CN107987691A - A kind of environment protection oil paint of antibacterial waterproof - Google Patents
A kind of environment protection oil paint of antibacterial waterproof Download PDFInfo
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- CN107987691A CN107987691A CN201711299160.0A CN201711299160A CN107987691A CN 107987691 A CN107987691 A CN 107987691A CN 201711299160 A CN201711299160 A CN 201711299160A CN 107987691 A CN107987691 A CN 107987691A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment protection oil paint of antibacterial waterproof, including the following raw material counted in parts by weight:15 25 parts of thermoplastic polyimide, 25 35 parts of medium oil linseed oil alkyd resin, 20 27 parts of alumina silicate, 6 12 parts of ethyl acetate, 10 17 parts of tricresyl phosphate, 7 14 parts of chlorinated paraffin, 48 parts of glycerine, 68 parts of glacial acetic acid, 5 10 parts of titanium dioxide, 10 20 parts of nano zine oxide, 0.5 0.9 parts of diacetanilide, stabilizer 1.5 2.5, diluent 0.5 1.8,20 30 parts of deionized water.Not only paint cost is cheap, and anti-corrosive antibacterial effect is good, and preparation process is simple, is easy to industrialization, and good with splendid high rigidity, water resistance, not easily to fall off, effectively reduces environmental pollution, service life length.
Description
Technical field
It is a kind of environment protection oil paint of antibacterial waterproof specifically the present invention relates to paint field.
Background technology
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses mixes
Compound coating.Be coated with coating in object surface, form layer protecting film, can prevent or postpone these breakoff phenomenons generation and
Development, extends the service life of a variety of materials.Modern coating progressively becomes a kind of multi-functional engineering material, is
An important industry in chemical industry.But in wet environment, paint can usually lose performance, it is impossible to normal use.
Moreover, with the improvement of living standards, people more take notice of health status, when article is chosen,
Environment-friendly materials are generally selected, meanwhile, the bacteriostasis of demand material in itself has higher requirement.Existing antiseptic antibiotic oil paint
It is in antibacterial to use antiseptic although anti-corrosion ability is good more, still there is certain injury to human body.
So need to provide a kind of good water-proof effect, and the paint for being capable of antibacterial environment protection is very important.
The content of the invention
It is an object of the invention to provide a kind of environment protection oil paint of antibacterial waterproof, not only paint cost is cheap, anti-corrosive antibacterial
Effect is good, and preparation process is simple, is easy to industrialization, and good with splendid high rigidity, water resistance, not easily to fall off,
Effectively reduce environmental pollution, service life length.
The present invention is achieved through the following technical solutions:A kind of environment protection oil paint of antibacterial waterproof, thermoplastic polyimide 15-25
Part, 25-35 parts of medium oil linseed oil alkyd resin, 20-27 parts of alumina silicate, 6-12 parts of ethyl acetate, tricresyl phosphate 10-17
Part, 7-14 parts of chlorinated paraffin, 4-8 parts of glycerine, 6-8 parts of glacial acetic acid, 5-10 parts of titanium dioxide, 10-20 parts of zinc oxide, biacetyl benzene
0.5-0.9 parts of amine, stabilizer 1.5-2.5, diluent 0.5-1.8,20-30 parts of deionized water.
Wherein, by adding alumina silicate, add the dispersion stabilization of paint, at the same avoid canister inner wall by
Corrosion.And ultra-fine, the network of alumina silicate make emulsion paint system slightly thicken, there is good suspension, and prevent solid
Part sink to the bottom and the appearance of surface water-separation.Superfine alumina silicate makes paint have good scrub resistance, weatherability, in addition can contract
Short surface drying time.
It is slow-moving with thoroughly very fast, there is fabulous gloss, flexible by adding medium oil linseed oil alkyd resin paint film
Property and weatherability.
It is good antimicrobial by adding glacial acetic acid, further prevents paint from corroding.
It can be used as the auxiliary agent medium of poor compatibility by adding tricresyl phosphate, improve the compatibility with resin.And
There are good compatibility, anti-flammability, mildew resistance, wearability, stain resistance, weatherability, radiation resistance and electric property.For oil
Paint, can increase the pliability of paint film.
By using nano zine oxide, the roughness of paint is improved, so as to improve the water resistance of its coating, improves oil
The durability of paint.
By the use of surface-modified nano titanium dioxide anti-bacterial agent, nano inorganic antimicrobial agent and paint matrix are improved
Compatibility, and nano inorganic antimicrobial agent is remarkably improved the antibacterial and bactericidal property of paint, resultant effect is excellent.
It is because it is the chlorinated derivatives of paraffin hydrocarbon to add chlorinated paraffin, has low volatility, fire-retardant, electrical insulating property is good
The advantages that good, inexpensive.
Wherein, the preparation method of paint includes following steps:
Step S1:Medium oil linseed oil alkyd resin, tricresyl phosphate are added in reaction kettle, warming while stirring, stirring
Rotating speed is 2000r/min, 30 minutes time;When temperature rises to 100 degrees Celsius, tricresyl phosphate, biacetyl benzene are added
Amine, thermoplastic polyimide continue warming while stirring, the temperature are kept after temperature rises to 150 degree 25 minutes;
Step S2:Reaction kettle in step S1 is cooled to 100 degree, then adds alumina silicate, titanium dioxide wherein, zinc oxide, go
Ionized water, diluent, then stirred 20 minutes with the rotating speed of 800r/min, obtain solution A;
Step S3:Chlorinated paraffin, glycerine, stabilizer will be added in resulting solution A in step S2, then at 80 degrees celsius
Uniform stirring 30 minutes, obtains solution B;
Step S4:Painted being stood after resulting solution B filterings in step S3.
In order to preferably realize the present invention, further, including the following raw material counted in parts by weight:Thermoplasticity polyamides is sub-
15 parts of amine, 25 parts of medium oil linseed oil alkyd resin, 20 parts of alumina silicate, 6 parts of ethyl acetate, 10 parts of tricresyl phosphate, chlorination
It is 7 parts of paraffin, 4 parts of glycerine, 6 parts of glacial acetic acid, 5 parts of titanium dioxide, 10 parts of zinc oxide, 0.5 part of diacetanilide, stabilizer 1.5, dilute
Release 20 parts of agent 0.5, deionized water.
In order to preferably realize the present invention, further, including the following raw material counted in parts by weight:Thermoplasticity polyamides is sub-
25 parts of amine, 35 parts of medium oil linseed oil alkyd resin, 27 parts of alumina silicate, 12 parts of ethyl acetate, 17 parts of tricresyl phosphate, chlorination
14 parts of paraffin, 8 parts of glycerine, 8 parts of glacial acetic acid, 10 parts of titanium dioxide, 20 parts of zinc oxide, 0.9 part of diacetanilide, stabilizer 2.5,
30 parts of diluent 1.8, deionized water.
In order to preferably realize the present invention, further, the stabilizer includes the following raw material counted in parts by weight:Silicon
Sour 11 parts of potassium, 8 parts of zinc powder, 15 parts of titanate esters, 24 parts of barium stearate.Add the stabilization that the stabilizer can be with raising to light and heat
Property, paint is not soluble in water, alcohol, gasoline, and gas, steam are leakage low;Be resistant at normal temperatures any concentration hydrochloric acid, 90% with
Under sulfuric acid, the nitric acid and less than 20% soda bath of 50-60%, there is certain resistance to chemical corrosion;It is quite steady to salt
It is fixed, but the organic solvents such as ether, ketone, chlorinated aliphatic and aromatic hydrocarbon can be dissolved in.But the light of POVC, heat endurance are poor,
More than 100 DEG C or through a long time solar exposure, will decompose, and further autocatalysis decompose, discoloration, physical mechanical property
It is rapid to decline.Therefore we add the stabilizer to solve drawbacks described above herein.
In order to preferably realize the present invention, further, the diluent includes the following raw material counted in parts by weight:Second
13 parts of glycol-butyl ether, 12 parts of methylisobutylketone, 14 parts of dimethylbenzene, 5 parts of n-butanol, 3 parts of styrene.
It is to reduce resin viscosity using the diluent, improves its processing performance.Thermosetting resin needs in paint
Diluent is added to reduce its viscosity easy to be processed further, these diluents are essentially all cheaper than resin organic
Solvent, therefore also act the cause Lian Zuoyong for reducing processing cost;Paint thinner paints the material of viscosity or denseness to reduce;Oil
The distinctive degreasing function of lacquer diluent.The degreasing before spray painting, the part of machinery can be put into solution and soaked, and played clear
Clean greasy dirt, effect of the increase with reference to power.
Compared with prior art, the present invention haing the following advantages and beneficial effect:
Heat-proof corrosion resistant erosion paint is made on the basis of rational formula design, by simple preparation method in the present invention, not only
Paint cost is cheap, and anti-corrosive antibacterial effect is good, and preparation process is simple, is easy to industrialization, and with splendid high rigidity,
Water resistance is good, not easily to fall off, effectively reduces environmental pollution, service life length.And by using nano zine oxide, improve
The roughness of paint, so as to improve the water resistance of its coating, improves the durability of paint;Pass through surface-modified nano titanium dioxide
The use of titanium antiseptic, improves the compatibility of nano inorganic antimicrobial agent and paint matrix, and nano inorganic antimicrobial agent can be notable
Antibacterial and bactericidal property, the resultant effect for improving paint are excellent.
Embodiment
Embodiment 1:
A kind of environment protection oil paint of antibacterial waterproof of the present embodiment, a kind of environment protection oil paint of antibacterial waterproof, thermoplastic polyimide 15-
25 parts, 25-35 parts of medium oil linseed oil alkyd resin, 20-27 parts of alumina silicate, 6-12 parts of ethyl acetate, tricresyl phosphate 10-
17 parts, 7-14 parts of chlorinated paraffin, 4-8 parts of glycerine, 6-8 parts of glacial acetic acid, 5-10 parts of titanium dioxide, 10-20 parts of zinc oxide, biacetyl
0.5-0.9 parts of aniline, stabilizer 1.5-2.5, diluent 0.5-1.8,20-30 parts of deionized water.
Wherein, by adding alumina silicate, add the dispersion stabilization of paint, at the same avoid canister inner wall by
Corrosion.And ultra-fine, the network of alumina silicate make emulsion paint system slightly thicken, there is good suspension, and prevent solid
Part sink to the bottom and the appearance of surface water-separation.Superfine alumina silicate makes paint have good scrub resistance, weatherability, in addition can contract
Short surface drying time.
It is slow-moving with thoroughly very fast, there is fabulous gloss, flexible by adding medium oil linseed oil alkyd resin paint film
Property and weatherability.
It is good antimicrobial by adding glacial acetic acid, further prevents paint from corroding.
It can be used as the auxiliary agent medium of poor compatibility by adding tricresyl phosphate, improve the compatibility with resin.And
There are good compatibility, anti-flammability, mildew resistance, wearability, stain resistance, weatherability, radiation resistance and electric property.For oil
Paint, can increase the pliability of paint film.
By using nano zine oxide, the roughness of paint is improved, so as to improve the water resistance of its coating, improves oil
The durability of paint.
By the use of surface-modified nano titanium dioxide anti-bacterial agent, nano inorganic antimicrobial agent and paint matrix are improved
Compatibility, and nano inorganic antimicrobial agent is remarkably improved the antibacterial and bactericidal property of paint, resultant effect is excellent.
It is because it is the chlorinated derivatives of paraffin hydrocarbon to add chlorinated paraffin, has low volatility, fire-retardant, electrical insulating property is good
The advantages that good, inexpensive.
Wherein, the preparation method of paint includes following steps:
Step S1:Medium oil linseed oil alkyd resin, tricresyl phosphate are added in reaction kettle, warming while stirring, stirring
Rotating speed is 2000r/min, 30 minutes time;When temperature rises to 100 degrees Celsius, tricresyl phosphate, biacetyl benzene are added
Amine, thermoplastic polyimide continue warming while stirring, the temperature are kept after temperature rises to 150 degree 25 minutes;
Step S2:Reaction kettle in step S1 is cooled to 100 degree, then adds alumina silicate, titanium dioxide wherein, zinc oxide, go
Ionized water, diluent, then stirred 20 minutes with the rotating speed of 800r/min, obtain solution A;
Step S3:Chlorinated paraffin, glycerine, stabilizer will be added in resulting solution A in step S2, then at 80 degrees celsius
Uniform stirring 30 minutes, obtains solution B;
Step S4:Painted being stood after resulting solution B filterings in step S3.
Embodiment 2:
The present embodiment does further optimization on the basis of embodiment 1, including the following raw material counted in parts by weight:Thermoplastic poly
15 parts of acid imide, 25 parts of medium oil linseed oil alkyd resin, 20 parts of alumina silicate, 6 parts of ethyl acetate, 10 parts of tricresyl phosphate,
7 parts of chlorinated paraffin, 4 parts of glycerine, 6 parts of glacial acetic acid, 5 parts of titanium dioxide, 10 parts of zinc oxide, 0.5 part of diacetanilide, stabilizer
1.5th, 20 parts of diluent 0.5, deionized water.
The other parts of the present embodiment are same as Example 1, and so it will not be repeated.
Embodiment 3:
The present embodiment does further optimization on the basis of embodiment 2, including the following raw material counted in parts by weight:Thermoplastic poly
25 parts of acid imide, 35 parts of medium oil linseed oil alkyd resin, 27 parts of alumina silicate, 12 parts of ethyl acetate, 17 parts of tricresyl phosphate,
14 parts of chlorinated paraffin, 8 parts of glycerine, 8 parts of glacial acetic acid, 10 parts of titanium dioxide, 20 parts of zinc oxide, 0.9 part of diacetanilide, stabilizer
2.5th, 30 parts of diluent 1.8, deionized water.
The other parts of the present embodiment are same as Example 2, and so it will not be repeated.
Embodiment 4:
The present embodiment does further optimization on the basis of embodiment 3, and the stabilizer includes the following original counted in parts by weight
Material:11 parts of potassium silicate, 8 parts of zinc powder, 15 parts of titanate esters, 24 parts of barium stearate.Adding the stabilizer can be with raising to light and heat
Stability, the not soluble in water, alcohol of paint, gasoline, gas, steam are leakage low;Be resistant at normal temperatures any concentration hydrochloric acid,
Less than 90% sulfuric acid, the nitric acid of 50-60% and less than 20% soda bath, have certain resistance to chemical corrosion;To salt phase
Work as stabilization, but the organic solvents such as ether, ketone, chlorinated aliphatic and aromatic hydrocarbon can be dissolved in.But the light of POVC, heat endurance
It is poor, more than 100 DEG C or through a long time solar exposure, will decompose, and further autocatalysis decompose, discoloration, physical machine
Tool performance declines rapidly.Therefore we add the stabilizer to solve drawbacks described above herein.
The diluent includes the following raw material counted in parts by weight:13 parts of ethylene glycol-ether, 12 parts of methylisobutylketone,
14 parts of dimethylbenzene, 5 parts of n-butanol, 3 parts of styrene.
It is to reduce resin viscosity using the diluent, improves its processing performance.Thermosetting resin needs in paint
Diluent is added to reduce its viscosity easy to be processed further, these diluents are essentially all cheaper than resin organic
Solvent, therefore also act the cause Lian Zuoyong for reducing processing cost;Paint thinner paints the material of viscosity or denseness to reduce;Oil
The distinctive degreasing function of lacquer diluent.The degreasing before spray painting, the part of machinery can be put into solution and soaked, and played clear
Clean greasy dirt, effect of the increase with reference to power.
The other parts of the present embodiment are same as Example 3, and so it will not be repeated.
The above, is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is every according to
Any simply modification, the equivalent variations made according to the technical spirit of the present invention to above example, each fall within the protection of the present invention
Within the scope of.
Claims (5)
- A kind of 1. environment protection oil paint of antibacterial waterproof, it is characterised in that:Including the following raw material counted in parts by weight:Thermoplasticity polyamides 15-25 parts of imines, 25-35 parts of medium oil linseed oil alkyd resin, 20-27 parts of alumina silicate, 6-12 parts of ethyl acetate, tripotassium phosphate 10-17 parts of phenyl ester, 7-14 parts of chlorinated paraffin, 4-8 parts of glycerine, 6-8 parts of glacial acetic acid, 5-10 parts of titanium dioxide, nano zine oxide 10- 20 parts, 0.5-0.9 parts of diacetanilide, stabilizer 1.5-2.5, diluent 0.5-1.8,20-30 parts of deionized water.
- A kind of 2. environment protection oil paint of antibacterial waterproof according to claim 1, it is characterised in that:Including it is following in parts by weight The raw material of meter:15 parts of thermoplastic polyimide, 25 parts of medium oil linseed oil alkyd resin, 20 parts of alumina silicate, 6 parts of ethyl acetate, It is 10 parts of tricresyl phosphate, 7 parts of chlorinated paraffin, 4 parts of glycerine, 6 parts of glacial acetic acid, 5 parts of titanium dioxide, 10 parts of nano zine oxide, double 0.5 part of antifebrin, stabilizer 1.5, diluent 0.5,20 parts of deionized water.
- A kind of 3. environment protection oil paint of antibacterial waterproof according to claim 1, it is characterised in that:Including it is following in parts by weight The raw material of meter:25 parts of thermoplastic polyimide, 35 parts of medium oil linseed oil alkyd resin, 27 parts of alumina silicate, 12 parts of ethyl acetate, 17 parts of tricresyl phosphate, 14 parts of chlorinated paraffin, 8 parts of glycerine, 8 parts of glacial acetic acid, 10 parts of titanium dioxide, 20 parts of nano zine oxide, 0.9 part of diacetanilide, stabilizer 2.5, diluent 1.8,30 parts of deionized water.
- 4. according to a kind of environment protection oil paint of antibacterial waterproof of claim 1-3 any one of them, it is characterised in that:The stabilizer Including the following raw material counted in parts by weight:11 parts of potassium silicate, 8 parts of zinc powder, 15 parts of titanate esters, 24 parts of barium stearate.
- 5. according to a kind of environment protection oil paint of antibacterial waterproof of claim 1-3 any one of them, it is characterised in that:The diluent Including the following raw material counted in parts by weight:13 parts of ethylene glycol-ether, 12 parts of methylisobutylketone, 14 parts of dimethylbenzene, n-butanol 5 Part, 3 parts of styrene.
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CN201711299160.0A CN107987691A (en) | 2017-12-08 | 2017-12-08 | A kind of environment protection oil paint of antibacterial waterproof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109054553A (en) * | 2018-07-11 | 2018-12-21 | 合肥达户电线电缆科技有限公司 | A kind of environment protection oil paint material and preparation method thereof |
CN109355912A (en) * | 2018-09-25 | 2019-02-19 | 湖州五兴达丝绸整理有限公司 | The production technology of full shading woven dacron |
-
2017
- 2017-12-08 CN CN201711299160.0A patent/CN107987691A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109054553A (en) * | 2018-07-11 | 2018-12-21 | 合肥达户电线电缆科技有限公司 | A kind of environment protection oil paint material and preparation method thereof |
CN109355912A (en) * | 2018-09-25 | 2019-02-19 | 湖州五兴达丝绸整理有限公司 | The production technology of full shading woven dacron |
CN109355912B (en) * | 2018-09-25 | 2023-08-08 | 湖州五兴达丝绸整理有限公司 | Production process of full-shading polyester cloth |
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Application publication date: 20180504 |