CN109137507A - 一种床上用纺织品的柔软剂 - Google Patents
一种床上用纺织品的柔软剂 Download PDFInfo
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- 239000004753 textile Substances 0.000 title claims abstract description 31
- 239000004902 Softening Agent Substances 0.000 title claims abstract description 27
- -1 triethanolamine ester Chemical class 0.000 claims abstract description 41
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 36
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 36
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 19
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 19
- 239000003760 tallow Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 15
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000005342 ion exchange Methods 0.000 claims description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 125000000217 alkyl group Chemical group 0.000 abstract description 4
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 abstract description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229950007687 macrogol ester Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/17—Halides of elements of Groups 3 or 13 of the Periodic Table
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
本发明涉及一种床上用纺织品的柔软剂，属于精细化工技术领域。本发明的家用纺织品柔软剂包括以下按照重量份数计的原料：三乙醇胺酯基季铵盐10‑15份、咪唑啉季铵盐10‑15份、双十八烷基二甲基氯化铵5‑18份、二牛油烷基二甲基氯化铵2‑10份、乙二醇2‑16份、异丙醇1‑12份、吐温201‑10份、聚乙二醇1‑5份、氯化铝2‑5份、水50‑80份。本发明采用合理的原料和配比，成本低，柔软效果合理适中。
Description
技术领域
本发明涉及一种柔软剂，更具体地说，本发明涉及一种床上用纺织品的柔软剂，属于精细化工技术领域。
背景技术
中国是纺织品生产和出口的大国，中国纺织行业自身经过多年的发展，竞争优势十分明显，具备世界上最完整的产业链，最高的加工配套水平，众多发达的产业集群地应对市场风险的自我调节能力不断增强，给行业保持稳健的发展步伐提供了坚实的保障。从国际环境看，国际市场仍有较大拓展空间和机遇。随着2007年底中欧纺织品设限纺织品到期、2008年底中美纺织品配额设限结束，中国纺织品无配额时代即将来临，约占全球纺织品市场60%以上份额地区全面开放，将会给中国纺织品贸易带来巨大机遇。而未来几年世界经济仍将处于上升区间，必将促进国际贸易的增长，这将给中国纺织品服装出口增长带来有利的国际市场保障。
国家知识产权局于2014.9.17公开了一件公开号为CN104047165A，名称为“一种生产毛巾的柔软剂及其制备方法”的发明专利，该专利公开了一种生产毛巾的柔软剂，由十二烷基硫酸钠、氨基三亚甲基膦酸五钠、聚乙二醇酯和柠檬酸组成；所述的组成原料都选用固体原料，其制备方法是将固体十二烷基硫酸钠、固体氨基三亚甲基膦酸五钠、固体聚乙二醇酯按2∶1∶1的质量比例混合，加热到60℃，搅拌完全后加入柠檬酸进行调和，使混合物成微酸性，PH达到6-6.5，用3℃-5℃的进行水浴冷却，直到混合物冷却成固态，最后对混合物成型包装。本发明提供的生产毛巾的柔软剂具有高柔软度和高舒适度的优点，制备工艺简单，可以大大的降低生产成本以及生产时间。
上述专利中的柔软剂成本较高，柔软效果过于柔软，不适用于很多家用纺织品。
发明内容
本发明旨在解决现有技术中的问题，提供一种床上用纺织品的柔软剂，达到成本低，柔软效果合理适中的目的，具备优越的生物降解性能。
为了实现上述发明目的，其具体技术方案如下：
一种床上用纺织品的柔软剂，其特征在于：包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 8-15份
咪唑啉季铵盐 8-15份
双十八烷基二甲基氯化铵 5-18份
二牛油烷基二甲基氯化铵 2-10份
乙二醇 2-16份
异丙醇 1-12份
吐温20 1-10份
聚乙二醇 1-5份
氯化铝 2-5份
水 50-80份。
本发明所述的一种床上用纺织品的柔软剂，其特征在于：包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 10-15份
咪唑啉季铵盐 10-15份
双十八烷基二甲基氯化铵 6-15份
二牛油烷基二甲基氯化铵 5-9份
乙二醇 3-15份
异丙醇 2-10份
吐温20 3-9份
聚乙二醇 2-4份
氯化铝 3-4份
水 55-76份。
本发明所述的一种床上用纺织品的柔软剂，其特征在于：包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 10份
咪唑啉季铵盐 10份
双十八烷基二甲基氯化铵 10份
二牛油烷基二甲基氯化铵 9份
乙二醇 8份
异丙醇 7份
吐温20 6份
聚乙二醇 5份
氯化铝 4份
水 66份。
本发明所述的二牛油烷基二甲基氯化铵为50-60%的甲醇溶液。
本发明所述的聚乙二醇的分子量为300-400。
本发明所述的氯化铝为20-40%的水溶液。
本发明所述的水为离子交换水。
本发明带来的有益技术效果：
本发明解决了现有技术中柔软剂成本较高，柔软效果过于柔软，不适用于很多家用纺织品的问题。本发明采用合理的原料和配比，成本低，柔软效果合理适，具备优越的生物降解性能。
具体实施方式
实施例1
一种床上用纺织品的柔软剂，包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 8份
咪唑啉季铵盐 8份
双十八烷基二甲基氯化铵 5份
二牛油烷基二甲基氯化铵 2份
乙二醇 2份
异丙醇 1份
吐温20 1份
聚乙二醇 1份
氯化铝 2份
水 50份。
实施例2
一种床上用纺织品的柔软剂，包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 15份
咪唑啉季铵盐 15份
双十八烷基二甲基氯化铵 18份
二牛油烷基二甲基氯化铵 10份
乙二醇 16份
异丙醇 12份
吐温20 10份
聚乙二醇 5份
氯化铝 5份
水 80份。
实施例3
一种床上用纺织品的柔软剂，包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 14份
咪唑啉季铵盐 14份
双十八烷基二甲基氯化铵 12份
二牛油烷基二甲基氯化铵 6份
乙二醇 9份
异丙醇 5.5份
聚乙二醇 3份
氯化铝 3.5份
水 65份。
实施例4
一种床上用纺织品的柔软剂，包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 9份
咪唑啉季铵盐 9份
双十八烷基二甲基氯化铵 10份
二牛油烷基二甲基氯化铵 8份
乙二醇 10份
异丙醇 8份
吐温20 10份
聚乙二醇 2份
氯化铝 3份
水 70份。
实施例5
一种床上用纺织品的柔软剂，包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 10份
咪唑啉季铵盐 10份
双十八烷基二甲基氯化铵 10份
二牛油烷基二甲基氯化铵 9份
乙二醇 8份
异丙醇 7份
吐温20 6份
聚乙二醇 5份
氯化铝 4份
水 66份。
实施例5
在实施例1-4的基础上，优选的：
所述的二牛油烷基二甲基氯化铵为50%的甲醇溶液。
所述的聚乙二醇的分子量为300。
所述的氯化铝为20%的水溶液。
所述的水为离子交换水。
实施例6
在实施例1-4的基础上，优选的：
所述的二牛油烷基二甲基氯化铵为60%的甲醇溶液。
所述的聚乙二醇的分子量为400。
所述的氯化铝为40%的水溶液。
所述的水为离子交换水。
实施例7
在实施例1-4的基础上，优选的：
所述的二牛油烷基二甲基氯化铵为55%的甲醇溶液。
所述的聚乙二醇的分子量为300。
所述的氯化铝为30%的水溶液。
所述的水为离子交换水。
实施例8
在实施例1-4的基础上，优选的：
所述的二牛油烷基二甲基氯化铵为52%的甲醇溶液。
所述的聚乙二醇的分子量为400。
所述的氯化铝为33%的水溶液。
所述的水为离子交换水。
Claims (7)
1.一种床上用纺织品的柔软剂，其特征在于：包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 8-15份
咪唑啉季铵盐 8-15份
双十八烷基二甲基氯化铵 5-18份
二牛油烷基二甲基氯化铵 2-10份
乙二醇 2-16份
异丙醇 1-12份
吐温20 1-10份
聚乙二醇 1-5份
氯化铝 2-5份
水 50-80份。
2.根据权利要求1所述的一种床上用纺织品的柔软剂，其特征在于：包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 10-15份
咪唑啉季铵盐 10-15份
双十八烷基二甲基氯化铵 6-15份
二牛油烷基二甲基氯化铵 5-9份
乙二醇 3-15份
异丙醇 2-10份
吐温20 3-9份
聚乙二醇 2-4份
氯化铝 3-4份
水 55-76份。
3.根据权利要求1所述的一种床上用纺织品的柔软剂，其特征在于：包括以下按照重量份数计的原料：
三乙醇胺酯基季铵盐 10份
咪唑啉季铵盐 10份
双十八烷基二甲基氯化铵 10份
二牛油烷基二甲基氯化铵 9份
乙二醇 8份
异丙醇 7份
吐温20 6份
聚乙二醇 5份
氯化铝 4份
水 66份。
4.根据权利要求1、2或3中任意一项所述的一种床上用纺织品的柔软剂，其特征在于：所述的二牛油烷基二甲基氯化铵为50-60%的甲醇溶液。
5.根据权利要求1、2或3中任意一项所述的一种床上用纺织品的柔软剂，其特征在于：所述的聚乙二醇的分子量为300-400。
6.根据权利要求1、2或3中任意一项所述的一种床上用纺织品的柔软剂，其特征在于：所述的氯化铝为20-40%的水溶液。
7.根据权利要求1、2或3中任意一项所述的一种床上用纺织品的柔软剂，其特征在于：所述的水为离子交换水。
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| CN110284328A (zh) * | 2019-06-04 | 2019-09-27 | 郑州洁灵科技有限公司 | 一种新型环保织物柔软剂及其制备方法 |
| CN113502588A (zh) * | 2021-08-02 | 2021-10-15 | 杭州职业技术学院 | 一种阻燃复合服装面料及其生产方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110284328A (zh) * | 2019-06-04 | 2019-09-27 | 郑州洁灵科技有限公司 | 一种新型环保织物柔软剂及其制备方法 |
| CN113502588A (zh) * | 2021-08-02 | 2021-10-15 | 杭州职业技术学院 | 一种阻燃复合服装面料及其生产方法 |
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