CN108822948A - A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam - Google Patents
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam Download PDFInfo
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- CN108822948A CN108822948A CN201810493290.6A CN201810493290A CN108822948A CN 108822948 A CN108822948 A CN 108822948A CN 201810493290 A CN201810493290 A CN 201810493290A CN 108822948 A CN108822948 A CN 108822948A
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- metalworking fluid
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- surfactant
- emulsifier
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- 239000006260 foam Substances 0.000 title claims abstract description 34
- 239000012530 fluid Substances 0.000 title claims abstract description 29
- 238000005555 metalworking Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002173 cutting fluid Substances 0.000 claims abstract description 29
- 239000004094 surface-active agent Substances 0.000 claims abstract description 29
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 24
- 239000013556 antirust agent Substances 0.000 claims abstract description 24
- 239000008233 hard water Substances 0.000 claims abstract description 24
- 239000003755 preservative agent Substances 0.000 claims abstract description 23
- 230000002335 preservative effect Effects 0.000 claims abstract description 23
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000002480 mineral oil Substances 0.000 claims abstract description 15
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims description 42
- 239000007788 liquid Substances 0.000 claims description 30
- 229960004418 trolamine Drugs 0.000 claims description 15
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 14
- -1 alcohol ether carboxylate Chemical class 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 7
- 230000000844 anti-bacterial effect Effects 0.000 claims description 7
- 239000003899 bactericide agent Substances 0.000 claims description 7
- 239000012964 benzotriazole Substances 0.000 claims description 7
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 7
- 238000005352 clarification Methods 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 238000010348 incorporation Methods 0.000 claims description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical group [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims description 7
- 239000004299 sodium benzoate Substances 0.000 claims description 7
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 6
- 239000012875 nonionic emulsifier Substances 0.000 claims description 6
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 5
- 239000010779 crude oil Substances 0.000 claims description 5
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical class CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 abstract description 8
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 150000002989 phenols Chemical class 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 4
- 239000002199 base oil Substances 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical group OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000012224 working solution Substances 0.000 description 2
- GOLXRNDWAUTYKT-UHFFFAOYSA-N 3-(1H-indol-3-yl)propanoic acid Chemical group C1=CC=C2C(CCC(=O)O)=CNC2=C1 GOLXRNDWAUTYKT-UHFFFAOYSA-N 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229960005068 monoethanolamine oleate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention provides a kind of low environment-friendly type microemulsified metalworking fluid of foam, the parts by weight of raw material are：20~30 parts of mineral oil, 5~8 parts of organic dibasic acid, 3~7 parts of triethanolamine, 3~7 parts of single hydramine, hard water resistance dose 1~3 part, 0.5~1 part of antirust agent, 0.1~0.3 part of antibacterial agent, 0.1~0.3 part of preservative, 11~14 parts of surfactant, 0.2-1.0 parts of emulsifier, 30~40 parts of water.Base oil used is the mineral oil that structure is uniform, low toxicity low evil, easily emulsifies, other raw materials are free of phenols, nitrite and heavy metallic salt；The present invention also provides the preparation methods of this cutting fluid simultaneously, have lower interfacial tension using cutting fluid made from this method, thus are not easy to spume.
Description
Technical field
The present invention relates to metalworking fluid field more particularly to a kind of systems of the environment-friendly type microemulsified metalworking fluid of low foam
Preparation Method.
Background technique
Cutting fluid is essential important consumptive material in metal cutting and machining, is had in metal cutting process cold
But, the critical functions such as lubrication, antirust, cleaning.At present on the market cutting fluid mainly have emulsified cutting fluid, semi-synthetic cutting fluid and
Fully synthetic cutting fluid three categories.Be easy to make bacterial reproduction when emulsified cutting fluid ingress of air, make emulsion it is corrupt, it is rotten,
It is smelly, it shortens the working life；Fully synthetic cutting fluid lubrication and rustless property are poor；Semi-synthetic cutting fluid combines emulsifying cutting
The properties advantage of liquid and fully synthetic cutting fluid, comprehensive performance with higher, but its is easy to foaming.With modern instruments plus
Work is popularized, and the demand to high-performance cutting fluid is more and more, to obtain more preferably machining surface.Due to import height
Shelves cutting fluid is expensive, limits its large-scale promotion application, therefore develop the high-grade water-based metal working fluid of super quality and competitive price,
To meet the needs of machining center material processing diversity and technique processing diversity are to high-performance cutting fluid market.In addition, working as
Modern Green Sustainable theory greatly enhances the environmental consciousness of people, and it is advanced that clean manufacturing, green manufacturing have become development
One of theme of manufacturing technology.
Summary of the invention
The problems such as poor, easy to be corrupt, easy to foaming, price is high for lubricity existing for existing cutting fluid and rust-preventing characteristic, this hair
Bright to provide a kind of environment-friendly type microemulsified metalworking fluid of low foam, base oil used is uniform structure, the low evil of low toxicity, easily emulsifies
Mineral oil, other raw materials are free of phenols, nitrite and heavy metallic salt；The present invention also provides this cutting fluids simultaneously
Preparation method has lower interfacial tension using cutting fluid made from this method, thus is not easy to spume.
A kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：20~30 parts of mineral oil, organic two
First acid 5~8 parts, 3~7 parts of triethanolamine, 3~7 parts of single hydramine, hard water resistance dose 1~3 part, 0.5~1 part of antirust agent, antibacterial agent
0.1~0.3 part, 0.1~0.3 part of preservative, 11~14 parts of surfactant, 0.2-1.0 parts of emulsifier, 30~40 parts of water.
Preferably, a kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：23 parts of naphthene base crude oil,
7 parts of organic dibasic acid, 5 parts of triethanolamine, 5 parts of single hydramine, hard water resistance dose 1.5 parts, 0.5 part of antirust agent, 0.2 part of antibacterial agent,
0.2 part of preservative, 12 parts of surfactant, 0.6 part of emulsifier, 35 parts of water.
Described hard water resistance dose is hard water resistance dose of alcohol ether carboxylate class；The antirust agent is benzotriazole.
The antibacterial agent is morpholine bactericide；The preservative is sodium benzoate.
The surfactant is sulfuric acid triethanolamine soap, triethanolamine oleate, fatty alcohol, four poly- ricinoleic acids
Any three kinds of compositions in ester, oleic acid.
The emulsifier is nonionic emulsifier fatty alcohol alkoxy compound.
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam, includes the following steps：
（1）Organic dibasic acid, triethanolamine, monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature
It is 30~50 DEG C, incorporation time is 30~60 min, obtains clarification mixed liquor A；
（2）Mineral oil is heated 40~60 DEG C, under stirring, antibacterial agent, preservative, emulsifier, constant temperature stirring 30 is added
~60 min, obtain mixed liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
The step（3）Middle mixed liquid B is added to the mode in mixed liquor A as uniform speed slow addition, and it is 0.4 that speed, which is added,
~1.2 Kg/min.
Beneficial effect of the present invention
1, low foam
Low foam environment-friendly type Emulsified Metal Cutting Fluid prepared by the present invention is because having lower interfacial tension, to be not likely to produce bubble
Foam, visual specific environment condition can be not added in use or slightly defoaming agent, invention are compounded by each raw material, phase
It mutually influences to reduce surface tension, the lowest surface tension of 5% working solution of product is 29 dyn/cm, is significantly less than GB/T6144-85
The numerical value of standard value or similar product, and the stability in storage of this product is good, room temperature can be saved at least 1 year or more.
2, environment-friendly type
Low foam environment-friendly type Emulsified Metal Cutting Fluid prepared by the present invention, base oil used are uniform structure, the low evil of low toxicity, easy cream
The mineral oil of change, other raw material are without phenols, nitrite and heavy metallic salt, and safety and environmental protection is easily handled.
3, preparation method is simple
Preparation method provided by the invention mixes water-soluble component with water, and oil-soluble constitents are mixed with oil heating, finally will
The two mixing, is finally made low foam environment-friendly type Emulsified Metal Cutting Fluid, preparation method is simple, preparation condition is mild, original used
Material is free of phenols, nitrite and heavy metallic salt, no pollution to the environment, safety and environmental protection harmless to human health.
4, using wide
The low foam environment-friendly type Emulsified Metal Cutting Fluid that the present invention prepares, since foam is few when processing uses, it may not be necessary to add
Defoaming agent is solved because of foam bring a series of problems, can be widely applied to the intermetallic composite coatings such as cast iron, carbon steel, steel alloy, raw
It produces at low cost, is worthy to be popularized.
Specific embodiment
Embodiment 1
A kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：20 parts of mineral oil, 5 parts of organic dibasic acid,
3 parts of triethanolamine, 7 parts of single hydramine, hard water resistance dose 1 part, 0.5 part of antirust agent, 0.3 part of antibacterial agent, 0.3 part of preservative, surface
11 parts of activating agent, 0.4 part of emulsifier, 30 parts of water.
Described hard water resistance dose is hard water resistance dose of alcohol ether carboxylate class；The antirust agent is benzotriazole.
The antibacterial agent is morpholine bactericide；The preservative is sodium benzoate.
The surfactant is 9 parts of sulfuric acid triethanolamine soap, 2 parts of triethanolamine oleate, 1 part of fatty alcohol.
The emulsifier is nonionic emulsifier fatty alcohol alkoxy compound.
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam, includes the following steps：
（1）Organic dibasic acid, triethanolamine, monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature
It is 30 DEG C, incorporation time is 60 min, obtains clarification mixed liquor A；
（2）Mineral oil is heated 40 DEG C, under stirring, antibacterial agent, preservative, emulsifier is added, constant temperature stirs 60 min,
Obtain mixed liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
The step（3）Middle mixed liquid B is added to the mode in mixed liquor A as uniform speed slow addition, and speed, which is added, is
0.4Kg/min。
Embodiment 2
A kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：30 parts of mineral oil, 8 parts of organic dibasic acid,
7 parts of triethanolamine, 3 parts of single hydramine, hard water resistance dose 3 parts, 1 part of antirust agent, 0.1 part of antibacterial agent, 0.1 part of preservative, surface work
Property 14 parts of agent, 0.8 part of emulsifier, 40 parts of water.
Described hard water resistance dose is hard water resistance dose of alcohol ether carboxylate class；The antirust agent is benzotriazole.
The antibacterial agent is morpholine bactericide；The preservative is sodium benzoate.
The surfactant is 2 parts of fatty alcohol, 9 parts of Monoethanolamine Oleate soap, 3 parts of oleic acid.
The emulsifier is nonionic emulsifier fatty alcohol alkoxy compound.
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam, includes the following steps：
（1）Organic dibasic acid, triethanolamine, monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature
It is 50 DEG C, incorporation time is 30 min, obtains clarification mixed liquor A；
（2）Mineral oil is heated 60 DEG C, under stirring, antibacterial agent, preservative, emulsifier is added, constant temperature stirs 30 min,
Obtain mixed liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
The step（3）Middle mixed liquid B is added to the mode in mixed liquor A as uniform speed slow addition, and it is 1.2 that speed, which is added,
Kg/min。
Embodiment 3
A kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：23 parts of naphthene base crude oil, organic dibasic acid 7
Part, 5 parts of triethanolamine, 5 parts of single hydramine, hard water resistance dose 1.5 parts, 0.5 part of antirust agent, 0.2 part of antibacterial agent, 0.2 part of preservative,
12 parts of surfactant, 0.6 part of emulsifier, 35 parts of water.
Described hard water resistance dose is hard water resistance dose of alcohol ether carboxylate class；The antirust agent is benzotriazole.
The antibacterial agent is morpholine bactericide；The preservative is sodium benzoate.
The surfactant is 7 parts of triethanolamine oleate, 2 parts of fatty alcohol, four 3 parts of poly- ricinoleate esters.
The emulsifier is nonionic emulsifier fatty alcohol alkoxy compound.
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam, includes the following steps：
（1）Organic dibasic acid, triethanolamine, monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature
It is 40 DEG C, incorporation time is 50 min, obtains clarification mixed liquor A；
（2）Mineral oil is heated 50 DEG C, under stirring, antibacterial agent, preservative, emulsifier is added, constant temperature stirs 50 min,
Obtain mixed liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
The step（3）Middle mixed liquid B is added to the mode in mixed liquor A as uniform speed slow addition, and it is 0.8 that speed, which is added,
Kg/min。
1 raw material of comparative example changes
A kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：23 parts of naphthene base crude oil, organic dibasic acid 7
Part, 5 parts of triethanolamine, 5 parts of single hydramine, hard water resistance dose 1.5 parts, 0.5 part of antirust agent, 0.2 part of antibacterial agent, 0.2 part of preservative,
12 parts of surfactant, 35 parts of water.
Described hard water resistance dose is hard water resistance dose of alcohol ether carboxylate class；The antirust agent is benzotriazole.
The antibacterial agent is morpholine bactericide；The preservative is sodium benzoate.
The surfactant is 7 parts of triethanolamine oleate, 2 parts of fatty alcohol, four 3 parts of poly- ricinoleate esters.
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam, includes the following steps：
（1）Organic dibasic acid, triethanolamine, monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature
It is 40 DEG C, incorporation time is 50 min, obtains clarification mixed liquor A；
（2）Mineral oil is heated 50 DEG C, under stirring, antibacterial agent, preservative is added, constant temperature stirs 50 min, must mix
Liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
The step（3）Middle mixed liquid B is added to the mode in mixed liquor A as uniform speed slow addition, and it is 0.8 that speed, which is added,
Kg/min。
2 raw material of comparative example changes
A kind of environment-friendly type microemulsified metalworking fluid of low foam, the parts by weight of raw material are：23 parts of naphthene base crude oil, 5 parts of triethanolamine,
5 parts of single hydramine, hard water resistance dose 1.5 parts, 0.5 part of antirust agent, 0.2 part of antibacterial agent, 0.2 part of preservative, 12 parts of surfactant,
0.6 part of emulsifier, 35 parts of water.
Described hard water resistance dose is hard water resistance dose of alcohol ether carboxylate class；The antirust agent is benzotriazole.
The antibacterial agent is morpholine bactericide；The preservative is sodium benzoate.
The surfactant is 7 parts of triethanolamine oleate, 2 parts of fatty alcohol, four 3 parts of poly- ricinoleate esters.
The emulsifier is nonionic emulsifier fatty alcohol alkoxy compound.
A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam, includes the following steps：
（1）Monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature is 40 DEG C, incorporation time 50
Min obtains clarification mixed liquor A；
（2）Mineral oil is heated 50 DEG C, under stirring, antibacterial agent, preservative, emulsifier is added, constant temperature stirs 50 min,
Obtain mixed liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
The step（3）Middle mixed liquid B is added to the mode in mixed liquor A as uniform speed slow addition, and it is 0.8 that speed, which is added,
Kg/min。
Compared with embodiment cutting fluid prepared by the comparative example is carried out performance.It the results are shown in Table 1
1 metalworking fluid performance evaluation of table
Note：Surface tension is the measurement result that this product concentration is 5% working solution (distilled water preparation).
Claims (8)
1. a kind of environment-friendly type microemulsified metalworking fluid of low foam, which is characterized in that the parts by weight of raw material are：Mineral oil 20~30
Part, 5~8 parts of organic dibasic acid, 3~7 parts of triethanolamine, 3~7 parts of single hydramine, hard water resistance dose 1~3 part, antirust agent 0.5~1
Part, 0.1~0.3 part of antibacterial agent, 0.1~0.3 part of preservative, 11~14 parts of surfactant, 0.2-1.0 parts of emulsifier, water 30
~40 parts.
2. metalworking fluid according to claim 1, which is characterized in that the parts by weight of raw material are：23 parts of naphthene base crude oil has
7 parts of machine binary acid, 5 parts of triethanolamine, 5 parts of single hydramine, hard water resistance dose 1.5 parts, it is 0.5 part of antirust agent, 0.2 part of antibacterial agent, anti-
0.2 part of rotten agent, 12 parts of surfactant, 0.6 part of emulsifier, 35 parts of water.
3. metalworking fluid according to claim 1 or 2, which is characterized in that described hard water resistance dose is alcohol ether carboxylate class
Hard water resistance dose；The antirust agent is benzotriazole.
4. metalworking fluid according to claim 1 or 2, which is characterized in that the antibacterial agent is morpholine bactericide；
The preservative is sodium benzoate.
5. metalworking fluid according to claim 1 or 2, which is characterized in that the surfactant is sulphur triethylenetetraminehexaacetic acid
Hydramine soap, triethanolamine oleate, fatty alcohol, four poly- ricinoleate esters, any three kinds of compositions in oleic acid.
6. metalworking fluid according to claim 1 or 2, which is characterized in that the emulsifier is nonionic emulsifier
Fatty alcohol alkoxy compound.
7. a kind of preparation method of metalworking fluid of any of claims 1 or 2, which is characterized in that include the following steps：
（1）Organic dibasic acid, triethanolamine, monoethanolamine, antirust agent and water are mixed under stirring, mixing temperature
It is 30~50 DEG C, incorporation time is 30~60 min, obtains clarification mixed liquor A；
（2）Mineral oil is heated 40~60 DEG C, under stirring, antibacterial agent, preservative, emulsifier, constant temperature stirring 30 is added
~60 min, obtain mixed liquid B；
（3）By step（2）Obtained in mixed liquid B be at the uniform velocity added to step（1）Obtained in mixed liquor A, while stirring plus
Enter；
（4）All addition finishes liquid B to be mixed, sequentially adds surfactant, and often plus one kind stirs evenly immediately, until being added
A kind of last surfactant, is added while stirring, and system is gradually thinning to brighten last to bright, and it is micro- that low foam environment-friendly type is made
Emulsion cutting fluid.
8. metalworking fluid according to claim 1, which is characterized in that the step（3）Middle mixed liquid B is added to mixing
Mode in liquid A is uniform speed slow addition, and addition speed is 0.4~1.2 Kg/min.
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| CN113801724A (en) * | 2021-09-30 | 2021-12-17 | 安美科技股份有限公司 | Metal processing cutting fluid and preparation method thereof |
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