CN105838180A - Waterborne fireproof heat-insulation paint for wooden building and preparation method thereof - Google Patents

Waterborne fireproof heat-insulation paint for wooden building and preparation method thereof Download PDF

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Publication number
CN105838180A
CN105838180A CN201610203777.7A CN201610203777A CN105838180A CN 105838180 A CN105838180 A CN 105838180A CN 201610203777 A CN201610203777 A CN 201610203777A CN 105838180 A CN105838180 A CN 105838180A
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parts
water
wood construction
waterborne
insulating moulding
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CN201610203777.7A
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冯淼
冯超
冯晶
夏黎山轻
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Jiangsu Lyuneng Environmental Protection Integrated Wooden House Co Ltd
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Jiangsu Lyuneng Environmental Protection Integrated Wooden House Co Ltd
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Priority to CN201610203777.7A priority Critical patent/CN105838180A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention specifically relates to a waterborne fireproof heat-insulation paint for a wooden building and a preparation method thereof, belonging to the technical field of functional paints. The waterborne fireproof heat-insulation paint mainly comprises the following raw materials by weight: 25 to 30 parts of silicon-acrylate emulsion, 10 to 15 parts of ammonium polyphosphate, 6 to 8 parts of melamine, 3 to 6 parts of pentaerythritol, 10 to 15 parts of rutile titanium dioxide, 3 to 6 parts of hollow glass beads, 2 to 5 parts of sericite, 2.5 to 6 parts of hollow ceramic beads, 2 to 4 parts of nanometer far-infrared ceramic powder, 4 to 7 parts of diatomite, 0.5 to 1 part of a waterborne thickening agent, 0.2 to 0.4 part of a waterborne antifoaming agent, 0.4 to 0.8 part of a waterborne wetting dispersant, 0.1 to 0.3 part of a waterborne mildew inhibitor, 1 to 2 parts of a film forming aid and 20 to 30 parts of deionized water. The preparation method is simple; and the prepared paint has heat resistance, heat insulation performance, mildew resistance, high adhesion, good ageing resistance and a plurality of purposes, is green and environment friendly, exerts beneficial effect on flame retardation of wooden buildings, heating caused by strong radiation of sunlight, prevention of losing of indoor heat to outdoor space, etc., effectively protects the buildings and saves energy.

Description

A kind of Wood construction water-based fireproof insulating moulding coating and preparation method thereof
Technical field
The invention belongs to functional paint technical field, particularly to a kind of water-based fireproof insulating moulding coating and preparation thereof Method.
Background technology
The easy ignition of timber buildings, the flameproof protection to timber structure, essence is the fire prevention of wood structures Protection.People are studying always and are seeking the approach that protection wood structure building is invaded and harassed effectively from fire. The method used mainly has clay facing flameproof protection, timber lath and plaster or steel wire plastering facing flameproof protection, water Cement mortar or concrete fireproof protection, the fire-proof board flameproof protection etc. to wood component, but its protected effect The most very good with the suitability.In existing engineering, most widely used, the suitability is the strongest, construction is the most convenient Still belong to fireproof coating.In daily commercial Application, APP, tripolycyanamide, tetramethylolmethane constitute fire retardant Cording has good flameproof effect.
Additionally, building energy consumption account for the whole nation energy consumption 35%, country new building has been taken mandatory every Hot Insulation, using heat insulating coatings that the roof of building, exterior wall are carried out application is that current emphasis pushes away One of wide power-economizing method.At present, the research of solvent type heat insulation coating is more, but in recent years, water-borne heat-insulating is coated with Material is subject to people's attention owing to it has the feature of environmental protection.
The Water-based thermal insulation coating of industrial application is difficult to combine obstruct, reflection, radiation effect, and becomes This height, seriously hinders the effect of insulating moulding coating.It is molten that cenosphere is that attritive powder suspends in high temperature gas flow Melt or after melt is atomized in high pressure draught, for reflection-type functional stuffing.Sericite can be filled out as body constitution Material increases the richness of paint film, it is possible to prevents ultraviolet from penetrating and changes weatherability and the thermostability of film, can To stop visible ray, also can shielding ultraviolet rays and infra-red radiation, it is also possible to stop microwave.Nano-far-infrared is made pottery Porcelain powder is radial pattern functional stuffing;Kieselguhr is isolation-type functional stuffing.The compound use of these materials, can To be effectively thermally shielded in terms of intercepting, reflect, radiate three.Therefore, how to utilize APP, Tripolycyanamide, tetramethylolmethane constitute flame-retardant system and these thermal insulating fillings above-mentioned carry out excellent the preventing of processability Fire insulating moulding coating has become a difficult problem for prior art.
Summary of the invention
In order to solve the problems referred to above that prior art exists, the invention provides a kind of Wood construction water-based fireproof every Hot coating and preparation method thereof, with silicone acrylic emulsion as film forming matter, with carbonifying catalyst APP, Foaming agent tripolycyanamide, carbon forming agent tetramethylolmethane constitute flame-retardant system, are compounded with hollow glass microbead, hollow The thermal insulating fillings such as ceramic fine bead, Rutile type titanium dioxide, nano far infrared ceramic powder, sericite, kieselguhr, And add water-based thickener, aqueous wetting agent, aqueous dispersion, aqueous defoamer, water mildow-proof agent and one-tenth Film auxiliary agent, is prepared for having obstruct, reflects and radiate three kinds of heat insulating functions and that fire-proof function is integrated is compound Type environmental-protection fireproof insulating moulding coating.
The technical solution adopted in the present invention is as follows:
A kind of Wood construction water-based fireproof insulating moulding coating, it is characterised in that: the described heat insulation painting of Wood construction water-based fireproof Material mainly includes the raw material of following weight parts: silicone acrylic emulsion 25~30 parts, APP 10~15 parts, trimerization Cyanamide 6~8 parts, tetramethylolmethane 3~6 parts, Rutile type titanium dioxide 10~15 parts, hollow glass microbead 3~6 Part, sericite 2~5 parts, hollow ceramic microspheres 2.5~6 parts, nano far infrared ceramic powder 2~4 parts, kieselguhr 4~7 parts, water-based thickener 0.5~1 part, aqueous defoamer 0.2~0.4 part, aqueous wetting dispersing agent 0.4~0.8 Part, water mildow-proof agent 0.1~0.3 part, coalescents 1~2 parts, deionized water 20~30 parts.
Described water-based thickener is in hydroxyethyl cellulose, hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose One or more.
Described aqueous defoamer is methyl-silicone oil.
Described aqueous wetting dispersing agent is silanol class nonionic surfactant.
Described water mildow-proof agent is benzimidazole methyl carbamate.
Described coalescents is propylene glycol phenylate.
A kind of preparation method of Wood construction water-based fireproof insulating moulding coating, it is characterised in that: mainly include following step Rapid:
(1) each raw material is weighed according to the parts by weight required by claim 1;
(2) by deionized water, aqueous wetting dispersing agent, aqueous defoamer, water mildow-proof agent with 500~700 Rev/min rotating speed at 10~50 DEG C, stir 10~30min;
(3) add again APP, tripolycyanamide, tetramethylolmethane, Rutile type titanium dioxide, sericite, Nano far infrared ceramic powder, kieselguhr, stir at 10~50 DEG C with the rotating speeds of 4000~6000 revs/min 20~50min;
(4) reduce rotating speed to 500~700 revs/min, add silicone acrylic emulsion, film forming that step (1) weighs Auxiliary agent, hollow glass microbead, hollow ceramic microspheres stir 10~30min at 20~50 DEG C, add step (1) water-based thickener weighed is stirred 10~30min, i.e. obtains the described heat insulation painting of Wood construction water-based fireproof Material.
The technique scheme of the present invention compared with prior art, has the advantage that
(1) environmental protection, the aqueous coating obtained by the present invention, as solvent, does not add organic solvent, The raw material used is all environment-friendly type, will not work the mischief the health of people and environment.
(2) flame-retardant system using APP, tripolycyanamide, tetramethylolmethane to constitute has well fire prevention Effect;Rutile type titanium dioxide, hollow glass microbead, sericite, kieselguhr have iris action, golden red Stone-type titanium dioxide and hollow ceramic microspheres have reflection, sericite and nano far infrared ceramic powder and have spoke Penetrate effect.Therefore, the coating obtained by the present invention is to combine obstruct, reflect and radiate three kinds of heat insulating functions And the functional coating that fire-proof function is integrated.
Detailed description of the invention
Describe the present invention in detail below in conjunction with specific embodiment, but the invention is not limited in specific embodiment.
Embodiment 1
A kind of Wood construction water-based fireproof insulating moulding coating, it is characterised in that: the described heat insulation painting of Wood construction water-based fireproof Material mainly includes the raw material of following weight parts: silicone acrylic emulsion 25 parts, APP 10 parts, tripolycyanamide 6 Part, tetramethylolmethane 3 parts, Rutile type titanium dioxide 10 parts, hollow glass microbead 3 parts, sericite 2 parts, Hollow ceramic microspheres 2.5 parts, nano far infrared ceramic powder 2 parts, 4 parts of kieselguhr, water-based thickener ethoxy Cellulose 0.5 part, aqueous defoamer methyl-silicone oil 0.2 part, aqueous wetting dispersing agent silanol class non-ionic surface Activating agent 0.4 part, water mildow-proof agent benzimidazole methyl carbamate 0.1 part, PPH 1 part, deionized water 20 parts.
The preparation method of above-mentioned Wood construction water-based fireproof insulating moulding coating, mainly comprises the steps that (1) will be each Raw material weighs according to the parts by weight required by claim 1;The deionized water that (2) step (1) weighed, Aqueous wetting dispersing agent, aqueous defoamer, water mildow-proof agent are stirred at 10 DEG C with the rotating speed of 700 revs/min Mix 30min;(3) APP that step (1) weighs, tripolycyanamide, tetramethylolmethane, golden red are added again Stone-type titanium dioxide, sericite, nano far infrared ceramic powder, kieselguhr, exist with the rotating speed of 4000 revs/min 50min is stirred at 10 DEG C;(4) reduce rotating speed to 500 revs/min, add silicon the third breast that step (1) weighs Liquid, coalescents, hollow glass microbead, hollow ceramic microspheres stir 30min at 20 DEG C, add step Suddenly the water-based thickener that (1) weighs is stirred 30min, the viscosity of regulation system, i.e. obtains described wood and builds Build water-based fireproof insulating moulding coating, obtained coating carried out performance detection, detect qualified after be packaged into finished product.
Embodiment 2
A kind of Wood construction water-based fireproof insulating moulding coating, it is characterised in that: the described heat insulation painting of Wood construction water-based fireproof Material mainly includes the raw material of following weight parts: silicone acrylic emulsion 28 parts, APP 10 parts, tripolycyanamide 6 Part, tetramethylolmethane 4 parts, Rutile type titanium dioxide 12 parts, hollow glass microbead 3 parts, sericite 3 parts, Hollow ceramic microspheres 3.5 parts, nano far infrared ceramic powder 2.5 parts, 5 parts of kieselguhr, water-based thickener hydroxypropyl Ylmethyl cellulose 0.6 part, aqueous defoamer methyl-silicone oil 0.3 part, aqueous wetting dispersing agent silanol class non-from Sub-surface activating agent 0.5 part, water mildow-proof agent benzimidazole methyl carbamate 0.1 part, coalescents the third two Alcohol phenylate 1 part, deionized water 25 parts.
The preparation method of above-mentioned Wood construction water-based fireproof insulating moulding coating, mainly comprises the steps that (1) will be each Raw material weighs according to the parts by weight required by claim 1;The deionized water that (2) step (1) weighed, Aqueous wetting dispersing agent, aqueous defoamer, water mildow-proof agent are stirred at 20 DEG C with the rotating speed of 600 revs/min Mix 20min;(3) APP that step (1) weighs, tripolycyanamide, tetramethylolmethane, golden red are added again Stone-type titanium dioxide, sericite, nano far infrared ceramic powder, kieselguhr, exist with the rotating speed of 5000 revs/min 30min is stirred at 40 DEG C;(4) reduce rotating speed to 600 revs/min, add silicon the third breast that step (1) weighs Liquid, coalescents, hollow glass microbead, hollow ceramic microspheres stir 20min at 40 DEG C, add step Suddenly the water-based thickener that (1) weighs is stirred 20min, the viscosity of regulation system, i.e. obtains described wood and builds Build water-based fireproof insulating moulding coating, obtained coating carried out performance detection, detect qualified after be packaged into finished product.
Embodiment 3
A kind of Wood construction water-based fireproof insulating moulding coating, it is characterised in that: the described heat insulation painting of Wood construction water-based fireproof Material mainly includes the raw material of following weight parts: silicone acrylic emulsion 30 parts, APP 15 parts, tripolycyanamide 8 Part, tetramethylolmethane 6 parts, Rutile type titanium dioxide 15 parts, hollow glass microbead 6 parts, sericite 5 parts, Hollow ceramic microspheres 6 parts, nano far infrared ceramic powder 4 parts, 7 parts of kieselguhr, water-based thickener carboxymethyl Sodium cellulosate 1 part, aqueous defoamer methyl-silicone oil 0.4 part, aqueous wetting dispersing agent silanol class non-ionic surface Activating agent 0.8 part, water mildow-proof agent benzimidazole methyl carbamate 0.3 part, PPH 2 parts, deionized water 30 parts.
The preparation method of above-mentioned Wood construction water-based fireproof insulating moulding coating, mainly comprises the steps that (1) will be each Raw material weighs according to the parts by weight required by claim 1;The deionized water that (2) step (1) weighed, Aqueous wetting dispersing agent, aqueous defoamer, water mildow-proof agent are stirred at 50 DEG C with the rotating speed of 500 revs/min Mix 10min;(3) APP that step (1) weighs, tripolycyanamide, tetramethylolmethane, golden red are added again Stone-type titanium dioxide, sericite, nano far infrared ceramic powder, kieselguhr, exist with the rotating speed of 6000 revs/min 20min is stirred at 50 DEG C;(4) reduce rotating speed to 700 revs/min, add silicon the third breast that step (1) weighs Liquid, coalescents, hollow glass microbead, hollow ceramic microspheres stir 10min at 50 DEG C, add step Suddenly the water-based thickener that (1) weighs is stirred 10min, the viscosity of regulation system, i.e. obtains described wood and builds Build water-based fireproof insulating moulding coating, obtained coating carried out performance detection, detect qualified after be packaged into finished product. The performance of the Wood construction water-based fireproof insulating moulding coating prepared according to the method described above is as shown in table 1:
The performance of table 1 Wood construction water-based fireproof insulating moulding coating
Project Technical specification Measured value Conclusion
Resistance to combustion time/min One-level (>=20) 34.8 One-level
Flame propagation ratio One-level (≤25) 16 One-level

Claims (7)

1. a Wood construction water-based fireproof insulating moulding coating, it is characterised in that: described Wood construction water-based fireproof is heat insulation Coating mainly includes the raw material of following weight parts: silicone acrylic emulsion 25~30 parts, APP 10~15 parts, three Poly cyanamid 6~8 parts, tetramethylolmethane 3~6 parts, Rutile type titanium dioxide 10~15 parts, hollow glass microbead 3~6 Part, sericite 2~5 parts, hollow ceramic microspheres 2.5~6 parts, nano far infrared ceramic powder 2~4 parts, kieselguhr 4~7 parts, water-based thickener 0.5~1 part, aqueous defoamer 0.2~0.4 part, aqueous wetting dispersing agent 0.4~0.8 Part, water mildow-proof agent 0.1~0.3 part, coalescents 1~2 parts, deionized water 20~30 parts.
A kind of Wood construction water-based fireproof insulating moulding coating the most according to claim 1, it is characterised in that: institute Stating water-based thickener is the one in hydroxyethyl cellulose, hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose Or it is several.
A kind of Wood construction water-based fireproof insulating moulding coating the most according to claim 1, it is characterised in that: institute Stating aqueous defoamer is methyl-silicone oil.
A kind of Wood construction water-based fireproof insulating moulding coating the most according to claim 1, it is characterised in that: institute Stating aqueous wetting dispersing agent is silanol class nonionic surfactant.
A kind of Wood construction water-based fireproof insulating moulding coating the most according to claim 1, it is characterised in that: institute Stating water mildow-proof agent is benzimidazole methyl carbamate.
A kind of Wood construction water-based fireproof insulating moulding coating the most according to claim 1, it is characterised in that: institute Stating coalescents is propylene glycol phenylate.
7. the preparation method of a Wood construction water-based fireproof insulating moulding coating, it is characterised in that: mainly include following Step:
(1) each raw material is weighed according to the parts by weight required by claim 1;
(2) deionized water that step (1) weighed, aqueous wetting dispersing agent, aqueous defoamer, aqueous Antifungus agent stirs 10~30min with the rotating speed of 500~700 revs/min at 10~50 DEG C;
(3) APP that step (1) weighs, tripolycyanamide, tetramethylolmethane, rutile-type are added again Titanium dioxide, sericite, nano far infrared ceramic powder, kieselguhr, exist with the rotating speed of 4000~6000 revs/min 20~50min are stirred at 10~50 DEG C;
(4) reduce rotating speed to 500~700 revs/min, add silicone acrylic emulsion, film forming that step (1) weighs Auxiliary agent, hollow glass microbead, hollow ceramic microspheres stir 10~30min at 20~50 DEG C, add step (1) water-based thickener weighed is stirred 10~30min, i.e. obtains the described heat insulation painting of Wood construction water-based fireproof Material.
CN201610203777.7A 2016-04-01 2016-04-01 Waterborne fireproof heat-insulation paint for wooden building and preparation method thereof Pending CN105838180A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106793232A (en) * 2016-12-22 2017-05-31 杨文举 A kind of forming method of micro-wave oven or oven cavity
CN107418346A (en) * 2017-09-17 2017-12-01 葛彬斌 A kind of expansion type flame-retarding interior wall coating and preparation method thereof
CN108822697A (en) * 2018-07-24 2018-11-16 芜湖彰鸿工程技术有限公司 A kind of heat-insulation and heat-preservation anti-flaming dope used for building exterior wall and preparation method thereof
CN109054556A (en) * 2018-07-11 2018-12-21 合肥信亚达智能科技有限公司 A kind of water nano compound heat-insulation coating and preparation method thereof
CN109233619A (en) * 2018-07-18 2019-01-18 安徽诺辰新型材料有限公司 Nano ceramics water paint
CN109233487A (en) * 2018-07-18 2019-01-18 安徽诺辰新型材料有限公司 High-temperature resistant nano Ceramic Composite coating
CN109836926A (en) * 2017-11-29 2019-06-04 公安部四川消防研究所 A kind of aqueous fire-proof coating, fire-proof plugging sheet material and its preparation method
CN114149714A (en) * 2021-11-05 2022-03-08 国网青海省电力公司检修公司 Water-based reflective heat-insulation coating and preparation method thereof
CN115029061A (en) * 2022-06-24 2022-09-09 厦门双瑞船舶涂料有限公司 Temperature-resistant, heat-insulating and anticorrosive coating for immersed tunnel smoke discharge flue and preparation method thereof
CN115449249A (en) * 2022-10-09 2022-12-09 重庆科博伦科技有限公司 Water-based fireproof transparent coating and preparation method thereof

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CN103073963A (en) * 2011-10-26 2013-05-01 比亚迪股份有限公司 Flame-retardant reflection insulation paint and preparation method thereof
CN103183996A (en) * 2013-04-11 2013-07-03 四川嘉宝莉涂料有限公司 High-effect reflective insulating coating and preparation method thereof
CN104177965A (en) * 2014-08-26 2014-12-03 山西省建筑科学研究院 Organic-inorganic composite nanometer heat-insulating fire-retardant coating and preparation method thereof

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CN103073963A (en) * 2011-10-26 2013-05-01 比亚迪股份有限公司 Flame-retardant reflection insulation paint and preparation method thereof
CN103183996A (en) * 2013-04-11 2013-07-03 四川嘉宝莉涂料有限公司 High-effect reflective insulating coating and preparation method thereof
CN104177965A (en) * 2014-08-26 2014-12-03 山西省建筑科学研究院 Organic-inorganic composite nanometer heat-insulating fire-retardant coating and preparation method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106793232A (en) * 2016-12-22 2017-05-31 杨文举 A kind of forming method of micro-wave oven or oven cavity
CN106793232B (en) * 2016-12-22 2020-05-01 深芏(中山)科技实业有限公司 Forming method of microwave oven or oven cavity
CN107418346A (en) * 2017-09-17 2017-12-01 葛彬斌 A kind of expansion type flame-retarding interior wall coating and preparation method thereof
CN109836926A (en) * 2017-11-29 2019-06-04 公安部四川消防研究所 A kind of aqueous fire-proof coating, fire-proof plugging sheet material and its preparation method
CN109054556A (en) * 2018-07-11 2018-12-21 合肥信亚达智能科技有限公司 A kind of water nano compound heat-insulation coating and preparation method thereof
CN109233619A (en) * 2018-07-18 2019-01-18 安徽诺辰新型材料有限公司 Nano ceramics water paint
CN109233487A (en) * 2018-07-18 2019-01-18 安徽诺辰新型材料有限公司 High-temperature resistant nano Ceramic Composite coating
CN108822697A (en) * 2018-07-24 2018-11-16 芜湖彰鸿工程技术有限公司 A kind of heat-insulation and heat-preservation anti-flaming dope used for building exterior wall and preparation method thereof
CN114149714A (en) * 2021-11-05 2022-03-08 国网青海省电力公司检修公司 Water-based reflective heat-insulation coating and preparation method thereof
CN115029061A (en) * 2022-06-24 2022-09-09 厦门双瑞船舶涂料有限公司 Temperature-resistant, heat-insulating and anticorrosive coating for immersed tunnel smoke discharge flue and preparation method thereof
CN115449249A (en) * 2022-10-09 2022-12-09 重庆科博伦科技有限公司 Water-based fireproof transparent coating and preparation method thereof

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Application publication date: 20160810

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