CN108892884A - 耐腐蚀复合板材 - Google Patents

耐腐蚀复合板材 Download PDF

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CN108892884A
CN108892884A CN201810491550.6A CN201810491550A CN108892884A CN 108892884 A CN108892884 A CN 108892884A CN 201810491550 A CN201810491550 A CN 201810491550A CN 108892884 A CN108892884 A CN 108892884A
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agent
corrosion
composite plate
plate material
fire retardant
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张冬平
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Taizhou Sailing Petroleum Analysis Instrument Co Ltd
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Taizhou Sailing Petroleum Analysis Instrument Co Ltd
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Priority to CN201810491550.6A priority Critical patent/CN108892884A/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/286Chlorinated polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

本发明公开了一种耐腐蚀复合板材,包括聚氯乙烯、聚甲基丙烯酸甲酯‑聚丁二烯‑聚苯乙烯共聚物、氯化聚乙烯、稳定剂、加工改性剂、增塑剂、润滑剂、耐磨剂、耐腐蚀剂、阻燃剂、SiC纳米粉末、增强剂、紫外线吸收剂;其改进之处在于:耐磨剂为FIAT‑A,耐腐蚀剂为S‑5373,紫外线吸收剂为UV‑326;进一步改进在于:增强剂为纳米级CaCO3;阻燃剂为三氧化二锑。本发明具有较高耐腐蚀性、韧性、耐磨性。

Description

耐腐蚀复合板材
技术领域
本发明涉及一种高分子复合材料,特别是一种PVC复合板。
背景技术
PVC复合板材由于存在着耐磨性差、耐候性差等缺陷,使得PVC复合板材在室外应用方面受到限制,特别是如应用到室外运动场上,需要PVC复合板材具有较高的强度、耐磨性和耐腐蚀性,而现有技术的PVC复合板材在这方面存在着明显的不足。
发明内容
本发明针对现有技术的不足,提出一种具有较高耐腐蚀性、韧性、耐磨性的耐腐蚀复合板材。
本发明通过下述技术方案实现技术目标。
耐腐蚀复合板材,包括聚氯乙烯、聚甲基丙烯酸甲酯-聚丁二烯-聚苯乙烯共聚物、氯化聚乙烯、稳定剂、加工改性剂、增塑剂、润滑剂、耐磨剂、耐腐蚀剂、阻燃剂、SiC纳米粉末、增强剂、紫外线吸收剂;其改进之处在于:所述耐磨剂为FIAT-A,耐腐蚀剂为S-5373,紫外线吸收剂为UV-326。
进一步改进在于:所述增强剂为纳米级CaCO3
进一步改进在于:所述阻燃剂为三氧化二锑。
本发明与现有技术相比,具有以下积极效果:
1、加入聚甲基丙烯酸甲酯-聚丁二烯-聚苯乙烯共聚物、氯化聚乙烯,增加PVC复合板材的韧性。
2、加入UV-326紫外线吸收剂使PVC复合板材在自然光照下不会分解;
3、加入FIAT-A耐磨剂使得PVC复合板材的耐磨性显著提高。
4、加入S-5373耐腐蚀剂,有效防止自然界弱酸弱碱对PVC复合板材的腐蚀。
5、加入SiC纳米粉末,增强耐磨性和强度,PVC复合板材不易变形、开裂。
6、增强剂为纳米级CaCO3,显著提高结构强度。
7、加入三氧化二锑,显著提高阻燃性能。
具体实施方式
下面结合实施例对本发明作进一步说明。
耐腐蚀复合板材,包括聚氯乙烯、聚甲基丙烯酸甲酯-聚丁二烯-聚苯乙烯共聚物、氯化聚乙烯、稳定剂、加工改性剂、增塑剂、润滑剂、耐磨剂、耐腐蚀剂、阻燃剂、SiC纳米粉末、增强剂、紫外线吸收剂;耐磨剂为FIAT-A,耐腐蚀剂为S-5373,紫外线吸收剂为UV-326,增强剂为纳米级CaCO3,阻燃剂为三氧化二锑。

Claims (3)

1.一种耐腐蚀复合板材,包括聚氯乙烯、聚甲基丙烯酸甲酯-聚丁二烯-聚苯乙烯共聚物、氯化聚乙烯、稳定剂、加工改性剂、增塑剂、润滑剂、耐磨剂、耐腐蚀剂、阻燃剂、SiC纳米粉末、增强剂、紫外线吸收剂;其特征在于:所述耐磨剂为FIAT-A,耐腐蚀剂为S-5373,紫外线吸收剂为UV-326。
2.根据权利要求1所述的耐腐蚀复合板材,其特征在于:所述增强剂为纳米级CaCO3
3.根据权利要求2所述的耐腐蚀复合板材,其特征在于:所述阻燃剂为三氧化二锑。
CN201810491550.6A 2018-05-22 2018-05-22 耐腐蚀复合板材 Pending CN108892884A (zh)

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Application publication date: 20181127