CN108948879A - A kind of PE ordor removing transparent priming and preparation method thereof - Google Patents
A kind of PE ordor removing transparent priming and preparation method thereof Download PDFInfo
- Publication number
- CN108948879A CN108948879A CN201810902995.9A CN201810902995A CN108948879A CN 108948879 A CN108948879 A CN 108948879A CN 201810902995 A CN201810902995 A CN 201810902995A CN 108948879 A CN108948879 A CN 108948879A
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- Prior art keywords
- parts
- agent
- ordor removing
- good
- transparent priming
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of PE ordor removing transparent primings, it is characterized in that, according to the mass fraction, including the following raw material: 40-60 parts of PE resin, 0.1-0.5 parts of dispersing agent, 0.1-0.5 parts of defoaming agent, 0.1-0.5 parts of PE anti-greening agent, 0.1-0.5 parts of fumed silica, 20-40 parts of talcum powder, 5-15 parts of transparent powder, 1-5 parts of zinc stearate, 0.1-0.5 parts of levelling agent, 3-6 parts of toluene.Products of the present invention comprehensive performance is good, has good levelability and adhesive force, and plate face texture is good, and richness is good, and clarity is high, and paint film contains the ordor removing factor, and paint film residual smell is extremely low after drying；Sanding property is good, gloss is low.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of PE ordor removing transparent priming and preparation method thereof.
Background technique
PE paint, i.e. unsaturated polyester varnish, are mutually concocted by host agent, promotor, initiator three and carry out polymerization bridging reaction
And solidify, solvent is styrene, and reaction is participated in when film forming.Compared with solvent type woodcare paint, PE paint the advantages of be to have
" 100% respond ", it means that liquid composition can be under the action of initiator, and no by-product releases and energy
It is completely reformed into solid polymer.The comprehensive performance of PE paint is high, it is wear-resisting, heat-resisting, corrosion-resistant, in terms of with PU paint phase
When, hardness, richness, transparency, in terms of be better than other coating.But after solvent paint needs a large amount of solvent volatilizations,
Paint film could be formed, such paint film is hard unlike forming resin solidification, and the volatilization of solvent causes certain ring
Border pollution, and the damage of health is also brought to construction personnel.
On the other hand, the limitation of existing unsaturated polyester (UP) priming paint Seal property as used by it cause closure,
Resist sagging and polishing limited time, in particular for without Seal treatment or the bad low-density medium density fiberboard of Seal treatment, this
Significant limitation is brought to the construction and performance of furniture coating.
In consideration of it, how to produce the PE transparent priming that integrated application is had excellent performance, smell is low, grinability is good is this field
One important research topic.
Summary of the invention
In order to overcome the defect of the prior art and product, the object of the present invention is to provide a kind of PE ordor removing transparent priming and its
Preparation method.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of PE ordor removing transparent priming, which is characterized in that according to the mass fraction, including the following raw material: PE resin 40-60
Part, 0.1-0.5 parts of dispersing agent, 0.1-0.5 parts of defoaming agent, 0.1-0.5 parts of PE anti-greening agent, 0.1-0.5 parts of fumed silica,
20-40 parts of talcum powder, 5-15 parts of transparent powder, 1-5 parts of zinc stearate, 0.1-0.5 parts of levelling agent, 3-6 parts of toluene.
Including the following raw material preferably, according to the mass fraction: 51 parts of PE resin, 0.1 part of dispersing agent, 0.2 part of defoaming agent,
0.1 part of the anti-greening agent of PE, 0.2 part of fumed silica, 32 parts of talcum powder, 10 parts of transparent powder, 2 parts of zinc stearate, levelling agent 0.1
Part, 4.3 parts of toluene.
Preferably, the dispersing agent is one of EFKA4010, BYK104, EFKA 8605, BYK164.
Preferably, the defoaming agent is one of BYK-A-555, BYK8801, EFKA2720, BYK055.
Preferably, the levelling agent is one of BYK358N, DEG0450, HX3130, EFKA3777.
Preferably, the anti-greening agent of the PE is one of JU-010 or BF-10.
A kind of preparation method of PE ordor removing transparent priming, which comprises the steps of:
(1) by PE resin, dispersing agent, defoaming agent, the anti-greening agent of PE and fumed silica, turn lower mixing in 800-1200
Dispersion 3-10 minutes；
(2) talcum powder and transparent powder are added under stiring, is dispersed to fineness≤55 μm in the case where 1000-1500 turns；
(3) zinc stearate is added under stiring, turns lower dispersion 1-5 minutes in 800-1200；
(4) levelling agent and toluene are added under stiring, 500-1000 turn lower dispersion 3-5 minutes to get.
Preferably, dispersion temperature≤55 DEG C of step (2).
This law it is bright the utility model has the advantages that
(1) there is good levelability and adhesive force, plate face texture is good, and richness is good, and clarity is high.
(2) paint film contains the ordor removing factor, and paint film residual smell is extremely low after drying.
(3) sanding property is good, gloss is low.
(4) comprehensive performance is good, can be widely used for the transparent effects such as office furniture, hotel, craftwork, cabinet, stair wood
Furniture primer painting processed.
Specific embodiment
The present invention is described further combined with specific embodiments below:
The number of the raw material of following embodiment refers both to parts by weight.
Embodiment 1
The preparation of PE ordor removing transparent priming
Raw material: 51 parts of PE resin, 0.1 part of EFKA4010,0.2 part of BYK-A-555,0.1 part of JU-010, gas phase dioxy
0.2 part of SiClx, 32 parts of talcum powder, 10 parts of transparent powder, 2 parts of zinc stearate, 0.1 part of BYK358N, 4.3 parts of toluene.
Preparation step:
(1) by PE resin, dispersing agent, defoaming agent, the anti-greening agent of PE and fumed silica, dispersion is mixed under 1000 turns
5 minutes；
(2) talcum powder and transparent powder are added under stiring, fineness≤55 μm, dispersion temperature 55 are dispersed under 1200 turns
℃；
(3) zinc stearate is added under stiring, disperses 3 minutes under 1000 turns；
(4) levelling agent and toluene are added under stiring, disperse under 800 turns 4 minutes to get.
Embodiment 2
The preparation of PE ordor removing transparent priming
Raw material: 60 parts of PE resin, 0.1 part of BYK104,0.5 part of BYK8801,0.1 part of BF-10, fumed silica
0.5 part, 40 parts of talcum powder, 5 parts of transparent powder, 5 parts of zinc stearate, 0.1 part of DEG0450,6 parts of toluene.
Preparation step:
(1) by PE resin, dispersing agent, defoaming agent, the anti-greening agent of PE and fumed silica, dispersion is mixed under 800 turns
10 minutes；
(2) talcum powder and transparent powder are added under stiring, fineness≤55 μm, dispersion temperature 50 are dispersed under 1000 turns
℃；
(3) zinc stearate is added under stiring, disperses 1 minute under 1200 turns；
(4) levelling agent and toluene are added under stiring, disperse under 1000 turns 3 minutes to get.
Embodiment 3
The preparation of PE ordor removing transparent priming
Raw material: 40 parts of PE resin, 8,605 0.5 parts of EFKA, 0.1 part of EFKA2720,0.5 part of BF-10, gas phase titanium dioxide
0.1 part of silicon, 20 parts of talcum powder, 15 parts of transparent powder, 1 part of zinc stearate, 0.5 part of HX3130,3 parts of toluene.
Preparation step:
(1) by PE resin, dispersing agent, defoaming agent, the anti-greening agent of PE and fumed silica, dispersion is mixed under 1200 turns
3 minutes；
(2) talcum powder and transparent powder are added under stiring, fineness≤55 μm, dispersion temperature 45 are dispersed under 1500 turns
℃；
(3) zinc stearate is added under stiring, disperses 5 minutes under 800 turns；
(4) levelling agent and toluene are added under stiring, disperse under 500 turns 5 minutes to get.
Embodiment 4
The preparation of PE ordor removing transparent priming
Raw material: 50 parts of PE resin, 0.3 part of BYK164,0.4 part of BYK055,0.3 part of BF-10, fumed silica 0.3
Part, 30 parts of talcum powder, 10 parts of transparent powder, 2 parts of zinc stearate, 0.3 part of EFKA3777,4 parts of toluene.
Preparation step:
(1) by PE resin, dispersing agent, defoaming agent, the anti-greening agent of PE and fumed silica, the mixing dispersion 6 under 900 turns
Minute；
(2) talcum powder and transparent powder are added under stiring, fineness≤55 μm, dispersion temperature 50 are dispersed under 1400 turns
℃；
(3) zinc stearate is added under stiring, disperses 3 minutes under 1100 turns；
(4) levelling agent and toluene are added under stiring, disperse under 700 turns 4 minutes to get.
Performance test
The embodiment 1-4 product prepared is tested for the property, as a result as follows:
Detailed construction technique are as follows: openpore polishing-brush closing-polishing-PE transparent priming-polishing-PE transparent priming-
Polishing-finishing coat.Construction temperature is 25 DEG C, humidity 75%.Diluent is DEX906L, mixing ratio 5:2.Comparative example is this
The DED3050D priming paint of company's production.
| Test index | Embodiment 1 | Embodiment 2# | Embodiment 3# | Embodiment 4# | Comparative example |
| Gloss (%) | 29 | 30 | 32 | 32 | 51 |
| Feel | Preferably | Preferably | Preferably | Preferably | Preferably |
| Levelability | It is good | It is good | It is good | It is good | Well |
| Grinability (h) | 8 | 8 | 8 | 8 | 5 |
| Smell | It is very low | It is very low | It is very low | It is very low | It is low |
| Surface effect | It is good | It is good | It is good | It is good | Preferably |
| Rotary viscosity (mpa.s) | 30000 | 30000 | 30000 | 30000 | 30000 |
| Surface drying (min) | 39 | 40 | 40 | 40 | 40 |
| It does solid work (h) | 8 | 8 | 8 | 8 | 8 |
| Gu containing (%) | 83 | 85 | 81 | 81 | 80 |
| Fineness (μm) | 55 | 55 | 55 | 55 | 54 |
| Clarity | 8 | 8.1 | 8.3 | 8.1 | 7.5 |
As seen from the above table, present invention PE ordor removing transparent priming produced is pale yellow transparent thick liquid, comprehensive performance
Well, there is good levelability and adhesive force, plate face texture is good, and richness is good, and clarity is high, and rear smell is low for 24 hours for dry film, beats
Mill performance is good, gloss is low, meets state quality standard, and it is saturating to can be widely used for office furniture, hotel, craftwork, cabinet, stair etc.
Obvious results fruit tree furniture primer painting.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Belong to those skilled in the art in the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of, all answers
It is included within the scope of the present invention.
Claims (8)
1. a kind of PE ordor removing transparent priming, which is characterized in that according to the mass fraction, including the following raw material: 40-60 parts of PE resin,
0.1-0.5 parts of dispersing agent, 0.1-0.5 parts of PE anti-greening agent, 0.1-0.5 parts of fumed silica, is slided 0.1-0.5 parts of defoaming agent
20-40 parts of mountain flour, 5-15 parts of transparent powder, 1-5 parts of zinc stearate, 0.1-0.5 parts of levelling agent, 3-6 parts of toluene.
2. a kind of PE ordor removing transparent priming according to claim 1, which is characterized in that according to the mass fraction, including it is as follows
Raw material: 51 parts of PE resin, 0.2 part of defoaming agent, 0.1 part of the anti-greening agent of PE, 0.2 part of fumed silica, is slided 0.1 part of dispersing agent
32 parts of mountain flour, 10 parts of transparent powder, 2 parts of zinc stearate, 0.1 part of levelling agent, 4.3 parts of toluene.
3. a kind of PE ordor removing transparent priming according to claim 1 or 2, which is characterized in that the dispersing agent is
One of EFKA4010, BYK104, EFKA 8605, BYK164.
4. a kind of PE ordor removing transparent priming according to claim 1 or 2, which is characterized in that the defoaming agent is BYK-
One of A-555, BYK8801, EFKA2720, BYK055.
5. a kind of PE ordor removing transparent priming according to claim 1 or 2, which is characterized in that the levelling agent is
One of BYK358N, DEG0450, HX3130, EFKA3777.
6. a kind of PE ordor removing transparent priming according to claim 1 or 2, which is characterized in that the anti-greening agent of the PE is
One of JU-010 or BF-10.
7. a kind of preparation method of PE ordor removing transparent priming, which comprises the steps of:
(1) by PE resin, dispersing agent, defoaming agent, the anti-greening agent of PE and fumed silica, turn lower mixing dispersion in 800-1200
3-10 minutes；
(2) talcum powder and transparent powder are added under stiring, is dispersed to fineness≤55 μm in the case where 1000-1500 turns；
(3) zinc stearate is added under stiring, turns lower dispersion 1-5 minutes in 800-1200；
(4) levelling agent and toluene are added under stiring, 500-1000 turn lower dispersion 3-5 minutes to get.
8. a kind of preparation method of PE ordor removing transparent priming according to claim 7, which is characterized in that point of step (2)
Dissipate temperature≤55 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810902995.9A CN108948879A (en) | 2018-08-09 | 2018-08-09 | A kind of PE ordor removing transparent priming and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810902995.9A CN108948879A (en) | 2018-08-09 | 2018-08-09 | A kind of PE ordor removing transparent priming and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108948879A true CN108948879A (en) | 2018-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116694201A (en) * | 2023-07-04 | 2023-09-05 | 嘉宝莉化工集团股份有限公司 | Non-color-changing unsaturated polyester primer and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604516A (en) * | 2012-03-02 | 2012-07-25 | 上海嘉宝莉涂料有限公司 | Anti-greening PE (Polyethylene) transparent primer and preparation method thereof |
| CN104497813A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | Nitrocellulose-modified low-temperature quick-drying unsaturated polyester primer and preparation method thereof |
| CN107189648A (en) * | 2017-02-24 | 2017-09-22 | 江苏赛鑫树脂有限公司 | A kind of net taste PE primer resins and preparation method thereof |
-
2018
- 2018-08-09 CN CN201810902995.9A patent/CN108948879A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604516A (en) * | 2012-03-02 | 2012-07-25 | 上海嘉宝莉涂料有限公司 | Anti-greening PE (Polyethylene) transparent primer and preparation method thereof |
| CN104497813A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | Nitrocellulose-modified low-temperature quick-drying unsaturated polyester primer and preparation method thereof |
| CN107189648A (en) * | 2017-02-24 | 2017-09-22 | 江苏赛鑫树脂有限公司 | A kind of net taste PE primer resins and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116694201A (en) * | 2023-07-04 | 2023-09-05 | 嘉宝莉化工集团股份有限公司 | Non-color-changing unsaturated polyester primer and preparation method and application thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181207 |
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