CN108797124A - 一种纯棉服装用防皱整理剂及其整理工艺 - Google Patents
一种纯棉服装用防皱整理剂及其整理工艺 Download PDFInfo
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Abstract
本发明提出了一种纯棉服装用防皱整理剂及其整理工艺，该防皱整理剂包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物5‑13％、环氧聚醚共改性硅油5‑10％、促进剂1‑4％、柠檬酸1.2‑4.5％、十二烷基硫酸镁1‑3％、纳米硅溶胶3‑10％、溶剂余量，还包括N‑甲基甲酰苯胺0‑3％、碳酸丙烯酯0‑3％、复合提取液0‑5％，本发明通过科学合理的原料搭配，具有优异的反应联结性，对棉织物的防皱处理性好，稳定性强，且具有良好的抗菌性，安全环保性好，综合实用性强。
Description
技术领域
本发明涉及服装整理技术领域，具体涉及一种纯棉服装用防皱整理剂及其整理工艺。
背景技术
棉织物又称棉布，是以棉纱为原料织造的织物。由于其具有多功能、柔软、透气、吸湿、全年穿着的舒适性、性能优良和耐穿等性能，棉织物广泛用于服装面料、装饰织物和产业用织物。
但原棉织物容易发生起皱与收缩，在穿着和洗涤的过程中容易起皱不能保持平整的外观，需要经常熨烫，因此需要及时对其进行防皱整理以达到保持织物外观平整的目的。同时因棉质面料容易成为微生物生长繁殖的良好场所，因而给人们带来了极大的不便利性。
棉织物的防皱整理已有近百年的历史，目前所用的防皱整理剂大部分都是2D树脂，但是经2D树脂整理后的织物在使用和贮存过程中会释放出大量的甲醛，危害人体健康。
随着人们环保意识的增强，人们更倾向于无甲醛或低甲醛，且防皱效果好的整理剂。另外，在日常生活中，人们不可避免地会接触到各种各样的微生物。为了获得高品质的棉质服装，急需研制出一种新型的抗菌型防皱整理剂。
发明内容
针对上述存在的问题，本发明提出了纯棉服装用防皱整理剂及其整理工艺，通过科学合理的原料搭配，具有优异的反应联结性，对棉织物的防皱处理性好，稳定性强，且具有良好的抗菌性，安全环保性好，综合实用性强。
为了实现上述的目的，本发明采用以下的技术方案：
一种纯棉服装用防皱整理剂，包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物5-13％、环氧聚醚共改性硅油5-10％、促进剂1-4％、柠檬酸1.2-4.5％、十二烷基硫酸镁1-3％、纳米硅溶胶3-10％、溶剂余量。
优选的，还包括N-甲基甲酰苯胺0-3％、碳酸丙烯酯0-3％、复合提取液0-5％。
优选的，促进剂采用质量比1:1:2-4的烷基酰胺、氨基甲酸甲酯、磷酸盐。
优选的，复合提取液包括黄芩、银杏、丁香，三者质量比为0.5-1:1-2:1-2。
优选的，纯棉服装用防皱整理剂，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌10-20min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌30-40min，然后将混料一加入其中，继续搅拌5-10min，40-45℃保温静置2-5h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理5-15min，即可。
优选的，步骤1)中加热高度搅拌具体为温度60-65℃，转速为700-1000rpm。
优选的，步骤2)中保温搅拌具体为温度53-55℃，转速为300-450rpm。
优选的，步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为10-15vt％，通入量为1.2-1.5L/h。
优选的，制得的纯棉服装用防皱整理剂的应用：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可。
优选的，浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
由于采用上述的技术方案，本发明的有益效果是：本发明通过科学合理的原料搭配，具有优异的反应联结性，对棉织物的防皱处理性好，稳定性强，且具有良好的抗菌性，安全环保性好，综合实用性强，值得推广。
本发明以壳聚糖接枝丙烯酰胺共聚物、环氧聚醚共改性硅油为主要交联成分，具有优异的反应活性和连接效果，对羟基、氨基、羧基的反应结合密度大，稳定性强，有效保证了除皱的效果和效率，持久性强，配合柠檬酸、十二烷基硫酸镁、纳米硅溶胶，原料分散性强，嵌合效果好，大大提高了反应的效率，且赋予了额外的优异抗菌、防护效果，紫外防护性好，同时具有柔软芳香效果，穿着舒适，面料综合实用性好。
采用本发明整理方法整理后的纺织品DP等级达大于3.8，吸氨值大于86％，整体纺织品WAR大于213°，经向拉伸为493.8N，纬向拉伸为266.4N，断裂强力大于348N，白度指数大于82.41(原纯棉织物白度为83.78)。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述。基于本发明的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
一种纯棉服装用防皱整理剂，包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物5％、环氧聚醚共改性硅油10％、促进剂4％、柠檬酸1.2％、十二烷基硫酸镁1％、纳米硅溶胶6％、溶剂余量。还包括N-甲基甲酰苯胺3％、碳酸丙烯酯2％、复合提取液4％。
其中：促进剂采用质量比1:1:2的烷基酰胺、氨基甲酸甲酯、磷酸盐；复合提取液包括黄芩、银杏、丁香，三者质量比为0.5:1:2。
纯棉服装用防皱整理剂，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌15min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌35min，然后将混料一加入其中，继续搅拌5min，40℃保温静置2h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理10min，即可。
步骤1)中加热高度搅拌具体为温度60℃，转速为800rpm；步骤2)中保温搅拌具体为温度53℃，转速为400rpm；步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为10vt％，通入量为1.2L/h。
制得的纯棉服装用防皱整理剂的应用：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可，浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
实施例2：
一种纯棉服装用防皱整理剂，包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物10％、环氧聚醚共改性硅油8％、促进剂3％、柠檬酸3.5％、十二烷基硫酸镁2.5％、纳米硅溶胶3％、溶剂余量。还包括N-甲基甲酰苯胺2％、碳酸丙烯酯1％、复合提取液3％。
其中：促进剂采用质量比1:1:3的烷基酰胺、氨基甲酸甲酯、磷酸盐；复合提取液包括黄芩、银杏、丁香，三者质量比为0.8:1.2:2。
纯棉服装用防皱整理剂，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌10min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌40min，然后将混料一加入其中，继续搅拌10min，40℃保温静置3h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理10min，即可。
步骤1)中加热高度搅拌具体为温度65℃，转速为700rpm；步骤2)中保温搅拌具体为温度53℃，转速为350rpm；步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为15vt％，通入量为1.5L/h。
制得的纯棉服装用防皱整理剂的应用：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可，浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
实施例3：
一种纯棉服装用防皱整理剂，包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物8％、环氧聚醚共改性硅油6％、促进剂2％、柠檬酸4％、十二烷基硫酸镁3％、纳米硅溶胶10％、溶剂余量。还包括N-甲基甲酰苯胺2％、碳酸丙烯酯3％、复合提取液5％。
其中：促进剂采用质量比1:1:2的烷基酰胺、氨基甲酸甲酯、磷酸盐；复合提取液包括黄芩、银杏、丁香，三者质量比为0.5:2:1.5。
纯棉服装用防皱整理剂，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌20min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌30min，然后将混料一加入其中，继续搅拌5min，45℃保温静置3h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理15min，即可。
步骤1)中加热高度搅拌具体为温度65℃，转速为1000rpm；步骤2)中保温搅拌具体为温度55℃，转速为300rpm；步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为15vt％，通入量为1.5L/h。
制得的纯棉服装用防皱整理剂的应用：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可，浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
实施例4：
一种纯棉服装用防皱整理剂，包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物13％、环氧聚醚共改性硅油5％、促进剂1％、柠檬酸4.5％、十二烷基硫酸镁2％、纳米硅溶胶5％、溶剂余量。还包括N-甲基甲酰苯胺1％、碳酸丙烯酯2％。
其中：促进剂采用质量比1:1:3的烷基酰胺、氨基甲酸甲酯、磷酸盐。
纯棉服装用防皱整理剂，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌15min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌40min，然后将混料一加入其中，继续搅拌10min，45℃保温静置5h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理15min，即可。
步骤1)中加热高度搅拌具体为温度60℃，转速为800rpm；步骤2)中保温搅拌具体为温度53℃，转速为450rpm；步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为10vt％，通入量为1.5L/h。
制得的纯棉服装用防皱整理剂的应用：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可，浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
实施例5：
一种纯棉服装用防皱整理剂，包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物12％、环氧聚醚共改性硅油10％、促进剂3％、柠檬酸2.8％、十二烷基硫酸镁1.5％、纳米硅溶胶4％、溶剂余量。
其中：促进剂采用质量比1:1:4的烷基酰胺、氨基甲酸甲酯、磷酸盐。
纯棉服装用防皱整理剂，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌10min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌40min，然后将混料一加入其中，继续搅拌10min，45℃保温静置3h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理10min，即可。
步骤1)中加热高度搅拌具体为温度65℃，转速为700rpm；步骤2)中保温搅拌具体为温度55℃，转速为450rpm；步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为15vt％，通入量为1.2L/h。
制得的纯棉服装用防皱整理剂的应用：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可，浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
采用本发明整理方法整理后的纺织品DP等级达大于3.8，吸氨值大于86％，整体纺织品WAR大于213°，经向拉伸为493.8N，纬向拉伸为266.4N，断裂强力大于348N，白度指数大于82.41(原纯棉织物白度为83.78)。
采用本发明实施例1中整理液对棉织物进行整理，整理后的布样分别不经机洗和机洗1次，将整理后的织物送到有资质的专业检测机构进行清新效果的检测，表明，棉织物经过整理液整理后，水洗前的织物清新效果良好，通过吸氨值测定，氨气浓度减少率为94％，机洗后的织物吸氨效果仍达到81％，满足消臭纺织品技术要求。
以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。
Claims (10)
1.一种纯棉服装用防皱整理剂，其特征在于：包括以下质量百分含量组分：壳聚糖接枝丙烯酰胺共聚物5-13％、环氧聚醚共改性硅油5-10％、促进剂1-4％、柠檬酸1.2-4.5％、十二烷基硫酸镁1-3％、纳米硅溶胶3-10％、溶剂余量。
2.根据权利要求1所述的纯棉服装用防皱整理剂，其特征在于：还包括N-甲基甲酰苯胺0-3％、碳酸丙烯酯0-3％、复合提取液0-5％。
3.根据权利要求2所述的纯棉服装用防皱整理剂，其特征在于：所述促进剂采用质量比1:1:2-4的烷基酰胺、氨基甲酸甲酯、磷酸盐。
4.根据权利要求2所述的纯棉服装用防皱整理剂，其特征在于：所述复合提取液包括黄芩、银杏、丁香，三者质量比为0.5-1:1-2:1-2。
5.根据权利要求1-4任一项所述的纯棉服装用防皱整理剂，其特征在于，制备方法如下：
1)按质量百分比称取原料，将壳聚糖机制丙烯酰胺共聚物与纳米硅溶胶共混，加热高速搅拌10-20min，得混料一；
2)将柠檬酸、十二烷基硫酸镁加入一半溶剂中，加热搅拌30-40min，然后将混料一加入其中，继续搅拌5-10min，40-45℃保温静置2-5h，得混料二；
3)将剩余物料进行共混，混匀后，在搅拌条件下缓慢加入混料二中，惰性氛围下超声处理5-15min，即可。
6.根据权利要求5所述的纯棉服装用防皱整理剂，其特征在于：步骤1)中加热高度搅拌具体为温度60-65℃，转速为700-1000rpm。
7.根据权利要求5所述的纯棉服装用防皱整理剂，其特征在于：步骤2)中保温搅拌具体为温度53-55℃，转速为300-450rpm。
8.根据权利要求5所述的纯棉服装用防皱整理剂，其特征在于：步骤3)中惰性氛围为氮气、二氧化碳混合气，其中二氧化碳含量为10-15vt％，通入量为1.2-1.5L/h。
9.一种由权利要求5制得的纯棉服装用防皱整理剂的应用，其特征在于：将制得的防皱整理剂与水按体积比1:10-30配制成整理液，将棉织物浸泡于整理液中，调节温度为55℃，浸泡时间为4-5h，取出，60-70℃真空干燥即可。
10.根据权利要求9所述的纯棉服装用防皱整理剂的应用，其特征在于：浸泡过程中采用通入热蒸汽保持溶液温度，且温度浮动不超过2℃。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113832744A (zh) * | 2021-10-12 | 2021-12-24 | 广州市当美服饰有限公司 | 环保服装染料及在服装印染中的应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632216A (zh) * | 2004-11-03 | 2005-06-29 | 华南理工大学 | 多功能棉织物整理剂及其制备方法 |
| CN101634108A (zh) * | 2009-07-24 | 2010-01-27 | 东莞市德能化工有限公司 | 纯棉服装用树脂整理剂组合物及其制备方法 |
| CN106758155A (zh) * | 2016-12-21 | 2017-05-31 | 阜阳市豹子头服饰科技有限公司 | 一种衬衫的阻燃透气型免烫整理液及其整理方法 |
| CN107164952A (zh) * | 2017-06-01 | 2017-09-15 | 广东群豪服饰有限公司 | 一种用于纺织品除臭防皱的整理工艺 |
-
2018
- 2018-07-02 CN CN201810708504.7A patent/CN108797124B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632216A (zh) * | 2004-11-03 | 2005-06-29 | 华南理工大学 | 多功能棉织物整理剂及其制备方法 |
| CN101634108A (zh) * | 2009-07-24 | 2010-01-27 | 东莞市德能化工有限公司 | 纯棉服装用树脂整理剂组合物及其制备方法 |
| CN106758155A (zh) * | 2016-12-21 | 2017-05-31 | 阜阳市豹子头服饰科技有限公司 | 一种衬衫的阻燃透气型免烫整理液及其整理方法 |
| CN107164952A (zh) * | 2017-06-01 | 2017-09-15 | 广东群豪服饰有限公司 | 一种用于纺织品除臭防皱的整理工艺 |
Non-Patent Citations (1)
| Title |
|---|
| 倪沛红等: ""壳聚糖接枝物对丝绸防皱整理的影响"", 《第六届全国印染后整理学术研讨会论文集》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113832744A (zh) * | 2021-10-12 | 2021-12-24 | 广州市当美服饰有限公司 | 环保服装染料及在服装印染中的应用 |
| CN113832744B (zh) * | 2021-10-12 | 2023-09-19 | 开平市信迪染整厂有限公司 | 环保服装染料及在服装印染中的应用 |
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