CN108865396A - A kind of machining Environmental Protection Cutting Fluid and preparation method thereof - Google Patents

A kind of machining Environmental Protection Cutting Fluid and preparation method thereof Download PDF

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Publication number
CN108865396A
CN108865396A CN201811077995.6A CN201811077995A CN108865396A CN 108865396 A CN108865396 A CN 108865396A CN 201811077995 A CN201811077995 A CN 201811077995A CN 108865396 A CN108865396 A CN 108865396A
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Prior art keywords
parts
cutting fluid
environmental protection
machining
protection cutting
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CN201811077995.6A
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Inventor
秦波
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Jiangsu Baoji Numerical Control Technology Co Ltd
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Jiangsu Baoji Numerical Control Technology Co Ltd
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Priority to CN201811077995.6A priority Critical patent/CN108865396A/en
Publication of CN108865396A publication Critical patent/CN108865396A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/288Partial esters containing free carboxyl groups
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045Polyureas; Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02Unspecified siloxanes; Silicones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A kind of machining Environmental Protection Cutting Fluid and preparation method thereof, is related to technical field of mechanical processing, is grouped as by each group of following mass fraction:Water-soluble elastic resin 4-10 parts, 2-6 parts of phosphate, 3-6 parts of butyl oleate, 2-8 parts of polyglyceryl fatty acid ester, 2-5 parts of phosphoric acid triacetamide, 2-4 parts of sodium citrate, 55-80 parts of deionized water, 1-4 parts of antioxidant, 1-3 parts of detersive.Machining Environmental Protection Cutting Fluid provided by the invention is guaranteeing outside the performances such as cutting fluid excellent cooling, lubrication, cleaning that the influence to environment is smaller, not will cause environmental pollution, is a kind of machining cutting fluid for taking into account industry and environmental protection.

Description

A kind of machining Environmental Protection Cutting Fluid and preparation method thereof
Technical field
The invention belongs to mechanical chemical industry field, in particular to a kind of machining Environmental Protection Cutting Fluid and preparation method thereof.
Background technique
Cutting fluid is a kind of in metal cutting, mill process, for cooling down and lubricating the work of cutter and workpiece Industry liquid, cutting fluid from a variety of super strong functional auxiliary agents through science it is compound with form, be provided simultaneously with good cooling performance, profit Slip energy, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.
The excellent performance of cutting fluid uses it largely in field of machining, almost irreplaceable.Cutting fluid is as work Industry product, significantly improves the service life and machining accuracy of machining tool, but from due to cutting fluid usage amount it is huge, undoubtedly Large effect can be generated to environment;In the prior art, the recovery system of cutting fluid still has deficiency, wants to reduce pollution, return Sequence of knocking off is more many and diverse, and cost is also higher, to provide the use cost of cutting fluid.How the performance of cutting fluid is guaranteed, together When reduce its pollution to environment, be cutting fluid development a urgent problem to be solved.
Summary of the invention
Present invention solves the technical problem that:In view of the above deficiencies, it overcomes the deficiencies of existing technologies, the purpose of the present invention is mention For a kind of machining Environmental Protection Cutting Fluid and preparation method thereof.
Technical solution of the present invention:
A kind of machining Environmental Protection Cutting Fluid is grouped as by each group of following mass fraction:
Water-soluble elastic resin 4-10 parts, 2-6 parts of phosphate, 3-6 parts of butyl oleate, 2-8 parts of polyglyceryl fatty acid ester, tricresyl phosphate 2-5 parts of ammonium acetate, 2-4 parts of sodium citrate, 55-80 parts of deionized water, 1-4 parts of antioxidant, 1-3 parts of detersive.
Preferably, the water solubility elastic resin is polyurethane resin, organic siliconresin or acrylic resin.
Preferably, the antioxidant is β-acid octadecanol ester, sulphide amino zinc formate or pentaerythritol ester.
Preferably, the detersive is that high base number synthesizes sulphur calcium, high base number calcium mahogany sulfonate or high three values calcium naphthenate.
A kind of preparation method being machined Environmental Protection Cutting Fluid, includes the following steps:
(1)It weighs:Each component is weighed according to the mass fraction of each component;
(2)Mixing:Each component is sequentially placed into blender and is stirred;
(3)Vacuum is stood:The mixed liquor being stirred is put into container, is placed under vacuum room temperature environment and stands 8-15h;
(4)Encapsulation:After vacuum is stood, packaging is carried out to get machining Environmental Protection Cutting Fluid is arrived.
Beneficial effect:Machining Environmental Protection Cutting Fluid provided by the invention is guaranteeing the excellent cooling of cutting fluid, profit Outside the performances such as sliding, cleaning, the influence to environment is smaller, not will cause environmental pollution, is a kind of machine for taking into account industry and environmental protection Tool Cutting fluid for processing.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention Limitation.
Embodiment 1:
A kind of machining Environmental Protection Cutting Fluid is grouped as by each group of following mass fraction:
10 parts of organic siliconresin, 6 parts of phosphate, 6 parts of butyl oleate, 8 parts of polyglyceryl fatty acid ester, 5 parts of phosphoric acid triacetamide, lemon 4 parts of lemon acid sodium, 80 parts of deionized water, β -4 parts of acid octadecanol ester, 3 parts of high base number calcium mahogany sulfonate.
A kind of preparation method being machined Environmental Protection Cutting Fluid, includes the following steps:
(1)It weighs:Each component is weighed according to the mass fraction of each component;
(2)Mixing:Each component is sequentially placed into blender and is stirred;
(3)Vacuum is stood:The mixed liquor being stirred is put into container, is placed under vacuum room temperature environment and stands 15h;
(4)Encapsulation:After vacuum is stood, packaging is carried out to get above-mentioned machining Environmental Protection Cutting Fluid is arrived.
The machining Environmental Protection Cutting Fluid obtained according to method made above, be homogeneous liquid, no layering and precipitating phenomenon, The thermal coefficient of measurement is: 0.61 w/(m*k).
Embodiment 2:
A kind of machining Environmental Protection Cutting Fluid is grouped as by each group of following mass fraction:
4 parts of polyurethane resin, 2 parts of phosphate, 3 parts of butyl oleate, 2 parts of polyglyceryl fatty acid ester, 2 parts of phosphoric acid triacetamide, lemon 2 parts of lemon acid sodium, 55 parts of deionized water, 1 part of sulphide amino zinc formate, high base number synthesize 1 part of sulphur calcium.
A kind of preparation method being machined Environmental Protection Cutting Fluid, includes the following steps:
(1)It weighs:Each component is weighed according to the mass fraction of each component;
(2)Mixing:Each component is sequentially placed into blender and is stirred;
(3)Vacuum is stood:The mixed liquor being stirred is put into container, quiet 15h under vacuum room temperature environment is placed on;
(4)Encapsulation:After vacuum is stood, packaging is carried out to get above-mentioned machining Environmental Protection Cutting Fluid is arrived
The machining Environmental Protection Cutting Fluid obtained according to method made above is homogeneous liquid, no layering and precipitating phenomenon, measurement Thermal coefficient be: 0.61 w/(m*k).
Embodiment 3:
A kind of machining Environmental Protection Cutting Fluid is grouped as by each group of following mass fraction:
8 parts of acrylic resin, 5 parts of phosphate, 3 parts of butyl oleate, 3 parts of polyglyceryl fatty acid ester, 4 parts of phosphoric acid triacetamide, lemon It is 3 parts of lemon acid sodium, 70 parts of deionized water, 2 parts of pentaerythritol ester, 2 parts of three values calcium naphthenate high.
A kind of preparation method being machined Environmental Protection Cutting Fluid, includes the following steps:
(1)It weighs:Each component is weighed according to the mass fraction of each component;
(2)Mixing:Each component is sequentially placed into blender and is stirred;
(3)Vacuum is stood:The mixed liquor being stirred is put into container, is placed under vacuum room temperature environment and stands 15h;
(4)Encapsulation:After vacuum is stood, packaging is carried out to get above-mentioned machining Environmental Protection Cutting Fluid is arrived.
The machining Environmental Protection Cutting Fluid obtained according to method made above, be homogeneous liquid, no layering and precipitating phenomenon, The thermal coefficient of measurement is: 0.62 w/(m*k);Antirust grade is excellent.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (5)

1. a kind of machining Environmental Protection Cutting Fluid, which is characterized in that be grouped as by each group of following mass fraction:It is water-soluble Elastic resin, 4-10 parts;Phosphate, 2-6 parts;Butyl oleate, 3-6 parts;Polyglyceryl fatty acid ester, 2-8 parts;Phosphoric acid triacetic acid Amine, 2-5 parts;Sodium citrate, 2-4 parts;Deionized water, 55-80 parts;Antioxidant, 1-4 parts;Detersive, 1-3 parts.
2. machining Environmental Protection Cutting Fluid according to claim 1, it is characterised in that:It is described water solubility elastic resin be Polyurethane resin, organic siliconresin or acrylic resin.
3. machining Environmental Protection Cutting Fluid according to claim 1, it is characterised in that:The antioxidant is β-acid 18 Carbon alcohol ester, sulphide amino zinc formate or pentaerythritol ester.
4. machining Environmental Protection Cutting Fluid according to claim 1, it is characterised in that:The detersive is high base number conjunction At sulphur calcium, high base number calcium mahogany sulfonate or high three values calcium naphthenate.
5. a kind of method for preparing machining Environmental Protection Cutting Fluid described in claim 1, which is characterized in that including following step Suddenly:
(1)It weighs:Each component is weighed according to the mass fraction of each component;
(2)Mixing:Each component is sequentially placed into blender and is stirred;
(3)Vacuum is stood:The mixed liquor being stirred is put into container, is placed under vacuum room temperature environment and stands 8-15h;
(4)Encapsulation:After vacuum is stood, packaging is carried out to get machining Environmental Protection Cutting Fluid is arrived.
CN201811077995.6A 2018-09-16 2018-09-16 A kind of machining Environmental Protection Cutting Fluid and preparation method thereof Pending CN108865396A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811077995.6A CN108865396A (en) 2018-09-16 2018-09-16 A kind of machining Environmental Protection Cutting Fluid and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201811077995.6A CN108865396A (en) 2018-09-16 2018-09-16 A kind of machining Environmental Protection Cutting Fluid and preparation method thereof

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CN108865396A true CN108865396A (en) 2018-11-23

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Application publication date: 20181123