CN109162100A - 一种衬衫面料用抗皱整理剂及其应用 - Google Patents
一种衬衫面料用抗皱整理剂及其应用 Download PDFInfo
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- CN109162100A CN109162100A CN201810909357.XA CN201810909357A CN109162100A CN 109162100 A CN109162100 A CN 109162100A CN 201810909357 A CN201810909357 A CN 201810909357A CN 109162100 A CN109162100 A CN 109162100A
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- shirt fabric
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Abstract
本发明公开了一种衬衫面料用抗皱整理剂及其应用。该抗皱整理剂包括以下按重量份数计的组分：纳米二氧化钛1‑5份、苹果酸12‑18份、异丙醇20‑30份、硫酸钠8‑14份、植物提取物20‑30份、丝蛋白2‑8份、失水山梨醇脂肪酸酯2‑4份、氨基硅油18‑27份、有机硅乳液1‑3份、椰油脂肪酸二乙醇酰胺3‑8份、改性聚氨酯35‑40份、氧化羧甲基纤维素钠2‑8份、去离子水30‑48份。与现有技术相比，本发明采用丝蛋白和改性聚氨酯混合提高了，衬衫面料的抗皱效果，且丝蛋白的润滑性，提高了面料与皮肤的亲和性。另外，植物提取物将多种植物混合，浸提后浓缩作为提取物，在保证整理剂抗皱效果下，减少了化学品的添加。
Description
技术领域
本发明属于面料整理领域，具体涉及一种衬衫面料用抗皱整理剂及其应用。
背景技术
申请号201610547449.9 ，名称为一种抗皱抗菌无刺激衬衫面料整理剂的制备方法，属于面料整理剂领域。本发明先将壳聚糖溶液和亚油酸和亚麻酸进行反应得脂肪酸壳聚糖，再从椰子肉中提取出椰子油，将两者混合后加入芦荟汁、香茅精油、糊精、苄索氯铵等混合得混合液，并将混合液和苹果酸、次磷酸钠、三乙醇胺、丁烷四羧酸和乙二醇加热混合，即可得到整理剂，本发明制备得到的整理剂虽然对织物的抗皱效果较好，折皱回弹性高，强力损失小，而且抗菌性好，抗菌时间持久，对人体无刺激，安全环保；抗菌性达到92%以上，重复洗涤100次后抗菌性达到80%以上，折皱回复角200°以上。
申请号201510696667.4，名称为一种耐久性抗皱整理剂，包括以下主要组分：以重量份计，二羟甲基脲树脂、二羟甲基三嗪酮、羟甲基三聚氰胺、丙烯酸丁酯、柠檬酸铵、马来酸-丙烯酸共聚物、多元羧酸盐、脂肪醇聚氧乙烯醚、纳米二氧化钛、分散剂和渗透剂。该抗皱整理液为一种纳米树脂整理液，将二羟甲基脲树脂、过量的二羟甲基三嗪酮和羟甲基三聚氰胺复配作为整理剂，同时添加具有催化效果或协同效应的纳米氧化物而制成，用于棉织物的抗皱整理加工，在保证抗皱效果的同时，改善以往抗皱整理强力和耐磨性损失较大的问题，同时织物无泛黄现。
现有抗皱效果性能强的整理剂，成本高，且耐磨性差，对于手工清洗的衣料，难以持久保留抗皱效果，急需要对整理剂的配方和耐磨性能给予提高。
发明内容
针对现有技术中抗皱整理剂的成本高，耐磨性差的问题，本发明提供了一种衬衫面料用抗皱整理剂及其应用，该抗皱整理剂有效提高了衬衫的抗皱效果，且成本低廉。
一种衬衫面料用抗皱整理剂，包括以下按重量份数计的组分：纳米二氧化钛1-5份、苹果酸12-18份、异丙醇20-30份、硫酸钠8-14份、植物提取物20-30份、丝蛋白2-8份、失水山梨醇脂肪酸酯2-4份、氨基硅油18-27份、有机硅乳液1-3份、椰油脂肪酸二乙醇酰胺3-8份、改性聚氨酯35-40份、氧化羧甲基纤维素钠2-8份、去离子水30-48份。
作为改进的是，上述衬衫面料用抗皱整理剂，包括以下按重量份数计的组分：纳米二氧化钛3份、苹果酸15份、异丙醇28份、硫酸钠12份、植物提取物28份、丝蛋白6份、失水山梨醇脂肪酸酯3份、氨基硅油25、有机硅乳液2份、椰油脂肪酸二乙醇酰胺6份、改性聚氨酯38份、氧化羧甲基纤维素钠6份、去离子水42份。
作为改进的是，所述改性聚氨酯由氧化锌、聚氨酯和壳聚糖混合而成，且氧化锌、聚氨酯和壳聚糖的摩尔比为3：5：1。
进一步改进的是，所述壳聚糖的平均分子量为1.6-1.8×10-4。
作为改进的是，所述植物提取物为银杏叶、香茅草和铁皮石斛杆混合，加入去离子水蒸馏20-30分钟，过滤，浓缩至含水率为20%，即可。
进一步改进的是，所述去离子水的重量为银杏叶、香茅草和铁皮石斛杆总重量的2-3倍。
具体地，将纳米二氧化钛、苹果酸、异丙醇、硫酸钠、植物提取物、丝蛋白、失水山梨醇脂肪酸酯、氨基硅油、有机硅乳液、椰油脂肪酸二乙醇酰胺、改性聚氨酯、氧化羧甲基纤维素钠、去离子水按照常规整理剂的制备方法混合而成，备用。
上述衬衫面料用抗皱整理剂的应用，包括以下步骤：
步骤1，将衬衫面料预处理后，浸渍于抗皱整理剂中，37℃下恒温振荡反应5-8小时；
步骤2，4-7℃低温冷藏过夜后去除，二浸二轧，老化干燥，水洗，常温晾干。
作为改进的是，步骤2中浸轧速率为10-20m/min，浸轧压力为2.5kg/cm3，浸轧残液率为28-45%。
有益效果：
与现有技术相比，本发明采用丝蛋白和改性聚氨酯混合提高了，衬衫面料的抗皱效果，且丝蛋白的润滑性，提高了面料与皮肤的亲和性。另外，植物提取物将多种植物混合，浸提后浓缩作为提取物，充当整理剂的抗氧化剂和抗菌剂，在保证整理剂抗皱效果下，减少了化学品的添加，进而减少对人体的伤害。
具体实施方式
下面通过具体实施例对本发明作进一步详细介绍。
实施例1
一种衬衫面料用抗皱整理剂，包括以下按重量份数计的组分：纳米二氧化钛1份、苹果酸12份、异丙醇20份、硫酸钠8份、植物提取物20份、丝蛋白2份、失水山梨醇脂肪酸酯2份、氨基硅油18份、有机硅乳液1-3份、椰油脂肪酸二乙醇酰胺3份、改性聚氨酯35份、氧化羧甲基纤维素钠2份、去离子水30份。
其中，所述改性聚氨酯由氧化锌、聚氨酯和壳聚糖混合而成，且氧化锌、聚氨酯和壳聚糖的摩尔比为3：5：1。所述壳聚糖的平均分子量为1.6×10-4。
所述植物提取物为银杏叶、香茅草和铁皮石斛杆混合，加入去离子水蒸馏20分钟，过滤，浓缩至含水率为20%，即可，所述去离子水的重量为银杏叶、香茅草和铁皮石斛杆总重量的2倍。
具体地，将纳米二氧化钛、苹果酸、异丙醇、硫酸钠、植物提取物、丝蛋白、失水山梨醇脂肪酸酯、氨基硅油、有机硅乳液、椰油脂肪酸二乙醇酰胺、改性聚氨酯、氧化羧甲基纤维素钠、去离子水按照常规整理剂的制备方法混合而成，备用。
上述衬衫面料用抗皱整理剂的应用，包括以下步骤：
步骤1，将衬衫面料预处理后，浸渍于抗皱整理剂中，37℃下恒温振荡反应5小时；
步骤2，4℃低温冷藏过夜后去除，二浸二轧，老化干燥，水洗，常温晾干，浸轧速率为10m/min，浸轧压力为2.5kg/cm3，浸轧残液率为28%。
对处理过的衬衫面料进行测试，面料经过15次洗涤烘干后外观平整度为5级，断裂强度为经向486N，纬向285N，甲醛含量低于15mg/Kg，耐磨性高于9200转，亲水性18S。
实施例2
一种衬衫面料用抗皱整理剂，包括以下按重量份数计的组分：纳米二氧化钛3份、苹果酸15份、异丙醇28份、硫酸钠12份、植物提取物28份、丝蛋白6份、失水山梨醇脂肪酸酯3份、氨基硅油25、有机硅乳液2份、椰油脂肪酸二乙醇酰胺6份、改性聚氨酯38份、氧化羧甲基纤维素钠6份、去离子水42份。
其中，所述改性聚氨酯由氧化锌、聚氨酯和壳聚糖混合而成，且氧化锌、聚氨酯和壳聚糖的摩尔比为3：5：1。所述壳聚糖的平均分子量为1.7×10-4。所述植物提取物为银杏叶、香茅草和铁皮石斛杆混合，加入去离子水蒸馏25分钟，过滤，浓缩至含水率为20%，即可，所述去离子水的重量为银杏叶、香茅草和铁皮石斛杆总重量的2.5倍。
具体地，将纳米二氧化钛、苹果酸、异丙醇、硫酸钠、植物提取物、丝蛋白、失水山梨醇脂肪酸酯、氨基硅油、有机硅乳液、椰油脂肪酸二乙醇酰胺、改性聚氨酯、氧化羧甲基纤维素钠、去离子水按照常规整理剂的制备方法混合而成，备用。
上述衬衫面料用抗皱整理剂的应用，包括以下步骤：
步骤1，将衬衫面料预处理后，浸渍于抗皱整理剂中，37℃下恒温振荡反应7小时；
步骤2，6℃低温冷藏过夜后去除，二浸二轧，老化干燥，水洗，常温晾干；浸轧速率为15m/min，浸轧压力为2.5kg/cm3，浸轧残液率为30%。
对处理过的衬衫面料进行测试，面料经过15次洗涤烘干后外观平整度为6级，断裂强度为经向496N，纬向275N，甲醛含量低于12mg/Kg，耐磨性高于9800转，亲水性19S。
实施例3
一种衬衫面料用抗皱整理剂，包括以下按重量份数计的组分：纳米二氧化钛5份、苹果酸18份、异丙醇30份、硫酸钠14份、植物提取物30份、丝蛋白8份、失水山梨醇脂肪酸酯4份、氨基硅油27份、有机硅乳液3份、椰油脂肪酸二乙醇酰胺8份、改性聚氨酯40份、氧化羧甲基纤维素钠8份、去离子水48份。
其中，所述改性聚氨酯由氧化锌、聚氨酯和壳聚糖混合而成，且氧化锌、聚氨酯和壳聚糖的摩尔比为3：5：1。所述壳聚糖的平均分子量为1.8×10-4。所述植物提取物为银杏叶、香茅草和铁皮石斛杆混合，加入去离子水蒸馏30分钟，过滤，浓缩至含水率为20%，即可，所述去离子水的重量为银杏叶、香茅草和铁皮石斛杆总重量的3倍。
具体地，将纳米二氧化钛、苹果酸、异丙醇、硫酸钠、植物提取物、丝蛋白、失水山梨醇脂肪酸酯、氨基硅油、有机硅乳液、椰油脂肪酸二乙醇酰胺、改性聚氨酯、氧化羧甲基纤维素钠、去离子水按照常规整理剂的制备方法混合而成，备用。
上述衬衫面料用抗皱整理剂的应用，包括以下步骤：
步骤1，将衬衫面料预处理后，浸渍于抗皱整理剂中，37℃下恒温振荡反应8小时；
步骤2， 7℃低温冷藏过夜后去除，二浸二轧，老化干燥，水洗，常温晾干，浸轧速率为20m/min，浸轧压力为2.5kg/cm3，浸轧残液率为45%。
对处理过的衬衫面料进行测试，面料经过15次洗涤烘干后外观平整度为5级，断裂强度为经向476N，纬向280N，甲醛含量低于13mg/Kg，耐磨性高于9400转，亲水性14S。
对比例1
除改性聚氨酯更换为聚氨酯外，其余同实施例2。
对处理过的衬衫面料进行测试，面料经过15次洗涤烘干后外观平整度为3级，断裂强度为经向426N，纬向235N，甲醛含量低于15mg/Kg，耐磨性高于6500转，亲水性8S。
对比例2
除不含丝蛋白外，其余同实施例2。
对处理过的衬衫面料进行测试，面料经过15次洗涤烘干后外观平整度为3级，断裂强度为经向406N，纬向225N，甲醛含量低于15mg/Kg，耐磨性高于9200转，亲水性7S。
从上述结果可以看出，本发明的衬衫面料用抗皱整理剂抗皱效果好，耐磨性强，亲水性佳，且耐磨，长期使用有润肤的功效。
以上所述，仅为本发明较佳的具体实施方式，本发明的保护范围不限于此，任何熟悉本技术领域的技术人员在本发明披露的技术范围内，可显而易见地得到的技术方案的简单变化或等效替换均落入本发明的保护范围内。
Claims (8)
1.一种衬衫面料用抗皱整理剂，其特征在于，包括以下按重量份数计的组分：纳米二氧化钛1-5份、苹果酸12-18份、异丙醇20-30份、硫酸钠8-14份、植物提取物20-30份、丝蛋白2-8份、失水山梨醇脂肪酸酯2-4份、氨基硅油18-27份、有机硅乳液1-3份、椰油脂肪酸二乙醇酰胺3-8份、改性聚氨酯35-40份、氧化羧甲基纤维素钠2-8份、去离子水30-48份。
2.根据权利要求1所述的衬衫面料用抗皱整理剂，其特征在于，包括以下按重量份数计的组分：纳米二氧化钛3份、苹果酸15份、异丙醇28份、硫酸钠12份、植物提取物28份、丝蛋白6份、失水山梨醇脂肪酸酯3份、氨基硅油25、有机硅乳液2份、椰油脂肪酸二乙醇酰胺6份、改性聚氨酯38份、氧化羧甲基纤维素钠6份、去离子水42份。
3.根据权利要求1所述的衬衫面料用抗皱整理剂，其特征在于，所述改性聚氨酯由氧化锌、聚氨酯和壳聚糖混合而成，且氧化锌、聚氨酯和壳聚糖的摩尔比为3：5：1。
4.根据权利要求3所述的衬衫面料用抗皱整理剂，其特征在于，所述壳聚糖的平均分子量为1.6-1.8×10-4。
5.根据权利要求1所述的衬衫面料用抗皱整理剂，其特征在于，所述植物提取物为银杏叶、香茅草和铁皮石斛杆混合，加入去离子水蒸馏20-30分钟，过滤，浓缩至含水率为20%，即可。
6.根据权利要求5所述的衬衫面料用抗皱整理剂，其特征在于，所述去离子水的重量为银杏叶、香茅草和铁皮石斛杆总重量的2-3倍。
7.基于权利要求1所述的衬衫面料用抗皱整理剂的应用，其特征在于，包括以下步骤：步骤1，将衬衫面料预处理后，浸渍于抗皱整理剂中，37℃下恒温振荡反应5-8小时；步骤2，4-7℃低温冷藏过夜后去除，二浸二轧，老化干燥，水洗，常温晾干。
8.根据权利要求7所述的应用，其特征在于，步骤2中浸轧速率为10-20m/min，浸轧压力为2.5kg/cm3，浸轧残液率为28-45%。
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| CN112853590A (zh) * | 2020-12-31 | 2021-05-28 | 无锡红豆居家服饰有限公司 | 一种爽滑透气短袖 |
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