CN109181392A - A kind of high dissolving power varnish thinner of environment-friendly type - Google Patents

A kind of high dissolving power varnish thinner of environment-friendly type Download PDF

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Publication number
CN109181392A
CN109181392A CN201810663493.5A CN201810663493A CN109181392A CN 109181392 A CN109181392 A CN 109181392A CN 201810663493 A CN201810663493 A CN 201810663493A CN 109181392 A CN109181392 A CN 109181392A
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CN
China
Prior art keywords
varnish
environment
dissolving power
high dissolving
friendly type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810663493.5A
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Chinese (zh)
Inventor
周思思
周琰
张祥功
李磊
代化
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Original Assignee
Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC filed Critical Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Priority to CN201810663493.5A priority Critical patent/CN109181392A/en
Publication of CN109181392A publication Critical patent/CN109181392A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of high dissolving power varnish thinner of environment-friendly type, the component raw material including following mass percent: propene carbonate (PC) 20%-60%, ethyl methyl carbonate (EMC) 10%-30%, 1,3-dioxolane 20%-50%, cucurbitacin b 0.01%-5%;The present invention has high dissolving power for varnish, varnish basement membrane mixed liquor containing the diluent can volatilize rapidly when metope coating prepares wallpaper basement membrane, the not remaining chemical component to human body poisonous and harmful substances in metope, it is a kind of Green environment-friendlydiluent diluent that totally nontoxic is harmless, can be used in mixed way with paints, additives such as other varnish thinners, essence.

Description

A kind of high dissolving power varnish thinner of environment-friendly type
Technical field
The present invention relates to coating organic solvent system, specifically a kind of environment-friendly type highly dissoluble varnish thinner.
Background technique
With the enhancing of science and technology being constantly progressive with the environmental consciousness of people, instantly to interior decoration ecological requirements It is increasingly enhanced.
During house decoration, pasting wallpaper in metope is a kind of common economical and practical decorating scheme.But Preparing in environment for wallpaper is pasted, the process of production metope varnish basement membrane, which is often difficult to avoid that, introduces the strong cause such as phenyl, phenol, aldehyde radical Harmful organic principle of cancer.
The harmful components that environment-friendly lacquer itself contains can evaporate into national safety standard in one week, but it is making wall A large amount of varnish thinners must be mixed into when the basement membrane of face, and traditional varnish thinner often contains formaldehyde, stupid, toluene etc. to human body The carcinogenic ingredient of intoxicating, and deeply infiltrated inside wall after being combined with wall, rate of release is very slow, and it is complete to paste wallpaper At in latter 1 to 2 years, pasting the ingredient that still can detect toxic gas in the room of wallpaper.
Many carbonate-based solvents, cyclic ether solvents evaporation rate are fast, but wherein low toxicity or nontoxic ingredient often with Varnish can not be compatible well, and sedimentation layering is easy to happen after mixing, can not use as wall basement membrane diluent.
Summary of the invention
In order to avoid conventional varnish diluent is polluted caused by wall, the present invention provides a kind of environment-friendly type highly dissolubles Organic diluent.
The technical solution adopted by the present invention to solve the technical problems is: a kind of high dissolving power varnish thinner of environment-friendly type, It must at least while include the component raw material of following mass percent: propene carbonate (PC) 20%-60%, ethyl methyl carbonate (EMC) 10%-30%, 1,3-dioxolane 20%-50%, cucurbitacin b 0.01%-5%.
Further, it is necessary to while the component raw material including following mass percent: propene carbonate 35%-60%, carbonic acid second Base methyl esters 20%-25%, 1,3-dioxolane 24%-40%, cucurbitacin b are 1%-5%.
The beneficial effects of the present invention are:
The present invention has high dissolving power for varnish, and the varnish basement membrane mixed liquor containing the diluent prepares wallpaper in metope coating It can volatilize rapidly when basement membrane, the not remaining chemical component to human body poisonous and harmful substances in metope, is that a kind of totally nontoxic is harmless Green environment-friendlydiluent diluent, can be used in mixed way with paints, additives such as other varnish thinners, essence.
Formaldehyde, benzene and benzene-series harmful toxic matter are entirely free of in present component, it can be sufficiently mixed with common lacquer materials Dissolution is closed, manufactured wall basement membrane can bond wallpaper immediately, and all organic solvents in room is made to volatilize completely in one week To 1 grade of architecture indoor standard≤0.5(mg/m3 of country) range.
Specific embodiment
Below with reference to embodiment, the present invention is further described in detail, but is not intended to limit guarantor of the invention Protect range.
Embodiment 1
The present embodiment is used to illustrate the preparation and its function of diluent provided by the invention.
A kind of high dissolving power varnish thinner of environment-friendly type, the component raw material including following mass percent: propene carbonate (PC) 35%, ethyl methyl carbonate (EMC) 20%, 1,3-dioxolane 40%, cucurbitacin b is 5%.
The configuration method of the above-mentioned high dissolving power solvent compositions of environment-friendly type is such as:
(1) component solvent and ingredient are measured according to mass ratio.
(2) in the environment of ventilation, the raw material of each component is sufficiently mixed, then by mixture and varnish in mass ratio one Than a mixing, it is uniformly mixing to obtain finished product.
(2) configured mixed liquor is coated in four sides inside the gypsum box that volume is 1 cubic metre and fills one layer, in gypsum box After closing, parallel two sides, opens one 1 cubic decimeter of square in the middle on two sides respectively in optional six face of cube Notch, and make the completely corresponding coincidence of the notch, ventilation situation when simulating finishing in room.
TVOC detector is put into above-mentioned gypsum box after 10 hours, blend rubber piece blocks above-mentioned notch, passes through network The TVOC detector in gypsum box is connected, the numerical value of TVOC after sealing 8 hours is read, is denoted as A1.
Embodiment 2
The present embodiment is used to illustrate the preparation and its function of diluent provided by the invention.
A kind of high dissolving power varnish thinner of environment-friendly type, the component raw material including following mass percent: propene carbonate (PC) 50%, ethyl methyl carbonate (EMC) 25%, 1,3-dioxolane 24%, cucurbitacin b is 1%.
The configuration method of the above-mentioned high dissolving power solvent compositions of environment-friendly type is such as:
(1) component solvent and ingredient are measured according to mass ratio.
(2) in the environment of ventilation, the raw material of each component is sufficiently mixed, then will be clear used in mixture and embodiment 1 In mass ratio one to one mixing of paint, is uniformly mixing to obtain finished product.
(2) configured mixed liquor is coated in four sides inside the gypsum box that volume is 1 cubic metre and fills one layer, in gypsum box After closing, parallel two sides, opens one 1 cubic decimeter of square in the middle on two sides respectively in optional six face of cube Notch, and make the completely corresponding coincidence of the notch, ventilation situation when simulating finishing in room.
TVOC detector is put into above-mentioned gypsum box after 10 hours, blend rubber piece blocks above-mentioned notch, passes through network The TVOC detector in gypsum box is connected, the numerical value of TVOC after sealing 8 hours is read, is denoted as A2.
Comparative example 1
The present embodiment is used to illustrate the preparation and its function of diluent provided by the invention.
Volume is coated in after the varnish thinner of commodity is mixed with varnish used in embodiment 1 in mass ratio 1 to 1 to stand for 1 Four sides fills one layer inside the gypsum box of square rice, and after the closing of gypsum box, in optional six face of cube parallel two sides, two One 1 cubic decimeter of square notch is opened in the middle in face respectively, and makes the completely corresponding coincidence of the notch, to simulate dress Ventilation situation when repairing in room.
TVOC detector is put into above-mentioned gypsum box after 10 hours, blend rubber piece blocks above-mentioned notch, passes through network The TVOC detector in gypsum box is connected, the numerical value of TVOC after sealing 8 hours is read, is denoted as A3.
After basement membrane is made in three kinds of mixed liquors, after volatilizing 10 hours in identical environment, then TVOC measured by closed 8 hours Content balance table it is as follows:
Mixed liquor type TVOC residual volume (mg/m3)
A1 0.12
A2 0.10
A3 19.00
As can be seen from the table, the mixed liquor evaporation rate made by the diluent of embodiment 1 and embodiment 2 containing varnish Fastly, when the varnish mixing of commercial simple diluents also severely exceeds, TVOC residual volume reaches the TVOC safety of 1 grade of building of country Standard, so that the process of wallpaper is more accelerated, and environmentally protective.
Above-described specific embodiment has carried out further the purpose of the present invention, technical scheme and beneficial effects It is described in detail, it should be understood that being not intended to limit the present invention the foregoing is merely a specific embodiment of the invention Protection scope, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include Within protection scope of the present invention.

Claims (2)

1. a kind of high dissolving power varnish thinner of environment-friendly type, it is characterised in that: the component raw material including following mass percent
Propene carbonate 20%-60%
Ethyl methyl carbonate 10%-30%
1,3- dioxolanes 20%-50%
Cucurbitacin b 0.01%-5%.
2. the high dissolving power varnish thinner of a kind of environment-friendly type according to claim 1, which is characterized in that including following quality The component raw material of percentage:
Propene carbonate 35%-60%
Ethyl methyl carbonate 20%-25%
1,3- dioxolanes 24%-40%
Cucurbitacin b is 1%-1.5%.
CN201810663493.5A 2018-06-25 2018-06-25 A kind of high dissolving power varnish thinner of environment-friendly type Pending CN109181392A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810663493.5A CN109181392A (en) 2018-06-25 2018-06-25 A kind of high dissolving power varnish thinner of environment-friendly type

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810663493.5A CN109181392A (en) 2018-06-25 2018-06-25 A kind of high dissolving power varnish thinner of environment-friendly type

Publications (1)

Publication Number Publication Date
CN109181392A true CN109181392A (en) 2019-01-11

Family

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Application Number Title Priority Date Filing Date
CN201810663493.5A Pending CN109181392A (en) 2018-06-25 2018-06-25 A kind of high dissolving power varnish thinner of environment-friendly type

Country Status (1)

Country Link
CN (1) CN109181392A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101529531A (en) * 2006-10-25 2009-09-09 拜尔材料科学股份公司 Aqueous silver-containing formulations and their use for producing conductive or reflective coatings
CN105102532A (en) * 2013-02-27 2015-11-25 太阳化学公司 Polyvinyl alcohol and ethylene vinyl alcohol copolymer barrier coatings
CN106687540A (en) * 2014-04-17 2017-05-17 富士胶片亨特化学制品美国有限公司 Low toxicity solvent system for polyamideimide and polyamide amic acid resin coating
CN106752253A (en) * 2016-11-24 2017-05-31 天津市汇合科技开发有限公司 A kind of environment-friendly type dissolving power solvent compositions high
US20170253777A1 (en) * 2013-11-13 2017-09-07 R.R. Donnelley & Sons Company Electrolyte material composition and method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101529531A (en) * 2006-10-25 2009-09-09 拜尔材料科学股份公司 Aqueous silver-containing formulations and their use for producing conductive or reflective coatings
CN105102532A (en) * 2013-02-27 2015-11-25 太阳化学公司 Polyvinyl alcohol and ethylene vinyl alcohol copolymer barrier coatings
US20170253777A1 (en) * 2013-11-13 2017-09-07 R.R. Donnelley & Sons Company Electrolyte material composition and method
CN106687540A (en) * 2014-04-17 2017-05-17 富士胶片亨特化学制品美国有限公司 Low toxicity solvent system for polyamideimide and polyamide amic acid resin coating
CN106752253A (en) * 2016-11-24 2017-05-31 天津市汇合科技开发有限公司 A kind of environment-friendly type dissolving power solvent compositions high

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Application publication date: 20190111