CN106701296A - Environment-friendly microemulsion cutting liquid and preparation method thereof - Google Patents

Environment-friendly microemulsion cutting liquid and preparation method thereof Download PDF

Info

Publication number
CN106701296A
CN106701296A CN201611234558.1A CN201611234558A CN106701296A CN 106701296 A CN106701296 A CN 106701296A CN 201611234558 A CN201611234558 A CN 201611234558A CN 106701296 A CN106701296 A CN 106701296A
Authority
CN
China
Prior art keywords
parts
cutting fluid
environmental protection
agent
micro emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611234558.1A
Other languages
Chinese (zh)
Inventor
史学斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Hengrun Environmental Protection Science And Technology Co Ltd
Original Assignee
Henan Hengrun Environmental Protection Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Hengrun Environmental Protection Science And Technology Co Ltd filed Critical Henan Hengrun Environmental Protection Science And Technology Co Ltd
Priority to CN201611234558.1A priority Critical patent/CN106701296A/en
Publication of CN106701296A publication Critical patent/CN106701296A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Abstract

The invention provides environment-friendly microemulsion cutting liquid and a preparation method thereof. The environment-friendly microemulsion cutting liquid is prepared from, by mass, 1-9 parts of monoethanolamine, 1-9 parts of triethanolamine, 0.1-5 parts of benzotriazole, 1-9 parts of fatty acid, 1-10 parts of ricinoleic acid, 5-25 parts of No.5 white oil, 1-10 parts of a water-based extreme pressure agent, 1-10 parts of oil-water equilibrium agent, 1-10 parts of dipropylene glycol, 0.5-5 parts of fatty alcohol ether phosphate, 1-10 parts of zinc naphthenate, 2.5-25 parts of an auxiliary, 0.5-5 parts of an additive and 15-85 parts of water. The environment-friendly microemulsion cutting liquid is higher in extreme pressure, better in rust resistance and lubricating property, higher in stability, longer in service life, non-flammable, non-explosive and easy to transport and store.

Description

A kind of micro emulsion Environmental Protection Cutting Fluid and preparation method thereof
Technical field
The present invention relates to cutting fluid technical field, and in particular to a kind of micro emulsion Environmental Protection Cutting Fluid and preparation method thereof.
Background technology
Metal working fluid includes emulsion, micro-emulsion cutting fluid and fully synthetic cutting fluid.Wherein emulsion cutting fluid belongs to biography System product, emulsion combines the lubricity and rust-preventing characteristic of oil with the fabulous cooling of water, is provided simultaneously with preferably lubrication Cooling, the metal cutting process thus for the high velocity, low pressure power being largely thermally generated is very effective, and price economy, but emulsion Shortcoming be easily to breed bacterium, mould, active ingredient in emulsion is produced chemical breakdown and smelly, rotten, use Short life, stability are poor, so the organic bactericide of general all additions small toxicity；The advantage of fully synthetic cutting fluid be it is economical, The strong and fabulous workpiece visibility of rapid heat dissipation, cleaning, it is easy to control processing dimension, its stability and anti-corrupt ability are than emulsification Liquid is strong, is mainly used in cooling down and requires occasion high, such as is ground, but has the disadvantage that lubricity is not good enough, and extreme pressure property is inadequate, and this will cause The adhesion and abrasion of lathe movable part, and, the thick residue that chemical synthesis leaves can influence the motion of machine parts, The faying surface of these parts can be also set to produce corrosion.Micro-emulsion cutting fluid is formed after mineral oil is dissolved in water, typically containing mineral Oily 5-35%, emulsifier content is higher by 3-6 times with oiliness thing content than emulsion, but its oily content is far below oil in emulsion Content, thus can make oil droplet formed particulate diameter very little, due to the distinctive compositing characteristic of microemulsion so that it has breast concurrently Change the advantage of both liquid and Synthesis liquid, lubrication, cooling, cleaning, rustless property are preferable, and its service life is more long than emulsion 4-6 times.Micro-emulsion cutting fluid has multipurpose, and using wide, good combination property, preferably, long lifespan is in semi-transparent after being watered to stability Bright or transparence；Therefore, developed country has passed by from emulsion to Synthesis liquid, then the process developed to microemulsion, micro- Emulsion has obtained unprecedented development and application.With the arrival in High-speed machining epoch, the raising of processing efficiency, to processing The requirement of part finish also more and more higher, and existing micro-emulsion cutting fluid is in antirust, lubrication, service life, stability, environmental protection Property etc. aspect still seem not enough, and current ability of the micro-emulsion cutting fluid without cleaning greasy dirt is inflammable, explosive, be difficult fortune It is defeated, not easy to store.
The content of the invention
In order to solve the above-mentioned technical problem, it is an object of the invention to provide a kind of micro emulsion Environmental Protection Cutting Fluid and its preparation side Method, the micro emulsion Environmental Protection Cutting Fluid extreme pressure is higher, and more preferably, stability is stronger, and service life is longer, no for antirust, greasy property It is inflammable, non-explosive, easily transport, easily storage.
The technical solution adopted in the present invention is：A kind of micro emulsion Environmental Protection Cutting Fluid, the micro emulsion Environmental Protection Cutting Fluid by The raw material composition of following mass parts：Monoethanolamine 1-9 parts, triethanolamine 1-9 parts, BTA 0.1-5 parts, aliphatic acid 1-9 Part, castor oil acid 1-10 parts, No. 5 white oil 5-25 parts, aqueous extreme pressure agent 1-10 parts, 1-10 parts of oil-water balance agent, a contracting dipropyl two Alcohol 1-10 parts .5-5 parts, zinc naphthenate 1-10 parts, auxiliary agent 2.5-25 parts, additive 0.5-5 parts of fatty alcohol ether phosphoesterase 30 and water 15-85 parts.
The aqueous extreme pressure agent is aqueous molybdenum.
The oil-water balance agent be one kind in 18 carbon branched-chain alcohols, butyl glycol ether, butyl or they Mixture.
The additive is one kind or their mixture in low molecular polyether, organosilicon.
The auxiliary agent according to parts by weight be by oleic acid diethyl amide 1-10 parts, 1-9 parts of polyethylene glycol double olein and 0.5-5 parts of composition of fatty acid methyl ester ethoxylate sulfonate.
A kind of preparation method of described micro emulsion Environmental Protection Cutting Fluid, comprises the following steps：According to proportioning, oleic acid is taken first The double oleins of diglycollic amide, polyethylene glycol and fatty acid methyl ester ethoxylate sulfonate mix and under the conditions of 20-30 DEG C Stirring 20-30min is with prepared auxiliary agent, then takes monoethanolamine, triethanolamine, BTA, aliphatic acid and castor oil acid fat Alcohol ether phosphate is well mixed, and then heats the mixture to 65-85 DEG C and stirs 30-50min, then mixture temperature is down to 20-30 DEG C, water, No. 5 white oils, aqueous extreme pressure agent, oil-water balance agent, dipropylene glycol, zinc naphthenate and auxiliary agents are subsequently adding, Stirring 30-50min, is eventually adding additive and stirs to as clear as crystal and obtain micro emulsion Environmental Protection Cutting Fluid.
Compared with prior art, the invention has the advantages that：
First, the auxiliary agent in the present invention is assembled as micella in No. 5 white oils, and makes to help in the case where the collaboration of dipropylene glycol promotes There is maximum in agent solubility under proportioning of the invention, so as to greatly reinforce the emulsifying capacity of auxiliary agent, makes the micro emulsion being made The emulsified particles of Environmental Protection Cutting Fluid is more tiny, and product is more stablized, nonflammable, non-explosive, easily transport, and easily storage, helps Effect of the polyethylene glycol pair oleins and oleic acid diethyl amide of addition in agent in fatty acid methyl ester ethoxylate sulfonate It is lower to be easier to adsorb and be enriched with oil-water interfaces, emulsion is easily formed, and reaction speed is further speeded up, save and prepare Time；
2nd, auxiliary agent to No. 5 white oils carry out emulsification so that cutting fluid of the invention greasy property is greatly improved at a lower temperature, and Aqueous extreme pressure agent in the present invention can form high-melting-point and chemically react under the condition of boundary lubrication of HTHP with metal surface Film, serves and reduces friction and prevent the effect of scratch and melting welding, and then ensure that the present invention under high-temperature and high-pressure conditions still With good lubrication；
3rd, micro emulsion Environmental Protection Cutting Fluid of the present invention is semi-synthetic product, and unique formula and the raw material of high-quality ensure The splendid cooling performance of product, greasy property, rustless property, cleaning performance, environmental-protecting performance, with splendid cutting lubricity With good cleaning greasy dirt ability, it is steady with fabulous biology with extremely strong rustless property while also maintain machines clean degree It is qualitative, not phosphorous, not chloride, not sulfur-bearing, without noxious materials such as nitrite, phenol, do not stimulate skin, protection operator's Health, nonflammable, non-explosive, easily transport, easily storage, is environmentally friendly machine；
4th, the present invention has superpower extreme pressure and antiwear behavior, high-mechanic performance, a boundary lubrication performance, splendid antirust function and Antirust reinforcing property, is particularly suited for disabling the occasion of the extreme pressure agents such as active sulfur, chlorine, and the aqueous extreme pressure agent for being used effectively overcomes Corrosion metal, the harmfulness of corrosion lathe caused by the aqueous extreme pressure agents such as in the market tradition sulfur-bearing, phosphorus, chlorine；
5th, the aqueous molybdenum and microemulsion intermiscibility used by the present invention are good, and tasteless, still, corrosion-free, aqueous molybdenum is in HTHP Condition of boundary lubrication under can form high-melting-point and with loose structure chemical reaction film with metal surface, this loose structure was both Diffusion path of the ion in chemical reaction film is shortened, its active surface is fully utilized again, substantially increase profit Slip.
Specifically apply mode
With reference to specific embodiment, the present invention is further elaborated, and protection scope of the present invention is not limited to following implementation Example.Implement process of the invention, condition, reagent etc., in addition to the following special content for referring to, be the universal knowledege of this area And common knowledge, the present invention is not particularly limited content.
Embodiment 1
A kind of micro emulsion Environmental Protection Cutting Fluid, the micro emulsion Environmental Protection Cutting Fluid is made up of the raw material of following mass parts：Monoethanolamine 1 Part, 1 part of triethanolamine, 0.1 part of BTA, 1 part of aliphatic acid, castor oil acid 1 part, No. 55 parts of white oils, aqueous extreme pressure agents 1 Part, 1 part of oil-water balance agent, 1 part of dipropylene glycol .5 parts of fatty alcohol ether phosphoesterase 30,1 part of zinc naphthenate, 2.5 parts of auxiliary agent, add Plus 15 parts of 0.5 part of agent and water.
The aqueous extreme pressure agent is aqueous molybdenum.
The oil-water balance agent be one kind in 18 carbon branched-chain alcohols, butyl glycol ether, butyl or they Mixture.
The additive is one kind or their mixture in low molecular polyether, organosilicon.
The auxiliary agent is by 1 part of oleic acid diethyl amide, 1 part of the double oleins of polyethylene glycol and aliphatic acid according to parts by weight 0.5 part of composition of FMEE sulfonate.
A kind of preparation method of described micro emulsion Environmental Protection Cutting Fluid, comprises the following steps：According to proportioning, oleic acid is taken first The double oleins of diglycollic amide, polyethylene glycol and the mixing of fatty acid methyl ester ethoxylate sulfonate and the stirring under the conditions of 20 DEG C 20min is with prepared auxiliary agent, then takes monoethanolamine, triethanolamine, BTA, aliphatic acid and castor oil acid fatty alcohol ether phosphoric acid Ester is well mixed, and then heats the mixture to 65 DEG C and stirs 30min, then mixture temperature is down into 20 DEG C, is subsequently adding Water, No. 5 white oils, aqueous extreme pressure agent, oil-water balance agent, dipropylene glycol, zinc naphthenate and auxiliary agents, stir 30min, finally add Enter additive and stir to as clear as crystal to obtain micro emulsion Environmental Protection Cutting Fluid.
Embodiment 2
A kind of micro emulsion Environmental Protection Cutting Fluid, the micro emulsion Environmental Protection Cutting Fluid is made up of the raw material of following mass parts：Monoethanolamine 5 Part, 5 parts of triethanolamine, 3.5 parts of BTA, 5 parts of aliphatic acid, castor oil acid 5.5 parts, No. 5 15 parts of white oils, aqueous extreme pressure agents 5.5 parts, 5.5 parts of oil-water balance agent, 5.5 parts of dipropylene glycol, 4.5 parts of fatty alcohol ether phosphate, 5.5 parts of zinc naphthenate, help 50 parts of 13.5 parts of agent, 3.5 parts of additive and water.
The aqueous extreme pressure agent is aqueous molybdenum.
The oil-water balance agent be one kind in 18 carbon branched-chain alcohols, butyl glycol ether, butyl or they Mixture.
The additive is one kind or their mixture in low molecular polyether, organosilicon.
The auxiliary agent is by 5.5 parts of oleic acid diethyl amide, 5 parts of the double oleins of polyethylene glycol and fat according to parts by weight 3.5 parts of compositions of sour FMEE sulfonate.
A kind of preparation method of described micro emulsion Environmental Protection Cutting Fluid, comprises the following steps：According to proportioning, oleic acid is taken first The double oleins of diglycollic amide, polyethylene glycol and the mixing of fatty acid methyl ester ethoxylate sulfonate and the stirring under the conditions of 25 DEG C 25min is with prepared auxiliary agent, then takes monoethanolamine, triethanolamine, BTA, aliphatic acid and castor oil acid fatty alcohol ether phosphoric acid Ester is well mixed, and then heats the mixture to 75 DEG C and stirs 40min, then mixture temperature is down into 25 DEG C, is subsequently adding Water, No. 5 white oils, aqueous extreme pressure agent, oil-water balance agent, dipropylene glycol, zinc naphthenate and auxiliary agents, stir 40min, finally add Enter additive and stir to as clear as crystal to obtain micro emulsion Environmental Protection Cutting Fluid.
Embodiment 3
A kind of micro emulsion Environmental Protection Cutting Fluid, the micro emulsion Environmental Protection Cutting Fluid is made up of the raw material of following mass parts：Monoethanolamine 9 Part, 9 parts of triethanolamine, 5 parts of BTA, 9 parts of aliphatic acid, castor oil acid 10 parts, No. 5 25 parts of white oils, aqueous extreme pressure agents 10 Part, 10 parts of oil-water balance agent, 10 parts of dipropylene glycol, 5 parts of fatty alcohol ether phosphate, 10 parts of zinc naphthenate, 25 parts of auxiliary agent, add Plus 85 parts of 5 parts of agent and water.
The aqueous extreme pressure agent is aqueous molybdenum.
The oil-water balance agent be one kind in 18 carbon branched-chain alcohols, butyl glycol ether, butyl or they Mixture.
The additive is one kind or their mixture in low molecular polyether, organosilicon.
The auxiliary agent is by 10 parts of oleic acid diethyl amide, 9 parts of the double oleins of polyethylene glycol and fat according to parts by weight 5 parts of compositions of sour FMEE sulfonate.
A kind of preparation method of described micro emulsion Environmental Protection Cutting Fluid, comprises the following steps：According to proportioning, oleic acid is taken first The double oleins of diglycollic amide, polyethylene glycol and the mixing of fatty acid methyl ester ethoxylate sulfonate and the stirring under the conditions of 30 DEG C 30min is with prepared auxiliary agent, then takes monoethanolamine, triethanolamine, BTA, aliphatic acid and castor oil acid fatty alcohol ether phosphoric acid Ester is well mixed, and then heats the mixture to 85 DEG C and stirs 50min, then mixture temperature is down into 30 DEG C, is subsequently adding Water, No. 5 white oils, aqueous extreme pressure agent, oil-water balance agent, dipropylene glycol, zinc naphthenate and auxiliary agents, stir 50min, finally add Enter additive and stir to as clear as crystal to obtain micro emulsion Environmental Protection Cutting Fluid.

Claims (6)

1. a kind of micro emulsion Environmental Protection Cutting Fluid, it is characterised in that：The micro emulsion Environmental Protection Cutting Fluid by following mass parts raw material Composition：Monoethanolamine 1-9 parts, triethanolamine 1-9 parts, BTA 0.1-5 parts, aliphatic acid 1-9 parts, castor oil acid 1-10 Part, No. 5 white oil 5-25 parts, aqueous extreme pressure agent 1-10 parts, 1-10 parts of oil-water balance agent, dipropylene glycol 1-10 parts, fatty alcohol Ether phosphate 0.5-5 parts, zinc naphthenate 1-10 parts, auxiliary agent 2.5-25 parts, additive 0.5-5 parts and water 15-85 parts.
2. a kind of micro emulsion Environmental Protection Cutting Fluid as claimed in claim 1, it is characterised in that：The aqueous extreme pressure agent is aqueous Molybdenum.
3. a kind of micro emulsion Environmental Protection Cutting Fluid as claimed in claim 1, it is characterised in that：The oil-water balance agent is 18 carbon One kind or their mixture in branched-chain alcoho, butyl glycol ether, butyl.
4. a kind of micro emulsion Environmental Protection Cutting Fluid as claimed in claim 1, it is characterised in that：The additive is poly- for low-molecular-weight One kind or their mixture in ether, organosilicon.
5. a kind of micro emulsion Environmental Protection Cutting Fluid as claimed in claim 1, it is characterised in that：The auxiliary agent is according to parts by weight By oleic acid diethyl amide 1-10 parts, double 1-9 parts and fatty acid methyl ester ethoxylate sulfonate 0.5-5 of the oleins of polyethylene glycol Part composition.
6. a kind of preparation method of micro emulsion Environmental Protection Cutting Fluid as claimed in claim 1, it is characterised in that including following step Suddenly：According to proportioning, the double oleins of oleic acid diethyl amide, polyethylene glycol and fatty acid methyl ester ethoxylate sulfonate are taken first Mix simultaneously under the conditions of 20-30 DEG C stir 20-30min be obtained auxiliary agent, then take monoethanolamine, triethanolamine, BTA, Aliphatic acid and castor oil acid fatty alcohol ether phosphate are well mixed, then heat the mixture to 65-85 DEG C and stir 30- 50min, then mixture temperature is down to 20-30 DEG C, it is subsequently adding water, No. 5 white oils, aqueous extreme pressure agent, oil-water balance agent, a contractings DPG, zinc naphthenate and auxiliary agent, stir 30-50min, are eventually adding additive and stir to as clear as crystal and obtain micro emulsion ring Guarantor's type cutting fluid.
CN201611234558.1A 2016-12-28 2016-12-28 Environment-friendly microemulsion cutting liquid and preparation method thereof Pending CN106701296A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611234558.1A CN106701296A (en) 2016-12-28 2016-12-28 Environment-friendly microemulsion cutting liquid and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611234558.1A CN106701296A (en) 2016-12-28 2016-12-28 Environment-friendly microemulsion cutting liquid and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106701296A true CN106701296A (en) 2017-05-24

Family

ID=58902878

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611234558.1A Pending CN106701296A (en) 2016-12-28 2016-12-28 Environment-friendly microemulsion cutting liquid and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106701296A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109504516A (en) * 2019-01-22 2019-03-22 无锡科捷化学有限公司 A kind of micro emulsion cutting fluid and preparation method thereof suitable for heavy load intermetallic composite coating
CN115786026A (en) * 2022-11-30 2023-03-14 潍坊奥润德新材料科技有限公司 Biodegradable micro-emulsified cutting fluid and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164283A (en) * 2014-08-19 2014-11-26 清华大学 Microemulsion metal cutting fluid
CN105754690A (en) * 2016-03-30 2016-07-13 安徽华灿润滑技术有限公司 Magnesium alloy cutting liquid and preparation method thereof
CN106281630A (en) * 2016-08-17 2017-01-04 南通科星化工有限公司 A kind of micro emulsion cutting fluid and preparation technology thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164283A (en) * 2014-08-19 2014-11-26 清华大学 Microemulsion metal cutting fluid
CN105754690A (en) * 2016-03-30 2016-07-13 安徽华灿润滑技术有限公司 Magnesium alloy cutting liquid and preparation method thereof
CN106281630A (en) * 2016-08-17 2017-01-04 南通科星化工有限公司 A kind of micro emulsion cutting fluid and preparation technology thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109504516A (en) * 2019-01-22 2019-03-22 无锡科捷化学有限公司 A kind of micro emulsion cutting fluid and preparation method thereof suitable for heavy load intermetallic composite coating
CN115786026A (en) * 2022-11-30 2023-03-14 潍坊奥润德新材料科技有限公司 Biodegradable micro-emulsified cutting fluid and preparation method and application thereof
CN115786026B (en) * 2022-11-30 2023-11-17 潍坊奥润德新材料科技有限公司 Biodegradable microemulsified cutting fluid and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN101531946A (en) Metal cutting solution of green semi-synthesis double-base oil and preparation method thereof
CN102220183B (en) Vegetable oil-based water-soluble cutting fluid
CN105861135B (en) Green metal cutting fluid and preparation method thereof
CN104479833A (en) High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof
CN101575550A (en) Ternary base oil microemulsified cutting solution and preparation method thereof
CN104130839A (en) Water-soluble cutting oil applied to cutting work and guide rail lubrication
CN102604728B (en) Environment-friendly emulsified cutting fluid and method for preparing same
CN106800963B (en) A kind of water soluble oil metalworking fluid raw material and metalworking fluid
CN105623809B (en) Synthetic ester environment-friendly type aluminium alloy cuts oil emulsion and preparation method thereof
CN106701296A (en) Environment-friendly microemulsion cutting liquid and preparation method thereof
JP4808855B2 (en) Lubricant composition
CN107353995A (en) A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof
EP0120665B1 (en) Soluble oil cutting fluid
CN106635357B (en) A kind of high detergency is low to steep semi-synthetic grinding fluid and preparation method thereof
CN107418673A (en) A kind of cutting fluid of novel emulsion system based on polyisobutenyl succinic anhydride and its preparation method and application
CN109797034A (en) A kind of pure magnesium working fluid of environment-friendly type and preparation method thereof
CN109735389A (en) A kind of water-soluble two-component metal working fluid
CN104877736A (en) Boron-free and phosphorus-free aluminum alloy piston micro-emulsification processing liquid, dilution liquid and preparation method thereof
CN103351925B (en) Cutting fluid composition
CN105670758A (en) High-lubricity and ecological safety water-based cutting fluid and preparation method thereof
CN104371818A (en) High-performance water-based full-synthetic cutting fluid and preparation method thereof
WO1998050139A1 (en) Surfactant mixture
CN107653042A (en) Pipe expanding fluid composition and application thereof
CN105542929A (en) Low-VOCs environment-friendly micro-emulsified cutting fluid and preparation method thereof
CN108822948A (en) A kind of preparation method of the environment-friendly type microemulsified metalworking fluid of low foam

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170524

RJ01 Rejection of invention patent application after publication