CN106634349A - Color reflection heat insulation and temperature reduction paint and preparation method thereof - Google Patents

Color reflection heat insulation and temperature reduction paint and preparation method thereof Download PDF

Info

Publication number
CN106634349A
CN106634349A CN201611193526.1A CN201611193526A CN106634349A CN 106634349 A CN106634349 A CN 106634349A CN 201611193526 A CN201611193526 A CN 201611193526A CN 106634349 A CN106634349 A CN 106634349A
Authority
CN
China
Prior art keywords
weight portion
heat
heat insulation
control coating
colour reflective
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611193526.1A
Other languages
Chinese (zh)
Inventor
韩耑壮
王福强
赵曦
李维虎
戴家兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanzhou Ke Tian Environmental Protection And Energy Saving Science And Technology Ltd
Original Assignee
Lanzhou Ke Tian Environmental Protection And Energy Saving Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanzhou Ke Tian Environmental Protection And Energy Saving Science And Technology Ltd filed Critical Lanzhou Ke Tian Environmental Protection And Energy Saving Science And Technology Ltd
Priority to CN201611193526.1A priority Critical patent/CN106634349A/en
Publication of CN106634349A publication Critical patent/CN106634349A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses color reflection heat insulation and temperature reduction paint and a preparation method thereof. The color reflection heat insulation and temperature reduction paint integrates heat insulation functions of blocking, reflection, radiation and the like; the reflection and heat insulation functions are excellent; the building energy consumption can be effectively reduced; meanwhile, an ordinary water-base colorant can be used for color regulation; the color requirements of people on building decoration individuation can be met.

Description

Colour reflective heat insulation and heat control coating and preparation method thereof
Technical field
The present invention relates to aqueous architectural coating technical field, especially a kind of colour reflective heat insulation and heat control coating and its preparation Method.
Background technology
In recent years, with national energy-saving, the enforcement of environmental protection industry policy, the awareness of saving energy of people is improved constantly, particularly China's building energy consumption accounts for 1/3 or so of energy wastage in bulk or weight, is even more increasingly subject to pay attention to.Therefore, develop and promote low energy consumption, The good reflective insulation High tailored coating of thermal and insulating performance has become the main trend of building coating industry.
In China, colored building coating utilization rate is about 80%, and development and application colour reflective heat insulation and heat control coating is just formed One upsurge.Such as prepare dark reflective insulation by adding heat reflection filler, hollow glass micropearl and composite inorganic toner Sealing wax, or by adding infra-red radiation filler and microcapsules of storing energy through phase change emulsion and being made using inorganic mixed phase metal oxide Multi-color system reflective heat-insulation paint coating system is prepared for coloring pigment, or by adding reflectivity functional filler and Gao Hong The pigment of external reflectance ratio is preparing colored solar heat reflecting and heat insulating coating etc..Above prior art belongs to obstruct-reflective insulation, anti- - radiation heat insulation type coating is penetrated, higher sun luminous reflectance and near-infrared reflection ratio is obtained, is imitated with fabulous heat insulation and heat control Really, but in their production processes infrared external reflection toner is adopted, it is impossible to using common mill base, colour system is complete, on the high side, production Bad control.Also have and colour reflective insulating moulding coating is prepared using common mill base by adding modified titanium in common coating Technology, but simply simple reflection heat-insulating type coating do not possess obstruct and radiation function, and cooling-down effect is limited.
The content of the invention
The present invention is directed to the deficiencies in the prior art, proposes a kind of colour reflective heat insulation and heat control coating, and composition is reasonable, collection resistance Every, reflection, radiation etc. heat insulating function in one.
In order to realize foregoing invention purpose, the present invention provides technical scheme below:A kind of colour reflective heat insulation and heat control coating, It is made up of following components in parts by weight:
Deionized water 15.00~30.00
Cellulose 0.20~0.60
PH adjusting agent 0.10~0.20
Dispersant 0.20~0.70
Wetting agent 0.00~0.40
Antifreezing agent 1.00~3.00
Defoamer 0.30~0.60
Titanium dioxide 0.00~20.00
Infra-red radiation filler 10.00~15.00
Powdered whiting 3.00~12.00
Heat reflection filler 3.00~6.00
Pure-acrylic emulsion 25.00~30.00
Organic silicon emulsion 5.00~10.00
The heat-insulated premix thing 5.00~10.00 of macromolecule
Coalescents 1.00~4.00
Preservative 0.10~0.30
Mould inhibitor 0.30~0.50
Thickener 0.00~1.00
Hollow glass micropearl 2.00~5.00
Organosilicon moisture repellent 0.30~0.60
Aqueous color paste 0.00~10.00.
Further, the cellulose is hydroxyethyl cellulose.
Further, the dispersant is polycarboxylic acids ammonium salt.
Further, the defoamer is mineral oil defoaming agent.
Further, the antifreezing agent is propane diols.
Further, the infra-red radiation filler is kaolin, mica powder, talcum powder, diatomite, zinc oxide and far infrared The mixture of powder.
Further, the heat-insulated premix thing of the macromolecule be opacity polymer, emissivity functional group modification polymer and The premix of expandable microspheres.
Further, the aqueous color paste is one kind or arbitrarily two or more groups of aqueous color paste and cold pigment black slurry Compound.
Further, the mould inhibitor is isothiazolinone derivatives or benzimidazole ester type compound and its derivative.
A kind of preparation method of colour reflective heat insulation and heat control coating as described above, comprises the following steps:
(1), it is pre-mixed:Under the rotating speed of 300~800r/min, the following component mixing of weight portion stirs:Deionization Water 14.50~29.00, cellulose 0.20~0.60, pH adjusting agent 0.10~0.20, dispersant 0.20~0.70, wetting agent 0.00~0.40, antifreezing agent 1.00~3.00 and defoamer 0.15~0.30;
(2), color stuffing dispersion:Step premixing material (1), under the rotating speed of 600~1200r/min, adds weight portion as follows Component:Titanium dioxide 0.0~20.0, infra-red radiation filler 10.00~15.00, powdered whiting 3.00~12.00, heat reflection Filler 3.00~6.00, under the rotating speed of 1500~2000r/min, disperses 25~30 minutes;
(3), paint:Step (2) dispersed material, under the rotating speed of 500-800r/min, the component for adding weight portion following:Pure third is newborn Liquid 25.00~30.00, organic silicon emulsion 5.00~10.00, coalescents 1.00~4.00, thickener 0.00~1.00 and height The heat-insulated premix thing 5.00~10.00 of molecule, is slow added into mould inhibitor 0.30~0.50, deionized water 0.50~1.00 and premixes Close preservative 0.10-0.30;Rotating speed is reduced to 300-600r/min, adds hollow glass micropearl 2.00~5.00, organosilicon hydrophobic Agent 0.30~0.60 and defoamer 0.10~0.20, stir;
(4), mix colours:(3) stir in material to step, add aqueous color paste 0.00~10.00, add defoamer 0.05~ 0.10, stir, filter, obtain filtrate.
Wherein, the cellulose is NATROSOL®250HBR, HS30000YP2;The pH adjusting agent is ammoniacal liquor, AMP-95 One kind;The dispersant is that polycarboxylic acids ammonium salt includes SN-Dispersant 5029, Dispex A40A;The wetting agent is Surfactant without APEO, nonrestrictive example includes TRITONTMEF-106.The defoamer disappears for mineral oils Infusion.The antifreezing agent is propane diols;The heat reflection filler, nonrestrictive example include Altiris550, Altiris800。
The cold pigment black slurry, nonrestrictive example includes the IR-801 of ANS Chemical.
The hollow glass micropearl, nonrestrictive example includes the VS5500 of 3M.
The pure-acrylic emulsion, nonrestrictive example includes Tao Shi Primal AC-261C.
The coalescents are ester alcohol -12.
The preservative is CIT/MIT type preservatives.
The thickener is the one or more than one in the swelling acrylic acid of hydrophobically-modified alkali and polyurethane thickener Combination.
Compared with prior art, the present invention has advantages below:Reflective insulation function is excellent, is effectively reduced building energy Consumption, can meet people's color requirements personalized to building decoration color.
The invention has the advantages that:
(1)Integrate the heat insulating functions such as reflection, obstruct, radiation, reduce heat absorption and weaken heat transfer property, improve heat-sinking capability, Effect of heat insulation is lasting for a long time.
(2)Common color paste toning can be adopted, low cost is convenient for production.
(3)Excellent ageing-resistant, colour retention, stain resistant and resistance to water.
Specific embodiment
Describe the present invention with reference to embodiment, the description of this part be only it is exemplary and explanatory, no Reply protection scope of the present invention has any restriction effect.
A kind of colour reflective heat insulation and heat control coating, it is made up of following components in parts by weight:
The weight portion of deionized water 15.00~30.00
The weight portion of cellulose 0.20~0.60
The weight portion of pH adjusting agent 0.10~0.20
The weight portion of dispersant 0.20~0.70
The weight portion of wetting agent 0.00~0.40
The weight portion of antifreezing agent 1.00~3.00
The weight portion of defoamer 0.30~0.60
The weight portion of titanium dioxide 0.00~20.00
The weight portion of infra-red radiation filler 10.00~15.00
The weight portion of powdered whiting 3.00~12.00
The weight portion of heat reflection filler 3.00~6.00
The weight portion of pure-acrylic emulsion 25.00~30.00
The weight portion of organic silicon emulsion 5.00~10.00
The heat-insulated weight portion of premix thing 5.00~10.00 of macromolecule
The weight portion of coalescents 1.00~4.00
The weight portion of preservative 0.10~0.30
The weight portion of mould inhibitor 0.30~0.50
The weight portion of thickener 0.00~1.00
The weight portion of hollow glass micropearl 2.00~5.00
The weight portion of organosilicon moisture repellent 0.30~0.60
The weight portion of aqueous color paste 0.00~10.00
Above-mentioned heat reflection filler, can make some medium shades and light color (L*>40), dark color (L*<40) with some beautiful colors Coating has very high solar reflecting properties, and nonrestrictive example includes Altiris550, Altiris800.
Above-mentioned infra-red radiation filler is the mixing of kaolin, mica powder, talcum powder, diatomite, zinc oxide and far-infrared powder Thing.Infra-red radiation filler has certain heat loss through radiation function in 8~14 microns of this " atmospheric window " infrared ray wave bands, can be with The emissivity of coating is improved, so as to reduce the effect of coat inside temperature.
The heat-insulated premix thing of above-mentioned macromolecule is opacity polymer, emissivity functional group modification polymer and expandable microspheres Mixture.Wherein, opacity polymer is hollow Opacifying polymers spheroid, is assembled with opposing heat reflection filler and titanium dioxide Effect, the space being sufficient filling with cenosphere makes the hollow ball of multistage-combination arrangement in coating even closer, so as to improve The sun light reflectivity of coating.Emissivity functional group modification polymer average grain diameter is less than 5 microns, is that one kind can launch infrared ray The high molecular polymer of heat energy.Expandable microspheres are a kind of plastic macromolecules of light hollow, are imitated with certain heat insulation and heat control Really.
Above-mentioned aqueous color paste is common water borne mill base(Except carbon black color paste)With one kind or any two of cold pigment black slurry Plant the composition of the above.Wherein, above-mentioned cold pigment black slurry, nonrestrictive example includes the IR-801 of ANS Chemical, Near infrared ray heat energy can be directly reflected, is reduced and is absorbed heat energy.
Above-mentioned hollow glass micropearl, nonrestrictive example includes the VS5500 of 3M, 15~85 microns of particle diameter, heat conduction system Number 0.062W/m.K, sunshine reflectivity ρ=0.90 has extremely strong emissivity to the micron waveband of infrared ray 8~14, and hemisphere is sent out Rate is penetrated up to 0.89.
Above-mentioned organic silicon emulsion steam permeability is good, water imbibition is low, be difficult laying dust, has excellent weather resistance.
Above-mentioned organosilicon moisture repellent can strengthen the resistance to water of coating, good gas permeability be kept, while improving water paint Workability.
The heat reflection filler of colour reflective heat insulation and heat control coating addition of the present invention, can reflect most of sunshine, weaken The heat absorption capacity of exterior wall paint film, reduces solar radiation heat energy and enters interior of building, and the hollow glass micropearl of addition and expansion are micro- Ball and opacity polymer are internally formed hollow housing in exterior wall paint film can reduce the conductivity of heat of exterior wall paint film, effectively intercept the sun The transmission of heat, the infra-red radiation filler and emissivity functional group modification polymer of addition have the performance of radiant heat energy, can have Effect improves the heat-sinking capability of exterior wall paint film, the solar thermal energy accumulation of exterior wall coating surface is reduced, so as to reach the mesh of heat insulation and heat control 's.
Colour reflective heat insulation and heat control coating of the present invention, also added silicone resin emulsion and organic silicon hydrophobic agent, its institute Comprising Si-O keys provide the excellent resistance to ag(e)ing of exterior wall paint film, colour retention, stain resistance and resistance to water.It is of the invention colored anti- Penetrating heat insulation and heat control coating can use common water borne color paste toning, and formulation cost is low, and production operation is simple, and with cold pigment black slurry generation For common carbon black color paste, exterior wall paint film heat insulation and heat control performance is enhanced.
A kind of preparation method of colour reflective heat insulation and heat control coating, its processing step is:
1)Premixing:Under the rotating speed of 300~800r/min, sequentially add in the deionized water of 14.50~29.00 weight portions The weight portion of cellulose 0.20~0.60, the weight portion of pH adjusting agent 0.10~0.20, the weight portion of dispersant 0.20~0.70, wetting agent 0.00~0.40 weight portion, the weight portion of antifreezing agent 1.00~3.00 and the weight portion of defoamer 0.15~0.30, stir;
2)Color stuffing disperses:Under the rotating speed of 600~1200r/min, the input weight portion of titanium dioxide 0.0~20.0, infra-red radiation The weight portion of filler 10.00~15.00, the weight portion of powdered whiting 3.00~12.00, the weight of heat reflection filler 3.00~6.00 Part, under the rotating speed of 1500~2000r/min, disperse 25~30 minutes;
3)Paint:Under the rotating speed of 500-800r/min, the weight portion of pure-acrylic emulsion 25.00~30.00, organic silicon emulsion are added 5.00~10.00 weight portions, the weight portion of coalescents 1.00~4.00, the weight portion of thickener 0.00~1.00 and macromolecule are heat-insulated The weight portion of premix thing 5.00~10.00, the weight portion of mould inhibitor 0.30~0.50, the weight portion of deionized water 0.50~1.00 are pre- It is slowly added to after mixing preservative 0.10-0.30 weight portions.Rotating speed is reduced to 300-600r/min, adds hollow glass micropearl 2.00 ~5.00 weight portions, the weight portion of organosilicon moisture repellent 0.30~0.60 and the weight portion of defoamer 0.10~0.20, stir, inspection Survey.
4)Toning:The weight portion of aqueous color paste 0.00~10.00 is added, the weight portion of defoamer 0.05~0.10 is added, is stirred Mix uniform, filter.
Embodiment 1
A kind of colour reflective heat insulation and heat control coating, it is made up of following components in parts by weight(It is adapted to high brightness light color(L*≥ 80):
The weight portion of deionized water 16.48
The weight portion of cellulose 0.22
The weight portion of pH adjusting agent 0.10
The weight portion of dispersant 0.40
The weight portion of wetting agent 0.10
The weight portion of antifreezing agent 1.50
The weight portion of defoamer 0.50
The weight portion of titanium dioxide 19.00
The weight portion of infra-red radiation filler 10.00
The weight portion of powdered whiting 3.00
The weight portion of heat reflection filler 4.00
The weight portion of pure-acrylic emulsion 27.00
The weight portion of organic silicon emulsion 5.00
The heat-insulated weight portion of premix thing 5.00 of macromolecule
The weight portion of coalescents 2.5
The weight portion of preservative 0.20
The weight portion of mould inhibitor 0.50
The weight portion of thickener 0.80
The weight portion of hollow glass micropearl 2.50
The weight portion of organic silicon hydrophobic agent 0.40
The weight portion of aqueous color paste 0.80
The preparation method of above-mentioned colour reflective heat insulation and heat control coating, prepares in accordance with the following methods:
1)Premixing:Under the rotating speed of 300~800r/min, in the deionized water of 15.98 weight portions cellulose is sequentially added 0.22 weight portion, the weight portion of pH adjusting agent 0.10, the weight portion of dispersant 0.40, the weight portion of wetting agent 0.10, the weight of antifreezing agent 1.50 Amount part and the weight portion of defoamer 0.25, stir;
2)Color stuffing disperses:Under the rotating speed of 600~1200r/min, the input weight portion of titanium dioxide 19.0, infra-red radiation filler 10.00 weight portions, the weight portion of powdered whiting 3.00, the weight portion of heat reflection filler 4.00, in the rotating speed of 1500~2000r/min Under, disperse 25~30 minutes;
3)Paint:Under the rotating speed of 500-800r/min, the weight portion of pure-acrylic emulsion 27.00, the weight of organic silicon emulsion 5.00 are added Part, the weight portion of coalescents 2.50, the weight portion of thickener 0.80 and the heat-insulated weight portion of premix thing 5.00 of macromolecule, mould inhibitor It is slowly added to after 0.50 weight portion, the weight portion of the deionized water 0.50 premixing weight portion of preservative 0.20.Rotating speed is reduced to 300- 600r/min, adds the weight portion of hollow glass micropearl 2.50, the weight portion of organosilicon moisture repellent 0.40 and the weight portion of defoamer 0.15, Stir, detect.
4)Toning:The weight portion of aqueous color paste 0.8 is added, the weight portion of defoamer 0.10 is added, is stirred, bag filter Dress.
Embodiment 2
A kind of colour reflective heat insulation and heat control coating, it is made up of following components in parts by weight(It is adapted to the light and middle color of middle lightness (80< L*<40):
The weight portion of deionized water 20.65
The weight portion of cellulose 0.25
The weight portion of pH adjusting agent 0.10
The weight portion of dispersant 0.40
The weight portion of wetting agent 0.10
The weight portion of antifreezing agent 1.50
The weight portion of defoamer 0.50
The weight portion of titanium dioxide 9.00
The weight portion of infra-red radiation filler 10.00
The weight portion of powdered whiting 4.00
The weight portion of heat reflection filler 4.00
The weight portion of pure-acrylic emulsion 29.00
The weight portion of organic silicon emulsion 5.00
The heat-insulated weight portion of premix thing 6.00 of macromolecule
The weight portion of coalescents 2.50
The weight portion of preservative 0.20
The weight portion of mould inhibitor 0.50
The weight portion of thickener 0.40
The weight portion of hollow glass micropearl 2.50
The weight portion of organosilicon moisture repellent 0.40
The weight portion of aqueous color paste 3.00
The preparation method of above-mentioned colour reflective heat insulation and heat control coating, prepares in accordance with the following methods:
1)Premixing:Under the rotating speed of 300~800r/min, in the deionized water of 20.15 weight portions cellulose is sequentially added 0.25 weight portion, the weight portion of pH adjusting agent 0.10, the weight portion of dispersant 0.40, the weight portion of wetting agent 0.10, the weight of antifreezing agent 1.50 Amount part and the weight portion of defoamer 0.25, stir;
2)Color stuffing disperses:Under the rotating speed of 600~1200r/min, the input weight portion of titanium dioxide 9.00, infra-red radiation filler 10.00 weight portions, the weight portion of powdered whiting 4.00, the weight portion of heat reflection filler 4.00, in the rotating speed of 1500~2000r/min Under, disperse 25~30 minutes;
3)Paint:Under the rotating speed of 500-800r/min, the weight portion of pure-acrylic emulsion 29.00, the weight of organic silicon emulsion 5.00 are added Part, the weight portion of coalescents 2.50, the weight portion of thickener 0.40 and the heat-insulated weight portion of premix thing 6.00 of macromolecule, mould inhibitor It is slowly added to after 0.50 weight portion, the weight portion of the deionized water 0.50 premixing weight portion of preservative 0.20.Rotating speed is reduced to 300- 600r/min, adds the weight portion of hollow glass micropearl 2.50, the weight portion of organosilicon moisture repellent 0.40 and the weight portion of defoamer 0.15, Stir, detect.
4)Toning:The weight portion of aqueous color paste 3.0 is added, the weight portion of defoamer 0.10 is added, is stirred, bag filter Dress.
Embodiment 3
A kind of colour reflective heat insulation and heat control coating, it is made up of following components in parts by weight(It is adapted to color and dark color in low lightness (L*≤40):
The weight portion of deionized water 21.60
The weight portion of cellulose 0.50
The weight portion of pH adjusting agent 0.10
The weight portion of dispersant 0.20
The weight portion of antifreezing agent 1.00
The weight portion of defoamer 0.50
The weight portion of infra-red radiation filler 13.00
The weight portion of powdered whiting 5.00
The weight portion of heat reflection filler 4.00
The weight portion of pure-acrylic emulsion 29.00
The weight portion of organic silicon emulsion 5.00
The heat-insulated weight portion of premix thing 6.00 of macromolecule
The weight portion of coalescents 2.50
The weight portion of preservative 0.20
The weight portion of mould inhibitor 0.50
The weight portion of hollow glass micropearl 2.50
The weight portion of organosilicon moisture repellent 0.40
The weight portion of aqueous color paste 8.00
The preparation method of above-mentioned colour reflective heat insulation and heat control coating, prepares in accordance with the following methods:
1)Premixing:Under the rotating speed of 300~800r/min, in the deionized water of 21.10 weight portions cellulose is sequentially added 0.50 weight portion, the weight portion of pH adjusting agent 0.10, the weight portion of dispersant 0.20, the weight portion of antifreezing agent 1.00 and the weight of defoamer 0.25 Amount part, stirs;
2)Color stuffing disperses:Under the rotating speed of 600~1200r/min, the weight portion of input infra-red radiation filler 13.00, heavy carbon The weight portion of sour calcium 5.00, the weight portion of heat reflection filler 4.00, under the rotating speed of 1500~2000r/min, disperse 25~30 minutes;
3)Paint:Under the rotating speed of 500-800r/min, the weight portion of pure-acrylic emulsion 29.00, the weight of organic silicon emulsion 5.00 are added Part, the weight portion of coalescents 2.50, the heat-insulated weight portion of premix thing 6.00 of macromolecule, the weight portion of mould inhibitor 0.50, use deionization It is slowly added to after the weight portion of the water 0.50 premixing weight portion of preservative 0.20.Rotating speed is reduced to 300-600r/min, adds hollow glass The weight portion of glass microballon 2.50, the weight portion of organosilicon moisture repellent 0.40 and the weight portion of defoamer 0.15, stir, detection.
4)Toning:The weight portion of aqueous color paste 8.00 is added, the weight portion of defoamer 0.10 is added, is stirred, bag filter Dress.
The above-mentioned Jing of specific embodiment 1 to 3 adopts common water borne mill base(Except carbon black color slurry)And cold pigment black slurry is entered Performance after row toning is as shown in table 1.
The colour reflective heat insulation and heat control coating property test data of table 1
As known from Table 1, by the sun reflectivity and near-infrared reflection ratio of the present invention prepared embodiment 1, embodiment 2 and embodiment 3 Meet JG/T235-2014《Architectural reflective heat-insulation High tailored coating》The requirement of standard.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (10)

1. a kind of colour reflective heat insulation and heat control coating, it is characterised in that:It is made up of following components in parts by weight:
Deionized water 15.00~30.00
Cellulose 0.20~0.60
PH adjusting agent 0.10~0.20
Dispersant 0.20~0.70
Wetting agent 0.00~0.40
Antifreezing agent 1.00~3.00
Defoamer 0.30~0.60
Titanium dioxide 0.00~20.00
Infra-red radiation filler 10.00~15.00
Powdered whiting 3.00~12.00
Heat reflection filler 3.00~6.00
Pure-acrylic emulsion 25.00~30.00
Organic silicon emulsion 5.00~10.00
The heat-insulated premix thing 5.00~10.00 of macromolecule
Coalescents 1.00~4.00
Preservative 0.10~0.30
Mould inhibitor 0.30~0.50
Thickener 0.00~1.00
Hollow glass micropearl 2.00~5.00
Organosilicon moisture repellent 0.30~0.60
Aqueous color paste 0.00~10.00.
2. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The cellulose is hydroxy ethyl fiber Element.
3. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The dispersant is polycarboxylic acids ammonium salt.
4. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The defoamer is mineral oils froth breaking Agent.
5. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The antifreezing agent is propane diols.
6. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The infra-red radiation filler is kaolinite The mixture of soil, mica powder, talcum powder, diatomite, zinc oxide and far-infrared powder.
7. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The heat-insulated premix thing of the macromolecule is The premix of opacity polymer, emissivity functional group modification polymer and expandable microspheres.
8. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The aqueous color paste be aqueous color paste and One kind of cold pigment black slurry or arbitrarily two or more compositions.
9. colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that:The mould inhibitor spreads out for OIT Biological or benzimidazole ester type compound and its derivative.
10. a kind of preparation method of colour reflective heat insulation and heat control coating as claimed in claim 1, it is characterised in that including following Step:
(1), it is pre-mixed:Under the rotating speed of 300~800r/min, the following component mixing of weight portion stirs:Deionization Water 14.50~29.00, cellulose 0.20~0.60, pH adjusting agent 0.10~0.20, dispersant 0.20~0.70, wetting agent 0.00~0.40, antifreezing agent 1.00~3.00 and defoamer 0.15~0.30;
(2), color stuffing dispersion:Step premixing material (1), under the rotating speed of 600~1200r/min, adds weight portion as follows Component:Titanium dioxide 0.0~20.0, infra-red radiation filler 10.00~15.00, powdered whiting 3.00~12.00, heat reflection Filler 3.00~6.00, under the rotating speed of 1500~2000r/min, disperses 25~30 minutes;
(3), paint:Step (2) dispersed material, under the rotating speed of 500-800r/min, the component for adding weight portion following:Pure third is newborn Liquid 25.00~30.00, organic silicon emulsion 5.00~10.00, coalescents 1.00~4.00, thickener 0.00~1.00 and height The heat-insulated premix thing 5.00~10.00 of molecule, is slow added into mould inhibitor 0.30~0.50, deionized water 0.50~1.00 and premixes Close preservative 0.10-0.30;Rotating speed is reduced to 300-600r/min, adds hollow glass micropearl 2.00~5.00, organosilicon hydrophobic Agent 0.30~0.60 and defoamer 0.10~0.20, stir;
(4), mix colours:(3) stir in material to step, add aqueous color paste 0.00~10.00, add defoamer 0.05~ 0.10, stir, filter, obtain filtrate.
CN201611193526.1A 2016-12-21 2016-12-21 Color reflection heat insulation and temperature reduction paint and preparation method thereof Pending CN106634349A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611193526.1A CN106634349A (en) 2016-12-21 2016-12-21 Color reflection heat insulation and temperature reduction paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611193526.1A CN106634349A (en) 2016-12-21 2016-12-21 Color reflection heat insulation and temperature reduction paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106634349A true CN106634349A (en) 2017-05-10

Family

ID=58834636

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611193526.1A Pending CN106634349A (en) 2016-12-21 2016-12-21 Color reflection heat insulation and temperature reduction paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106634349A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189600A (en) * 2017-05-31 2017-09-22 句容市恒鑫遮阳科技有限公司 A kind of outdoor heat insulation and heat control coating used for textiles and preparation method thereof
CN107722751A (en) * 2017-05-11 2018-02-23 南昌大学 A kind of novel aqueous heat insulating reflecting coating and preparation method thereof
CN110306679A (en) * 2019-05-21 2019-10-08 重庆多仑建材有限公司 A kind of exterior wall reflective thermal insulation heat-insulation system
CN110396316A (en) * 2019-07-23 2019-11-01 太仓淼品源材料科技有限公司 A kind of low thermal conductivity infrared-reflection heat-insulation coating and preparation method thereof
CN110643244A (en) * 2019-10-14 2020-01-03 杭州美多乐环保新材料有限公司 Reflective heat-insulating coating for buildings and preparation method thereof
CN111635681A (en) * 2020-05-07 2020-09-08 上海大学 Water-based reflective heat-insulating hydrophobic coating and preparation method thereof
CN112457699A (en) * 2020-11-24 2021-03-09 佛山市顺德区中辐环保科技有限公司 Bactericidal functional coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343453A (en) * 2008-08-12 2009-01-14 无锡市虎皇漆业有限公司 Aqueous and elastic thermal-insulation energy-conservation paint and preparation thereof
CN102477241A (en) * 2010-11-26 2012-05-30 深圳市嘉达高科产业发展有限公司 Highly contamination resistant heat-insulating building coating
CN103146275A (en) * 2013-03-05 2013-06-12 北京国泰瑞华精藻硅特种材料有限公司 Grey heat-insulation flame-retardant external wall paint
CN104877474A (en) * 2015-05-29 2015-09-02 江苏恒智纳米科技有限公司 Nanometer reflective heat-insulation coating for exterior wall and preparation technique thereof
CN105567021A (en) * 2015-04-16 2016-05-11 湖南省金海科技有限公司 Water-based cold-pigment multifunctional heat-insulating true stone paint for exterior wall and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343453A (en) * 2008-08-12 2009-01-14 无锡市虎皇漆业有限公司 Aqueous and elastic thermal-insulation energy-conservation paint and preparation thereof
CN102477241A (en) * 2010-11-26 2012-05-30 深圳市嘉达高科产业发展有限公司 Highly contamination resistant heat-insulating building coating
CN103146275A (en) * 2013-03-05 2013-06-12 北京国泰瑞华精藻硅特种材料有限公司 Grey heat-insulation flame-retardant external wall paint
CN105567021A (en) * 2015-04-16 2016-05-11 湖南省金海科技有限公司 Water-based cold-pigment multifunctional heat-insulating true stone paint for exterior wall and preparation method thereof
CN104877474A (en) * 2015-05-29 2015-09-02 江苏恒智纳米科技有限公司 Nanometer reflective heat-insulation coating for exterior wall and preparation technique thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李东光: "《实用化工产品配方与制备 (九)》", 31 August 2013, 中国纺织出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107722751A (en) * 2017-05-11 2018-02-23 南昌大学 A kind of novel aqueous heat insulating reflecting coating and preparation method thereof
CN107189600A (en) * 2017-05-31 2017-09-22 句容市恒鑫遮阳科技有限公司 A kind of outdoor heat insulation and heat control coating used for textiles and preparation method thereof
CN110306679A (en) * 2019-05-21 2019-10-08 重庆多仑建材有限公司 A kind of exterior wall reflective thermal insulation heat-insulation system
CN110396316A (en) * 2019-07-23 2019-11-01 太仓淼品源材料科技有限公司 A kind of low thermal conductivity infrared-reflection heat-insulation coating and preparation method thereof
CN110643244A (en) * 2019-10-14 2020-01-03 杭州美多乐环保新材料有限公司 Reflective heat-insulating coating for buildings and preparation method thereof
CN111635681A (en) * 2020-05-07 2020-09-08 上海大学 Water-based reflective heat-insulating hydrophobic coating and preparation method thereof
CN112457699A (en) * 2020-11-24 2021-03-09 佛山市顺德区中辐环保科技有限公司 Bactericidal functional coating

Similar Documents

Publication Publication Date Title
CN106634349A (en) Color reflection heat insulation and temperature reduction paint and preparation method thereof
CN101870842B (en) Aqueous cold pigment double-coat multifunctional thermal-insulation external wall paint and preparation method thereof
CN103214905B (en) A kind of temperature sensing color changing thermal insulating coating and preparation method thereof
CN101712835B (en) Heat reflection paint with hollow glass microballoon
CN105694629B (en) Nano transparent insulating coating and preparation method thereof
CN103074002B (en) Intelligent temperature-control energy-saving composite coating film
CN103073943B (en) Vanadium dioxide intelligent temperature control coating
CN105567021B (en) A kind of aqueous cold pigment multifunctional thermal-insulation exterior wall true stone paint and preparation method thereof
CN102277058B (en) Compound deep color water-based insulating exterior wall coating and preparation method thereof
CN106380972B (en) Colorful complex layer coating with incubation and thermal insulation function and preparation method thereof
CN102826810B (en) Reflective heat-insulation powder coating and preparation method thereof
WO2017028471A1 (en) Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof
CN103146269A (en) Preparation method for water-based high reflection radiation compound heat preservation and heat insulation coatings
CN103421394B (en) Functional type water fever radiation multicolor finish preparation method and application
CN105176211A (en) Organic-inorganic composite thermal insulation paint and preparation method thereof
CN108610815A (en) Aerosil composite thermal barrier coatings and preparation method thereof
CN106634461A (en) Oxidized graphene heat insulation glass double-ingredient paint and preparation method thereof
CN106007571A (en) Inorganic dry powder heat insulation paint
CN109456675A (en) A kind of heat-insulated camouflage painting composite coating of watery anti-corrosion
CN103183996B (en) High-effect reflective heat-insulation paint and preparation method thereof
CN102115620A (en) Colored ternary thermal insulation paint
CN106084962A (en) Adiabatic compositions of additives and purposes
CN105131764A (en) Reflective heat-insulation texture coating and preparation method thereof
CN101824258A (en) Waterborne reflective heat-insulating building coating
CN105755800A (en) A thermal reflective coating cloth

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170510

RJ01 Rejection of invention patent application after publication