CN109054553A - A kind of environment protection oil paint material and preparation method thereof - Google Patents
A kind of environment protection oil paint material and preparation method thereof Download PDFInfo
- Publication number
- CN109054553A CN109054553A CN201810757650.9A CN201810757650A CN109054553A CN 109054553 A CN109054553 A CN 109054553A CN 201810757650 A CN201810757650 A CN 201810757650A CN 109054553 A CN109054553 A CN 109054553A
- Authority
- CN
- China
- Prior art keywords
- parts
- oil
- preparation
- environment protection
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of environment protection oil paint material and preparation method thereof, is prepared by following component: polyamide, acrylic resin, calcium carbonate powder, rosin, zinc oxide, tartaric acid, plants essential oil, chlorinated paraffin, sodium carboxymethylcellulose, dibutyl tin dilaurate, oil resistivity auxiliary agent, glacial acetic acid, retarder thinner, stabilizer, mill base and deionized water.The raw material environmental protection that the present invention uses, manufacturing method is simple, mild condition, low in cost, obtained paint application is good, and drying time is moderate, and the paint film after drying is beautiful in colour, and paint obtained will not all generate harm to environment and human body, and ingredient stability, adhesive force is strong, will not generate peculiar smell.
Description
Technical field
The invention belongs to environment-friendly materials technical fields, and in particular to a kind of environment protection oil paint material and preparation method thereof.
Background technique
Paint be it is a kind of can securely be covered on body surface, the chemistry for playing protection, decoration, mark and other specific uses is mixed
Close object coating.Paint is viscous oily pigment, inflammable in not dry situation, not soluble in water, is slightly soluble in fat, dissolve in alcohol, aldehyde,
Ether, benzene, alkane are soluble in gasoline, kerosene, diesel oil.There are many paint type currently on the market, but mainly contain toluene, also have a small amount of
Benzene influences human body very big.
Environment protection oil paint refers to the performance indicator of painting, safety index under the premise of meeting respective product standard.Symbol
Close the painting for the technical requirements that National Environmental famous special product proposes.Be applied to body surface can be formed with protection, decoration or
The general name of a kind of liquid or solid material of the solid coated film of property.Paint is indispensable during Household fit-up and decoration
One of material, in recent years, with the continuous improvement of people's lives, and environmentally friendly cry grows to even greater heights, and people are to decoration
The requirement of paint is higher and higher.Because it is household it should be further noted that environmental protection and safety, paint now on the market is many kinds of, but
It is the increase with people to the functional requirement of paint, existing to paint this needs for being no longer satisfied people, paint is
No longer it is only only to require excellent protective value, decoration functions, has higher requirement to its safety.
In existing paint, many paint have used stupid class, ketone and lipid equal solvent in process of production, these
Solvent highly volatile can cause environmental pollution in production and in, can also cause not to the health of the worker of construction site
With the harm of degree.But although in the prior art paint meets the requirement of environmental-protecting performance, since environment protection oil paint is big
It is chiefly used in daily life, this just has higher requirement to the antibacterial of environment protection oil paint and oil resistance.Publication number:
CN104893473B discloses a kind of composite environmental-friendly paint, and the mass parts composition of the Compound paint is as follows: thermoplastic acrylic
40-60 parts of resin, 8-12 parts of cellulose acetate, nano-calcium carbonate calcium powder, 5-10 parts of nano-zinc oxide powder, limonene 36-48
Part, 6-12 parts of polyalcohol, 8-15 parts of phthalic anhydride, coated by titanium dioxide 0.8-2.4 parts of mica, coupling agent 0.8-2.4
Part.It is not easy to turn to be yellow in composite environmental-friendly paint use process, falls off, cracks, but its oil resistant and anti-microbial property are unable to satisfy reality
Demand when border uses, it is difficult to be applied to having on the implements of ecological requirements for oil smoke weight easily growth bacterium.Publication number:
CN107858098A discloses environmentally protective paint of a kind of Cortex Eucommiae oil base and preparation method thereof, and the raw material of the paint includes: Cortex Eucommiae
50-70 parts oily, 10-30 parts of lacquer, 5-20 parts of rosin resin, 3-12 parts of shellac, 1-20 parts of kochenite, 4-7 parts of manganese naphthenate,
1-3 parts of calcium oxide, 2-3 parts of gutta-percha, 3-5 parts of plants essential oil, 0-10 parts of pigment, 20-30 parts of diluent.Preparation process includes,
Eucommia Oil and lacquer mixed liquor heat-activated, high-temperature digestion film forming matter, catalyst negative pressure catalysis, plants essential oil seasoning, dilution
Dilution agent and etc..Likewise, the prior art cost of raw material is higher, be not suitable for lacking for industrialization large-scale promotion production
Point.
In summary, it is therefore desirable to a kind of better material of paint, to improve the deficiencies in the prior art.
Summary of the invention
The object of the present invention is to provide a kind of environment protection oil paint material and preparation method thereof, raw material ring that the present invention uses
It protects, manufacturing method is simple, mild condition, and low in cost, obtained paint application is good, and drying time is moderate, the paint after drying
Film is beautiful in colour, and paint obtained will not all generate harm, and ingredient stability to environment and human body, and adhesive force is strong, will not produce
Raw peculiar smell.
The present invention provides the following technical solutions:
A kind of environment protection oil paint material, the raw material including following parts by weight: 19-24 parts of polyamide, acrylic resin 23-27
Part, 11-15 parts of calcium carbonate powder, 3-7 parts of rosin, 5-10 parts of zinc oxide, 6-10 parts of tartaric acid, 4-7 parts of plants essential oil, chlorination stone
7-12 parts of wax, 6-11 parts of sodium carboxymethylcellulose, 4-8 parts of dibutyl tin dilaurate, 6-10 parts of oil resistivity auxiliary agent, glacial acetic acid 4-
9 parts, 9-14 parts of retarder thinner, 5-10 parts of stabilizer, 8-13 parts of mill base and 9-14 parts of deionized water.
Preferably, the material of paint includes the raw material of following parts by weight: 21-24 parts of polyamide, acrylic resin
23-25 parts, 13-15 parts of calcium carbonate powder, 3-6 parts of rosin, 7-10 parts of zinc oxide, 6-9 parts of tartaric acid, 5-7 parts of plants essential oil, chlorine
7-11 parts of fossil waxes, 8-11 parts of sodium carboxymethylcellulose, 4-6 parts of dibutyl tin dilaurate, 7-10 parts of oil resistivity auxiliary agent, ice vinegar
4-8 parts sour, 9-12 parts of retarder thinner, 7-10 parts of stabilizer, 8-10 parts of mill base and 11-14 parts of deionized water.
Preferably, the material of paint includes the raw material of following parts by weight: 22 parts of polyamide, acrylic resin 24
Part, 14 parts of calcium carbonate powder, 5 parts of rosin, 8 parts of zinc oxide, 7 parts of tartaric acid, 7 parts of plants essential oil, 10 parts of chlorinated paraffin, carboxymethyl
10 parts of sodium cellulosate, 6 parts of dibutyl tin dilaurate, 9 parts of oil resistivity auxiliary agent, 5 parts of glacial acetic acid, 10 parts of retarder thinner, stabilizer 8
Part, 9 parts of mill base and 12 parts of deionized water.
A kind of preparation method of environment protection oil paint material, including following preparation step:
A, calcium carbonate powder, chlorinated paraffin and deionized water are mixed, 20- is dispersed with stirring with the revolving speed of 400-500r/min
25min adds polyamide, acrylic resin, is warming up to 84-87 DEG C, insulation reaction 0.8-1.1h, after cooling, obtains
Material one；
B, oil resistivity auxiliary agent, zinc oxide are imported in ball mill, ball milling 0.5-0.6h, adds rosin, tartaric acid, plant essence
Oil stirs evenly, and obtains material two；
C, material one and material two are imported in high-speed mixer, is divided at normal temperature with being stirred under the revolving speed of 800-1000r/min
10-13min is dissipated, glacial acetic acid, retarder thinner and stabilizer is added, is warming up to 52-55 DEG C, is slowly stirred reaction 0.6-0.8h,
After cooling, material three is obtained；
D, material three, sodium carboxymethylcellulose, dibutyl tin dilaurate and mill base are imported in reaction kettle and is added at 65-70 DEG C
After being cooled to room temperature, finished product is can be obtained in thermal response 1-1.2h.
Preferably, the oil resistivity auxiliary agent of the step b the preparation method comprises the following steps: octylisothiazolinone is mixed importing with water
In reaction kettle, it is warming up to 68-72 DEG C, reacts 7-11min, nano-titanium dioxide, zinc stearate, magnesium stearate and carbon is then added
SiClx powder, is warming up to 76-78 DEG C, is stirred to react 0.6-0.8h, adds silane coupling agent, 4-dimethylaminopyridine, is warming up to
82-85 DEG C, be stirred to react 0.5-0.6h under nitrogen protection, after being cooled to room temperature, remove supernatant liquor, it is washed, filter, it is cold
It is lyophilized dry, oil resistivity auxiliary agent can be obtained.
Preferably, the oil resistivity auxiliary agent of the step b the preparation method comprises the following steps: octylisothiazolinone is mixed importing with water
In reaction kettle, 70 DEG C are warming up to, reacts 8min, nano-titanium dioxide, zinc stearate, magnesium stearate and silicon carbide is then added
Powder is warming up to 78 DEG C, is stirred to react 0.8h, adds silane coupling agent, 4-dimethylaminopyridine, 84 DEG C is warming up to, in nitrogen
It is stirred to react 0.5h under protection, after being cooled to room temperature, removes supernatant liquor, washed, suction filtration, freeze-drying can be obtained resistance to
Oiliness auxiliary agent.
Preferably, the plants essential oil of the step b is that honeysuckle essential oil, Peppermint essential oil, lemon and clove oil are pressed
Mass ratio 2:1:1:1 is mixed.
Preferably, the retarder thinner of the step c be methylisobutylketone, dimethylbenzene, n-butanol and styrene in mass ratio
1:2:2:1 is mixed.
Preferably, the stabilizer of the step c be barium stearate, titanate esters and potassium silicate 3:2:2 in mass ratio mix and
At.
Preferably, the mill base of the step d is the mill base extracted in natural plants.
The beneficial effects of the present invention are:
The raw material environmental protection that the present invention uses, manufacturing method is simple, mild condition, and low in cost, obtained paint application is good,
Drying time is moderate, it is dry after paint film it is beautiful in colour, paint obtained will not all generate harm to environment and human body, and at
Part is stablized, and adhesive force is strong, will not generate peculiar smell.
Oil resistivity auxiliary agent in the present invention significantly improves the oil resistance of environment protection oil paint prepared by the present invention, and of the invention
In polyamide, acrylic materials not only there is oil resistance, also there is good compatibility, with oil resistivity auxiliary agent
Synergistic effect, while promoting the finished product of preparation to have paint substrate performance again, oil resistivity is significantly improved.
Plants essential oil in the present invention is honeysuckle essential oil, Peppermint essential oil, the proportion of lemon and clove oil, gold and silver
There is certain antimicrobial component in flower essential oil, Peppermint essential oil, and lemon and clove oil have a very strong natural fragrance, two
Under the combination of person, not only make the paint of preparation that there is excellent anti-microbial property, purification air, disinfection, sterilization can be played
Effect, and the fragrance distributed is nontoxic.
Retarder thinner in the present invention is the proportion of methylisobutylketone, dimethylbenzene, n-butanol and styrene, in the ratio
Under, resin viscosity can be reduced, its processing performance is improved, improves its compatibility, dispersibility.
Stabilizer in the present invention is the proportion of barium stearate, titanate esters and potassium silicate, and under the ratio, the above ingredient can
The thermal stability of mixture system is effectively improved, and also can increase its machining property to a certain extent.
Specific embodiment
Embodiment 1
A kind of environment protection oil paint material, the raw material including following parts by weight: 19 parts of polyamide, 27 parts of acrylic resin, carbonic acid
15 parts of calcium powder, 3 parts of rosin, 10 parts of zinc oxide, 10 parts of tartaric acid, 4 parts of plants essential oil, 7 parts of chlorinated paraffin, carboxymethyl cellulose
11 parts of sodium, 4 parts of dibutyl tin dilaurate, 10 parts of oil resistivity auxiliary agent, 4 parts of glacial acetic acid, 14 parts of retarder thinner, 5 parts of stabilizer, color
13 parts and 9 parts of deionized water of slurry.
A kind of preparation method of environment protection oil paint material, including following preparation step:
A, calcium carbonate powder, chlorinated paraffin and deionized water are mixed, 20min is dispersed with stirring with the revolving speed of 400r/min, then plus
Enter polyamide, acrylic resin, is warming up to 87 DEG C, insulation reaction 1.1h, after cooling, obtains material one；
B, oil resistivity auxiliary agent, zinc oxide are imported in ball mill, ball milling 0.5h adds rosin, tartaric acid, plants essential oil, stirs
It mixes uniformly, obtains material two；
C, material one and material two are imported in high-speed mixer, at normal temperature to be dispersed with stirring under the revolving speed of 1000r/min
13min adds glacial acetic acid, retarder thinner and stabilizer, is warming up to 55 DEG C, is slowly stirred reaction 0.8h and obtains object after cooling
Material three；
D, material three, sodium carboxymethylcellulose, dibutyl tin dilaurate and mill base are imported in reaction kettle and is heated at 70 DEG C
1h is reacted, after being cooled to room temperature, finished product can be obtained.
Importing in reaction kettle the preparation method comprises the following steps: octylisothiazolinone is mixed with water for the oil resistivity auxiliary agent of step b, rises
Temperature reacts 11min to 72 DEG C, and nano-titanium dioxide, zinc stearate, magnesium stearate and carborundum powder is then added, is warming up to 76
DEG C, it is stirred to react 0.6h, adds silane coupling agent, 4-dimethylaminopyridine, is warming up to 85 DEG C, stirring is anti-under nitrogen protection
0.6h is answered, after being cooled to room temperature, removes supernatant liquor, oil resistivity auxiliary agent can be obtained in washed, suction filtration, freeze-drying.
The plants essential oil of step b is honeysuckle essential oil, Peppermint essential oil, lemon and clove oil 2:1:1 in mass ratio:
1 mixes.
The retarder thinner of step c is methylisobutylketone, dimethylbenzene, n-butanol and styrene 1:2:2:1 in mass ratio mixing
It forms.
The stabilizer of step c is that barium stearate, titanate esters and potassium silicate 3:2:2 in mass ratio are mixed.
The mill base of step d is the mill base extracted in natural plants.
Embodiment 2
A kind of environment protection oil paint material, the raw material including following parts by weight: 24 parts of polyamide, 25 parts of acrylic resin, carbonic acid
15 parts of calcium powder, 6 parts of rosin, 7 parts of zinc oxide, 9 parts of tartaric acid, 7 parts of plants essential oil, 7 parts of chlorinated paraffin, sodium carboxymethylcellulose
8 parts, 4 parts of dibutyl tin dilaurate, 7 parts of oil resistivity auxiliary agent, 4 parts of glacial acetic acid, 12 parts of retarder thinner, 10 parts of stabilizer, mill base 8
Part and 14 parts of deionized water.
A kind of preparation method of environment protection oil paint material, including following preparation step:
A, calcium carbonate powder, chlorinated paraffin and deionized water are mixed, 25min is dispersed with stirring with the revolving speed of 500r/min, then plus
Enter polyamide, acrylic resin, is warming up to 87 DEG C, insulation reaction 0.8h, after cooling, obtains material one；
B, oil resistivity auxiliary agent, zinc oxide are imported in ball mill, ball milling 0.5-0.6h, adds rosin, tartaric acid, plant essence
Oil stirs evenly, and obtains material two；
C, material one and material two are imported in high-speed mixer, at normal temperature to be dispersed with stirring under the revolving speed of 800r/min
10min adds glacial acetic acid, retarder thinner and stabilizer, is warming up to 55 DEG C, is slowly stirred reaction 0.8h and obtains object after cooling
Material three；
D, material three, sodium carboxymethylcellulose, dibutyl tin dilaurate and mill base are imported in reaction kettle and is heated at 70 DEG C
1h is reacted, after being cooled to room temperature, finished product can be obtained.
Importing in reaction kettle the preparation method comprises the following steps: octylisothiazolinone is mixed with water for the oil resistivity auxiliary agent of step b, rises
Temperature reacts 7min to 72 DEG C, and nano-titanium dioxide, zinc stearate, magnesium stearate and carborundum powder is then added, is warming up to 78
DEG C, it is stirred to react 0.8h, adds silane coupling agent, 4-dimethylaminopyridine, is warming up to 82 DEG C, stirring is anti-under nitrogen protection
0.5h is answered, after being cooled to room temperature, removes supernatant liquor, oil resistivity auxiliary agent can be obtained in washed, suction filtration, freeze-drying.
The plants essential oil of step b is honeysuckle essential oil, Peppermint essential oil, lemon and clove oil 2:1:1 in mass ratio:
1 mixes.
The retarder thinner of step c is methylisobutylketone, dimethylbenzene, n-butanol and styrene 1:2:2:1 in mass ratio mixing
It forms.
The stabilizer of step c is that barium stearate, titanate esters and potassium silicate 3:2:2 in mass ratio are mixed.
The mill base of step d is the mill base extracted in natural plants.
Embodiment 3
A kind of environment protection oil paint material, the raw material including following parts by weight: 22 parts of polyamide, 24 parts of acrylic resin, carbonic acid
14 parts of calcium powder, 5 parts of rosin, 8 parts of zinc oxide, 7 parts of tartaric acid, 7 parts of plants essential oil, 10 parts of chlorinated paraffin, carboxymethyl cellulose
10 parts of sodium, 6 parts of dibutyl tin dilaurate, 9 parts of oil resistivity auxiliary agent, 5 parts of glacial acetic acid, 10 parts of retarder thinner, 8 parts of stabilizer, color
9 parts and 12 parts of deionized water of slurry.
A kind of preparation method of environment protection oil paint material, including following preparation step:
A, calcium carbonate powder, chlorinated paraffin and deionized water are mixed, 20min is dispersed with stirring with the revolving speed of 500r/min, then plus
Enter polyamide, acrylic resin, is warming up to 87 DEG C, insulation reaction 0.8h, after cooling, obtains material one；
B, oil resistivity auxiliary agent, zinc oxide are imported in ball mill, ball milling 0.6h adds rosin, tartaric acid, plants essential oil, stirs
It mixes uniformly, obtains material two；
C, material one and material two are imported in high-speed mixer, at normal temperature to be dispersed with stirring under the revolving speed of 1000r/min
10min adds glacial acetic acid, retarder thinner and stabilizer, is warming up to 55 DEG C, is slowly stirred reaction 0.8h and obtains object after cooling
Material three；
D, material three, sodium carboxymethylcellulose, dibutyl tin dilaurate and mill base are imported in reaction kettle and is heated at 65 DEG C
1.2h is reacted, after being cooled to room temperature, finished product can be obtained.
Importing in reaction kettle the preparation method comprises the following steps: octylisothiazolinone is mixed with water for the oil resistivity auxiliary agent of step b, rises
Temperature reacts 8min to 70 DEG C, and nano-titanium dioxide, zinc stearate, magnesium stearate and carborundum powder is then added, is warming up to 78
DEG C, it is stirred to react 0.8h, adds silane coupling agent, 4-dimethylaminopyridine, is warming up to 84 DEG C, stirring is anti-under nitrogen protection
0.5h is answered, after being cooled to room temperature, removes supernatant liquor, oil resistivity auxiliary agent can be obtained in washed, suction filtration, freeze-drying.
The plants essential oil of step b is honeysuckle essential oil, Peppermint essential oil, lemon and clove oil 2:1:1 in mass ratio:
1 mixes.
The retarder thinner of step c is methylisobutylketone, dimethylbenzene, n-butanol and styrene 1:2:2:1 in mass ratio mixing
It forms.
The stabilizer of step c is that barium stearate, titanate esters and potassium silicate 3:2:2 in mass ratio are mixed.
The mill base of step d is the mill base extracted in natural plants.
Comparative example 1
It is detected using common paint in the prior art.
The finished product for detecting above embodiments and comparative example preparation, obtains following detection data:
Table one:
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 |
| Adhesive force (3M600,3 times) | Do not fall | Do not fall | Do not fall | Do not fall |
| It is RCA(times wear-resisting) (the paper tape 175g of resistance to grinding machine power) | 100 | 100 | 150 | 30 |
| Ethanol-tolerant test (analysis absolute alcohol, the test of 500 power) | 300 | 300 | 380 | 80 |
| Hardness (test of Mitsubishi's pencil, 1kg power) | 2H | 2H | 2H | H |
| Organotin test | Pass through | Pass through | Pass through | Pass through |
| Gloss (60 degree of gloss) | 95 | 95 | 97 | 88 |
By the resulting experimental data of table one, it can be deduced that, the properties of the finished product of preparation method preparation of the invention are significantly excellent
Different from common product in the prior art, and the preferred preparation method in the embodiment of the present invention 3, obtain at moral character
It can be the most excellent.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of environment protection oil paint material, which is characterized in that the raw material including following parts by weight: 19-24 parts of polyamide, propylene
23-27 parts of acid resin, 11-15 parts of calcium carbonate powder, 3-7 parts of rosin, 5-10 parts of zinc oxide, 6-10 parts of tartaric acid, plants essential oil
4-7 parts, 7-12 parts of chlorinated paraffin, 6-11 parts of sodium carboxymethylcellulose, 4-8 parts of dibutyl tin dilaurate, oil resistivity auxiliary agent 6-
10 parts, 4-9 parts of glacial acetic acid, 9-14 parts of retarder thinner, 5-10 parts of stabilizer, 8-13 parts of mill base and 9-14 parts of deionized water.
2. a kind of environment protection oil paint material according to claim 1, which is characterized in that the material of paint includes following weight
The raw material of part: 21-24 parts of polyamide, 23-25 parts of acrylic resin, 13-15 parts of calcium carbonate powder, 3-6 parts of rosin, oxidation
7-10 parts of zinc, 6-9 parts of tartaric acid, 5-7 parts of plants essential oil, 7-11 parts of chlorinated paraffin, 8-11 parts of sodium carboxymethylcellulose, two laurels
Sour dibutyl tin 4-6 parts, 7-10 parts of oil resistivity auxiliary agent, 4-8 parts of glacial acetic acid, 9-12 parts of retarder thinner, 7-10 parts of stabilizer, mill base
8-10 parts and deionized water 11-14 parts.
3. a kind of environment protection oil paint material according to claim 1, which is characterized in that the material of paint includes following weight
The raw material of part: 22 parts of polyamide, 24 parts of acrylic resin, 14 parts of calcium carbonate powder, 5 parts of rosin, 8 parts of zinc oxide, winestone
Sour 7 parts, 7 parts of plants essential oil, 10 parts of chlorinated paraffin, 10 parts of sodium carboxymethylcellulose, 6 parts of dibutyl tin dilaurate, oil resistivity
9 parts of auxiliary agent, 5 parts of glacial acetic acid, 10 parts of retarder thinner, 8 parts of stabilizer, 9 parts of mill base and 12 parts of deionized water.
4. a kind of described in any item preparation methods of environment protection oil paint material of claim 1-3, which is characterized in that including following system
Standby step:
A, calcium carbonate powder, chlorinated paraffin and deionized water are mixed, 20- is dispersed with stirring with the revolving speed of 400-500r/min
25min adds polyamide, acrylic resin, is warming up to 84-87 DEG C, insulation reaction 0.8-1.1h, after cooling, obtains
Material one；
B, oil resistivity auxiliary agent, zinc oxide are imported in ball mill, ball milling 0.5-0.6h, adds rosin, tartaric acid, plant essence
Oil stirs evenly, and obtains material two；
C, material one and material two are imported in high-speed mixer, is divided at normal temperature with being stirred under the revolving speed of 800-1000r/min
10-13min is dissipated, glacial acetic acid, retarder thinner and stabilizer is added, is warming up to 52-55 DEG C, is slowly stirred reaction 0.6-0.8h,
After cooling, material three is obtained；
D, material three, sodium carboxymethylcellulose, dibutyl tin dilaurate and mill base are imported in reaction kettle and is added at 65-70 DEG C
After being cooled to room temperature, finished product is can be obtained in thermal response 1-1.2h.
5. a kind of preparation method of environment protection oil paint material according to claim 4, which is characterized in that the step b's is resistance to
Oiliness auxiliary agent imports in reaction kettle the preparation method comprises the following steps: octylisothiazolinone is mixed with water, is warming up to 68-72 DEG C, reaction
Then nano-titanium dioxide, zinc stearate, magnesium stearate and carborundum powder is added in 7-11min, be warming up to 76-78 DEG C, stirring is anti-
0.6-0.8h is answered, silane coupling agent, 4-dimethylaminopyridine are added, 82-85 DEG C is warming up to, is stirred to react under nitrogen protection
0.5-0.6h after being cooled to room temperature, removes supernatant liquor, and oil resistivity auxiliary agent can be obtained in washed, suction filtration, freeze-drying.
6. a kind of preparation method of environment protection oil paint material according to claim 5, which is characterized in that the step b's is resistance to
Oiliness auxiliary agent imports in reaction kettle the preparation method comprises the following steps: octylisothiazolinone is mixed with water, is warming up to 70 DEG C, reaction
Then 8min is added nano-titanium dioxide, zinc stearate, magnesium stearate and carborundum powder, is warming up to 78 DEG C, is stirred to react
0.8h adds silane coupling agent, 4-dimethylaminopyridine, is warming up to 84 DEG C, is stirred to react 0.5h under nitrogen protection, cooling
To room temperature, supernatant liquor is removed, oil resistivity auxiliary agent can be obtained in washed, suction filtration, freeze-drying.
7. a kind of preparation method of environment protection oil paint material according to claim 4, which is characterized in that the plant of the step b
Object essential oil is that honeysuckle essential oil, Peppermint essential oil, lemon and clove oil 2:1:1:1 in mass ratio are mixed.
8. a kind of preparation method of environment protection oil paint material according to claim 4, which is characterized in that the step c's is dilute
Releasing solvent is that methylisobutylketone, dimethylbenzene, n-butanol and styrene 1:2:2:1 in mass ratio are mixed.
9. a kind of preparation method of environment protection oil paint material according to claim 4, which is characterized in that the step c's is steady
Determining agent is that barium stearate, titanate esters and potassium silicate 3:2:2 in mass ratio are mixed.
10. a kind of preparation method of environment protection oil paint material according to claim 4, which is characterized in that the color of the step d
Slurry is the mill base extracted in natural plants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810757650.9A CN109054553A (en) | 2018-07-11 | 2018-07-11 | A kind of environment protection oil paint material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810757650.9A CN109054553A (en) | 2018-07-11 | 2018-07-11 | A kind of environment protection oil paint material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109054553A true CN109054553A (en) | 2018-12-21 |
Family
ID=64815927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810757650.9A Withdrawn CN109054553A (en) | 2018-07-11 | 2018-07-11 | A kind of environment protection oil paint material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109054553A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462492A (en) * | 2015-12-31 | 2016-04-06 | 文登蓝岛建筑工程有限公司 | Environment-friendly paint and preparation method thereof |
| CN107987691A (en) * | 2017-12-08 | 2018-05-04 | 成都米利得科技有限公司 | A kind of environment protection oil paint of antibacterial waterproof |
| CN108084871A (en) * | 2017-11-26 | 2018-05-29 | 长沙无道工业设计有限公司 | Environment protection oil paint |
-
2018
- 2018-07-11 CN CN201810757650.9A patent/CN109054553A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462492A (en) * | 2015-12-31 | 2016-04-06 | 文登蓝岛建筑工程有限公司 | Environment-friendly paint and preparation method thereof |
| CN108084871A (en) * | 2017-11-26 | 2018-05-29 | 长沙无道工业设计有限公司 | Environment protection oil paint |
| CN107987691A (en) * | 2017-12-08 | 2018-05-04 | 成都米利得科技有限公司 | A kind of environment protection oil paint of antibacterial waterproof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104449205A (en) | Antibacterial and scrubbing-resistant waterborne coating for glass door and preparation method of waterborne coating | |
| CN101121859A (en) | Water epoxy resin coating with bacterium-resistant function and preparation method thereof | |
| CN106609095A (en) | Graphene paint and preparation method thereof | |
| CN107573791A (en) | A kind of environment-friendly type inner wall face sealing wax | |
| CN103183831B (en) | Universal binder resin for water-based plastic surface printing ink, preparation method thereof and printing ink using binder resin | |
| CN111944069A (en) | Biomass nano-composite environment-friendly water-based heat-insulating coating and preparation method thereof | |
| CN106833330A (en) | A kind of sintering blower Wear-resistant, high-temperature resistant coating and preparation method thereof | |
| CN104710917B (en) | A kind of preparation method of novel, aqueous alkyd resin coating | |
| CN103805007A (en) | Benzene-free spray paint and preparation method thereof | |
| CN107434951B (en) | A kind of concrete floor coloring agent and preparation method thereof | |
| CN109054553A (en) | A kind of environment protection oil paint material and preparation method thereof | |
| CN103132370B (en) | A kind of composition of antimicrobial health care function paper clay and preparation method and purposes | |
| CN113845793A (en) | Slow-release mildew-proof coating and preparation method thereof | |
| CN107629662A (en) | A kind of environment-friendly water-based paint for wicker products | |
| CN104292975A (en) | Printing ink with antibacteria and mould proofing effects and preparation method for printing ink | |
| CN103849312B (en) | Improve lac and the method for modifying thereof of varnish thermotolerance | |
| CN107459931A (en) | A kind of water paint of water resistant abrasive proof | |
| CN106147613A (en) | A kind of Environment-friendlynon-toxic non-toxic paint | |
| CN104693887B (en) | Soft version inner-printing ink and preparation method thereof | |
| CN105504971A (en) | Epoxy-resin-modified UV (ultraviolet) raw lacquer ink for digital jet printing and preparation method thereof | |
| CN109608924A (en) | A kind of flame-proof antibiotic paint preparation method for wooden equipment | |
| CN108753157A (en) | A kind of novel environment friendly coatings and preparation method thereof | |
| CN108610877A (en) | A kind of water-resistant type environment protection oil paint | |
| CN109111790B (en) | Environment-friendly offset printing ink and preparation method thereof | |
| CN104497698A (en) | High-performance water-based polyurethane printing ink preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181221 |