CN109157423A - A kind of preparation method and application of water-in-oil nano-emulsion - Google Patents
A kind of preparation method and application of water-in-oil nano-emulsion Download PDFInfo
- Publication number
- CN109157423A CN109157423A CN201811158639.7A CN201811158639A CN109157423A CN 109157423 A CN109157423 A CN 109157423A CN 201811158639 A CN201811158639 A CN 201811158639A CN 109157423 A CN109157423 A CN 109157423A
- Authority
- CN
- China
- Prior art keywords
- polyglycereol
- water
- emulsion
- oil
- oil nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of preparation method of water-in-oil nano-emulsion, a kind of water-in-oil nano-emulsion provided by the present invention is made by following methods: 60-70% grease, 10-20% thorn A Gan tree benevolence oil being added in oily phase pot, stirred evenly, acquisition mixed liquor A；Under stirring condition, 3-10% polyglycereol class emulsifier is added in gained mixed liquor A, stirs evenly, obtains mixed liquid B；Under stirring condition, 10%-20% water is added in mixed liquid B, stirs evenly, obtains the water-in-oil nano-emulsion.Water-in-oil nano-emulsion provided by the invention is, and it is an object of the present invention to provide can easily prepare that stability, use feeling be excellent, cosmetics without skin irritation.
Description
Technical field
The invention belongs to technology cosmetic fields, and in particular to a kind of water-in-oil nano-emulsion preparation method and application.
Background technique
Nanoemulsions are defined as having partial size in oil-in-water (O/W) lotion or Water-In-Oil (W/O) cream of 50-1000nm
Liquid.The production equipment and technique of nanoemulsions are different from traditional vacuum emulsifying method, but use high-speed mixing method, by water
Phase constituent is added in oil-phase component and is mixed, and forms partial size by adjusting a series of physical process such as high voltage parameter and temperature
Controllable fine emulsion.
A kind of water-in-oil nano-emulsion mainly is synthesized using Synthetic Oil and natural oil emulsification the present invention provides a kind of
Obtain preparation method and applications.
Summary of the invention
The technical problem to be solved by the present invention is to prepare a kind of water-in-oil nano-emulsion, with other raw materials, make properties of product
Optimized.
In a first aspect, it is that the present invention provides a kind of preparation methods of water-in-oil nano-emulsion, the preparation method is that:
(1) 60-70% grease, 10-20% thorn A Gan tree benevolence oil are added in oily phase pot, stir evenly, obtains mixed liquor
A；
(2) under stirring condition, 3-10% polyglycereol class emulsifier is added in gained mixed liquor A, stirs evenly, is mixed
Close liquid B；
(3) under stirring condition, 10%-20% water is added in mixed liquid B, stirs evenly, obtains the Water-In-Oil nanometer
Lotion.
Preferably, grease of the present invention is Synthetic Oil.
It is further preferred that the Synthetic Oil is isononyl isononanoate, one in cetostearyl alcohol ethylhexoate
Kind.
Polyglycereol ester emulsifying agent of the present invention includes polyglyceryl fatty acid ester, can specifically enumerate six gather it is sweet
Oily monolaurate, six polyglycereol list isostearates, six polyglycereol list myristinates, six Plurol Oleique CC497s, six gather
Two myristinate of glycerol, six polyglycereol dipalmitates, six polyglycerol distearates, six polyglycereol, two behenate, six
Polyglycereol trilaurin, six polyglycereol, three myristinate, six polyglycereol tripalmitates, six polyglycereol tristearates,
Six polyglycereol tribehenin acid esters, six polyglycereol, four laurate, six polyglycereol, four myristinate, six polyglycereol, four palmitinic acid
Ester, six polyglycereol tetrastearates, six polyglycereol, four behenate, six polyglycereol, five laurate, six polyglycereol, five nutmeg
Acid esters, six polyglycereol, five palmitate, six polyglycerol 5 stearates, six polyglycereol, five behenate, ten polyglycereol list capric acid
Ester, ten polyglycereol monolaurates, ten polyglycereol list myristinates, ten polyglycereol monopalmitates, ten polyglycereol lists are stearic
Acid esters, ten polyglycerol monooleates, ten polyglycereol list linoleates, ten polyglycereol list isostearates, ten polyglycereol, two capric acid
Ester, ten polyglycerol dilaurates, ten polyglycereol, two myristinate, ten polyglycereol dipalmitates, ten polyglycereol distearyls
Acid esters, ten Risorex PGIS 22s, ten polyglycereol trilaurins, ten polyglycereol, three myristinate, ten polyglycereol three
Palmitate, ten polyglycereol tristearates, ten polyglycereol trioleates, ten polyglycereol tribehenin acid esters, ten polyglycereol five stiffness
Resin acid ester, ten polyglycereol, five oleate, ten polyglycereol, five isostearate, ten polyglycereol, seven stearate, ten polyglycereol ten are hard
Resin acid ester, ten polyglycereol, ten oleate, ten polyglycereol, ten isostearate etc., but it is not limited to these.
Preferably, polyglycereol class emulsifier is three isostearate of polyglycereol -2.
Aqueous solution of the present invention includes but is not limited to one of deionized water, pure water, distilled water or a variety of.
It is further preferred that aqueous solution is deionized water.
Isononyl isononanoate of the present invention has unique more methyl branch structures, and silk-like feeling is dry and comfortable and extremely soft
Soft feel, splendid emollient.It is good to silicone oil intermiscibility, it can solve the problems, such as that silicone oil low temperature is precipitated, be the stabilization of silicone oil
Agent and coupling agent.There is good dispersibility to colorant, extraordinary makeup removing power, viscosity is low, and skin sense is salubrious, no greasy feeling.
Cetostearyl alcohol ethylhexoate of the present invention is commonly called as seabird feather oil, is the cheap substitution of natural saualane
New product is the especially excellent emollient of waterproof performance, has gas permeability and spreadability good, not sticky, can moisten soft skin
The advantages of, can be applied to lipstick and make colorant dispersant and basic finish, glossy dose of lipstick, brilliantine agent, cream emulsion softness
Agent etc..
Thorn A Gan tree benevolence oil of the present invention contains abundant fatty acid, sterol, vitamin e and phenolic compound.Wherein wrap
Include a large amount of essential fatty acid, unsaturated fatty acid and linoleic acid, it is that these cannot all be synthesized in human body and must be from fat
In acquire.Fatty acid maintains the hydration levels of human health, and research points out that linoleic acid is applied on the skin to anti-inflammatory
Acne are reduced, have positive effect on moisture-keeping functions；And the shortage of essential unsaturated fatty acid can lead to skin and cross senilism
Change and wrinkle.Macadamia nut oil has scientifically been confirmed that it contains its life E of the dimension of 2 times of olive oil.Macadamia nut oil also contains rare
Phytosterol, phytosterol can help softening skin, stimulate pore toxin expelling, restore natural lipid barrier.Polyphenol is then many institute's weeks
The antioxidant known, it can not only delay skin aging, can be with other antioxidants such as vitamin E in prolonged human body, dimension life
The action time of plain C.
- 2 three isostearate of polyglycereol of the present invention is nonionic surfactant, due to polyglyceryl fatty acid ester
Safety, they have been approved as food additives.Compared with nonionic polyoxyethylene surfactant, it shows pole
Good oxidation stability and pH stability.Compared with sucrose, glycerol, sorbitan ester etc., there is fabulous thermal stability.
Second aspect is that the present invention also provides using a kind of oil packet made from preparation method as described in relation to the first aspect
Water nanoemulsions.The water-in-oil nano-emulsion that the present invention synthesizes has the characteristics that safety and environmental protection, mild inirritative.
A kind of water-in-oil nano-emulsion that second aspect of the present invention provides, by mass percentage, raw material composition packet
It includes:
60-70% grease；
10-20% pierces A Gan tree benevolence oil；
3-10% polyglycereol class emulsifier；
10-20% aqueous solution；
It is further preferred that the water-in-oil nano-emulsion, by mass percentage, raw material composition includes:
60-70% isononyl isononanoate；
10-20% pierces A Gan tree benevolence oil；
- 2 three isostearate of 3-10% polyglycereol；
10-20% deionized water；
It is further preferred that the water-in-oil nano-emulsion, by mass percentage, raw material composition includes:
60-70% cetostearyl alcohol ethylhexoate；
10-20% pierces A Gan tree benevolence oil；
- 2 three isostearate of 3-10% polyglycereol；
10-20% deionized water；
According to preferred embodiment, composition of the invention is lotion, especially nanoemulsions.
It is understood to one skilled in the art that other raw materials can also be added in the present invention, as preservative, foaming agent,
Propellant and essence etc..
The third aspect, the present invention provides a kind of water-in-oil nano-emulsions to prepare the application in cosmetics.
It is further preferred that the cosmetics include but is not limited to makeup remover, makeup remover, makeup removing foam, foam makeup remover
Mousse, water laser accunputure or Essence.
Fourth aspect uses water-in-oil nano-emulsion described in second aspect of the present invention for raw material the present invention provides a kind of
The makeup remover of preparation, by mass percentage, the raw material composition of the makeup remover includes:
Water-in-oil nano-emulsion 5%-10%
Benzyl alcohol 0.1%-0.5%
PEG- glycerol coconut oil rouge 1.5%-3%
Essence 0.1%-0.2%
Water 93.3%-86.3.
5th aspect, uses water-in-oil nano-emulsion described in second aspect of the present invention for raw material the present invention provides a kind of
The makeup remover of preparation, by mass percentage, the raw material composition of the makeup remover includes:
Water-in-oil nano-emulsion 50%-60%
Parahydroxyacet-ophenone 0.4%-1%
Hexylene glycol 0.4%-1%
Hexylene glycol 2%-5%
Essence 0.2%-0.3%
PEG-7 glycerol coconut oil rouge 2.5%-5%
Water 27.7%-44.5%.
6th aspect, uses water-in-oil nano-emulsion described in second aspect of the present invention for raw material the present invention provides a kind of
The makeup removing foam of preparation, by mass percentage, the raw material composition of the makeup remover includes:
Water-in-oil nano-emulsion 5%-10%
Cocoamidopropyl betaine 3%-6%
Benzyl alcohol 0.1%-0.5%
Essence 0.1%-0.2%
PEG-7 glycerol coconut oil rouge 0.5%-1%
Water 82.3%-91.3%.
7th aspect, uses water-in-oil nano-emulsion described in second aspect of the present invention for raw material the present invention provides a kind of
The foam makeup remover mousse of preparation, by mass percentage, the raw material composition of the makeup remover includes:
Water-in-oil nano-emulsion 50%-60%
Benzyl alcohol 0.2%-0.5%
Benzyl alcohol 0.2%-0.5%
Essence 0.2%-0.3%
PEG-7 glycerol coconut oil rouge 0.5%-1%
Water 39.8%-49.6%.
Eighth aspect uses water-in-oil nano-emulsion described in second aspect of the present invention for raw material the present invention provides a kind of
The water laser accunputure of preparation, by mass percentage, the raw material composition of the makeup remover includes:
Water-in-oil nano-emulsion 2%-5%
Essence 0.2%-0.3%
Hyaluronic acid 0.1%-0.2%
Caprylhydroxamic acid 0.6%-1%
1,3 propylene glycol 5%-8%
Trimethylglycine 2%-5%
C10-30 alkylol acrylamide acid esters
Cross-linked polymer 0.03%-0.06%
Tromethamine 0.02%-0.03%
Water 80.61%-90.2%.
9th aspect, uses water-in-oil nano-emulsion described in second aspect of the present invention for raw material the present invention provides a kind of
The Essence of preparation, by mass percentage, the raw material composition of the makeup remover includes:
Water-in-oil nano-emulsion 2%-5%
Essence 0-0.3%
Hyaluronic acid 0.1%-0.2%
Caprylhydroxamic acid 0.6%-1%
1,3 propylene glycol 5%-8%
Trimethylglycine 2%-5%
C10-30 alkylol acrylamide acid esters
Cross-linked polymer 0.15%-0.2%
Tromethamine 0.065%-0.085%
Dimethyl silicone polymer 0-5%
Niacinamide 0-3%
Water 80.61%-90.2%.
It will be appreciated by persons skilled in the art that the makeup remover is unloaded in fourth aspect present invention into the 9th aspect
Adornment is oily, the preparation method of remove ornaments and formal dress foam, foam makeup remover mousse, water laser accunputure or Essence uses conventional method in that art.
Compared with prior art, the invention has the benefit that a kind of water-in-oil nano-emulsion provided by the invention, uses
The perfect collocation of isononyl isononanoate or cetostearyl alcohol ethylhexoate, thorn A Gan tree benevolence oil, polyglycereol class emulsifier, water.
Isononyl isononanoate has good dispersibility to colorant, and extraordinary makeup removing power, viscosity is low, and skin sense is salubrious, no greasy feeling.Whale
Wax stearyl alcohol ethylhexoate is the especially excellent emollient of waterproof performance, has gas permeability and spreadability good, not sticky, can be grown
The advantages of moistening soft skin.The dry tree benevolence oil of Ci A is also known as argan oil, is a kind of natural skin care item.The emulsification of polyglycereol class
Agent be made of being esterified at high temperature as natural glycerin and fatty acid, in the metabolic process, can be analyzed to sweet oil & fat, thus
It is absorbed by the body or excretes, be highly safe.Cosmetic material composition, performance is made by the above ingredient
Safety, it is non-stimulated, it is compounded with the surfactant described in other, makes mutually to cooperate between each component, make the function of each component
Effect is optimized.
Compared with prior art, the beneficial effects of the invention are that: nanometer water-in-oil emulsion provided by the invention, safety it is stingless
Swash and is not easy sensitization.Its excellent in stability also has effects that moist moisturizing, repairs skin.Nanometer Water-In-Oil provided by the invention
Lotion Environmental compatibility is good, meets environmentally protective trend.The preparation method of nanometer water-in-oil emulsion provided by the invention, preparation
Simple process is easy to operate, is conducive to save production cost.
Detailed description of the invention
Fig. 1: being that the water-in-oil nano-emulsion that the present invention is prepared according to embodiment 2 is obtained at dynamic light scattering (DLS)
The nanoemulsions partial size arrived.
Specific embodiment
The present invention is further described With reference to embodiment, the embodiment provided is only for illustrating this
Invention, the range being not intended to be limiting of the invention, because without departing from the spirit and scope of the present invention, it can be right
The present invention carries out many changes.It is understood that those skilled in the art are after reading this specification according to conventional needs
That makes does not have creative modification, but as long as all by the protection of Patent Law in scope of the presently claimed invention.
Constituent content in following embodiments is unless otherwise specified mass percent.It is as used in the following examples
Raw material, reagent material etc. can be commercially available unless otherwise specified from conventional distributors.
Cosmetics of the present invention contain " the Water-In-Oil nano-emulsion of the invention including the cosmetics by summary of the invention requirement
Liquid ", and contain the ingredient in water-in-oil nano-emulsion.
The component information of embodiment 1-3
Embodiment 1-3 is a kind of water-in-oil nano-emulsion prepared according to inventive formulation, contained component information such as table 1
It is shown.
A kind of preparation method of water-in-oil nano-emulsion of embodiment 1-3, includes the following steps:
(1) it weighs the isononyl isononanoate centainly matched to be mutually put into oily phase pot with the oil of the dry tree benevolence oil composition of Ci A, stir
It mixes uniformly, obtains mixed liquor A；
(2) three isostearate of polyglycereol -2 centainly matched is weighed, is put into oily phase pot, is stirred evenly, mixed
Liquid B；
(3) water that will centainly match slowly is pumped into oily phase pot, stirs evenly, obtains water-in-oil nano-emulsion；
The component information of embodiment 4-6
The preparation method of embodiment 4-6 is identical as the preparation method of embodiment 1-3, and isononyl isononanoate is only substituted for whale
Its contained component information of wax stearyl alcohol ethylhexoate is as shown in table 2.
Embodiment 4: the particle size determination of nanoemulsions
By dynamic light scattering (DLS), also referred to as Photon Correlation Spectrum (PCS), the nanoemulsions particle of embodiment 1-4 is measured
Size, as shown in Figure 1, learning that embodiment 1-6 nanoemulsions partial size is about average in 500nm.
Application Example
The product of following Application Example 1-4 is prepared by 2 composition of embodiment.
The ingredient for nursing frost produced according to 2 composition of embodiment is as shown in table 3 below.
1 makeup remover of Application Example
The makeup removing water constituent of table 3
The step of preparation method, is as follows:
(1) it is uniformly mixed after A first being added in ingredient C under room temperature, for use；
(2) D is added in the mixture of step (1), it is stirring while adding；
(3) B is added and stirs evenly and can discharge after supplying water；
2 makeup remover of Application Example
The makeup removing oil component of table 4
The step of preparation method, is as follows:
(1) A is heated to start to cool down after 70 DEG C or so additions are completely dissolved B；
(2) C is added when cooling to 50 DEG C or less and stirs 5min to uniform；
(3) last to add D stirring 30min discharging under stiring；
The makeup removing foam of Application Example 3
The makeup removing foam of table 5
The step of preparation method, is as follows:
(1) it is uniformly mixed after A first being added in E and D under room temperature；
(2) mixture of step (1) is added water to, it is stirring while adding；
(3) B and C are eventually adding and stirs evenly and can discharge after supplying F；
4 foam makeup remover mousse of application example
6 foam makeup remover mousse of table
The step of preparation method, is as follows:
(1) it is uniformly mixed after A first being added in B under room temperature；
(2) D of room temperature is added into the mixture of step (1), it is stirring while adding；
(3) C etc. is added and stirs evenly and can discharge after supplying water, after discharging plus E is filled；
The product of following Application Example 5-6 is prepared by 5 composition of embodiment.
5 water laser accunputure of application example
7 water laser accunputure of table
The step of preparation method, is as follows:
(1) it is uniformly mixed after first B being added in A under room temperature；
(2) mixture of step (1) is added in the H and C solution of room temperature, it is stirring while adding, it is preparatory to be stirring evenly and then adding into F
The G neutralization that 10% concentration is added after scattered 1.5% dispersion liquid stirs evenly；
(3) E and D is added and stirs evenly and can discharge after supplying H.
6 Essence of application example
8 Essence of table
The step of preparation method, is as follows:
(1) it is uniformly mixed after first B being added in A under room temperature；
(2) first C, F, G, H and I are added in whole water to neutralize and J, Bian Jia is added in the mixture of step (1) again after mixing evenly
Side stirring；
(3) E and D etc. is added and stirs evenly and can discharge after supplying J.
Performance test 1
Product prepared by embodiment 2 is carried out to be applicable in detection effect, while commercially available declaring mildly clearly to unload with a
Makeup remover-the Bei Demashu of adornment effect grinds multiple-effect clean skin liquid and is control group 1 and a commercially available declares mild non-stimulated there is makeup removing
The make up remover of effect-Maybelline rinse-off eye makeup solvent is control group 2.Test method is as follows:
(1) the removal experiment of oil pen: prepare liquid is dipped in nose pad pasting paper handkerchief, the oiliness person's handwriting of wiping picture on the skin wipes more
It is secondary less to clean, wiping number is write down to compare.
(2) the removal experiment of lip gloss: prepare liquid is dipped in nose pad pasting paper handkerchief, wipes endermic lip gloss, wipes 25 times, sees wiping
Cleaning effect after complete.
(3) Ocular irritation is tested: being dipped in prepare liquid with nose pad pasting paper handkerchief, is applied in eye, sees that, whether there is or not fever, tingling sensation finally uses paper
Towel wiping eyes see that whether there is or not excitements.
(4) stability test: by Examples 1 to 4 and control group 1~2 respectively under room temperature, low temperature (5 DEG C) and high temperature (48 DEG C)
Place two hours, surveys its transparency.
The benchmark of evaluation is as described below
Removal effect, which is 100%, indicates complete removal, and removal effect, which is 0%, indicates no removal efficiency；
Table 9
As shown in Table 9, example 1 of the invention to example 4 product compared to commercial product makeup removing ability, gentle degree,
This several respect of stability have promotion.
Performance test 2
Product prepared by embodiment 5 is carried out to be applicable in detection effect, while commercially available declaring moisture saver mask with a ---
Intelligent's facial mask is control group 3 and a commercially available facial mask for declaring mildly to moisten --- the net fresh milk olive moisture saver mask of Yu Mei after Korea Spro
For control group 4.Test method is as follows:
Test object: each experimental group is 30 women (22-30 years old)；Test zone: Face and cheek；It uses: twice daily,
Persistently use 4 weeks；Test item: humidity of skin, skin smoothness.Result on trial see the table below 8.
Table 10
As shown in Table 10, there is moisturizing skin, smooth skin by the facial mask come out prepared by water-in-oil nano-emulsion
Effect.
Performance test 3
(1) skin elasticity is tested
Skin elasticity year skin aging and reduce, therefore skin elasticity is the one of the important signs that for judging skin aging, is
The effect of anti-aging cosmetics, detects essential project.
Test method: every group selection health, skin is normal, without the tested crowd of cosmetic allergic contact dermatitis history, and the age 30-45 years old, female
Property 20.One week is as a treatment course, totally four courses for the treatment of, and every time using preceding by facial cleansing, and the face cleaning time is identical every time, to
Skin uses corresponding product after drying, and each group uses corresponding product 1 time daily, and 10g is taken uniformly to be applied on the face.
Measurement: selecting Face and cheek as test zone, is tested after product 10min to be used.It is surveyed using skin elasticity
Try instrument and measure skin elasticity curve, according to the amount of tension of skin and resilience data, can moisturizing to cosmetics and
Anti-senescence function is assessed.
Experimental result: skin elasticity test is to utilize suction and stretch principle, generates one on the surface of tested skin and bears
Pressure, by skin inspiration one special test probe, skin is inhaled into depth and is surveyed by a non-contact optical detection system
, measurement result usually indicates that unit 1, numerical value is bigger with an index, illustrates that skin elasticity is stronger.Water of the invention
Influence of the laser accunputure to skin elasticity is as shown in table 9.
11 skin elasticity of table tests table
As can be seen from Table 11, skin elasticity can be remarkably reinforced in water laser accunputure of the invention, illustrate painting type of the invention
Water laser accunputure has good anti-aging and compact skin and other effects, enhances elasticity of skin, and deep layer repairs skin, allows skin full of work
Power.
(2) skin moisture content is tested
Experimental method: every group selection healthy skin, no tested crowd of cosmetic allergic contact dermatitis history, women 20, age 30-45
Year.25 DEG C ± 1 DEG C of room temperature；Humidity 50% ± 5%.Face is cleaned when test, and everyone face cleaning time is identical, after skin dries
It selects Face and cheek 4cm × 4cm skin as test zone, 0.8g is taken uniformly to be applied on the face.
Measurement: 10min is tested after Face and cheek (4cm × 4cm) test zone, product to be used.Use digital skin
Moisture detector carrys out the water content of aspect of measure skin of cheek.Using 2h, 4h, 6h after corresponding product, surveys Face and cheek skin and contain
Water, measurement are averaged three times.Test result is shown in Table 10.
12 moisture content test value list position of table: %
As can be seen from Table 12, painting type water laser accunputure moisturizing effect of the invention is good, moisture preserving time is long, illustrates of the invention
Water laser accunputure can effectively inhibit excess oil, balance skin grease, lasting moisturizing.
The above, only specific embodiments of the present invention, but scope of protection of the present invention is not limited thereto, it is any
Those skilled in the art within the technical scope disclosed by the invention, the variation that can be expected without creative work
Or replacement, it should be covered by the protection scope of the present invention.Therefore protection scope of the present invention should be with claims institute
Subject to the protection scope of restriction.
Claims (10)
1. a kind of preparation method of water-in-oil nano-emulsion, which is characterized in that according to mass percent, comprising the following steps:
(1) 60-70% grease, 10-20% thorn A Gan tree benevolence oil are added in oily phase pot, stir evenly, obtains mixed liquor A；
(2) under stirring condition, 3-10% polyglycereol class emulsifier is added in gained mixed liquor A, stirs evenly, obtains mixed liquor
B；
(3) under stirring condition, 10%-20% water is added in mixed liquid B, stirs evenly, obtains the water-in-oil nano-emulsion.
2. preparation method according to claim 1, which is characterized in that the grease is Synthetic Oil.
3. preparation method according to claim 2, which is characterized in that the Synthetic Oil is isononyl isononanoate, spermaceti
One of stearyl alcohol ethylhexoate.
4. preparation method according to claim 1, which is characterized in that the polyglycereol class emulsifier, including polyglycerol ester
Fat acid esters, the polyglyceryl fatty acid ester include six polyglycereol monolaurates, six polyglycereol list isostearates, six polyglycereol
Single myristinate, six Plurol Oleique CC497s, six polyglycereol, two myristinate, six polyglycereol dipalmitates, six gather it is sweet
Oily distearate, six polyglycereol, two behenate, six polyglycereol trilaurins, six polyglycereol, three myristinate, six gather
Tripalmitin, six polyglycereol tristearates, six polyglycereol tribehenin acid esters, six polyglycereol, four laurate, six gather
Four myristinate of glycerol, six polyglycereol, four palmitate, six polyglycereol tetrastearates, six polyglycereol, four behenate, six
Five laurate of polyglycereol, six polyglycereol, five myristinate, six polyglycereol, five palmitate, six polyglycerol 5 stearates,
Six polyglycereol, five behenate, ten polyglycereol monkey cells, ten polyglycereol monolaurates, ten polyglycereol list myristinates,
Ten polyglycereol monopalmitates, ten polyglycerol monostearates, ten polyglycerol monooleates, ten polyglycereol list linoleates, ten
Polyglycereol list isostearate, ten polyglycereol dicaprates, ten polyglycerol dilaurates, ten polyglycereol, two myristinate,
Ten polyglycereol dipalmitates, ten polyglycerol distearates, ten Risorex PGIS 22s, ten polyglycereol trilauryls
Ester, ten polyglycereol, three myristinate, ten polyglycereol tripalmitates, ten polyglycereol tristearates, ten polyglycereol, three oleic acid
Ester, ten polyglycereol tribehenin acid esters, ten polyglycerol 5 stearates, ten polyglycereol, five oleate, ten polyglycereol, five isostearic acid
Ester, ten polyglycereol, seven stearate, ten polyglycereol, ten stearate, ten polyglycereol, ten oleate, ten polyglycereol, ten isostearic acid
One of ester is a variety of.
5. preparation method according to claim 1, it is characterized in that, the aqueous solution include deionized water, it is pure
One of water, distilled water are a variety of.
6. a kind of water-in-oil nano-emulsion, which is characterized in that the water-in-oil nano-emulsion is using described in claim 1
The method for preparing water-in-oil nano-emulsion is made.
7. water-in-oil nano-emulsion according to claim 6, which is characterized in that the water-in-oil nano-emulsion, by matter
Percentages are measured, material component includes:
The isononyl isononanoate of 60-70%；
The thorn A Gan tree benevolence oil of 10-20%；
The polyglycereol class emulsifier of 3-10%；
10-20% aqueous phase solution.
8. water-in-oil nano-emulsion according to claim 6, which is characterized in that the water-in-oil nano-emulsion, by matter
Percentages are measured, material component includes:
The cetostearyl alcohol ethylhexoate of 60-70%；
The thorn A Gan tree benevolence oil of 10-20%；
The polyglycereol class emulsifier of 3-10%；
10-20% aqueous phase solution.
9. a kind of water-in-oil nano-emulsion as claimed in claim 7 is preparing the application in cosmetics.
10. a kind of cosmetics, which is characterized in that the cosmetics include makeup remover, makeup remover, makeup removing foam, foam makeup remover
Mousse, water laser accunputure or Essence；The cosmetics use water-in-oil nano-emulsion described in second aspect of the present invention for raw material system
Standby gained, by mass percentage, the raw material composition of the cosmetics includes any one of following (1)-(6):
(1) the raw material composition of makeup remover includes:
(2) the raw material composition of makeup remover includes:
(3) the raw material composition of makeup removing foam includes:
(4) the raw material composition of foam makeup remover mousse includes:
(5) the raw material composition of water laser accunputure includes:
(6) the raw material composition of Essence includes:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158639.7A CN109157423A (en) | 2018-09-30 | 2018-09-30 | A kind of preparation method and application of water-in-oil nano-emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158639.7A CN109157423A (en) | 2018-09-30 | 2018-09-30 | A kind of preparation method and application of water-in-oil nano-emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109157423A true CN109157423A (en) | 2019-01-08 |
Family
ID=64877432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811158639.7A Pending CN109157423A (en) | 2018-09-30 | 2018-09-30 | A kind of preparation method and application of water-in-oil nano-emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109157423A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923842A (en) * | 2019-11-25 | 2020-03-27 | 杭州奔马化纤纺丝有限公司 | Preparation process of non-dyed primary polyester staple fiber |
| CN111529432A (en) * | 2020-04-20 | 2020-08-14 | 上海舒彩网络科技有限公司 | Reversed micelle solubilizing cleansing oil and preparation method thereof |
| CN111803415A (en) * | 2020-07-16 | 2020-10-23 | 广州市澳键丰泽生物科技股份有限公司 | Plant essential oil nano emulsion, preparation method thereof and application thereof in lip products |
| CN112746353A (en) * | 2020-12-30 | 2021-05-04 | 苏州禾川化学技术服务有限公司 | Chemical fiber oiling agent for high-speed spinning and preparation method thereof |
| CN115381741A (en) * | 2022-08-25 | 2022-11-25 | 广州雅纯化妆品制造有限公司 | Superfine microemulsion, preparation method thereof and application thereof in open and closed acne |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103215125A (en) * | 2013-04-10 | 2013-07-24 | 陕西科技大学 | Preparation method of water-in-oil nano-emulsion |
| CN104523445A (en) * | 2014-12-12 | 2015-04-22 | 唯美度科技（北京）有限公司 | Nanoscale emulsion with high transdermal absorbency |
| CN108295684A (en) * | 2018-03-06 | 2018-07-20 | 宁波高新区绿元汇生物科技有限公司 | A kind of preparation method of water-in-oil nano-emulsion |
-
2018
- 2018-09-30 CN CN201811158639.7A patent/CN109157423A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103215125A (en) * | 2013-04-10 | 2013-07-24 | 陕西科技大学 | Preparation method of water-in-oil nano-emulsion |
| CN104523445A (en) * | 2014-12-12 | 2015-04-22 | 唯美度科技（北京）有限公司 | Nanoscale emulsion with high transdermal absorbency |
| CN108295684A (en) * | 2018-03-06 | 2018-07-20 | 宁波高新区绿元汇生物科技有限公司 | A kind of preparation method of water-in-oil nano-emulsion |
Non-Patent Citations (1)
| Title |
|---|
| 张卫明: "《一带一路经济植物》", 31 December 2017 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110923842A (en) * | 2019-11-25 | 2020-03-27 | 杭州奔马化纤纺丝有限公司 | Preparation process of non-dyed primary polyester staple fiber |
| CN110923842B (en) * | 2019-11-25 | 2022-05-03 | 杭州奔马化纤纺丝有限公司 | Preparation process of non-dyed primary polyester staple fiber |
| CN111529432A (en) * | 2020-04-20 | 2020-08-14 | 上海舒彩网络科技有限公司 | Reversed micelle solubilizing cleansing oil and preparation method thereof |
| CN111803415A (en) * | 2020-07-16 | 2020-10-23 | 广州市澳键丰泽生物科技股份有限公司 | Plant essential oil nano emulsion, preparation method thereof and application thereof in lip products |
| CN111803415B (en) * | 2020-07-16 | 2023-02-17 | 广州市澳键丰泽生物科技股份有限公司 | Plant essential oil nano emulsion, preparation method thereof and application thereof in lip products |
| CN112746353A (en) * | 2020-12-30 | 2021-05-04 | 苏州禾川化学技术服务有限公司 | Chemical fiber oiling agent for high-speed spinning and preparation method thereof |
| CN115381741A (en) * | 2022-08-25 | 2022-11-25 | 广州雅纯化妆品制造有限公司 | Superfine microemulsion, preparation method thereof and application thereof in open and closed acne |
| CN115381741B (en) * | 2022-08-25 | 2023-08-15 | 广州雅纯化妆品制造有限公司 | Ultrafine emulsion, preparation method thereof and application thereof in open and closed acne |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109157423A (en) | A kind of preparation method and application of water-in-oil nano-emulsion | |
| CN102366384B (en) | Skin-refreshing face-repairing cream composition and preparation method thereof | |
| CA2312886C (en) | Skin care composition with improved skin hydration capability | |
| WO2021109319A1 (en) | Bath moisturizer having high moisture retention effect and preparation method therefor | |
| CN111568782B (en) | Nanoemulsion composition capable of improving skin barrier and application thereof | |
| KR102127674B1 (en) | Water-drop solid type cosmetic composition in the form of water-in-oil emulsion of silicone-free and peg-free, and preparation method of the same | |
| CN102406578A (en) | Silky bright-color smoothing toner composition and preparation method | |
| KR20130055069A (en) | O/w emulsion having recrystallized particle and cosmetic composition comprising thereof | |
| CN109843250A (en) | From expansion type cosmetic combination and its manufacturing method | |
| JPH07256085A (en) | Polyol-containing water-in-oil emulsion and make-up material composition containing it | |
| CN105434258A (en) | Fructus phyllanthi cream capable of activating and moisturizing skin | |
| KR100732728B1 (en) | Emulsion cosmetic composite of low viscocity | |
| CN111658555A (en) | Nano anti-wrinkle essence cream and preparation method thereof | |
| KR101288236B1 (en) | Manufacturing Method for Cosmetic Emulsion Using High Content Silicone Derivatives and The Cosmetic Composition Containing This Method | |
| CN110721097B (en) | Water-in-oil frost and preparation method and application thereof | |
| CN112842921A (en) | Multilayer cleansing lotion and preparation method thereof | |
| CN106309169B (en) | Vegetable-based skin care compositions comprising petrolatum substitutes | |
| KR102432885B1 (en) | Cosmetic composition for anti-aging | |
| CN114344198B (en) | Anhydrous double-layer hair care oil and preparation method thereof | |
| CN113101239B (en) | Multiphase coated micro-emulsified facial cleansing oil and preparation method thereof | |
| CN113768809B (en) | Composition with mild exfoliating effect and preparation method and application thereof | |
| CN115501123A (en) | Stable double-layer toning lotion and preparation method thereof | |
| US20130345315A1 (en) | Water-releasing cosmetic composition | |
| KR101690144B1 (en) | A method of preparing cosmetic composition for moisturizing the skin and promoting the differenciation of keratinocyte cell comprising the agar and the cosmetic composition prepared therefrom | |
| CN110840778A (en) | Emulsion type mask liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190108 |