CN103183996A - High-effect reflective insulating coating and preparation method thereof - Google Patents
High-effect reflective insulating coating and preparation method thereof Download PDFInfo
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- CN103183996A CN103183996A CN2013101249252A CN201310124925A CN103183996A CN 103183996 A CN103183996 A CN 103183996A CN 2013101249252 A CN2013101249252 A CN 2013101249252A CN 201310124925 A CN201310124925 A CN 201310124925A CN 103183996 A CN103183996 A CN 103183996A
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Abstract
The invention discloses a high-effect reflective insulating coating and a preparation method thereof, and belongs to the technical field of application of coating. The high-effect reflective insulating coating consists of an emulsion, a polymer Youchuang E, titanium dioxide, ground calcium carbonate, nano far infrared ceramic powder, fine diatomite, ZR coating powder, ultraviolet-proof inorganic powder, reflective powder, hollow glass beads, a dispersant, a wetting agent, a pH adjustor, a film forming agent, a defoamer, a thickener, an antiseptic antimildew agent and water. The invention further provides a preparation method of the coating. According to the invention, an orthogonal test method is adopted, and primary and secondary sequences of factors are calculated according to a range R by means of complexing technology so as to obtain an insulating coating formula with optimal match. Through detection by a Chinese building material test center, the solar reflectivity is 0.88, the semi-spherical emissivity is 0.91, and the insulating temperature difference is 16.9 DEG C.
Description
Technical field
The invention belongs to the application of paints technical field, be specifically related to a kind of high-effect reflective heat-insulation paint and preparation method thereof.
Background technology
China has implemented " Energy Conservation Law of the People's Republic of China " on April 1st, 2008, building energy conservation has become China's statutory requirement at present, the Ministry of Construction has carried out strict mandatory regulation to China's covil construction are energy-conservation in the 143rd command about covil construction administration of energy conservation regulation.Building energy conservation the most important thing is to make body of wall, roofing, door and window of buildings etc. to have heat-proof quality and good airtight performance preferably.In numerous building heat preservation lagging materials in the market, architectural reflective heat-insulation paint obtains to accept widely and use because of advantages such as its economy, easy to use and reflective insulation are reliable for effect.
Architectural reflective heat-insulation paint is base-material with the synthetic resin emulsion, be dispersion medium with water, add functional color stuffing (being mainly sunlight reflection, radiation, obstruct class color stuffing) and auxiliary agent, the coating with reflective insulation effect that the certain technological process of process is made.
In daily life, white or light article itself just have luminous reflectanc preferably, to the low absorptivity of solar heat.The traditional architecture reflective heat-insulation paint mainly is in conjunction with the phenomenon in the daily life, adopting refraction coefficient is that 2.76 Rutile type Titanium Dioxide is functional white color pigment, general volume accounts for the 30%-40% of formulation for coating material total amount, the paint vehicle that is prepared into mostly is white or light, thereby reaches certain cooling, heat-blocking action.Yet, theoretically, each titanium white particle can the certain light of scattering, and when being the twice of titanium white particle dia, the particle interbody spacer reaches maximum scattering, when the pigment volume concentration (PVC) (PVC)＜10% of titanium dioxide, the titanium dioxide particle can meet or exceed this requirement at interval usually, and when the titanium white powder pigment volumetric concentration〉10% the time, the gathering of titanium dioxide can make the scattering efficiency of scattered light reduce greatly, thereby cause overall titanium dioxide scattering power to descend, the relative interior wall of the applied environment of exterior coating is more abominable in addition, cause traditional reflective heat-insulation paint sun reflectivity can not satisfy the index of national standard 0.80, poor owing to contamination resistance after wall for some time on the coating, almost lose the reflective insulation effect, so the traditional reflective thermal insulating coating can not obtain the reason that large-scale popularization is used.
In addition, existing market is to mix hollow glass micropearl in the reflective heat-insulation paint more than 80% to remedy titanium dioxide as functional stuffing to cross the sun reflectivity index that poly-phenomenon causes defective, improve the reflectivity of coating to a certain extent, but the hollow glass micropearl technology of domestic production is immature, the hollow structure of glass microballon is destroyed in the coating material production process, destroy the back because suction is expanded after making coating, the knot lump, the package stability extreme difference of coating.Simultaneously, hollow glass micropearl mixes and makes that too much the coatingsurface degree of roughness is higher, and contamination resistance can be had a greatly reduced quality, and influences the lasting reflective insulation effect of whole paint film.
Summary of the invention
The objective of the invention is to address the above problem, a kind of high-effect reflective heat-insulation paint with reflection, obstruct, radiation solar heat and preparation method thereof is provided, this coating detects through national building materials test center and draws, sun reflectivity can reach 0.88, and hemispherical emissivity can reach 0.91, and the heat insulation temperature difference can reach 16.9 ℃, can effectively reduce the torridity summer room temp, improve living environment, reduce the operation of air conditioner rate, reach the effect of energy-saving and emission-reduction.
To achieve these goals, technical scheme of the present invention is as follows:
High-effect reflective heat-insulation paint is characterized in that, it is made up of the raw material of following weight part:
25～38 parts of emulsions
5～10 parts of polymkeric substance Unihub E
5～15 parts of titanium dioxides
10～15 parts of coarse whitings
2～6 parts of nano far infrared ceramic powders
6～12 parts in meticulous diatomite
2～5 parts in ZR coating powder
1～3 part in the inorganic powder of antiultraviolet
1～3 part in reflective powder
5～10 parts of hollow glass micropearls
0.4～0.8 part of dispersion agent
0.2～0.5 part of wetting agent
0.1～0.3 part of pH regulator agent
2～3 parts of film coalescence aid
0.5～0.8 part of defoamer
0.3～0.7 part of thickening material
0.1～0.3 part of Antisepticize and mildew preventive
15～25 parts in water.
Further, described emulsion is pure acrylic acid ester emulsion.
The preparation method of above-mentioned high-effect reflective heat-insulation paint may further comprise the steps:
(1) with weight part is 15～25 parts water, X
1The thickening material of part, 0.4～0.8 part dispersion agent, X
2Part defoamer and 0.2～0.5 part wetting agent add one liter successively plastics pot in, stir 5～8min to mixing;
(2) the slow nano far infrared ceramic powder that adds 2～6 parts in the above-mentioned solution that stirs, 6～12 parts meticulous diatomite, 2～5 parts ZR coating powder, the inorganic powder of 1～3 part antiultraviolet, 1～3 part reflective powder, 5～15 parts of titanium dioxides and 10～15 parts of coarse whitings stir 20～30min under the rotating speed of 1500～2000r/min, make it abundant dispersion, the film coalescence aid high speed dispersion 5～8min that adds 2～3 parts again makes dispersion system;
(3) the above-mentioned dispersion system of stirring at low speed adds 25～38 parts emulsion and 5～10 parts polymkeric substance Unihub E, and after stirring, pH value to 7～9 are regulated in the pH regulator agent that adds 0.1～0.3 part;
(4) under the rotating speed of 200～350r/min, stir, slowly add 5～10 parts hollow glass micropearl then and stir can't see the hollow glass micropearl of suspension to the surface till;
(5) add Y
1Thickening material, the Y of part
2The defoamer of part and 0.1～0.3 part Antisepticize and mildew preventive evenly stir 10～15min, namely get product;
Wherein, 0.3≤X
1+ Y
1≤ 0.7,0.5≤X
2+ Y
2≤ 0.8; And X
1≠ 0, Y
1≠ 0, X
2≠ 0, Y
2≠ 0.
The present invention compared with prior art has the following advantages and beneficial effect:
(1) the present invention adopts the method for orthogonal test, utilize compounded technology, calculate the primary and secondary order of each factor through extreme difference R, obtain the thermal insulating coating prescription of optimum level collocation, detection draws through national building materials test center, the solar energy reflection ratio can reach 0.88, and hemispherical emissivity can reach 0.91, and the heat insulation temperature difference can reach 16.9 ℃.
(2) the present invention utilizes and mixes the assembly mode spherical hollow structure and the elastic emulsion of aqueous core shell structure polymkeric substance self mixed assembly, add in the reflective heat-insulation paint and can replace 17% titanium dioxide, increase substantially coating contamination resistance and hiding rare when saving cost.
(3) the present invention reduces the voidage in the paint film by the collocation to different color stuffing thickness particles, improve the planeness of coating integral body, thereby obtain the good reflective insulation coating of contamination resistance, and heat insulation temperature difference pad value is about 4.4 ℃.
(4) the present invention is by the analysis to common toner or mill base kind and volume, drawing charcoal blacks has the greatest impact to the coating reflectivity, be not more than 10% with the reflectivity of reflective heat-insulation paint in 300～2500 nano waveband scopes of carbon black class mill base modulation is the highest, the present invention also can add the dark pigment alternative carbon black of IR composite inorganic class pigment according to the actual requirements, all the other are blue, red, green, yellow, in the case, utilize mill base 300～2500 nano waveband scope internal reflection rates just to prepare the colour reflective thermal insulating coating of different tones, control the addition of every kind of mill base, prepare the reflectivity of colour reflective thermal insulating coating all more than 65%.
Embodiment
The invention will be further described below in conjunction with embodiment, and embodiments of the present invention include but not limited to the following example.
Embodiment 1
Be that the wetting agent of 25 parts water, 0.1 part thickening material (Natvosol), 0.4 part dispersion agent, 0.2 part defoamer and 0.2 part adds in one liter the plastics pot successively with weight part, and middling speed stir 5～8min and fully dissolves to thickening material and mix; The nano far infrared ceramic powder that slowly adds 2 parts again, 12 parts meticulous diatomite, 2 parts ZR coating powder, the inorganic powder of 1 part antiultraviolet, 1 part reflective powder, 15 parts of titanium dioxides and 10 parts of coarse whitings stir 10～15min under the rotating speed of 1500～2000r/min, make it abundant dispersion, the film coalescence aid high speed dispersion 5～8min that then adds 2 parts makes dispersion system; Add 25 parts pure acrylic acid ester emulsion and 10 parts polymkeric substance Unihub E then under the stirring at low speed condition, after stirring, pH value to 7～9 are regulated in the pH regulator agent that adds 0.1 part; Under the rotating speed of 200～350r/min, stir again, slowly add 5 parts hollow glass micropearl then and stir can't see the hollow glass micropearl of suspension to the surface till; Add 0.2 part thickening material, 0.3 part defoamer and 0.1 part Antisepticize and mildew preventive at last, stir 10～15min and after evenly, can tinning store.
Every performance as shown in table 1, as to press the index detection coating among the CB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", detected result shows that every traditional performance index of this coating all complies with the national standard requirements.
As shown in table 2, carry out the test of heat insulation temperature difference effect by method described in JG/T235-2008 " architectural reflective heat-insulation paint " standard, be the blank test plate (panel) of heat insulation temperature difference experiment with fiber reinforced calcium silicate board, adopt 120 μ m lines rod spreader twice to make the heat insulation test plate (panel) of test, carry out heat insulation temperature test behind the dry 7d, light source adopts two 250 watts heating lamp to shine, irradiation time is 1h, record a secondary data every 5min, under same light source irradiation, heat insulation test plate (panel) and blank model are carried out the heat insulation temperature difference to contrast, and heat insulation test plate (panel) is than low 8.9 ℃ of blank model; After 5 anti-contamination circulations, the heat insulation temperature difference decays to 5.6 ℃, and therefore, the present invention has reflective insulation effect preferably.
Embodiment 2
Be that the wetting agent of 15 parts water, 0.3 part thickening material (Natvosol), 0.8 part dispersion agent, 0.3 part defoamer and 0.5 part adds in one liter the plastics pot successively with weight part, and middling speed stir 5～8min and fully dissolves to thickening material and mix; The nano far infrared ceramic powder that slowly adds 4 parts again, 8 parts meticulous diatomite, 3 parts ZR coating powder, the inorganic powder of 2 parts antiultraviolet, 2 parts reflective powder, 5 parts of titanium dioxides and 15 parts of coarse whitings stir 10～15min under the rotating speed of 1500～2000r/min, make it abundant dispersion, the film coalescence aid high speed dispersion 5～8min that then adds 3 parts makes dispersion system; Add 38 parts pure acrylic acid ester emulsion and 5 parts polymkeric substance Unihub E then under the stirring at low speed condition, after stirring, pH value to 7～9 are regulated in the pH regulator agent that adds 0.3 part; Under the rotating speed of 200～350r/min, stir again, slowly add 10 parts hollow glass micropearl then and stir can't see the hollow glass micropearl of suspension to the surface till; Add 0.4 part thickening material, 0.5 part defoamer and 0.3 part Antisepticize and mildew preventive at last, stir 10～15min and after evenly, can tinning store.
Every performance as shown in table 1, as to press the index detection coating among the CB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", detected result shows that every traditional performance index of this coating all complies with the national standard requirements.
As shown in table 2, carry out the test of heat insulation temperature difference effect by method described in JG/T235-2008 " architectural reflective heat-insulation paint " standard, be the blank test plate (panel) of heat insulation temperature difference experiment with fiber reinforced calcium silicate board, adopt 120 μ m lines rod spreader twice to make the heat insulation test plate (panel) of test, carry out heat insulation temperature test behind the dry 7d, light source adopts two 250 watts heating lamp to shine, irradiation time is 1h, record a secondary data every 5min, under same light source irradiation, heat insulation test plate (panel) and blank model are carried out the heat insulation temperature difference to contrast, and heat insulation test plate (panel) is than low 10.3 ℃ of blank model; After 5 anti-contamination circulations, the heat insulation temperature difference decays to 5.9 ℃, and therefore, the present invention has reflective insulation effect preferably.
Embodiment 3
Be that the wetting agent of 20 parts water, 0.2 part thickening material (Natvosol), 0.6 part dispersion agent, 0.3 part defoamer and 0.3 part adds in one liter the plastics pot successively with weight part, and middling speed stir 5～8min and fully dissolves to thickening material and mix; The nano far infrared ceramic powder that slowly adds 6 parts again, 10 parts meticulous diatomite, 5 parts ZR coating powder, the inorganic powder of 3 parts antiultraviolet, 3 parts reflective powder, 10 parts of titanium dioxides and 10 parts of coarse whitings stir 10～15min under the rotating speed of 1500～2000r/min, make it abundant dispersion, the film coalescence aid high speed dispersion 5～8min that then adds 2.5 parts makes dispersion system; Add 33 parts pure acrylic acid ester emulsion and 8 parts polymkeric substance Unihub E then under the stirring at low speed condition, after stirring, pH value to 7～9 are regulated in the pH regulator agent that adds 0.2 part; Under the rotating speed of 200～350r/min, stir again, slowly add 8 parts hollow glass micropearl then and stir can't see the hollow glass micropearl of suspension to the surface till; Add 0.3 part thickening material, 0.3 part defoamer and 0.2 part Antisepticize and mildew preventive at last, stir 10～15min and after evenly, can tinning store.
Every performance as shown in table 1, as to press the index detection coating among the CB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", detected result shows that every traditional performance index of this coating all complies with the national standard requirements.
As shown in table 2, carry out the test of heat insulation temperature difference effect by method described in JG/T235-2008 " architectural reflective heat-insulation paint " standard, be the blank test plate (panel) of heat insulation temperature difference experiment with fiber reinforced calcium silicate board, adopt 120 μ m lines rod spreader twice to make the heat insulation test plate (panel) of test, carry out heat insulation temperature test behind the dry 7d, light source adopts two 250 watts heating lamp to shine, irradiation time is 1h, record a secondary data every 5min, under same light source irradiation, heat insulation test plate (panel) and blank model are carried out the heat insulation temperature difference to contrast, and heat insulation test plate (panel) is than low 16.9 ℃ of blank model; After 5 anti-contamination circulations, the heat insulation temperature difference decays to 4.9 ℃, and therefore, the present invention has reflective insulation effect preferably.
Table 1
Annotate: examining report is gone out by national hazardous chemical quality supervision and test center.
Table 2
| Interventions Requested | Standard-required | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Sun reflectivity (white) | ≥0.83 | 0.85 | 0.87 | 0.88 |
| Hemispherical emissivity | ≥0.85 | 0.85 | 0.88 | 0.91 |
| The heat insulation temperature difference | ≥10℃ | 8.9℃ | 10.3℃ | 16.9℃ |
| Heat insulation temperature difference decay (white) | ≤10℃ | 5.6℃ | 5.9℃ | 4.9℃ |
Annotate: examining report is gone out by national building materials inspection center.
According to above-described embodiment, just can realize the present invention well.What deserves to be explained is; under the prerequisite based on above-mentioned design, for solving same technical problem, even some that make in the present invention do not have substantial change or polishing; the essence of the technical scheme that adopts is still the same with the present invention, so it also should be in protection scope of the present invention.
Claims (3)
1. high-effect reflective heat-insulation paint is characterized in that, it is made up of the raw material of following weight part:
25～38 parts of emulsions
5～10 parts of polymkeric substance Unihub E
5～15 parts of titanium dioxides
10～15 parts of coarse whitings
2～6 parts of nano far infrared ceramic powders
6～12 parts in meticulous diatomite
2～5 parts in ZR coating powder
1～3 part in the inorganic powder of antiultraviolet
1～3 part in reflective powder
5～10 parts of hollow glass micropearls
0.4～0.8 part of dispersion agent
0.2～0.5 part of wetting agent
0.1～0.3 part of pH regulator agent
2～3 parts of film coalescence aid
0.5～0.8 part of defoamer
0.3～0.7 part of thickening material
0.1～0.3 part of Antisepticize and mildew preventive
15～25 parts in water.
2. high-effect reflective heat-insulation paint according to claim 1 is characterized in that, described emulsion is pure acrylic acid ester emulsion.
3. the preparation method of each described high-effect reflective heat-insulation paint of claim 1～2 is characterized in that, may further comprise the steps:
(1) with weight part is 15～25 parts water, X
1The thickening material of part, 0.4～0.8 part dispersion agent, X
2Part defoamer and 0.2～0.5 part wetting agent add one liter successively plastics pot in, stir 5～8min to mixing;
(2) the slow nano far infrared ceramic powder that adds 2～6 parts in the above-mentioned solution that stirs, 6～12 parts meticulous diatomite, 2～5 parts ZR coating powder, the inorganic powder of 1～3 part antiultraviolet, 1～3 part reflective powder, 5～15 parts of titanium dioxides and 10～15 parts of coarse whitings stir 10～15min under the rotating speed of 1500～2000r/min, make it abundant dispersion, the film coalescence aid high speed dispersion 5～8min that adds 2～3 parts again makes dispersion system;
(3) the above-mentioned dispersion system of stirring at low speed adds 25～38 parts emulsion and 5～10 parts polymkeric substance Unihub E, and after stirring, pH value to 7～9 are regulated in the pH regulator agent that adds 0.1～0.3 part;
(4) under the rotating speed of 200～350r/min, stir, slowly add 5～10 parts hollow glass micropearl then and stir can't see the hollow glass micropearl of suspension to the surface till;
(5) add Y
1Thickening material, the Y of part
2The defoamer of part and 0.1～0.3 part Antisepticize and mildew preventive evenly stir 10～15min, namely get product;
Wherein, 0.3≤X
1+ Y
1≤ 0.7,0.5≤X
2+ Y
2≤ 0.8; And X
1≠ 0, Y
1≠ 0, X
2≠ 0, Y
2≠ 0.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001756A (en) * | 2015-07-08 | 2015-10-28 | 当涂县科辉商贸有限公司 | Super thermal insulation coating and preparation method therefor |
| CN105001754A (en) * | 2015-07-08 | 2015-10-28 | 当涂县科辉商贸有限公司 | Nano far-infrared ceramic powder loading super thermal insulation coating and preparation method therefor |
| CN105419531A (en) * | 2016-01-26 | 2016-03-23 | 哈尔滨艾斯贝科科技发展有限公司 | Preparing method of superhigh-sunshine reflectance ratio coating |
| CN105733384A (en) * | 2016-04-22 | 2016-07-06 | 哈尔滨理工大学 | Preparation method of cool and sunlight-reflective waterproof coating for roof and outer wall |
| CN105838180A (en) * | 2016-04-01 | 2016-08-10 | 江苏绿能环保集成木屋有限公司 | Waterborne fireproof heat-insulation paint for wooden building and preparation method thereof |
| CN107603367A (en) * | 2017-09-29 | 2018-01-19 | 常熟三爱富中昊化工新材料有限公司 | A kind of feature waterborne fluoro emulsion and preparation method thereof |
| CN110628285A (en) * | 2019-10-29 | 2019-12-31 | 天津宝丽杰涂料有限公司 | Environment-friendly coating with heat insulation effect |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319121A (en) * | 2008-06-03 | 2008-12-10 | 董善刚 | Multifunctional high-efficiency thermal insulation insulating mold paint |
-
2013
- 2013-04-11 CN CN201310124925.2A patent/CN103183996B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319121A (en) * | 2008-06-03 | 2008-12-10 | 董善刚 | Multifunctional high-efficiency thermal insulation insulating mold paint |
Non-Patent Citations (1)
| Title |
|---|
| 彭红: ""高效外墙隔热涂料的配制及性能研究"", 《中国优秀硕士学位论文全文数据库》, no. 12, 15 December 2009 (2009-12-15) * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001756A (en) * | 2015-07-08 | 2015-10-28 | 当涂县科辉商贸有限公司 | Super thermal insulation coating and preparation method therefor |
| CN105001754A (en) * | 2015-07-08 | 2015-10-28 | 当涂县科辉商贸有限公司 | Nano far-infrared ceramic powder loading super thermal insulation coating and preparation method therefor |
| CN105419531A (en) * | 2016-01-26 | 2016-03-23 | 哈尔滨艾斯贝科科技发展有限公司 | Preparing method of superhigh-sunshine reflectance ratio coating |
| CN105838180A (en) * | 2016-04-01 | 2016-08-10 | 江苏绿能环保集成木屋有限公司 | Waterborne fireproof heat-insulation paint for wooden building and preparation method thereof |
| CN105733384A (en) * | 2016-04-22 | 2016-07-06 | 哈尔滨理工大学 | Preparation method of cool and sunlight-reflective waterproof coating for roof and outer wall |
| CN107603367A (en) * | 2017-09-29 | 2018-01-19 | 常熟三爱富中昊化工新材料有限公司 | A kind of feature waterborne fluoro emulsion and preparation method thereof |
| CN110628285A (en) * | 2019-10-29 | 2019-12-31 | 天津宝丽杰涂料有限公司 | Environment-friendly coating with heat insulation effect |
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| CN103183996B (en) | 2015-11-25 |
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