CN108998181A - A kind of high lubrication water-base cutting fluid and preparation method thereof - Google Patents

A kind of high lubrication water-base cutting fluid and preparation method thereof Download PDF

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Publication number
CN108998181A
CN108998181A CN201811076879.2A CN201811076879A CN108998181A CN 108998181 A CN108998181 A CN 108998181A CN 201811076879 A CN201811076879 A CN 201811076879A CN 108998181 A CN108998181 A CN 108998181A
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CN
China
Prior art keywords
parts
cutting fluid
base cutting
high lubrication
lubrication water
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811076879.2A
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Chinese (zh)
Inventor
秦波
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Jiangsu Baoji Numerical Control Technology Co Ltd
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Jiangsu Baoji Numerical Control Technology Co Ltd
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Priority to CN201811076879.2A priority Critical patent/CN108998181A/en
Publication of CN108998181A publication Critical patent/CN108998181A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A kind of high lubrication water-base cutting fluid and preparation method thereof, it is related to technical field of mechanical processing, is grouped as by each group of following mass fraction: 5-11 parts of Petropols, vulcanization haco oil 2-6 parts, 1-3 parts of polyacrylamide, 1-4 parts of polyvinyl n-butyl ether, 1-2 parts of sulphide amino zinc formate, 3-7 parts of stearic acid butyl ester, 55-75 parts of deionized water, 2-4 parts of defoaming agent, 1-3 parts of emulsifier.High lubrication water-base cutting fluid provided by the invention, not only has many advantages, such as general aqueous cutting fluid, and it is with fine lubrication function, more importantly its preparation process is easy, it can situ configuration as needed, it avoids going bad under long-term preservation and influences its performance, therefore, cutting fluid provided by the invention is a kind of high-performance cutting fluid ideal in field of machining.

Description

A kind of high lubrication water-base cutting fluid and preparation method thereof
Technical field
The invention belongs to mechanical chemical industry field, in particular to a kind of high lubrication water-base cutting fluid and preparation method thereof.
Background technique
Cutting fluid is a kind of in metal cutting, mill process, for cooling down and lubricating the work of cutter and workpiece Industry liquid, cutting fluid from a variety of super strong functional auxiliary agents through science it is compound with form, be provided simultaneously with good cooling performance, profit Slip energy, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.
Machine tooling is designed into various cutters and workpiece, to the more demanding of cutting fluid.Existing cutting fluid, from matrix Can be divided into two classes: water-base cutting fluid and non-water-base cutting fluid, the advantages of water-base cutting fluid is that mobility is preferable, cooling performance compared with It is good；Disadvantage viscosity is lower, and lubricating action is not so good as non-water-base cutting fluid；Non- water-base cutting fluid, i.e. generally solvent type cutting fluid, it is excellent Point is modest viscosity, and lubricant effect is ideal, the disadvantage is that poor fluidity, cooling effect is bad.In view of all of water-base cutting fluid How more advantages improve its greasy property, become a big problem of water-base cutting fluid development and application.
Summary of the invention
Present invention solves the technical problem that: it in view of the above deficiencies, overcomes the deficiencies of existing technologies, the purpose of the present invention is mention For a kind of high lubrication water-base cutting fluid and preparation method thereof.
Technical solution of the present invention:
A kind of high lubrication water-base cutting fluid, is grouped as by each group of following mass fraction:
5-11 parts of Petropols, haco oil 2-6 parts of vulcanization, 1-3 parts of polyacrylamide, 1-4 parts of polyvinyl n-butyl ether, vulcanization 1-2 parts of carbaminate, 3-7 parts of stearic acid butyl ester, 55-75 parts of deionized water, 2-4 parts of defoaming agent, 1-3 parts of emulsifier.
Preferably, the defoaming agent is acrylic acid and ether copolymer or castor oil polyoxyethylene ether.
Preferably, the emulsifier is alkyl phenol polyoxyethylene ether, nonylphenol polyoxyethylene ether or sorbitan list Oleate.
More preferably, the emulsifier is sorbitan monooleate.
A kind of preparation method of high lubrication water-base cutting fluid, comprising the following steps:
(1) it weighs: weighing each component according to the mass fraction of each component；
(2) it mixes: each component being sequentially placed into blender and is stirred；
(3) vacuum is stood: the mixed liquor being stirred being put into container, is placed under vacuum room temperature environment and stands 8-15h；
(4) it encapsulates: after vacuum is stood, carrying out packaging to get high lubrication water-base cutting fluid is arrived.
The utility model has the advantages that high lubrication water-base cutting fluid provided by the invention, not only many excellent with general aqueous cutting fluid Point, and it is with fine lubrication function, more importantly its preparation process is easy, can situ configuration as needed, avoid Going bad under long-term preservation influences its performance, and therefore, cutting fluid provided by the invention is a kind of ideal in field of machining High-performance cutting fluid.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention Limitation.
Embodiment 1:
A kind of high lubrication water-base cutting fluid, is grouped as by each group of following mass fraction:
11 parts of Petropols, vulcanization 6 parts of haco oil, 3 parts of polyacrylamide, 4 parts of polyvinyl n-butyl ether, sulphide amino formic acid 4 parts of 2 parts of zinc, 7 parts of stearic acid butyl ester, 75 parts of deionized water, acrylic acid and ether copolymer, 3 parts of nonylphenol polyoxyethylene ether.
A kind of preparation method of high lubrication water-base cutting fluid, comprising the following steps:
(1) it weighs: weighing each component according to the mass fraction of each component；
(2) it mixes: each component being sequentially placed into blender and is stirred；
(3) vacuum is stood: the mixed liquor being stirred being put into container, is placed under vacuum room temperature environment and stands 15h；
(4) it encapsulates: after vacuum is stood, carrying out packaging to get to above-mentioned height and lubricate water-base cutting fluid.
The high lubrication water-base cutting fluid obtained according to method made above, is homogeneous liquid, no layering and precipitating phenomenon, measurement Thermal coefficient are as follows: 0.61 w/(m*k).
Embodiment 2:
A kind of high lubrication water-base cutting fluid, is grouped as by each group of following mass fraction:
5 parts of Petropols, vulcanization 2 parts of haco oil, 1 part of polyacrylamide, 1 part of polyvinyl n-butyl ether, sulphide amino formic acid 1 part of zinc, 3 parts of stearic acid butyl ester, 55 parts of deionized water, 2 parts of castor oil polyoxyethylene ether, 1 part of alkyl phenol polyoxyethylene ether.
A kind of preparation method of high lubrication water-base cutting fluid, comprising the following steps:
(1) it weighs: weighing each component according to the mass fraction of each component；
(2) it mixes: each component being sequentially placed into blender and is stirred；
(3) vacuum is stood: the mixed liquor being stirred being put into container, quiet 15h under vacuum room temperature environment is placed on；
(4) it encapsulates；After vacuum is stood, packaging is carried out to get to above-mentioned height and lubricates water-base cutting fluid
The high lubrication water-base cutting fluid obtained according to method made above, for homogeneous liquid, no layering and precipitating phenomenon, measurement is led Hot coefficient are as follows: 0.60 w/(m*k).
Embodiment 3:
A kind of high lubrication water-base cutting fluid, is grouped as by each group of following mass fraction:
9 parts of Petropols, vulcanization 5 parts of haco oil, 2 parts of polyacrylamide, 2 parts of polyvinyl n-butyl ether, sulphide amino formic acid 3 parts of 2 parts of zinc, 4 parts of stearic acid butyl ester, 68 parts of deionized water, acrylic acid and ether copolymer, 2 parts of sorbitan monooleate.
A kind of preparation method of high lubrication water-base cutting fluid, comprising the following steps:
(1) it weighs: weighing each component according to the mass fraction of each component；
(2) it mixes: each component being sequentially placed into blender and is stirred；
(3) vacuum is stood: the mixed liquor being stirred being put into container, is placed under vacuum room temperature environment and stands 15h；
(4) it encapsulates: after vacuum is stood, carrying out packaging to get to above-mentioned height and lubricate water-base cutting fluid.
The high lubrication water-base cutting fluid obtained according to method made above, is homogeneous liquid, no layering and precipitating phenomenon, measurement Thermal coefficient are as follows: 0.62 w/(m*k)；Antirust grade is excellent.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (5)

1. a kind of high lubrication water-base cutting fluid, which is characterized in that be grouped as by each group of following mass fraction: Petropols, 5-11 parts；Vulcanization haco oil, 2-6 parts；Polyacrylamide, 1-3 parts；Polyvinyl n-butyl ether, 1-4 parts；Sulphide amino formic acid Zinc, 1-2 parts；Stearic acid butyl ester, 3-7 parts；Deionized water, 55-75 parts；Defoaming agent, 2-4 parts；Emulsifier, 1-3 parts.
2. high lubrication water-base cutting fluid according to claim 1, it is characterised in that: the defoaming agent is that acrylic acid and ether are total Polymers or castor oil polyoxyethylene ether.
3. high lubrication water-base cutting fluid according to claim 1, it is characterised in that: the emulsifier is alkyl phenol polyoxy second Alkene ether, nonylphenol polyoxyethylene ether or sorbitan monooleate.
4. high lubrication water-base cutting fluid according to claim 3, it is characterised in that: the emulsifier is sorbitan list Oleate.
5. a kind of method for preparing high lubrication water-base cutting fluid described in claim 1, which comprises the following steps:
(1) it weighs: weighing each component according to the mass fraction of each component；
(2) it mixes: each component being sequentially placed into blender and is stirred；
(3) vacuum is stood: the mixed liquor being stirred being put into container, is placed under vacuum room temperature environment and stands 8-15h；
(4) it encapsulates: after vacuum is stood, carrying out packaging to get high lubrication water-base cutting fluid is arrived.
CN201811076879.2A 2018-09-14 2018-09-14 A kind of high lubrication water-base cutting fluid and preparation method thereof Pending CN108998181A (en)

Priority Applications (1)

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CN201811076879.2A CN108998181A (en) 2018-09-14 2018-09-14 A kind of high lubrication water-base cutting fluid and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201811076879.2A CN108998181A (en) 2018-09-14 2018-09-14 A kind of high lubrication water-base cutting fluid and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452762A (en) * 2019-07-31 2019-11-15 南宁珀源能源材料有限公司 Polytenization sheet silicon wafer cutting fluid and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452762A (en) * 2019-07-31 2019-11-15 南宁珀源能源材料有限公司 Polytenization sheet silicon wafer cutting fluid and preparation method thereof

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Application publication date: 20181214