CN108976085A - A kind of preparation method of tea tree vernalization special fertilizer - Google Patents
A kind of preparation method of tea tree vernalization special fertilizer Download PDFInfo
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- CN108976085A CN108976085A CN201810959942.0A CN201810959942A CN108976085A CN 108976085 A CN108976085 A CN 108976085A CN 201810959942 A CN201810959942 A CN 201810959942A CN 108976085 A CN108976085 A CN 108976085A
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- vernalization
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- tea tree
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- special fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention belongs to technical field of fertilizers, and in particular to a kind of preparation method of tea tree vernalization special fertilizer.The preparation method of fertilizer special for tea trees provided by the invention, the first mixed serum of preparation biomass carbon, ammonium hydroxide and humic acid, then it is passed through CO2Or contain CO2Gas, then separation product obtains tea tree vernalization special fertilizer after dry.The application is different from biomass carbon and mixes with the direct of ammonium hydrogen carbonate, is to prepare biomass carbon based compound fertilizer using the biomass carbon of surface acidic functionality rich in as the nuclei of crystallization/carrier with physical and chemical adsorption-chemical reaction method, that is, utilizes NH3+CO2+H2O is reacted in charcoal matrix pores surfaces externally and internally and is obtained, and after the combination with biomass carbon and humic acid, the comprehensive utilization ratio of nitrogen has been effectively ensured, has had remarkable result on to tea tree spring vernalization;And stability is high, achievees the effect that sustained release, overcomes the shortcomings that traditional ammonium bicarbonate fertilizer easily decomposes volatilization, effectively improves the utilization rate of fertilizer.
Description
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of preparation method of tea tree vernalization special fertilizer.
Background technique
In recent decades, China's tea yield and quality increase substantially, and wherein play can not for the update of fertilizer practice
The effect of substitution.Tea tree is perennial crop, machine matter contained in the yield and quality of tealeaves and the soil of plantation tea tree, complete
Nitrogen, available N, P, K etc. are closely related.Organic fertilizer is the full price fertilizer with various nutrient elements, and tea place application of organic fertilizers can
Soil physico-chemical property is improved, balanced soil nutrient improves utilization rate of fertilizer, promotes growth of tea plant, to improve the yield of tealeaves
And quality.In addition to base manure, tea tree generally also needs the first time topdressing before top dressing, especially spring tea exploitation, and tea tree passes through a winter
" rest and reorganization ", in spring in next year, temperature, rainwater condition maturity, bud-leaf falls over each other to sprout, there is an urgent need to nutrition, top dressing have promotes tea
Bud-leaf early hair, the effect that multiple, hair is neat, hair is strong are set, so, also it is called " vernalization fertilizer ".
It was found that the absorbability of tea tree nutrient is 3 times stronger than Wintering Period when spring tea sprouts, to nitrogen utilization efficiency also compared with
It is high.High-quality, high yield tea place picking intensity is big, requires leaf quality high, has the characteristics that early adopt, tender adopt, adopt in batches, tea tree more
Nutrient consumption is also larger, so the effect of vernalization fertilizer is extremely important to the economic benefit in tea place.In the prior art, tea tree is dedicated urges
The ingredient of bud fertilizer is often more complex, such as Chinese patent CN106167439A provides the top dressing liquid of tea picking phase a kind of, should
Fertilizer composition includes 30~40 parts of tea tree fertilizer special for organic, 5~15 parts of vegetables, 5~10 parts of oil meal, 3~7 parts of potassium dihydrogen phosphate, carbon
3~6 parts of sour hydrogen ammonium.Not only ingredient is more complex for the top dressing liquid that the technology provides, and preparation is time-consuming also longer, needs first that tea tree is dedicated
Organic fertilizer, which is put into the water of 3~5 times of weight, to be impregnated 5~10 days, organic fertilizer filtrate is obtained by filtration, then vegetables are broken into vegetable juice,
Mixing is placed on 20~25 DEG C of 4~10h of processing, oil meal, potassium dihydrogen phosphate and ammonium hydrogen carbonate is then sequentially added, then at 20~25
DEG C environment in handle 2~4 days.
So the preparation method for how obtaining a kind of dedicated vernalization fertilizer of the efficient tea tree suitable for production is still this field
Technical staff's yet unresolved issue.
Summary of the invention
It is an object of the invention to solve the dedicated vernalization fertilizer complicated component of tea tree in the prior art, the cumbersome time-consuming of preparation process
Long defect, and then a kind of preparation method of dedicated vernalization fertilizer of the efficient tea tree suitable for production is provided.
Above-mentioned purpose of the invention is achieved through the following technical solutions:
A kind of preparation method of tea tree vernalization special fertilizer, including,
The mixed serum for preparing biomass carbon, ammonium hydroxide and humic acid, is passed through CO2Or contain CO2Gas;
Collect obtained solid and drying.
It further include being passed through the CO2Or contain CO2Gas when the mixed serum is stirred.
It further include often being passed through the CO2Or contain CO20.5~3min of gas after, rotten plant is added into the mixed serum
Acid.
Often it is passed through the CO2Or contain CO20.5~1min of gas after, add humic acid into the mixed serum.
The biomass carbon is that biomass is carbonized to obtain at 450~530 DEG C.
Biomass is carbonized at 450~530 DEG C, obtains pyrolysis gas and biomass carbon;
Pyrolysis gas is burnt, burning gained flue gas is collected;
The biomass carbon is crushed, is made into mixed serum with ammonium hydroxide and humic acid, the flue gas is passed through and is reacted;
Collect obtained solid and drying.
Pyrolysis gas is condensed or sprayed, biogas is obtained, is burnt, burning gained flue gas is collected.
The condensate liquid of the pyrolysis gas or spray liquid are subjected to water-oil separating, gained water phase is sprayed to the biomass carbon
On, the preparation of mixed serum is then carried out again.
Liquid is used as Recycling Mother Solution after the collection solid.
Technical solution of the present invention has the advantages that
1. the preparation method of fertilizer special for tea trees provided by the invention, preparation biomass carbon, ammonium hydroxide and humic acid is mixed first
Slurries are closed, then are passed through CO2Or contain CO2Gas, then separation product obtains tea tree vernalization special fertilizer after dry.By using height
Aromatization, porous solid matter biomass carbon are spent as the nuclei of crystallization/carrier, so that the CO being passed through2It reacts with ammonia water, generates carbon
Sour hydrogen ammonium.Ammonium hydrogen carbonate property is unstable, volatile, plant recovery of nutrient is low be easy to cause waste, and the application is different from biology
Matter charcoal is mixed with the direct of ammonium hydrogen carbonate, be using the biomass carbon of surface acidic functionality rich in as the nuclei of crystallization/carrier,
Biomass carbon based compound fertilizer is prepared with physical and chemical adsorption-chemical reaction method, that is, utilizes NH3+CO2+H2O is in charcoal matrix
Hole surfaces externally and internally is reacted and is obtained, and after the combination with biomass carbon and humic acid, the comprehensive benefit of nitrogen has been effectively ensured
With rate, there is remarkable result on to tea tree spring vernalization;And stability is high, achievees the effect that sustained release, overcomes traditional ammonium bicarbonate
Fertilizer easily decomposes the shortcomings that volatilization, effectively improves the utilization rate of fertilizer.
2. the preparation method of fertilizer special for tea trees provided by the invention, the operation by adding humic acid can obtain effect more
Excellent tea tree vernalization special fertilizer.The present invention is also by using the combustion product gases of pyrolysis gas produced by charing biomass carbon as dedicated
Fertile raw materials for production turn waste into wealth the carbon dioxide sequestration in combustion product gases, reduce greenhouse gas emission;Meanwhile pyrolysis gas fires
Burn the SO in flue gas2、NOxIt can be also converted into ammonium nitrate and ammonium sulfate, be adsorbed on biomass carbon, collaboration improves fertilizer efficiency.
3. the preparation method of fertilizer special for tea trees provided by the invention still further preferably passes through pyrolysis gas condensate liquid or spray
The biomass carbon of the sprinkling of water phase obtained by liquid water-oil separating, so that biomass carbon contains multiple nutritional components.In addition, biomass carbon is also
It is good soil conditioner, nutrient can also be provided while capable of improving soil texture for crop, while it is useless to realize agricultural
The comprehensive utilization of gurry, biomass carbon and fertilizer are complex as soil-fertilizer-environment and propose comprehensive solution.
Specific embodiment
Technical solution of the present invention will be clearly and completely described below, it is clear that described embodiment is this hair
Bright a part of the embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not having
Every other embodiment obtained under the premise of creative work is made, shall fall within the protection scope of the present invention.In addition, below
Technical characteristic involved in described different embodiments of the present invention as long as they do not conflict with each other can be mutual
In conjunction with.
Embodiment 1
A kind of preparation method of tea tree vernalization special fertilizer is present embodiments provided, including,
Biomass carbon, industrial ammonia and humic acid are taken, is stirred, mixed serum is configured to;Gained slurries are placed in instead
It answers in kettle, is passed through CO2.Reaction gained suspension is separated by solid-liquid separation, solid is dried to get dedicated to tea tree vernalization
Fertilizer.
Embodiment 2
A kind of preparation method of tea tree vernalization special fertilizer is present embodiments provided, including,
Biomass carbon, ammonium hydroxide and humic acid are taken, is stirred, mixed serum is configured to;Gained slurries are placed in reaction kettle
It is interior, it is passed through CO2, and humic acid is inwardly added every 1min.To be centrifuged after the reaction was completed, obtained solid is done
It is dry to get arrive tea tree vernalization special fertilizer.
Embodiment 3
A kind of preparation method of tea tree vernalization special fertilizer is present embodiments provided, including,
It takes biomass to be carbonized under 450~530 DEG C, limited oxygen condition, obtains pyrolysis gas and biomass carbon.Combustion and pyrolysis
Gas collects combustion product gases;The heat that burning generates can be used as biomass carbonated heat source.
The biomass carbon that charing is obtained crushes, and takes 10kg and 5kg ammonium hydroxide and 1kg humic acid to be stirred, is configured to mix
Close slurries;Gained slurries are placed in reaction kettle, the flue gas that the pyrolysis gas burning that volume is slurries 1:1 generates is passed through, carries out anti-
It answers, and every 2min adds humic acid 0.5kg until reaction terminates.
Reaction gained suspension is separated by solid-liquid separation, solid is dried to arrive tea tree vernalization special fertilizer.
Embodiment 4
A kind of preparation method of tea tree vernalization special fertilizer is present embodiments provided, including,
It takes biomass to be carbonized under 450~530 DEG C, limited oxygen condition, obtains pyrolysis gas and biomass carbon.Made using water
Obtained pyrolysis gas is sprayed for spray agent, spray liquid, which is stood, carries out water-oil separating, and gained water phase is sprayed to biomass
On charcoal, and the clean pyrolysis gas that the spray that burns obtains, collect combustion product gases;The heat that burning generates can be used as biomass carbonated
Heat source.
Above-mentioned biomass carbon is crushed, 10kg and 6kg ammonium hydroxide and 2kg humic acid is taken to be stirred, is configured to mixed serum;
Gained slurries are placed in reaction kettle, the flue gas that clean pyrolysis gas burning generates is passed through, is reacted.
Reaction gained suspension is separated by solid-liquid separation, solid is dried to arrive tea tree vernalization special fertilizer.
Embodiment 5
A kind of preparation method of tea tree vernalization special fertilizer is present embodiments provided, including,
It takes biomass to be carbonized under 450~530 DEG C, limited oxygen condition, obtains pyrolysis gas and biomass carbon.Made using water
Obtained pyrolysis gas is sprayed for spray agent, spray liquid, which is stood, carries out water-oil separating, and gained water phase is sprayed to biomass
On charcoal, and the clean pyrolysis gas that the spray that burns obtains, collect combustion product gases;The heat that burning generates can be used as biomass carbonated
Heat source.
Above-mentioned biomass carbon is crushed and is stirred with ammonium hydroxide and humic acid, mixed serum is configured to;Gained slurries are set
In the flue gas in reaction kettle, being passed through clean pyrolysis gas burning generation, reacted.
Reaction gained suspension is separated by solid-liquid separation, solid is dried to arrive tea tree vernalization special fertilizer.
Comparative example
This comparative example provides a kind of preparation method of tea tree vernalization fertilizer, including,
Biomass carbon, industrial ammonia are taken, is stirred, mixed serum is configured to;Gained slurries are placed in reaction kettle, are led to
Enter CO2.Reaction gained suspension is separated by solid-liquid separation, solid is dried to get fertile to tea tree vernalization.
Experimental example
The tea tree vernalization fertilizer that each embodiment and comparative example is obtained is with commercially available ammonium hydrogen carbonate chemical fertilizer in the same of Nanjing tea place
Test is compared in one kind, the tea tree in same tea age.Setting processing is respectively as follows: 1: singly apply ammonium hydrogen carbonate chemical fertilizer, 2: singly applying
3-1: comparative example 1 vernalization fertilizer singly applies embodiment 1 vernalization fertilizer, 3-2: singly applying embodiment 2 vernalization fertilizer, 3-3: singly apply 3 vernalization of embodiment
Fertilizer, 3-4: singly apply embodiment 4 vernalization fertilizer, 3-5: singly applying embodiment 5 vernalization fertilizer, 4-1: 5 vernalization fertilizer of embodiment, which is matched, applies foliar fertilizer, 4-
2: 1 vernalization fertilizer of comparative example, which is matched, applies foliar fertilizer.Tealeaves new-tip length and hundred-bud weight are detected, as a result as shown in table 1 below.
Table 1 respectively handles fresh tea new-tip length and hundred-bud weight
The tealeaves sprouting budding relatively processing 1 and processing 2 of comparison discovery, processing 3-1~3-4 and processing 4 will shift to an earlier date 1-2 days.
In addition, as can be seen from the above table, the more conventional ammonium hydrogen carbonate processing of new-tip length of vernalization fertilizer processing will be grown, meanwhile, hundred buds
Weight is also heavier than processed conventionally;And with the better effect for applying blade face.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
Variation is still in the protection scope of this invention.
Claims (9)
1. a kind of preparation method of tea tree vernalization special fertilizer, which is characterized in that including,
The mixed serum for preparing biomass carbon, ammonium hydroxide and humic acid, is passed through CO2Or contain CO2Gas;
Collect obtained solid and drying.
2. the preparation method of tea tree vernalization special fertilizer according to claim 1, which is characterized in that further include being passed through the CO2
Or contain CO2Gas when the mixed serum is stirred.
3. the preparation method of tea tree vernalization special fertilizer according to claim 1 or 2, which is characterized in that further include being passed through CO2
Or contain CO2Gas process in, intermittently add humic acid into the mixed serum.
4. the preparation method of tea tree vernalization special fertilizer according to claim 3, which is characterized in that intermittently to described mixed
When adding humic acid in conjunction slurries, the time interval for adding humic acid is 0.5~3min.
5. the preparation method of tea tree vernalization special fertilizer according to claim 1-4, which is characterized in that the biology
Matter charcoal is that biomass is carbonized to obtain at 450~530 DEG C.
6. the preparation method of tea tree vernalization special fertilizer according to claim 5, which is characterized in that including biomass exists
It is carbonized at 450~530 DEG C, obtains pyrolysis gas and biomass carbon;
Pyrolysis gas is burnt, burning gained flue gas is collected;
The biomass carbon is crushed, is made into mixed serum with ammonium hydroxide and humic acid, the flue gas is passed through and is reacted;
Collect obtained solid and drying.
7. the preparation method of tea tree vernalization special fertilizer according to claim 6, which is characterized in that further include, by pyrolysis gas
It is condensed or is sprayed, obtain biogas, burnt, collect burning gained flue gas.
8. the preparation method of tea tree vernalization special fertilizer according to claim 7, which is characterized in that further include, by the heat
The condensate liquid or spray liquid vented one's spleen carry out water-oil separating, and gained water phase is sprayed on the biomass carbon, is then mixed again
Close the preparation of slurries.
9. the preparation method of tea tree vernalization special fertilizer according to claim 1-8, which is characterized in that the collection
Liquid is used as Recycling Mother Solution after solid.
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CN1746138A (en) * | 2004-09-08 | 2006-03-15 | 北海奥克兰生物工程有限公司 | Production of long-effective ammonium bicarbonate composite fertilizer of vegetable |
WO2010139028A1 (en) * | 2009-06-05 | 2010-12-09 | Industrial Ecosystems Pty Ltd | Method and integrated system for producing electric power and fertiliser |
CN102924189A (en) * | 2012-11-07 | 2013-02-13 | 浙江大学 | Method for recovering carbon-based ammonium bicarbonate in refuse landfill |
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Application publication date: 20181211 |