CN108913234A - A kind of low-carbon environment-friendly fuel and preparation method thereof based on diesel oil - Google Patents
A kind of low-carbon environment-friendly fuel and preparation method thereof based on diesel oil Download PDFInfo
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- CN108913234A CN108913234A CN201810971426.XA CN201810971426A CN108913234A CN 108913234 A CN108913234 A CN 108913234A CN 201810971426 A CN201810971426 A CN 201810971426A CN 108913234 A CN108913234 A CN 108913234A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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Abstract
The invention discloses a kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：12-32 parts of methanol, 2-6 parts of isobutanol, 1-6 parts of oleic acid .5-4 parts of hydrogen peroxidase 10,0.5-6 parts of n-butanol, 0.3-1.5 parts of potassium permanganate and suitable diesel oil and ferrocene.The invention also discloses the preparation methods of the low-carbon environment-friendly fuel.Low-carbon environment-friendly fuel prepared by the present invention has excellent combustibility, it is prepared by being made to be added in diesel oil after denatured methyl alcohol for raw material with methanol, ferrocene, isobutanol, n-butanol, oleic acid, hydrogen peroxide, potassium permanganate etc., alcohol oil layer existing for methanol diesel-oil can be fully solved and day is cold-started undesirable problem, derv fuel cost can be reduced again, the black smoke in CO and hydrocarbons content and elimination exhaust emissions when significantly reducing vehicle burning diesel oil in exhaust emissions, has a vast market foreground.
Description
Technical field
The present invention relates to technical field of fuel, specifically a kind of low-carbon environment-friendly fuel and its preparation side based on diesel oil
Method.
Background technique
Diesel oil is a kind of oils, it is complicated hydro carbons（Carbon atom number about 10-22）Mixture, in vehicle, ship
Have in the diesel engine of oceangoing ship etc. and is widely applied.As the disposable energy such as petroleum is increasingly in short supply, environmental pollution is increasingly serious
Overall background under, low carbon diesel fuel, can be effective as a kind of at low cost, more thorough vehicle fuel alternative energy source product of burning
China's oil import is reduced, improves city environmental quality, reduce fuel cost and create employment opportunities.
Low carbon diesel fuel in order to obtain, mixing in diesel oil and burning methanol is one of effective means.Pass through currently on the market
Mix burn methanol prepare methanol diesel-oil method it is very much, but their typically costs are higher, moreover, when modulating methanol diesel-oil, due to
Methanol ratio be more than diesel oil weight 5-10% after just will appear alcohol oil layer and day is cold-started bad phenomenon, cause
Modulation cost greatly increases when weather cold modulates methanol diesel-oil, seriously limits its scope of application.
Summary of the invention
It is a kind of based on diesel oil the object of the invention is to provide to solve above-mentioned problems of the prior art
Low-carbon environment-friendly fuel and preparation method thereof, by with methanol, ferrocene, isobutanol, n-butanol, oleic acid, hydrogen peroxide, Gao Meng
Sour potassium etc. is that heated be made after denatured methyl alcohol of raw material is added in diesel oil the system of being stirred under normal temperature and pressure conditions
At low-carbon environment-friendly fuel of the invention, methanol, which mixes burning amount, can achieve the 15-30% of diesel oil weight, and alcohol oil will not be layered,
Using not influencing normally to start under arctic weather, solves alcohol oil layer existing for methanol diesel-oil and day cold start-up is undesirable
Problem, and derv fuel cost can be reduced, discharge amount of exhaust gas is well below national standard in combustion process.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：12-32 parts of methanol, isobutanol
2-6 parts, 1-6 parts of oleic acid .5-4 parts of hydrogen peroxidase 10,0.5-6 parts of n-butanol, 0.3-1.5 parts of potassium permanganate and suitable bavin
Oil and ferrocene.
Further, the low-carbon environment-friendly fuel based on diesel oil includes the following raw material according to parts by weight：Methanol 15-
30 parts, 3-5 parts of isobutanol, 2-5 parts of oleic acid, 1-3 parts of hydrogen peroxide, 1-5 parts of n-butanol, 0.5-1 parts of potassium permanganate, and it is appropriate
Diesel oil and ferrocene.
Further, the low-carbon environment-friendly fuel based on diesel oil includes the following raw material according to parts by weight：Methanol 20
Part, 4 parts of isobutanol, 3 parts of oleic acid, 2 parts of hydrogen peroxide, 3 parts of n-butanol, 0.7 part of potassium permanganate and suitable diesel oil and two cyclopentadienyls
Iron.
Further, the methanol is the industrial methanol for meeting GB338-2004.
Further, the diesel oil is No. 0 diesel oil of national standard.
A kind of preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically include following steps：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, 0.00006- is then added
The ferrocene of 0.00009% times of methanol weight is stirred, and obtains mixture A；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 60 DEG C -80 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oil
The mutual cooperation of acid, hydrogen peroxide and potassium permanganate, effectively increases the modified effect to methanol, the denatured methyl alcohol B of preparation can
It is added under normal temperature and pressure conditions and carries out preparing low carbon diesel fuel into diesel oil, while methanol mixes burning amount can achieve diesel oil weight
The 15-30% of amount, and alcohol oil will not be layered, and using under arctic weather does not influence normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get.
Further, step 1）In, the stirring is to be stirred 10min with the stirring rate of 50r/min.
Further, step 3）In, the additional amount of the denatured methyl alcohol B is the 15-30% of diesel oil weight.
The low-carbon environment-friendly fuel based on diesel oil is preparing the purposes in low-carbon fuel product.
Ferrocene, also known as bicyclopentadiene close iron, cyclopentadienyl group iron, are a kind of organic transitionals with aromatic nature
Metallic compound, fusing point are 172 degree of -174 degree, are soluble in the organic solvents such as benzene, ether, gasoline, diesel oil.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
1）Low-carbon environment-friendly fuel prepared by the present invention based on diesel oil has excellent combustibility, changes traditional in bavin
Direct blending combustion methanol prepares low carbon diesel fuel in oil, but by with methanol, ferrocene, isobutanol, n-butanol, oleic acid, mistake
Hydrogen oxide, potassium permanganate etc. be raw material it is heated be made after denatured methyl alcohol to be added in diesel oil under normal temperature and pressure conditions made
It is standby, can be fully solved alcohol oil layer existing for methanol diesel-oil and day be cold-started undesirable problem and reduce derv fuel at
This, it is black in the CO and hydrocarbons content and elimination exhaust emissions when significantly reducing vehicle burning diesel oil in exhaust emissions
Cigarette has a vast market foreground；
2）Low-carbon environment-friendly fuel prepared by the present invention based on diesel oil can be used completely with diesel oil substitute, easy to use, fired
Discharge amount of exhaust gas can be effectively reduced condensation point of diesel oil by the way that denatured methyl alcohol is added, make bavin well below national standard during burning
Oil firing is more abundant, does not have black smoke in exhaust emissions, and the pollution to atmosphere is greatly lowered, while can be reduced and provide to natural oil
The consumption in source, while cost is more at low cost than diesel oil, is a kind of energy-saving and environment-friendly alternative energy source product；
3）The present invention can be modulated low carbon diesel fuel under normal temperature and pressure conditions, and methanol, which mixes burning amount, can achieve diesel oil weight
The 15 ~ 30% of amount, and alcohol oil will not be layered, and using under arctic weather does not influence normally to start, not black in exhaust emissions
Cigarette, and in weather cold, modulation cost will not increase；
4）Raw material of the invention is the industrial chemicals being easy to get, and reduces fuel cost, while reducing and providing to natural oil
The consumption in source can reduce petroleum import, and pollution is greatly reduced, and improve urban environment, have important social benefit and warp
Ji benefit.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.The present embodiment is based on the technical solution of the present invention
Implemented, the detailed implementation method and specific operation process are given, but protection scope of the present invention be not limited to it is following
Embodiment.
Embodiment 1
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：12 parts of methanol, 2 parts of isobutanol,
1 part of oleic acid .5 parts of hydrogen peroxidase 10,0.5 part of n-butanol, 0.3 part of potassium permanganate and suitable diesel oil and ferrocene；Wherein,
The methanol is the industrial methanol for meeting GB338-2004；The diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.00006% times
The ferrocene of methanol weight is stirred, and obtains mixture A；The stirring is to be stirred with the stirring rate of 50r/min
10min；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 60 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, and alcohol oil will not be layered, and be made under arctic weather
With not influencing normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 15% of diesel oil weight.
Embodiment 2
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：32 parts of methanol, 6 parts of isobutanol,
6 parts of oleic acid, 4 parts of hydrogen peroxide, 6 parts of n-butanol, 1.5 parts of potassium permanganate and suitable diesel oil and ferrocene；Wherein, described
Methanol is the industrial methanol for meeting GB338-2004；The diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.00009% times
The ferrocene of methanol weight is stirred, and obtains mixture A；The stirring is to be stirred with the stirring rate of 50r/min
10min；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 80 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, and alcohol oil will not be layered, and be made under arctic weather
With not influencing normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 30% of diesel oil weight.
Embodiment 3
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：22 parts of methanol, 4 parts of isobutanol,
3.5 parts of oleic acid, 2.25 parts of hydrogen peroxide, 3.25 parts of n-butanol, 0.9 part of potassium permanganate and suitable diesel oil and ferrocene；Its
In, the diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.000075% times
The ferrocene of methanol weight is stirred, and obtains mixture A；The stirring is to be stirred with the stirring rate of 50r/min
10min；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 70 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, while methanol mixes burning amount can achieve diesel oil weight
15-30%, and alcohol oil will not be layered, and using under arctic weather does not influence normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 22.5% of diesel oil weight.
In the present embodiment, by being modulated low carbon diesel fuel under normal temperature and pressure conditions, methanol is mixed burning amount and can be reached
To the 15-30% of diesel oil weight, and alcohol oil will not be layered, and using under arctic weather does not influence normally to start, exhaust emissions
In there is no black smoke, and in weather cold modulate cost will not increase, can be used completely with diesel oil substitute, it can be reduced
Condensation point of diesel oil keeps diesel combustion more abundant, does not have black smoke in exhaust emissions, the pollution to atmosphere is greatly lowered, while can subtract
Few consumption to natural oil resource, and the product cost is more at low cost than diesel oil, is a kind of with great social benefit and economy
The low-carbon energy-saving environment-friendly type alternative energy source product of benefit.
Embodiment 4
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：15 parts of methanol, 3 parts of isobutanol,
2 parts of oleic acid, 1 part of hydrogen peroxide, 1 part of n-butanol, 0.5 part of potassium permanganate and suitable diesel oil and ferrocene；Wherein, described
Methanol is the industrial methanol for meeting GB338-2004；The diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.00006% times
The ferrocene of methanol weight is stirred, and obtains mixture A；The stirring is to be stirred with the stirring rate of 50r/min
10min；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 60 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, and alcohol oil will not be layered, and be made under arctic weather
With not influencing normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 15% of diesel oil weight.
Embodiment 5
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：30 parts of methanol, 5 parts of isobutanol,
5 parts of oleic acid, 3 parts of hydrogen peroxide, 5 parts of n-butanol, 1 part of potassium permanganate and suitable diesel oil and ferrocene；Wherein, the first
Alcohol is the industrial methanol for meeting GB338-2004；The diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.00009% times
The ferrocene of methanol weight is stirred, and obtains mixture A；The stirring is to be stirred with the stirring rate of 50r/min
10min；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 80 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, and alcohol oil will not be layered, and be made under arctic weather
With not influencing normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 30% of diesel oil weight.
Embodiment 6
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：22.5 parts of methanol, isobutanol 4
Part, 3.5 parts of oleic acid, 2 parts of hydrogen peroxide, 3 parts of n-butanol, 0.75 part of potassium permanganate and suitable diesel oil and ferrocene；Its
In, the methanol is the industrial methanol for meeting GB338-2004；The diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.000075% times
The ferrocene of methanol weight is stirred, and obtains mixture A；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 70 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, while methanol mixes burning amount can achieve diesel oil weight
15-30%, and alcohol oil will not be layered, and using under arctic weather does not influence normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 22.5% of diesel oil weight.
Embodiment 7
A kind of low-carbon environment-friendly fuel based on diesel oil, including below according to the raw material of parts by weight：20 parts of methanol, 4 parts of isobutanol,
3 parts of oleic acid, 2 parts of hydrogen peroxide, 3 parts of n-butanol, 0.7 part of potassium permanganate and suitable diesel oil and ferrocene；Wherein, described
Methanol is the industrial methanol for meeting GB338-2004；The diesel oil is No. 0 diesel oil of national standard.
In the present embodiment, the preparation method of the low-carbon environment-friendly fuel based on diesel oil, this method specifically includes following
Step：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, be then added 0.000075% times
The ferrocene of methanol weight is stirred, and obtains mixture A；The stirring is to be stirred with the stirring rate of 50r/min
10min；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 70 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；Pass through oleic acid, mistake
The mutual cooperation of hydrogen oxide and potassium permanganate effectively increases the modified effect to methanol, and the denatured methyl alcohol B of preparation can be in room temperature
It is added under condition of normal pressure and carries out preparing low carbon diesel fuel into diesel oil, and alcohol oil will not be layered, and be made under arctic weather
With not influencing normally to start；
3）Under normal temperature and pressure conditions, it weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, it is mixed through being sufficiently stirred
Close uniformly to get；Wherein, the additional amount of the denatured methyl alcohol B is the 22.5% of diesel oil weight.
In the present embodiment, by being modulated low carbon diesel fuel under normal temperature and pressure conditions, methanol is mixed burning amount and can be reached
To the 15-30% of diesel oil weight, and alcohol oil will not be layered, and using under arctic weather does not influence normally to start, exhaust emissions
In there is no black smoke, and in weather cold modulate cost will not increase, can be used completely with diesel oil substitute, it can be reduced
Condensation point of diesel oil keeps diesel combustion more abundant, does not have black smoke in exhaust emissions, the pollution to atmosphere is greatly lowered, while can subtract
Few consumption to natural oil resource, and the product cost is more at low cost than diesel oil, is a kind of with great social benefit and economy
The low-carbon energy-saving environment-friendly type alternative energy source product of benefit；
The low-carbon environment-friendly fuel based on diesel oil can be fully solved alcohol oil layer existing for methanol diesel-oil and day cold start-up
Undesirable problem, and derv fuel cost can be reduced, CO and hydrocarbonization when significantly reducing vehicle burning diesel oil in exhaust emissions
It closes object content and eliminates the black smoke in exhaust emissions, discharge amount of exhaust gas is well below national standard in combustion；
The primary raw material of the low-carbon environment-friendly fuel based on diesel oil is the common industrial chemicals easily obtained, is being used
Thoroughly solve alcohol oil layer and the undesirable technical problem of low-temperature cool starting in journey, in short, the low-carbon environment-friendly based on diesel oil
Type fuel has six big features：（1）Pollution can be greatly reduced, improve urban environment；（2）Condensation point of diesel oil can be reduced；（3）Drop
Low fuel cost；（4）The consumption to natural oil resource is reduced, petroleum import is reduced, there is important social benefit and warp
Ji benefit；（5）It is easy to use；（6）Create job opportunity.
Present invention has the advantages that the low-carbon environment-friendly fuel prepared by the present invention based on diesel oil has excellent flammability
Can, it changes traditional direct blending combustion methanol in diesel oil and prepares low carbon diesel fuel, but by with methanol, ferrocene, different
Butanol, n-butanol, oleic acid, hydrogen peroxide, potassium permanganate etc., which are that raw material is heated, to be made after denatured methyl alcohol in normal temperature and pressure conditions
Under be added in diesel oil and prepared, alcohol oil layer existing for methanol diesel-oil can be fully solved and day is cold-started undesirable difficulty
Topic, and derv fuel cost can be reduced, CO and hydrocarbons content when significantly reducing vehicle burning diesel oil in exhaust emissions
Black smoke in elimination exhaust emissions, has a vast market foreground；Meanwhile the low-carbon environment-friendly prepared by the present invention based on diesel oil
Type fuel can be used completely with diesel oil substitute, easy to use, and discharge amount of exhaust gas leads to well below national standard in combustion
Crossing addition denatured methyl alcohol can be effectively reduced condensation point of diesel oil, keep diesel combustion more abundant, not have black smoke in exhaust emissions, significantly
Reduce pollution to atmosphere, while can be reduced the consumption to natural oil resource, while cost is more at low cost than diesel oil, be it is a kind of both
The alternative energy source product of energy conservation and environmental protection；Moreover, the present invention can be modulated low carbon diesel fuel under normal temperature and pressure conditions,
Methanol, which mixes burning amount, can achieve the 15-30% of diesel oil weight, and alcohol oil will not be layered, and using under arctic weather does not influence
It is normal to start, there is no black smoke in exhaust emissions, and modulate cost in weather cold to increase；Raw material of the invention is
The industrial chemicals being easy to get reduces fuel cost, while reducing the consumption to natural oil resource, can reduce petroleum into
Mouthful, pollution is greatly reduced, improves urban environment, there is important Social benefit and economic benefit, have a vast market
Prospect.
The above description of the embodiments is intended to facilitate ordinary skill in the art to understand and use the invention.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiments without having to go through creative labor.There is no need and unable to give all embodiments
With exhaustion.Therefore, the present invention is not limited to the above embodiments, and those skilled in the art's announcement according to the present invention does not depart from this hair
The improvement and modification that bright scope is made all should be within protection scope of the present invention.
Claims (9)
1. a kind of low-carbon environment-friendly fuel based on diesel oil, which is characterized in that including below according to the raw material of parts by weight：Methanol
12-32 parts, 2-6 parts of isobutanol, 1-6 parts of oleic acid .5-4 parts of hydrogen peroxidase 10,0.5-6 parts of n-butanol, potassium permanganate 0.3-1.5
Part and suitable diesel oil and ferrocene.
2. the low-carbon environment-friendly fuel according to claim 1 based on diesel oil, which is characterized in that including below according to weight
The raw material of part：15-30 parts of methanol, 3-5 parts of isobutanol, 2-5 parts of oleic acid, 1-3 parts of hydrogen peroxide, 1-5 parts of n-butanol, potassium permanganate
0.5-1 parts and suitable diesel oil and ferrocene.
3. the low-carbon environment-friendly fuel according to claim 2 based on diesel oil, which is characterized in that including below according to weight
The raw material of part：20 parts of methanol, 4 parts of isobutanol, 3 parts of oleic acid, 2 parts of hydrogen peroxide, 3 parts of n-butanol, 0.7 part of potassium permanganate, and
Suitable diesel oil and ferrocene.
4. the low-carbon environment-friendly fuel according to claim 2 based on diesel oil, which is characterized in that the methanol is to meet
The industrial methanol of GB338-2004.
5. the low-carbon environment-friendly fuel according to claim 1 based on diesel oil, which is characterized in that the diesel oil is national standard 0
Number diesel oil.
6. a kind of preparation method of the low-carbon environment-friendly fuel a method as claimed in any one of claims 1 to 5 based on diesel oil, feature exist
In this method specifically includes following steps：
1）Under conditions of normal temperature and pressure, methanol is weighed according to parts by weight and is added into reaction kettle, 0.00006- is then added
The ferrocene of 0.00009% times of methanol weight is stirred, and obtains mixture A；
2）N-butanol, isobutanol, oleic acid, hydrogen peroxide and potassium permanganate are weighed according to parts by weight, is added to step 1）In obtain
Mixture A in, 60 DEG C -80 DEG C are heated to after mixing and is sufficiently dissolved, room temperature is then down to, obtains denatured methyl alcohol B；
3）It weighs suitable diesel oil and step 2 is added）Obtained in denatured methyl alcohol B, be thoroughly mixed uniformly to get.
7. the preparation method of the low-carbon environment-friendly fuel according to claim 6 based on diesel oil, which is characterized in that step 1）
In, the stirring is to be stirred 10min with the stirring rate of 50r/min.
8. the preparation method of the low-carbon environment-friendly fuel according to claim 7 based on diesel oil, which is characterized in that step 3）
In, the additional amount of the denatured methyl alcohol B is the 15-30% of diesel oil weight.
9. a kind of low-carbon environment-friendly fuel a method as claimed in any one of claims 1 to 5 based on diesel oil is in preparing low-carbon fuel product
Purposes.
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| CN103642542A (en) * | 2013-12-25 | 2014-03-19 | 济南开发区星火科学技术研究院 | Methanol diesel oil |
| CN104447279A (en) * | 2014-12-05 | 2015-03-25 | 辽宁石油化工大学 | Method for synthesizing anchoic acid through combined oxidation of hydrogen peroxide and potassium permanganate |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101033419A (en) * | 2006-03-07 | 2007-09-12 | 北京福众金源环保科技有限公司 | Environmental protection methanol diesel oil |
| CN101368115A (en) * | 2008-10-10 | 2009-02-18 | 上海龙津石油有限公司 | Methanol diesel oil for automobile |
| CN103642542A (en) * | 2013-12-25 | 2014-03-19 | 济南开发区星火科学技术研究院 | Methanol diesel oil |
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Application publication date: 20181130 |