CN109078209A - A kind of footwear taste removal sterilized composition and preparation method thereof - Google Patents
A kind of footwear taste removal sterilized composition and preparation method thereof Download PDFInfo
- Publication number
- CN109078209A CN109078209A CN201810924736.6A CN201810924736A CN109078209A CN 109078209 A CN109078209 A CN 109078209A CN 201810924736 A CN201810924736 A CN 201810924736A CN 109078209 A CN109078209 A CN 109078209A
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- CN
- China
- Prior art keywords
- footwear
- taste removal
- mixed liquor
- sterilized composition
- cyclodextrin
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 108
- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 37
- 125000002091 cationic group Chemical group 0.000 claims abstract description 19
- 230000002070 germicidal effect Effects 0.000 claims abstract description 19
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 18
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 13
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 235000019441 ethanol Nutrition 0.000 claims description 39
- 239000012752 auxiliary agent Substances 0.000 claims description 26
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 22
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 21
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 21
- 229940041616 menthol Drugs 0.000 claims description 21
- 239000002994 raw material Substances 0.000 claims description 18
- 239000003002 pH adjusting agent Substances 0.000 claims description 17
- 239000001116 FEMA 4028 Substances 0.000 claims description 15
- 229960004853 betadex Drugs 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 14
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- -1 Alkyl dimethyl benzyl ammonium bromide Chemical compound 0.000 claims description 13
- 241000894006 Bacteria Species 0.000 claims description 13
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- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000002738 chelating agent Substances 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000000686 essence Substances 0.000 claims description 6
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
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- 235000010199 sorbic acid Nutrition 0.000 claims description 6
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- YZOUYRAONFXZSI-SBHWVFSVSA-N (1S,3R,5R,6R,8R,10R,11R,13R,15R,16R,18R,20R,21R,23R,25R,26R,28R,30R,31S,33R,35R,36R,37S,38R,39S,40R,41S,42R,43S,44R,45S,46R,47S,48R,49S)-5,10,15,20,25,30,35-heptakis(hydroxymethyl)-37,39,40,41,42,43,44,45,46,47,48,49-dodecamethoxy-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontane-36,38-diol Chemical compound O([C@@H]([C@H]([C@@H]1OC)OC)O[C@H]2[C@@H](O)[C@@H]([C@@H](O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3O)OC)O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3OC)OC)O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3OC)OC)O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3OC)OC)O3)O[C@@H]2CO)OC)[C@H](CO)[C@H]1O[C@@H]1[C@@H](OC)[C@H](OC)[C@H]3[C@@H](CO)O1 YZOUYRAONFXZSI-SBHWVFSVSA-N 0.000 claims description 4
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims description 4
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 4
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 4
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 claims description 4
- 229940080345 gamma-cyclodextrin Drugs 0.000 claims description 4
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 claims description 4
- PCWPQSDFNIFUPO-VDQKLNDWSA-N (1S,3R,5R,6S,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31S,33R,35R,36R,37S,38R,39S,40R,41S,42R,43S,44R,45S,46R,47S,48R,49S)-37,39,41,43,45,47,49-heptakis(2-hydroxyethoxy)-5,10,15,20,25,30,35-heptakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontane-36,38,40,42,44,46,48-heptol Chemical compound OCCO[C@H]1[C@H](O)[C@@H]2O[C@H]3O[C@H](CO)[C@@H](O[C@H]4O[C@H](CO)[C@@H](O[C@H]5O[C@H](CO)[C@@H](O[C@H]6O[C@H](CO)[C@@H](O[C@H]7O[C@H](CO)[C@@H](O[C@H]8O[C@H](CO)[C@@H](O[C@H]1O[C@@H]2CO)[C@@H](O)[C@@H]8OCCO)[C@@H](O)[C@@H]7OCCO)[C@@H](O)[C@@H]6OCCO)[C@@H](O)[C@@H]5OCCO)[C@@H](O)[C@@H]4OCCO)[C@@H](O)[C@@H]3OCCO PCWPQSDFNIFUPO-VDQKLNDWSA-N 0.000 claims description 3
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 3
- 229960001950 benzethonium chloride Drugs 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 claims description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
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- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 claims 1
- CFDPIEVTQXNRKJ-UHFFFAOYSA-N azanium ethene propanoate Chemical compound [NH4+].C=C.CCC([O-])=O CFDPIEVTQXNRKJ-UHFFFAOYSA-N 0.000 claims 1
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- 239000007788 liquid Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 35
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- 230000001954 sterilising effect Effects 0.000 abstract description 13
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- 238000012360 testing method Methods 0.000 description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 210000002683 foot Anatomy 0.000 description 12
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- 238000004090 dissolution Methods 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
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- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 7
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
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- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
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- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
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- 239000003381 stabilizer Substances 0.000 description 2
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
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- FKPUYTAEIPNGRM-UHFFFAOYSA-N 1-(diaminomethylidene)guanidine;hydron;chloride Chemical compound [Cl-].N\C([NH3+])=N/C(N)=N FKPUYTAEIPNGRM-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 206010017533 Fungal infection Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002413 Polyhexanide Polymers 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- AJXBTRZGLDTSST-UHFFFAOYSA-N amino 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)ON AJXBTRZGLDTSST-UHFFFAOYSA-N 0.000 description 1
- 229940077484 ammonium bromide Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- XJMWHXZUIGHOBA-UHFFFAOYSA-N azane;propanoic acid Chemical compound N.CCC(O)=O XJMWHXZUIGHOBA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229940060038 chlorine Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 231100000286 mucous membrane, eye irritation or corrosion testing Toxicity 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000010057 rubber processing Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
- 229960002722 terbinafine Drugs 0.000 description 1
- DOMXUEMWDBAQBQ-WEVVVXLNSA-N terbinafine Chemical compound C1=CC=C2C(CN(C\C=C\C#CC(C)(C)C)C)=CC=CC2=C1 DOMXUEMWDBAQBQ-WEVVVXLNSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to sterilization chemical product technical field, specially a kind of footwear taste removal sterilized compositions and preparation method thereof.The present invention is by carrying out compatibility for bicarbonate, cyclodextrin, acylate and cationic germicide these types key component, optimize the proportion of each component, especially optimize the ratio of cyclodextrin and cationic germicide, footwear taste removal sterilized composition of the invention can be made both to have the effect of quick sterilization, has the function of long-acting bacteriostatic again, and irritation and toxicity are smaller.Wherein, cyclodextrin is the taste removal ingredient of a kind of safety, high performance-price ratio, can include certain odor molecules containing cavity structure；Bicarbonate can neutralize footwear peculiar smell well, and have very high safety；On the one hand acylate can neutralize peculiar smell, on the other hand its neutralized reaction product helps to inhibit bacterial fungus in shoes to breed, and the present invention acylate used and its product neutralized with peculiar smell are without obvious smell；Cationic germicide has the characteristics that high-efficiency low-toxicity.
Description
Technical field
The present invention relates to sterilization chemical product technical field more particularly to a kind of footwear taste removal sterilized composition and its preparation sides
Method.
Background technique
The foot of people contains a large amount of sweat glands, and in walking movement, foot is easy fever perspiration, contains in sweat there are many nutriment,
Bacterium easy to breed generates foot odour taste；It is chronically at humid tropical condition or even is also easy to cause fungal infection, form tinea pedis (foot
Tinea), smell is bigger.In addition, footwear usually will not as clothing frequent clean, on the one hand because washing after need the long period to dry in the air
Dry, on the other hand often washing can make shoes quickening wear, and shorten service life, especially leather shoes, winter shoes.Therefore footwear be peculiar smell and
The high-incidence place of bacterium, there is an urgent need to administer, to adapt to the demand of people's quality of the life raising.
Solving the smelly mode of shoes at present is usually shoes to be taken to outdoor sunning, or frequently replace footgear, the effect of these methods
Fruit is limited or holds time shorter.Also there is by using the shoe chest with function of odor removal the peculiar smell for alleviating shoes sending, that is, exist
Fresh air system or air purifier are loaded onto shoe chest, the peculiar smell that footwear can be distributed is got rid of.The technology can preferably reduce shoes
Smell in cabinet, but the generation of footwear peculiar smell cannot be inhibited, and complex, it is at high cost.
In the prior art, some technologies are that will have degerming deodorization by textile finishing technology or rubber processing techniques
Silver ion, titanium dioxide, carbon fiber, fungicide of function etc. are supported on inside the materials such as vamp, sole, insole, socks or table
Layer realizes that deodorization is antibacterial.But there is higher cost, and the problem that effect is not lasting enough in this technology.
In addition, also disclosing a kind of rapid footgear deodorant agent just like patent document CN201210533599.6 comprising molten
Agent (full gear ethyl alcohol and deionized water), fungicide (trichlorocarbanilide, salicylic acid, terbinafine HCl), eliminating smell agent (castor oil
Sour zinc salt), lasting agent (polyethylene glycol 400, propylene glycol), stabilizer (iminodisuccinic acid) and other auxiliary material (essence and colors
Element).It is made with preferable bactericidal effect and certain taste removal effect, but using ricinoleic acid zinc salt (Tego Sorb A30)
It is at high cost, stability is poor for taste removal ingredient, though and make stabilizer using iminodisuccinic acid, under cryogenic still
It is easy to appear turbidity and precipitation, in addition lasting agent (polyethylene glycol 400, propylene glycol) is the difficult substance easy to moisture absorption that volatilizees, using rear unfavorable
In keeping dry and comfortable in shoes, microbial growth may be aggravated.
For another example patent document CN201610497199.2 provides a kind of footgear deodorization and sterilization and is sprayed reagent and its preparation side
Method, raw material include that 0.1%-0.3% triclosan, 1%-2% rilanit special, 60%-70% medicine ethyl alcohol, 1%-3% are removed
Taste agent (plant extracts), 20%-40% deionized water, 1%-5% essence.It is with good bactericidal effect, but for
The shoes of generation are smelly, can only be covered with essence, can not remove well, are easy additional increase greasy dirt using rilanit special, increase
Burden when cleaning.
Summary of the invention
There are taste removal effect is unobvious or not lasting, at high cost etc. for footwear taste removal degerming product is currently used for by the present invention
Problem, providing one kind can quickly remove odors, and can efficient sterilizing, long-acting bacteriostatic reduces shoes and generates peculiar smell and at low cost
The preparation method of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition.
To achieve the above object, the present invention uses following technical scheme.
A kind of footwear taste removal sterilized composition, each raw material component containing following mass percent:
Cyclodextrin 0.2%-1.5%, bicarbonate 0.1%-1%, organic acid or its salt 0.02%-0.3%, cation kill
Microbial inoculum 0.01%-0.3%, ethyl alcohol 20%-35%, menthol 0.01%-0.2%, surplus are water.
Preferably, the bicarbonate is sodium bicarbonate and/or saleratus.
Preferably, the organic acid or its salt be selected from benzoic acid, sorbic acid, dehydroactic acid and their sodium salt and they
At least one of sylvite.
Preferably, the cationic germicide is selected from C8-18 zephiran, C8-18 alkyl dimethyl
Benzylphosphonium Bromide ammonium, C8-18 alkyl trimethyl ammonium chloride, C8-18 alkyl trimethyl ammonium bromide, benzethonium chloride, Cetylpyridinium Chloride, chlorine oneself
Calmly, at least one in double-track suspended self-propelled conveyor, double decyl methyl polyoxyethylene propionic acid ammoniums, hexamethylene
Kind.
Preferably, the cyclodextrin is selected from alpha-cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin, hydroxypropyl-β-cyclodextrin, hydroxyl second
At least one of group-beta-cyclodextrin, methyl-B-cyclodextrin, more preferable beta-cyclodextrin.
Preferably, above-described footwear taste removal sterilized composition also contains other auxiliary agents, and other auxiliary agents are described
Mass percentage in footwear taste removal sterilized composition is 0.01%-2%, and other auxiliary agents include pH adjusting agent, chelating
At least one of agent, surfactant, essence, pigment.
The effect of other auxiliary agents is the organoleptic indicator of modified product or the susceptibility for reducing product, does not influence product
Key performance can add other auxiliary agents in footwear taste removal sterilized composition, can not also add.Wherein, pH is adjusted
Such as sodium hydroxide, hydrochloric acid, citric acid, sodium carbonate, sodium citrate, phosphate, triethanolamine may be selected in agent；Chelating agent may be selected
Such as EDTA, HEDP, ATMP, GLDA acid or salt (salt of chelating agent is easily water-soluble, and the acid easily alcohol of chelating agent is molten)；Surfactant
Such as dodecyldimethyl ammonium oxide, fatty alcohol polyoxyethylene ether may be selected.
Preferably, the pH value of footwear taste removal sterilized composition described above is 8-10.
The preparation method of footwear taste removal sterilized composition described above, comprising the following steps:
S1, cyclodextrin, bicarbonate, cationic germicide are dissolved in the water and are uniformly mixed, obtain S1 mixed liquor；If former
Contain acylate in material component, then also acylate is dissolved in the water and is uniformly mixed simultaneously, obtain S1 mixed liquor；
S2, menthol is dissolved in ethyl alcohol and is uniformly mixed, obtain S2 mixed liquor；If containing organic acid in raw material components,
Then also organic acid is dissolved in ethyl alcohol and is uniformly mixed simultaneously, obtains S2 mixed liquor；
S3, S2 mixed liquor is added in S1 mixed liquor, is mixed well, obtain S3 mixed liquor.
Further include step S4, the pH value of S3 mixed liquor is detected, if the pH value of S3 mixed liquor is led to not in the range of 8-10
It crosses pH adjusting agent and adjusts the pH value of S3 mixed liquor to 8-10.
When in the footwear taste removal sterilized composition also contain other auxiliary agents when, other auxiliary agents include pH adjusting agent,
At least one of chelating agent, surfactant, essence, pigment；
In above-mentioned steps S1, it will also belong in addition to ph adjusters water-soluble component in other auxiliary agents simultaneously and be dissolved in the water
And be uniformly mixed, obtain S1 mixed liquor；In above-mentioned steps S2, also it will belong in addition to ph adjusters alcohol-soluble in other auxiliary agents simultaneously
Component be dissolved in ethyl alcohol and be uniformly mixed, obtain S2 mixed liquor.
Compared with prior art, the beneficial effects of the present invention are: the present invention is by by bicarbonate, cyclodextrin, organic acid
Salt and cationic germicide these types key component carry out compatibility, optimize the proportion of each component, especially optimization cyclodextrin and sun
The ratio of ion sterilizing agent can make footwear taste removal sterilized composition of the invention not only have the effect of quick sterilization, but also have length
Antibacterial effect is imitated, and irritation and toxicity are smaller.Wherein, cyclodextrin is the taste removal ingredient of a kind of safety, high performance-price ratio,
Certain odor molecules can be included containing cavity structure；Bicarbonate can neutralize footwear peculiar smell well, and have very high safety；
On the one hand acylate can neutralize peculiar smell, on the other hand its neutralized reaction product helps to inhibit bacterial fungus in shoes to breed, and this
The acylate used and its product neutralized with peculiar smell are invented without obvious smell；Cationic germicide has high-efficiency low-toxicity
Feature.There are good cooperative compensatings to go the smelly effect of shoes with bicarbonate for cyclodextrin, and bicarbonate can increase cyclodextrin (especially
Beta-cyclodextrin) water solubility；There are package action between cyclodextrin and cationic germicide, the ratio of the two removes footwear taste removal
The effect of bacteria composition has a major impact, and the package action between cyclodextrin and cationic germicide can delay cationic germicide
Speed of action, reduce the effect of cationic germicide quick sterilization, but the effect of cationic germicide long-acting bacteriostatic can be improved, together
When this package action can reduce the irritation of cationic germicide, appropriate proportion can be put down between cyclodextrin and cationic germicide
The quick sterilization performance that weighs and long-acting bacteriostatic performance；Second alcohol and water offer quick sterilization and the effect as dissolving medium, and
Ethyl alcohol additive amount can get excellent bactericidal effect at 30% or so in this system.
Footwear taste removal sterilized composition of the invention has very high safety, in addition to cationic germicide (additive amount pole
It is few) outside, other components are using mature food raw material.Footwear taste removal sterilized composition of the invention passes through acute warp
The verifying of the toxicology such as mouth, Acute inhalation, skin irritatin and Eye irritation, reaches nontoxic grade or nonirritant level.
Footwear taste removal sterilized composition is sprayed in shoes, water by footwear taste removal sterilized composition of the invention without bad smell
Divide taste removal ingredient and degerming component remaining after volatilizing with ethyl alcohol not easy to moisture absorption, helps to maintain dry and comfortable in shoes.Non-volatile matter
Confrontation skin is corrosion-free, non-stimulated, is easy to water-soluble, can easily wash away when cleaning shoes, not will increase cleaning burden.
Footwear taste removal sterilized composition degerming of the invention, taste removal effect be good, it is safe and non-toxic, easy to use, low in cost,
Preparation is easy.The footwear taste removal sterilized composition is used to be sprayed in the shoes of peculiar smell or socks, or even is sprayed at foot,
Can quick dispelling abnormal flavor, and can efficient sterilizing long-acting bacteriostatic, reduce the generation of peculiar smell.
Detailed description of the invention
Fig. 1 is the flow chart of the preparation method of footwear taste removal sterilized composition of the present invention.
Specific embodiment
The preparation method of footwear taste removal sterilized composition of the present invention is as shown in Figure 1, comprising the following steps:
S1, cyclodextrin, bicarbonate, cationic germicide are dissolved in the water and are uniformly mixed, obtain S1 mixed liquor；If former
Contain acylate in material component, then also acylate is dissolved in the water and is uniformly mixed simultaneously, obtain S1 mixed liquor.
When also containing other auxiliary agents in the footwear taste removal sterilized composition, (other auxiliary agents include pH adjusting agent, chelating
At least one of agent, surfactant, essence, pigment): in step S1, also simultaneously by other auxiliary agents in addition to ph adjusters
Belong to water-soluble component to be dissolved in the water and be uniformly mixed, obtains S1 mixed liquor.
S2, menthol is dissolved in ethyl alcohol and is uniformly mixed, obtain S2 mixed liquor；If containing organic acid in raw material components,
Then also organic acid is dissolved in ethyl alcohol and is uniformly mixed simultaneously, obtains S2 mixed liquor.
When also containing other auxiliary agents in the footwear taste removal sterilized composition, (other auxiliary agents include pH adjusting agent, chelating
At least one of agent, surfactant, essence, pigment): in above-mentioned steps S2, also pH will be removed in other auxiliary agents simultaneously and adjusted
The component for belonging to alcohol-soluble outside agent is dissolved in ethyl alcohol and is uniformly mixed, and obtains S2 mixed liquor.
S3, S2 mixed liquor is added in S1 mixed liquor, is mixed well, obtain S3 mixed liquor.
Preferably, further include step S4, detect the pH value of S3 mixed liquor, if the pH value of S3 mixed liquor not in 8-10 range,
Then pass through the pH value of pH adjusting agent adjusting S3 mixed liquor to 8-10.
In order to more fully understand technology contents of the invention, combined with specific embodiments below to technical solution of the present invention
It is described further and illustrates.
Embodiment 1
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): beta-cyclodextrin 0.6%, sodium bicarbonate 0.5%, sodium benzoate 0.1%, dodecyl benzyl dimethyl ammonium chloride
0.04%, ethyl alcohol 30%, menthol 0.1%, EDTA-4Na 0.1%, surplus is softened water；It may also include suitable as pH
The pH value of composition is adjusted to 8-10 range by the sodium carbonate of regulator.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) successively put into clean container softened water, beta-cyclodextrin, sodium bicarbonate, sodium benzoate, EDTA-4Na,
Dodecyl benzyl dimethyl ammonium chloride, stirring and dissolving obtain S1 mixed liquor；
(2) menthol and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then proper amount of sodium carbonate is added and adjusts to this range, inspection
It is packed after testing qualification, obtains footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 2
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): alpha-cyclodextrin 0.4%, saleratus 0.4%, dehydroactic acid sodium 0.15%, double-track suspended self-propelled conveyor 0.02%,
Ethyl alcohol 25%, menthol 0.1%, surplus are softened water；It may also include suitable citric acid and hydroxide as pH adjusting agent
The pH value of composition is adjusted to 8-10 range by sodium.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) softened water, alpha-cyclodextrin, saleratus, dehydroactic acid sodium, double decyls two are successively put into clean container
Ammonio methacrylate, stirring and dissolving obtain S1 mixed liquor；
(2) menthol and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then appropriate citric acid is added and sodium hydroxide adjusting is arrived
This range, is packed after the assay was approved, obtains footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 3
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): hydroxypropyl-β-cyclodextrin 0.7%, sodium bicarbonate 0.4%, potassium sorbate 0.2%, benzethonium chloride 0.1%, ethyl alcohol
35%, menthol 0.1%, surplus is softened water；It may also include suitable disodium hydrogen phosphate as pH adjusting agent, will combine
The pH value of object is adjusted to 8-10 range.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) softened water, hydroxypropyl-β-cyclodextrin, sodium bicarbonate, potassium sorbate, benzyl are successively put into clean container
Rope oronain, stirring and dissolving obtain S1 mixed liquor；
(2) menthol and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then appropriate disodium hydrogen phosphate is added and adjusts to this model
It encloses, packs after the assay was approved, obtain footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 4
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): methyl-B-cyclodextrin 0.7%, sodium bicarbonate 0.4%, benzoic acid 0.1%, Cetylpyridinium Chloride 0.08%, ethyl alcohol 35%,
Menthol 0.1%, surplus are softened water；It may also include suitable sodium hydroxide as pH adjusting agent, by the pH of composition
Value is adjusted to 8-10 range.
The preparation method of the footwear taste removal sterilized composition of the present embodiment: interior
(1) softened water, methyl-B-cyclodextrin, sodium bicarbonate, Cetylpyridinium Chloride are successively put into clean container, stirred
Dissolution, obtains S1 mixed liquor；
(2) menthol, benzoic acid and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then appropriate sodium hydroxide is added and adjusts to this range,
It packs after the assay was approved, obtains footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 5
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): beta-cyclodextrin 0.4%, gamma-cyclodextrin 0.2%, sodium bicarbonate 0.4%, sorbic acid 0.3%, poly hexamethylene biguanide
Hydrochloride 0.04%, ethyl alcohol 35%, menthol 0.1%, surplus are softened water；It may also include suitable hydrogen as pH adjusting agent
The pH value of composition is adjusted to 8-10 range by sodium oxide molybdena and citric acid.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) softened water, beta-cyclodextrin, gamma-cyclodextrin, sodium bicarbonate, poly- six methylene are successively put into clean container
Base biguanide hydrochloride, stirring and dissolving obtain S1 mixed liquor；
(2) menthol, sorbic acid and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then appropriate sodium hydroxide is added and citric acid adjusting is arrived
This range, is packed after the assay was approved, obtains footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 6
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): beta-cyclodextrin 0.4%, alpha-cyclodextrin 0.2%, sodium bicarbonate 0.1%, potassium sorbate 0.2%, cetyl trimethyl
Ammonium chloride 0.06%, ethyl alcohol 30%, menthol 0.1%, surplus are softened water；It may also include suitable carbon as pH adjusting agent
The pH value of composition is adjusted to 8-10 range by sour sodium.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) successively put into clean container softened water, beta-cyclodextrin, alpha-cyclodextrin, sodium bicarbonate, potassium sorbate,
Hexadecyltrimethylammonium chloride, stirring and dissolving obtain S1 mixed liquor；
(2) menthol and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then proper amount of sodium carbonate is added and adjusts to this range, inspection
It is packed after testing qualification, obtains footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 7
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): beta-cyclodextrin 0.5%, hydroxyethyl-β-cyclodextrin 1%, sodium bicarbonate 0.3%, potassium sorbate 0.2%, dodecyl
Dimethyl benzyl ammonium chloride 0.3%, ethyl alcohol 28%, menthol 0.01%, surplus are softened water；It may also include suitable as pH
The pH value of composition is adjusted to 8-10 range by the disodium hydrogen phosphate of regulator.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) softened water, beta-cyclodextrin, hydroxyethyl-β-cyclodextrin, sodium bicarbonate, mountain are successively put into clean container
Potassium sorbate, dodecyl benzyl dimethyl ammonium chloride, stirring and dissolving obtain S1 mixed liquor；
(2) menthol and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then appropriate disodium hydrogen phosphate is added and adjusts to this model
It encloses, packs after the assay was approved, obtain footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Embodiment 8
The present embodiment provides the preparation sides of a kind of footwear taste removal sterilized composition and this kind of footwear taste removal sterilized composition
Method.
The footwear taste removal sterilized composition of the present embodiment includes that (total amount is for each raw material component of following mass percent
100%): beta-cyclodextrin 0.2%, sodium bicarbonate 1%, sorbic acid 0.02%, double decyl methyl polyoxyethylene propionic acid ammoniums 0.01%,
Ethyl alcohol 28%, menthol 0.2%, surplus are softened water；It may also include suitable sodium hydroxide as pH adjusting agent, by group
The pH value for closing object is adjusted within the scope of 8-10.
The preparation method of the footwear taste removal sterilized composition of the present embodiment:
(1) softened water, beta-cyclodextrin, sodium bicarbonate, double decyl methyl polyoxyethylenes are successively put into clean container
Propionic acid ammonium, stirring and dissolving obtain S1 mixed liquor；
(2) menthol, sorbic acid and ethyl alcohol mixed dissolution are obtained into S2 mixed liquor in the container of another cleaning；
(3) S2 mixed liquor is added in S1 mixed liquor, is stirred, and S3 mixed liquor is obtained；
(4) pH value for detecting S3 mixed liquor, such as deviates 8-10 range, then appropriate sodium hydroxide is added and adjusts to this range,
It packs after the assay was approved, obtains footwear taste removal sterilized composition finished product.
The footwear taste removal sterilized composition finished product of the present embodiment in the spray bottle with spray effect, be sprayed in shoes or
Socks surface, or even be sprayed on foot, can be very good to remove odors and bacterium.
Comparative example 1
This comparative example provides a kind of rapid footgear deodorant agent referring to disclosed in patent of invention document CN201210533599.6,
It includes (mass percents): ethyl alcohol 60%, TCC 0.3%, Tegosorb A30 4%, PPG400 3%, propylene glycol
0.4%, iminodisuccinic acid 0.5%, essence 1.8%, water adds to 100%.
Preparation method is: TCC, essence being added in ethanol, mixes to obtain I phase.In water be added Tegosorb A30,
PPG400, propylene glycol, iminodisuccinic acid mix to obtain II phase.II phase is slowly added into I phase and is stirred evenly, must be compared
The rapid footgear deodorant agent of example 1.
Comparative example 2
The product for having preferable removal effect to isovaleric acid is declared using certain money on Japanese market.It marks main component
Persimmon extract according to its also aqueous, ethyl alcohol of test result and has certain fragrance.
Comparative example 3
This comparative example provides a kind of mark of the product according to comparative example 2 and the eliminating smell agent of analysis result preparation, it includes:
Persimmon extract 5%, sodium benzoate 0.3%, ethyl alcohol 30%, essence 0.1%, water 64.6%.
Preparation method is: by the premix of essence and ethyl alcohol it is uniform I phase；Sodium benzoate is added to the water, stirring makes molten
Solution adds the mixing of persimmon extract, obtains II phase.I is added in II phase, is sufficiently mixed uniformly, obtains the taste removal of comparative example 3
Agent.
The effect of product removal shoes smell described in the footwear taste removal sterilized composition and comparative example of test above-described embodiment
Fruit, quick sterilization effect, long-acting bacteriostatic effect and progress toxicology test.
Test one: the sense organ removal of shoes smell is compared
The isovaleric acid spray solution of mass concentration 0.1% is simulated into peculiar smell existing for footgear on quilted stockings, it then will be real
Applying the footwear taste removal sterilized composition of a 1-8 and comparative example 1-2, uniform equivalent is sprayed on above-mentioned peculiar smell socks respectively, with pure water
As control, interval different time carries out nasil comparison after spraying the footwear taste removal sterilized composition of each example, is compared by sense organ
Product is evaluated and tested to the removal effect of peculiar smell.Scoring, the footwear taste removal of above-described embodiment 1-8 are compared by the standards of grading of table 1
The results are shown in Table 2 for the contrast test of sterilized composition and comparative example 1-2.The footwear taste removal sterilized composition pair of embodiment 1-8
The removal effect of footwear peculiar smell is obvious.
1 taste removal effect standards of grading of table
The footwear taste removal sterilized composition of 2 embodiment 1-8 of table evaluates and tests effect to the sense organ of shoes stink
| Sample | In 1min | When 5min | When 20min | 60min |
| Embodiment 1 | 4 | 5 | 4 | 5 |
| Embodiment 2 | 4 | 4 | 5 | 4 |
| Embodiment 3 | 4 | 4 | 4 | 5 |
| Embodiment 4 | 4 | 5 | 4 | 5 |
| Embodiment 5 | 4 | 4 | 5 | 5 |
| Embodiment 6 | 3 | 4 | 4 | 4 |
| Embodiment 7 | 4 | 4 | 5 | 4 |
| Embodiment 8 | 4 | 5 | 5 | 5 |
| Comparative example 1 | 2 | 3 | 3 | 4 |
| Comparative example 2 | 1 | 2 | 2 | 2 |
| Pure water | 0 | 1 | 1 | 1 |
Test two: the GC of isovaleric acid removal effect is tested
In view of sense organ evaluation and test is there may be interference and sense organ error, we are using gas-chromatography further come comparative sample
To the removal effect of isovaleric acid.Test carries out in 20ml ml headspace bottle, and 10 μ L of isovaleric acid, eliminating smell agent sample 30mg is added, and mixes
Afterwards, the concentration of air detection isovaleric acid in each ml headspace bottle is extracted after 1h.Concentration is directly proportional to peak area, according to peak area, with pure
Water removal rate is 0, calculates eliminating smell agent sample to the opposite removal rate of isovaleric acid, as a result such as table 3.Embodiment 1 and 3 pair isovaleric acid is gone
Except effect is obvious, it is better than comparative example 1 and 3.
Removal effect of the footwear taste removal sterilized composition of 3 embodiment 1,3 of table to isovaleric acid
| Sample | Peak area | Opposite removal rate, % |
| Embodiment 1 | 32 | 92 |
| Embodiment 3 | 40 | 91 |
| Comparative example 1 | 159 | 62 |
| Comparative example 3 | 339 | 20 |
| Pure water | 423 | 0 |
Test three: quick sterilization effect
According to the test method test product of 2.1.1.7.4 and 2.1.1.9 in " disinfection technology standard version in 2002 " to allusion quotation
Type microorganism staphylococcus aureus ATCC 6538, Escherichia coli 8099 and Candida albicans ATCC 10231 bactericidal effect.
To the test result such as table 4 of the footwear taste removal sterilized composition of above-described embodiment 1,3,5,6.They to these three typical bacterium
Killing rate is up to 99.999% or more.
The quick sterilization effect of the footwear taste removal sterilized composition of 4 embodiment 1,3,5,6 of table
Test four: long-acting bacteriostatic effect
According to method test product in 2.1.8.8 in " disinfection technology standard (version in 2002) " to staphylococcus aureus
The fungistatic effect of ATCC 6538, the test result such as table 5 of the footwear taste removal sterilized composition of above-described embodiment 1-3.They make
Bacteriostasis rate is still up to 99.9% or more after being finished for 24 hours.
The long-acting bacteriostatic effect of the footwear taste removal sterilized composition of 5 embodiment 1-3 of table
Test five: toxicology test
According to " disinfection technology standard (version in 2002) " carry out an intact skin irritant test, acute eye irritation test,
The toxicology tests such as acute inhalation toxicity test, acute oral toxicity test combine the footwear taste removal degerming of Examples 1 and 2
The test result of object is as shown in table 6.They reach nonirritant and practical nontoxic grade.
The toxicology test result of the footwear taste removal sterilized composition of 6 embodiment 1-2 of table
In above-described embodiment in addition to each raw material component, part is only added to pH adjusting agent, chelating agent, is not added with institute
State surfactant, essence and the pigment etc. in other auxiliary agents.Because the effect of other auxiliary agents be modified product organoleptic indicator or
The susceptibility for reducing product, does not influence the key performance of product, can add in footwear taste removal sterilized composition described other
Auxiliary agent can not also add.In other embodiments, it can need to add other auxiliary agents by product design, chelating agent is optional
Select such as sodium citrate, EDTA, HEDP, ATMP, GLDA；Such as dodecyldimethyl ammonium oxide, rouge may be selected in surfactant
Fat alcohol polyoxyethylene ether；Such as sodium hydroxide, hydrochloric acid, citric acid, phosphate also may be selected in pH adjusting agent.The addition of other auxiliary agents
Amount is preferably controlled in the 0.01%-2% for accounting for each raw material component quality sum.
It is described above that technology contents of the invention are only further illustrated with embodiment, in order to which reader is easier to understand,
But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this
Bright protection.
Claims (10)
1. a kind of footwear taste removal sterilized composition, which is characterized in that each raw material component containing following mass percent:
Cyclodextrin 0.2%-1.5%, bicarbonate 0.1%-1%, organic acid or its salt 0.02%-0.3%, cationic germicide
0.01%-0.3%, ethyl alcohol 20%-35%, menthol 0.01%-0.2%, surplus are water.
2. footwear taste removal sterilized composition according to claim 1, which is characterized in that the bicarbonate is sodium bicarbonate
And/or saleratus.
3. footwear taste removal sterilized composition according to claim 1, which is characterized in that the organic acid or its salt are selected from benzene
Formic acid, sorbic acid, dehydroactic acid and at least one of their sodium salt and their sylvite.
4. footwear taste removal sterilized composition according to claim 1, which is characterized in that the cationic germicide is selected from
C8-18 zephiran, C8-18 Alkyl dimethyl benzyl ammonium bromide, C8-18 alkyl trimethyl ammonium chloride, C8-
18 alkyl trimethyl ammonium bromides, benzethonium chloride, Cetylpyridinium Chloride, Chlorhexidine, double-track suspended self-propelled conveyor, double decyl methyl polyoxies
At least one of ethylene propionic acid ammonium, hexamethylene.
5. footwear taste removal sterilized composition according to claim 1, which is characterized in that the cyclodextrin is selected from α-ring paste
Essence, beta-cyclodextrin, gamma-cyclodextrin, hydroxypropyl-β-cyclodextrin, hydroxyethyl-β-cyclodextrin, at least one in methyl-B-cyclodextrin
Kind.
6. footwear taste removal sterilized composition according to claim 1-5, which is characterized in that also helped containing other
Agent, mass percentage of the other auxiliary agents in the footwear taste removal sterilized composition is 0.01%-2%, described other
Auxiliary agent includes at least one of pH adjusting agent, chelating agent, surfactant, essence, pigment.
7. footwear taste removal sterilized composition according to claim 1-5, which is characterized in that the footwear taste removal removes
The pH value of bacteria composition is 8-10.
8. a kind of preparation method of footwear taste removal sterilized composition as described in claim 1, which is characterized in that including following step
It is rapid:
S1, cyclodextrin, bicarbonate, cationic germicide are dissolved in the water and are uniformly mixed, obtain S1 mixed liquor；If raw material group
Contain acylate in point, then also acylate is dissolved in the water and is uniformly mixed simultaneously, obtain S1 mixed liquor；
S2, menthol is dissolved in ethyl alcohol and is uniformly mixed, obtain S2 mixed liquor；If containing organic acid in raw material components, also
Organic acid is dissolved in ethyl alcohol and is uniformly mixed simultaneously, obtains S2 mixed liquor；
S3, S2 mixed liquor is added in S1 mixed liquor, is mixed well, obtain S3 mixed liquor.
9. the preparation method of footwear taste removal sterilized composition according to claim 8, which is characterized in that it further include step S4,
The pH value of S3 mixed liquor is detected, if the pH value of S3 mixed liquor adjusts S3 mixing not in the range of 8-10, through pH adjusting agent
The pH value of liquid is to 8-10.
10. the preparation method of footwear taste removal sterilized composition according to claim 8, which is characterized in that the footwear taste removal
Also contain other auxiliary agents in sterilized composition, other auxiliary agents include pH adjusting agent, chelating agent, surfactant, essence, color
At least one of element；
In step S1, it will also belong in addition to ph adjusters water-soluble component in other auxiliary agents simultaneously and be dissolved in the water and mix
It is even, obtain S1 mixed liquor；
In step S2, also the component for belonging to alcohol-soluble in other auxiliary agents in addition to ph adjusters is dissolved in ethyl alcohol and is mixed simultaneously
Uniformly, S2 mixed liquor is obtained.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111358991A (en) * | 2020-03-24 | 2020-07-03 | 福建省海乐威生物工程有限公司 | Deodorizing and antibacterial composition for footgear and preparation method thereof |
| CN112359596A (en) * | 2020-10-28 | 2021-02-12 | 合肥艾尔纳新材料科技有限公司 | Novel cloth deodorant and preparation method thereof |
| CN113455506A (en) * | 2021-06-29 | 2021-10-01 | 无锡宏霸医疗科技有限公司 | Water-phase deodorizing agent suitable for daily chemical products and preparation method thereof |
| CN115843795A (en) * | 2022-10-28 | 2023-03-28 | 南京华狮新材料有限公司 | Supermolecule wrapped deodorizing, disinfecting and sterilizing composition |
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2018
- 2018-08-14 CN CN201810924736.6A patent/CN109078209A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111358991A (en) * | 2020-03-24 | 2020-07-03 | 福建省海乐威生物工程有限公司 | Deodorizing and antibacterial composition for footgear and preparation method thereof |
| CN112359596A (en) * | 2020-10-28 | 2021-02-12 | 合肥艾尔纳新材料科技有限公司 | Novel cloth deodorant and preparation method thereof |
| CN113455506A (en) * | 2021-06-29 | 2021-10-01 | 无锡宏霸医疗科技有限公司 | Water-phase deodorizing agent suitable for daily chemical products and preparation method thereof |
| CN115843795A (en) * | 2022-10-28 | 2023-03-28 | 南京华狮新材料有限公司 | Supermolecule wrapped deodorizing, disinfecting and sterilizing composition |
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