CN106635357B - A kind of high detergency is low to steep semi-synthetic grinding fluid and preparation method thereof - Google Patents
A kind of high detergency is low to steep semi-synthetic grinding fluid and preparation method thereof Download PDFInfo
- Publication number
- CN106635357B CN106635357B CN201611223124.1A CN201611223124A CN106635357B CN 106635357 B CN106635357 B CN 106635357B CN 201611223124 A CN201611223124 A CN 201611223124A CN 106635357 B CN106635357 B CN 106635357B
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- Prior art keywords
- acid
- grinding fluid
- low
- semi
- synthetic
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- 238000000227 grinding Methods 0.000 title claims abstract description 72
- 239000012530 fluid Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 150000002148 esters Chemical class 0.000 claims abstract description 26
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000013556 antirust agent Substances 0.000 claims abstract description 7
- 239000007822 coupling agent Substances 0.000 claims abstract description 7
- 150000007524 organic acids Chemical class 0.000 claims abstract description 7
- 239000006260 foam Substances 0.000 claims description 53
- -1 polyoxyethylene groups Polymers 0.000 claims description 31
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 12
- 239000003093 cationic surfactant Substances 0.000 claims description 12
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 12
- 239000008158 vegetable oil Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003784 tall oil Substances 0.000 claims description 9
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 230000000844 anti-bacterial effect Effects 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- 239000003899 bactericide agent Substances 0.000 claims description 5
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- LPUBRQWGZPPVBS-UHFFFAOYSA-N 3-butoxypropan-1-amine Chemical compound CCCCOCCCN LPUBRQWGZPPVBS-UHFFFAOYSA-N 0.000 claims description 3
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims description 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims description 3
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 3
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 3
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 3
- 239000005639 Lauric acid Substances 0.000 claims description 3
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 claims description 3
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043276 diisopropanolamine Drugs 0.000 claims description 3
- 239000000539 dimer Substances 0.000 claims description 3
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 3
- 125000004185 ester group Chemical group 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 230000008014 freezing Effects 0.000 claims description 3
- 239000000174 gluconic acid Substances 0.000 claims description 3
- 235000012208 gluconic acid Nutrition 0.000 claims description 3
- 229940102253 isopropanolamine Drugs 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 238000005070 sampling Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract description 12
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract description 6
- 239000004327 boric acid Substances 0.000 abstract description 6
- 235000010288 sodium nitrite Nutrition 0.000 abstract description 6
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 230000000855 fungicidal effect Effects 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 231100001261 hazardous Toxicity 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 238000009736 wetting Methods 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000001050 lubricating effect Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 210000004994 reproductive system Anatomy 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- AGLSQWBSHDEAHB-UHFFFAOYSA-N azane;boric acid Chemical class N.OB(O)O AGLSQWBSHDEAHB-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- C10M173/00—Lubricating compositions containing more than 10% water
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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- C10M2207/10—Carboxylix acids; Neutral salts thereof
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- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/18—Tall oil acids
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- C10M2207/20—Rosin acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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Abstract
The invention discloses a kind of low semi-synthetic grinding fluid of bubble of high detergency, the components including following weight percent content: self-emulsifying ester 15~30%；Organic acid 5~10%；Organic amine 10~15%；Antirust agent 10~15%；Emulsifier 1~2%；Surfactant 0.5~1%；Coupling agent 2~5%；Fungicide 1~2%；Surplus is water.The low semi-synthetic grinding fluid of bubble of high detergency of the invention, has excellent cleansing performance and excellent low bubble performance, does not use the environmentally hazardous raw material such as sodium nitrite, nonylphenol class, boric acid, makes product more green, environmental protection.The invention also discloses the low preparation methods for steeping semi-synthetic grinding fluid of above-mentioned high detergency.
Description
Technical Field
The invention relates to a high-cleanness low-foam semi-synthetic grinding fluid and a preparation method thereof.
Background
The grinding machining is a common metal machining mode, redundant materials on a workpiece are cut off by using a grinding wheel rotating at a high speed, machining allowance is small, and size precision is high. The grinding fluid matched with the grinding fluid mainly plays roles in cooling, lubricating, washing, rust prevention and the like. The traditional water-insoluble grinding fluid consists of base oil and a small amount of oil-soluble additives, has good lubricity and rust resistance, but has serious potential safety hazard of flammability, and meanwhile, the oil mist generated in the processing process can also influence the physical health of operators, so the application of the water-based grinding fluid is more and more popular recently. The water-based grinding fluid is basically divided into semi-synthetic type and fully synthetic type. The fully synthetic grinding fluid consists of water and soluble chemical components, has good cooling property and foaming property, but has relatively poor lubricating property. The semi-synthetic grinding fluid contains lubricating components such as base oil, synthetic ester, long-chain fatty acid and the like, is emulsified in water by using a surfactant, has both cooling performance and lubricating performance in performance, and has a relatively wide application range.
However, the existing semi-synthetic grinding fluid also has a plurality of problems in application. Firstly, the formula contains more emulsifying agents for emulsifying lubricating components such as base oil, synthetic ester and the like, the emulsifying agents cause a large amount of foams in the circulation and spraying processes of the grinding fluid, if the control is not good, a liquid tank can overflow to pollute a working area, meanwhile, the existing automatic grinding fluid cooling circulation system is provided with a liquid level alarm, and the rising foams can trigger the alarm to cause abnormal shutdown, so that the normal production rhythm is influenced.
Secondly, a large amount of grinding dust is generated in the grinding process, the grinding dust splashes to the inner wall of the machine tool along with the grinding fluid and is combined with viscous components in the grinding fluid to form black dirt, the black dirt is difficult to wash away by the grinding fluid after a long time, and an operator needs to spend extra time for cleaning regularly. If the dirt is adhered to automatic transmission devices such as a tool rest, a rotating shaft and the like, abnormal shutdown accidents can also be caused.
Thirdly, the prior semisynthetic grinding fluid uses sodium nitrite, nonyl phenol surfactant, boric acid and other raw materials which are harmful to the environment and the human health. Sodium nitrite is widely used in grinding fluid due to its good rust prevention effect and low price, but it is converted into nitrosamine under certain conditions and has strong carcinogenicity. Nonyl phenol surfactants have good emulsifying capacity, but are decomposed to form nonyl phenol, which accumulates in the organism and is toxic to the reproductive system of the organism. Boric acid has certain antirust and bactericidal effects, but also has toxicity to the reproductive system of organisms.
Disclosure of Invention
The invention aims to provide a high-cleanness low-foam semisynthetic grinding fluid which has excellent cleanness and excellent low-foam performance, and does not use raw materials such as sodium nitrite, nonyl phenol, boric acid and the like which are harmful to the environment, so that the product is more green and environment-friendly.
The invention also aims to provide a preparation method of the semi-synthetic grinding fluid with high detergency and low foam.
One technical scheme for achieving the above purpose is as follows: a high-cleanness low-foam semi-synthetic grinding fluid comprises the following components in percentage by weight:
the semi-synthetic grinding fluid with high cleanness and low foam is prepared by polymerizing and modifying vegetable oil to obtain a synthetic ester; the structural formula of the self-emulsifying ester contains ester groups and carboxyl active groups; the main carbon chain of the self-emulsifying ester is of a branched chain structure, and 2-4 polyoxyethylene groups and 4-8 polyoxypropylene groups are added simultaneously; the HLB value of the self-emulsifying ester is 6-8.
The high-cleanness low-foam semisynthetic grinding fluid is characterized in that the organic acid is one or a mixture of more of refined tall oil acid, refined vegetable oil acid, dimer acid, neodecanoic acid, lactic acid, gluconic acid and isooctanoic acid; wherein,
the content of abietic acid in the refined tall oil acid is 25-30%;
the refined vegetable oil acid is extracted from palm oil, and the freezing point of the refined vegetable oil acid is 6 ℃.
The high-cleanness low-foam semisynthetic grinding fluid is characterized in that the organic amine is one or a mixture of more of isopropanolamine, diisopropanolamine, triisopropanolamine, 2-amino-2-methylpropanol, 3-butoxypropylamine and N, N-dibutylethanol.
The high-cleanness low-foam semisynthetic grinding fluid is characterized in that the antirust agent is one or a mixture of more of amine salt of lauric acid, tall oil acid diethanolamide, benzotriazole derivative, oleoyl sarcosine and lauroyl amino acid.
The high-cleanness low-foam semisynthetic grinding fluid is characterized in that the emulsifier is one or a mixture of more of fatty amine polyoxyethylene polyoxypropylene ether, polyisobutylene maleic anhydride, ether carboxylate and sodium lignosulphonate; wherein,
the carbon chain length of the fatty amine polyoxyethylene polyoxypropylene ether is C16-C18, the polyoxyethylene addition number is 6-10, and the polyoxypropylene addition number is 4-6;
the carbon chain length of the ether carboxylate is C8-C10, and the addition number of polyoxyethylene on the carbon chain of the ether carboxylate is 6-8.
The high-cleanness low-foam semisynthetic grinding fluid is characterized in that the surfactant is a cationic surfactant, and the surfactant is one or a mixture of polyethylene imine, dodecyl trimethyl ammonium chloride and dioctadecyl dimethyl ammonium chloride.
The high-cleanness low-foam semisynthetic grinding fluid is characterized in that the coupling agent is long-carbon-chain fatty alcohol with a branched-chain structure.
The semi-synthetic grinding fluid with high cleanness and low foam is prepared by mixing benzisothiazolinone, copper pyrithione sodium or iodopropynyl butylcarbamate.
The raw materials are all commercial products.
The invention also provides a preparation method of the high-detergency low-foam semi-synthetic grinding fluid, which comprises the following steps:
step A, sequentially adding self-emulsifying ester, organic acid, organic amine, antirust agent and emulsifier into a reaction kettle, controlling the temperature at 25-40 ℃, and stirring for 30 minutes at the stirring speed of 400-800 rpm;
step B, sequentially adding water, the bactericide and the coupling agent into the reaction kettle, and continuously stirring for 30 minutes at the stirring speed of 400-800 rpm;
step C, adding a surfactant into the reaction kettle, and stirring for 30 minutes at a stirring speed of 400-800 rpm;
and D, sampling, analyzing, discharging and packaging.
Compared with the prior art, the technical scheme of the high-cleanness low-foam semi-synthetic grinding fluid and the preparation method thereof has the following advantages:
(1) excellent detergency: materials (such as mineral oil, amine borate salts, borate esters, etc.) which tend to cause tackiness of grinding fluid residues have been excluded from formulation design; secondly, by introducing the cationic surfactant with weaker polarity and matching with the emulsifier and the self-emulsifying ester, the product obtains excellent wetting capacity, and the grinding ash generated in the grinding process is quickly and effectively wetted and wrapped by the grinding fluid and is washed away by the grinding fluid.
(2) Excellent low foam performance: the foam of traditional semi-synthetic grinding fluids is mainly caused by anionic and nonionic surfactants in the formulation. The surface of the liquid film of the foam is covered with anionic and nonionic surfactants, and the more stable the foam is, the longer the foam lasts. After the proper weak cationic surfactant is added into the formula, due to the interaction of the cationic surfactant and the anionic surfactant, a liquid film of the foam cannot be stable, and the foam duration is short, so that the defoaming effect is achieved. On the other hand, by introducing the self-emulsifying ester, the dosage of the emulsifier is reduced, and the generation of foam is reduced by phase change;
(3) during the formula design, the raw materials such as sodium nitrite, nonyl phenol, boric acid and the like which are harmful to the environment are not used, so that the product is more green and environment-friendly.
Drawings
FIG. 1 is a comparison graph of dynamic surface tension of the high-detergency low-foam semi-synthetic grinding fluid of the present invention and a conventional product under 5% tap water.
Detailed Description
The present inventors, in order to better understand the technical solution of the present invention, will now be described in detail by referring to the specific embodiments with reference to the attached drawings:
a high-cleanness low-foam semi-synthetic grinding fluid comprises the following components in percentage by weight:
the self-emulsifying ester is a synthetic ester obtained by polymerizing and modifying vegetable oil; the chemical ester has a structural formula containing ester groups and carboxyl active groups; the main carbon chain of the esterified ester is a branched chain structure, and 2-4 polyoxyethylene groups and 4-8 polyoxypropylene groups are added simultaneously; the HLB value of the esterified ester is 6-8.
The organic acid is one or more of refined tall oil acid, refined vegetable oil acid, dimer acid, neodecanoic acid, lactic acid, gluconic acid and isooctanoic acid; wherein the content of abietic acid in the refined tall oil acid is 25-30%; the refined vegetable oil acid is extracted from palm oil, and the freezing point of the refined vegetable oil acid is 6 ℃.
The organic amine is one or a mixture of more of isopropanolamine, diisopropanolamine, triisopropanolamine, 2-amino-2-methylpropanol, 3-butoxypropylamine and N, N-dibutylethanol.
The antirust agent is one or a mixture of more of amine salt of lauric acid, tall oil acid diethanolamide, benzotriazole derivatives, oleoyl sarcosine and lauroyl amino acid.
The emulsifier is one or a mixture of several of fatty amine polyoxyethylene polyoxypropylene ether, polyisobutylene maleic anhydride, ether carboxylate and sodium lignosulfonate; wherein the carbon chain length of the fatty amine polyoxyethylene polyoxypropylene ether is C16-C18, the addition number of polyoxyethylene is 6-10, and the addition number of polyoxypropylene is 4-6; the carbon chain length of the ether carboxylate is C8-C10, and the addition number of polyoxyethylene on the carbon chain of the ether carboxylate is 6-8.
The surfactant is cationic surfactant, and is one or more of polyethyleneimine, dodecyl trimethyl ammonium chloride and dioctadecyl dimethyl ammonium chloride.
The coupling agent is a long carbon chain fatty alcohol with a branched structure.
The bactericide is a mixture of benzisothiazolinone, copper pyrithione sodium or iodopropynyl butyl carbamate.
The raw materials are all commercial products.
Example 1
A high-cleanness low-foam semi-synthetic grinding fluid comprises the following components in percentage by weight:
example 2
A high-cleanness low-foam semi-synthetic grinding fluid comprises the following components in percentage by weight:
example 3
A high-cleanness low-foam semi-synthetic grinding fluid comprises the following components in percentage by weight:
the highly clean, low-foam semi-synthetic grinding fluids of examples 1 to 3 were prepared by the following production steps:
step A, adding self-emulsifying ester, organic acid, organic amine, antirust agent and emulsifier into a reaction kettle according to the formula amount in sequence, controlling the temperature at 25-40 ℃, and stirring for 30 minutes;
step B, sequentially adding water, the bactericide and the coupling agent into the reaction kettle, and continuously stirring for 30 minutes;
step C, finally adding the surfactant into the reaction kettle, and stirring for 30 minutes;
and D, sampling, analyzing, discharging and packaging.
The stirring speed of the stirring kettle is controlled to be 400-800 rpm.
In the process of developing the high-detergency low-foam semi-synthetic grinding fluid, the inventor designs different components and different proportions of the components according to the requirements of low-foam and high-cleanness performances required by products. The cleaning performance depends on the wettability and the permeability of the product, the formula concept of the weak cationic surfactant and the self-emulsifying ester is adopted, the wetting and the permeability of the product are greatly improved, and the foam performance of the product is also well improved. The grinding dust produced during grinding is mostly fine metal powder, the surface of which is usually negatively charged. Therefore, the cationic surfactant is more easily attached to the surface of the metal powder, thereby achieving the effect of quick wetting. Cationic surfactants have not been used in traditional semi-synthetic grinding fluids primarily because they can interfere with the emulsification of emulsifiers (which typically contain large amounts of anionic surfactants), resulting in emulsion breaking and other undesirable consequences. The invention selects the cationic surfactant with weaker polarity, and the emulsifier and the self-emulsifying ester which are tested and selected have better compatibility and little influence on the stability of the emulsion. The foam of traditional semi-synthetic grinding fluids is mainly caused by emulsifiers (including anionic and nonionic surfactants) in the formulation. The surface layer of the liquid film of the foam is covered with an anionic surfactant and a nonionic surfactant, and the closer the arrangement between the surface active molecules, the longer the foam lasts. After the proper cationic surfactant is added into the formula, due to the interaction of the cationic surfactant and the anionic surfactant, a liquid film of the foam cannot be stabilized, and the foam duration is short, so that the defoaming effect is achieved. The self-emulsifying ester used in the invention contains polyether, ester and carboxylic acid structures in a single molecule, and the special structure ensures good lubricity, has certain emulsification and good wetting performance, reduces the dosage of the emulsifier and reduces the generation of foams. And secondly, the grinding fluid has good hard water resistance, so that the grinding fluid is more stable in the using process, and the generation of metal soap which is easy to adhere to grinding dust is reduced.
The performance comparison of the high-cleanness low-foam semi-synthetic grinding fluid and the traditional semi-synthetic grinding fluid is tested.
Foam performance:
the circulating pump test method was used, the nozzle was 120 cm from the liquid surface, the flow was 12 liters per minute, and the foam performance test results are shown in table 1:
| 5% tap water | Traditional product | High-detergency low-foam semi-synthetic grinding fluid |
| Foam height (ml) | 120 | 70 |
| Defoaming time (minutes) | 20 | 5 |
TABLE 1
Wetting property:
the cotton cloth is lightly placed on the surface of the grinding fluid, the time required for the cotton cloth to be completely wetted and sink into the grinding fluid is recorded, the shorter the time, the stronger the wetting and settling capacity of the grinding fluid is, and the results of the wetting performance test are shown in the table 2:
| 5% tap water | Traditional product | High-detergency low-foam semi-synthetic grinding fluid |
| Wetting time | 60 seconds | 10 seconds |
TABLE 2
Meanwhile, the dynamic surface tension can well reflect the wetting capacity of the product:
referring to fig. 1, the dynamic surface tension of the highly-detergent low-foam semi-synthetic grinding fluid 1 of the present invention is compared with that of the conventional product 2 under the condition of 5% tap water, and as can be seen from fig. 1, compared with the conventional grinding fluid, the highly-detergent low-foam semi-synthetic grinding fluid of the present invention has very low dynamic surface tension, and thus has very good wetting property.
In conclusion, the high-detergency low-foam semisynthetic grinding fluid disclosed by the invention has excellent detergency and low-foam performance, and does not use raw materials such as sodium nitrite, nonyl phenol and boric acid which are harmful to the environment, so that the product is more green and environment-friendly.
It will be appreciated by persons skilled in the art that the above embodiments are illustrative only and not limiting as to the invention, and that changes in the above described embodiments will fall within the purview of the appended claims, provided they fall within the true spirit and scope of the invention.
Claims (2)
1. The high-cleanness low-foam semi-synthetic grinding fluid is characterized by comprising the following components in percentage by weight:
the self-emulsifying ester is a synthetic ester obtained by polymerizing and modifying vegetable oil; the structural formula of the self-emulsifying ester contains ester groups and carboxyl active groups; the main carbon chain of the self-emulsifying ester is of a branched chain structure, and 2-4 polyoxyethylene groups and 4-8 polyoxypropylene groups are added simultaneously; the HLB value of the self-emulsifying ester is 6-8;
the organic acid is one or a mixture of more of refined tall oil acid, refined vegetable oil acid, dimer acid, neodecanoic acid, lactic acid, gluconic acid and isooctanoic acid; wherein,
the content of abietic acid in the refined tall oil acid is 25-30%;
the refined vegetable oil acid is extracted from palm oil, and the freezing point of the refined vegetable oil acid is 6 ℃;
the organic amine is one or a mixture of more of isopropanolamine, diisopropanolamine, triisopropanolamine, 2-amino-2-methylpropanol, 3-butoxypropylamine and N, N-dibutylethanol;
the antirust agent is one or a mixture of more of amine salt of lauric acid, tall oil acid diethanolamide, benzotriazole derivatives, oleoyl sarcosine and lauroyl amino acid;
the emulsifier is one or a mixture of more of fatty amine polyoxyethylene polyoxypropylene ether, polyisobutylene maleic anhydride, ether carboxylate and sodium lignosulfonate; wherein,
the carbon chain length of the fatty amine polyoxyethylene polyoxypropylene ether is C16-C18, the polyoxyethylene addition number is 6-10, and the polyoxypropylene addition number is 4-6;
the carbon chain length of the ether carboxylate is C8-C10, and the addition number of polyoxyethylene on the carbon chain of the ether carboxylate is 6-8;
the surfactant is a cationic surfactant, and is one or a mixture of polyethylene imine, dodecyl trimethyl ammonium chloride and dioctadecyl dimethyl ammonium chloride;
the coupling agent is long-carbon-chain fatty alcohol with a branched-chain structure;
the bactericide is a mixture of benzisothiazolinone, copper pyrithione sodium or iodopropynyl butyl carbamate.
2. The preparation method of the high-cleanness low-foam semi-synthetic grinding fluid as claimed in claim 1, which is characterized by comprising the following steps:
step A, sequentially adding self-emulsifying ester, organic acid, organic amine, antirust agent and emulsifier into a reaction kettle, controlling the temperature at 25-40 ℃, and stirring for 30 minutes at the stirring speed of 400-800 rpm;
step B, sequentially adding water, the bactericide and the coupling agent into the reaction kettle, and continuously stirring for 30 minutes at the stirring speed of 400-800 rpm;
step C, adding a surfactant into the reaction kettle, and stirring for 30 minutes at a stirring speed of 400-800 rpm;
and D, sampling, analyzing, discharging and packaging.
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| CN103484207A (en) * | 2013-07-11 | 2014-01-01 | 东莞市安美润滑科技有限公司 | Water-based semisynthetic cutting fluid used for presser rolls, and preparation method and application method thereof |
| CN104673473A (en) * | 2013-11-30 | 2015-06-03 | 鸿富锦精密工业（深圳）有限公司 | Water-based grinding fluid and preparation method thereof |
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| CN103484207A (en) * | 2013-07-11 | 2014-01-01 | 东莞市安美润滑科技有限公司 | Water-based semisynthetic cutting fluid used for presser rolls, and preparation method and application method thereof |
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