CN109169689B - Plugging agent for preventing and treating Taurus tonsuratus as well as preparation method and application of plugging agent - Google Patents
Plugging agent for preventing and treating Taurus tonsuratus as well as preparation method and application of plugging agent Download PDFInfo
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- CN109169689B CN109169689B CN201811141457.9A CN201811141457A CN109169689B CN 109169689 B CN109169689 B CN 109169689B CN 201811141457 A CN201811141457 A CN 201811141457A CN 109169689 B CN109169689 B CN 109169689B
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- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 241001481710 Cerambycidae Species 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003906 humectant Substances 0.000 claims abstract description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004519 grease Substances 0.000 claims abstract description 11
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 11
- 239000002917 insecticide Substances 0.000 claims abstract description 10
- 239000002981 blocking agent Substances 0.000 claims abstract description 6
- 239000000575 pesticide Substances 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 241000607479 Yersinia pestis Species 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 229910052626 biotite Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 4
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 claims description 4
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 claims description 4
- 241000158728 Meliaceae Species 0.000 claims description 4
- 229930014456 matrine Natural products 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229940057995 liquid paraffin Drugs 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004495 emulsifiable concentrate Substances 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 13
- 241000353522 Earias insulana Species 0.000 abstract description 4
- 235000006040 Prunus persica var persica Nutrition 0.000 description 7
- 244000144730 Amygdalus persica Species 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 210000003608 fece Anatomy 0.000 description 4
- 206010015150 Erythema Diseases 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000002674 ointment Substances 0.000 description 3
- 241000545593 Scolytinae Species 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 210000003739 neck Anatomy 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 241000751139 Beauveria bassiana Species 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 241001635274 Cydia pomonella Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
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- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 230000013872 defecation Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G17/00—Cultivation of hops, vines, fruit trees, or like trees
- A01G17/005—Cultivation methods
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Botany (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Forests & Forestry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention relates to a plugging agent for preventing and treating Taurus nobilis, which comprises 800-1200 g of a filling agent, 180-200 ml of water, 15-21 ml of an insecticide, 180-200 ml of a humectant and 10-30 mg of lithium-based grease. The invention also relates to a preparation method and application of the plugging agent. The blocking agent has simple preparation method and excellent control effect and can effectively kill the pink-neck longicorn and other stem borers.
Description
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a plugging agent for preventing and treating Taurus mahogany, and a preparation method and application thereof.
Background
Peach is an important fruit tree and ornamental tree species, the longicorn with red neck is a destructive pest of the peach, the larva eats branches, phloem and xylem of the branches and the trunk, the transportation and conduction tissue of the tree is cut off, nutrient and moisture transportation is hindered, the tree vigor is weakened, the branches are dried, a large amount of sawdust-like insect manure is accumulated outside the moth holes, the damaged parts often generate gummosis, the yield and the quality of the fruit are greatly reduced, when the damage is serious, the whole tree is even withered, and the damage to the fruit tree and the forest and the urban garden greening is greatly threatened. In addition, the peach red-neck longicorn also harms the tree species such as apricot, plum, cherry, and the like.
The early-hatched larvae of the pink-neck longicorn are firstly eaten under the bark of the tree, then gradually eaten into the phloem, the marginal wood of the phloem and the xylem is damaged by eating upwards and downwards, the wormhole is flat, the boundary is not neat and is bent, the wormhole is full of the excrement, and part of the excrement is squeezed out from the wormhole holes and the cracks of the bark. When the larva grows about 3 cm in length, the larva enters xylem from the middle part of the gallery, eats towards medulla, turns around, eats upwards or downwards along xylem, forms a curved oval gallery, and the longest length can reach 75 cm.
The red peach-neck longicorn has hidden harm and long life history, generally finishes 1 generation in 2 years, and has great prevention and treatment difficulty. Larvae hidden under bark, phloem or xylem of a tree can be manually dug out or hooked by a spiral steel wire, but because the larvae are long and complicated in path, the larvae are not easy to clean and have low efficiency; natural enemies such as beauveria bassiana and pathogenic nematodes have a certain control effect on the pests, but the production, transportation, storage, reproduction and release of the natural enemies require harsh environmental conditions, the technical difficulty is high, and the application is inconvenient; high-concentration liquid medicine or ointment is filled into the moth holes, a certain prevention and treatment effect is achieved on larvae which are damaged on root necks or vertical trunks, however, as peach trees are mostly in the shape of open-heart trees, main branches are relatively flat, the larvae on the branches are prevented and treated, and particularly when the larvae which are damaged below the branches or inclined trunks are prevented and treated, the liquid medicine and the ointment are not easy to inject and easy to overflow, the drug effect is affected, wet mud is required to be used for plugging after drug injection, time and labor are wasted, and the prevention effect is not good.
Disclosure of Invention
The invention aims to provide a plugging agent for preventing and treating Taurus tonsuratus, which is simple to operate and excellent in prevention effect, and a preparation method and application thereof.
The invention adopts the following technical scheme:
a plugging agent for preventing and treating Taurus mahogany comprises 800-1200 g of a filler, 180-200 ml of water, 15-21 ml of an insecticide, 180-200 ml of a humectant and 10-30 mg of lithium-based grease.
Preferably, it includes 1000g of a filler, 190ml of water, 18ml of an insecticide, 190ml of a humectant, and 20mg of a lithium base grease.
Wherein the filler is one or two of bentonite or biotite.
Preferably, the filler is bentonite and biotite, and the mass ratio is 1: 1.
Wherein, the bentonite and the biotite in the filler are fine powder of 300 meshes to 400 meshes.
Preferably, the bentonite and the biotite in the filler are fine powder with 350 meshes.
The pesticide is more than one of 1% matrine soluble solution, 45% beta-cypermethrin emulsifiable solution and 25% alpha-chlorbenzuron suspending agent, and the percentages are mass percentages of the active ingredients.
Wherein the pesticide is 1% matrine soluble agent and 45% beta-cypermethrin emulsifiable concentrate with the volume ratio of 1: 2.
Wherein the humectant is one or two of liquid paraffin and glycerol.
Wherein the humectant is liquid paraffin and glycerol with the volume ratio of 1: 1.
The preparation method of the plugging agent for preventing and treating the pink-neck longicorn comprises the following steps:
(1) weighing the filling agent and the lithium-based grease, and weighing water, the insecticide and the humectant;
(2) adding water into the filler and then fully stirring;
(3) adding the pesticide into the mixture obtained in the step (2), and fully stirring;
(4) and adding the humectant and the lithium-based grease, and repeatedly stirring until the mixture becomes uniform and smooth viscous paste, thus obtaining the plugging agent.
The blocking agent for preventing and treating the pink-neck longicorn can also be applied to preventing and treating other stem borers, in particular to preventing and treating longicorn, codling moth, sulcus orbital or bark beetle.
The method for preventing and treating the pink-neck longicorn by using the plugging agent comprises the following steps:
(a) removing bark of the damaged part of the longicorn bullhorn by using an iron wire or a screwdriver, and cleaning the wood chips and the insect feces to find wormholes;
(b) squeezing the plugging agent into the moth-eaten holes until the plugging agent is squeezed to overflow the moth-eaten holes;
(c) and smoothing the wormholes.
The invention has the beneficial effects that: the plugging agent of the invention has low toxicity, no smell and no harm to plants and natural enemies. The plugging agent can be used in one step, wet mud is not needed for plugging after the agent is used, manpower and time are saved, the agent is not easy to flow due to high viscosity, the agent is easy to keep in the wormholes of pests, and the lasting period is more than 2 weeks. The blocking agent is not affected by air temperature, and can be used in all seasons and different regions.
Detailed Description
The present invention will be described in detail with reference to examples. The scope of protection of the invention is not limited to the embodiments, and any modification made by those skilled in the art within the scope defined by the claims also falls within the scope of protection of the invention.
Examples 1 to 9
The proportion of each component in examples 1 to 9 is shown in Table 1.
TABLE 1 component proportion Table
Examples 1-9 all produced sealant products as follows.
(1) Weighing the filling agent and the lithium-based grease, and weighing water, the insecticide and the humectant;
(2) adding water into the filler and then fully stirring;
(3) adding the pesticide into the mixture obtained in the step (2), and fully stirring;
(4) and adding the humectant and the lithium-based grease, and repeatedly stirring until the mixture becomes uniform and smooth viscous paste, thus obtaining the plugging agent.
Comparative example
The applicant filed 2010 the application of "a paste for controlling stem borers", patent No. 201010592873.8, now uses example 1 in the above patent as a comparative example, and compares it with examples 1 to 9 of the present application.
Examples of effects
The blocking agent related to the invention is applied to the coastal areas, water parks, Yuxi parks, century parks and other places of the water systems of the city of Shijiazhuang to carry out the control effect test on the peach red neck longicorn harming peach trees.
In the examples 1-9 and the comparative examples, clear water is used as a control, 50 fresh defecation holes are treated respectively, and the application method comprises the following steps:
(a) removing bark of the damaged part of the longicorn bullhorn by using an iron wire or a screwdriver, and cleaning wood chips and excrement to find wormholes;
(b) squeezing the plugging agent into the moth-eaten holes until the plugging agent is squeezed to overflow the moth-eaten holes;
(c) and smoothing the wormholes.
Labeling with red lacquer after application, cleaning the insect feces and wood dust of the trees, counting the number of wormholes without fresh insect feces as dead insect numbers after 5, 10 and 15 days after application respectively, and calculating the corrected mortality according to the following formula.
Corrected mortality = (treatment-clear water control mortality)/(1-clear water control mortality) × 100%.
The control results are shown in table 2.
Table 2 examples 1-9 and comparative examples control corrected mortality of pink-neck longicorn (%)
As can be seen from Table 2, the examples 1 to 9 have excellent control effect on the Taurus mahogany, the corrected mortality rate is more than 96% on the 5 th day after the application, and particularly, the corrected mortality rates of the examples 7 and 9 reach 100% on the 5 th day after the application, so that the application has obvious advantages compared with 82% of the comparative example. As can be seen from Table 2, the examples 1 to 9 have good control effect 5 days after application, and the corrected death rate is unchanged with time, which shows that the blocking agent of the invention has high insecticidal speed.
The invention uses the filler as the main component, matches with the auxiliary components such as the insecticide, the humectant and the lubricant (lithium-based grease), and fills the wormhole with the filler, the humectant and the lubricant can guide the filler to smoothly and rapidly fill the wormhole, thereby achieving the purposes of blocking the wormhole and isolating the air, wherein a small amount of the insecticide can directly kill pests through stomach toxicity and contact killing in the process of filling the wormhole, and the variety of the used insecticide has no obvious influence on the control effect.
On the 5 th day after the application of the comparative example, the corrected mortality rate was only 82%, which was associated with low paste viscosity and strong fluidity. Under the action of gravity, the paste can easily flow out from the wormholes. Therefore, the ointment has a good lethal effect on the pink-neck longicorn which is harmful to the root neck or the upright trunk. However, most of peach trees are in open-heart tree shapes, the main branches are relatively flat, and when the paste is injected into the branches, the paste easily flows out of the branches directly, so that pests cannot be touched, and the effect of the pesticide is influenced. When the larvae on the branches, particularly the larvae harmful below the branches are prevented and treated, in order to achieve good prevention effect, the pesticide needs to be applied for many times, or wet mud is used for plugging after the pesticide is injected, so that time and labor are wasted, and the prevention effect is not good.
It should be noted that the plugging agent for controlling the pink-neck longicorn of the invention can also be applied to control other stem borers, in particular to control longicorn, wood moth, orbital elephant or bark beetle. Experiments prove that the corrected mortality rate is not lower than 95 percent compared with that of clear water.
The present invention is described in detail with reference to the above-mentioned embodiments. It should be noted that the above embodiments are only for illustrating the invention. Numerous alternatives and modifications can be devised by those skilled in the art without departing from the spirit and scope of the invention, which should be construed as within the scope of the invention.
Claims (4)
1. The blocking agent for preventing and treating the pink-neck longicorn is characterized by comprising 800-1200 g of a filling agent, 180-200 ml of water, 15-21 ml of an insecticide, 180-200 ml of a humectant and 10-30 mg of lithium-based grease;
the filler is composed of bentonite and biotite in a mass ratio of 1:1, and the bentonite and the biotite are fine powder of 300-400 meshes;
the humectant is liquid paraffin and glycerol with the volume ratio of 1: 1;
the pesticide is more than one of 1% matrine soluble solution, 45% beta-cypermethrin emulsifiable solution and 25% alpha-chlorbenzuron suspending agent.
2. The plugging agent for preventing and treating taurus mahogany as claimed in claim 1, wherein the pesticide is 1% matrine soluble solution and 45% beta cypermethrin emulsifiable concentrate in a volume ratio of 1: 2.
3. A method for preparing the plugging agent for preventing and treating the pink-neck longicorn as claimed in claim 1 or 2, which comprises the following steps:
(1) weighing the filling agent and the lithium-based grease, and weighing water, the insecticide and the humectant;
(2) adding water into the filler and then fully stirring;
(3) adding the pesticide into the mixture obtained in the step (2), and fully stirring;
(4) and adding the humectant and the lithium-based grease, and repeatedly stirring until the mixture becomes uniform and smooth viscous paste, thus obtaining the plugging agent.
4. Use of the plugging agent for controlling a taurus domesticus according to claim 1 or 2 for controlling a trunk-boring pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811141457.9A CN109169689B (en) | 2018-09-28 | 2018-09-28 | Plugging agent for preventing and treating Taurus tonsuratus as well as preparation method and application of plugging agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811141457.9A CN109169689B (en) | 2018-09-28 | 2018-09-28 | Plugging agent for preventing and treating Taurus tonsuratus as well as preparation method and application of plugging agent |
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| CN109169689A CN109169689A (en) | 2019-01-11 |
| CN109169689B true CN109169689B (en) | 2021-01-19 |
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| CN115088537A (en) * | 2022-08-03 | 2022-09-23 | 广州毅田生物技术有限公司 | Prevention and control method for tea tree tea longicorn |
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| CN105418205A (en) * | 2014-09-03 | 2016-03-23 | 刘志鹏 | Apple tree rot disease prevention and control ointment |
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2018
- 2018-09-28 CN CN201811141457.9A patent/CN109169689B/en not_active Expired - Fee Related
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|---|---|---|---|---|
| CN102125028A (en) * | 2010-12-17 | 2011-07-20 | 乔建国 | Paste for preventing and curing stem borer |
| CN103039520A (en) * | 2012-12-25 | 2013-04-17 | 林玉财 | Ointment capable of preventing and curing tree moths |
| CN103999874A (en) * | 2014-05-28 | 2014-08-27 | 甘肃省农业科学院植物保护研究所 | Grease ointment, preparation method and application of grease ointment |
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