CN108864865A - A kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint and its preparation method and application - Google Patents
A kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint and its preparation method and application Download PDFInfo
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- CN108864865A CN108864865A CN201810551172.6A CN201810551172A CN108864865A CN 108864865 A CN108864865 A CN 108864865A CN 201810551172 A CN201810551172 A CN 201810551172A CN 108864865 A CN108864865 A CN 108864865A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paints, including following parts by weight ingredient：10~30 parts of deionized water；10~25 parts of acrylic emulsion；10~25 parts of polyaminoester emulsion；5~20 parts of talcum powder；5~25 parts of titanium dioxide；5~25 parts of ceramic powder；5~25 parts of auxiliary agent；Cerium -5~25 parts of aluminium codope zinc oxide.Cerium-aluminium codope zinc oxide generates surface-active under photocatalysis as rare earth mixing with nano particle, absorb the moisture in air, the attachment of moisture of absorption in plate surface and is decomposed into moisture, cooled down or reflect the effectiveness that appropriate infrared ray carries out reflective insulation, therefore generated and reach best heat dissipation, energy conservation emission reduction effect.
Description
Technical field
It is aqueous roasting that the present invention relates to functional coating fields more particularly to a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving
Paint and preparation method thereof.
Background technique
At present heat-insulating and energy-saving functional material application only applied in general coating, and mainly by glass bead retroreflective come
Realize heat insulating function.In functional water-based stoving paint coating, heat-insulating and energy-saving water-based stoving paint is still in starting and develops development phase,
The present invention is intended to provide a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint.
Summary of the invention
In view of this, the present invention is intended to provide a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint.
A kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, including following parts by weight ingredient：Deionized water 10
~30 parts；10~25 parts of acrylic emulsion；10~25 parts of polyaminoester emulsion；5~20 parts of talcum powder；5~25 parts of titanium dioxide；Ceramics
5~25 parts of powder；5~25 parts of auxiliary agent；Cerium -5~25 parts of aluminium codope zinc oxide.
Preferably, the auxiliary agent be surfactant, dispersing agent, defoaming agent, coalescing agent at least one.
Preferably, including following parts by weight ingredient:20 parts of deionized water；18 parts of polyaminoester emulsion；Acrylic emulsion 17
Part；13 parts of talcum powder；15 parts of titanium dioxide；15 parts of ceramic powder；12 parts of auxiliary agent；Cerium -10 parts of aluminium codope zinc oxide.
The present invention also provides a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, including it is following
Step：
S1：It is separately added into deionized water (10~30 parts) into reaction kettle, is stirred using blender；
S2：Titanium dioxide (5~25 parts) and talcum powder (5~20 parts) are added into reaction kettle, is stirred using blender；
S3：Acrylic emulsion (10~25 parts), polyaminoester emulsion (10~25 parts) and ceramic powder (5 are added into reaction kettle
~25 parts), it is stirred using blender；
S4：Auxiliary agent (5~25 parts) and cerium-aluminium codope zinc oxide (5~25 parts) are added into reaction kettle, uses blender
Stirring.
Preferably, the step S1The mixing time of middle blender is 5min, revolving speed 1500r/min.
Preferably, the step S2The mixing time of middle blender is 10min, revolving speed 1500r/min.
Preferably, the step S3The mixing time of middle blender is 15min, revolving speed 1500r/min.
Preferably, the step S4The mixing time of middle blender is 10min, revolving speed 1500r/min.
Cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint is applied to sheet metal or building board material.
Compared with prior art, the present invention having the following advantages that and beneficial effect：
Cerium-aluminium codope zinc oxide generates surface-active under photocatalysis as rare earth mixing with nano particle, absorbs
The attachment of moisture of absorption in plate surface and is decomposed moisture by the moisture in air, is cooled down or reflects appropriate infrared ray
The effectiveness of reflective insulation is carried out, therefore generates and reaches best heat dissipation, energy conservation emission reduction effect.
Cerium-aluminium codope zinc oxide is cerium-aluminium codope zinc oxide of the prior art.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, including following parts by weight at
Point：30 parts of deionized water；10 parts of acrylic emulsion；10 parts of polyaminoester emulsion；20 parts of talcum powder；5 parts of titanium dioxide；Ceramic powder 25
Part；5 parts of surfactant；Cerium -5 parts of aluminium codope zinc oxide.
Cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, includes the following steps in the present embodiment：
S1：Deionized water is added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 5min；
S2：Titanium dioxide and talcum powder are added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 10min；
S3：Acrylic emulsion, polyaminoester emulsion and ceramic powder are added into reaction kettle, is stirred using blender, revolving speed
1500 turns, stirring 15min；
S4：Surfactant and cerium-aluminium codope zinc oxide are added into reaction kettle, is stirred using blender, revolving speed
1500 turns, stirring 10min.
Embodiment 2
The present embodiment provides a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, including following parts by weight at
Point：10 parts of deionized water；25 parts of acrylic emulsion；25 parts of polyaminoester emulsion；5 parts of talcum powder；25 parts of titanium dioxide；5 parts of ceramic powder；
8 parts of coalescing agent, 9 parts of defoaming agent；8 parts of dispersing agent；Cerium -25 parts of aluminium codope zinc oxide.
Cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, includes the following steps in the present embodiment：
S1：Deionized water is added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 5min；
S2：Titanium dioxide and talcum powder are added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 10min；
S3：Acrylic emulsion, polyaminoester emulsion and ceramic powder are added into reaction kettle, is stirred using blender, revolving speed
1500 turns, stirring 15min；
S4：Be added into reaction kettle coalescing agent, defoaming agent, dispersing agent and cerium-aluminium codope zinc oxide, use stirring
Machine stirring, 1500 turns of revolving speed, stirring 10min.
Embodiment 3
The present embodiment provides a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, including following parts by weight at
Point：20 parts of deionized water；18 parts of polyaminoester emulsion；17 parts of acrylic emulsion；13 parts of talcum powder；15 parts of titanium dioxide；Ceramic powder 15
Part；8 parts of coalescing agent；4 parts of dispersing agent；Cerium -10 parts of aluminium codope zinc oxide.
Cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, includes the following steps in the present embodiment：
S1：Deionized water is added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 5min；
S2：Titanium dioxide and talcum powder are added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 10min；
S3：Acrylic emulsion, polyaminoester emulsion and ceramic powder are added into reaction kettle, is stirred using blender, revolving speed
1500 turns, stirring 15min；
S4：Coalescing agent, dispersing agent and cerium-aluminium codope zinc oxide are added into reaction kettle, is stirred using blender, turns
1500 turns of speed, stirring 10min.
Embodiment 4
The present embodiment provides a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, including following parts by weight at
Point：20 parts of deionized water；18 parts of polyaminoester emulsion；17 parts of acrylic emulsion；13 parts of talcum powder；15 parts of titanium dioxide；Ceramic powder 15
Part；8 parts of coalescing agent；4 parts of dispersing agent；Cerium -25 parts of aluminium codope zinc oxide.
Cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, includes the following steps in the present embodiment：
S1：Deionized water is added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 5min；
S2：Titanium dioxide and talcum powder are added into reaction kettle, is stirred using blender, 1500 turns of revolving speed, stirring 10min；
S3：Acrylic emulsion, polyaminoester emulsion and ceramic powder are added into reaction kettle, is stirred using blender, revolving speed
1500 turns, stirring 15min；
S4：Coalescing agent, dispersing agent and cerium-aluminium codope zinc oxide are added into reaction kettle, is stirred using blender, turns
1500 turns of speed, stirring 10min.
Comparative example
This comparative example provides a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, including following parts by weight at
Point：20 parts of deionized water；18 parts of polyaminoester emulsion；17 parts of acrylic emulsion；13 parts of talcum powder；15 parts of titanium dioxide；Ceramic powder 15
Part；8 parts of coalescing agent；4 parts of dispersing agent.
Embodiment 1-4 and the cerium of comparative example-uniform showering of aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint are being built
It builds above plate, high-temperature baking 1h is carried out in 200 DEG C of oven, test the temperature between plate test architecture plate and coating
Degree, it is as shown in the table to obtain result.
| Project | Surface temperature/DEG C | Degree of adhesion |
| Embodiment 1 | 161 | Securely |
| Embodiment 2 | 167 | Securely |
| Embodiment 3 | 141 | Securely |
| Embodiment 4 | 155 | Securely |
| Comparative example | 195 | It is bubbled |
The above are wherein specific implementations of the invention, and the description thereof is more specific and detailed, but can not therefore manage
Solution is limitations on the scope of the patent of the present invention.For those of ordinary skill in the art, present inventive concept is not being departed from
Under the premise of, various modifications and improvements can be made, these obvious alternative forms all belong to the scope of protection of the present invention.
Claims (9)
1. a kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, which is characterized in that including following parts by weight ingredient：
2. cerium according to claim 1-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, which is characterized in that described to help
Agent be surfactant, dispersing agent, defoaming agent, coalescing agent at least one.
3. cerium according to claim 1-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, which is characterized in that including with
Lower parts by weight ingredient:
4. a kind of cerium as described in claim 1-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, feature exist
In including the following steps：
S1：Deionized water (10~30 parts) are added into reaction kettle, are stirred using blender；
S2：Titanium dioxide (5~25 parts) and talcum powder (5~20 parts) are added into reaction kettle, is stirred using blender；
S3：Acrylic emulsion (10~25 parts), polyaminoester emulsion (10~25 parts) and ceramic powder (5~25 are added into reaction kettle
Part), it is stirred using blender；
S4：Auxiliary agent (5~25 parts) and cerium-aluminium codope zinc oxide (5~25 parts) are added into reaction kettle, is stirred using blender.
5. cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, feature exist according to claim 4
In the step S1The mixing time of middle blender is 5min, revolving speed 1500r/min.
6. cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, feature exist according to claim 5
In the step S2The mixing time of middle blender is 10min, revolving speed 1500r/min.
7. cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, feature exist according to claim 6
In the step S3The mixing time of middle blender is 15min, revolving speed 1500r/min.
8. cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint preparation method, feature exist according to claim 7
In the step S4The mixing time of middle blender is 10min, revolving speed 1500r/min.
9. a kind of application of cerium as described in claim 1-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint, which is characterized in that
The cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint is applied to sheet metal or building board material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810551172.6A CN108864865A (en) | 2018-05-31 | 2018-05-31 | A kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810551172.6A CN108864865A (en) | 2018-05-31 | 2018-05-31 | A kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint and its preparation method and application |
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| CN108864865A true CN108864865A (en) | 2018-11-23 |
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| CN201810551172.6A Pending CN108864865A (en) | 2018-05-31 | 2018-05-31 | A kind of cerium-aluminium codope zinc oxide heat-insulating and energy-saving water-based stoving paint and its preparation method and application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114806306A (en) * | 2022-06-11 | 2022-07-29 | 方贵龙 | Zirconium-gadolinium co-doped zinc oxide self-cleaning film and preparation method and application thereof |
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2018
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| CN107177260A (en) * | 2017-07-18 | 2017-09-19 | 广东易置新材料科技有限公司 | A kind of cerium aluminium codope zinc oxide negative ion paint and preparation method and application |
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| CN114806306A (en) * | 2022-06-11 | 2022-07-29 | 方贵龙 | Zirconium-gadolinium co-doped zinc oxide self-cleaning film and preparation method and application thereof |
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