CN108822629A - A kind of vamp whitening emulsion and preparation method thereof - Google Patents
A kind of vamp whitening emulsion and preparation method thereof Download PDFInfo
- Publication number
- CN108822629A CN108822629A CN201810561352.2A CN201810561352A CN108822629A CN 108822629 A CN108822629 A CN 108822629A CN 201810561352 A CN201810561352 A CN 201810561352A CN 108822629 A CN108822629 A CN 108822629A
- Authority
- CN
- China
- Prior art keywords
- vamp
- lotion
- sufficiently stirred
- emulsion
- whitening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention belongs to nanocomposite technical fields, and in particular to a kind of vamp whitening emulsion and preparation method thereof.The lotion is grouped as by following group as mass fraction：Sodium benzoate 0.3%, rubbing agent 1%~15%, glycerol 0%~30%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 10%~40%, titanium dioxide 1%~15%, styrene-acrylic emulsion 15%~30%, talcum powder 0%~3%, dehydrated alcohol 0%~40%, fragrance 0 ~ 0.7%, wherein, dehydrated alcohol and the total content of deionized water are fixed as 50%, and the sum of the above components mass fraction is 100%.Vamp whitening emulsion formula of the present invention is simple, and manufacture craft is simple, and lotion soil resistant, whitening effect are good, colour stable, has the advantages that good stability, asepsis environment-protecting, has significant economic benefit and social benefit.
Description
Technical field
The invention belongs to nanocomposite technical fields, and in particular to a kind of vamp whitening emulsion and preparation method thereof.
Background technique
In general, the pollution that attaches on shoes surface mainly includes two kinds of contact scar of attachment contact scar and sucking.The former refers to ash
The pollutants such as dirt are attached to the outer surface of shoes, and the latter refers in outer surface that pollutant enters shoes on the basis of attachment
Portion, especially when vamp is white, pollution is the most obvious, and the reflection light ability that these pollutants cause vamp reduces, white
Degree decline.Compared to attachment contact scar, sucking contact scar is then more difficult to remove.The former can pass through the elimination that simply rubs >=80% pollution
Object, the latter, to increase pollutant volume, can be allowed to subtract with basal body binding force by fine particle by spreading in conjunction with pollutant
It is weak；There are also one is coating to be attached directly to shoes surface, depth covering is carried out to pollutant, also further protection vamp from
Secondary infringement, but this is temporary cleaning, and pollutant is still present in shoes surface.Shoes are dirty, not only accelerate vamp
Aging returns people and leaves bad impression.Therefore in the prior art, the stain resistance of vamp is improved mainly by applying on its surface
Trowel coating is allowed to be difficult to adsorb to pollutant and is easy to remove, and the method is for a user, easy to operate, convenient, by wide
The favor of big consumer.These paint ingredients are mostly surfactant, detergent, preservative, weather resisting agent, moisturizer, fragrance
Deng other additives, then pass through simple hybrid technique at room temperature, prepares homogeneous afterwards for 24 hours by standing, it is resistance to be stained with
Dirty has cleaning, brightens coating.
But to there is product whitening effect mostly bad for existing white vamp brightening agent on the market, time-consuming for film forming, smearing
The problems such as surface is discontinuous, big multicomponent are surfactant, brightening agent, preservative, emulsifier, moisturizer, detergent, fragrance
Deng, complicated component has some ingredients to environment, or even is harmful to the human body, such as：Phenyl-hydrogen-sulfate sodium is often used as washing assisant,
To application on human skin nocuousness；White oil is often used as moisturizer, and people, which excessively takes in, easily causes diarrhea etc..And most of components is organic high
Molecular material, the thin film mechanical performance and loss of properties on aging prepared, intensity has certain limitation, and has a single function.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of vamp whitening emulsion and preparation method thereof.
The lotion soil resistant, whitening effect are good, colour stable, have the advantages that good stability, asepsis environment-protecting.
To achieve the purpose of the present invention, it adopts the following technical scheme that：
A kind of vamp whitening emulsion is grouped as by following group as mass fraction：Sodium benzoate 0.3%, rubbing agent 1%~15%,
Glycerol 0%~30%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 10%~40%, titanium dioxide 1%~15%, benzene
Acrylic emulsion 15%~30%, talcum powder 0%~3%, dehydrated alcohol 0%~40%, fragrance 0 ~ 0.7%, wherein dehydrated alcohol and deionization
The total content of water is fixed as 50%, and the sum of the above components mass fraction is 100%.
The rubbing agent is one of silica, calcium carbonate, calcium bicarbonate, aluminium hydroxide.
A method of vamp whitening emulsion as described above is prepared, is included the following steps：
1）At 25 DEG C, sodium carboxymethylcellulose is added into deionized water, glycerol is sufficiently stirred, revolving speed 4r/s, stirring
Time 30min~60min prepares uniform, transparent colloid；
2）In step 1）NaLS is added in the colloid of preparation, is sufficiently stirred, revolving speed 3r/s, mixing time 20min
~40min is prepared containing bladdery colloid；
3）By step 2）After obtained colloid carries out vacuum outgas, it is anhydrous to sequentially add rubbing agent, talcum powder, titanium dioxide and part
Ethyl alcohol is sufficiently stirred, revolving speed 4r/s, mixing time 30min~60min, prepares homogeneous, stable white lotion；
4）Toward step 3）Styrene-acrylic emulsion is added dropwise in obtained white lotion, is sufficiently stirred and grinds 1h~2h, lotion is made；
5）Sodium benzoate, remaining dehydrated alcohol are slowly dropped to step 4）In made lotion, be sufficiently stirred 30min~
Fragrance is added in 40min, and vamp whitening emulsion is made.
For the present invention in addition to outer increase rubbing agent on composition, binder styrene-acrylic emulsion also functions to a variety of effects, on the one hand,
Shoes outer surface, which is smeared, coats, and plays pollutant covering, whitening effect, secondly rubbing agent in coating（Nano particle）Pass through diffusion
Inner surface is penetrated into, is adsorbed on air pollutants with intermolecular force, is allowed to weaken with basal body binding force；On the other hand,
It after coating is on vamp, is cleaned with tap water and hairbrush, also can achieve cleaning, the effect brightened.In technique, this hair
It is bright by ingredient, feed intake step by step, mechanical stirring, grinding, vacuum outgas, ageing process are prepared uniformly, stabilization, the increasing of stain resistant
Whiting.
The present invention has the following advantages that compared with the prior art：
1）The present invention can reduce to the maximum extent functionality under the premise of ensuring to be brightened, is clean, realize that a material is more
With giving full play to cooperative effect between recipe ingredient, reduce the production cost of vamp brightening agent, while preparing modest viscosity
Lotion, greatly reduce because corner remain so that being wasted caused by coating；The complementary color that can also be used in common metope, expands
Application field；
2）Vamp whitening emulsion formula of the present invention is simple, and manufacture craft is simple, and lotion soil resistant, whitening effect are good, colour stable,
Have the advantages that good stability, asepsis environment-protecting, there is significant economic benefit and social benefit.
Specific embodiment
Further to disclose rather than the present invention is limited, the present invention is described in further detail below in conjunction with example.
Embodiment 1
A kind of vamp whitening emulsion is grouped as by following group as mass fraction：Sodium benzoate 0.3%, nano silica
10%, glycerol 5%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 30%, titanium dioxide 4%, styrene-acrylic emulsion
28.7%, dehydrated alcohol 20%.
The preparation method of vamp whitening emulsion, the specific steps are：
1）At 25 DEG C, sodium carboxymethylcellulose is added into deionized water, glycerol is sufficiently stirred, revolving speed 4r/s, stirring
Time 45min prepares uniform, transparent colloid；
2）In step 1）NaLS is added in the colloid of preparation, is sufficiently stirred, revolving speed 3r/s, mixing time 30min,
It prepares containing bladdery colloid；
3）By step 2）After obtained colloid carries out vacuum outgas, it is anhydrous to sequentially add nano silica, titanium dioxide and part
Ethyl alcohol is sufficiently stirred, revolving speed 4r/s, mixing time 45min, prepares homogeneous, stable white lotion；
4）Toward step 3）Styrene-acrylic emulsion is added dropwise in obtained white lotion, is sufficiently stirred and grinds 1.5h, lotion is made；
5）Sodium benzoate, remaining dehydrated alcohol are slowly dropped to step 4）It in made lotion, carries out that 35min is sufficiently stirred, make
Obtain vamp whitening emulsion.
Ageing is coated on vamp with sponge brush afterwards for 24 hours, and coating layer thickness is about 0.03mm, at room temperature when film-forming
Between 5 min.The micro-crack that surface occurs plays infiltration and fills up reparation, and common attachment contact scar and sucking contact scar are in vamp
Spot, can easily cover, coating is well combined with vamp, and whitening effect is presented, and figure layer surface is continuous, smooth, does not roll into a ball
The defects of poly- little particle.
Embodiment 2
A kind of vamp whitening emulsion is grouped as by following group as mass fraction：Sodium benzoate 0.3%, nano silica
4%, glycerol 5%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 20%, titanium dioxide 8%, styrene-acrylic emulsion 30%, nothing
Water-ethanol 30%, fragrance 0.7%, wherein dehydrated alcohol and the total content of deionized water are fixed as 50%, the above components quality point
The sum of number is 100%.
The preparation method of vamp whitening emulsion, the specific steps are：
1）At 25 DEG C, sodium carboxymethylcellulose is added into deionized water, glycerol is sufficiently stirred, revolving speed 4r/s, stirring
Time 30min prepares uniform, transparent colloid；
2）In step 1）NaLS is added in the colloid of preparation, is sufficiently stirred, revolving speed 3r/s, mixing time 40min,
It prepares containing bladdery colloid；
3）By step 2）After obtained colloid carries out vacuum outgas, it is anhydrous to sequentially add nano silica, titanium dioxide and part
Ethyl alcohol is sufficiently stirred, revolving speed 4r/s, mixing time 30min, prepares homogeneous, stable white lotion；
4）Toward step 3）Styrene-acrylic emulsion is added dropwise in obtained white lotion, is sufficiently stirred and grinds 2h, lotion is made；
5）Sodium benzoate, remaining dehydrated alcohol are slowly dropped to step 4）In made lotion, carries out that 30min is sufficiently stirred, add
Enter fragrance, vamp whitening emulsion is made.
It is coated on vamp after being aged 24 h with sponge brush, coating layer thickness is about 0.03 mm, at room temperature film-forming
10 min of time.The micro-crack that surface occurs plays infiltration and fills up reparation, and common attachment contact scar and sucking contact scar are in shoes
The spot in face can be covered easily, and coating and vamp compatibility are good, and whitening effect is presented, and figure layer surface is continuous, smooth, does not have
There is the defects of reunion little particle.
Embodiment 3
A kind of vamp whitening emulsion is grouped as by following group as mass fraction：Sodium benzoate 0.3%, nano silica
4%, glycerol 10%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 20%, titanium dioxide 8%, styrene-acrylic emulsion 25%,
Dehydrated alcohol 30%, essence 0.7%.
The preparation method of vamp whitening emulsion, the specific steps are：
1）At 25 DEG C, sodium carboxymethylcellulose is added into deionized water, glycerol is sufficiently stirred, revolving speed 4r/s, stirring
Time 60min prepares uniform, transparent colloid；
2）In step 1）NaLS is added in the colloid of preparation, is sufficiently stirred, revolving speed 3r/s, mixing time 20min,
It prepares containing bladdery colloid；
3）By step 2）After obtained colloid carries out vacuum outgas, it is anhydrous to sequentially add nano silica, titanium dioxide and part
Ethyl alcohol is sufficiently stirred, revolving speed 4r/s, mixing time 60min, prepares homogeneous, stable white lotion；
4）Toward step 3）Styrene-acrylic emulsion is added dropwise in obtained white lotion, is sufficiently stirred and grinds 2h, lotion is made；
5）Sodium benzoate, remaining dehydrated alcohol are slowly dropped to step 4）In made lotion, carries out that 40min is sufficiently stirred, add
Enter fragrance, vamp whitening emulsion is made.
After being aged 24 h, bubble-free in coating, it is porous the defects of.It is coated on vamp with sponge brush, coating layer thickness is about
0.03 mm, 10 min of film-forming time, coating are well combined with vamp at room temperature, and brightness effect is brightened in presentation, are schemed
The defects of layer surface is continuous, smooth, little particle of not reuniting.
Embodiment 4
A kind of vamp whitening emulsion is grouped as by following group as mass fraction：Sodium benzoate 0.3%, nano silica
5%, glycerol 0%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 30%, titanium dioxide 9%, styrene-acrylic emulsion 30%, cunning
Mountain flour 3%, dehydrated alcohol 20%, essence 0.7%.
The preparation method of vamp whitening emulsion, the specific steps are：
1）At 25 DEG C, sodium carboxymethylcellulose is added into deionized water, glycerol is sufficiently stirred, revolving speed 4r/s, stirring
Time 50min prepares uniform, transparent colloid；
2）In step 1）NaLS is added in the colloid of preparation, is sufficiently stirred, revolving speed 3r/s, mixing time 35min,
It prepares containing bladdery colloid；
3）By step 2）After obtained colloid carries out vacuum outgas, nano silica, talcum powder, titanium dioxide and portion are sequentially added
Divide dehydrated alcohol, is sufficiently stirred, revolving speed 4r/s, mixing time 50min, prepares homogeneous, stable white lotion；
4）Toward step 3）Styrene-acrylic emulsion is added dropwise in obtained white lotion, is sufficiently stirred and grinds 1.8h, lotion is made；
5）Sodium benzoate, remaining dehydrated alcohol are slowly dropped to step 4）In made lotion, carries out that 35min is sufficiently stirred, add
Enter fragrance, vamp whitening emulsion is made.
After being aged 24 h, bubble-free in coating, it is porous the defects of.It is coated on vamp with sponge brush, coating layer thickness is about
0.03 mm, 2 min of film-forming time, coating are well combined with vamp at room temperature, and brightness effect is brightened in presentation, are schemed
Layer surface is continuous, smooth.
The addition of talcum powder helps to shorten the film-forming time, and talcum powder main component is magnesium silicate, needle-shaped and fine
What dimension structure increased vamp whitening emulsion leads ductility, adhesive force, strong adsorption force, convenient for whitening emulsion in the good, steady of vamp
Fixed attachment and bonding；Simultaneously because talcum powder has special taxis and slip, and rubbing agent nano-silica powder dirt
Superfine, specific surface area reaches 100m2/ g or more, superficial attractive forces are strong, and surface can be big, and chemical purity is high, dispersion performance is good, favorably
It sprawls and permeates vamp is smooth in vamp whitening emulsion, preferably bond, play a role between vamp.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, is all covered by the present invention.
Claims (3)
1. a kind of vamp whitening emulsion, it is characterised in that：It is grouped as by following group as mass fraction：Sodium benzoate 0.3%,
Rubbing agent 1%~15%, glycerol 0%~30%, NaLS 1%, sodium carboxymethylcellulose 1%, deionized water 10%~40%, titanium
White powder 1%~15%, styrene-acrylic emulsion 15%~30%, talcum powder 0%~3%, dehydrated alcohol 0%~40%, fragrance 0 ~ 0.7%, wherein nothing
Water-ethanol and the total content of deionized water are fixed as 50%, and the sum of the above components mass fraction is 100%.
2. vamp whitening emulsion according to claim 1, it is characterised in that：The rubbing agent is silica, carbonic acid
One of calcium, calcium bicarbonate, aluminium hydroxide.
3. a kind of method for preparing vamp whitening emulsion as claimed in claim 1 or 2, it is characterised in that：Include the following steps：
1）At 25 DEG C, sodium carboxymethylcellulose is added into deionized water, glycerol is sufficiently stirred, revolving speed 4r/s, stirring
Time 30min~60min prepares uniform, transparent colloid；
2）In step 1）NaLS is added in the colloid of preparation, is sufficiently stirred, revolving speed 3r/s, mixing time 20min
~40min is prepared containing bladdery colloid, can carry out appropriate vacuumize；
3）By step 2）After obtained colloid carries out vacuum outgas, it is anhydrous to sequentially add rubbing agent, talcum powder, titanium dioxide and part
Ethyl alcohol is sufficiently stirred, revolving speed 4r/s, mixing time 30min~60min, prepares homogeneous, stable white lotion；
4）Toward step 3）Styrene-acrylic emulsion is added dropwise in obtained white lotion, is sufficiently stirred and grinds 1h~2h, lotion is made；
5）Sodium benzoate, remaining dehydrated alcohol are slowly dropped to step 4）In made lotion, be sufficiently stirred 30min~
Fragrance is added in 40min, and vamp whitening emulsion is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810561352.2A CN108822629A (en) | 2018-06-04 | 2018-06-04 | A kind of vamp whitening emulsion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810561352.2A CN108822629A (en) | 2018-06-04 | 2018-06-04 | A kind of vamp whitening emulsion and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108822629A true CN108822629A (en) | 2018-11-16 |
Family
ID=64143367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810561352.2A Pending CN108822629A (en) | 2018-06-04 | 2018-06-04 | A kind of vamp whitening emulsion and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108822629A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073475A (en) * | 1991-12-16 | 1993-06-23 | 黄立 | Cleaner special for leather sports shoes |
| US20020123437A1 (en) * | 2000-10-30 | 2002-09-05 | Conboy Frank Edward | Fragrance composition of a cyclic ketone |
| CN103059735A (en) * | 2011-10-24 | 2013-04-24 | 汤治强 | White shoe cream and preparation method thereof |
| CN104958225A (en) * | 2015-07-24 | 2015-10-07 | 大连民族大学 | Cherry toothpaste and preparation method thereof |
| CN106700947A (en) * | 2016-11-29 | 2017-05-24 | 梧州市海邦科技有限公司 | High-gloss shoe cream |
| CN107904054A (en) * | 2017-11-07 | 2018-04-13 | 杨寿 | A kind of white footwear detergent |
-
2018
- 2018-06-04 CN CN201810561352.2A patent/CN108822629A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073475A (en) * | 1991-12-16 | 1993-06-23 | 黄立 | Cleaner special for leather sports shoes |
| US20020123437A1 (en) * | 2000-10-30 | 2002-09-05 | Conboy Frank Edward | Fragrance composition of a cyclic ketone |
| CN103059735A (en) * | 2011-10-24 | 2013-04-24 | 汤治强 | White shoe cream and preparation method thereof |
| CN104958225A (en) * | 2015-07-24 | 2015-10-07 | 大连民族大学 | Cherry toothpaste and preparation method thereof |
| CN106700947A (en) * | 2016-11-29 | 2017-05-24 | 梧州市海邦科技有限公司 | High-gloss shoe cream |
| CN107904054A (en) * | 2017-11-07 | 2018-04-13 | 杨寿 | A kind of white footwear detergent |
Non-Patent Citations (2)
| Title |
|---|
| 陈泽森，刘俊才: "《水性建筑涂料生产技术》", 31 January 2007, 中国纺织出版社 * |
| 颜进华: "《造纸化学品》", 31 August 2015, 华南理工大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103555045B (en) | Water-tolerant decorative fiber coating | |
| EP3556815B1 (en) | Waterborne inorganic anti-doodling ceramic paint for indoor walls and preparation method therefor | |
| CN106243966A (en) | A kind of composite multifunction double-component aqueous woodenware white finish paint and preparation method thereof | |
| CN105694631B (en) | A kind of stain resistant aqueous glaze and preparation method thereof, application | |
| KR100947235B1 (en) | Wood panel with loess adhesive layer and its manufacturing method thereof | |
| CN103819145B (en) | A kind of illusion-colour lines coating process of diatom ooze coating | |
| CN101781485B (en) | Production method of fiber grain liquid wallpaper | |
| CN106883688A (en) | A kind of wear-resisting automatically cleaning emulsion paint of safe environment protection type and preparation method thereof | |
| CN101585678A (en) | Attapulgite interior wall emulsion varnish | |
| CN105219272A (en) | A kind of purifying formaldehyde type dry powder paint and preparation method thereof | |
| CN110395965A (en) | It is a kind of to remove aldehyde interior wall coating and preparation method thereof by the inorganic of filler material of conch meal | |
| CN108822629A (en) | A kind of vamp whitening emulsion and preparation method thereof | |
| CN107674574A (en) | Children's interior wall coating and production method | |
| CN104774518B (en) | A kind of aqueouss texture coating and preparation method thereof | |
| CN101585691B (en) | Attapulgite interior wall powder coating | |
| CN111423783A (en) | Antibacterial odor-removing water-based environment-friendly building coating and preparation method thereof | |
| TW201610030A (en) | Nano anion functional water-in-water interior wall paint and preparation method thereof | |
| CN109796824A (en) | A kind of emulation mineral varnish color grain, emulation mineral varnish and its preparation method and application | |
| CN111849272A (en) | Sand coating and preparation method thereof | |
| CN108727925A (en) | A kind of environmentally friendly water-repellent paint and preparation method thereof | |
| CN109651910A (en) | A kind of coating | |
| CN109593418A (en) | Polyacrylate aqueous latex paint and preparation method thereof | |
| CN107474621A (en) | One kind is except formaldehyde multifunctional wall surface putty powder and preparation method thereof | |
| CN1621457A (en) | Fiber containing paint composition and its preparation method and use | |
| CN106189625A (en) | A kind of environment-friendly waterproof fluorescent paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181116 |
|
| RJ01 | Rejection of invention patent application after publication |