CN109135454A - A kind of colorful noctilucent emulsion glue and preparation method thereof - Google Patents

A kind of colorful noctilucent emulsion glue and preparation method thereof Download PDF

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Publication number
CN109135454A
CN109135454A CN201810985113.XA CN201810985113A CN109135454A CN 109135454 A CN109135454 A CN 109135454A CN 201810985113 A CN201810985113 A CN 201810985113A CN 109135454 A CN109135454 A CN 109135454A
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CN
China
Prior art keywords
stirring
added
emulsion glue
defoaming agent
colorful noctilucent
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CN201810985113.XA
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Chinese (zh)
Inventor
钱小华
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NINGBO PASCO UNITED INDUSTRY Co Ltd
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NINGBO PASCO UNITED INDUSTRY Co Ltd
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Priority to CN201810985113.XA priority Critical patent/CN109135454A/en
Publication of CN109135454A publication Critical patent/CN109135454A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/45Anti-settling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of colorful noctilucent emulsion glue of the invention, the weight percent of each raw material are as follows: antifreeze: 1.0-10.0%, stickum: 5.0-20.0%, thickener: 0-5.0%, suspension aids: 0.1-5.0%, lotion: 10.0-60.0%, surfactant: 0.01-0.5%, plasticizer: 1.0-10.0%, defoaming agent: 0-0.5%, preservative: 0.1%-0.5%, mill base: 0-0.5%, luminescent powder: 1.0-10.0%, remaining as water;Preparation method: water, antifreeze are added in a kettle, stickum, thickener, surfactant and part defoaming agent is added in stirring, dissolution is added in heating after standing defoaming, add lotion after cooling, again plus suspension aids, plasticizer and remaining defoaming agent, additive color slurry, luminescent powder and preservative discharge filling after standing defoaming.

Description

A kind of colorful noctilucent emulsion glue and preparation method thereof
Technical field
The present invention relates to a kind of emulsion glue, a kind of colorful noctilucent emulsion glue and preparation method thereof is referred specifically to.
Background technique
Currently, emulsion glue in the market is PVAc lotion, polyacrylate dispersion etc., be all it is white, color is more single One, it is not abundant enough.Also having part is that color has been added to be made colored emulsion glue, and color is that comparison is abundant, but if in dark Place or when bad night light, then these emulsion glues can not just be seen, lack highlighting.The people that emulsion glue uses Group is greatly children, student, is mainly used for manual DIY and makes, paints, doing crystal mud etc., if emulsion glue can be in dark Or the imperfect place of light can show different illumination effects, while give colourful visual effect, Ke Yizeng Add interest and creativeness, unexpected effect can be generated in use, but will be presented after crystal mud is made colourful Colorful visual perception's effect, when for before glue desiccation and different illumination effects can be presented after desiccation when painting, decorating. As described a kind of colorful noctilucent paint in patent of invention CN102533037A, a kind of night for being made into using pure-acrylic emulsion as adhesive Optical coating can shine at dark or night, but because being mainly used for decorative paint added with harmful substances such as ethylene glycol, It cannot function as children's coating.
Summary of the invention
The technical problem to be solved by the present invention is to be directed to above-mentioned state of the art, and provide under night or dark condition A kind of colorful noctilucent emulsion glue that can be shone, illumination effect is good, lighting time interval is long after desiccation, and adhesive property is good, and And environmental protection, without insalubrious substances such as formaldehyde;Preparation method simple process, it is with short production cycle.
The technical scheme of the invention to solve the technical problem is:
A kind of colorful noctilucent emulsion glue, the weight percent of each raw material are as follows:
Antifreeze: 1.0%-10.0%;
Stickum: 5.0%-20.0%;
Thickener: 0%-5.0%;
Suspension aids: 0.1%-5.0%;
Lotion: 10.0%-60.0%;
Surfactant: 0.01%-0.5%;
Plasticizer: 1.0%-10.0%;
Defoaming agent: 0%-0.5%;
Preservative: 0.1%-0.5%;
Mill base: 0%-0.5%;
Luminescent powder: 1.0%-10.0%;
Remaining as water, the summation of above-mentioned each component is 100%.
To optimize above-mentioned technical proposal, the measure taken further include:
Above-mentioned stickum is hydrosoluble adhesive substance, and the hydrosoluble adhesive substance is polyvinyl alcohol, one in starch The mixing of kind either polyvinyl alcohol and starch.
Above-mentioned thickener is the mixing of one of xanthan gum, guar gum either xanthan gum and guar gum.
Above-mentioned antifreeze is the mixing of one of propylene glycol, glycerol either propylene glycol and glycerol.
Above-mentioned suspension aids are one of polyacrylamide, cellulose ethers either polyacrylamide and cellulose The mixing of ethers.
Above-mentioned lotion is PVAc lotion.
Above-mentioned surfactant is dodecyl sodium sulfate.
Above-mentioned defoaming agent is aqueous polyether antifoam agent or waterborne organic silicon class defoaming agent.
Above-mentioned preservative is the preservative of food preservative or cosmetics-stage.
A kind of preparation method of colorful noctilucent emulsion glue, comprising the following steps:
Step 1: preparing raw material, and water is added in a kettle, antifreeze is then added while stirring, is uniformly mixed;
Step 2: stickum, thickener, surfactant and part defoaming agent are added while stirring, stirring 50min is extremely 70min, and stood according to dispersion infiltration and bubble situation, be completely dissolved stickum and eliminate part bubble or whole gas Bubble;
Step 3: warming while stirring to 80 DEG C to 90 DEG C, keeps constant temperature, is uniformly dissolved substance thoroughly;
Step 4: being cooled while stirring to 50 DEG C, lotion is added, is uniformly dissolved;
Suspension aids, plasticizer and remaining defoaming agent, mixing time 5min are added while stirring Step 5: being added while stirring To 10min, mix them thoroughly uniformly;
Step 6: mill base and luminescent powder is added, it is stirring evenly and then adding into preservative, continuing stirring 30min to 60min keeps mixing equal It is even, after standing defoaming, discharge filling.
Compared with prior art, the present invention uses addition mill base and luminescent powder in emulsion glue and manufactured colorful noctilucent is newborn Liquid glue, is added to suspension aids in preparation process to prevent luminescent powder from settling in standing defoaming process, made Emulsion glue has certain transparency that light can be made to enter and project, to reach preferable luminous effect.This colorful noctilucent lotion Glue sticking performance is good, and environmental protection, is free of insalubrious substance, and use is fool proof, is suitble to making for children, student etc. With.
Specific embodiment
Present invention is further described in detail with reference to embodiments.
A kind of colorful noctilucent emulsion glue, the weight percent of each raw material are as follows:
Antifreeze: 1.0%-10.0%;
Stickum: 5.0%-20.0%;
Thickener: 0%-5.0%;
Suspension aids: 0.1%-5.0%;
Lotion: 10.0%-60.0%;
Surfactant: 0.01%-0.5%;
Plasticizer: 1.0%-10.0%;
Defoaming agent: 0%-0.5%;
Preservative: 0.1%-0.5%;
Mill base: 0%-0.5%;
Luminescent powder: 1.0%-10.0%;
Remaining as water, the summation of above-mentioned each component is 100%.
The stickum is hydrosoluble adhesive substance, and the hydrosoluble adhesive substance is polyvinyl alcohol (PVA), forms sediment The mixing of one of powder either polyvinyl alcohol and starch.
The thickener is the mixing of one of xanthan gum, guar gum either xanthan gum and guar gum.
The antifreeze is the mixing of one of propylene glycol, glycerol either propylene glycol and glycerol.
The suspension aids are one of polyacrylamide, cellulose ethers either polyacrylamide and cellulose The mixing of ethers.
The lotion is PVAc lotion.PVAc lotion desiccation film forming caudacoria has certain transparency, and transparency is higher Better.
The surfactant is dodecyl sodium sulfate.
The defoaming agent is aqueous polyether antifoam agent or waterborne organic silicon class defoaming agent.
The preservative is the preservative of food preservative or cosmetics-stage.
The water uses deionized water.
A kind of preparation method of colorful noctilucent emulsion glue, comprising the following steps:
Step 1: preparing raw material, and water is added in a kettle, antifreeze is then added while stirring, is uniformly mixed;
Step 2: stickum, thickener, surfactant and part defoaming agent are added while stirring, stirring 50min is extremely 70min, and stood according to dispersion infiltration and bubble situation, be completely dissolved stickum and eliminate part bubble or whole gas Bubble;
Step 3: warming while stirring to 80 DEG C to 90 DEG C, keeps constant temperature, is uniformly dissolved substance thoroughly;
Step 4: being cooled while stirring to 50 DEG C, lotion is added, is uniformly dissolved;
Suspension aids, plasticizer and remaining defoaming agent, mixing time 5min are added while stirring Step 5: being added while stirring To 10min, mix them thoroughly uniformly;
Step 6: mill base and luminescent powder is added, it is stirring evenly and then adding into preservative, continuing stirring 30min to 60min keeps mixing equal It is even, after standing defoaming, discharge filling.
It is illustrated below by specific embodiment.
Embodiment one:
Prepare raw material according to following weight percent:
Deionized water: 34.7%;
Antifreeze (glycerol): 2.0%;
Stickum (PVA): 7.5%;
Thickener (xanthan gum): 0.6%;
Suspension aids (cellulose ether): 0.50%;
Lotion (PVAc lotion): 45.0%;
Surfactant (dodecyl sodium sulfate): 0.1%;
Plasticizer: 3.0%;
Defoaming agent (aqueous polyether antifoam agent): 0.3%;
Preservative (food preservative): 0.1%;
Mill base (food colour): 0.2%;
Luminescent powder: 6.0%.
A kind of preparation method of colorful noctilucent emulsion glue, comprising the following steps:
Step 1: preparing raw material, and deionized water is added in a kettle, antifreeze (glycerol) then is added while stirring, mixes It closes uniform;
Step 2: stickum (PVA), thickener (xanthan gum), surfactant (dodecyl sodium sulfonate are added while stirring Sodium) and part defoaming agent (aqueous polyether antifoam agent), 50min to 70min is stirred, and quiet according to dispersion infiltration and bubble situation It sets, be completely dissolved stickum and eliminate part bubble or whole bubbles;
Step 3: warming while stirring to 80 DEG C to 90 DEG C, keeps constant temperature, is uniformly dissolved substance thoroughly;
Step 4: being cooled while stirring to 50 DEG C, it is added lotion (PVAc lotion), is uniformly dissolved;
Suspension aids (cellulose ether), plasticizer and remaining defoaming agent, stirring are added while stirring Step 5: being added while stirring Time is 5min to 10min, is mixed them thoroughly uniformly;
Step 6: mill base (food colour) and luminescent powder is added, it is stirring evenly and then adding into preservative (food preservative), continues to stir Mix 30min makes to be uniformly mixed to 60min, after standing defoaming, discharges filling.
It is tested through experiment, the emulsion glue prepared by above-mentioned formula is (strong according to illumination by illumination 60min or longer time Depending on degree), be placed in dark surrounds observation illumination effect it is good, lighting time interval is more than 2h, is adjusted according to mill base and luminescent powder It haircuts light effect.
Embodiment two:
Prepare raw material according to following weight percent:
Deionized water: 41.0%;
Antifreeze (glycerol): 2.0%;
Stickum (PVA): 10.0%;
Thickener (xanthan gum): 0.6%;
Suspension aids (cellulose ether): 0.70%;
Lotion (PVAc lotion): 35.0%;
Surfactant (dodecyl sodium sulfate): 0.1%;
Plasticizer: 3.0%;
Defoaming agent (polyethers aqueous defoamer): 0.3%;
Preservative (preservative of cosmetics-stage): 0.1%;
Mill base (food colour): 0.2%;
Luminescent powder: 7.0%.
A kind of preparation method of colorful noctilucent emulsion glue, comprising the following steps:
Step 1: preparing raw material, and deionized water is added in a kettle, antifreeze (glycerol) then is added while stirring, mixes It closes uniform;
Step 2: stickum (PVA), thickener (xanthan gum), surfactant (dodecyl sodium sulfonate are added while stirring Sodium) and part defoaming agent (polyethers aqueous defoamer), 50min to 70min is stirred, and quiet according to dispersion infiltration and bubble situation It sets, be completely dissolved stickum and eliminate part bubble or whole bubbles;
Step 3: warming while stirring to 80 DEG C to 90 DEG C, keeps constant temperature, is uniformly dissolved substance thoroughly;
Step 4: being cooled while stirring to 50 DEG C, it is added lotion (PVAc lotion), is uniformly dissolved;
Suspension aids (cellulose ether), plasticizer and remaining defoaming agent, stirring are added while stirring Step 5: being added while stirring Time is 5min to 10min, is mixed them thoroughly uniformly;
Step 6: mill base (food colour) and luminescent powder is added, it is stirring evenly and then adding into preservative (preservative of cosmetics-stage), Continue stirring 30min makes to be uniformly mixed to 60min, after standing defoaming, discharges filling.
It is tested through experiment, the emulsion glue prepared by above-mentioned formula is (strong according to illumination by illumination 60min or longer time Depending on degree), be placed in dark surrounds observation illumination effect it is good, lighting time interval is more than 2h, is adjusted according to mill base and luminescent powder It haircuts light effect;Emulsion glue in the present embodiment, light emission luminance effect and duration are slightly promoted compared with embodiment one, gluing Effect is declined slightly compared with embodiment one.
Embodiment three:
Prepare raw material according to following weight percent:
Deionized water: 34.5%;
Antifreeze (propylene glycol): 2.0%;
Stickum (PVA and starch mixture): 7.5%;
Thickener (guar gum): 0.5%;
Suspension aids (polyacrylamide): 0.80%;
Lotion (PVAc lotion): 45.0%;
Surfactant (dodecyl sodium sulfate): 0.1%;
Plasticizer: 3.0%;
Defoaming agent (polyethers aqueous defoamer): 0.3%;
Preservative (food preservative): 0.1%;
Mill base (food colour): 0.2%;
Luminescent powder: 6.0%.
A kind of preparation method of colorful noctilucent emulsion glue, comprising the following steps:
Step 1: preparing raw material, and deionized water is added in a kettle, antifreeze (propylene glycol) then is added while stirring, It is uniformly mixed;
Step 2: stickum (PVA and starch mixture), thickener (guar gum), surfactant are added while stirring (dodecyl sodium sulfate) and part defoaming agent (polyethers aqueous defoamer) stir 50min to 70min, and are soaked according to dispersion Profit and bubble situation are stood, and are completely dissolved stickum and are eliminated part bubble or whole bubbles;
Step 3: warming while stirring to 80 DEG C to 90 DEG C, keeps constant temperature, is uniformly dissolved substance thoroughly;
Step 4: being cooled while stirring to 50 DEG C, it is added lotion (PVAc lotion), is uniformly dissolved;
Suspension aids (polyacrylamide), plasticizer and remaining defoaming agent are added while stirring Step 5: being added while stirring, stirs Mixing the time is 5min to 10min, is mixed them thoroughly uniformly;
Step 6: mill base (food colour) and luminescent powder is added, it is stirring evenly and then adding into preservative (food preservative), continues to stir Mix 30min makes to be uniformly mixed to 60min, after standing defoaming, discharges filling.
It is tested through experiment, the emulsion glue prepared by above-mentioned formula is (strong according to illumination by illumination 60min or longer time Depending on degree), good as dark surrounds observation illumination effect, lighting time interval is more than 2h, is adjusted according to mill base and luminescent powder It haircuts light effect;Emulsion glue in the present embodiment, mobility are promoted compared with embodiment one, embodiment two, illumination effect base This is as embodiment one.
Highly preferred embodiment of the present invention has illustrated, and the various change or remodeling made by those of ordinary skill in the art are not It can depart from the scope of the present invention.

Claims (10)

1. a kind of colorful noctilucent emulsion glue, it is characterized in that: the weight percent of each raw material are as follows:
Antifreeze: 1.0%-10.0%;
Stickum: 5.0%-20.0%;
Thickener: 0%-5.0%;
Suspension aids: 0.1%-5.0%;
Lotion: 10.0%-60.0%;
Surfactant: 0.01%-0.5%;
Plasticizer: 1.0%-10.0%;
Defoaming agent: 0%-0.5%;
Preservative: 0.1%-0.5%;
Mill base: 0%-0.5%;
Luminescent powder: 1.0%-10.0%;
Remaining as water, the summation of above-mentioned each component is 100%.
2. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the stickum is water-soluble viscous Property substance, the hydrosoluble adhesive substance be one of polyvinyl alcohol, starch either polyvinyl alcohol and starch mixing.
3. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the thickener is xanthan gum, melon The mixing of one of your bean gum either xanthan gum and guar gum.
4. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the antifreeze be propylene glycol, it is sweet The mixing of one of oil either propylene glycol and glycerol.
5. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the suspension aids are polyacrylamide The mixing of one of amine, cellulose ethers either polyacrylamide and cellulose ethers.
6. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the lotion is PVAc lotion.
7. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the surfactant is dodecane Base sodium sulfonate.
8. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the defoaming agent is aqueous polyethers Defoaming agent or waterborne organic silicon class defoaming agent.
9. a kind of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the preservative is food antiseptic The preservative of agent or cosmetics-stage.
10. a kind of preparation method of colorful noctilucent emulsion glue according to claim 1, it is characterized in that: the following steps are included:
Step 1: preparing raw material, and water is added in a kettle, antifreeze is then added while stirring, is uniformly mixed;
Step 2: stickum, thickener, surfactant and part defoaming agent are added while stirring, stirring 50min is extremely 70min, and stood according to dispersion infiltration and bubble situation, be completely dissolved stickum and eliminate part bubble or whole gas Bubble;
Step 3: warming while stirring to 80 DEG C to 90 DEG C, keeps constant temperature, is uniformly dissolved substance thoroughly;
Step 4: being cooled while stirring to 50 DEG C, lotion is added, is uniformly dissolved;
Suspension aids, plasticizer and remaining defoaming agent, mixing time 5min are added while stirring Step 5: being added while stirring To 10min, mix them thoroughly uniformly;
Step 6: mill base and luminescent powder is added, it is stirring evenly and then adding into preservative, continuing stirring 30min to 60min keeps mixing equal It is even, after standing defoaming, discharge filling.
CN201810985113.XA 2018-08-28 2018-08-28 A kind of colorful noctilucent emulsion glue and preparation method thereof Pending CN109135454A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110523091A (en) * 2019-08-22 2019-12-03 临沂市博士爱文具有限公司 A kind of children's safety crystal mud preparation process with antibacterial functions
CN114515536A (en) * 2022-02-28 2022-05-20 江苏路强智慧交通科技有限公司 Preparation method of noctilucent paint applied to traffic guardrail

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1230576A (en) * 1998-03-27 1999-10-06 卢伟 Luminous paint
CN103254838A (en) * 2013-05-21 2013-08-21 昆山韩保胶带科技有限公司 Preparation method of adhesive tape with fluorescent effect
CN107779018A (en) * 2017-11-24 2018-03-09 广东瑞安杰智能科技有限公司 A kind of multi-functional vinylacetate inner wall decorative coating
CN108300017A (en) * 2017-10-12 2018-07-20 西安富士得高分子化工有限公司 A method of producing crystal white glue with vinyl using lotion
CN108410394A (en) * 2018-04-02 2018-08-17 浙江凯达文具用品有限公司 A kind of water-soluble multifunctional liquid glue and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1230576A (en) * 1998-03-27 1999-10-06 卢伟 Luminous paint
CN103254838A (en) * 2013-05-21 2013-08-21 昆山韩保胶带科技有限公司 Preparation method of adhesive tape with fluorescent effect
CN108300017A (en) * 2017-10-12 2018-07-20 西安富士得高分子化工有限公司 A method of producing crystal white glue with vinyl using lotion
CN107779018A (en) * 2017-11-24 2018-03-09 广东瑞安杰智能科技有限公司 A kind of multi-functional vinylacetate inner wall decorative coating
CN108410394A (en) * 2018-04-02 2018-08-17 浙江凯达文具用品有限公司 A kind of water-soluble multifunctional liquid glue and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110523091A (en) * 2019-08-22 2019-12-03 临沂市博士爱文具有限公司 A kind of children's safety crystal mud preparation process with antibacterial functions
CN114515536A (en) * 2022-02-28 2022-05-20 江苏路强智慧交通科技有限公司 Preparation method of noctilucent paint applied to traffic guardrail
CN114515536B (en) * 2022-02-28 2023-01-03 江苏路强智慧交通科技有限公司 Preparation method of noctilucent paint applied to traffic guardrail

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Application publication date: 20190104