CN106753598B - A kind of low-carbon environment-friendly fuel and its preparation method and application - Google Patents

A kind of low-carbon environment-friendly fuel and its preparation method and application Download PDF

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Publication number
CN106753598B
CN106753598B CN201611100824.1A CN201611100824A CN106753598B CN 106753598 B CN106753598 B CN 106753598B CN 201611100824 A CN201611100824 A CN 201611100824A CN 106753598 B CN106753598 B CN 106753598B
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parts
fuel
low
tert
raw material
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CN106753598A (en
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不公告发明人
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Saide Energy Technology Henan Co ltd
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Shenzhen Southern Wealth Investment Management Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1266Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/1811Organic compounds containing oxygen peroxides; ozonides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2300/00Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20Mixture of two components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention discloses a kind of low-carbon environment-friendly fuel and its preparation method and application, which is made of the raw material below according to parts by weight: 42-50 parts of gutter oil, 15-23 parts of gallic acid, 1-5 parts of cerous nitrate, 20-30 parts of tert-butyl hydroperoxide, 3-7 parts of vanillic aldehyde.The present invention uses gutter oil for primary raw material; the fuel as made from dehydration after vanillic aldehyde, gallic acid, cerous nitrate processing again is first pre-processed to it using tert-butyl hydroperoxide improves low-carbon oil ignition performance; the Cetane number of fuel is greatly improved, greasy property is good, resists dry property and stability with good; clean and environmental protection energy conservation; non-corrosive, no mechanical wear, exhaust emissions reaches national emission standard; not only environment is protected, but also alleviates the anxiety of petroleum resources.Raw material abundance of the present invention is at low cost, and simple production process reduces production cost, improves the environment friendly of fuel, can be widely used in fields such as boiler, vehicles.

Description

A kind of low-carbon environment-friendly fuel and its preparation method and application
Technical field
The present invention relates to fuel technology field, specifically a kind of low-carbon environment-friendly fuel and its preparation method and application.
Background technique
With the development and progress of society, the global reserves amount of this non-renewable resources of petroleum is also increasingly being reduced, stone The price of oil product is constantly soaring, all brings serious financial burden to people's lives and communications and transportation.Traditional stone Change class A fuel A in burning, particulate matter, nitrogen oxides and hydrocarbonization since itself feature leads to incomplete combustion, in tail gas It is very high to close object content, serious harm is caused to environment, global warming, ozone hole, the environmental problems such as acid rain are gradually people Class is paid attention to.In order to reduce environmental pollution, alleviates the anxiety of petroleum resources, mitigate the financial burden of business and consumer, research and develop Low-carbon new energy is extremely urgent.Gutter oil is a kind of food and drink Residual oil, is the rubbish to trickle in city sewer, and people talk oil colours and become It is because it causes seriously to pollute to environment, or even is refined into edible oil by illegal retailer's collection, processing and is entered catering market.For It changes the status quo, how people to turn waste into wealth gutter oil if beginning one's study.
Summary of the invention
The purpose of the present invention is to provide a kind of low-carbon environment-friendly fuel and its preparation method and application, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of low-carbon environment-friendly fuel, is made of the raw material below according to parts by weight: 42-50 parts of gutter oil, gallic acid 15- 23 parts, 1-5 parts of cerous nitrate, 20-30 parts of tert-butyl hydroperoxide, 3-7 parts of vanillic aldehyde.
As a further solution of the present invention: the low-carbon environment-friendly fuel is made of: ground the raw material below according to parts by weight 44-48 parts of ditch oil, 17-21 parts of gallic acid, 2-4 parts of cerous nitrate, 22-28 parts of tert-butyl hydroperoxide, 4-6 parts of vanillic aldehyde.
As a further solution of the present invention: the low-carbon environment-friendly fuel is made of: ground the raw material below according to parts by weight Ditch oil 46 parts, 19 parts of gallic acid, 3 parts of cerous nitrate, 25 parts of tert-butyl hydroperoxide, 5 parts of vanillic aldehyde.
Another object of the present invention is to provide a kind of preparation method of low-carbon environment-friendly pot furnace fuel, comprises the steps of:
1) gutter oil is mixed with tert-butyl hydroperoxide, handles 2.3h in 58 DEG C of at a temperature of heating stirring, then drops To 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.3-4.5h at such a temperature, then decolourizes, is dehydrated, mixture is made;
2) said mixture is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process at such a temperature 3.8h, then be dehydrated up to fuel.
Another object of the present invention is to provide application of the fuel in vehicle or boiler.
Compared with prior art, the beneficial effects of the present invention are:
The present invention uses gutter oil for primary raw material, is first pre-processed using tert-butyl hydroperoxide to it and passes through chinese cymbidium again Fuel obtained is dehydrated after element, gallic acid, cerous nitrate processing and improves low-carbon oil ignition performance, greatly improves the hexadecane of fuel Value, greasy property is good, and product is without side-effects to any system unit, and power is strong, and noise is small, resists dry property and stabilization with good Property, clean and environmental protection is energy saving, and long-time service does not generate carbon distribution, non-corrosive, no mechanical wear, and exhaust emissions reaches country's discharge mark Standard not only protects environment, but also alleviates the anxiety of petroleum resources.Raw material abundance of the present invention is at low cost, simple production process, reduces Production cost, uses fuel of the invention, it is possible to reduce internal combustion engine carbon monoxide, nitrogen oxides, hydrocarbons, visible granular Etc. harmful substances discharge, improve the environment friendly of fuel, can be widely used in fields such as boiler, vehicles.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of low-carbon environment-friendly fuel is made of: gutter oil 42 raw material below according to parts by weight Part, 15 parts of gallic acid, 1 part of cerous nitrate, 20 parts of tert-butyl hydroperoxide, 3 parts of vanillic aldehyde.
Gutter oil is mixed with tert-butyl hydroperoxide, 2.3h is handled in 58 DEG C of at a temperature of heating stirring, is then down to 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.3h at such a temperature, then decolourizes, is dehydrated, mixture is made.By above-mentioned mixing Object is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process 3.8h at such a temperature, then is dehydrated up to fuel.
Embodiment 2
In the embodiment of the present invention, a kind of low-carbon environment-friendly fuel is made of: gutter oil 50 raw material below according to parts by weight Part, 23 parts of gallic acid, 5 parts of cerous nitrate, 30 parts of tert-butyl hydroperoxide, 7 parts of vanillic aldehyde.
Gutter oil is mixed with tert-butyl hydroperoxide, 2.3h is handled in 58 DEG C of at a temperature of heating stirring, is then down to 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.5h at such a temperature, then decolourizes, is dehydrated, mixture is made.By above-mentioned mixing Object is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process 3.8h at such a temperature, then is dehydrated up to fuel.
Embodiment 3
In the embodiment of the present invention, a kind of low-carbon environment-friendly fuel is made of: gutter oil 44 raw material below according to parts by weight Part, 17 parts of gallic acid, 2 parts of cerous nitrate, 22 parts of tert-butyl hydroperoxide, 4 parts of vanillic aldehyde.
Gutter oil is mixed with tert-butyl hydroperoxide, 2.3h is handled in 58 DEG C of at a temperature of heating stirring, is then down to 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.4h at such a temperature, then decolourizes, is dehydrated, mixture is made.By above-mentioned mixing Object is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process 3.8h at such a temperature, then is dehydrated up to fuel.
Embodiment 4
In the embodiment of the present invention, a kind of low-carbon environment-friendly fuel is made of: gutter oil 48 raw material below according to parts by weight Part, 21 parts of gallic acid, 4 parts of cerous nitrate, 28 parts of tert-butyl hydroperoxide, 6 parts of vanillic aldehyde.
Gutter oil is mixed with tert-butyl hydroperoxide, 2.3h is handled in 58 DEG C of at a temperature of heating stirring, is then down to 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.4h at such a temperature, then decolourizes, is dehydrated, mixture is made.By above-mentioned mixing Object is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process 3.8h at such a temperature, then is dehydrated up to fuel.
Embodiment 5
In the embodiment of the present invention, a kind of low-carbon environment-friendly fuel is made of: gutter oil 46 raw material below according to parts by weight Part, 19 parts of gallic acid, 3 parts of cerous nitrate, 25 parts of tert-butyl hydroperoxide, 5 parts of vanillic aldehyde.
Gutter oil is mixed with tert-butyl hydroperoxide, 2.3h is handled in 58 DEG C of at a temperature of heating stirring, is then down to 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.4h at such a temperature, then decolourizes, is dehydrated, mixture is made.By above-mentioned mixing Object is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process 3.8h at such a temperature, then is dehydrated up to fuel.
Comparative example 1
In addition to without containing tert-butyl hydroperoxide, material content and preparation process and embodiment 5 are unanimously.
Comparative example 2
In addition to without containing gallic acid, material content and preparation process and embodiment 5 are unanimously.
Comparative example 3
In addition to without containing tert-butyl hydroperoxide and gallic acid, material content and preparation process and embodiment 5 one It causes.
Embodiment 6
According to relevant national standard, the basic performance of low-carbon oil of the present invention is detected, test result is as shown in table 1:
Table 1
The present invention deploys manufactured fuel under the interaction of each raw material, in addition to flash-point, remaining performance and national standard diesel oil It is very close.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (4)

1. a kind of low-carbon environment-friendly fuel, which is characterized in that be made of the raw material below according to parts by weight: 42-50 parts of gutter oil does not have 15-23 parts of gallate-based, 1-5 parts of cerous nitrate, 20-30 parts of tert-butyl hydroperoxide, 3-7 parts of vanillic aldehyde;
The preparation method of the low-carbon environment-friendly fuel, comprises the steps of:
1) gutter oil is mixed with tert-butyl hydroperoxide, handles 2.3h in 58 DEG C of at a temperature of heating stirring, is then down to 50 DEG C, vanillic aldehyde is added, and sealing stirring 4.3-4.5h at such a temperature, then decolourizes, is dehydrated, mixture is made;
2) said mixture is mixed with gallic acid, cerous nitrate, is warming up to 66 DEG C, and stir process 3.8h at such a temperature, It is dehydrated again up to fuel.
2. low-carbon environment-friendly fuel according to claim 1, which is characterized in that be made of the raw material below according to parts by weight: 44-48 parts of gutter oil, 17-21 parts of gallic acid, 2-4 parts of cerous nitrate, 22-28 parts of tert-butyl hydroperoxide, 4-6 parts of vanillic aldehyde.
3. low-carbon environment-friendly fuel according to claim 1, which is characterized in that be made of the raw material below according to parts by weight: 46 parts of gutter oil, 19 parts of gallic acid, 3 parts of cerous nitrate, 25 parts of tert-butyl hydroperoxide, 5 parts of vanillic aldehyde.
4. application of the fuel a method according to any one of claims 1-3 in vehicle or boiler.
CN201611100824.1A 2016-12-05 2016-12-05 A kind of low-carbon environment-friendly fuel and its preparation method and application Active CN106753598B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033413A (en) * 2007-04-03 2007-09-12 程汝林 Synthetic environmental protection oil
US20080096983A1 (en) * 2003-10-28 2008-04-24 Technol Fuel Conditioners, Inc. Heavy oil emulsion stabilizers containing saccharide based emulsion stabilizer
CN101768475A (en) * 2010-02-09 2010-07-07 上海舜天化工科技有限公司 High-cleanness environment-friendly liquid domestic fuel
CN102634384A (en) * 2012-04-17 2012-08-15 罗浩南 Novel vehicle alcohols environment-friendly fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080096983A1 (en) * 2003-10-28 2008-04-24 Technol Fuel Conditioners, Inc. Heavy oil emulsion stabilizers containing saccharide based emulsion stabilizer
CN101033413A (en) * 2007-04-03 2007-09-12 程汝林 Synthetic environmental protection oil
CN101768475A (en) * 2010-02-09 2010-07-07 上海舜天化工科技有限公司 High-cleanness environment-friendly liquid domestic fuel
CN102634384A (en) * 2012-04-17 2012-08-15 罗浩南 Novel vehicle alcohols environment-friendly fuel

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