CN109148369A - A kind of heating laser peel-off device - Google Patents

A kind of heating laser peel-off device Download PDF

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Publication number
CN109148369A
CN109148369A CN201811196018.8A CN201811196018A CN109148369A CN 109148369 A CN109148369 A CN 109148369A CN 201811196018 A CN201811196018 A CN 201811196018A CN 109148369 A CN109148369 A CN 109148369A
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CN
China
Prior art keywords
laser
heating
sample stage
peel
insulation cover
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Granted
Application number
CN201811196018.8A
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Chinese (zh)
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CN109148369B (en
Inventor
孙永健
莫少琼
豆学刚
王光普
郭坚
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Baoding Zhongchuang Yanyuan Semiconductor Technology Co Ltd
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Baoding Zhongchuang Yanyuan Semiconductor Technology Co Ltd
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Priority to CN201811196018.8A priority Critical patent/CN109148369B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/7806Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices involving the separation of the active layers from a substrate
    • H01L21/7813Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices involving the separation of the active layers from a substrate leaving a reusable substrate, e.g. epitaxial lift off
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/40Removing material taking account of the properties of the material involved
    • B23K26/402Removing material taking account of the properties of the material involved involving non-metallic material, e.g. isolators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67098Apparatus for thermal treatment
    • H01L21/67103Apparatus for thermal treatment mainly by conduction

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Power Engineering (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Laser Beam Processing (AREA)

Abstract

The invention discloses a kind of heating laser peel-off devices, including laser lift-off apparatus body, the laser lift-off apparatus body includes the mobile platform for being set to lower end, the mobile platform is provided with heated base, sample stage is provided on the heated base, the heated base includes the electric heater unit being set to below the sample stage and for heating to the sample stage, the sample stage lower end is additionally provided with the temperature sensor for test sample platform temperature, insulation cover is covered with above the sample stage, the heat-insulation transparent window for facilitating laser to pass through is provided on position corresponding to the top of the insulation cover and the sample stage.Heating laser peel-off device of the invention provides suitable temperature environment for peeling GaN epitaxial wafer, solves the problems, such as the residual mechanical stress of the GaN epitaxy piece of Grown on Sapphire Substrates, generation the case where easy fragmentation when avoiding removing.

Description

A kind of heating laser peel-off device
Technical field
The present invention relates to a kind of heating laser peel-off devices.
Background technique
III/V nitride based on GaN and InGaN, AlGaN is the semiconductor material being concerned in recent years, is The core component part of light emitting diode, the direct band gap of 1.9~6.2eV continuous variable, excellent object in semiconductor lighting Reason, chemical stability, high saturated electrons mobility etc., etc. characteristics, become laser, light emitting diode etc. photoelectron device The optimal material selection of part.
However, large area GaN material now is grown in mostly due to the limitation of GaN (gallium nitride) growing technology itself In Sapphire Substrate.Although the GaN of Grown on Sapphire Substrates is of high quality, using also most wide, but due to it is sapphire not Conductive and poor thermal conduction characteristic significantly limits the development of GaN (third generation semiconductor material) based semiconductor device.In order to Avoid this disadvantage, after sapphire growth GaN base device, sapphire is removed, and replace high thermal conductivity, highly conductive Si, Cu etc. The method of substrate is invented.During sapphire removal, main method to be applied is exactly laser lift-off technique.Although blue The GaN grown on jewel substrate is of high quality, and application is also very extensive, but, since Sapphire Substrate and GaN crystal are heterogeneous Material, there are a great differences for the lattice constant and thermal expansion coefficient of the two, and the lattice constant between GaN and Sapphire Substrate is lost With degree more than 14%, thermal mismatching degree is differed more than one times, and lattice mismatch big in this way and differential thermal expansion will necessarily cause in indigo plant The residual mechanical stress problem of GaN epitaxy piece is grown on jewel substrate, when removing is easy to break.
In laser lift-off, for peeling GaN thickness at 4-5 microns, the fragmentation problem in stripping process is not serious, and thick When degree is more than 50 microns, wants completely to strip down GaN film with regard to extremely difficult using common removing mode, can generate broken It splits.
The patent of invention of Patent No. " 200910136458.9 " discloses a kind of " solid laser lift and cutting integration Equipment " is by laser lift-off GaN epitaxy piece, however, it was found that it provides adding for preference temperature to removing environment due to lacking Hot heating device leads to easily cause the residual mechanical stress problem for growing GaN epitaxy piece on a sapphire substrate, and when removing is fragile It splits.
Summary of the invention
In order to solve the above-mentioned technical problem, the object of the present invention is to provide a kind of heating laser peel-off devices, to solve indigo plant The residual mechanical stress problem of the GaN epitaxy piece grown on jewel substrate avoids cover thickness easy fragmentation when removing when being more than 50 microns The case where occur.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
A kind of heating laser peel-off device, including laser lift-off apparatus body, the laser lift-off apparatus body include setting It is placed in the mobile platform of lower end, the mobile platform is provided with heated base, and sample stage is provided on the heated base, described Heated base includes the electric heater unit being set to below the sample stage and for heating to the sample stage, the sample stage Lower end is additionally provided with the temperature sensor for test sample platform temperature, is covered with insulation cover, the heat preservation above the sample stage The heat-insulation transparent window for facilitating laser to pass through is provided on position corresponding to the top of cover and the sample stage.
Further, the laser lift-off apparatus body includes solid state laser, beam shaping mirror, beam expanding lens, galvanometer electricity Machine, galvanometer eyeglass, field lens and NI Vision Builder for Automated Inspection further include that industrial PC and control software, the beam shaping mirror are located at institute It states below solid state laser, the beam expanding lens, galvanometer eyeglass, galvanometer motor and field lens, beam shaping mirror are located at the solid and swash After light device, the laser beam reshaping that the solid state laser is issued, the galvanometer motor is located at before field lens, according to control software The instruction of sending controls the movement of the galvanometer eyeglass, to realize different scan path and cutting path, the movement is flat Platform is located at below the solid state laser, and the control software is run on the industrial PC.
Further, the lower end of the insulation cover is connected and fixed in the groove of the heated base upper end.
Further, cavity is provided in the side inner wall of the insulation cover, winding is provided with cooling water in the cavity Circulation pipe, wherein the inlet and outlet of the cooling water circulation pipe are located on the outer wall of the insulation cover.
Further, the temperature sensor is thermocouple.
Further, the electric heater unit is electric heating wire or electric heating sheets or electric heating lamp.
Further, the temperature sensor and electric heater unit are connect with engineering computer respectively.
Further, the electric heater unit is used to the sample stage being heated to 800-1200 DEG C in 3-5min, such as 900 DEG C or 1000 DEG C.
Further, the height of the heating cavity constituted between the insulation cover and heated base is 300-500mm, preferably 300-400mm。
Further, the transparency window is the heatproof lens or heat-protecting glass for not absorbing laser
Wherein the beam shaping mirror is shaped as laser facula the small light spot of different geometries.In solid of the invention Laser lift-off and cutting integration apparatus in, the geometry include square, rectangle, circle, ellipse, pentagon and Hexagon.3-1000 microns of small light spot Zhou Changwei of square hot spot.The circular light spot that small light spot is diameter 3-300 microns.It is small Spot center energy is most strong, and energy gradually dies down around.The NI Vision Builder for Automated Inspection includes imaging lens, CCD, video acquisition Card, mobile work platform.Have the function of removing and cutting simultaneously.The beam expander mirror and the beam shaping mirror work simultaneously Make.In solid laser lift of the invention and cutting integration apparatus, the beam expander mirror and the beam shaping mirror point When work.The laser is used to remove and cut simultaneously.Used laser is the DPSS solid that wavelength is less than 400nm Laser.
Compared with prior art, advantageous effects of the invention:
Since Sapphire Substrate and GaN crystal are dissimilar materials, the lattice constant and thermal expansion coefficient of the two exist very Different, the lattice constant mismatch degree between GaN and Sapphire Substrate is more than 14%, and thermal mismatching degree differs more than one times, big in this way Lattice mismatch and differential thermal expansion will necessarily cause the residual mechanical stress problem for growing GaN epitaxy piece on a sapphire substrate, Easy to break when removing, sample stage when being given by heating device using laser lift-off peeling GaN epitaxial wafer provides suitable temperature Degree environment (800-1000 DEG C is heated in 3-5min, can guarantee to greatest extent at this temperature peeling effect and meanwhile avoid to every The influence of the translucency of hot transparency window), it reduces since there are a great differences to cause for the lattice constant and thermal expansion coefficient of the two Lattice constant thermal mismatching between GaN and Sapphire Substrate spends high problem, while being covered sample stage by insulation cover, makes It is in a closed heating cavity, guarantees peeling effect, further decreases risk easy to break when removing, cavity cavity Height is 300-500mm (preferably 300-400mm), avoids height too self raising flour dirt window easy to pollute, while avoiding due to highly too It is low that lens is caused to cause light transmittance to change even fragmentation due to heat radiation denaturation;Heat-insulation transparent window can facilitate laser to pass through and not Laser, laser energy free of losses are absorbed, and its thermal insulation can be effectively protected well laser head and avoid laser head excessively high It is damaged under heat.
Detailed description of the invention
The invention will be further described for explanation with reference to the accompanying drawing.
Fig. 1 is the structural schematic diagram of the heating device on the mobile platform of heating laser peel-off device of the present invention;
Fig. 2 is the schematic diagram of cooling water-circulating pipe;
Description of symbols: 1- heated base;2- electric heater unit;3- sample stage;4- thermocouple;5- protective cover;6- every Thermal lens;7- water inlet;8- water outlet;9- cools down water-circulating pipe;10- mobile platform.
Specific embodiment
A kind of heating laser peel-off device, including the laser lift-off apparatus body (specific structure of laser lift-off apparatus body With application method referring to the patent in background technique), the laser lift-off apparatus body includes the mobile platform for being set to lower end 10, as shown in Figure 1, being provided with heated base 1 on the mobile platform 10, it is provided with sample stage on the heated base 1, it is described Heated base 1 includes being set to 3 lower section of sample stage and the electric heater unit 2 for heating to the sample stage 3, the sample 3 lower end of sample platform is additionally provided with the thermocouple 4 for 3 temperature of test sample platform, and insulation cover 5 is covered with above the sample stage 3, described The heatproof lens 6 for facilitating laser to pass through are provided on position corresponding to the top of insulation cover 5 and the sample stage 3.
In the present embodiment, the lower end of the insulation cover 6 is connected and fixed in the groove 101 of 1 upper end of heated base.Such as Shown in Fig. 2, cavity is provided in the side inner wall of the insulation cover 5, winding is provided with cooling water-circulating pipe 9 in the cavity, Wherein the water inlet 7 of the cooling water circulation pipe 9 and water outlet 8 are located on the outer wall of the insulation cover 5.The electric heating Device 2 is electric heating wire or electric heating sheets, such as nichrome point heater strip.The thermocouple 4 and electric heater unit 2 respectively with work The connection of journey computer, engineering computer are used for the working condition of the feedback control electric heater unit 2 according to thermocouple 4.The electric heating Device 2 is used to the sample stage being heated to 600-1500 DEG C, preferably 800-1200 DEG C in 3-5min, such as 800 DEG C, 900 DEG C, 1000 DEG C etc..The control circuit being related to is ordinary skill in the art means, not excessive herein to repeat.
In use, then covering upper protective cover 5 by being placed on sample stage 3 in the Sapphire Substrate of growth GaN material, opening Dynamic electric heater unit 2, to be heated to set temperature, thermocouple feedback signal gives engineering computer, and control electric heater unit stops adding Then with by laser head the Sapphire Substrate that growth GaN material is irradiated in the scanning of laser light heatproof lens 6 occurs for heat, to reach To the purpose of peeling GaN epitaxial wafer.It is located at suitable temperature environment when due to GaN epitaxy piece, avoids due to GaN material and indigo plant There are a great differences, and lattice constant thermal mismatching between the two to be caused to be spent for the lattice constant and thermal expansion coefficient of jewel substrate High problem.And heatproof lens 6 can facilitate laser to pass through and laser head is effectively protected, and avoid laser head in excessively high heat The lower damage of amount.
Embodiment 1
A kind of heating laser peel-off device, including the laser lift-off apparatus body (specific structure of laser lift-off apparatus body With application method referring to the patent in background technique), the laser lift-off apparatus body includes the mobile platform for being set to lower end 10, as shown in Figure 1, being provided with heated base 1 on the mobile platform 10, it is provided with sample stage on the heated base 1, it is described Heated base 1 includes being set to 3 lower section of sample stage and the electric heater unit 2 for heating to the sample stage 3, the sample 3 lower end of sample platform is additionally provided with the thermocouple 4 for 3 temperature of test sample platform, and insulation cover 5 is covered with above the sample stage 3, described The heatproof lens 6 for facilitating laser to pass through are provided on position corresponding to the top of insulation cover 5 and the sample stage 3.The guarantor The lower end of temperature cover 6 is connected and fixed in the groove 101 of 1 upper end of heated base.As shown in Fig. 2, the side of the insulation cover 5 Be provided with cavity in inner wall, winding is provided with cooling water-circulating pipe 9 in the cavity, wherein the cooling water circulation pipe 9 into The mouth of a river 7 and water outlet 8 are located on the outer wall of the insulation cover 5.The electric heater unit 2 is electric heating wire or electric heating Piece, such as nichrome point heater strip.The thermocouple 4 and electric heater unit 2 are connect with engineering computer respectively, and engineering computer is used for According to the working condition of the feedback control electric heater unit 2 of thermocouple 4.The electric heater unit 2 is by the sample stage in 4min Inside it is heated to 900 DEG C.
Embodiment 2
It is other same as Example 1, the difference is that insulation cover 6, which is not used, forms closed heating cavity.
Embodiment 3
It is other same as Example 1, the difference is that the electric heater unit 2 adds the sample stage in 4min Heat is to 600 DEG C or 700 DEG C.
Embodiment 4
It is other same as Example 1, the difference is that the electric heater unit 2 adds the sample stage in 4min Heat is to 1300 DEG C.
Embodiment 5
It is other same as Example 1, the difference is that the electric heater unit 2 adds the sample stage in 4min Heat is to 1600 DEG C.
Embodiment 6
It is other same as Example 1, the difference is that not added using the electric heater unit 2 to the sample stage Heat.
Embodiment 7
It is other same as Example 1, the difference is that the electric heater unit 2 adds the sample stage in 4min Heat is to 1200 DEG C.
Embodiment 8
It is other same as Example 1, the difference is that the electric heater unit 2 adds the sample stage in 4min Heat is to 800 DEG C.
The result of each embodiment is as shown in the table:
In actual operation when laser lift-off, for peeling GaN thickness at 4-5 microns, the fragmentation problem in stripping process is simultaneously It is not serious, and when thickness is more than 50 microns, want completely to strip down GaN film using common removing mode and just be stranded very much Difficulty can generate fragmentation.The present invention is by a large amount of research and practice discovery, when cover thickness is more than 50 microns, by sample Sample platform is heated to 800-1200 DEG C and insulation cover is used to form heat preservation (heating) chamber heat preservation, can effectively avoid using commonly Removing mode leads to the problem of fragmentation when completely stripping down GaN film, and peeling effect stability is high, tests 20 times Removing, without a fragmentation phenomenon;When without heating, 20 removings are tested, 12 fragmentations occur;And when heating but not keeping the temperature, examination 20 removings are tested, 6 fragmentations occur.It can be seen that by being heated to 800-1200 DEG C to sample stage and forming heat preservation using insulation cover The heat preservation of (heating) chamber effectively avoids completely removing the GaN film that thickness is more than 50 microns using common removing mode Fragmentation is led to the problem of when getting off.
Embodiment described above is only that preferred embodiment of the invention is described, and is not carried out to the scope of the present invention It limits, without departing from the spirit of the design of the present invention, those of ordinary skill in the art make technical solution of the present invention Various changes and improvements, should all fall into claims of the present invention determine protection scope in.

Claims (10)

1. a kind of heating laser peel-off device, including laser lift-off apparatus body, the laser lift-off apparatus body includes setting Mobile platform in lower end, it is characterised in that: the mobile platform is provided with heated base, is provided with sample on the heated base Sample platform, the heated base include the electric heater unit being set to below the sample stage and for heating to the sample stage, The sample stage lower end is additionally provided with the temperature sensor for test sample platform temperature, is covered with heat preservation above the sample stage The heat-insulation transparent window for facilitating laser to pass through is provided on position corresponding to cover, the top of the insulation cover and the sample stage.
2. heating laser peel-off device according to claim 1, it is characterised in that: the laser lift-off apparatus body includes Solid state laser, beam shaping mirror, beam expanding lens, galvanometer motor, galvanometer eyeglass, field lens and NI Vision Builder for Automated Inspection, further include industry control Computer and control software, the beam shaping mirror are located at below the solid state laser, the beam expanding lens, galvanometer eyeglass, galvanometer Motor and field lens, beam shaping mirror are located at after the solid state laser, the laser beam reshaping that the solid state laser is issued, The galvanometer motor is located at before field lens, the movement of the galvanometer eyeglass is controlled according to the instruction that control software issues, to realize Different scan paths and cutting path, the mobile platform are located at below the solid state laser, the control software operation On the industrial PC.
3. heating laser peel-off device according to claim 1, it is characterised in that: the lower end of the insulation cover connects and fixes In in the groove of the heated base upper end.
4. heating laser peel-off device according to claim 1, it is characterised in that: set in the side inner wall of the insulation cover It is equipped with cavity, winding is provided with cooling water-circulating pipe in the cavity, wherein the water inlet of the cooling water circulation pipe and water outlet Mouth is located on the outer wall of the insulation cover.
5. heating laser peel-off device according to claim 1, it is characterised in that: the temperature sensor is thermocouple.
6. heating laser peel-off device according to claim 1, it is characterised in that: the electric heater unit is electric heating wire Or electric heating sheets or electric heating lamp.
7. heating laser peel-off device according to claim 1, it is characterised in that: the temperature sensor and electric heating dress It sets and is connect respectively with engineering computer.
8. heating laser peel-off device according to claim 1, it is characterised in that: the electric heater unit is used for will be described Sample stage is heated to 800-1200 DEG C in 3-5min.
9. heating laser peel-off device according to claim 1, it is characterised in that: between the insulation cover and heated base The height of the heating cavity of composition is 300-500mm.
10. heating laser peel-off device according to claim 7, it is characterised in that: the transparency window be heatproof lens or Glass.
CN201811196018.8A 2018-10-15 2018-10-15 Heating laser stripping equipment Active CN109148369B (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN110085537A (en) * 2019-04-15 2019-08-02 东莞市中镓半导体科技有限公司 The device for high-temperature laser removing of temperature-controllable
CN110102877A (en) * 2019-05-07 2019-08-09 东莞市中镓半导体科技有限公司 The laser lift-off device and method of liquid metal auxiliary heat conduction
CN110534477A (en) * 2019-08-26 2019-12-03 东莞市中镓半导体科技有限公司 The integrated equipment of laser lift-off
CN113432379A (en) * 2021-07-30 2021-09-24 上海睿昇半导体科技有限公司 Heating and cooling integrated tray body and manufacturing method and application thereof
CN113628960A (en) * 2021-07-28 2021-11-09 山东大学 High-temperature laser stripping device and method for GaN single crystal substrate on sapphire template

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CN208889638U (en) * 2018-10-15 2019-05-21 保定中创燕园半导体科技有限公司 A kind of heating laser peel-off device

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CN110102877A (en) * 2019-05-07 2019-08-09 东莞市中镓半导体科技有限公司 The laser lift-off device and method of liquid metal auxiliary heat conduction
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CN113628960A (en) * 2021-07-28 2021-11-09 山东大学 High-temperature laser stripping device and method for GaN single crystal substrate on sapphire template
CN113628960B (en) * 2021-07-28 2024-03-22 山东大学 High-temperature laser stripping device and method for GaN single crystal substrate on sapphire template
CN113432379A (en) * 2021-07-30 2021-09-24 上海睿昇半导体科技有限公司 Heating and cooling integrated tray body and manufacturing method and application thereof

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