CN108928875A - A kind of dedicated improver of water quality in fish pond and preparation method thereof - Google Patents
A kind of dedicated improver of water quality in fish pond and preparation method thereof Download PDFInfo
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- CN108928875A CN108928875A CN201810802821.5A CN201810802821A CN108928875A CN 108928875 A CN108928875 A CN 108928875A CN 201810802821 A CN201810802821 A CN 201810802821A CN 108928875 A CN108928875 A CN 108928875A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 95
- 241000251468 Actinopterygii Species 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 51
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 43
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000006213 oxygenation reaction Methods 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 239000002253 acid Substances 0.000 claims abstract description 21
- 150000007513 acids Chemical class 0.000 claims abstract description 21
- 230000009286 beneficial effect Effects 0.000 claims abstract description 21
- 230000004048 modification Effects 0.000 claims abstract description 21
- 238000012986 modification Methods 0.000 claims abstract description 21
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims abstract description 20
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 16
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000006872 improvement Effects 0.000 claims abstract description 16
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 16
- 241000411851 herbal medicine Species 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 43
- 239000002002 slurry Substances 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 30
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 20
- 241000894006 Bacteria Species 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 239000002077 nanosphere Substances 0.000 claims description 12
- 239000010457 zeolite Substances 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 11
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 10
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims description 10
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 10
- 239000001569 carbon dioxide Substances 0.000 claims description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 10
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims description 10
- 229940099429 polyoxyl 40 stearate Drugs 0.000 claims description 10
- 244000025254 Cannabis sativa Species 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 240000006054 Agastache cana Species 0.000 claims description 6
- 241000205585 Aquilegia canadensis Species 0.000 claims description 6
- 241000193830 Bacillus <bacterium> Species 0.000 claims description 6
- 239000002028 Biomass Substances 0.000 claims description 6
- 235000010650 Hyssopus officinalis Nutrition 0.000 claims description 6
- 241000108664 Nitrobacteria Species 0.000 claims description 6
- 240000004980 Rheum officinale Species 0.000 claims description 6
- 235000008081 Rheum officinale Nutrition 0.000 claims description 6
- 230000000243 photosynthetic effect Effects 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- 239000004343 Calcium peroxide Substances 0.000 claims description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 5
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims description 5
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 5
- 239000000920 calcium hydroxide Substances 0.000 claims description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 5
- 235000019402 calcium peroxide Nutrition 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 5
- 229930182817 methionine Natural products 0.000 claims description 5
- 239000011664 nicotinic acid Substances 0.000 claims description 5
- 229960003512 nicotinic acid Drugs 0.000 claims description 5
- 235000001968 nicotinic acid Nutrition 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 5
- 229940045872 sodium percarbonate Drugs 0.000 claims description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 5
- 230000003381 solubilizing effect Effects 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 229920002522 Wood fibre Polymers 0.000 claims description 3
- 239000010231 banlangen Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 235000007516 Chrysanthemum Nutrition 0.000 claims 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims 1
- 244000269722 Thea sinensis Species 0.000 claims 1
- 240000003307 Zinnia violacea Species 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 239000003344 environmental pollutant Substances 0.000 abstract description 4
- 238000000855 fermentation Methods 0.000 abstract description 4
- 230000004151 fermentation Effects 0.000 abstract description 4
- 231100000719 pollutant Toxicity 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 8
- 238000009360 aquaculture Methods 0.000 description 7
- 239000003599 detergent Substances 0.000 description 7
- 244000228451 Stevia rebaudiana Species 0.000 description 5
- 235000006092 Stevia rebaudiana Nutrition 0.000 description 5
- 241000801064 Zinnia Species 0.000 description 5
- 244000144974 aquaculture Species 0.000 description 5
- -1 Sodium dialkyl sulfate Chemical class 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- 241000238557 Decapoda Species 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 244000300264 Spinacia oleracea Species 0.000 description 2
- 235000009337 Spinacia oleracea Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 235000015170 shellfish Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical group O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 208000004232 Enteritis Diseases 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 241001482311 Trionychidae Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000002180 anti-stress Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 210000002249 digestive system Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- BQPIGGFYSBELGY-UHFFFAOYSA-N mercury(2+) Chemical compound [Hg+2] BQPIGGFYSBELGY-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000006041 probiotic Substances 0.000 description 1
- 235000018291 probiotics Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 125000003396 thiol group Chemical class [H]S* 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
- A01K63/042—Introducing gases into the water, e.g. aerators, air pumps
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Marine Sciences & Fisheries (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Fodder In General (AREA)
- Feed For Specific Animals (AREA)
- Farming Of Fish And Shellfish (AREA)
Abstract
The invention discloses dedicated improver of water quality in a kind of fish pond and preparation method thereof, the raw material including following parts by weight: 30-40 parts of modified zeolite powder, 1-2 parts of biological modification mushroom, beneficial 1-2 parts of acids object, 17-25 parts of Chinese herbal medicine, 1-3 parts of sulfydryl lignocellulosic, 15-25 parts of montmorillonite, 0.4-0.6 parts of L-AA, improvement calcium carbonate 10-14 parts, 10-20 parts of oxygenation agent, 8-12 parts of water-soluble emulsifier.The dedicated improver of water quality in fish pond of the invention is safe and healthy, water oxygenation can be continuously, and the performance with disinfection and absorption heavy metal element, adsorption efficiency is high, furthermore product is solid extruding form to the pollutant that can be adsorbed more wide spectrum, it is possible to reduce water quality is polluted in waste and putrefactive fermentation；Preparation method of the invention simultaneously, material cost is lower, raw material is easy to get and technique is concise, use value with higher and good application prospect.
Description
Technical field
The present invention relates to technical field of aquaculture, and in particular to a kind of dedicated improver of water quality in fish pond and its preparation side
Method.
Background technique
Aquaculture has the modes such as extensive cultivation, intensive culture and high density culture, and extensive cultivation is to launch seedling in medium and small natural water area
Kind, aquatic products are formed by natural bait completely, such as lake and reservoir breeds fish and supports shellfish with shallow sea, intensive culture is in compared with small size pond with throwing
Bait, fertilizing method form aquatic products, such as aqiuculrue, fish culture in net pen and enclosure culture, net enclosure culture.High density culture is using flowing water, control
It temperature, oxygenation and the methods of feeds high-quality bait, high-density breeding is carried out in small size pond, so that high yield is obtained, as flowing water is highly dense
Degree breeds fish, shrimp etc., and world aquaculture is the most flourishing with some countries in Asia, mainly has China, Japan, India and Southeast Asia all
State.The total output of the aquacultures such as early 1980s whole world fish, shellfish, shrimp, crab class is about 6,000,000 tons, wherein 66%
For freshwater aquiculture yield, remaining is sea-farming yield.Countries in Asia's yield (China accounts for half therein) accounts for cultivation total output
85%, the Soviet Union accounts for 6%, and America and Europe respectively account for 2% or so, and aquaculture will use a large amount of feeds leads to water degradation, makes
At environmental problems such as water pollutions.
Chinese patent literature (publication number: CN104386895A) discloses a kind of improver of water quality used for aquiculture, with weight
It measures part to count, including following components: 5-10 parts of rape, 5-10 parts of corn, 7-15 parts of spinach, 2-5 parts of bacillus, photosynthetic bacteria 3-
7 parts, 2-5 parts of nitrobacteria, 5-10 parts of amino acid, 2-10 parts of chitosan, the improver of water quality is based on rape, corn, spinach
Material, the nutriment provided for aquatic products or not good enough, while chitosan adsorption effect is smaller, limits modifying agent and supports in aquatic products
The development of plantation technology.
Summary of the invention
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of dedicated improver of water quality in fish pond, the modifying agents
It is safe and healthy, it can be continuously water oxygenation, and the performance with disinfection and absorption heavy metal element, adsorption efficiency
Height, furthermore product is solid extruding form to the pollutant that can be adsorbed more wide spectrum, it is possible to reduce waste and putrefactive fermentation pollution
Water quality；Preparation method of the invention simultaneously, material cost is lower, raw material is easy to get and technique is concise, with higher to use valence
Value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that
The present invention provides a kind of dedicated improver of water quality in fish pond, the raw material including following parts by weight:
30-40 parts of modified zeolite powder, 1-2 parts of biological modification mushroom, beneficial 1-2 parts of acids object, 17-25 parts of Chinese herbal medicine, mercapto
1-3 parts of base lignocellulosic, 15-25 parts of montmorillonite, 0.4-0.6 parts of L-AA, improvement calcium carbonate 10-14 parts, oxygenation agent
10-20 parts, 8-12 parts of water-soluble emulsifier.
Preferably, the dedicated improver of water quality in the fish pond includes the raw material of following parts by weight:
35 parts of modified zeolite powder, 1.5 parts of biological modification mushroom, beneficial 1.5 parts of acids object, 20 parts of Chinese herbal medicine, sulfydryl are wooden
2 parts of cellulose, 20 parts of montmorillonite, 0.5 part of L-AA, improvement 12 parts of calcium carbonate, 15 parts of oxygenation agent, water-soluble emulsifier 10
Part.
Preferably, the modified zeolite powder, preparation method thereof is to mix zeolite powder, calcium sulfate, then be placed in temperature and be
30min is calcined at 200 DEG C, is sent into ball mill after cooling and is carried out ball milling, being milled to partial size is 100 mesh, by zeolite powder after ball milling
Being added to mass fraction is in 2% ferric chloride solution, and speed of agitator 160r/min disperses 20min, ten are then added thereto
Sodium dialkyl sulfate, sodium hydroxide continue to stir 50min, are eventually adding cumyl peroxide, nanosphere, speed of agitator liter
To 200r/min, continue to stir 1.5h to get nanosphere modified zeolite powder.
Preferably, the biological modification mushroom is phosphate solubilizing bacteria, nitrobacteria, photosynthetic bacteria and bacillus according to weight ratio
The mixture of 4:1:2:1 composition.
Preferably, the mixture that the beneficial acids object is niacin, citric acid, methionine are formed according to weight ratio 5:1:2.
Preferably, the Chinese herbal medicine includes the raw material of following parts by weight: 3-5 parts of Radix Glycyrrhizae, 1-2 parts of rheum officinale, honeysuckle 5-9
Part, 10-14 parts of Radix Isatidis, 6-8 parts of Zinnia, 6-10 parts of STEVIA REBAUDIANA, 4-6 parts of hyssop.
Preferably, the modified calcium carbonate the preparation method comprises the following steps: being passed through carbon dioxide into 20% calcium hydroxide slurry
Gas, and into slurry, 10% persulfuric acid calcium solution of addition and 25% hydrazine hydrate solution are sufficiently stirred, persulfuric acid calcium solution
Additional amount be the 5% of slurry volume, the additional amount of hydrazine hydrate solution is the 8% of slurry volume, and carbon dioxide gas is passed through
It is dry then by slurry filtration until amount is so that slurry pH value is in neutrality, crushed after being dried again with account for dry biomass
7% sodium polyacrylate disperant is uniformly mixed, and finally disperses the deionized water of 5 times of volumes of mixture that suspension is made,
Spray dried, modified calcium carbonate needed for being made.
Preferably, the oxygenation agent are as follows: oxygenation agent is coated slow-release SODIUM PERCARBONATE or coated slow-release calper calcium peroxide；
The water-soluble emulsifier is pure NaLS or polyoxyl 40 stearate, the molten type emulsifier of oil
The ester of Span series is formed by from different higher fatty acids for pure NaLS or polyoxyl 40 stearate.
The present invention also provides a kind of methods for preparing the dedicated improver of water quality in fish pond, comprising the following steps:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground in grinder by step 2
200 meshes obtain powder A；
Step 3 L-AA is added in the water of 15-25 times of its weight, and being heated to temperature is 40-50 DEG C, and feeding is stirred
It mixes in machine, sequentially adds sulfydryl lignocellulosic, beneficial to acids object, water-soluble emulsifier, be 350-450r/ in speed of agitator
It is stirred 20-30 minutes under min, adds powder A, the oxygenation agent of step 2 preparation, continue stirring 15-25 minutes, mixed
Close object B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, is 200-300r/min in speed of agitator
Lower stirring 20-30 minutes sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, turns in stirring
Speed is to stir 30-40 minutes under 400-500r/min, obtain mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls by step 5, barrel temperature
Feed zone control is at 50 DEG C, and interlude control is at 60 DEG C, and discharging section control is at 50 DEG C, screw speed 35-45r/min, feeding
Speed 30-40r/min obtains the dedicated improver of water quality in granular fish pond.
Preferably, the preparation step are as follows:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground in grinder by step 2
200 meshes obtain powder A；
Step 3 L-AA is added in the water of 20 times of its weight, and being heated to temperature is 45 DEG C, is sent into blender
In, it sequentially adds sulfydryl lignocellulosic, beneficial to acids object, water-soluble emulsifier, is stirred in the case where speed of agitator is 400r/min
25 minutes, powder A, the oxygenation agent of step 2 preparation are added, continues stirring 20 minutes, obtains mixture B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, is stirred in the case where speed of agitator is 250/min
It mixes 25 minutes, sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, be in speed of agitator
Under 450r/min, stirs 35 minutes, obtain mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls by step 5, barrel temperature
Feed zone control is at 50 DEG C, and interlude control is at 60 DEG C, and discharging section control is at 50 DEG C, screw speed 40r/min, rate of feeding
35r/min obtains the dedicated improver of water quality in granular fish pond.
Compared with prior art, the present invention have it is following the utility model has the advantages that
(1) a kind of Chinese herbal medicine substance of the dedicated improver of water quality addition in fish pond of the invention, predominantly Radix Glycyrrhizae, rheum officinale, gold
Honeysuckle flower, Radix Isatidis, Zinnia, STEVIA REBAUDIANA, hyssop can effectively enhance the immunocompetence of soft-shelled turtle, improve its digestive system,
The survival rate and anti-stress ability of fish are improved, the generation of fish sperm bottom plate, Leucoplakia, enteritis is reduced, improves trimmed size and quality；
And the usage amount that can be reduced antibiotic, the problem of water eutrophication is effectively relieved, improve the economic benefit of raiser.
(2) the dedicated improver of water quality in a kind of fish pond of the invention is added to zeolite powder and is modified by nanosphere, boiling
Stone surface not only has a large amount of micropores, while nanosphere is engaged with zeolite, promotes the small substances such as absorption heavy metal, reaches
Fine improved effect.
(3) montmorillonite in the dedicated improver of water quality in a kind of fish pond of the invention can play collaboration with modified zeolite powder and make
With, have the function that purification, clarification water body, improve the transparency of water body；L-AA, biological modification mushroom and beneficial acids
Object can have the function that carry out disinfection to water body disinfection by the means of chemistry and biology, reduce harmful microorganism in water body
Quantity；L-AA can not only play antioxidation, and can be used as the nutritional supplement of aquatic biological, improve
The immunity of aquatic biological.The effect of sodium bicarbonate in component is to carry out the buffering adjusting of water PH value, avoids water body
Acidification, influences the health of aquatic products.
(4) calcium carbonate of the dedicated improver of water quality modified calcium carbonate in a kind of fish pond of the invention, this type has quality
By force, the characteristics of porosity and looseness, it can replace active carbon and used as inorganic matter adsorbent, this material material compared with active carbon
It is at low cost while also more environmentally-friendly, the consumption to biomass resource can be reduced.
(5) the dedicated improver of water quality in a kind of fish pond of the invention is safe and healthy, can be continuously water oxygenation, and have
The performance of disinfection and absorption heavy metal element, adsorption efficiency is high, and furthermore product is the pollutant that can be adsorbed more wide spectrum
Solid extruding form, it is possible to reduce water quality is polluted in waste and putrefactive fermentation；Preparation method of the invention simultaneously, material cost compared with
Low, raw material is easy to get and technique is concise, use value with higher and good application prospect.
Specific embodiment
Combined with specific embodiments below, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of dedicated improver of water quality in fish pond of the present embodiment, the raw material including following parts by weight:
30 parts of modified zeolite powder, 1 part of biological modification mushroom, beneficial 1 part of acids object, 17 parts of Chinese herbal medicine, sulfydryl wood fibre
1 part of element, 15 parts of montmorillonite, 0.4 part of L-AA, improvement 10 parts of calcium carbonate, 10 parts of oxygenation agent, 8 parts of water-soluble emulsifier.
Modified zeolite powder, preparation method thereof in the present embodiment is to mix zeolite powder, calcium sulfate, then be placed in temperature and be
30min is calcined at 200 DEG C, is sent into ball mill after cooling and is carried out ball milling, being milled to partial size is 100 mesh, by zeolite powder after ball milling
Being added to mass fraction is in 2% ferric chloride solution, and speed of agitator 160r/min disperses 20min, ten are then added thereto
Sodium dialkyl sulfate, sodium hydroxide continue to stir 50min, are eventually adding cumyl peroxide, nanosphere, speed of agitator liter
To 200r/min, continue to stir 1.5h to get nanosphere modified zeolite powder.
Biological modification mushroom in the present embodiment is phosphate solubilizing bacteria, nitrobacteria, photosynthetic bacteria and bacillus according to weight
Than the mixture of 4:1:2:1 composition.
Beneficial acids object in the present embodiment is the mixing that niacin, citric acid, methionine are formed according to weight ratio 5:1:2
Object.
Chinese herbal medicine in the present embodiment includes the raw material of following parts by weight: 3 parts of Radix Glycyrrhizae, 1 part of rheum officinale, 5 parts of honeysuckle, plate are blue
10 parts of root, 6 parts of Zinnia, 6 parts of STEVIA REBAUDIANA, 4 parts of hyssop.
Modified calcium carbonate in the present embodiment the preparation method comprises the following steps: being passed through carbon dioxide into 20% calcium hydroxide slurry
Gas, and into slurry, 10% persulfuric acid calcium solution of addition and 25% hydrazine hydrate solution are sufficiently stirred, persulfuric acid calcium solution
Additional amount be the 5% of slurry volume, the additional amount of hydrazine hydrate solution is the 8% of slurry volume, and carbon dioxide gas is passed through
It is dry then by slurry filtration until amount is so that slurry pH value is in neutrality, crushed after being dried again with account for dry biomass
7% sodium polyacrylate disperant is uniformly mixed, and finally disperses the deionized water of 5 times of volumes of mixture that suspension is made,
Spray dried, modified calcium carbonate needed for being made.
Oxygenation agent in the present embodiment are as follows: oxygenation agent is coated slow-release SODIUM PERCARBONATE or coated slow-release calper calcium peroxide；
The water-soluble emulsifier is pure NaLS or polyoxyl 40 stearate, the molten type emulsifier of oil
The ester of Span series is formed by from different higher fatty acids for pure NaLS or polyoxyl 40 stearate.
A kind of preparation method of the dedicated improver of water quality in fish pond of the present embodiment, comprising the following steps:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground in grinder by step 2
200 meshes obtain powder A；
Step 3 L-AA is added in the water of 15 times of its weight, and being heated to temperature is 40 DEG C, is sent into blender
In, sulfydryl lignocellulosic is sequentially added, beneficial to acids object, water-soluble emulsifier, in the case where speed of agitator is 350-450r/min
Stirring 20 minutes adds powder A, the oxygenation agent of step 2 preparation, continues stirring 15 minutes, obtain mixture B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, is stirred in the case where speed of agitator is 200r/min
It mixes 20 minutes, sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, be in speed of agitator
Under 400r/min, stirs 30 minutes, obtain mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls by step 5, barrel temperature
Feed zone control is at 50 DEG C, and interlude control is at 60 DEG C, and discharging section control is at 50 DEG C, screw speed 35r/min, rate of feeding
30r/min obtains the dedicated improver of water quality in granular fish pond.
Embodiment 2.
A kind of dedicated improver of water quality in fish pond of the present embodiment, the raw material including following parts by weight:
40 parts of modified zeolite powder, 2 parts of biological modification mushroom, beneficial 2 parts of acids object, 25 parts of Chinese herbal medicine, sulfydryl wood fibre
3 parts of element, 25 parts of montmorillonite, 0.6 part of L-AA, improvement 14 parts of calcium carbonate, 20 parts of oxygenation agent, 12 parts of water-soluble emulsifier.
Modified zeolite powder, preparation method thereof in the present embodiment is to mix zeolite powder, calcium sulfate, then be placed in temperature and be
30min is calcined at 200 DEG C, is sent into ball mill after cooling and is carried out ball milling, being milled to partial size is 100 mesh, by zeolite powder after ball milling
Being added to mass fraction is in 2% ferric chloride solution, and speed of agitator 160r/min disperses 20min, ten are then added thereto
Sodium dialkyl sulfate, sodium hydroxide continue to stir 50min, are eventually adding cumyl peroxide, nanosphere, speed of agitator liter
To 200r/min, continue to stir 1.5h to get nanosphere modified zeolite powder.
Biological modification mushroom in the present embodiment is phosphate solubilizing bacteria, nitrobacteria, photosynthetic bacteria and bacillus according to weight
Than the mixture of 4:1:2:1 composition.
Beneficial acids object in the present embodiment is the mixing that niacin, citric acid, methionine are formed according to weight ratio 5:1:2
Object.
Chinese herbal medicine in the present embodiment includes the raw material of following parts by weight: 5 parts of Radix Glycyrrhizae, 2 parts of rheum officinale, 9 parts of honeysuckle, plate are blue
14 parts of root, 8 parts of Zinnia, 10 parts of STEVIA REBAUDIANA, 6 parts of hyssop.
Modified calcium carbonate in the present embodiment the preparation method comprises the following steps: being passed through carbon dioxide into 20% calcium hydroxide slurry
Gas, and into slurry, 10% persulfuric acid calcium solution of addition and 25% hydrazine hydrate solution are sufficiently stirred, persulfuric acid calcium solution
Additional amount be the 5% of slurry volume, the additional amount of hydrazine hydrate solution is the 8% of slurry volume, and carbon dioxide gas is passed through
It is dry then by slurry filtration until amount is so that slurry pH value is in neutrality, crushed after being dried again with account for dry biomass
7% sodium polyacrylate disperant is uniformly mixed, and finally disperses the deionized water of 5 times of volumes of mixture that suspension is made,
Spray dried, modified calcium carbonate needed for being made.
Oxygenation agent in the present embodiment are as follows: oxygenation agent is coated slow-release SODIUM PERCARBONATE or coated slow-release calper calcium peroxide；
The water-soluble emulsifier is pure NaLS or polyoxyl 40 stearate, the molten type emulsifier of oil
The ester of Span series is formed by from different higher fatty acids for pure NaLS or polyoxyl 40 stearate.
A kind of preparation method of the dedicated improver of water quality in fish pond of the present embodiment, comprising the following steps:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground in grinder by step 2
200 meshes obtain powder A；
Step 3 L-AA is added in the water of 25 times of its weight, and being heated to temperature is 50 DEG C, is sent into blender
In, it sequentially adds sulfydryl lignocellulosic, beneficial to acids object, water-soluble emulsifier, is stirred in the case where speed of agitator is 450r/min
30 minutes, powder A, the oxygenation agent of step 2 preparation are added, continues stirring 25 minutes, obtains mixture B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, is stirred in the case where speed of agitator is 300r/min
It mixes 30 minutes, sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, be in speed of agitator
Under 500r/min, stirs 40 minutes, obtain mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls by step 5, barrel temperature
Feed zone control is at 50 DEG C, and interlude control is at 60 DEG C, and discharging section control is at 50 DEG C, screw speed 45r/min, rate of feeding
40r/min obtains the dedicated improver of water quality in granular fish pond.
Embodiment 3.
A kind of dedicated improver of water quality in fish pond of the present embodiment, the raw material including following parts by weight:
35 parts of modified zeolite powder, 1.5 parts of biological modification mushroom, beneficial 1.5 parts of acids object, 20 parts of Chinese herbal medicine, sulfydryl are wooden
2 parts of cellulose, 20 parts of montmorillonite, 0.5 part of L-AA, improvement 12 parts of calcium carbonate, 15 parts of oxygenation agent, water-soluble emulsifier 10
Part.
Modified zeolite powder, preparation method thereof in the present embodiment is to mix zeolite powder, calcium sulfate, then be placed in temperature and be
30min is calcined at 200 DEG C, is sent into ball mill after cooling and is carried out ball milling, being milled to partial size is 100 mesh, by zeolite powder after ball milling
Being added to mass fraction is in 2% ferric chloride solution, and speed of agitator 160r/min disperses 20min, ten are then added thereto
Sodium dialkyl sulfate, sodium hydroxide continue to stir 50min, are eventually adding cumyl peroxide, nanosphere, speed of agitator liter
To 200r/min, continue to stir 1.5h to get nanosphere modified zeolite powder.
Biological modification mushroom in the present embodiment is phosphate solubilizing bacteria, nitrobacteria, photosynthetic bacteria and bacillus according to weight
Than the mixture of 4:1:2:1 composition.
Beneficial acids object in the present embodiment is the mixing that niacin, citric acid, methionine are formed according to weight ratio 5:1:2
Object.
Chinese herbal medicine in the present embodiment includes the raw material of following parts by weight: 4 parts of Radix Glycyrrhizae, 1.5 parts of rheum officinale, 7 parts of honeysuckle, plate
12 parts of blue root, 7 parts of Zinnia, 8 parts of STEVIA REBAUDIANA, 5 parts of hyssop.
Modified calcium carbonate in the present embodiment the preparation method comprises the following steps: being passed through carbon dioxide into 20% calcium hydroxide slurry
Gas, and into slurry, 10% persulfuric acid calcium solution of addition and 25% hydrazine hydrate solution are sufficiently stirred, persulfuric acid calcium solution
Additional amount be the 5% of slurry volume, the additional amount of hydrazine hydrate solution is the 8% of slurry volume, and carbon dioxide gas is passed through
It is dry then by slurry filtration until amount is so that slurry pH value is in neutrality, crushed after being dried again with account for dry biomass
7% sodium polyacrylate disperant is uniformly mixed, and finally disperses the deionized water of 5 times of volumes of mixture that suspension is made,
Spray dried, modified calcium carbonate needed for being made.
Oxygenation agent in the present embodiment are as follows: oxygenation agent is coated slow-release SODIUM PERCARBONATE or coated slow-release calper calcium peroxide；
The water-soluble emulsifier is pure NaLS or polyoxyl 40 stearate, the molten type emulsifier of oil
The ester of Span series is formed by from different higher fatty acids for pure NaLS or polyoxyl 40 stearate.
A kind of preparation method of the dedicated improver of water quality in fish pond of the present embodiment, comprising the following steps:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground in grinder by step 2
200 meshes obtain powder A；
Step 3 L-AA is added in the water of 20 times of its weight, and being heated to temperature is 45 DEG C, is sent into blender
In, it sequentially adds sulfydryl lignocellulosic, beneficial to acids object, water-soluble emulsifier, is stirred in the case where speed of agitator is 400r/min
25 minutes, powder A, the oxygenation agent of step 2 preparation are added, continues stirring 20 minutes, obtains mixture B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, is stirred in the case where speed of agitator is 250r/min
It mixes 25 minutes, sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, be in speed of agitator
Under 450r/min, stirs 35 minutes, obtain mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls by step 5, barrel temperature
Feed zone control is at 50 DEG C, and interlude control is at 60 DEG C, and discharging section control is at 50 DEG C, screw speed 40r/min, rate of feeding
35r/min obtains the dedicated improver of water quality in granular fish pond.
Table first is that water quality cleansing agent made from the various embodiments described above and the microbial bacteria water quality cleansing agent of the prior art property
Energy contrast table, wherein existing cleanser 1 is prepared according to method disclosed in the Chinese invention that publication No. is CN103845365A
Bacillus licheniformis probiotics；Existing cleanser 2 is according to disclosed in the Chinese invention that publication No. is CN103409338A
The composite microbial bacteria water quality cleansing agent of method preparation.Water quality cleansing agent obtained by above-described embodiment is used for fishery in the present invention
Dosage is that 10~13mg is added in every cube of fishery cultivating water when cultivation water purifies.
Table one
There are above table data to can be seen that the water quality cleansing agent of water quality cleansing agent of the invention compared with the prior art
Say, either in living bacteria count amount or conserving time limit on have it is obvious must improve, more adaptation the marketization demand.In addition
It is of the invention no matter for the removal of mercury ion, COD, nitrite or ammonia nitrogen for the improvement situation to water quality
Water quality cleansing agent also has obvious advantage.
The dedicated improver of water quality in a kind of fish pond of the invention is safe and healthy, can be continuously water oxygenation, and have and disappear
The performance of toxic action and absorption heavy metal element, adsorption efficiency is high, and furthermore product is solid to the pollutant that can be adsorbed more wide spectrum
Body extruding form, it is possible to reduce water quality is polluted in waste and putrefactive fermentation；Preparation method of the invention simultaneously, material cost compared with
Low, raw material is easy to get and technique is concise, use value with higher and good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (10)
1. a kind of dedicated improver of water quality in fish pond, which is characterized in that the raw material including following parts by weight:
30-40 parts of modified zeolite powder, 1-2 parts of biological modification mushroom, beneficial 1-2 parts of acids object, 17-25 parts of Chinese herbal medicine, sulfydryl wood
1-3 parts of matter cellulose, 15-25 parts of montmorillonite, 0.4-0.6 parts of L-AA, improvement calcium carbonate 10-14 parts, oxygenation agent 10-20
Part, 8-12 parts of water-soluble emulsifier.
2. the dedicated improver of water quality in a kind of fish pond according to claim 1, which is characterized in that the dedicated water quality in fish pond changes
The good dose of raw material including following parts by weight:
35 parts of modified zeolite powder, 1.5 parts of biological modification mushroom, beneficial 1.5 parts of acids object, 20 parts of Chinese herbal medicine, sulfydryl wood fibre
2 parts of element, 20 parts of montmorillonite, 0.5 part of L-AA, improvement 12 parts of calcium carbonate, 15 parts of oxygenation agent, 10 parts of water-soluble emulsifier.
3. the dedicated improver of water quality in a kind of fish pond according to claim 1 or 2, which is characterized in that the modified zeolite powder
Preparation method is to mix zeolite powder, calcium sulfate, then being placed in temperature is that 30min is calcined at 200 DEG C, is sent into ball milling after cooling
Ball milling is carried out in machine, be milled to partial size be 100 mesh, by zeolite powder after ball milling be added to mass fraction be 2% ferric chloride solution in,
Speed of agitator is 160r/min, disperses 20min, lauryl sodium sulfate then is added thereto, sodium hydroxide continues to stir
50min is eventually adding cumyl peroxide, nanosphere, and speed of agitator rises to 200r/min, continue stir 1.5h to get
Nanosphere modified zeolite powder.
4. the dedicated improver of water quality in a kind of fish pond according to claim 1 or 2, which is characterized in that the biological modification bacterium
Class is the mixture that phosphate solubilizing bacteria, nitrobacteria, photosynthetic bacteria and bacillus form according to weight ratio 4:1:2:1.
5. the dedicated improver of water quality in a kind of fish pond according to claim 1 or 2, which is characterized in that the beneficial acids object
The mixture formed for niacin, citric acid, methionine according to weight ratio 5:1:2.
6. the dedicated improver of water quality in a kind of fish pond according to claim 1 or 2, which is characterized in that the Chinese herbal medicine includes
The raw material of following parts by weight: 3-5 parts of Radix Glycyrrhizae, 1-2 parts of rheum officinale, 5-9 parts of honeysuckle, 10-14 parts of Radix Isatidis, 6-8 parts of Zinnia, sweet tea
6-10 parts of leaf chrysanthemum, 4-6 parts of hyssop.
7. the dedicated improver of water quality in a kind of fish pond according to claim 1 or 2, which is characterized in that the modified calcium carbonate
The preparation method comprises the following steps: be passed through carbon dioxide gas into 20% calcium hydroxide slurry, and be added into slurry 10% persulfuric acid
Calcium solution and 25% hydrazine hydrate solution are sufficiently stirred, and the additional amount of persulfuric acid calcium solution is the 5% of slurry volume, hydrazine hydrate solution
Additional amount be the 8% of slurry volume, until the intake of carbon dioxide gas is so that slurry pH value is in neutrality, then will
Slurry filtration, dry, crushed after being dried is uniformly mixed with the sodium polyacrylate disperant for accounting for dry biomass 7% again, will finally mix
The deionized water for closing 5 times of volumes of object disperses that suspension, spray dried, modified calcium carbonate needed for being made is made.
8. the dedicated improver of water quality in a kind of fish pond according to claim 1 or 2, which is characterized in that the oxygenation agent are as follows: increase
Oxygen agent is coated slow-release SODIUM PERCARBONATE or coated slow-release calper calcium peroxide；
The water-soluble emulsifier is pure NaLS or polyoxyl 40 stearate, and the molten type emulsifier of oil is pure
NaLS or polyoxyl 40 stearate are formed by the ester of Span series from different higher fatty acids.
9. a kind of method for preparing the dedicated improver of water quality in fish pond as claimed in claim 1 or 2, which is characterized in that including with
Lower step:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground 200 in grinder by step 2
Mesh obtains powder A；
Step 3 L-AA is added in the water of 15-25 times of its weight, and being heated to temperature is 40-50 DEG C, is sent into blender
In, sulfydryl lignocellulosic is sequentially added, beneficial to acids object, water-soluble emulsifier, in the case where speed of agitator is 350-450r/min
Stirring 20-30 minutes adds powder A, the oxygenation agent of step 2 preparation, continues stirring 15-25 minutes, obtain mixture B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, is stirred in the case where speed of agitator is 200-300r/min
It mixes 20-30 minutes, sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, be in speed of agitator
Under 400-500r/min, stirs 30-40 minutes, obtain mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls, the charging of barrel temperature by step 5
Section control is at 50 DEG C, and interlude control is at 60 DEG C, and discharging section control is at 50 DEG C, screw speed 35-45r/min, rate of feeding
30-40r/min obtains the dedicated improver of water quality in granular fish pond.
10. a kind of preparation method of the dedicated improver of water quality in fish pond according to claim 9, which is characterized in that the system
Standby step are as follows:
Step 1 weighs each component raw material as required；
The medicinal clear water of medium-height grass is rinsed, is sent into pulverizer and crushes after drying, be re-fed into ground 200 in grinder by step 2
Mesh obtains powder A；
Step 3 L-AA is added in the water of 20 times of its weight, and being heated to temperature is 45 DEG C, is sent into blender, according to
Secondary addition sulfydryl lignocellulosic, beneficial acids object, water-soluble emulsifier stir 25 points in the case where speed of agitator is 400r/min
Clock adds powder A, the oxygenation agent of step 2 preparation, continues stirring 20 minutes, obtain mixture B；
The water of its weight 30% is added in modified zeolite powder, montmorillonite by step 4, stirs 25 points in the case where speed of agitator is 250/min
Clock sequentially adds mixture B, the improvement calcium carbonate, biological modification mushroom of step 3 preparation, is 450r/min in speed of agitator
Under, it stirs 35 minutes, obtains mixture C；
The mixture C of step 4 preparation is sent into twin (double) screw extruder, point three sections of temperature controls, the charging of barrel temperature by step 5
Section control is at 50 DEG C, and at 60 DEG C, discharging section is controlled at 50 DEG C, screw speed 40r/min, rate of feeding 35r/ for interlude control
Min obtains the dedicated improver of water quality in granular fish pond.
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| CN110642391A (en) * | 2019-10-15 | 2020-01-03 | 汤怀信 | Water treatment agent for pond |
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