CN108998957A - A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity - Google Patents

A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity Download PDF

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Publication number
CN108998957A
CN108998957A CN201810809395.8A CN201810809395A CN108998957A CN 108998957 A CN108998957 A CN 108998957A CN 201810809395 A CN201810809395 A CN 201810809395A CN 108998957 A CN108998957 A CN 108998957A
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CN
China
Prior art keywords
fiber
wrist guard
fibre
antibacterial
hygroscopicity
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Application number
CN201810809395.8A
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Chinese (zh)
Inventor
王永国
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Hefei Xu Ya New Mstar Technology Ltd
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Hefei Xu Ya New Mstar Technology Ltd
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Priority to CN201810809395.8A priority Critical patent/CN108998957A/en
Publication of CN108998957A publication Critical patent/CN108998957A/en
Withdrawn legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08Organic compounds
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8271Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing amide and nitrile groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Abstract

The invention mainly relates to staple fibre processing technique fields, a kind of antibacterial wrist guard elastic woven material of high-hygroscopicity is disclosed, is prepared from the following raw materials: acrylic fibers 42 ~ 44, polyvinyl chloride fibre 33 ~ 35, bamboo fibre 21 ~ 23, soybean fiber 15 ~ 17, modified chitosan fiber 15 ~ 17, polyacrylonitrile-based carbon fibre 8 ~ 10, flax fiber 5 ~ 7;The antibacterial wrist guard elastic woven material of high-hygroscopicity provided by the invention, excellent spring, moisture absorption is ventilative, and conducive to wiping the sweat, bacteriostasis rate reaches 87.9%, can effectively inhibit the growth of wrist guard surface bacteria for a long time, avoids generating injury to the skin of sporter;Bamboo fibre and flax fiber are handled through folic acid high temperature ultrasonic first, increase the flexibility of bamboo fibre and flax fiber, makes wrist guard elasticity with higher, is close to wrist, plays preferable defencive function.

Description

A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity
Technical field
The invention mainly relates to staple fibre processing technique field more particularly to a kind of antibacterial wrist guard elastical cloths of high-hygroscopicity Material.
Background technique
Wrist guard is used to protect and fix wrist during the motion, and people get used to wrist guard and wipe the sweat, but presently commercially available Wrist guard hygroscopicity it is poor, do not have bacteria resistance function, it is both unhygienic in this way, it is also unhealthy, on wrist guard a large amount of sweat and spot appearance Bacterium is easily bred, is easy to damage skin after wiping the sweat.
Existing 103911849 A of patent document CN discloses a kind of wrist guard of anti-mite antibacterial, is that acrylic fibers are carried out with sterilization to remove Be woven into wrist guard towel after mite immersion treatment, whens immersion treatment acrylic fibers joined copper chloride, lanthanum chloride, acetic acid, sodium thiosulfate, X-GL is golden yellow and paregal O, and it is few by remaining except acarus and bacteria, and in acrylic fibers for can specifying wrist guard towel after treatment Amount chemical reagent can play the role of except acarus and bacteria in a short time, but these chemical reagent also can generate injury to skin, With the reduction of residual chemical agents after multiple washing, except the effect of acarus and bacteria can be also substantially reduced, and goose suction of being talked about methods It is moist poor, be prepared into wrist guard towel can not good absorption sweat, practicability is high, it is therefore desirable to a kind of high-hygroscopicity and The permanent wrist guard cloth of bactericidal effect.
Summary of the invention
In order to make up the defect of prior art, the object of the present invention is to provide the antibacterial wrist guard elastic woven materials of high-hygroscopicity.
A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity, is made of raw material from the following weight: acrylic fibers 42 ~ 44, polyvinyl chloride fibre 33 ~ 35, bamboo fibre 21 ~ 23, soybean fiber 15 ~ 17, modified chitosan fiber 15 ~ 17, polyacrylonitrile-based carbon fibre 8 ~ 10, flax are fine Dimension 5 ~ 7.
The modified chitosan fiber, it is that chitosan is added in 1 ~ 2% acetum that chitosan, which is dissolved in volume fraction, Stirring makes the concentration expressed in percentage by weight 4 ~ 5% of chitosan, then cellulose ether is added into solution, additional amount is shell to abundant dissolution The 0.7 ~ 0.9% of glycan weight, stirring mix to complete, mixed solution are placed in microwave and is heated, and frequency is 800 ~ 900MHz is heated 3 ~ 4 minutes, is stopped 1 ~ 2 minute, Repeat-heating 5 ~ 6 times, is increased the biocidal property and flexibility of chitin fiber, Conducive to the increase of wound healing and wrist guard elasticity, wet spinning obtains modified chitosan fiber.
A kind of preparation method of the antibacterial wrist guard elastic woven material of high-hygroscopicity, comprising the following steps:
(1) bamboo fibre and flax fiber are added to the water, folic acid is added, in 40 ~ 50 DEG C, 30 ~ 32kHz ultrasound 25 ~ 30 minutes, increased The flexibility for adding bamboo fibre and flax fiber makes wrist guard elasticity with higher, is close to wrist, plays preferable defencive function, Obtain pretreatment of fiber;
(2) water is added in acrylic fibers, polyvinyl chloride fibre, soybean fiber, modified chitosan fiber, polyacrylonitrile-based carbon fibre and pretreatment of fiber In, it is uniformly mixed, blended, line density is 17 ~ 19dtex, obtains blend fibre;
(3) blend fibre is placed in spinachrome dyeing liquor, in 25 ~ 30 DEG C soaking and dyeing 40 ~ 50 minutes, take out, dry, obtain Dye wrist guard fiber;
(4) it weaves: dyeing wrist guard fiber being traditionally woven into wrist guard cloth, obtains the antibacterial wrist guard elastical cloth of high-hygroscopicity Material.
The folic acid of the step (1), additive amount are the 0.05 ~ 0.07% of bamboo fibre and flax fiber total weight.
The invention has the advantages that the antibacterial wrist guard elastic woven material of high-hygroscopicity provided by the invention, excellent spring, moisture absorption are saturating Gas, conducive to wiping the sweat, bacteriostasis rate reaches 87.9%, can effectively inhibit the growth of wrist guard surface bacteria for a long time, avoid to sporter's Skin generates injury;Bamboo fibre and flax fiber are handled through folic acid high temperature ultrasonic first, increase the soft of bamboo fibre and flax fiber Toughness makes wrist guard elasticity with higher, is close to wrist, plays preferable defencive function;Again by acrylic fibers, polyvinyl chloride fibre, soybean fiber, Modified chitosan fiber, polyacrylonitrile-based carbon fibre and pretreatment of fiber carry out it is blended, acrylic fibers and polyvinyl chloride fibre be capable of providing wrist guard compared with High elasticity and intensity keeps the basic function of wrist guard, and soybean fiber can increase the smooth sense and higher hygroscopicity of wrist guard, Cooling feeling can be generated when wiping the sweat, is conducive to movement, and modified chitosan fiber is added cellulose ether through chitosan and is modified, increases The biocidal property and flexibility of chitin fiber, conducive to the increase of wound healing and wrist guard elasticity, polyacrylonitrile-based carbon fibre can The intensity and adsorptivity of wrist guard are significantly increased, sweat and spot are quickly absorbed, wrist guard is avoided to generate peculiar smell because absorbing a large amount of sweat, Keep salubrious sense and the practicability of wrist guard.
Specific embodiment
Illustrate the present invention with specific embodiment below.
Embodiment 1
A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity, is made of raw material from the following weight: acrylic fibers 42, polyvinyl chloride fibre 33, bamboo fibre 21, soybean fiber 15, modified chitosan fiber 15, polyacrylonitrile-based carbon fibre 8, flax fiber 5.
The modified chitosan fiber, it is that chitosan is added, stirs in 1% acetum that chitosan, which is dissolved in volume fraction, It mixes to abundant dissolution, makes the concentration expressed in percentage by weight 4% of chitosan, then cellulose ether is added into solution, additional amount is chitosan The 0.7% of weight, stirring mix to complete, mixed solution are placed in microwave and is heated, and frequency 800MHz heats 3 points Clock stops 1 minute, Repeat-heating 5 times, increases the biocidal property and flexibility of chitin fiber, is conducive to wound healing and wrist guard bullet The increase of property, wet spinning obtain modified chitosan fiber.
A kind of preparation method of the antibacterial wrist guard elastic woven material of high-hygroscopicity, comprising the following steps:
(1) bamboo fibre and flax fiber are added to the water, folic acid is added, additive amount is bamboo fibre and flax fiber total weight 0.05%, in 40 DEG C, 30kHz ultrasound 25 minutes, increases the flexibility of bamboo fibre and flax fiber, make wrist guard bullet with higher Property, it is close to wrist, plays preferable defencive function, obtain pretreatment of fiber;
(2) water is added in acrylic fibers, polyvinyl chloride fibre, soybean fiber, modified chitosan fiber, polyacrylonitrile-based carbon fibre and pretreatment of fiber In, it is uniformly mixed, blended, line density 17dtex obtains blend fibre;
(3) blend fibre is placed in spinachrome dyeing liquor, in 25 DEG C soaking and dyeing 40 minutes, take out, dry, shield must be dyed Wrist fiber;
(4) it weaves: dyeing wrist guard fiber being traditionally woven into wrist guard cloth, obtains the antibacterial wrist guard elastical cloth of high-hygroscopicity Material.
Embodiment 2
A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity, is made of raw material from the following weight: acrylic fibers 43, polyvinyl chloride fibre 34, bamboo fibre 22, soybean fiber 16, modified chitosan fiber 16, polyacrylonitrile-based carbon fibre 9, flax fiber 6.
The modified chitosan fiber, it is that chitosan is added in 1.5% acetum that chitosan, which is dissolved in volume fraction, Stirring makes the concentration expressed in percentage by weight 4.5% of chitosan, then cellulose ether is added into solution, additional amount is shell to abundant dissolution The 0.8% of glycan weight, stirring mix to complete, mixed solution are placed in microwave and is heated, frequency 850MHz, heating 3 Minute, stop 2 minutes, Repeat-heating 6 times, increase the biocidal property and flexibility of chitin fiber, is conducive to wound healing and wrist guard The increase of elasticity, wet spinning obtain modified chitosan fiber.
A kind of preparation method of the antibacterial wrist guard elastic woven material of high-hygroscopicity, comprising the following steps:
(1) bamboo fibre and flax fiber are added to the water, folic acid is added, additive amount is bamboo fibre and flax fiber total weight 0.06%, in 45 DEG C, 31kHz ultrasound 28 minutes, increases the flexibility of bamboo fibre and flax fiber, make wrist guard bullet with higher Property, it is close to wrist, plays preferable defencive function, obtain pretreatment of fiber;
(2) water is added in acrylic fibers, polyvinyl chloride fibre, soybean fiber, modified chitosan fiber, polyacrylonitrile-based carbon fibre and pretreatment of fiber In, it is uniformly mixed, blended, line density 18dtex obtains blend fibre;
(3) blend fibre is placed in spinachrome dyeing liquor, in 28 DEG C soaking and dyeing 45 minutes, take out, dry, shield must be dyed Wrist fiber;
(4) it weaves: dyeing wrist guard fiber being traditionally woven into wrist guard cloth, obtains the antibacterial wrist guard elastical cloth of high-hygroscopicity Material.
Embodiment 3
A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity, is made of raw material from the following weight: acrylic fibers 44, polyvinyl chloride fibre 35, bamboo fibre 23, soybean fiber 17, modified chitosan fiber 17, polyacrylonitrile-based carbon fibre 10, flax fiber 7.
The modified chitosan fiber, it is that chitosan is added, stirs in 2% acetum that chitosan, which is dissolved in volume fraction, It mixes to abundant dissolution, makes the concentration expressed in percentage by weight 5% of chitosan, then cellulose ether is added into solution, additional amount is chitosan The 0.9% of weight, stirring mix to complete, mixed solution are placed in microwave and is heated, and frequency 900MHz heats 4 points Clock stops 2 minutes, Repeat-heating 6 times, increases the biocidal property and flexibility of chitin fiber, is conducive to wound healing and wrist guard bullet The increase of property, wet spinning obtain modified chitosan fiber.
A kind of preparation method of the antibacterial wrist guard elastic woven material of high-hygroscopicity, comprising the following steps:
(1) bamboo fibre and flax fiber are added to the water, folic acid is added, additive amount is bamboo fibre and flax fiber total weight 0.07%, in 50 DEG C, 32kHz ultrasound 30 minutes, increases the flexibility of bamboo fibre and flax fiber, make wrist guard bullet with higher Property, it is close to wrist, plays preferable defencive function, obtain pretreatment of fiber;
(2) water is added in acrylic fibers, polyvinyl chloride fibre, soybean fiber, modified chitosan fiber, polyacrylonitrile-based carbon fibre and pretreatment of fiber In, it is uniformly mixed, blended, line density 19dtex obtains blend fibre;
(3) blend fibre is placed in spinachrome dyeing liquor, in 30 DEG C soaking and dyeing 50 minutes, take out, dry, shield must be dyed Wrist fiber;
(4) it weaves: dyeing wrist guard fiber being traditionally woven into wrist guard cloth, obtains the antibacterial wrist guard elastical cloth of high-hygroscopicity Material.
Comparative example 1
Remove acrylic fibers, remaining preparation method, with embodiment 1.
Comparative example 2
Remove polyvinyl chloride fibre, remaining preparation method, with embodiment 1.
Comparative example 3
Remove bamboo fibre, remaining preparation method, with embodiment 1.
Comparative example 4
Remove soybean fiber, remaining preparation method, with embodiment 1.
Comparative example 5
Remove modified chitosan fiber, remaining preparation method, with embodiment 1.
Comparative example 6
Remove polyacrylonitrile-based carbon fibre, remaining preparation method, with embodiment 1.
Comparative example 7
Remove flax fiber, remaining preparation method, with embodiment 1.
Comparative example 8
It removes step (1), remaining preparation method, with embodiment 1.
Comparative example 9
103911849 A of patent document CN discloses a kind of wrist guard of anti-mite antibacterial.
The performance of embodiment and comparative example wrist guard cloth:
Each 10 pieces of wrist guard cloth of embodiment and comparative example are randomly choosed, size is 5 × 5cm, according to " biology of cotton fabrics is thrown Light processing " detects fibre strength, and results are averaged, referring to GB/T22799-2009 to the wrist guard cloth of embodiment and comparative example Water imbibition measurement is carried out, every kind of wrist guard cloth measures 5 times, and results are averaged, the performance of embodiment and comparative example wrist guard cloth It is shown in Table 1.
The performance of 1 embodiment and comparative example wrist guard cloth of table
As it can be seen from table 1 in the same time, the capillary effect of wrist guard cloth is obviously than wrist guard cloth in comparative example in embodiment The height of the capillary effect of material is big, shows hygroscopicity of the hygroscopicity than wrist guard cloth in comparative example of wrist guard cloth in embodiment By force;From the point of view of the sedimentation time, the sedimentation time of embodiment shorter than the sedimentation time of comparative example show wrist guard cloth in embodiment more The hygroscopicity of material is stronger than the hygroscopicity of wrist guard cloth in comparative example.
The bacteriostasis property of embodiment and comparative example wrist guard cloth:
Antibacterial is carried out using standard GB/T/T20944.3-2008 " the evaluation third portion of antibacterial textile performance: succusion " Property quantitative test, before the wrist guard cloth washing of testing example and comparative example, washing 50 times, washing 100 times and washing 200 times The bacteriostasis property of Escherichia coli bacteriostasis rate, embodiment and comparative example wrist guard cloth is shown in Table 2.
Table 2: the bacteriostasis property of embodiment and comparative example wrist guard cloth
From table 2 the result shows that, the antibacterial wrist guard elastic woven material of the high-hygroscopicity of embodiment, with the increase of wash number, antibacterial Rate decline slowly, is able to carry out long-term antibacterial, and it is preferable to show that the antibacterial wrist guard elastic woven material of high-hygroscopicity provided by the invention has Bacteriostasis property.

Claims (4)

1. a kind of antibacterial wrist guard elastic woven material of high-hygroscopicity, which is characterized in that be made of raw material from the following weight: acrylic fibers 42 ~ 44, polyvinyl chloride fibre 33 ~ 35, bamboo fibre 21 ~ 23, soybean fiber 15 ~ 17, modified chitosan fiber 15 ~ 17, polyacrylonitrile-based carbon fibre 8 ~ 10, flax fiber 5 ~ 7.
2. the antibacterial wrist guard elastic woven material of high-hygroscopicity according to claim 1, which is characterized in that the modification of chitosan is fine Dimension, it is that chitosan is added in 1 ~ 2% acetum that chitosan, which is dissolved in volume fraction, and stirring makes chitosan to abundant dissolution Concentration expressed in percentage by weight is 4 ~ 5%, then cellulose ether is added into solution, and additional amount is the 0.7 ~ 0.9% of chitosan weight, and stirring is extremely It mixes completely, mixed solution is placed in microwave and is heated, frequency is 800 ~ 900MHz, is heated 3 ~ 4 minutes, stops 1 ~ 2 point Clock, Repeat-heating 5 ~ 6 times, wet spinning obtains modified chitosan fiber.
3. a kind of preparation method of the antibacterial wrist guard elastic woven material of high-hygroscopicity according to claim 1, which is characterized in that including Following steps:
(1) bamboo fibre and flax fiber are added to the water, folic acid is added and is obtained in 40 ~ 50 DEG C, 30 ~ 32kHz ultrasound 25 ~ 30 minutes Pretreatment of fiber;
(2) water is added in acrylic fibers, polyvinyl chloride fibre, soybean fiber, modified chitosan fiber, polyacrylonitrile-based carbon fibre and pretreatment of fiber In, it is uniformly mixed, blended, line density is 17 ~ 19dtex, obtains blend fibre;
(3) blend fibre is placed in spinachrome dyeing liquor, in 25 ~ 30 DEG C soaking and dyeing 40 ~ 50 minutes, take out, dry, obtain Dye wrist guard fiber;
(4) it weaves: dyeing wrist guard fiber being traditionally woven into wrist guard cloth, obtains the antibacterial wrist guard elastical cloth of high-hygroscopicity Material.
4. the preparation method of the antibacterial wrist guard elastic woven material of high-hygroscopicity according to claim 3, which is characterized in that the step (1) folic acid, additive amount are the 0.05 ~ 0.07% of bamboo fibre and flax fiber total weight.
CN201810809395.8A 2018-07-23 2018-07-23 A kind of antibacterial wrist guard elastic woven material of high-hygroscopicity Withdrawn CN108998957A (en)

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CN113174671A (en) * 2020-06-22 2021-07-27 中国石化集团胜利石油管理局有限公司电力分公司 Carbon glass hybrid variable-angle winding method and using method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113174671A (en) * 2020-06-22 2021-07-27 中国石化集团胜利石油管理局有限公司电力分公司 Carbon glass hybrid variable-angle winding method and using method thereof

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Application publication date: 20181214