CN108884299A - 固化性组合物、固化物的制造方法、及其固化物 - Google Patents
固化性组合物、固化物的制造方法、及其固化物 Download PDFInfo
- Publication number
- CN108884299A CN108884299A CN201780020027.9A CN201780020027A CN108884299A CN 108884299 A CN108884299 A CN 108884299A CN 201780020027 A CN201780020027 A CN 201780020027A CN 108884299 A CN108884299 A CN 108884299A
- Authority
- CN
- China
- Prior art keywords
- compound
- polymer
- group
- carbon atom
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 109
- 238000007711 solidification Methods 0.000 title claims abstract description 57
- 230000008023 solidification Effects 0.000 title claims abstract description 57
- 239000000463 material Substances 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- -1 oxetane compound Chemical class 0.000 claims abstract description 204
- 229920000642 polymer Polymers 0.000 claims abstract description 55
- 239000004615 ingredient Substances 0.000 claims abstract description 44
- 239000000178 monomer Substances 0.000 claims abstract description 41
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 39
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 18
- 239000003505 polymerization initiator Substances 0.000 claims abstract description 13
- 238000010538 cationic polymerization reaction Methods 0.000 claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 76
- 150000001721 carbon Chemical group 0.000 claims description 72
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 33
- 239000004593 Epoxy Substances 0.000 claims description 31
- 125000003118 aryl group Chemical group 0.000 claims description 26
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 22
- 125000002947 alkylene group Chemical group 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 11
- 125000002723 alicyclic group Chemical group 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 10
- 125000003566 oxetanyl group Chemical group 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 9
- 125000004104 aryloxy group Chemical group 0.000 claims description 5
- 238000001723 curing Methods 0.000 claims description 3
- 150000003254 radicals Chemical class 0.000 claims description 3
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 150000002924 oxiranes Chemical class 0.000 claims 1
- 230000009477 glass transition Effects 0.000 abstract description 7
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 abstract description 5
- 239000007870 radical polymerization initiator Substances 0.000 abstract description 5
- 150000002148 esters Chemical class 0.000 description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 21
- 239000002253 acid Substances 0.000 description 19
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
- 239000002904 solvent Substances 0.000 description 13
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N methyl pentane Natural products CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 150000002118 epoxides Chemical class 0.000 description 10
- 150000001450 anions Chemical class 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 8
- 230000006978 adaptation Effects 0.000 description 8
- 230000003287 optical effect Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 229910052731 fluorine Inorganic materials 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 229910000077 silane Inorganic materials 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
- 206010070834 Sensitisation Diseases 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229940052303 ethers for general anesthesia Drugs 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 230000008313 sensitization Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229960000834 vinyl ether Drugs 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 4
- 0 C*1C(*)/C=C/C(F)=C=CC1 Chemical compound C*1C(*)/C=C/C(F)=C=CC1 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 239000007767 bonding agent Substances 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 description 3
- FNYWFRSQRHGKJT-UHFFFAOYSA-N 3-ethyl-3-[(3-ethyloxetan-3-yl)methoxymethyl]oxetane Chemical class C1OCC1(CC)COCC1(CC)COC1 FNYWFRSQRHGKJT-UHFFFAOYSA-N 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 2
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 description 2
- BIDWUUDRRVHZLQ-UHFFFAOYSA-N 3-ethyl-3-(2-ethylhexoxymethyl)oxetane Chemical class CCCCC(CC)COCC1(CC)COC1 BIDWUUDRRVHZLQ-UHFFFAOYSA-N 0.000 description 2
- LMIOYAVXLAOXJI-UHFFFAOYSA-N 3-ethyl-3-[[4-[(3-ethyloxetan-3-yl)methoxymethyl]phenyl]methoxymethyl]oxetane Chemical compound C=1C=C(COCC2(CC)COC2)C=CC=1COCC1(CC)COC1 LMIOYAVXLAOXJI-UHFFFAOYSA-N 0.000 description 2
- YYPNJNDODFVZLE-UHFFFAOYSA-N 3-methylbut-2-enoic acid Chemical compound CC(C)=CC(O)=O YYPNJNDODFVZLE-UHFFFAOYSA-N 0.000 description 2
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 2
- HMBNQNDUEFFFNZ-UHFFFAOYSA-N 4-ethenoxybutan-1-ol Chemical compound OCCCCOC=C HMBNQNDUEFFFNZ-UHFFFAOYSA-N 0.000 description 2
- FVCSARBUZVPSQF-UHFFFAOYSA-N 5-(2,4-dioxooxolan-3-yl)-7-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C(OC2=O)=O)C2C(C)=CC1C1C(=O)COC1=O FVCSARBUZVPSQF-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 229920002284 Cellulose triacetate Polymers 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 125000005997 bromomethyl group Chemical group 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- 150000001896 cresols Chemical class 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 description 2
- MAWOHFOSAIXURX-UHFFFAOYSA-N cyclopentylcyclopentane Chemical group C1CCCC1C1CCCC1 MAWOHFOSAIXURX-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 125000005446 heptyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000005921 isopentoxy group Chemical group 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 2
- 150000002921 oxetanes Chemical class 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 150000003577 thiophenes Chemical class 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 2
- 229940113165 trimethylolpropane Drugs 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- UNMJLQGKEDTEKJ-UHFFFAOYSA-N (3-ethyloxetan-3-yl)methanol Chemical compound CCC1(CO)COC1 UNMJLQGKEDTEKJ-UHFFFAOYSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- SJHPCNCNNSSLPL-CSKARUKUSA-N (4e)-4-(ethoxymethylidene)-2-phenyl-1,3-oxazol-5-one Chemical compound O1C(=O)C(=C/OCC)\N=C1C1=CC=CC=C1 SJHPCNCNNSSLPL-CSKARUKUSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MIOPJNTWMNEORI-GMSGAONNSA-N (S)-camphorsulfonic acid Chemical compound C1C[C@@]2(CS(O)(=O)=O)C(=O)C[C@@H]1C2(C)C MIOPJNTWMNEORI-GMSGAONNSA-N 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- ZXPCCXXSNUIVNK-UHFFFAOYSA-N 1,1,1,2,3-pentachloropropane Chemical compound ClCC(Cl)C(Cl)(Cl)Cl ZXPCCXXSNUIVNK-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical class ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- ZXHDVRATSGZISC-UHFFFAOYSA-N 1,2-bis(ethenoxy)ethane Chemical compound C=COCCOC=C ZXHDVRATSGZISC-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- KATAXDCYPGGJNJ-UHFFFAOYSA-N 1,3-bis(oxiran-2-ylmethoxy)propan-2-ol Chemical compound C1OC1COCC(O)COCC1CO1 KATAXDCYPGGJNJ-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- MWZJGRDWJVHRDV-UHFFFAOYSA-N 1,4-bis(ethenoxy)butane Chemical compound C=COCCCCOC=C MWZJGRDWJVHRDV-UHFFFAOYSA-N 0.000 description 1
- UKXGGMCMWNJILJ-UHFFFAOYSA-N 1,4-dibutoxynaphthalene Chemical compound C1=CC=C2C(OCCCC)=CC=C(OCCCC)C2=C1 UKXGGMCMWNJILJ-UHFFFAOYSA-N 0.000 description 1
- LJSLYKNKVQMIJY-UHFFFAOYSA-N 1,4-diethoxynaphthalene Chemical compound C1=CC=C2C(OCC)=CC=C(OCC)C2=C1 LJSLYKNKVQMIJY-UHFFFAOYSA-N 0.000 description 1
- FWWRTYBQQDXLDD-UHFFFAOYSA-N 1,4-dimethoxynaphthalene Chemical compound C1=CC=C2C(OC)=CC=C(OC)C2=C1 FWWRTYBQQDXLDD-UHFFFAOYSA-N 0.000 description 1
- APQSQLNWAIULLK-UHFFFAOYSA-N 1,4-dimethoxynaphthalene Natural products C1=CC=C2C(C)=CC=C(C)C2=C1 APQSQLNWAIULLK-UHFFFAOYSA-N 0.000 description 1
- JJPJWPYRFJDRMH-UHFFFAOYSA-N 1,4-dipropoxynaphthalene Chemical compound C1=CC=C2C(OCCC)=CC=C(OCCC)C2=C1 JJPJWPYRFJDRMH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NQMUGNMMFTYOHK-UHFFFAOYSA-N 1-Methoxynaphthalene Natural products C1=CC=C2C(OC)=CC=CC2=C1 NQMUGNMMFTYOHK-UHFFFAOYSA-N 0.000 description 1
- VEGNIXCUDMQGFZ-UHFFFAOYSA-N 1-[3-[3-[2,3-bis(oxiran-2-ylmethoxy)propoxy]-2-hydroxypropoxy]-2-(oxiran-2-ylmethoxy)propoxy]-3-(oxiran-2-ylmethoxy)propan-2-ol Chemical compound C1OC1COCC(OCC1OC1)COCC(O)COCC(OCC1OC1)COCC(O)COCC1CO1 VEGNIXCUDMQGFZ-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- LAYAKLSFVAPMEL-UHFFFAOYSA-N 1-ethenoxydodecane Chemical class CCCCCCCCCCCCOC=C LAYAKLSFVAPMEL-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- XTVNGRMJOGNDOG-UHFFFAOYSA-N 1-trimethoxysilylpropan-2-yl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CC(C)OC(=O)C(C)=C XTVNGRMJOGNDOG-UHFFFAOYSA-N 0.000 description 1
- VRRDONHGWVSGFH-UHFFFAOYSA-N 2,5-diethylcyclohexane-1,4-diamine Chemical compound CCC1CC(N)C(CC)CC1N VRRDONHGWVSGFH-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- VMSIYTPWZLSMOH-UHFFFAOYSA-N 2-(dodecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCOCC1CO1 VMSIYTPWZLSMOH-UHFFFAOYSA-N 0.000 description 1
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- JZUMVFMLJGSMRF-UHFFFAOYSA-N 2-Methyladipic acid Chemical compound OC(=O)C(C)CCCC(O)=O JZUMVFMLJGSMRF-UHFFFAOYSA-N 0.000 description 1
- XRBWKWGATZNBFW-UHFFFAOYSA-N 2-[2-(2-ethenoxyethoxy)ethoxy]ethanol Chemical class OCCOCCOCCOC=C XRBWKWGATZNBFW-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- VSRMIIBCXRHPCC-UHFFFAOYSA-N 2-[2-[2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxy]ethoxy]ethoxymethyl]oxirane Chemical compound C1OC1COCCOCCOCCOCCOCC1CO1 VSRMIIBCXRHPCC-UHFFFAOYSA-N 0.000 description 1
- SHKUUQIDMUMQQK-UHFFFAOYSA-N 2-[4-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical group C1OC1COCCCCOCC1CO1 SHKUUQIDMUMQQK-UHFFFAOYSA-N 0.000 description 1
- WTYYGFLRBWMFRY-UHFFFAOYSA-N 2-[6-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COCCCCCCOCC1CO1 WTYYGFLRBWMFRY-UHFFFAOYSA-N 0.000 description 1
- 125000006012 2-chloroethoxy group Chemical group 0.000 description 1
- VUIWJRYTWUGOOF-UHFFFAOYSA-N 2-ethenoxyethanol Chemical class OCCOC=C VUIWJRYTWUGOOF-UHFFFAOYSA-N 0.000 description 1
- XAYUYBHNVNEQGZ-UHFFFAOYSA-N 2-ethyl-9,10-di(propan-2-yloxy)anthracene Chemical compound C1=CC=CC2=C(OC(C)C)C3=CC(CC)=CC=C3C(OC(C)C)=C21 XAYUYBHNVNEQGZ-UHFFFAOYSA-N 0.000 description 1
- SURWYRGVICLUBJ-UHFFFAOYSA-N 2-ethyl-9,10-dimethoxyanthracene Chemical compound C1=CC=CC2=C(OC)C3=CC(CC)=CC=C3C(OC)=C21 SURWYRGVICLUBJ-UHFFFAOYSA-N 0.000 description 1
- BDPJILVXUVJWBF-UHFFFAOYSA-N 2-ethyl-9,10-dipropoxyanthracene Chemical compound CCC1=CC=C2C(OCCC)=C(C=CC=C3)C3=C(OCCC)C2=C1 BDPJILVXUVJWBF-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- KCYSEXMGPHIRHT-UHFFFAOYSA-N 2-methyl-9,10-dipropoxyanthracene Chemical group CC1=CC2=C(C3=CC=CC=C3C(=C2C=C1)OCCC)OCCC KCYSEXMGPHIRHT-UHFFFAOYSA-N 0.000 description 1
- GYMFBYTZOGMSQJ-UHFFFAOYSA-N 2-methylanthracene Chemical group C1=CC=CC2=CC3=CC(C)=CC=C3C=C21 GYMFBYTZOGMSQJ-UHFFFAOYSA-N 0.000 description 1
- KIBVFIDMXQZCBS-UHFFFAOYSA-N 2-methyloctanedioic acid Chemical compound OC(=O)C(C)CCCCCC(O)=O KIBVFIDMXQZCBS-UHFFFAOYSA-N 0.000 description 1
- ZRNSSRODJSSVEJ-UHFFFAOYSA-N 2-methylpentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(C)C ZRNSSRODJSSVEJ-UHFFFAOYSA-N 0.000 description 1
- DZKKXYZKADGXTD-UHFFFAOYSA-N 2-methylprop-2-enoic acid hydrate Chemical compound O.CC(=C)C(O)=O.CC(=C)C(O)=O DZKKXYZKADGXTD-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- HYPIHGLKOQBQNW-UHFFFAOYSA-N 3,7-dimethyldecanedioic acid Chemical compound OC(=O)CCC(C)CCCC(C)CC(O)=O HYPIHGLKOQBQNW-UHFFFAOYSA-N 0.000 description 1
- CPSKVIYXUCHQAR-UHFFFAOYSA-N 3,8-dimethyldecanedioic acid Chemical compound OC(=O)CC(C)CCCCC(C)CC(O)=O CPSKVIYXUCHQAR-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- UKLWXKWTXHHMFK-UHFFFAOYSA-N 3-(chloromethyl)-3-ethyloxetane Chemical class CCC1(CCl)COC1 UKLWXKWTXHHMFK-UHFFFAOYSA-N 0.000 description 1
- DSSAWHFZNWVJEC-UHFFFAOYSA-N 3-(ethenoxymethyl)heptane Chemical compound CCCCC(CC)COC=C DSSAWHFZNWVJEC-UHFFFAOYSA-N 0.000 description 1
- REEBWSYYNPPSKV-UHFFFAOYSA-N 3-[(4-formylphenoxy)methyl]thiophene-2-carbonitrile Chemical compound C1=CC(C=O)=CC=C1OCC1=C(C#N)SC=C1 REEBWSYYNPPSKV-UHFFFAOYSA-N 0.000 description 1
- DOYKFSOCSXVQAN-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CCO[Si](C)(OCC)CCCOC(=O)C(C)=C DOYKFSOCSXVQAN-UHFFFAOYSA-N 0.000 description 1
- LAYPWKMPTSNIRX-UHFFFAOYSA-N 3-ethyl-3-(hexoxymethyl)oxetane Chemical class CCCCCCOCC1(CC)COC1 LAYPWKMPTSNIRX-UHFFFAOYSA-N 0.000 description 1
- JUXZNIDKDPLYBY-UHFFFAOYSA-N 3-ethyl-3-(phenoxymethyl)oxetane Chemical compound C=1C=CC=CC=1OCC1(CC)COC1 JUXZNIDKDPLYBY-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- ULYIFEQRRINMJQ-UHFFFAOYSA-N 3-methylbutyl 2-methylprop-2-enoate Chemical compound CC(C)CCOC(=O)C(C)=C ULYIFEQRRINMJQ-UHFFFAOYSA-N 0.000 description 1
- ZVYGIPWYVVJFRW-UHFFFAOYSA-N 3-methylbutyl prop-2-enoate Chemical compound CC(C)CCOC(=O)C=C ZVYGIPWYVVJFRW-UHFFFAOYSA-N 0.000 description 1
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 1
- FQMIAEWUVYWVNB-UHFFFAOYSA-N 3-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OC(C)CCOC(=O)C=C FQMIAEWUVYWVNB-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- PQBWUHWJQRHCQH-UHFFFAOYSA-N 4-(aminomethyl)benzenediazonium Chemical compound NCC1=CC=C([N+]#N)C=C1 PQBWUHWJQRHCQH-UHFFFAOYSA-N 0.000 description 1
- HVMHLMJYHBAOPL-UHFFFAOYSA-N 4-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)propan-2-yl]-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2OC2CC1C(C)(C)C1CC2OC2CC1 HVMHLMJYHBAOPL-UHFFFAOYSA-N 0.000 description 1
- INBYRLZHIQCNTL-UHFFFAOYSA-N 4-hexoxynaphthalen-1-ol Chemical class C1=CC=C2C(OCCCCCC)=CC=C(O)C2=C1 INBYRLZHIQCNTL-UHFFFAOYSA-N 0.000 description 1
- KSGYKTRNRCPDHT-KVSWJAHQSA-N 4-n-[1-[(3-fluorophenyl)methyl]indazol-5-yl]-5-[(e)-2-methoxyethoxyiminomethyl]pyrimidine-4,6-diamine Chemical compound COCCO\N=C\C1=C(N)N=CN=C1NC1=CC=C(N(CC=2C=C(F)C=CC=2)N=C2)C2=C1 KSGYKTRNRCPDHT-KVSWJAHQSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- GAYWCADKXYCKCG-UHFFFAOYSA-N 5-pyridin-3-yl-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1NC(=S)N=C1C1=CC=CN=C1 GAYWCADKXYCKCG-UHFFFAOYSA-N 0.000 description 1
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 1
- RBHIUNHSNSQJNG-UHFFFAOYSA-N 6-methyl-3-(2-methyloxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2(C)OC2CC1C1(C)CO1 RBHIUNHSNSQJNG-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- GJEZBVHHZQAEDB-UHFFFAOYSA-N 6-oxabicyclo[3.1.0]hexane Chemical compound C1CCC2OC21 GJEZBVHHZQAEDB-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- HWTDMFJYBAURQR-UHFFFAOYSA-N 80-82-0 Chemical compound OS(=O)(=O)C1=CC=CC=C1[N+]([O-])=O HWTDMFJYBAURQR-UHFFFAOYSA-N 0.000 description 1
- BIDNFOLOHMWYGB-UHFFFAOYSA-N 9,10-bis(2-butoxyethoxy)anthracene Chemical class C1=CC=C2C(OCCOCCCC)=C(C=CC=C3)C3=C(OCCOCCCC)C2=C1 BIDNFOLOHMWYGB-UHFFFAOYSA-N 0.000 description 1
- BEFARLHNOSBDOH-UHFFFAOYSA-N 9,10-bis(2-ethoxyethoxy)anthracene Chemical class C1=CC=C2C(OCCOCC)=C(C=CC=C3)C3=C(OCCOCC)C2=C1 BEFARLHNOSBDOH-UHFFFAOYSA-N 0.000 description 1
- IXYPOJJOFMWNSH-UHFFFAOYSA-N 9,10-di(propan-2-yloxy)anthracene Chemical compound C1=CC=C2C(OC(C)C)=C(C=CC=C3)C3=C(OC(C)C)C2=C1 IXYPOJJOFMWNSH-UHFFFAOYSA-N 0.000 description 1
- NYEVBSJUVMRZNE-UHFFFAOYSA-N 9,10-dibutoxy-2-ethylanthracene Chemical compound CCC1=CC=C2C(OCCCC)=C(C=CC=C3)C3=C(OCCCC)C2=C1 NYEVBSJUVMRZNE-UHFFFAOYSA-N 0.000 description 1
- KSMGAOMUPSQGTB-UHFFFAOYSA-N 9,10-dibutoxyanthracene Chemical compound C1=CC=C2C(OCCCC)=C(C=CC=C3)C3=C(OCCCC)C2=C1 KSMGAOMUPSQGTB-UHFFFAOYSA-N 0.000 description 1
- FUWFDADDJOUNDL-UHFFFAOYSA-N 9,10-diethoxy-2-ethylanthracene Chemical compound CCC1=CC=C2C(OCC)=C(C=CC=C3)C3=C(OCC)C2=C1 FUWFDADDJOUNDL-UHFFFAOYSA-N 0.000 description 1
- GJNKQJAJXSUJBO-UHFFFAOYSA-N 9,10-diethoxyanthracene Chemical compound C1=CC=C2C(OCC)=C(C=CC=C3)C3=C(OCC)C2=C1 GJNKQJAJXSUJBO-UHFFFAOYSA-N 0.000 description 1
- JWJMBKSFTTXMLL-UHFFFAOYSA-N 9,10-dimethoxyanthracene Chemical compound C1=CC=C2C(OC)=C(C=CC=C3)C3=C(OC)C2=C1 JWJMBKSFTTXMLL-UHFFFAOYSA-N 0.000 description 1
- LBQJFQVDEJMUTF-UHFFFAOYSA-N 9,10-dipropoxyanthracene Chemical compound C1=CC=C2C(OCCC)=C(C=CC=C3)C3=C(OCCC)C2=C1 LBQJFQVDEJMUTF-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BXQOGTHSKFRGDV-UHFFFAOYSA-N C(CC)[Si](OCC)(OCC)C.[O] Chemical compound C(CC)[Si](OCC)(OCC)C.[O] BXQOGTHSKFRGDV-UHFFFAOYSA-N 0.000 description 1
- CYRRYHPFWXNRRH-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)(=O)OOCCCC Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)OOCCCC CYRRYHPFWXNRRH-UHFFFAOYSA-N 0.000 description 1
- KIMWUAQXWKOBTF-UHFFFAOYSA-N C1(CCCCC1)C1C(C(CC2C1O2)C)(C(=O)O)C.[O] Chemical class C1(CCCCC1)C1C(C(CC2C1O2)C)(C(=O)O)C.[O] KIMWUAQXWKOBTF-UHFFFAOYSA-N 0.000 description 1
- AKSFWDNJWGSQMY-UHFFFAOYSA-N CC(=CC(=O)OCCCCO)C Chemical compound CC(=CC(=O)OCCCCO)C AKSFWDNJWGSQMY-UHFFFAOYSA-N 0.000 description 1
- ZJEIQAVSKHHECZ-UHFFFAOYSA-N CCCCC[O] Chemical group CCCCC[O] ZJEIQAVSKHHECZ-UHFFFAOYSA-N 0.000 description 1
- FHUGBSPFIIEFFZ-UHFFFAOYSA-N CO[SiH](CCCOC(=O)C=CC)OC Chemical compound CO[SiH](CCCOC(=O)C=CC)OC FHUGBSPFIIEFFZ-UHFFFAOYSA-N 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 206010018612 Gonorrhoea Diseases 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- JIMPAYYJPMENLQ-UHFFFAOYSA-N acetic acid;2-(2-methoxypropoxy)propan-1-ol Chemical class CC(O)=O.COC(C)COC(C)CO JIMPAYYJPMENLQ-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000012675 alcoholic extract Substances 0.000 description 1
- 239000004844 aliphatic epoxy resin Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910001439 antimony ion Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- SYEOWUNSTUDKGM-UHFFFAOYSA-N beta-methyladipic acid Natural products OC(=O)CC(C)CCC(O)=O SYEOWUNSTUDKGM-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229940063013 borate ion Drugs 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- AKOHUFLQBXMCOZ-UHFFFAOYSA-N butane-1,3-diol 3-methylbut-2-enoic acid Chemical compound CC(=CC(=O)O)C.C(CC(C)O)O AKOHUFLQBXMCOZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- FEXXLIKDYGCVGJ-UHFFFAOYSA-N butyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCC1OC1CCCCCCCC(=O)OCCCC FEXXLIKDYGCVGJ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- UNTORJADNWVACA-UHFFFAOYSA-N carbamic acid;methylcyclohexane Chemical group NC(O)=O.CC1CCCCC1 UNTORJADNWVACA-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- QDYLMAYUEZBUFO-UHFFFAOYSA-N cetalkonium chloride Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 QDYLMAYUEZBUFO-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- XCJXQCUJXDUNDN-UHFFFAOYSA-N chlordene Chemical compound C12C=CCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl XCJXQCUJXDUNDN-UHFFFAOYSA-N 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- NLUNLVTVUDIHFE-UHFFFAOYSA-N cyclooctylcyclooctane Chemical group C1CCCCCCC1C1CCCCCCC1 NLUNLVTVUDIHFE-UHFFFAOYSA-N 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 125000005520 diaryliodonium group Chemical group 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 125000004772 dichloromethyl group Chemical group [H]C(Cl)(Cl)* 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- UWGJCHRFALXDAR-UHFFFAOYSA-N diethoxy-ethyl-methylsilane Chemical compound CCO[Si](C)(CC)OCC UWGJCHRFALXDAR-UHFFFAOYSA-N 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229940113088 dimethylacetamide Drugs 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- FUXJJBJXVZIIMV-UHFFFAOYSA-N dioctyl cyclohexane-1,2-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1CCCCC1C(=O)OCCCCCCCC FUXJJBJXVZIIMV-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- UHKJHMOIRYZSTH-UHFFFAOYSA-N ethyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OCC UHKJHMOIRYZSTH-UHFFFAOYSA-N 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- HTSRFYSEWIPFNI-UHFFFAOYSA-N ethyl-dimethoxy-methylsilane Chemical compound CC[Si](C)(OC)OC HTSRFYSEWIPFNI-UHFFFAOYSA-N 0.000 description 1
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 125000006343 heptafluoro propyl group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-M isovalerate Chemical compound CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Natural products CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 150000002632 lipids Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 125000004092 methylthiomethyl group Chemical group [H]C([H])([H])SC([H])([H])* 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 125000005246 nonafluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- FKUVGXBVCSQMHI-UHFFFAOYSA-N octyl 2-hydroxyacetate Chemical compound CCCCCCCCOC(=O)CO FKUVGXBVCSQMHI-UHFFFAOYSA-N 0.000 description 1
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical class CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 1
- 125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005651 polypropylene glycol dimethacrylate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 125000006253 t-butylcarbonyl group Chemical group [H]C([H])([H])C(C(*)=O)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical class CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- 125000006007 trichloroethoxy group Chemical group 0.000 description 1
- 125000006000 trichloroethyl group Chemical group 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- GJOGTGLNIWPDPF-UHFFFAOYSA-N trifluoromethyl hydrogen sulfite Chemical compound OS(=O)OC(F)(F)F GJOGTGLNIWPDPF-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- AKQNYQDSIDKVJZ-UHFFFAOYSA-N triphenylsilane Chemical compound C1=CC=CC=C1[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 AKQNYQDSIDKVJZ-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/16—Cyclic ethers having four or more ring atoms
- C08G65/18—Oxetanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Polyethers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
本发明提供固化物的玻璃化转变温度高、密合性优异的固化性组合物、固化物的制造方法、及其固化物。以(A)和(C)和(E)的总计为100质量份的方式含有:阳离子聚合性成分(A)15~90质量份、阳离子聚合引发剂(B)1~10质量份、自由基聚合性成分(C)10~50质量份、自由基聚合引发剂(D)1~10质量份、及聚合物(E)1~20质量份,所述聚合物(E)的重均分子量为1000~30000,所述聚合物(E)选自由下述聚合物组成的组:由下述式(I)所示的单体得到的聚合物、由下述式(II)所示的单体得到的聚合物等,(A)将多元醇的缩水甘油化物等(A1)和氧杂环丁烷化合物(A2)作为必须成分,(A1)为35~65质量份,自由基聚合性成分(C)将具有环氧基和烯属不饱和基团的化合物(C1)等作为必须成分。
Description
技术领域
本发明涉及固化性组合物、固化物的制造方法、及其固化物,详细而言涉及固化物的玻璃化转变温度高、密合性优异的固化性组合物、固化物的制造方法、及其固化物。
背景技术
固化性组合物用于墨、涂料、各种涂布剂、粘接剂、光学构件等的领域中。有关这样的固化性组合物的改良进行了各种报告。
例如,下述专利文献1~4中提出了:含有阳离子聚合性成分和自由基聚合性成分的能量射线固化性组合物或其固化物。具体而言,专利文献1中提出了:初始固化性和粘接性优异的偏光板用粘接剂组合物。另外,专利文献2中提出了一种低粘度的光固化性粘接剂,即使在将透湿度低的树脂薄膜作为保护膜的情况下,光照射后也迅速地显示出粘接力,经过一定时间后的粘接力相对于各种力是良好的,且耐久试验后也不会出现问题,耐湿热试验结束后的粘接力也良好。进而,专利文献3中提出了:能够兼顾包含不饱和脂环式环氧酯化合物的高耐热性、高折射率化及透明性的活性能量射线聚合性树脂组合物。
现有技术文献
专利文献
专利文献1:日本特开2014-105218号公报
专利文献2:日本特开2015-040283号公报
专利文献3:日本特开2015-168757号公报
发明内容
发明要解决的问题
然而,即使作为专利文献1~3中提出的固化性组合物,对于固化性和密合性而言,有时也未必能满足要求,现状是期望能够高度地兼顾固化性和密合性的、新型的固化性组合物。
因此,本发明的目的在于提供固化物的玻璃化转变温度高、密合性优异的固化性组合物、固化物的制造方法、及其固化物。
用于解决问题的方案
本发明人等为了解决上述课题而进行了深入研究,结果发现若是具有特定的组成的固化性组合物就能解决上述课题,以至完成了本发明。
即,本发明的固化性组合物的特征在于,其以阳离子聚合性成分(A)和自由基聚合性成分(C)和聚合物(E)的总计为100质量份的方式含有:前述阳离子聚合性成分(A)15~90质量份、阳离子聚合引发剂(B)1~10质量份、前述自由基聚合性成分(C)10~50质量份、自由基聚合引发剂(D)1~10质量份、及前述聚合物(E)1~20质量份,前述聚合物(E)的重均分子量为1000~30000,前述聚合物(E)选自由下述聚合物组成的组:由下述式(I)所示的单体得到的聚合物、由下述式(II)所示的单体得到的聚合物、由选自前述式(I)所示的单体中的两种以上单体得到的聚合物、由选自前述式(II)所示的单体中的两种以上单体得到的聚合物、或由前述式(I)所示的单体和前述式(II)所示的单体得到的聚合物,
式(I)中,X为碳原子数1~7的烷基、碳原子数1~7的烷氧基、碳原子数6~12的芳基、碳原子数6~12的芳氧基或碳原子数6~10的脂环式烃基、或这些基团中的氢原子被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上基团取代的基团,
式(II)中,R1表示氢原子、甲基或卤素原子,X’为碳原子数1~7的烷基、碳原子数6~12的芳基或碳原子数6~10的脂环式烃基、或这些基团中的氢原子被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上基团取代的基团,
前述阳离子聚合性成分(A)将多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)、及氧杂环丁烷化合物(A2)作为必须成分,
相对于前述阳离子聚合性成分(A)、前述自由基聚合性成分(C)、及前述聚合物(E)的总计为100质量份,前述多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)为35~65质量份,
前述自由基聚合性成分(C)将具有环氧基和烯属不饱和基团的化合物(C1)、或碳原子数2~20的多元醇的丙烯酸酯或者碳原子数2~20的多元醇的甲基丙烯酸酯(C2)作为必须成分。此处,重均分子量是指:在四氢呋喃(THF)溶剂中,利用GPC测定并以苯乙烯换算求出的重均分子量。
对于本发明的固化性组合物,作为前述阳离子聚合性成分(A),优选进一步含有芳香族环氧化合物(A3)。另外,对于本发明的固化性组合物,前述芳香族环氧化合物(A3)优选为多官能芳香族环氧化合物。进而,对于本发明的固化性组合物,优选:前述聚合物(E)是由前述式(I)所示的单体和前述式(II)所示的单体得到的聚合物,前述式(I)中的X为碳原子数6~12的芳基,前述式(II)中的X’为碳原子数1~7的烷基,前述烷基被环氧基取代。
本发明的固化物的制造方法的特征在于,对本发明的固化性组合物照射活性能量射线或进行加热。
本发明的固化物的特征在于,其为本发明的固化性组合物的固化物。
发明的效果
根据本发明,可以提供固化物的玻璃化转变温度高、密合性优异的固化性组合物、固化物的制造方法、及其固化物。本发明的固化性组合物尤其对粘接剂是有用的。
具体实施方式
以下对本发明的固化性组合物进行详细地说明。
本发明的固化性组合物含有:阳离子聚合性成分(A)15~90质量份、阳离子聚合引发剂(B)1~10质量份、自由基聚合性成分(C)10~50质量份、及自由基聚合引发剂(D)1~10质量份、及所述聚合物(E)1~20质量份,所述聚合物(E)的重均分子量为1000~30000,所述聚合物(E)选自由下述聚合物组成的组:由下述式(I)所示的单体得到的聚合物、由下述式(II)所示的单体得到的聚合物、由选自前述式(I)所示的单体中的两种以上单体得到的聚合物、由选自前述式(II)所示的单体中的两种以上单体得到的聚合物、以及由前述式(I)所示的单体和前述式(II)所示的单体得到的聚合物。
对于本发明的固化性组合物,阳离子聚合性成分(A)将多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)和氧杂环丁烷化合物(A2)作为必须成分,且相对于阳离子聚合性成分(A)、自由基聚合性成分(C)、及聚合物(E)的总计为100质量份,多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)为35~65质量份。另外,自由基聚合性成分(C)将具有环氧基和烯属不饱和基团的化合物(C1)、或碳原子数为2~20的多元醇的丙烯酸酯或者碳原子数为2~20的多元醇的甲基丙烯酸酯(C2)作为必须成分。
此处,式(I)中,X为碳原子数1~7的烷基、碳原子数1~7的烷氧基、碳原子数6~12的芳基、碳原子数6~12的芳氧基或碳原子数6~10的脂环式烃基、或这些基团中的氢原子被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上基团取代的基团。
此处,式(II)中,R1表示氢原子、甲基或卤素原子,X’为碳原子数1~7的烷基、碳原子数6~12的芳基或碳原子数6~10的脂环式烃基、或这些基团中的氢原子被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上基团取代的基团。
本发明的固化性组合物的阳离子聚合性成分(A)是通过利用能量射线照射或加热而活化的阳离子聚合引发剂来发生高分子化或交联反应的化合物。可列举出:环氧化合物、氧杂环丁烷化合物、乙烯基醚化合物等。
本发明的固化性组合物的阳离子聚合性成分(A)将多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)、及氧杂环丁烷化合物(A2)作为必须成分,作为其它环氧化合物,可以使用芳香族环氧化合物(A3)和脂环式环氧化合物(A4)等。
作为上述多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1),可列举出使多元醇或多元醇环氧烷加成物缩水甘油基化而成的物质,优选缩水甘油化物的分子量为250以上。
作为上述多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1),可列举出:1,4-丁二醇二缩水甘油醚、1,6-己二醇二缩水甘油醚、新戊二醇二缩水甘油醚、甘油的三缩水甘油醚、三羟甲基丙烷的三缩水甘油醚、山梨醇的四缩水甘油醚、二季戊四醇的六缩水甘油醚、聚乙二醇的二缩水甘油醚、聚丙二醇的二缩水甘油醚、二环戊二烯二甲醇二缩水甘油醚等多元醇的缩水甘油醚、另外通过在丙二醇、三羟甲基丙烷、甘油等脂肪族多元醇中加成1种或2种以上的环氧烷而得到的聚醚多元醇的多缩水甘油醚化物、脂肪族长链二元酸的二缩水甘油酯。
作为多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1),进而可列举出:脂肪族高级醇的单缩水甘油醚、高级脂肪酸的缩水甘油酯、环氧化大豆油、环氧硬脂酸辛酯、环氧硬脂酸丁酯、环氧化大豆油、环氧化聚丁二烯等。
作为多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1),具有饱和稠环的情况使固化物的固化性和密合性提高,故而优选。
作为上述多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1),可以使用市售品,例如可列举出:DENACOL EX-121、DENACOL EX-171、DENACOL EX-192、DENACOL EX-211、DENACOL EX-212、DENACOL EX-313、DENACOL EX-314、DENACOL EX-321、DENACOL EX-411、DENACOL EX-421、DENACOL EX-512、DENACOL EX-521、DENACOL EX-611、DENACOL EX-612、DENACOL EX-614、DENACOL EX-622、DENACOL EX-810、DENACOL EX-811、DENACOL EX-850、DENACOL EX-851、DENACOL EX-821、DENACOL EX-830、DENACOL EX-832、DENACOL EX-841、DENACOL EX-861、DENACOL EX-911、DENACOL EX-941、DENACOL EX-920、DENACOL EX-931(Nagase ChemteX Corporation制);Epolight M-1230、Epolight 40E、Epolight 100E、Epolight 200E、Epolight 400E、Epolight 70P、Epolight 200P、Epolight400P、Epolight 1500NP、Epolight 1600、Epolight 80MF、Epolight 100MF(共荣社化学株式会社制),ADEKA Glycirol ED-503、ADEKA Glycirol ED-503G、ADEKA Glycirol ED-506、ADEKA Glycirol ED-523T、ADEKA RESIN EP-4088S、ADEKA RESIN EP-4080E(ADEKA株式会社制)等。
作为上述氧杂环丁烷化合物(A2),可列举出:3,7-双(3-氧杂环丁基)-5-氧代-壬烷、1,4-双[(3-乙基-3-氧杂环丁基甲氧基)甲基]苯、1,2-双[(3-乙基-3-氧杂环丁基甲氧基)甲基]乙烷、1,3-双[(3-乙基-3-氧杂环丁基甲氧基)甲基]丙烷、乙二醇双(3-乙基-3-氧杂环丁基甲基)醚、三乙二醇双(3-乙基-3-氧杂环丁基甲基)醚、四乙二醇双(3-乙基-3-氧杂环丁基甲基)醚、1,4-双(3-乙基-3-氧杂环丁基甲氧基)丁烷、1,6-双(3-乙基-3-氧杂环丁基甲氧基)己烷等二官能脂肪族氧杂环丁烷化合物、3-乙基-3-[(苯氧基)甲基]氧杂环丁烷、3-乙基-3-(己氧基甲基)氧杂环丁烷、3-乙基-3-(2-乙基己氧基甲基)氧杂环丁烷、3-乙基-3-(羟基甲基)氧杂环丁烷、3-乙基-3-(氯甲基)氧杂环丁烷等单官能氧杂环丁烷化合物等。它们可以单独使用1种或组合使用2种以上。多官能氧杂环丁烷化合物使固化物的固化性和密合性提高,故而特别优选。
作为上述氧杂环丁烷化合物(A2),可以使用市售品,例如可列举出:2-羟乙基乙烯基醚、二乙二醇单乙烯基醚、4-羟丁基乙烯基醚(丸善石油化学株式会社制);ARON OXETANEOXT-121、OXT-221、EXOH、POX、OXA、OXT-101、OXT-211、OXT-212(东亚合成株式会社制),ETERNACOLL OXBP、OXTP(宇部兴产株式会社制)等。
上述芳香族环氧化合物(A3)是指包含芳香环的环氧化合物,作为芳香族环氧化合物(A3)的具体例子,可列举出:苯酚、甲酚、丁基苯酚等具有至少1个芳香族环的多元酚或其环氧烷加成物的单/多缩水甘油醚化物、例如:双酚A、双酚F、或在它们中进而加成了环氧烷的化合物的缩水甘油醚化物、酚醛清漆环氧树脂;间苯二酚、对苯二酚、邻苯二酚等具有2个以上酚羟基的芳香族化合物的单/多缩水甘油醚化物;苯基二甲醇、苯基二乙醇、苯基二丁醇等具有2个以上醇羟基的芳香族化合物的缩水甘油醚化物;邻苯二甲酸、对苯二甲酸、偏苯三酸等具有2个以上羧酸的多元酸芳香族化合物的缩水甘油酯、苯甲酸的缩水甘油酯、苯乙烯氧化物或二乙烯基苯的环氧化物等。
作为上述芳香族环氧化合物(A3),可以使用市售品,例如可列举出:DENACOL EX-146、DENACOL EX-147、DENACOL EX-201、DENACOL EX-203、DENACOL EX-711、DENACOL EX-721、ONCOAT EX-1020、ONCOAT EX-1030、ONCOAT EX-1040、ONCOAT EX-1050、ONCOAT EX-1051、ONCOAT EX-1010、ONCOAT EX-1011、ONCOAT 1012(Nagase ChemteX Corporation制);OGSOL PG-100、OGSOL EG-200、OGSOL EG-210、OGSOL EG-250(Osaka Gas Chemicals Co.,Ltd.制);HP4032、HP4032D、HP4700(DIC株式会社制);ESN-475V(新日铁住金化学株式会社制);EPIKOTE YX8800(三菱化学株式会社制);MARPROOF G-0105SA、MARPROOF G-0130SP(日油株式会社制);EPICLON N-665、EPICLON HP-7200(DIC株式会社制);EOCN-1020、EOCN-102S、EOCN-103S、EOCN-104S、XD-1000、NC-3000、EPPN-501H、EPPN-501HY、EPPN-502H、NC-7000L(日本化药株式会社制);ADEKA RESIN EP-4000、ADEKA RESIN EP-4005、ADEKA RESINEP-4100、ADEKA RESIN EP-4901(ADEKA株式会社制);TECHMORE VG-3101L(Printech Co.,Ltd.制)等。作为上述芳香族环氧化合物(A3),多官能芳香族环氧化合物的固化性优异,故而优选。
上述脂环式环氧化合物(A4)是指环氧乙烷环不借助键合基团而直接连接在饱和环上。作为脂环式环氧化合物(A4)的具体例子,可列举出:通过利用氧化剂使具有至少1个脂环式环的多元醇的多缩水甘油醚化物或环己烯、含有环戊烯环的化合物环氧化而得到的环己烯氧化物、含有环戊烯氧化物的化合物。例如可列举出:3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯、3,4-环氧-1-甲基环己基-3,4-环氧-1-甲基己基甲酸酯、6-甲基-3,4-环氧环己基甲基-6-甲基-3,4-环氧环己基甲酸酯、3,4-环氧-3-甲基环己基甲基-3,4-环氧-3-甲基环己基甲酸酯、3,4-环氧-5-甲基环己基甲基-3,4-环氧-5-甲基环己基甲酸酯、双(3,4-环氧环己基甲基)己二酸酯、3,4-环氧-6-甲基环己基甲酸酯、亚甲基双(3,4-环氧环己烷)、丙烷-2,2-二基-双(3,4-环氧环己烷)、2,2-双(3,4-环氧环己基)丙烷、双环戊二烯二环氧化物、亚乙基双(3,4-环氧环己基甲酸酯)、环氧六氢化邻苯二甲酸二辛酯、环氧六氢化邻苯二甲酸二-2-乙基己酯、1-环氧乙基-3,4-环氧环己烷、1,2-环氧-2-环氧乙基环己烷、α-蒎烯氧化物、柠檬烯二氧化物等。作为脂环式环氧化合物(A4),3,4-环氧环己基甲基-3,4-环氧环己基甲酸酯或3,4-环氧-1-甲基环己基-3,4-环氧-1-甲基己基甲酸酯从密合性提高的观点出发而优选。
作为上述脂环式环氧化合物(A4),可以使用市售品,例如可列举出:CELLOXIDE2021P、CELLOXIDE 2081、CELLOXIDE 2000、CELLOXIDE 3000(Daicel Corporation制)等。
作为上述乙烯基醚化合物,例如可列举出:二乙二醇单乙烯基醚、三乙二醇二乙烯基醚、正十二烷基乙烯基醚、环己基乙烯基醚、2-乙基己基乙烯基醚、2-氯乙基乙烯基醚、乙基乙烯基醚、异丁基乙烯基醚、三乙二醇乙烯基醚、2-羟乙基乙烯基醚、4-羟丁基乙烯基醚、1,6-环己烷二甲醇单乙烯基醚、乙二醇二乙烯基醚、1,4-丁二醇二乙烯基醚、1,6-环己烷二甲醇二乙烯基醚等。
上述阳离子聚合性成分(A)中,对于上述多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)、氧杂环丁烷化合物(A2)、芳香族环氧化合物(A3)、脂环式环氧化合物(A4)和乙烯基醚化合物的使用比例,相对于阳离子聚合性成分(A)、自由基聚合性成分(C)、及聚合物(E)的总计100质量份为:多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)50~90质量份、氧杂环丁烷化合物(A2)10~50质量份、芳香族环氧化合物(A3)0~50质量份、脂环式环氧化合物(A4)0~30质量份、乙烯基醚化合物0~20质量份,在此情况下使粘度、涂覆性、反应性和固化性提高,故而优选。
本发明的固化性组合物的阳离子聚合引发剂(B)只要是能利用能量射线照射或加热而释放出引发阳离子聚合的物质的化合物就可以是任意聚合引发剂,优选为通过能量射线的照射而释放出路易斯酸的鎓盐也就是复盐、或其衍生物。作为上述化合物的代表性物质,可以列举出由下述通式表示的阳离子和阴离子的盐。
[A]r+[B]r-
此处阳离子[A]r+优选为鎓,其结构例如可以由下述通式表示。
[(R2)aQ]r+
进而,此处,R2是碳原子数为1~60、可以包含除若干个碳原子以外的原子的有机基团。a是1~5的整数。a个R2各自独立地可以相同也可以不同。另外,至少1个优选为具有芳香环的上述那样的有机基团。Q是选自由S、N、Se、Te、P、As、Sb、Bi、O、I、Br、Cl、F、N=N组成的组中的原子或原子团。另外,将阳离子[A]r+中的Q的原子价设为q时,需要使r=a-q的关系成立(其中,N=N视为原子价0)。
另外,阴离子[B]r-优选为卤化物络合物,其结构例如可以由下述通式表示。
[LYb]r-
进而,此处,L是作为卤化物络合物的中心原子的金属或半金属(Metalloid),B、P、As、Sb、Fe、Sn、Bi、Al、Ca、In、Ti、Zn、Sc、V、Cr、Mn、Co等。Y为卤素原子。b为3~7的整数。另外,将阴离子[B]r-中的L的原子价设为p时,需要使r=b-p的关系成立。
作为上述通式的阴离子[LYb]r-的具体例子,可以列举出:四(五氟苯基)硼酸根、四(3,5-二氟-4-甲氧基苯基)硼酸根、四氟硼酸根(BF4)-、六氟磷酸根(PF6)-、六氟锑酸根(SbF6)-、六氟砷酸根(AsF6)-、六氯锑酸根(SbCl6)-等。
另外,阴离子[B]r-还可以优选使用下述通式所示的结构。
[LYb-1(OH)]r-
L、Y、b与上述相同。另外,作为其它可以使用的阴离子,可以列举出:高氯酸根离子(ClO4)-、三氟甲基亚硫酸根离子(CF3SO3)-、氟磺酸根离子(FSO3)-、甲苯磺酸根阴离子、三硝基苯磺酸根阴离子、樟脑磺酸根、九氟丁烷磺酸根、十六氟辛烷磺酸根、四芳基硼酸根、四(五氟苯基)硼酸根等。
本发明的固化性组合物中,这样的鎓盐中,使用下述(i)~(iii)的芳香族鎓盐是特别有效的。其中,可以单独使用其1种或混合使用2种以上。
(i)苯基重氮鎓六氟磷酸盐、4-甲氧基苯基重氮鎓六氟锑酸盐、4-甲基苯基重氮鎓六氟磷酸盐等芳基重氮盐
(ii)二苯基碘鎓六氟锑酸盐、二(4-甲基苯基)碘鎓六氟磷酸盐、二(4-叔丁基苯基)碘鎓六氟磷酸盐、甲苯基枯基碘鎓四(五氟苯基)硼酸盐等二芳基碘鎓盐
(iii)下述组I或组II所示的锍阳离子和六氟锑离子、六氟磷酸根离子、四(五氟苯基)硼酸根离子等的锍盐
<组I>
<组II>
另外,作为其它优选的物质,可以列举出:(η5-2,4-环戊二烯-1-基)〔(1,2,3,4,5,6-η)-(1-甲基乙基)苯〕-铁-六氟磷酸盐等铁-芳烃络合物、三(乙酰丙酮)铝、三(乙基丙酮乙酸)铝、三(水杨醛)铝等铝络合物与三苯基硅烷醇等硅烷醇类的混合物;噻吩鎓盐、四氢噻吩盐、苄基铵、吡啶鎓盐、肼盐等盐;二亚乙基三胺、三亚乙基三胺、四亚乙基五胺等多烷基多胺类;1,2-二氨基环己烷、1,4-二氨基-3,6-二乙基环己烷、异佛尔酮二胺等脂环式多胺类;间苯二甲胺、二氨基二苯基甲烷、二氨基二苯基砜等芳香族多胺类;通过利用常规方法使上述多胺类、与苯基缩水甘油醚、丁基缩水甘油醚、双酚A-二缩水甘油醚、双酚F-二缩水甘油醚等缩水甘油醚类或羧酸的缩水甘油酯类等各种环氧树脂反应而制造的聚环氧加成改性物;通过利用常规方法使上述有机多胺类、与邻苯二甲酸、间苯二甲酸、二聚酸等羧酸类反应而制造的酰胺化改性物;通过利用常规方法使上述多胺类与甲醛等醛类及在苯酚、甲酚、二甲苯酚、叔丁基苯酚、间苯二酚等核中至少具有一个醛化反应性位置的酚类反应而制造的曼尼希化改性物;多元羧酸(草酸、丙二酸、琥珀酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、十二酸、2-甲基琥珀酸、2-甲基己二酸、3-甲基己二酸、3-甲基戊二酸、2-甲基辛二酸、3,8-二甲基癸二酸、3,7-二甲基癸二酸、氢化二聚酸、二聚酸等脂肪族二羧酸类;邻苯二甲酸、对苯二甲酸、间苯二甲酸、萘二羧酸等芳香族二羧酸类;环己烷二羧酸等脂环式二羧酸类;偏苯三酸、均苯三酸、蓖麻油脂肪酸的三聚体等三羧酸类;均苯四甲酸等四羧酸类等)的酸酐;双氰胺、咪唑类、羧酸酯、磺酸酯、胺酰亚胺等。
其中,从提高使用方面和光灵敏度的观点出发,优选使用:芳香族碘鎓盐、芳香族锍盐、铁-芳烃络合物,进一步优选:相对于阳离子聚合引发剂(B)100质量%,至少含有0.1质量%以上的具有下述结构的芳香族锍盐。
此处,式中,R11、R12、R13、R14、R15、R16、R17、R18、R19和R20分别独立地表示氢原子、卤素原子、碳原子数1~10的烷基、碳原子数1~10的烷氧基或碳原子数2~10的酯基,R21、R22、R23和R24分别独立地表示氢原子、卤素原子或碳原子数1~10的烷基,R25表示氢原子、卤素原子、碳原子数1~10的烷基或选自下述化学式(A)~(C)中任一种的取代基,Anq-表示q价的阴离子,p表示使电荷为中性的系数。
此处,式中,R11、R12、R13、R14、R15、R16、R17、R18、R19、R20、R21、R22、R23、R24、R26、R27、R28、R29、R35、R36、R37、R38和R39分别独立地表示氢原子、卤素原子、碳原子数1~10的烷基、碳原子数1~10的烷氧基或碳原子数2~10的酯基,R30、R31、R32、R33和R34分别独立地表示氢原子、卤素原子或碳原子数1~10的烷基。
上述通式所示的化合物中,作为R11、R12、R13、R14、R15、R16、R17、R18、R19、R20、R21、R22、R23、R24、R25、R26、R27、R28、R29、R30、R31、R32、R33、R34、R35、R36、R37、R38和R39所示的卤素原子,可列举出:氟、氯、溴、碘等。
作为R11、R12、R13、R14、R15、R16、R17、R18、R19、R20、R21、R22、R23、R24、R25、R26、R27、R28、R29、R30、R31、R32、R33、R34、R35、R36、R37、R38和R39所示的碳原子数1~10的烷基,可列举出:甲基、乙基、丙基、异丙基、丁基、仲丁基、叔丁基、异丁基、戊基、异戊基、叔戊基、己基、环己基、庚基、辛基、壬基、乙基辛基、2-甲氧基乙基、3-甲氧基丙基、4-甲氧基丁基、2-丁氧基乙基、甲氧基乙氧基乙基、甲氧基乙氧基乙氧基乙基、3-甲氧基丁基、2-甲硫基乙基、氟甲基、二氟甲基、三氟甲基、氯甲基、二氯甲基、三氯甲基、溴甲基、二溴甲基、三溴甲基、二氟乙基、三氯乙基、二氯二氟乙基、五氟乙基、七氟丙基、九氟丁基、十氟戊基、十三氟己基、十五氟庚基、十七氟辛基、甲氧基甲基、1,2-环氧乙基、甲氧基乙基、甲氧基乙氧基甲基、甲硫基甲基、乙氧基乙基、丁氧基甲基、叔丁硫基甲基、4-戊烯基氧基甲基、三氯乙氧基甲基、双(2-氯乙氧基)甲基、甲氧基环己基、1-(2-氯乙氧基)乙基、1-甲基-1-甲氧基乙基、乙基二硫乙基、三甲基甲硅烷基乙基、叔丁基二甲基甲硅烷基氧基甲基、2-(三甲基甲硅烷基)乙氧基甲基、叔丁氧基羰基甲基、乙基氧基羰基甲基、乙基羰基甲基、叔丁氧基羰基甲基、丙烯酰氧基乙基、甲基丙烯酰氧基乙基、2-甲基-2-金刚烷基氧基羰基甲基、乙酰乙基、2-甲氧基-1-丙烯基、羟基甲基、2-羟乙基、1-羟乙基、2-羟基丙基、3-羟基丙基、3-羟丁基、4-羟丁基、1,2-二羟乙基等。
作为R11、R12、R13、R14、R15、R16、R17、R18、R19、R20、R21、R22、R23、R24、R26、R27、R28、R29、R35、R36、R37、R38和R39所示的碳原子数1~10的烷氧基,可列举出:甲氧基、乙氧基、丙基氧基、异丙基氧基、丁基氧基、仲丁基氧基、叔丁基氧基、异丁基氧基、戊基氧基、异戊基氧基、叔戊基氧基、己基氧基、环己基氧基、环己基甲基氧基、四氢呋喃基氧基、四氢吡喃基氧基、2-甲氧基乙基氧基、3-甲氧基丙基氧基、4-甲氧基丁基氧基、2-丁氧基乙基氧基、甲氧基乙氧基乙基氧基、甲氧基乙氧基乙氧基乙基氧基、3-甲氧基丁基氧基、2-甲硫基乙基氧基、三氟甲基氧基等。
作为R11、R12、R13、R14、R15、R16、R17、R18、R19、R20、R21、R22、R23、R24、R26、R27、R28、R29、R35、R36、R37、R38和R39所示的碳原子数2~10的酯基,可列举出:甲氧基羰基、乙氧基羰基、异丙基氧基羰基、苯氧基羰基、乙酰氧基、丙酰基氧基、丁酰基氧基、氯乙酰氧基、二氯乙酰氧基、三氯乙酰氧基、三氟乙酰氧基、叔丁基羰基氧基、甲氧基乙酰氧基、苯甲酰基氧基等。
本发明的固化性组合物的自由基聚合性成分(C)以具有环氧基和烯属不饱和基团的化合物(C1)、或碳原子数2~20的醇的丙烯酸酯或者碳原子数2~20的醇的甲基丙烯酸酯(C2)作为必须成分。
作为具有上述环氧基和烯属不饱和基团的化合物(C1),例如可以列举出:环氧丙烯酸酯或环氧甲基丙烯酸酯,具体而言,是现有公知的芳香族环氧树脂、脂环式环氧树脂、脂肪族环氧树脂等与丙烯酸或甲基丙烯酸反应而得到的丙烯酸酯。这些环氧丙烯酸酯或环氧甲基丙烯酸酯中,特别优选的是醇类的缩水甘油醚的丙烯酸酯或甲基丙烯酸酯。
作为上述碳原子数2~20的醇的丙烯酸酯或者碳原子数2~20的醇的甲基丙烯酸酯(C2),可列举出:在分子中具有至少1个羟基的芳香族或脂肪族醇、及其环氧烷加成体与丙烯酸或甲基丙烯酸反应而得到的丙烯酸酯或甲基丙烯酸酯。具体而言,可列举出:丙烯酸-2-乙基己酯、丙烯酸-2-羟基乙酯、丙烯酸-2-羟基丙酯、丙烯酸异戊酯、丙烯酸月桂基酯、丙烯酸硬脂基酯、丙烯酸异辛酯、丙烯酸四氢糠基酯、丙烯酸异冰片基酯、丙烯酸苄基酯、1,3-丁二醇二丙烯酸酯、1,4-丁二醇二丙烯酸酯、1,6-己二醇二丙烯酸酯、二乙二醇二丙烯酸酯、三乙二醇二丙烯酸酯、新戊二醇二丙烯酸酯、聚乙二醇二丙烯酸酯、聚丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、季戊四醇四丙烯酸酯、二季戊四醇六丙烯酸酯、ε-己内酯改性二季戊四醇六丙烯酸酯、甲基丙烯酸-2-乙基己酯、甲基丙烯酸-2-羟基乙酯、甲基丙烯酸-2-羟基丙酯、甲基丙烯酸异戊酯、甲基丙烯酸月桂基酯、甲基丙烯酸硬脂基酯、甲基丙烯酸异辛酯、甲基丙烯酸四氢糠基酯、甲基丙烯酸异冰片基酯、甲基丙烯酸苄基酯、1,3-丁二醇二甲基丙烯酸酯、1,4-丁二醇二甲基丙烯酸酯、1,6-己二醇二甲基丙烯酸酯、二乙二醇二甲基丙烯酸酯、三乙二醇二甲基丙烯酸酯、新戊二醇二甲基丙烯酸酯、聚乙二醇二甲基丙烯酸酯、聚丙二醇二甲基丙烯酸酯、三羟甲基丙烷三甲基丙烯酸酯、季戊四醇四甲基丙烯酸酯、二季戊四醇六甲基丙烯酸酯、ε-己内酯改性二季戊四醇六甲基丙烯酸酯等。需要说明的是,这些丙烯酸酯或甲基丙烯酸酯中,特别优选多元醇的聚丙烯酸酯类或多元醇的聚甲基丙烯酸酯类。
作为上述自由基聚合性成分(C),可以使用除(C1)或(C2)以外的通过利用能量射线照射或加热而活化的自由基聚合引发剂来进行高分子化或交联反应的化合物,例如可列举出:烯丙基氨酯化合物、不饱和聚酯化合物、苯乙烯系化合物等。自由基聚合性成分(C)中的上述(C1)成分和(C2)成分的比例优选50质量%以上。
作为本发明的固化性组合物中的自由基引发剂(D),没有特别限制,可以使用公知的自由基引发剂。例如可以使用:苯乙酮系化合物、苯偶酰系化合物、二苯甲酮系化合物、噻吨酮系化合物等酮系化合物、肟系化合物等。
本发明的固化性组合物中的聚合物(E)选自由如下聚合物组成的组、且重均分子量以聚苯乙烯换算为1000~30000:由上述式(I)所示的单体得到的聚合物、由上述式(II)所示的单体得到的聚合物、由选自上述式(I)所示的单体中的两种以上单体得到的聚合物、由选自上述式(II)所示的单体中的两种以上单体得到的聚合物、及由上述式(I)所示的单体和上述式(II)所示的单体得到的聚合物。
作为上述式(I)中的X所示的碳原子数1~7的烷基,可列举出:甲基、乙基、丙基、异丙基、丁基、仲丁基、叔丁基、异丁基、戊基、异戊基、叔戊基、己基、2-己基、3-己基、环己基、4-甲基环己基、庚基、2-庚基、3-庚基、异庚基、叔庚基等。其中,碳原子数1~4的烷基、或被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上的基团部分取代的碳原子数1~4的烷基从固化性方面考虑而优选。
作为上述式(I)中的X所示的碳原子数1~7的烷氧基,可列举出:甲氧基、乙氧基、丙基氧基、异丙基氧基、丁基氧基、仲丁基氧基、叔丁基氧基、异丁基氧基、戊基氧基、异戊基氧基、叔戊基氧基、己基氧基、2-己基氧基、3-己基氧基、环己基氧基、4-甲基环己基氧基、庚基氧基、2-庚基氧基、3-庚基氧基、异庚基氧基、叔庚基氧基等。其中,碳原子数1~4的烷氧基、或被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上的基团部分取代的碳原子数1~4的烷氧基从固化性方面考虑而优选。
作为上述式(I)中的X所示的碳原子数6~12的芳基,可列举出:苯基、甲基苯基、萘基等。
作为上述式(I)中的X所示的碳原子数6~12的芳氧基,可列举出:苯基氧基、甲基苯基氧基、萘基氧基等。
作为上述式(I)中的X所示的碳原子数6~10的脂环式烃基,可列举出:环己基、甲基环己基、降冰片基、二环戊基、二环辛基、三甲基二环庚基、三环辛基、三环癸基、螺辛基、螺二环戊基、金刚烷基、异冰片基等。
对于这些烷基、烷氧基、芳基、芳氧基和脂环式烃基,这些基团中的氢原子还可以被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上的基团取代。
上述式(I)中,X的一部分被环氧基或氧杂环丁烷基取时,作为式(I)所示的单体,例如可列举出下述式(1)~(3)所示的单体。
此处,式(1)中,R3表示氢原子或碳原子数1~6的烷基,m为1~6的整数。
此处,式(2)中,R4表示氢原子或碳原子数1~6的烷基,n为1~6的整数。
此处,式(3)中,R5表示氢原子或碳原子数1~6的烷基,s为1~6的整数。
上述式(II)中,作为R1所示的卤素原子,可列举出:氟、氯、溴、碘等。
上述式(II)中,作为X’的碳原子数1~7的烷基、碳原子数6~12的芳基或碳原子数6~10的脂环式烃基,可以列举出与上述式(I)相同的基团。
上述式(II)中,X’的一部分被环氧基或氧杂环丁烷基取代时,作为式(II)所示的单体,可列举出下述式(4)~(6)所示的物质。
此处,式(4)中,R1与上述式(II)相同,R6表示氢原子或碳原子数1~6的烷基,t为1~6的整数。
此处,式(5)中,R1与上述式(II)相同,R7表示氢原子或碳原子数1~6的烷基,q为1~6的整数。
此处,式(6)中,R1与上述式(II)相同,R8表示氢原子或碳原子数1~6的烷基,y为1~6的整数。
上述聚合物(E)中,构成聚合物的单体的使用比例如下时粘接性提高故而优选:上述X为被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上的基团取代的碳原子数1~7的烷基、碳原子数6~12的芳基或碳原子数6~10的脂环式烃基时,上述(I)或(II)所示的单体为10~100质量%。
本发明的固化性组合物中,上述阳离子聚合性成分(A)为15~90质量份、优选为50~80质量份、上述阳离子聚合引发剂(B)为1~10质量份、优选为1~6质量份、上述自由基聚合性成分(C)为10~50质量份、优选为10~20质量份、上述自由基聚合引发剂(D)为1~10质量份、优选为1~5质量份、上述聚合物(E)为1~20质量份、优选为5~15质量份。不是上述的配混比例时,有固化物的固化性和密合性变差的担心。需要说明的是,阳离子聚合性成分(A)、自由基聚合性成分(C)、及聚合物(E)的总计为100质量份。
本发明的固化性组合物中,根据需要还可以进一步使用敏化剂和/或敏化助剂。敏化剂是在比阳离子聚合引发剂(B)所示出的最大吸收波长更长的波长处显示出最大吸收,促进基于阳离子聚合引发剂(B)的聚合引发反应的化合物。另外敏化助剂是更进一步促进敏化剂的作用的化合物。
作为敏化剂和敏化助剂,可列举出:蒽系化合物、萘系化合物等。
作为蒽系化合物,例如可列举出下述式(7)所示的物质。
此处,式(7)中,R50和R51各自独立地表示氢原子、碳原子数1~6的烷基或碳原子数2~12的烷氧基烷基,R52表示氢原子或碳原子数1~6的烷基。
列举上述式(7)所示的蒽系化合物的具体例子时,有以下那样的化合物。
例如可列举出:9,10-二甲氧基蒽、9,10-二乙氧基蒽、9,10-二丙氧基蒽、9,10-二异丙氧基蒽、9,10-二丁氧基蒽、9,10-二戊基氧基蒽、9,10-二己基氧基蒽、9,10-双(2-甲氧基乙氧基)蒽、9,10-双(2-乙氧基乙氧基)蒽、9,10-双(2-丁氧基乙氧基)蒽、9,10-双(3-丁氧基丙氧基)蒽、2-甲基-或2-乙基-9,10-二甲氧基蒽、2-甲基-或2-乙基-9,10-二乙氧基蒽、2-甲基-或2-乙基-9,10-二丙氧基蒽、2-甲基-或2-乙基-9,10-二异丙氧基蒽、2-甲基-或2-乙基-9,10-二丁氧基蒽、2-甲基-或2-乙基-9,10-二戊基氧基蒽、2-甲基-或2-乙基-9,10-二己基氧基蒽等。
作为萘系化合物,例如可列举出下述式(8)所示的物质。
此处,式(8)中,R53和R54各自独立地表示碳原子数1~6的烷基。
列举上述式(8)所示的萘系化合物的具体例子时,有以下那样的化合物。
例如可列举出:4-甲氧基-1-萘酚、4-乙氧基-1-萘酚、4-丙氧基-1-萘酚、4-丁氧基-1-萘酚、4-己基氧基-1-萘酚、1,4-二甲氧基萘、1-乙氧基-4-甲氧基萘、1,4-二乙氧基萘、1,4-二丙氧基萘、1,4-二丁氧基萘等。
敏化剂和敏化助剂相对于上述阳离子聚合性成分(A)的使用比例没有特别限定,在不阻碍本发明的目的的范围内大致以通常的使用比例使用即可,例如,相对于上述阳离子聚合性成分(A)的100质量份,敏化剂和敏化助剂分别为0.1~3质量份,从固化性提高的观点出发而优选。
本发明的固化性组合物中,可以根据需要使用硅烷偶联剂。作为硅烷偶联剂,例如可以使用:二甲基二甲氧基硅烷、二甲基二乙氧基硅烷、甲基乙基二甲氧基硅烷、甲基乙基二乙氧基硅烷、甲基三甲氧基硅烷、甲基三乙氧基硅烷、乙基三甲氧基硅烷、乙基三甲氧基硅烷等烷基官能性烷氧基硅烷、乙烯基三氯硅烷、乙烯基三甲氧基硅烷、乙烯基三乙氧基硅烷、烯丙基三甲氧基硅烷等烯基官能性烷氧基硅烷、3-甲基丙烯酰氧基丙基三乙氧基硅烷、3-甲基丙烯酰氧基丙基三甲氧基硅烷、3-甲基丙烯酰氧基丙基甲基二乙氧基硅烷、3-甲基丙烯酰氧基丙基甲基二甲氧基硅烷、2-甲基丙烯酰氧基丙基三甲氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅烷、γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3,4-环氧环己基)乙基三甲氧基硅烷等环氧官能性烷氧基硅烷、N-β(氨基乙基)-γ-氨基丙基三甲氧基硅烷、γ-氨基丙基三乙氧基硅烷、N-苯基-γ-氨基丙基三甲氧基硅烷等氨基官能性烷氧基硅烷、γ-巯基丙基三甲氧基硅烷等巯基官能性烷氧基硅烷、四异丙氧基钛、四正丁氧基钛等烷氧基钛类、双(甘醇酸辛酯)钛酸二辛氧基酯,双(乙酰乙酸乙酯)钛酸二异丙氧基酯等钛螯合物类、四乙酰丙酮锆、三丁氧基单乙酰丙酮锆等锆螯合物类、三丁氧基单硬脂酸锆等锆酰化物类、甲基三异氰酸酯硅烷等异氰酸酯硅烷类等。
上述硅烷偶联剂的用量没有特别限定,通常相对于固化性组合物中的固体物的总量100质量份,为0.01~20质量份的范围。
本发明的固化性组合物中,通过根据需要使用热塑性有机聚合物,从而还能改善固化物的特性。作为热塑性有机聚合物,例如可列举出:聚苯乙烯、聚甲基丙烯酸甲酯、甲基丙烯酸甲酯-丙烯酸乙酯共聚物、甲基丙烯酸甲酯-甲基丙烯酸缩水甘油酯共聚物、聚(甲基)丙烯酸、苯乙烯-(甲基)丙烯酸共聚物、(甲基)丙烯酸-甲基丙烯酸甲酯共聚物、(甲基)丙烯酸缩水甘油酯-聚(甲基)丙烯酸甲酯共聚物、聚乙烯醇缩丁醛、纤维素酯、聚丙烯酰胺、饱和聚酯等。
本发明的固化性组合物中,根据需要可以进一步使用:紫外线吸收剂;在常温下为非活性,通过加热至规定温度/光照射/酸等使保护基团脱离、经活化从而显示出紫外线吸收能力的化合物。
另外,在不损害本发明的效果的范围内可以根据需要添加多元醇、无机填料、有机填料、颜料、染料等着色剂、消泡剂、增稠剂、表面活性剂、流平剂、阻燃剂、触变剂、稀释剂、增塑剂、稳定剂、阻聚剂、紫外线吸收剂、抗氧化剂、抗静电剂、流动调节剂、粘接促进剂等各种树脂添加物等。
本发明的固化性组合物中,没有特别限制,可以使用通常使用的能溶解或分散上述(A)、(B)、(C)、(D)和(E)各成分的溶剂。作为溶剂,例如可列举出:甲乙酮、甲戊酮、二乙酮、丙酮、甲基异丙基酮、甲基异丁基酮、环己酮、2-庚酮等酮类;乙醚、二氧杂环己烷、四氢呋喃、1,2-二甲氧基乙烷、1,2-二乙氧基乙烷、丙二醇单甲醚、二丙二醇二甲基醚等醚系溶剂;乙酸甲酯、乙酸乙酯、乙酸正丙酯、乙酸异丙酯、乙酸正丁酯、乙酸环己酯、乳酸乙酯、琥珀酸二甲酯、Texanol等酯系溶剂;乙二醇单甲醚、乙二醇单乙醚等溶纤剂系溶剂;甲醇、乙醇、异丙醇或正丙醇、异丁醇或正丁醇、戊醇等醇系溶剂;乙二醇单甲醚乙酸酯、乙二醇单乙醚乙酸酯、丙二醇-1-单甲醚-2-乙酸酯(PGMEA),二丙二醇单甲醚乙酸酯、3-甲氧基丁基乙酸酯、乙氧基乙基丙酸酯等醚酯系溶剂;苯、甲苯、二甲苯等BTX系溶剂;己烷、庚烷、辛烷、环己烷等脂肪族烃系溶剂;松节油、D-柠檬烯、蒎烯等萜烯系烃油;矿油精、Swasol#310(CosmoMatsuyama Oil Co.,Ltd.制),SOLVESSO#100(Exxon Mobil Corporation)等链烷烃系溶剂;四氯化碳、氯仿、三氯乙烯、二氯甲烷、1,2-二氯乙烷等卤代脂肪族烃系溶剂;氯苯等卤代芳香族烃系溶剂;碳酸亚丙酯、卡必醇系溶剂、苯胺、三乙胺、吡啶、乙酸、乙腈、二硫化碳、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺、N-甲基吡咯烷酮、二甲基亚砜、水等。这些溶剂可以使用1种或2种以上的混合溶剂。
本发明的固化性组合物使固化性、粘接性、液体保存稳定性提高,因此水分量优选为5质量份以下、进一步优选为3质量份以下。水分过多时有发生白浊或成分析出的担心,故而不优选。
本发明的固化性组合物可利用辊涂机、帘式涂布机、各种印刷、浸渍等公知的手段涂布于支撑基体上。另外,也可以暂时施于薄膜等支撑基体上之后转印到其它支撑基体上,其应用方法没有特别限制。
作为上述支撑基体的材料,没有特别限制,可以使用通常使用的材料,例如可列举出:玻璃等无机材料;二乙酰纤维素、三乙酰纤维素(TAC),丙酰基纤维素、丁酰基纤维素、乙酰丙酰基纤维素、硝基纤维素等纤维素酯;聚酰胺;聚酰亚胺;聚氨酯;环氧树脂;聚碳酸酯;聚对苯二甲酸乙二醇酯、聚萘二甲酸乙二醇酯、聚对苯二甲酸丁二醇酯、聚对苯二甲酸-1,4-环己烷二甲醇酯、聚亚乙基-1,2-二苯氧基乙烷-4,4’-二羧酸酯、聚对苯二甲酸丁二醇酯等聚酯;聚苯乙烯;聚乙烯、聚丙烯、聚甲基戊烯等聚烯烃;聚乙酸乙烯酯、聚氯乙烯、聚氟乙烯等乙烯基化合物;聚甲基丙烯酸甲酯、聚丙烯酸酯等丙烯酸类树脂;聚碳酸酯;聚砜;聚醚砜;聚醚酮;聚醚酰亚胺;聚氧乙烯、降冰片烯树脂、环烯烃聚合物(COP)等高分子材料。需要说明的是,还可以对上述支撑基体进行电晕放电处理、火焰处理、紫外线处理、高频射线处理、辉光放电处理、活性等离子体处理、激光处理等表面活化处理。
利用能量射线的照射使本发明的固化性组合物固化的方法中,作为能量射线,可以列举出:紫外线、电子射线、X射线、放射射线、高频射线等,在经济上,最优选紫外线。作为紫外线的光源,可列举出:紫外线激光、汞灯、氙激光、金属卤化物灯等。
利用加热使本发明的固化性组合物固化的方法中的条件是在70~250℃下1~100分钟。可以在预烘焙(PAB;Pre applied bake)后加压并进行后烘焙(PEB;Post exposurebake),或还可以在不同的多阶段的温度下进行烘焙。加热条件根据各成分的种类和配混比例而不同,例如在70~180℃下用干燥机时为5~15分钟、用热板时为1~5分钟。然后,为了使涂膜固化,可以通过在180~250℃、优选在200~250℃下、用干燥机时进行30~90分钟、用热板时进行5~30分钟加热处理而得到固化膜。
作为本发明的固化性组合物或其固化物的具体的用途,可以列举出:粘接剂、眼镜、摄像用透镜所代表的光学材料、涂料、涂布剂、衬里剂、墨、抗蚀剂、液态抗蚀剂、印刷版、彩电、PC监视器、便携信息终端、数码相机、有机EL、触摸屏等显示元件、绝缘清漆、绝缘片、层叠板、印刷基板、半导体装置用/LED包装用/液晶注入口用/有机EL用/光元件用/电绝缘用/电子部件用/分离膜用等密封剂、成形材料、油灰、玻璃纤维浸渗剂、填隙剂、半导体用/太阳能电池用等钝化膜、层间绝缘膜、保护膜、液晶显示装置的背光中使用的棱镜透镜薄片、投影电视等的屏幕中使用的菲涅尔透镜薄片、柱状透镜薄片等透镜薄片的透镜部、或使用这样的片的背灯等、微透镜等光学透镜、光学元件、光连接器、光波导、光学的造形用铸塑剂等。
作为本发明的显示装置,可列举出:在透明支撑体上根据需要设置有底涂层、防反射层、偏光元件层、相位差层、双折射率层、光散射层、硬涂层、润滑层、保护层等各层的装置,各层可以使用由本发明的固化物构成的薄膜。
实施例
以下,列举实施例等对本发明进行进一步详细地说明,但本发明不受这些实施例的限定。
[实施例1~19、比较例1~8]
以下述[表1]~[表6]所示的配混充分地混合各成分,分别得到实施例1~19的固化性组合物和比较例1~8的固化性组合物。需要说明的是,实施例和比较例的单位为质量份。
作为阳离子聚合性成分(A),使用下述化合物。
化合物(A1-1):新戊二醇二缩水甘油醚
化合物(A1-2):1,4-丁二醇二缩水甘油醚
化合物(A2-1):ARON OXETANE OXT-221(东亚合成株式会社制)
化合物(A3-1):双酚型二缩水甘油醚
化合物(A3-2):TECHMORE VG3101(芳香族3官能环氧:Printech Co.,Ltd.制)
作为阳离子聚合引发剂(B),使用下述化合物(B-1)。
化合物B-1:下述式(9)所示的化合物和下述式(10)所示的化合物的混合物的碳酸亚丙酯50%溶液
作为自由基聚合性成分(C),使用下述化合物。
化合物(C1-1):环氧酯M-600A(共荣社化学株式会社制)
化合物(C1-2):环氧酯70PA(共荣社化学株式会社制)
化合物(C2-1):1,6-己二醇二丙烯酸酯
作为自由基聚合引发剂(D),使用下述化合物(D-1)。
化合物(D-1):IRGACURE 184(BASF公司制)
作为聚合物(E),使用下述化合物(E-1)和(E-2)。
聚合物(E-1):甲基丙烯酸甲酯75质量份和甲基丙烯酸缩水甘油酯25的共聚物(重均分子量7000)
作为聚合物(E’),使用下述化合物(E’-1)和(E’-2)。
化合物(E’-1):甲基丙烯酸甲酯75质量份和甲基丙烯酸缩水甘油酯25的共聚物(重均分子量800)
化合物(E’-2:甲基丙烯酸甲酯75质量份和甲基丙烯酸缩水甘油酯25的共聚物(重均分子量35000)
对于得到的实施例1~19和比较例1~8的各固化性组合物,依据下述步骤进行了玻璃化转变温度(Tg)、弹性模量和密合性的评价。将结果一并示于[表1]~[表6]。
(玻璃化转变温度和弹性模量)
对于得到的实施例1~19和比较例1~8的各固化性组合物,分别利用棒涂机涂布在聚对苯二甲酸乙二醇酯(PET)薄膜上成30μm的厚度,使用金属卤化物灯照射3000mJ/cm2的能量。24小时后从薄膜上取出粘接剂固化物,使用Hitachi High-TechnologiesCorporation制的粘弹性测定装置(DMA7100)测定了Tg和在80℃下的弹性模量。
(粘度)
对于得到的实施例1~19和比较例1~8的固化性组合物,分别利用E型粘度计测定了在25℃下的粘度。
(密合性:COP)
分别将上述得到的实施例1~19和比较例1~8的固化性组合物涂布在一张电晕处理PMMA薄膜(住友化学株式会社制:Technology 125S001)上,然后使用层压机与另一张实施有电晕放电处理的COP(环烯烃聚合物、Zeon Corporation株式会社制:型号Zeonor Film14-060)薄膜贴合,使用无电极紫外光灯隔着COP薄膜照射相当于1000mJ/cm2的光进行粘接而得到试验片。进行了得到的试验片的90度剥离试验。
[表1]
[表2]
[表3]
[表4]
[表5]
[表6]
由[表1]~[表6]可知,对于本发明的固化性组合物,固化物的玻璃化转变温度高和密合性优异。
Claims (7)
1.一种固化性组合物,其特征在于,其以阳离子聚合性成分(A)和自由基聚合性成分(C)和聚合物(E)的总计为100质量份的方式含有:所述阳离子聚合性成分(A)15~90质量份、阳离子聚合引发剂(B)1~10质量份、所述自由基聚合性成分(C)10~50质量份、自由基聚合引发剂(D)1~10质量份、及所述聚合物(E)1~20质量份,所述聚合物(E)的重均分子量为1000~30000,所述聚合物(E)选自由下述聚合物组成的组:由下述式(I)所示的单体得到的聚合物、由下述式(II)所示的单体得到的聚合物、由选自所述式(I)所示的单体中的两种以上单体得到的聚合物、由选自所述式(II)所示的单体中的两种以上单体得到的聚合物、以及由所述式(I)所示的单体和所述式(II)所示的单体得到的聚合物,
式(I)中,X为碳原子数1~7的烷基、碳原子数1~7的烷氧基、碳原子数6~12的芳基、碳原子数6~12的芳氧基或碳原子数6~10的脂环式烃基、或这些基团中的氢原子被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上基团取代的基团,
式(II)中,R1表示氢原子、甲基或卤素原子,X’为碳原子数1~7的烷基、碳原子数6~12的芳基或碳原子数6~10的脂环式烃基、或这些基团中的氢原子被选自由环氧基、氧杂环丁烷基、羟基和羧基组成的组中的1种以上基团取代的基团,
所述阳离子聚合性成分(A)将多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)、及氧杂环丁烷化合物(A2)作为必须成分,
相对于所述阳离子聚合性成分(A)、所述自由基聚合性成分(C)、及所述聚合物(E)的总计为100质量份,所述多元醇的缩水甘油化物或多元醇环氧烷加成物的缩水甘油化物(A1)为35~65质量份,
所述自由基聚合性成分(C)将具有环氧基和烯属不饱和基团的化合物(C1)、或碳原子数2~20的多元醇的丙烯酸酯或者碳原子数2~20的多元醇的甲基丙烯酸酯(C2)作为必须成分。
2.根据权利要求1所述的固化性组合物,其中,作为所述阳离子聚合性成分(A),还含有芳香族环氧化合物(A3)。
3.根据权利要求2所述的固化性组合物,其中,所述芳香族环氧化合物(A3)为多官能芳香族环氧化合物。
4.根据权利要求1所述的固化性组合物,其中,所述聚合物(E)是由所述式(I)所示的单体和所述式(II)所示的单体得到的聚合物,所述式(I)中的X为碳原子数6~12的芳基,所述式(II)中的X’为碳原子数1~7的烷基,所述烷基被环氧基取代。
5.一种固化性组合物的固化方法,其特征在于,对权利要求1~4中任一项所述的固化性组合物照射活性能量射线。
6.一种固化性组合物的固化方法,其特征在于,对权利要求1~4中任一项所述的固化性组合物进行加热。
7.一种固化物,其特征在于,其是权利要求1~4中任一项所述的固化性组合物的固化物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016-069796 | 2016-03-30 | ||
JP2016069796A JP6993766B2 (ja) | 2016-03-30 | 2016-03-30 | 硬化性組成物、硬化物の製造方法、およびその硬化物 |
PCT/JP2017/013288 WO2017170883A1 (ja) | 2016-03-30 | 2017-03-30 | 硬化性組成物、硬化物の製造方法、およびその硬化物 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108884299A true CN108884299A (zh) | 2018-11-23 |
Family
ID=59965991
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201780020027.9A Pending CN108884299A (zh) | 2016-03-30 | 2017-03-30 | 固化性组合物、固化物的制造方法、及其固化物 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP6993766B2 (zh) |
KR (1) | KR102356381B1 (zh) |
CN (1) | CN108884299A (zh) |
TW (1) | TWI788285B (zh) |
WO (1) | WO2017170883A1 (zh) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015068454A1 (ja) * | 2013-11-07 | 2015-05-14 | 積水化学工業株式会社 | 有機エレクトロルミネッセンス表示素子用封止剤 |
CN104745104A (zh) * | 2013-12-25 | 2015-07-01 | 东亚合成株式会社 | 光固化性粘接剂组合物、偏光板及其制造方法、光学构件以及液晶显示装置 |
JP2015179210A (ja) * | 2014-03-19 | 2015-10-08 | 富士フイルム株式会社 | 重合性非線形光学材料、非線形光学膜、光学素子、光変調素子、及び非線形光学膜の製造方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI251123B (en) * | 1999-09-17 | 2006-03-11 | Hitachi Chemical Co Ltd | Photosensitive resin composition, photosensitive element using the resin composition, method of manufacturing resist pattern, and method of manufacturing printed wiring board |
JP4667145B2 (ja) * | 2004-07-22 | 2011-04-06 | 三井化学株式会社 | 光硬化型樹脂組成物及びそれからなるプラスチック用樹脂組成物 |
JP5296575B2 (ja) | 2009-03-06 | 2013-09-25 | 住友化学株式会社 | 光硬化性接着剤組成物、偏光板とその製造法、光学部材及び液晶表示装置 |
JP5240380B1 (ja) * | 2011-07-05 | 2013-07-17 | Jsr株式会社 | 樹脂組成物、重合体、硬化膜および電子部品 |
JP6103687B2 (ja) | 2012-11-22 | 2017-03-29 | チェイル インダストリーズ インコーポレイテッド | 偏光板用接着剤組成物 |
JP6075237B2 (ja) | 2013-07-12 | 2017-02-08 | 東亞合成株式会社 | プラスチック製フィルム又はシート用活性エネルギー線硬化型接着剤組成物 |
JP6164609B2 (ja) | 2013-08-23 | 2017-07-19 | 東亞合成株式会社 | 光硬化性接着剤組成物、偏光板とその製造法、光学部材及び液晶表示装置 |
JP6284721B2 (ja) | 2013-08-26 | 2018-02-28 | 株式会社Adeka | エネルギー線感受性組成物 |
JP6337523B2 (ja) | 2014-03-07 | 2018-06-06 | 東洋インキScホールディングス株式会社 | 活性エネルギー線重合性樹脂組成物および積層体 |
JP6292400B2 (ja) | 2014-06-06 | 2018-03-14 | 東亞合成株式会社 | プラスチック製フィルム又はシート用活性エネルギー線硬化型接着剤組成物 |
-
2016
- 2016-03-30 JP JP2016069796A patent/JP6993766B2/ja active Active
-
2017
- 2017-03-30 WO PCT/JP2017/013288 patent/WO2017170883A1/ja active Application Filing
- 2017-03-30 KR KR1020187030441A patent/KR102356381B1/ko active IP Right Grant
- 2017-03-30 TW TW106110862A patent/TWI788285B/zh active
- 2017-03-30 CN CN201780020027.9A patent/CN108884299A/zh active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015068454A1 (ja) * | 2013-11-07 | 2015-05-14 | 積水化学工業株式会社 | 有機エレクトロルミネッセンス表示素子用封止剤 |
CN104745104A (zh) * | 2013-12-25 | 2015-07-01 | 东亚合成株式会社 | 光固化性粘接剂组合物、偏光板及其制造方法、光学构件以及液晶显示装置 |
JP2015179210A (ja) * | 2014-03-19 | 2015-10-08 | 富士フイルム株式会社 | 重合性非線形光学材料、非線形光学膜、光学素子、光変調素子、及び非線形光学膜の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2017170883A1 (ja) | 2017-10-05 |
TW201803909A (zh) | 2018-02-01 |
JP6993766B2 (ja) | 2022-01-14 |
KR102356381B1 (ko) | 2022-01-26 |
JP2017179163A (ja) | 2017-10-05 |
TWI788285B (zh) | 2023-01-01 |
KR20180132724A (ko) | 2018-12-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104955866B (zh) | 阳离子聚合性组合物 | |
CN109312055A (zh) | 固化性组合物、固化物的制造方法、及其固化物 | |
CN107075082A (zh) | 组合物 | |
KR102272147B1 (ko) | 경화성 조성물, 경화물의 제조 방법, 및 그 경화물 | |
CN110114376A (zh) | 固化性组合物、固化物的制造方法、其固化物、及使用其的粘接剂 | |
CN108884297A (zh) | 固化性组合物、固化物的制造方法、及其固化物 | |
CN108699320A (zh) | 固化性组合物、固化物的制造方法、及其固化物 | |
CN108884299A (zh) | 固化性组合物、固化物的制造方法、及其固化物 | |
CN107075083A (zh) | 组合物 | |
CN108779321A (zh) | 固化性组合物、固化物的制造方法、及其固化物 | |
JP6817702B2 (ja) | 硬化性組成物、その硬化方法、これにより得られる硬化物および接着剤 | |
JP6949458B2 (ja) | 硬化性組成物、硬化物の製造方法、およびその硬化物 | |
CN108884298B (zh) | 固化性组合物、固化物的制造方法、及其固化物 | |
TW201827517A (zh) | 硬化性組成物、其硬化方法、藉其所得之硬化物 | |
TWI814894B (zh) | 組成物、含有其之接著劑、其硬化物及其製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |