CN104727140A - Antibacterial fiber and preparation method thereof - Google Patents
Antibacterial fiber and preparation method thereof Download PDFInfo
- Publication number
- CN104727140A CN104727140A CN201510023120.8A CN201510023120A CN104727140A CN 104727140 A CN104727140 A CN 104727140A CN 201510023120 A CN201510023120 A CN 201510023120A CN 104727140 A CN104727140 A CN 104727140A
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- Prior art keywords
- cotton fiber
- nano silver
- bacterial fibre
- preparation
- nano
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses an antibacterial fiber and a preparation method thereof, belonging to the technical field of spinning. According to the technical scheme, the antibacterial fiber structurally comprises a cotton fiber core layer and a nano-silver/cellulose composite surface layer; the preparation method comprises the following steps: (1) soaking the cotton fiber in a nano-silver solution, adjusting the pH to be 7-8, soaking for 5-30 minutes, taking out and drying to obtain the cotton fiber capable of adsorbing the nano-silver; (2) soaking the cotton fiber capable of adsorbing the nano-silver into a cellulose-based xanthate salt solution for 5-60 minutes, taking out and drying to obtain the cotton fiber adhered with the nano-silver; and (3) soaking the cotton fiber adhered with the nano-silver into a sulfuric acid solution for 5-30 minutes, taking out and drying to obtain the antibacterial fiber. The antibacterial fiber has the beneficial effects that (1) the antibacterial fiber is excellent in antibacterial property and good in washing fastness; and (2) the antibacterial fiber is ingenious in design and adopts a simple production method, and has great application potential in the fields of garment and textiles, and industrialized production is easy to realize.
Description
Technical field
The present invention relates to a kind of fiber, particularly a kind of anti-bacterial fibre and preparation method thereof, belong to textile technology field.
Background technology
In daily life, bacterium is ubiquitous, and textiles, in wearing process, absorbs the materials such as secretion, sweat, sebum, be very easy to become vegetative hotbed, under the condition that temperature humidity is applicable to, the reproduction speed of bacterium is very fast, the short bacterium that can breed 1,000,000 quantity for 4 hours.Not only can volatilize in the process and there is the metabolic waste of foul odour, also can cause relevant infectious disease.Therefore towel, underpants, sheet etc. become the best medium of cross infection, significant threat is become to health, therefore, the weaving face fabric with antibacterial functions has extremely important effect for preventing the infringement of germ, and along with the development of science and technology, in the middle of each details extensively and being in depth radiated life, the commodity made of antiseptic weaving face fabric are gradually by people are paid attention to.The antibacterial textile that Nano Silver makes has more report, application number is 201110210130.4, name is called that the patent of invention of " soluble alginate/carboxymethyl carrageenan composite antibacterial fiber and preparation method thereof " discloses a kind of composite antibacterial fibre, adopts wet spinning process to be prepared from by the mixed solution of soluble alginate, carboxymethyl carrageenan and nano silver dispersion; Application number is 201110075463.0, name is called in the patent of invention of " a kind of processing method of Multifunctional composite textile " and adds modified polyorganosiloxane defoamer fully stir after polyurethane and dimethyl formamide mixing, leave standstill after being coated with at twice scraping in release liners oven dry as fabric slurry after more than 12 hours, laminating nano silver fibre base fabric, after finally drying, rolling is peeled off, and leaves standstill and obtains composite textile after 12 hours.But, Nano Silver in the anti-bacterial fibre prepared by said method is adopted to be the top layer being scattered in fiber by adhesive, along with the cleaning Nano Silver of adhesive can run off gradually, cause antibacterial effect permanent and, effect is undesirable, also there is the shortcomings such as fibre strength is inadequate, preparation method is loaded down with trivial details on the other hand.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of preparation method is simple, anti-microbial property is superior and the anti-bacterial fibre that effect is lasting, utilize cellulose xanthate to meet acid and form cellulosic principle, after Nano Silver being adsorbed on core fibers surface, be dipped into further in cellulose xanthate solution and form with acid solution reduction the technical scheme being compounded with the cellulose top layer of Nano Silver again, obtaining take viscose glue as the Nano Silver cotton fiber of modifier, and its preparation method is simple, fibre strength is large, anti-microbial property is lasting.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of anti-bacterial fibre, and the structure of the antibacterial dimension of described fibre comprises the top layer of cotton fiber sandwich layer and Nano Silver/cellulose compound.
The present invention also provides the preparation method of above-mentioned a kind of anti-bacterial fibre, said method comprising the steps of:
1. cotton fiber is soaked in Nano silver solution, tune pH is 7-8, takes out dry, must adsorb the cotton fiber of Nano Silver after soaking 5-30min;
2. the cotton fiber of absorption Nano Silver is soaked in 5-60min in cellulose base xanthates solution, takes out dry, the cotton fiber of the Nano Silver that must bond;
3. the cotton fiber of bonding Nano Silver is soaked 5-30min in sulfuric acid solution, take out washing, drying, obtain anti-bacterial fibre.
In technique scheme, take cotton fiber as sandwich layer, absorption Nano Silver, then the cotton fiber of absorption Nano Silver is soaked in the viscose solution of cellulose base xanthates, Nano Silver is positioned at cotton fiber periphery, further the cotton fiber of bonding Nano Silver is immersed in acid solution, cellulose base xanthates is met acid and is formed cellulose, dispersed nano-silver particles is in viscose glue top layer, formation take viscose glue as the Nano Silver cotton fabric of modifier, its structure is take cotton fiber as sandwich layer, with Nano Silver/cellulose composite for top layer.In this anti-bacterial fibre, few Nano Silver just can produce powerful bactericidal action, strong suppression and killing action is had to multiple pathogenic microorganisms such as Escherichia coli, gonococcus, chlamydia trachomatises, 650 various bacteria can be killed in several minutes, broad-spectrum sterilization and without any drug resistance, on the other hand, the reparation of the healing of wound, the growth of cell and damaged cell can also be promoted, any irritant reaction is not found yet to skin, in field extensive uses such as textile material, medicine equipment and goods, furniture appliance layer.And the Nano Silver in anti-bacterial fibre is and cellulose compound, not simple physical absorption, and there is not Nano Silver and adhesive different in kind and easily coming off of causing, even if therefore cleaning repeatedly also can not come off, not only ensure that antibacterial effect, and environmental friendliness.
The beneficial effect adopting technique scheme to produce is: (1) anti-bacterial fibre of the present invention anti-microbial property is superior, and washing fastness is good.(2) be skillfully constructed, production method is simple, be easy to realize suitability for industrialized production, have huge application potential in the field such as clothes, weaving.
Accompanying drawing explanation
Fig. 1 is anti-bacterial fibre cross-sectional structure schematic diagram of the present invention;
In figure, 1, cotton fiber sandwich layer, 2, Nano Silver, 3, top layer.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is illustrated.
Embodiment 1
Be that the nano-Ag particles solution dilution of 5% is to 50ppm by mass concentration, regulate pH=7, by cotton fiber with bath raio 1: 10 immerse 50ppm nano-Ag particles solution in 10min, make Nano Silver be adsorbed on cotton fiber, then put into drier carry out drying process absorption Nano Silver cotton fiber; The cotton fiber of absorption Nano Silver being dipped into viscosity is again that in the sodium cellulose xanthate solution of 1000CPas, (bath raio 1: 5) continues 10min, then dry at the machine of getting rid of, be immersed in 15min in the sulfuric acid of 5g/L again; bath raio 1: 10; finally take out through hot water wash, cold wash; then dry at a high speed with drier, namely heated-air drying, sizing obtain anti-bacterial fibre of the present invention.
Embodiment 2
By mass concentration be 5% Nano silver solution be diluted to 25ppm, regulate pH=8, cotton fiber immersed 30min in this solution with bath raio 1: 20, makes Nano Silver be adsorbed on cotton fiber, then put into drier and carry out drying and process to obtain the cotton fiber of absorption Nano Silver; The cotton fiber of absorption Nano Silver being dipped into viscosity is again that in the sodium cellulose xanthate solution of 5000CPas, (bath raio 1: 10) continues 20min, then dry at the machine of getting rid of, be immersed in 30min in the sulfuric acid of 15g/L again; bath raio 1: 20, finally take out and namely obtain anti-bacterial fibre of the present invention through hot water wash, cold wash, dehydration, oven dry, sizing.
Embodiment 3
By mass concentration be 5% Nano silver solution be diluted to 100ppm, regulate pH=8, cotton fiber to be immersed in this solution 15 minutes with bath raio 1: 5, makes Nano Silver be adsorbed on cotton fiber, then put into drier and carry out drying and process to obtain the cotton fiber of absorption Nano Silver; The cotton fiber of absorption Nano Silver being dipped into viscosity is again continue 50min in the sodium cellulose xanthate solution of 50000CPas; bath raio 1: 15; then dry at the machine of getting rid of; be immersed in 10min in the sulfuric acid bath of 30g/L again; bath raio 1: 10, finally takes out and namely obtains anti-bacterial fibre of the present invention through hot water wash, cold wash, dehydration, oven dry.
Embodiment 4
Optimal enforcement example, by mass concentration be 5% Nano silver solution be diluted to 100ppm, regulate pH=8, cotton fiber to be immersed in this solution 5 minutes with bath raio 1: 10, make Nano Silver be adsorbed on cotton fiber, then put into drier carry out drying process absorption Nano Silver cotton fiber; The cotton fiber of absorption Nano Silver being dipped into viscosity is again continue 30min in the sodium cellulose xanthate solution of 5000CPas, and bath raio 1: 10, then dries at the machine of getting rid of, then 10min in the sulfuric acid bath being immersed in 25g/L, bath raio 1: 20.Finally take out and namely obtain anti-bacterial fibre of the present invention through hot water wash, cold wash, dehydration, oven dry.
The said goods is carried out antibacterial detection according to FZ/T 73023 " antibiosis knitting product " standard method, and washing 50 is taken second place its anti-microbial property of post-evaluation, and antibiotic rate is as shown in table 1 below, and method of testing is wherein with reference to following formula:
Xs=(A-B)/A × 100%, in formula, Xs is antibiotic rate (%), A is average colony number before test specimens experiment, and B is average colony number after test specimens experiment.
The bacteriostasis rate (%) of table 1 embodiment 1-4 products obtained therefrom
As fully visible, utilize the anti-bacterial fibre preparation method prepared by method of the present invention simple, good anti-bacterial effect, washing fastness is good.
Claims (9)
1. an anti-bacterial fibre, is characterized in that, the structure of described antibacterial dimension comprises the top layer (3) of cotton fiber sandwich layer (1) and Nano Silver (2)/cellulose compound.
2. a kind of anti-bacterial fibre according to claim 1, is characterized in that, the cellulose of described top layer (3) is generated by cellulose base xanthates and sulfuric acid reaction.
3. a kind of anti-bacterial fibre according to claim 2, is characterized in that, described cellulose base xanthates is cellulose base sodium xanthogenate.
4. the preparation method of a kind of anti-bacterial fibre according to claim 1, is characterized in that, said method comprising the steps of:
1. cotton fiber is soaked in Nano silver solution, tune pH is 7-8, takes out dry, must adsorb the cotton fiber of Nano Silver after soaking 5-30min;
2. the cotton fiber of absorption Nano Silver is soaked in 5-60min in cellulose base xanthates solution, takes out dry, the cotton fiber of the Nano Silver that must bond;
3. the cotton fiber of bonding Nano Silver is soaked 5-30min in sulfuric acid solution, take out washing, drying, obtain anti-bacterial fibre.
5. the preparation method of a kind of anti-bacterial fibre according to claim 4, is characterized in that, described step 1., 2. and 3. middle bath raio is respectively 1: 5-20,1: 5-15 and 1: 10-20.
6. the preparation method of a kind of anti-bacterial fibre according to claim 4 or 5, is characterized in that, described step 2. middle cellulose base xanthates is cellulose base xanthates sodium.
7. the preparation method of a kind of anti-bacterial fibre according to claim 4 or 5, is characterized in that, described step 2. middle cellulose base xanthates viscosity is 1000-50000CPas.
8. the preparation method of a kind of anti-bacterial fibre according to claim 4 or 5, is characterized in that, described step 3. middle sulfuric acid concentration is 5-30g/L.
9. the preparation method of a kind of anti-bacterial fibre according to claim 4, is characterized in that, described step 1. middle Nano silver solution concentration is 25-200ppm.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510023120.8A CN104727140B (en) | 2015-01-15 | 2015-01-15 | Antibacterial fiber and preparation method thereof |
| CN201610539691.1A CN106012510B (en) | 2015-01-15 | 2015-01-15 | Have anti-bacterial fibre, antibacterial textile of washability and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510023120.8A CN104727140B (en) | 2015-01-15 | 2015-01-15 | Antibacterial fiber and preparation method thereof |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610539691.1A Division CN106012510B (en) | 2015-01-15 | 2015-01-15 | Have anti-bacterial fibre, antibacterial textile of washability and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104727140A true CN104727140A (en) | 2015-06-24 |
| CN104727140B CN104727140B (en) | 2017-01-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610539691.1A Active CN106012510B (en) | 2015-01-15 | 2015-01-15 | Have anti-bacterial fibre, antibacterial textile of washability and preparation method thereof |
| CN201510023120.8A Active CN104727140B (en) | 2015-01-15 | 2015-01-15 | Antibacterial fiber and preparation method thereof |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610539691.1A Active CN106012510B (en) | 2015-01-15 | 2015-01-15 | Have anti-bacterial fibre, antibacterial textile of washability and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109371669A (en) * | 2018-10-26 | 2019-02-22 | 福建闽瑞环保纤维股份有限公司 | A kind of preparation method of Antimicrobial sanitation composite fibre |
| CN113652868A (en) * | 2021-09-17 | 2021-11-16 | 日东生物科技(浙江)有限公司 | Antibacterial and antiviral auxiliary for textiles and preparation method and application thereof |
| CN114395835A (en) * | 2022-03-03 | 2022-04-26 | 苏州市星京泽纤维科技有限公司 | Functional vortex spinning core-spun yarn and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319938A (en) * | 2016-08-25 | 2017-01-11 | 厦门博正科技有限公司 | Nano silver durable antibacterial cloth permeated by semiconductor and preparing method thereof |
| ES2952015B2 (en) * | 2022-03-18 | 2024-03-06 | Ancor Tecnologica Canaria S L | BIOCIDAL AND PHOTOLUMINESCENT TREATMENT OF VISCOSE FIBER IMMEDIATELY AFTER THE ADDING OF CARBON DISULFIDE IN THE PROCESS OF CONVERSION OF CELLULOSE INTO VISCOSE (XANTATHIATION) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1940168A (en) * | 2005-09-29 | 2007-04-04 | 沈鹤柏 | Antibacterial nano-silver medical fibre, its production and use |
| WO2007074484A2 (en) * | 2005-12-28 | 2007-07-05 | Mauro Pollini | Antibacterial surface treatments based on silver clusters deposition |
| CN103612465A (en) * | 2013-12-02 | 2014-03-05 | 湖州金塔地纺织厂 | Process for fabricating medical fabric |
| CN103882688A (en) * | 2012-12-22 | 2014-06-25 | 青岛同冠王实业有限公司 | Method for preparing underwear from nano-silver fiber |
-
2015
- 2015-01-15 CN CN201610539691.1A patent/CN106012510B/en active Active
- 2015-01-15 CN CN201510023120.8A patent/CN104727140B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1940168A (en) * | 2005-09-29 | 2007-04-04 | 沈鹤柏 | Antibacterial nano-silver medical fibre, its production and use |
| WO2007074484A2 (en) * | 2005-12-28 | 2007-07-05 | Mauro Pollini | Antibacterial surface treatments based on silver clusters deposition |
| CN103882688A (en) * | 2012-12-22 | 2014-06-25 | 青岛同冠王实业有限公司 | Method for preparing underwear from nano-silver fiber |
| CN103612465A (en) * | 2013-12-02 | 2014-03-05 | 湖州金塔地纺织厂 | Process for fabricating medical fabric |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109371669A (en) * | 2018-10-26 | 2019-02-22 | 福建闽瑞环保纤维股份有限公司 | A kind of preparation method of Antimicrobial sanitation composite fibre |
| CN113652868A (en) * | 2021-09-17 | 2021-11-16 | 日东生物科技(浙江)有限公司 | Antibacterial and antiviral auxiliary for textiles and preparation method and application thereof |
| CN113652868B (en) * | 2021-09-17 | 2022-03-22 | 日东生物科技(浙江)有限公司 | Antibacterial and antiviral auxiliary for textiles and preparation method and application thereof |
| CN114395835A (en) * | 2022-03-03 | 2022-04-26 | 苏州市星京泽纤维科技有限公司 | Functional vortex spinning core-spun yarn and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106012510A (en) | 2016-10-12 |
| CN106012510B (en) | 2018-06-22 |
| CN104727140B (en) | 2017-01-11 |
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Effective date of registration: 20230609 Address after: 362000 1st floor, building D, factory building, 249 Keji Road, Huacheng community, Huada street, Fengze District, Quanzhou City, Fujian Province Patentee after: Fujian Longfeng Biotechnology Co.,Ltd. Address before: 362000 1st floor, building D, Haixi electronic information industry breeding base, Keji Road, high tech Industrial Park, Fengze District, Quanzhou City, Fujian Province Patentee before: QUANZHOU YALIN NEW MATERIAL TECHNOLOGY CO.,LTD. |
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