CN108841333A - Black single-sided conductive adhesive tape and preparation method thereof and coating for conductive tape - Google Patents

Black single-sided conductive adhesive tape and preparation method thereof and coating for conductive tape Download PDF

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Publication number
CN108841333A
CN108841333A CN201810633260.0A CN201810633260A CN108841333A CN 108841333 A CN108841333 A CN 108841333A CN 201810633260 A CN201810633260 A CN 201810633260A CN 108841333 A CN108841333 A CN 108841333A
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CN
China
Prior art keywords
parts
coating
black
conductive adhesive
conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810633260.0A
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Chinese (zh)
Inventor
邓联文
吴娜娜
施艳萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HANPING (KUNSHAN) ELECTRONIC CO Ltd
Original Assignee
HANPING (KUNSHAN) ELECTRONIC CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HANPING (KUNSHAN) ELECTRONIC CO Ltd filed Critical HANPING (KUNSHAN) ELECTRONIC CO Ltd
Priority to CN201810633260.0A priority Critical patent/CN108841333A/en
Publication of CN108841333A publication Critical patent/CN108841333A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/02Electrically-conducting adhesives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/314Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses black single-sided conductive adhesive tapes, it is related to single-sided conductive adhesive tape area, including what is set gradually from top to bottom, conductive fiber and conductive adhesive film, the conductive fiber upper layer is also attached with the coating of black, conduction, ethanol-tolerant, and the coating includes by mass parts:Epoxy resin, carbon black wrap up toner, levelling agent, defoaming agent, isophorone.The application is by being provided with the primary coating with black, conduction, alcohol resistance energy on conductive tape surface, so that will not impact to the electric conductivity of the application when being wiped using alcohol.

Description

Black single-sided conductive adhesive tape and preparation method thereof and coating for conductive tape
Technical field
The present invention relates to conductive tape field, in particular to black single-sided conductive adhesive tape and preparation method thereof and for conduction The coating of adhesive tape.
Background technique
Adhesive tape used in modern electronic materialss is many kinds of, it is related to multiple fields and subject in electronics industry.Mesh Preceding conventional use of black single-sided conductive cloth rubber belt, uses more and plays bound edge below mobile phone screen, computer screen, shading, leads Electric screening action, can have that screen surface is dirty to go to wipe with alcohol in use, on the market existing black conductive Cloth is that will cause screen surface secondary pollution in wiping process, therefore a surface ethanol-tolerant of demand is black without alcohol tolerance Color conductive tape, while original black conductive cloth shading, electric conductivity need to be covered, the above problem is asking for this field urgent need to resolve Topic.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of shading, conduction and the black single-sided conductives with alcohol resistance energy Adhesive tape.
The technical solution adopted by the present invention to solve the technical problems is:Black single-sided conductive adhesive tape, including from top to bottom It setting gradually, conductive fiber and conductive adhesive film, the conductive fiber upper layer are also attached with the coating of black, conduction, ethanol-tolerant, The coating includes by mass parts:35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, 3 to 10 parts of toner are wrapped up, levelling agent 0.5 To 1.5 parts, 0.2 to 1 part of defoaming agent, 13 to 30 parts of isophorone.
The application by conductive tape surface be provided with it is primary with black, conduction, alcohol resistance can coating so that When being wiped using alcohol will not electric conductivity to the application and shading performance impact.
It is further:The conductive fiber includes fibrous layer, is attached with nickel layer on the fibrous layer, attached on the nickel layer Have the layers of copper of high conductivity, be attached with antioxidant, etch-proof nickel metal layer in the layers of copper, set on the conductive fiber Set the one side setting polyurethane adhesive of coating.
It is further:Overall thickness is 0.01mm to 0.5mm.
It is further:The conductive adhesive film lower layer is also attached with release layer.
Invention further provides the production method of black single-sided conductive adhesive tape, used technical solution is:System The method for making black single-sided conductive adhesive tape, includes the following steps:
S0:The coating with black, conduction, alcohol resistance energy is made, is specifically included the following steps:
A, sequentially added by mass parts into stirred tank 35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, levelling agent 0.5 to Then 13 to 30 parts of 1.5 parts, 0.2 to 1 part of defoaming agent and isophorone are stirred up to forming uniform dispersed paste,
B, the dispersed paste is poured into grinder and is ground, until fine and smooth ink is formed,
C, the ink is put into stirred tank to and is added 3 to 10 parts of toner of package, be mixed makes the two uniformly Mixing,
D, slurry mixed in step c is filtered,
E, filtered slurry is stood and is vented;
S1, conductive fiber is laid with as substrate;
S2, the coating to the coating of conductive fiber upper surface with black, conduction, alcohol resistance energy;
S3, the another side attaching conductive adhesive film in conductive fiber.
It is further:Mixing time is 25min to 50min in the step a, and milling time is in the step b Mixing time is 15min to 45min in 60min to 90min, the step c, in the step e evacuation time be 20min extremely 50min。
It is further:It is coated in coater oven in the step S2 using the coating made in step S0.
It is further:The coater oven temperature is 80 DEG C to 150 DEG C, coating speed 5m/min to 20m/min.
Invention further provides the coating for conductive tape, used technical solution is:For conductive tape Coating, mass parts include:35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, wrap up 3 to 10 parts of toner, levelling agent 0.5 to 1.5 parts, 0.2 to 1 part of defoaming agent, 13 to 30 parts of isophorone.
The beneficial effects of the invention are as follows:The application has black, conduction, resistance to by being provided with once on conductive tape surface The coating of alcohol performance so that when being wiped using alcohol will not electric conductivity to the application and shading performance cause shadow It rings.The application joined carbon black in the coating and wrap up in toner, and by the cooperation of other components so that the application is with good Electric conductivity and alcohol tolerance.
Detailed description of the invention
Fig. 1 is the application flow diagram.
Fig. 2 is the application structural schematic diagram.
In figure label for:Coating 1, conductive fiber 2, conductive adhesive film 3, release layer 4.
Specific embodiment
The present invention is further described with reference to the accompanying drawings and detailed description.
Black single-sided conductive adhesive tape, including what is set gradually from top to bottom, conductive fiber 2 and conductive adhesive film 3, the conduction 2 upper layer of fiber is also attached with the coating 1 of black, conduction, ethanol-tolerant, and the conductive fiber 2 includes fibrous layer, on the fibrous layer It is electroplate with nickel layer, the layers of copper of high conductivity is coated on the nickel layer, antioxidant, etch-proof nickel gold are electroplate in the layers of copper Belong to layer, the one side that coating 1 is arranged on the conductive fiber 2 is coated with polyurethane adhesive, and copper and mickel combines and provides splendid conduction Property and good effectiveness;Occur inverse osmosis, the conduction when its single side, which is coated with polyurethane glue, to prevent coating 1 Glue film 3 can be conductive heat melten gel and be set to 2 lower surface of conductive fiber by hot pressing, also electrically conductive polyurethane laminate or third Olefin(e) acid glue film is set to the lower surface of conductive fiber 2 by pressing with docile.
The application specifically additionally provide with black, conduction, ethanol-tolerant coating 1, the coating 1 press mass parts packet It includes:35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, 3 to 10 parts of toner of package, 0.5 to 1.5 part of levelling agent, defoaming agent 0.2 To 1 part, 13 to 30 parts of isophorone.
The wherein epoxy resin:As matrix resin, ink is made to be firmly attached to coated article surface, is to constitute conductive oil The basis of ink;The carbon black:As shading dyes, while providing electric conductivity;Wrap up toner:That is conducting powder plays conductive work With;Levelling agent:As auxiliary agent, 1 surface uniformity of coating when improving production;Defoaming agent:As auxiliary agent, product can be carried out Defoaming;Isophorone:Lytic agent and chemically synthesized intermediate as matrix resin;
The application is by carbon black and wraps up in toner, so that the coating 1 in the application has good conductive property, in addition, adopting Use epoxy resin as host and cooperation isophorone and cooperation so that the application has good alcohol tolerance.The application's Overall thickness may be configured as 0.01mm to 0.5mm.
After tested, the application attaches and product surface, uses alcohol with 300gf wiping 10 times, coating 1 without fall off, without de- Pornographic condition occurs, and the application sheet resistance X/Y/Z is to respectively less than 0.1 Ω/inch2, light-proofness is up to 85%.
In addition, 3 lower layer of conductive adhesive film is also attached with release layer 4, the release layer in order to be easy to use the application 4 can be release film, and the layer upper surface and conductive adhesive film 3 of the release film attach.
In order to make it easy to understand, present invention also provides the specific embodiments of several coatings 1 proportion.
Embodiment one
The coating 1 includes by mass parts:35 parts of epoxy resin, 45 parts of carbon black, 3 parts of toner of package, 0.5 part of levelling agent, 0.2 part of defoaming agent, 13 parts of isophorone.
Embodiment two
The coating 1 includes by mass parts:45 parts of epoxy resin, 60 parts of carbon black, 5 parts of toner is wrapped up, 1 part of levelling agent, is disappeared 0.6 part of infusion, 22 parts of isophorone.
Embodiment three
The coating 1 includes by mass parts:55 parts of epoxy resin, 80 parts of carbon black, 10 parts of toner of package, 1.5 parts of levelling agent, 1 part of defoaming agent, 30 parts of isophorone.
On the basis of the above, present invention also provides the production methods of production black single-sided conductive adhesive tape, including following step Suddenly:
S0:The coating 1 with black, conduction, alcohol resistance energy is made, is specifically included the following steps:
A, sequentially added by mass parts into stirred tank 35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, levelling agent 0.5 to Then 13 to 30 parts of 1.5 parts, 0.2 to 1 part of defoaming agent and isophorone are stirred until form uniform dispersed paste, due to Viscosity will increase after carbon black is added, therefore mixing speed is unsuitable too fast, and mixing speed can be stirred by 600-1000r/min, Specific mixing time is 25min to 50min, the specific can be that 25min, 35min, 40min or 50min.
B, the dispersed paste is poured into grinder and is ground, until form fine and smooth ink, during this process for Be fully ground dispersed paste, the milling time preferably in 60min to 90min, the specific can be that 60min, 70min, 80min or 90min.
C, the ink is put into stirred tank to and is added 3 to 10 parts of toner of package, be mixed makes the two uniformly Mixing is solid particle due to wrapping up in toner, and mixing speed is also unsuitable too fast, mixing speed can by 600-1000r/min into Row stirring, specific mixing time is 15min to 45min, the specific can be that 15min, 25min, 35min or 45min.
D, slurry mixed in step c is filtered, specifically, the strainer that 400 mesh can be used is filtered, due to There are certain viscosityes can not filter if filter screen is too small for slurry, and filter screen then filters greatly very much insufficient.
E, filtered slurry is stood and is vented, in order to sufficiently exclude bubble, the evacuation time is 20min to 50min, The specific can be that 20min, 30min, 40min or 50min;
S1, conductive fiber 2 is laid with as substrate;
S2, the coating 1 to the coating of 2 upper surface of conductive fiber with black, conduction, alcohol resistance energy, particularly use Slurry is coated on the upper surface of conductive fiber 2, the coater oven temperature by the slurry made in step S0 in coater oven It is 80 DEG C to 150 DEG C, coating speed 5m/min to 20m/min, slurry is allowed to dry and be solidified into during being coated Type, to form coating 1 in conductive fiber surfaces.
S3, coating 1 will be attached with and the conductive fiber 2 being cured takes out, attaches pressing in the another side of conductive fiber 2 and leads Electric glue film 3, completes the production.
The application is made by being provided with the primary coating 1 with black, conduction, alcohol resistance energy on conductive tape surface It obtains and alcohol is used not impact to the electric conductivity of the application when being wiped.The application joined carbon black in coating 1 With wrap up in toner, and by the cooperation of other components so that the application has good conductive property and alcohol tolerance.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in guarantor of the invention Within the scope of shield.

Claims (9)

1. black single-sided conductive adhesive tape, including what is set gradually from top to bottom, conductive fiber (2) and conductive adhesive film (3), feature It is:Conductive fiber (2) upper layer is also attached with the coating (1) of black, conduction, ethanol-tolerant, and the coating (1) presses mass parts Including:35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, 3 to 10 parts of toner of package, 0.5 to 1.5 part of levelling agent, defoaming agent 0.2 To 1 part, 13 to 30 parts of isophorone.
2. black single-sided conductive adhesive tape as described in claim 1, it is characterised in that:The conductive fiber (2) includes fibrous layer, It is attached with nickel layer on the fibrous layer, the layers of copper of high conductivity is attached on the nickel layer, is attached in the layers of copper anti-oxidation Polyurethane adhesive is arranged in agent, etch-proof nickel metal layer, the one side that coating (1) is arranged on the conductive fiber (2).
3. black single-sided conductive adhesive tape as described in claim 1, it is characterised in that:Overall thickness is 0.01mm to 0.5mm.
4. black single-sided conductive adhesive tape as claimed any one in claims 1 to 3, it is characterised in that:The conductive adhesive film (3) Lower layer is also attached with release layer (4).
5. the method for making black single-sided conductive adhesive tape, it is characterised in that:Include the following steps:
S0:The coating (1) with black, conduction, alcohol resistance energy is made, is specifically included the following steps:
A, 35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, levelling agent 0.5 to 1.5 are sequentially added into stirred tank by mass parts Then 13 to 30 parts of part, 0.2 to 1 part of defoaming agent and isophorone are stirred up to forming uniform dispersed paste,
B, the dispersed paste is poured into grinder and is ground, until fine and smooth ink is formed,
C, the ink is put into stirred tank to and is added 3 to 10 parts of toner of package, be mixed makes the two uniformly mixing,
D, slurry mixed in step c is filtered,
E, filtered slurry is stood and is vented;
S1, conductive fiber (2) are laid with as substrate;
S2, the coating (1) to the coating of conductive fiber (2) upper surface with black, conduction, alcohol resistance energy;
S3, another side attaching conductive adhesive film (3) in conductive fiber (2).
6. the method for production black single-sided conductive adhesive tape as claimed in claim 5, it is characterised in that:It is stirred in the step a Time is 25min to 50min, and milling time is 60min to 90min in the step b, and mixing time is in the step c Evacuation time is 20min to 50min in 15min to 45min, the step e.
7. the method for production black single-sided conductive adhesive tape as claimed in claim 6, it is characterised in that:It is used in the step S2 The coating (1) made in step S0 is coated in coater oven.
8. the method for production black single-sided conductive adhesive tape as claimed in claim 7, it is characterised in that:The coater oven temperature It is 80 DEG C to 150 DEG C, coating speed 5m/min to 20m/min.
9. being used for the coating of conductive tape, it is characterised in that:Mass parts include:35 to 55 parts of epoxy resin, 45 to 80 parts of carbon black, 3 to 10 parts of toner, 0.5 to 1.5 part of levelling agent, 0.2 to 1 part of defoaming agent, 13 to 30 parts of isophorone of package.
CN201810633260.0A 2018-06-20 2018-06-20 Black single-sided conductive adhesive tape and preparation method thereof and coating for conductive tape Pending CN108841333A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810633260.0A CN108841333A (en) 2018-06-20 2018-06-20 Black single-sided conductive adhesive tape and preparation method thereof and coating for conductive tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810633260.0A CN108841333A (en) 2018-06-20 2018-06-20 Black single-sided conductive adhesive tape and preparation method thereof and coating for conductive tape

Publications (1)

Publication Number Publication Date
CN108841333A true CN108841333A (en) 2018-11-20

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011194824A (en) * 2010-03-23 2011-10-06 Achilles Corp Shading film and shading adhesive sheet using the same
CN105754512A (en) * 2016-03-28 2016-07-13 江苏伊诺尔新材料科技有限公司 Non-bright, anti-fingerprint and scraping-resistant single-side adhesive tape for conductive fabric and preparation method
CN107022316A (en) * 2017-03-22 2017-08-08 深圳市金晖科技有限公司 A kind of preparation method of ultra-thin light-shielding conductive metal composite membrane adhesive tape
CN207362122U (en) * 2017-06-27 2018-05-15 深圳市佰瑞兴实业有限公司 A kind of solvent-proof suction ripple shielding tape

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011194824A (en) * 2010-03-23 2011-10-06 Achilles Corp Shading film and shading adhesive sheet using the same
CN105754512A (en) * 2016-03-28 2016-07-13 江苏伊诺尔新材料科技有限公司 Non-bright, anti-fingerprint and scraping-resistant single-side adhesive tape for conductive fabric and preparation method
CN107022316A (en) * 2017-03-22 2017-08-08 深圳市金晖科技有限公司 A kind of preparation method of ultra-thin light-shielding conductive metal composite membrane adhesive tape
CN207362122U (en) * 2017-06-27 2018-05-15 深圳市佰瑞兴实业有限公司 A kind of solvent-proof suction ripple shielding tape

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘新: "《电力工业防腐涂装技术》", 31 January 2010, 中国电力出版社 *

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Application publication date: 20181120