the ball-milling slurry to 70 ℃, stirring for 2 hours at 70 ℃ at 200 rpm to obtain modified slurry, drying the modified slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
The modifier is N-sodium lauroyl sarcosine.
The modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 100 parts of 4 wt% hydrochloric acid, stirring at 45 deg.C at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl in the washing solution is detected by 0.1mol/L silver nitrate solution-The obtained precipitate is pre-precipitatedTreating medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is cerium oxide.
Example 9
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral balls are MPH + ceramic mineral balls.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of modified medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the horny layer obtained in the step (2) and 0.03 part of lanthanum titanate into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material-ball ratio of 1:3, adding 3 parts of 10 wt% modifier aqueous solution after ball milling for 20 hours, and continuing ball milling for 2 hours to obtain ball milling slurry;
(4) heating the ball-milling slurry to 70 ℃, stirring for 2 hours at 70 ℃ at 200 rpm to obtain modified slurry, drying the modified slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
The modifier is sodium caprylic/capric acyl oat amino acid.
The modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 100 parts of 4 wt% hydrochloric acid, stirring at 45 deg.C at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl in the washing solution is detected by 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is cerium oxide.
Example 10
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral balls are MPH + ceramic mineral balls.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of modified medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the horny layer obtained in the step (2) and 0.03 part of lanthanum titanate into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material-ball ratio of 1:3, adding 3 parts of 10 wt% modifier aqueous solution after ball milling for 20 hours, and continuing ball milling for 2 hours to obtain ball milling slurry;
(4) heating the ball-milling slurry to 70 ℃, stirring for 2 hours at 70 ℃ at 200 rpm to obtain modified slurry, drying the modified slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
The modifier is a mixture of N-sodium lauroyl sarcosinate and sodium caprylocaproyl and capric acid oat amino acid, and the mass ratio of the N-sodium lauroyl sarcosinate to the sodium caprylocaproyl and capric acid oat amino acid is 1: 3.
specifically, a 10 wt% of sodium lauroyl sarcosinate aqueous solution and a 10 wt% of decanoic acid acyl oat amino acid sodium aqueous solution are mixed according to the mass ratio of 1:3 and stirring at 100 rpm for 10 minutes to obtain a 10 wt% aqueous solution of the modifier.
The modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 100 parts of 4 wt% hydrochloric acid, stirring at 45 deg.C at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl in the washing solution is detected by 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is cerium oxide.
Example 11
A preparation method of water with novel beautifying and makeup removing functions comprises the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: 10, soaking for 3 hours, and filtering by adopting 200-mesh filter cloth to obtain the water with the novel beautifying and makeup removing functions.
The mineral balls are terahertz ceramic mineral balls and MPH + ceramic mineral balls according to a mass ratio of 1: 1.
The MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.5 part of adhesive into 15 parts of water, stirring for 15 minutes at 80 ℃ at 200 rpm to obtain an adhesive solution, mixing 30 parts of albite, 20 parts of pretreated shell powder, 15 parts of modified medical stone powder, 15 parts of zeolite powder, 10 parts of tourmaline powder and 10 parts of zinc oxide, stirring for 50 minutes at 800 rpm to obtain mixed powder, adding the adhesive solution into the mixed powder, stirring for 2 hours at 800 rpm to obtain mixed slurry, and processing the mixed slurry into spherical particles with the diameter of 4mm by a ball roller;
(2) drying the spherical particles at 45 ℃ for 3 hours, then putting the dried spherical particles into a sintering furnace, heating to 350 ℃ at a speed of 10 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 700 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 25 minutes, heating to 1050 ℃ at a speed of 20 ℃/min, carrying out heat preservation sintering for 2 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls.
The adhesive is sodium alginate.
The pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.5mm coarse powder;
(2) mixing 8 parts of shell coarse powder and 25 parts of 5 wt% sodium carbonate aqueous solution, stirring at 200 revolutions per minute for 50 minutes, standing for 6 hours, stirring at 800 revolutions per minute for 30 minutes, filtering by using 100-mesh filter cloth, washing a filter cake for 2 times by using 25 parts of water, and drying at 110 ℃ for 3 hours to obtain the shell coarse powder with the horny layer removed;
(3) putting the shell coarse powder without the horny layer obtained in the step (2) and 0.03 part of lanthanum titanate into a ball milling tank for ball milling, adding 8 parts of ethanol as a ball milling medium at a ball milling speed of 450 rpm by adopting zirconia balls with a material-ball ratio of 1:3, adding 3 parts of 10 wt% modifier aqueous solution after ball milling for 20 hours, and continuing ball milling for 2 hours to obtain ball milling slurry;
(4) heating the ball-milling slurry to 70 ℃, stirring for 2 hours at 70 ℃ at 200 rpm to obtain modified slurry, drying the modified slurry at 90 ℃, grinding, and sieving with a 800-mesh sieve to obtain the pretreated shell powder.
The shell is mussel shell.
The modifier is a mixture of N-sodium lauroyl sarcosinate and sodium caprylocaproyl and capric acid oat amino acid, and the mass ratio of the N-sodium lauroyl sarcosinate to the sodium caprylocaproyl and capric acid oat amino acid is 1: 3.
the modified medical stone powder is prepared by the following method, wherein the parts are all by weight:
(1) mixing 8 parts of medical stone powder and 100 parts of 4 wt% hydrochloric acid, stirring at 45 deg.C at 80 rpm for 30 minutes, centrifuging at 5000 rpm for 30 minutes, washing the obtained precipitate with water until no Cl in the washing solution is detected by 0.1mol/L silver nitrate solution-The obtained precipitate is pretreated medical stone powder;
(2) heating the pretreated medical stone powder to 250 ℃ at a speed of 10 ℃/min, preserving heat for 3.5 hours at the temperature of 250 ℃, naturally cooling to room temperature along with a furnace, grinding, and sieving with a 800-mesh sieve to obtain the thermally modified medical stone;
(3) mixing 6 parts of thermally modified medical stone with 50 parts of water, adding 0.1 part of sodium hexametaphosphate, stirring at 70 ℃ at 80 rpm for 15 minutes, adding 0.01 part of metal oxide, stirring at 70 ℃ at 80 rpm for 8 minutes, stirring at 25 ℃ at 80 rpm for 25 minutes, standing for 50 minutes, centrifuging at 5000 rpm for 30 minutes, washing a lower-layer precipitate with 50 parts of water for 2 times, drying at 90 ℃ for 6 hours, grinding, and sieving with a 800-mesh sieve to obtain the modified medical stone powder.
The metal oxide is cerium oxide.
Test example 1
The far infrared emissivity of the MPH + ceramic mineral spheres prepared in examples 3 to 10 at 25 ℃ was measured using an IR-2 type two-band emissivity measuring instrument manufactured by shanghai honest wave photoelectric technology science and technology ltd, and the measurement range was 8 to 14 μm, and the specific results are shown in table 1.
Table 1 table of far infrared emissivity test results
| Far infrared emissivity | |
| Example 3 | 0.76 |
| Example 4 | 0.81 |
| Example 5 | 0.78 |
| Example 6 | 0.77 |
| Example 7 | 0.84 |
| Example 8 | 0.86 |
| Example 9 | 0.87 |
| Example 10 | 0.93 |
Test example 2
The pH of the novel beauty and makeup removing water prepared in examples 2 to 11 was measured, and the specific test results are shown in table 2.
Taking 0.6mL of water with novel beautifying and makeup removing functions in a nuclear magnetic tube, and passing through an analysis and test center of a university of Compound denier17The full width at half maximum of the nuclear magnetic resonance measurement lines of the water with the novel beautifying and makeup removing functions prepared in the examples 1 to 10 are measured by an O NMR nuclear magnetic resonance method, and specific results are shown in a table 2.
TABLE 2 pH and NMR test results of water for novel beauty and makeup removal
The water with the novel beautifying and makeup removing functions contains various mineral substances beneficial to human bodies, and can carry out hydrolysis reaction on the water, so that the pH value of the water is changed from weak acidity to weak alkalinity. Meanwhile, the molecular group of the water with the novel beautifying and makeup removing functions prepared by the invention is obviously reduced, so that the water has excellent permeability and solubility and good makeup removing effect.
Test example 3
The makeup removing effect of the water for the novel makeup beautifying and removing functions obtained in examples 2 to 11 was tested.
The specific test method is as follows: the test population was 200 women between 20-40 years of age with healthy skin and no history of allergies. The subjects were divided into 10 groups of 20 persons each, and the makeup removal effect was evaluated for 7 days after the face of the subjects was made up with the same makeup cosmetic and then wiped off with water having the novel makeup-removing functions of examples 2 to 11, respectively, with the following evaluation criteria:
remarkably: the makeup is removed completely, and no residue is left after the face is wiped.
In general: slight residue remained after makeup removal.
None: no makeup removal effect.
The specific results are shown in Table 3.
Table 3 test result table of water makeup removal effect of novel beauty and makeup removal function
Claims (7)
1. A preparation method of water with functions of beautifying and removing makeup is characterized by comprising the following steps:
(1) taking purified water for drinking;
(2) mineral ball activation: mixing drinking purified water and mineral balls according to a mass ratio of 100: (5-30) mixing, soaking for 2-4 hours, and filtering to obtain water with the functions of beautifying and removing makeup;
the mineral balls are terahertz ceramic mineral balls and/or MPH + ceramic mineral balls;
the MPH + ceramic mineral ball is prepared by the following method, wherein the parts are all by weight:
(1) adding 0.2-2 parts of adhesive into 10-20 parts of water, stirring for 10-20 minutes at 75-85 ℃ at 300 revolutions/minute of 100-;
(2) drying the spherical particles at 40-50 ℃ for 2-4 hours, then placing the spherical particles into a sintering furnace, heating to 400 ℃ at 8-12 ℃/min, carrying out heat preservation sintering for 20-30 minutes, heating to 750 ℃ at 15-25 ℃/min, carrying out heat preservation sintering for 20-30 minutes, heating to 1100 ℃ at 15-25 ℃/min, carrying out heat preservation sintering for 1-3 hours, and cooling to room temperature along with the furnace to obtain the MPH + ceramic mineral balls;
the adhesive is one or a mixture of sodium alginate, polyvinyl alcohol and sodium carboxymethylcellulose;
the pretreatment shell powder is prepared by the following method, wherein the parts are all by weight:
(1) cleaning shell, removing impurities, draining off surface water, and pulverizing into 0.1-1mm coarse powder;
(2) mixing 5-10 parts of shell coarse powder and 20-30 parts of 3-8 wt% sodium carbonate aqueous solution, stirring for 40-60 minutes at 100-;
(3) putting the shell coarse powder without the horny layer obtained in the step (2) and 0.01-0.05 part of lanthanum titanate into a ball milling tank for ball milling, adding 5-10 parts of ethanol as a ball milling medium, wherein the ball milling rotation speed is 400-600 rpm, adding 1-5 parts of 8-12 wt% modifier aqueous solution after ball milling for 15-25 hours, and continuing ball milling for 1-3 hours to obtain ball milling slurry;
(4) heating the ball milling slurry to 60-80 ℃, stirring for 1-3 hours at 60-80 ℃ at 100-.
2. The method for preparing water with skin beautifying and makeup removing functions according to claim 1, wherein the modifier is sodium N-lauroyl sarcosinate and/or sodium caprylocamphetamine.
3. The method for preparing water with the functions of beautifying and removing makeup according to claim 2, wherein the modifier is a mixture of sodium N-lauroyl sarcosinate and sodium caprylocatanoyl avenantamino acid, and the mass ratio of the sodium N-lauroyl sarcosinate to the sodium caprylocatanoyl avenantamino acid is 1: (1-5).
4. The method for preparing water with skin caring and makeup removing effects according to claim 1, wherein the shell is one or more of mussel shell, scallop shell, oyster shell, and flower shell.
5. The method for preparing water with the functions of beautifying and removing makeup according to claim 1, wherein the modified medical stone powder is prepared by the following method, wherein the parts are all in parts by weight:
(1) mixing 5-10 parts of medical stone powder and 80-120 parts of 3-5 wt% hydrochloric acid, stirring at 60-100 rpm for 20-40 minutes at 40-50 ℃, centrifuging at 4000-;
(2) heating the pretreated medical stone powder to 200-300 ℃ at the speed of 8-12 ℃/min, preserving the heat for 3-4 hours at the temperature of 200-300 ℃, naturally cooling to room temperature along with the furnace, and grinding to obtain the thermally modified medical stone;
(3) mixing 4-8 parts of thermally modified medical stone with 40-60 parts of water, adding 0.05-0.2 part of sodium hexametaphosphate, stirring at 60-80 ℃ for 10-20 minutes at 60-100 revolutions per minute, adding 0.01 part of metal oxide, stirring at 60-80 ℃ for 5-10 minutes at 60-100 revolutions per minute, stirring at 20-30 ℃ for 20-30 minutes, standing for 40-60 minutes, separating the core at 5000 revolutions per minute for 20-30 minutes, washing the lower-layer precipitate with 40-60 parts of water for 1-3 times, and drying at 80-100 ℃ for 4-8 hours to obtain the modified medical stone powder;
the metal oxide is one of cerium oxide, zirconium oxide and titanium oxide.
6. The method for preparing water for beauty and makeup removal according to claim 5, wherein said metal oxide is cerium oxide.
7. A water for beautifying and removing makeup, characterized by being prepared by the method of any one of claims 1 to 6.
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