CN108887555A - A kind of degrading pesticide residue agent containing algal polysaccharides - Google Patents

A kind of degrading pesticide residue agent containing algal polysaccharides Download PDF

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Publication number
CN108887555A
CN108887555A CN201810648884.XA CN201810648884A CN108887555A CN 108887555 A CN108887555 A CN 108887555A CN 201810648884 A CN201810648884 A CN 201810648884A CN 108887555 A CN108887555 A CN 108887555A
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China
Prior art keywords
parts
algal polysaccharides
pesticide residue
chinese medicine
rare earth
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CN201810648884.XA
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Chinese (zh)
Inventor
李作前
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Zunyi Huizhou District Huizhou Ecological Agriculture Development Co Ltd
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Zunyi Huizhou District Huizhou Ecological Agriculture Development Co Ltd
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Priority to CN201810648884.XA priority Critical patent/CN108887555A/en
Publication of CN108887555A publication Critical patent/CN108887555A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/276Treatment with inorganic compounds

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The degrading pesticide residue agent containing algal polysaccharides that the invention discloses a kind of, is made of the raw material of following components:20-35 parts of complexes of alga polysaccharide with rare earth, 5-10 parts of Chinese medicine extract, 1-5 parts of nano zine oxide, 1-2 parts of nanometer titanium dioxide iron, 2-4 parts of potassium selenite, 30-50 parts of water.Degradating agent for residual agricultural chemicals provided by the invention, the pesticide residue for the crop surface that can both degrade can also reduce the pesticide infiltrated through inside crops, put into low and significant effect.

Description

A kind of degrading pesticide residue agent containing algal polysaccharides
Technical field
The invention belongs to daily-use chemical industry technical fields, and in particular to a kind of degrading pesticide residue agent containing algal polysaccharides.
Background technique
With the development of agricultural, the use of pesticide is following at essential link in agricultural development Environmental pollution, soil hardening, fertility decline, crops enhance pesticide resistance, or even cause serious injury etc. to people and animals A series of problems causes the great attention of people, for carrying out to Residue in fruits pesticide effective how after using pesticide Degradation, reducing pesticide is very necessary to the degradation of pesticide compound of the injury of people and animals.
Pesticide residue is referred to the pesticide parent remained in organism, agricultural product and environment due to pesticides application and its had Impurity, metabolite and the general name of reaction of toxicological significance.China is that world pesticide produces and use big country.A large amount of pesticide Residual will cause acute toxicity.Remains of pesticide can also be accumulated in human body, more than will lead to some diseases, such as painstaking effort after a certain amount of Pipe disease, diabetes, hepatopathy, cancer etc.;Pesticide can also be transmitted to the next generation by pregnant and lactation in the intracorporal accumulation of people, bring disaster to The health of descendants.Bread is the staff of life, eats with An Weixian.The same of the big industry of the first in the world is had evolved into food industry When, food safety also receives significant attention.Therefore, the pesticide residue for reducing agricultural product is trend of the times.Production currently on the market Product belong to types of detergents mostly, can not real degrading pesticide, and will cause the secondary pollution to water quality.
Summary of the invention
To solve above-mentioned the shortcomings of the prior art, the present invention provides a kind of degrading pesticide residue containing algal polysaccharides Agent, the pesticide residue for the crop surface that can both degrade can also reduce the pesticide infiltrated through inside crops, put into low and imitate Fruit is significant.
To achieve the goals above, the present invention provides the following technical solutions, a kind of remains of pesticide drop containing algal polysaccharides Agent is solved, is made of the raw material of following components:It is 20-35 parts of complexes of alga polysaccharide with rare earth, 5-10 parts of Chinese medicine extract, nano oxidized 1-5 parts of zinc, 1-2 parts of nanometer titanium dioxide iron, 2-4 parts of potassium selenite, 30-50 parts of water.
Further, the degradating agent for residual agricultural chemicals is made of the raw material of following components:Complexes of alga polysaccharide with rare earth 35 Part, 8 parts of Chinese medicine extract, 2.8 parts of nano zine oxide, 1.5 parts of nanometer titanium dioxide iron, 3 parts of potassium selenite, 48 parts of water.
Further, the Chinese medicine extract is that soapberry extract and Bi dial extracting solution and press 1:The ratio of 0.5-2 is prepared It forms.
Further, the Chinese medicine extract is made of following steps:By 1:The ratio of 0.5-2 takes soapberry and Bi to dial, 60~100 meshes are smashed it through, are mixed, by solid-liquid ratio 1:Dehydrated alcohol is added in 3~12g/ml, in 60~85 DEG C of refluxing extractions, Filtering, obtains Chinese medicine extract.
Further, the complexes of alga polysaccharide with rare earth is made of following steps:Algin, sweet dew are produced using kelp Waste after pure and mild iodine ingredient is made algal polysaccharides by acid, alkali process, then presses algal polysaccharides in conjunction with rare earth 0.03-0.1:Complexes of alga polysaccharide with rare earth is made in the ratio of 1-10.
Nano zine oxide has good photocatalysis performance, it can absorb luminous energy, and generating, there is the substance of strong oxidizing property to come Chemical bond in degrading pesticide.Persulfate can be sodium peroxydisulfate or potassium peroxydisulfate, be oxidizing species.In sodium selenite Selenium plant cell can be quickly entered in photosynthesis, the foreign substance removing function of cell is added, while accelerating the old of pesticide molecule chain Change and be broken, substantially reduces the pesticide residue in crops.
Soapberry, alias:Wood is suffered from sub (Compendium of Materia Medica), and oil is suffered from sub (Sichuan), and hardship suffers from tree (Hainan), yellow mesh tree, mesh wave tree (Taiwan), You Luoshu, fruit of washing one's hands, elsewhere name:Rub mesh, false longan, Devil Frown etc. with the hands.Soapberry deciduous tree, branch are opened Exhibition, leaf alternate;Without stipule;There is handle;Panicle, basidixed and side are raw;Flower polygamy, corolla light green have shortly clawed;Floral disc cup-shaped; Filigree has a fine, soft fur, medicine back it is raw, hermaphrodite flower stamen is small, and filigree has fur.Drupe is spherical, yellow or brown color when ripe.Seed Spherical shape, black, 6~July of florescence, 9~October of fruiting period.Various regions and South East Asia Mainland various regions, print on the south the Yangtze river basin originating in China Degree and Japan.Pericarp contains saponin, can do boxboard and wooden comb etc. for soap, timber.Root, browse, seed:Bitter, micro-pungent, It is cold;It is slightly poisonous.Heat-clearing eliminating the phlegm, disperse accumulation desinsection.For diphtheria, abscess of throat, acute tonsillitis, cough, pertussis, food stagnation malnutrition due to parasitic infestation;It is used for outside Trichomonas vaginalis.Kernel:It is pungent, it puts down, disperse accumulation wards off evil;For infantile malnutrition due to digestive disturbances or intestinalparasites, roundworm disease, inflatable in abdomen, halitosis.
Bi is dialled, and is the nearly mature or mature fruit cluster of drying also known as Bi Bo, fructus piperis longi, piper longum that Piperaceae plant Bi is dialled.Climb up by holding on to rattan This, is up to several meters;Branch has thick vertical rib and groove, and by superfine powdery pubescence when young, hair falls off quickly.Stem is carefully such as chopsticks, and leaf is seemingly Ji leaf, son are adopted August like mulberry fruit, and fruit ear is removed impurity, dried, can be used as medicine by harvesting when green blackening.Bi, which is dialled, special fragrance, Acrid flavour is peppery, therefore it is mainly used for cooking flavouring, there is the effect of flavoring flavouring, is chiefly used in the dish such as burning, roasting, braised, is also pot-stewed fowl One of fragrance.According to the saying of traditional chinese medicine, it is also a kind of Chinese medicine that Bi, which is dialled, and for the stomachic tonic that eases pain, acrid flavour heat is nontoxic, Clinically it is usually used in abdominal pain caused by stomach cold, vomiting, diarrhea, coronary heart diseases and angina pectoris, nervous headache and toothache etc..
In conclusion the present invention as the above scheme is adopted, has the advantages that:
1, each ingredient has obvious synergistic function in Chinese medicine extract contained by the present invention, can be substantially reduced pesticide residue Amount, spectrum of use is wide, has degradation to systemic pesticide.
2, the present invention can greatly reduce residual quantity of the pesticide in vegetables, and the time is longer, and degradation rate is higher.
Specific embodiment
Below with reference to embodiment, the present invention is described further.
Embodiment 1
A kind of degrading pesticide residue agent containing algal polysaccharides, is made of the raw material of following components:Complexes of alga polysaccharide with rare earth 35 parts, 8 parts of Chinese medicine extract, 2.8 parts of nano zine oxide, 1.5 parts of nanometer titanium dioxide iron, 3 parts of potassium selenite, 48 parts of water.
Wherein, Chinese medicine extract is that soapberry extract and Bi dial extracting solution and press 1:1.2 ratio is formulated;Chinese medicine mentions Liquid is taken to be made of following steps:By 1:1.2 ratio takes soapberry and Bi to dial, and smashes it through 60~100 meshes, mixes, by material Liquor ratio 1:Dehydrated alcohol is added in 3~12g/ml, and in 60~85 DEG C of refluxing extractions, filtering obtains Chinese medicine extract;
Complexes of alga polysaccharide with rare earth is made of following steps:It is useless after producing algin, mannitol and iodine ingredient using kelp Gurry is made algal polysaccharides by acid, alkali process, then algal polysaccharides is pressed to 0.06 in conjunction with rare earth:Seaweed is made in 5 ratio Polysaccharide rare earth compounding.
Embodiment 2
A kind of degrading pesticide residue agent containing algal polysaccharides, is made of the raw material of following components:Complexes of alga polysaccharide with rare earth 30 parts, 8 parts of Chinese medicine extract, 3 parts of nano zine oxide, 1 part of nanometer titanium dioxide iron, 3 parts of potassium selenite, 40 parts of water.
Wherein, Chinese medicine extract is that soapberry extract and Bi dial extracting solution and press 1:2 ratio is formulated;
Chinese medicine extract is made of following steps:By 1:2 ratio takes soapberry and Bi to dial, and smashes it through 60~100 meshes, mixes It closes, by solid-liquid ratio 1:Dehydrated alcohol is added in 3~12g/ml, and in 60~85 DEG C of refluxing extractions, filtering obtains Chinese medicine extract;
Complexes of alga polysaccharide with rare earth is made of following steps:It is useless after producing algin, mannitol and iodine ingredient using kelp Gurry is made algal polysaccharides by acid, alkali process, then algal polysaccharides is pressed to 0.08 in conjunction with rare earth:Sea is made in 10 ratio Polysaccharides rare earth compounding, complexes of alga polysaccharide with rare earth stoste solid content are 3%.
Embodiment 3
A kind of degrading pesticide residue agent containing algal polysaccharides, is made of the raw material of following components:Complexes of alga polysaccharide with rare earth 20 parts, 10 parts of Chinese medicine extract, 5 parts of nano zine oxide, 1 part of nanometer titanium dioxide iron, 2 parts of potassium selenite, 33 parts of water.
Wherein, Chinese medicine extract is that soapberry extract and Bi dial extracting solution and press 1:0.5 ratio is formulated;
Chinese medicine extract is made of following steps:By 1:0.5 ratio takes soapberry and Bi to dial, and smashes it through 60~100 meshes, Mixing, by solid-liquid ratio 1:Dehydrated alcohol is added in 3~12g/ml, and in 60~85 DEG C of refluxing extractions, filtering obtains Chinese medicine extract;
Complexes of alga polysaccharide with rare earth is made of following steps:It is useless after producing algin, mannitol and iodine ingredient using kelp Gurry is made algal polysaccharides by acid, alkali process, then algal polysaccharides is pressed to 0.03 in conjunction with rare earth:Seaweed is made in 1 ratio Polysaccharide rare earth compounding.
The foregoing is merely the preferred embodiments of invention, are not intended to limit the invention, all in spirit of the invention Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (5)

1. a kind of degrading pesticide residue agent containing algal polysaccharides, which is characterized in that the degradation agent by following components raw material Composition:20-35 parts of complexes of alga polysaccharide with rare earth, 5-10 parts of Chinese medicine extract, 1-5 parts of nano zine oxide, nanometer titanium dioxide iron 1-2 parts, 2-4 parts of potassium selenite, 30-50 parts of water.
2. a kind of degrading pesticide residue agent containing algal polysaccharides according to claim 1, which is characterized in that the pesticide Residue degrading agent is made of the raw material of following components:It is 35 parts of complexes of alga polysaccharide with rare earth, 8 parts of Chinese medicine extract, nano oxidized 2.8 parts of zinc, 1.5 parts of nanometer titanium dioxide iron, 3 parts of potassium selenite, 48 parts of water.
3. a kind of degrading pesticide residue agent containing algal polysaccharides according to claim 1, it is characterised in that:The Chinese medicine Extracting solution is that soapberry extract and Bi dial extracting solution and press 1:The ratio of 0.5-2 is formulated.
4. a kind of degrading pesticide residue agent containing algal polysaccharides according to claim 1, which is characterized in that the Chinese medicine Extracting solution is made of following steps:By 1:The ratio of 0.5-2 takes soapberry and Bi to dial, and smashes it through 60~100 meshes, mixes, By solid-liquid ratio 1:Dehydrated alcohol is added in 3~12g/ml, and in 60~85 DEG C of refluxing extractions, filtering obtains Chinese medicine extract.
5. a kind of degrading pesticide residue agent containing algal polysaccharides according to claim 1, which is characterized in that the seaweed Polysaccharide rare earth compounding is made of following steps:Waste after being produced algin, mannitol and iodine ingredient using kelp, is passed through Algal polysaccharides are made in acid, alkali process, then algal polysaccharides are pressed to 0.03-0.1 in conjunction with rare earth:It is more that seaweed is made in the ratio of 1-10 Sugared rare earth compounding.
CN201810648884.XA 2018-06-22 2018-06-22 A kind of degrading pesticide residue agent containing algal polysaccharides Pending CN108887555A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105455691A (en) * 2015-12-10 2016-04-06 北京弘宝源生物科技有限公司 Household intelligent device for degrading pesticide residue in vegetables and fruits
CN205337517U (en) * 2015-12-10 2016-06-29 北京弘宝源生物科技有限公司 Bathing pool device of degradation fruit vegetables remains of pesticide
CN106387612A (en) * 2016-08-26 2017-02-15 浙江奇异鸟生物科技有限公司 Method for removing pesticide residues
CN107821921A (en) * 2017-11-30 2018-03-23 孙铭岐 A kind of degrading pesticide residue agent
CN107874173A (en) * 2017-11-21 2018-04-06 荣成海锐芯生物科技有限公司 A kind of method that algal polysaccharides oral liquid is prepared using Enteromorpha

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105455691A (en) * 2015-12-10 2016-04-06 北京弘宝源生物科技有限公司 Household intelligent device for degrading pesticide residue in vegetables and fruits
CN205337517U (en) * 2015-12-10 2016-06-29 北京弘宝源生物科技有限公司 Bathing pool device of degradation fruit vegetables remains of pesticide
CN106387612A (en) * 2016-08-26 2017-02-15 浙江奇异鸟生物科技有限公司 Method for removing pesticide residues
CN107874173A (en) * 2017-11-21 2018-04-06 荣成海锐芯生物科技有限公司 A kind of method that algal polysaccharides oral liquid is prepared using Enteromorpha
CN107821921A (en) * 2017-11-30 2018-03-23 孙铭岐 A kind of degrading pesticide residue agent

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