CN108914626A - 一种新型分散印花糊料 - Google Patents

一种新型分散印花糊料 Download PDF

Info

Publication number
CN108914626A
CN108914626A CN201810670168.1A CN201810670168A CN108914626A CN 108914626 A CN108914626 A CN 108914626A CN 201810670168 A CN201810670168 A CN 201810670168A CN 108914626 A CN108914626 A CN 108914626A
Authority
CN
China
Prior art keywords
parts
printing gum
crosslinked
starch
novel dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810670168.1A
Other languages
English (en)
Inventor
刘新国
庄辛娟
黄晓敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Tupu Refined Co Ltd
Original Assignee
Shandong Tupu Refined Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Tupu Refined Co Ltd filed Critical Shandong Tupu Refined Co Ltd
Publication of CN108914626A publication Critical patent/CN108914626A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D06P1/50—Derivatives of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67366—Phosphates or polyphosphates

Abstract

本发明公开了一种新型分散印花糊料，各组分按重量份为：羧甲基纤维素钠20‑30份、无水硫酸钠5‑35份、醚化交联淀粉50‑70份、无水乙醇5‑15份、六偏磷酸钠1‑3份、过氧化氢0.5‑1份。本发明所制得的印花糊料，得色量高，渗透性好，分散性能好，能使染料均匀的分散并固定在织物上而不渗化，使得印染花纹轮廓清晰，色泽鲜艳，色牢度高。

Description

一种新型分散印花糊料
技术领域
本发明涉及一种新型分散印花糊料，属于印染化工领域。
背景技术
印花糊料是指在色浆中能起增稠作用的高分子化合物，能溶解于水中形成具有一定粘度的胶体溶液。印花糊料是印花色浆的主组分，它决定着印花运转性能，染料的表面给色量、花纹轮廓的光洁度等。
在本领域现有技术中，普通分散染料存在固色率低、染色牢度差，有粘色严重、高效皂洗、工艺流程长等问题，为解决以上技术问题，本发明提供一种脱糊性能好，具有良好的化学稳定性，印染花纹轮廓清晰，色泽鲜艳，色泽鲜艳的新型分散印花糊料，以解决上述技术问题的不足。
发明内容
本发明的目的是针对上述现有技术中的缺陷，提供了一种粘度适中的分散印花糊料。
本发明通过以下技术方案来具体实施：
一种新型分散印花糊料，各组分由以下按重量份原材料制成：羧甲基纤维素钠20-30份、无水硫酸钠5-35份、醚化交联淀粉50-70份、无水乙醇5-15份、六偏磷酸钠1-3份、过氧化氢 0.5-1份。
上述新型分散印花糊料，根据本发明各组分按重量份优选为：羧甲基纤维素钠30份、无水硫酸钠35份、醚化交联淀粉70份、无水乙醇15份、六偏磷酸钠 3份、过氧化氢 1份。
或者：羧甲基纤维素钠20份、无水硫酸钠30份、醚化交联淀粉60份、无水乙醇10份、六偏磷酸钠 2份、过氧化氢 0.5份。
或者
羧甲基纤维素钠25份、无水硫酸钠25份、醚化交联淀粉50份、无水乙醇5份、六偏磷酸钠1份、过氧化氢 0.5份。
本发明的有益效果：
(1) 本发明使用的醚化交联淀粉，可溶水，溶于一些与水混融的溶剂，如乙醇，是良好的增稠剂，在冷水中易化开，在热水或冷水中能分散形成粘稠液。交联化学键的强度远高于氢键,增强颗粒结构的强度,抑制颗粒膨胀、破裂和粘度下降。随交联程度增加,淀粉分子间交联化学键数量增加。约100个AGU(脱水葡萄糖单元),有一个交联键时,则交联完全抑制颗粒在沸水中膨胀,不糊化。 交联淀粉的许多性能优于普通淀粉,首先交联淀粉提高了糊化温度和粘度,抗剪切力比淀粉糊稳定程度有很大提高，淀粉糊粘度受剪切力影响降低很多,而经低度交联便能提高稳定性,交联淀粉的抗酸、碱的稳定性也大大优于淀粉。醚化交联淀粉原料为芋头淀粉，来源广，价格低，相容性稳定性高，渗透性好，能显著提高印花鲜艳度。醚化交联淀粉对比低粘度醚化淀粉（低粘度羟烷基醚化淀粉或低粘度羧甲基醚化淀粉），具有稳定性高，渗透性好，能显著提高印花鲜艳度的作用，经实践证明，醚化交联淀粉性能优于低粘度醚化淀粉（低粘度羟烷基醚化淀粉或低粘度羧甲基醚化淀粉）。其糊化温度和粘度,抗剪切力优于酸化、酶化、酯化、预糊化淀粉和低粘度醚化淀粉。
(2) 能激活染料中的活性集团、着色率高的无水硫酸钠；
(3) 能使染料均匀的分散并固定在织物上而不渗化，使得印染花纹轮
廓清晰，色泽鲜艳，色泽鲜艳。
具体实施方式
实施例1：
一种新型分散印花糊料，由以下按重量份原材料制成：：羧甲基纤维素钠30份、无水硫酸钠35份、醚化交联淀粉70份、无水乙醇15份、六偏磷酸钠 3份、过氧化氢 1份。
经检测，本发明制备的印花糊料渗透率达到38％以上，印花粘度指数为0.579，成糊率达到10.2％，脱糊率为94％。
实施例2：
一种新型分散印花糊料，由以下按重量份原材料制成：：羧甲基纤维素钠20份、无水硫酸钠30份、醚化交联淀粉60份、无水乙醇10份、六偏磷酸钠 2份、过氧化氢 0.5份。
经检测，本发明制备的印花糊料渗透率达到37％，印花粘度指数为0.553，成糊率达到12.2％，脱糊率为96％。
实施例3：
一种新型分散印花糊料，由以下按重量份原材料制成：羧甲基纤维素钠25份、无水硫酸钠25份、醚化交联淀粉50份、无水乙醇5份、六偏磷酸钠1份、过氧化氢 0.5份。
经检测，本发明制备的印花糊料渗透率达到37％以上，印花粘度指数为0.579，成糊率达到10.1％，脱糊率为90％。
上述说明并非对本发明实例的限制，本发明也不仅限于上述举例，本技术领域的技术人员在本发明的实质范围内所做出的变化、改型、添加或替换，也属于本发明保护的范围。
对比试验：
本发明在各组份的重量份的对比试验中，应用磷酸酯淀粉代替醚化交联淀粉来对比技术效果。
对比实验的对照组由以下按重量份原材料制成：
羧甲基纤维素钠20份、无水硫酸钠30份、磷酸酯淀粉60份、无水乙醇10份、六偏磷酸钠2份、过氧化氢 0.5份来对比技术效果。
经检测，用此重量份的制备的印花糊料渗透率达不到37％，印花粘度指数为0.49，成糊率达到9.1％，脱糊率为86％，明显低于实施例1-3的技术水平。

Claims (3)

1.一种新型分散印花糊料，其特征在于：所述新型分散印花糊料由以下重量份原材料制成：羧甲基纤维素钠20-30份、无水硫酸钠5-35份、醚化交联淀粉50-70份、无水乙醇5-15份、六偏磷酸钠1-3份、过氧化氢 0.5-1份。
2.根据权利要求1所述的新型分散印花糊料，其特征在于：所述新型分散印花糊料由以下重量份原材料制成：羧甲基纤维素钠30份、无水硫酸钠35份、醚化交联淀粉70份、无水乙醇15份、六偏磷酸钠 3份、过氧化氢 1份。
3.根据权利要求1所述的新型分散印花糊料，其特征在于：所述新型分散印花糊料由以下重量份原材料制成：羧甲基纤维素钠20份、无水硫酸钠30份、醚化交联淀粉60份、无水乙醇10份、六偏磷酸钠 2份、过氧化氢 0.5份。
CN201810670168.1A 2018-06-08 2018-06-26 一种新型分散印花糊料 Pending CN108914626A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201810586311 2018-06-08
CN2018105863119 2018-06-08

Publications (1)

Publication Number Publication Date
CN108914626A true CN108914626A (zh) 2018-11-30

Family

ID=64421337

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810670168.1A Pending CN108914626A (zh) 2018-06-08 2018-06-26 一种新型分散印花糊料

Country Status (1)

Country Link
CN (1) CN108914626A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108951217A (zh) * 2018-06-07 2018-12-07 山东港源海洋生物工程有限公司 一种海藻酸钠印花糊料及其制备工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1563558A (zh) * 2004-03-15 2005-01-12 江南大学 一种粘度可调的复配变性淀粉印花糊料的制备方法和应用
CN102154851A (zh) * 2011-06-03 2011-08-17 江西博大化工有限公司 一种磷酸酯淀粉印花糊料及其制备方法
CN103410019A (zh) * 2013-07-23 2013-11-27 甘肃圣大方舟马铃薯变性淀粉有限公司 复合印花糊料的制备方法
CN105777917A (zh) * 2016-04-05 2016-07-20 杭州弘博新材料有限公司 一种活性染料印花用羧甲基淀粉的制备
CN107142750A (zh) * 2017-05-18 2017-09-08 杭州弘博新材料有限公司 一种分散染料印花用复合糊料的制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1563558A (zh) * 2004-03-15 2005-01-12 江南大学 一种粘度可调的复配变性淀粉印花糊料的制备方法和应用
CN102154851A (zh) * 2011-06-03 2011-08-17 江西博大化工有限公司 一种磷酸酯淀粉印花糊料及其制备方法
CN103410019A (zh) * 2013-07-23 2013-11-27 甘肃圣大方舟马铃薯变性淀粉有限公司 复合印花糊料的制备方法
CN105777917A (zh) * 2016-04-05 2016-07-20 杭州弘博新材料有限公司 一种活性染料印花用羧甲基淀粉的制备
CN107142750A (zh) * 2017-05-18 2017-09-08 杭州弘博新材料有限公司 一种分散染料印花用复合糊料的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈英华等: "《纺织品印花工艺制订与实施》", 31 January 2015, 东华大学出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108951217A (zh) * 2018-06-07 2018-12-07 山东港源海洋生物工程有限公司 一种海藻酸钠印花糊料及其制备工艺

Similar Documents

Publication Publication Date Title
CN101408003B (zh) 一种环保型涂料拔染印花拔染浆及其拔染印花工艺
CN103911885A (zh) 一种印染糊料
CN104710841B (zh) 一种红色活性染料组合物
CN104499299B (zh) 一种用于绒面型超细纤维合成革的表面处理固色法
CN103924457B (zh) 一种印染糊料的生产工艺
WO2021196736A1 (zh) 耐沸水煮水性玻璃涂覆料及其制备方法
CN108049207A (zh) 复合活性印花糊料
CN108468233A (zh) 一种活性染料的高效快速汽蒸印花工艺
CN107142750A (zh) 一种分散染料印花用复合糊料的制备方法
CN105484067A (zh) 一种新型分散印花增稠剂及其制备方法
CN108914626A (zh) 一种新型分散印花糊料
CN103509370B (zh) 一种活性绿色染料
WO2005080668A2 (en) Thickener for textile printing paste
CN105218686A (zh) 一种新型活性染料印花用增稠剂的制备方法
CN103924456B (zh) 一种活性印花糊料的生产工艺
CN104497154A (zh) 一种羟丁基淀粉醚或羟丁基变性淀粉醚的制备方法
US4826504A (en) Calcium/sodium aliginate dye printing paste
CN103938469A (zh) 一种亚麻织物活性印染糊料的制备方法
CN103711014A (zh) 一种棉织物染料冷转移印花方法
CN103911881A (zh) 一种适用于棉麻织物的印花糊料
JP2629067B2 (ja) モノアゾレーキ顔料および印刷インキ組成物
JPS59230073A (ja) ヒドロキシアルキル−カルボキシメチル化タマリンド糊剤
CN104650620A (zh) 一种艳蓝色活性染料混合物及其应用
CN108914638A (zh) 印花糊料
US1977250A (en) Vat dyestuff paste

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181130