CN108794175A - A kind of organic fertilizer and preparation method thereof - Google Patents
A kind of organic fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN108794175A CN108794175A CN201810710548.3A CN201810710548A CN108794175A CN 108794175 A CN108794175 A CN 108794175A CN 201810710548 A CN201810710548 A CN 201810710548A CN 108794175 A CN108794175 A CN 108794175A
- Authority
- CN
- China
- Prior art keywords
- parts
- fertilizer
- organic fertilizer
- poly
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/35—Capsules, e.g. core-shell
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/37—Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer
Abstract
The invention belongs to fertilizer processing technique field, it is related to a kind of organic fertilizer and preparation method thereof, the organic fertilizer constituent and its quality parts ratio are：60~70 parts of filter mud of sugar refinery, 15~30 parts of urea, 5~12 parts of monoammonium phosphate, 15~25 parts of potassium chloride, modified 10~15 parts of poly-aspartic-acid resin, 5~8 parts of composite fermentation microbial inoculum, 2~4 parts of composite functional bacterial agent, it is mixed to prepare biological organic fertilizer after 5~8 parts of composite fermentation microbial inoculum, 60~70 parts of addition filter mud of sugar refinery progress fermentation maturities, then with 15~30 parts of urea, 5~12 parts of monoammonium phosphate, 15~25 parts of potassium chloride, modified 10~15 parts of poly-aspartic-acid resin, 2~4 parts of composite functional bacterial agent.The organic fertilizer pest controling effect of the present invention is good, efficacy stability, and the drug effect phase is long, it can inhibit weed growth when preventing desinsection, moreover it is possible to nutrient be provided, be not in de- fertile phenomenon in the plant growth later stage, the nutritional need for ensureing plant growth, integrates nutrition, soil improvement and pest control.
Description
The application is application No. is 2017108908032, and the applying date is on 09 27th, 2017, and invention and created name is
The divisional application of the patent of " a kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and preparation method thereof ".
Technical field
The invention belongs to fertilizer processing technique field, it is related to a kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and its preparation side
Method.
Background technology
Fertilizer can provide nutriment to crop, ensure the growth of crop, constantly occur in the process of plant growth each
Kind insect pest achievees the purpose that kill pest and disease damage using drug to remove the insect pest of process of crop growth.Pesticide and chemical fertilizer are agricultures
Common chemicals in industry production, it is a large amount of using can contaminated soils, water body etc., asked in the product of production there is also pesticide is exceeded
Topic, endangers the health of the mankind.Currently, cane planting is most of also according to traditional fertilizer and pesticide separate administration pattern, band
There are random and blindness, time-consuming, waste of resource, and some pesticide-fertilizer products to circulate in the market are also that insect prevention is single, are not had
There are simultaneous anti-ground and subterranean pest-insect, and pesticide and fertilizer, without any sustained release performance, the lasting period is shorter.
Medicine fertilizer refers to being formed by fertilizer and pesticide are stable in specific compound system by certain technology
Novel ecological fertilizer, the system can ensure that fertilizer nutrient and pesticide active ingredient while effect does not reduce, can play
The synergistic effect of the two does not constitute potential pollution to crop and soil agricultural production system.Medicine fertilizer is usually to make pesticide with fertilizer
Carrier.Medicine is used in combination with the two, avoids multiple fertilising, reduces labour, and reduce time and energy
The consumption in source reduces production cost.
Sugarcane is the major economic crops in Guangxi, and growth phase is long, and yield is high, and entire breeding time needs a large amount of nutrient,
It is the bigger crop of fertilizer requirement, people also take away a large amount of nutrient while harvesting sugarcane, therefore it is true to supplement fertilizer
Protect the key of sugarcane high and stable yields.Sugarcane production each period all can there is pest and disease damage, such as sugarcane borer, grub, aphid,
These insect pests cause the withered heart seedling of sugarcane, middle and later periods to destroy sugarcane stem tissue, frangibility lodging in early period.The prevention and control of plant diseases, pest control is improper to be made
At sugarcane quality decline and the underproduction, heavy economic losses is caused.
Clothianidin is a kind of insecticide in anabasine, is a kind of highly effective and safe, highly selective novel pesticide,
Effect is similar with nicotinic acetylcholine receptor, have tag, stomach toxicity and systemic activity, have that efficient, wide spectrum, dosage be few, toxicity
Low, drug effect lasting period is long, to crop without poisoning, it is safe to use, with conventional pesticide no interactions resistance the advantages that, have remarkable interior suction
And osmosis.Control of insect by clothianidin pesticide for crops such as sugarcanes, it is environmentally friendly, moreover it is possible to preferably to prevent a variety of
Crop pest has preferable control effect to sugarcane moth borer, sugarcane aphid etc..
Sustained-controll-release fertiliser refers to making the initial slow release of its nutrient by various regulatory mechanisms, it is effective to its to extend crop
The term of validity of nutrient uptake and utilization, make its nutrient according to setting release rate and acquisition time slowly or control release make nutrients release
The curve fertilizer consistent with crop demand.The fertilizer outstanding feature is to synchronize supply according to plant growth law curve effectively to support
Point, to make fertilizer nutrient effective rate of utilization be greatly improved, under the premise of ensuring plant growth, with same analysis fertilizer
It compares, improves utilization rate of fertilizer, the dosage of traditional fertilizer can be made to greatly reduce.Sustained-controll-release fertiliser, which has, to be reduced dose, saves
Chemical fertilizer production raw material improves utilization rate of fertilizer, reduces the advantages that ecological environmental pollution.
For medicine fertilizer, Chinese patent (201110191806.X), discloses a kind of controlled release particle pesticide-containing fertilizer of stabilization at present, should
Medicine fertilizer is nucleocapsid, is in granular form, and the core of medicine fertilizer is the mixture of fertilizer and pesticide, one layer of epoxy resin control of outer layer covers
Preparative layer, the medicine fertilizer enable pesticide, fertilizer to be stabilized simultaneously slow release, reduce crop growth period fertilising and spraying times, save
Field labour.
For another example, Chinese patent (201320781660.9) disclose a kind of medicine fertilizer, and the medicine fertilizer is by five layers of different materials group
At, including pesticide powder core, it is enclosed with the first fertilizer layer on the outside of the pesticide powder core, is wrapped on the outside of the first fertilizer layer
It is wrapped with the first sustained release oxidant layer, the first pesticide powder oxidant layer is enclosed on the outside of the first sustained release oxidant layer, in first pesticide powder
Layer outside is enclosed with the second sustained release oxidant layer, and the second fertilizer layer is enclosed on the outside of the second sustained release oxidant layer.The medicine fertilizer is in soil
Start to apply fertilizer when farming, nutrition is provided at crop germination initial stage, medicinal powder acts on crop root and kill off the insect pests, in crop second
Growth period provides fertilizer and medicinal powder again, secondary to nutrient and kill off the insect pests.The medicine fertilizer labor intensity is small, efficiency of applying fertilizer
Height can provide crop yield, while save labour.
For another example Chinese patent (201210533645.2) disclose a kind of Smart controlled-release fertilizer, the medicine fertilizer respectively composition at
Divide and its weight proportion is：0.2%-0.5% modified form reticular structure polyacrylamides, 0.5%-0.8% polymer wood quality,
Remaining ingredient is nitrogen, phosphorus, potassium and other fillers, and filler is clay and anticaking agent.The fertilizer is by the netted poly- propionamide of modified form
Molecule and polymer wood quality combine, and form each small-sized netted reservoir and nutrient pool in the soil, make nutrient, moisture and soil
It firmly combines, N P and K no longer leaching loss and volatilization, small-sized nutrient pool are fixed, to control Releasing nutrient speed.Medicine fertilizer
It can be enough obviously improved soil aggregate structure, alleviate soil hardening and acidification, increase gas permeability, increase soil water storage ability, tool
Loosen the soil water retaining function, promotes root growth, keeps vigorous fertilizer sucting ability, and can reduce rate of fertilizer.
In terms of for prevention sugarcane pest and disease damage, Chinese patent (201210407726.8) discloses a kind of prevention sugarcane borer
The fertilizer granules of worm, the medicine fertilizer particle are made of anabasine insecticide, crop nutrition and carrier, and each component and its content are
0.01-0.7 parts of anabasine insecticide, 50-95 parts of crop nutrition, 5-50 parts of carrier.It is more that the medicine fertilizer composition realizes a fertilizer
Purpose achievees the purpose that kill the pests such as sugarcane moth borer when to crop fertilization, have the characteristics that efficient, safe, less toxic.
For another example, Chinese patent (201310388799.1) discloses a kind of sugarcane disease-prevention and insecticide medicament fertilizer formulation and producer
Method, the formula and its weight part ratio of medicine fertilizer are：15-30 parts of chlopyrifos, 5-10 parts of imidacloprid, 30-50 parts of Bravo, phosphoric acid
5-10 parts of potassium dihydrogen；1-3 parts of wetting agent, 2-5 parts of dispersant, 1-1.5 parts of anticaking agent, 0.01-0.05 parts of antifoaming agent, suspending agent
0.5-1 parts, 10-20 parts of filler.The medicine fertilizer using double worm mixer mixing and airslide disintegrating mill crushing and processing by being formed.The medicine
A fertile medicine is multi-purpose, improves the disease-resistant effect of insect prevention, reduces spraying times, saves every cost.
For another example, Chinese patent (201610353274.8) discloses a kind of medicament-fertilizer mixture of clothianidin-containing, by clothianidin system
At the clothianidin-containing granular pesticide with slow release effect, the granular pesticide by three layers of active ingredient, each active ingredient by
Clothianidin, crosslinking agent, auxiliary material form according to a certain ratio, then the pesticide granules and fertilizer are mixed to get medicament-fertilizer mixture.Medicine fertilizer
The dosage of drug and fertilizer can be reduced, labour cost is reduced, reduces environmental pollution.
Invention content
The purpose of the present invention is overcoming desinsection drug effect in existing medicine fertilizer single, and pesticide high poison high residue, drug effect is unstable,
The problems such as drug effect phase is short, and environmental pollution is serious provides a kind of prevention pest and disease damage new drug fertilizer, the medicine fertilizer have it is safe efficient, less toxic,
The advantages of low-residual, can provide nutrient to crops such as sugarcanes, and can make with good prevention to the pest of sugarcane production phase
With, while the growth of sugarcane weeds can also be inhibited, it is environmentally friendly medicine fertilizer.
The scheme of the invention is realize in this way：A kind of clothianidin-containing prevention pest and disease damage new drug fertilizer, the medicine fertilizer is by two
Layer composition, internal layer core are the mixture of clothianidin microcapsules, organic fertilizer and filler, and the outer layer is clothianidin and weeding
The mixture of microcapsules, organic fertilizer and filler that agent is mixed, the interlayer membrane material are ethyl cellulose and lignin
Mixture, characterized in that the medicine each constituent of fertilizer and its weight part ratio are：0.06% 1~2 part of clothianidin solution,
50~60 parts of biological organic fertilizer, 1~3 part of herbicide, 10~15 parts of capsule wall material, 10~15 parts of binder, filler 20~30
Part.
The technical principle that the present invention realizes is：
Slow releasing medicinal fertilizer is made in the medicine fertilizer, can need to release nutriment and drug according to the growth of crop.The medicine
Fertilizer is formed by two layers, and outermost layer is organic fertilizer, insecticide clothianidin, herbicide, and outermost layer substance can be given when applying fertilizer early stage
Sugarcane provides nutrient, and the generation of pest control inhibits the growth of weeds, microcapsules is made in clothianidin and herbicide, drug is slow
Slow release is released, and can ensure the duration and stability of drug effect, to achieve the effect that long period insect prevention and weeding.Medicine fertilizer
Granule core ethyl cellulose and lignin package, the speed ratio outer layer medicine fertilizer rate of release of release is slow, can be constant
Ground provides fertilizer nutrient to soil, discharges insecticidal materials again, achievees the effect that pest control.Clothianidin is that novel nicotinoids are high
Active insecticide, with absorbability, the broad spectrum pesticide tagged with stomach poison function, can effectively to kill to organic phosphates, amino
Formate ester and pyrethroid insecticides have resistance pest, have to snout moth's larva, aphid, the sugarcane tortoise etc. on sugarcane good
Good preventive effect is the drug for preventing pest and disease damage with clothianidin, can prevent the generation of a variety of pest and disease damages of sugarcane, and clothianidin dosage
Less, toxicity is low, drug effect is long, to crop object poisoning, safe to use.Herbicide used is that first is gone out diuron and methyl sulphur grass
Ketone, first go out diuron be a kind of wide spectrum, low toxicity, low-residual herbicide, be mainly used for preventing and kill off sugarcane field annual grassy weeds,
High risk population：Barnyard grass, lady's-grass, three-coloured amaranth, eleusine indica, Japanese grass, Ageratum conyzoides etc., in Sugarcane Seedlings phase drug safety, dispenser
Phase is wide, and the lasting period is long；Mesotrione effect is fast, and dosage is few, and weeding has broad spectrum activity, quickly can widely drop in the soil
Solution, is finally metabolized as co 2, is influenced on sugarcane crop safety, environment small, is used in compounding with the first diuron that goes out, more can
Effectively remove the weeds in sugarcane.The filler of addition is zeolite, bentonite, vermiculite, diatomite, they have certain expansion
Property, adsorptivity, adherence etc., soil porosity can be reduced by applying in soil, the nutritional ingredient adsorbed in soil reaches fixed
Effect, does not lead to the loss of medicine fertilizer, moreover it is possible to macro- and trace-element (Ca, Mg, K, Fe needed for plant growth are brought to soil
Deng), have the function of fertilizer conservation, water conservation, improve soil texture；Modified poly-aspartic-acid resin can strengthen sugarcane to N, P, K
And the absorption of middle trace element, promote the growth of sugarcane, provide utilization rate of fertilizer, and there is powerful water suction moisture-keeping function,
It can ensure the water demand of sugarcane in the weather of arid, itself has good biocompatibility, can be biodegradable again
It is environmentally friendly at nontoxic substance；The poly butylene succinate or poly- of the package difficult degradation of membrane material of microcapsules A
Caprolactone acid, the slow release of insecticidal materials clothianidin can be extended, extend the drug effect phase of clothianidin, the medicine fertilizer invented according to
Prepared by the growth rhythm of crop, consistent with crop demand, the advantageous good growth for using crop.
It is further improved as the present invention, the organic fertilizer constituent and its quality parts ratio are：Filter mud of sugar refinery 60
~70 parts, 15~30 parts of urea, 5~12 parts of monoammonium phosphate, 15~25 parts of potassium chloride, modified poly-aspartic-acid resin 10~15
Part, 5~8 parts of composite fermentation microbial inoculum, 2~4 parts of composite functional bacterial agent；The preparation method of the organic fertilizer is by composite zymocyte
5~8 parts of agent is added after 60~70 parts of filter mud of sugar refinery carry out fermentation maturities, then with 15~30 parts of urea, 5~12 parts of monoammonium phosphate,
15~25 parts of potassium chloride, modified 10~15 parts of poly-aspartic-acid resin, 2~4 parts of composite functional bacterial agent is mixed to prepare biology has
Machine fertilizer.
It is further improved as the present invention, the modification poly-aspartic-acid resin chelates for poly-aspartic-acid resin
Calcium, magnesium, sulphur, boron, manganese, zinc, molybdenum element.
It is further improved as the present invention, the composite fermentation microbial inoculum is saccharomycete, bacillus licheniformis, withered grass gemma
The mixing of bacillus, Thermophilic Bacteria, bacillus pumilus；The composite functional bacterial agent be phosphate solubilizing bacteria, potassium solubilizing bacteria, nitrogen-fixing bacteria it is mixed
It closes.
It is further improved as the present invention, the herbicide is that first is gone out the mixing of diuron and mesotrione
Object.
It is further improved as the present invention, the capsule wall material is poly butylene succinate, polycaprolactone is sour, shell is poly-
Sugar, carboxymethyl cellulose, ethyl cellulose, lignin.
It is further improved as the present invention, the filler is zeolite, bentonite, vermiculite, diatomite；The bonding
Agent is the mixing of polyethylene glycol, sodium metasilicate, starch one or more；The emulsifier is Span-80, Tween-80 a kind of
Or two kinds of mixing.
A method of the clothianidin-containing prevention pest and disease damage new drug fertilizer is prepared, is included the following steps：
S1：It is prepared by microcapsules：1) microcapsules A:10~15 parts of poly butylene succinates or polycaprolactone acid solution are put
Enter in reaction kettle, the mixing of 10~15 parts of emulsifiers is added, 0.5~1 part of 0.06% clothianidin is added in reaction kettle, 40~
20~30min is stirred under 60 DEG C of 600~800r/min of temperature rotating speed, stirring allows utricule fully to adsorb drug, adjust pH be 8~
10, under conditions of temperature is 40~60 DEG C, shearing dispersion reaction 50~80 minutes after encystation, through being separated by solid-liquid separation, drying, is made
Obtain 0.06% clothianidin microcapsules A；2) microcapsules B:10~15 parts of chitosans and 10~15 parts of sodium carboxymethylcelluloses are mixed
Solution is added in reaction kettle, 0.5~1 part of 0.06% clothianidin, 1~3 herbicide of part is added, in 800~1000r/min speed
10~20min of lower stirring adjusts pH to 8~10, stirs 10~15min, and through being separated by solid-liquid separation, drying, 0.06% clothianidin is made
With herbicide mixing microcapsule B；
S2:Part microcapsules A, 60~70 parts of biological organic fertilizers, 20~35 parts of packing materials are mixed to get mixture A, it will
Part microcapsules B, 50~60 parts of biological organic fertilizers, 20~35 parts of packing materials are mixed to get mixture B；
S3:Granulated Cores are made by granulating disc in mixture A, in 10~15 parts of ethyls of Granulated Cores surface spraying
The mixed liquor of cellulose and lignin, again by wrapping up in comminutor, addition mixture B, 10~15 binders are wrapped core
It wraps up in granulation and particle medicinal fertilizer is made.
The present invention has following good result：
1. clothianidin is prevented for sugarcane moth borer, effect is better than conventional particles agent, and other insect pests are shown to sugarcane
Good preventive effect effect；
2. according to the nutrient demand of the crops such as sugarcane, the load using biological organic fertilizer made of filter mud of sugar refinery as medicament
Body takes full advantage of the abundant organic fertilizer raw material resource in Guangxi, reduces the use of invalid carrier in conventional particles agent, is conducive to
Reduce cost environments；
3. product adds poly-aspartic-acid as compound fertilizer carrier synergist, the utilization of pesticide and fertilizer is effectively increased
Rate promotes the absorption of Plant To Nutrient element；
4. first by active ingredient make microcapsules again with biological organic fertilizer hybrid process patent medicine fertilizer, to ensure active ingredient
Stability and lasting period in the soil.
5. this product effectively ensures the scientific and reasonable release of pesticide, fertilizer using current newest slow release method, extend production
The lasting period of product, it is ensured that desinsection, fertilising double effects；
6. this product pharmacodynamic stability is strong, in sugarcane production entire season, only twice with fertilising, the pest and disease damage of sugarcane can
Control, and Sugarcane growth is good, and the later stage is not in de- fertile phenomenon, ensure that sugarcane robust growth, while reducing labour
Power reduces cost of labor.
7. the medicine fertilizer of the present invention, it is reasonable that nutriment provides, and N, P, K nutrients ratio are balanced, can meet the nutrition need of sugarcane
It asks, for opposite conventional composite fertilizer, can also make sugarcane production-increasing 10% after the medicine fertilizer dosage for reducing 10%, improve fertilizer
Utilization rate has saved economic cost.
Description of the drawings
Fig. 1 is the structural schematic diagram of the present invention, and wherein inner layer material is microcapsules A and biological organic fertilizer, packing material are mixed
Conjunction obtains；Membrane material is the package membrane material that ethyl cellulose and lignin are mixed to get；Outer layer is that material is microcapsules B, life
Organic fertilizer, packing material are mixed to get.
Specific implementation mode
With reference to embodiments pest and disease damage new drug fertilizer and its preparation side are prevented with a kind of clothianidin-containing of the attached drawing description present invention
Method, these descriptions are not to be further limited to the content of present invention.
Embodiment 1：
The preparation of organic fertilizer：5 parts of composite fermentation microbial inoculum is added after 70 parts of filter mud of sugar refinery carry out fermentation maturities, then with urea
16 parts, 8 parts of monoammonium phosphate, 15 parts of potassium chloride, modified 12 parts of poly-aspartic-acid resin, 4 parts of composite functional bacterial agent be mixed to prepare
Biological organic fertilizer.
It is prepared by microcapsules A:15 parts of poly butylene succinate solution are put into reaction kettle, it is mixed that 10 parts of emulsifiers are added
It closes, 1.5 part of 0.06% clothianidin solution is added in reaction kettle, 30min is stirred at 45 DEG C of temperature rotating speed 800r/min, stirs
It mixes and utricule is allowed fully to adsorb drug, it is 10 to adjust pH, under conditions of temperature is 45 DEG C, shearing dispersion reaction 75 minutes, encystation
Afterwards, through being separated by solid-liquid separation, drying, clothianidin microcapsules A is made；
It is prepared by microcapsules B:12 parts of chitosans and 13 parts of sodium carboxymethylcellulose mixed solutions are added in reaction kettle, are added
Enter 1.8 part of 0.06% clothianidin, 1.5 parts of herbicides, 15min is stirred under 1000r/min speed, adjusts pH to 10, stirring
Clothianidin and herbicide mixing microcapsule B is made through being separated by solid-liquid separation, drying in 12min；
Material mixes:12 parts of microcapsules A, 70 parts of biological organic fertilizers, 20 parts of packing materials are mixed to get mixture A, it will
13 parts of microcapsules B, 70 parts of biological organic fertilizers, 20 parts of packing materials are mixed to get mixture B；
It is prepared by medicine fertilizer:Granulated Cores are made by granulating disc in mixture A, in 13 parts of second of Granulated Cores surface spraying
The mixed liquor of base cellulose and lignin, again by wrapping up in comminutor, addition mixture B, 11 parts of binders are wrapped core
It wraps up in granulation and particle medicinal fertilizer is made.
Embodiment 2：
The preparation of organic fertilizer：6 parts of composite fermentation microbial inoculum is added after 60 parts of filter mud of sugar refinery carry out fermentation maturities, then with urea
15 parts, 5 parts of monoammonium phosphate, 18 parts of potassium chloride, modified 14 parts of poly-aspartic-acid resin, 2 parts of composite functional bacterial agent be mixed to prepare
Biological organic fertilizer.
It is prepared by microcapsules A:11 parts of polycaprolactone acid solutions are put into reaction kettle, 13 parts of emulsifier mixing are added, by 1 part
0.06% clothianidin solution is added in reaction kettle, and 20min is stirred at 55 DEG C of temperature rotating speed 650r/min, and stirring allows utricule to fill
Divide absorption drug, it is 8 to adjust pH, under conditions of temperature is 40 DEG C, dispersion reaction 50 minutes is sheared, after encystation, through solid-liquid point
From, it is dry, clothianidin microcapsules A is made；
It is prepared by microcapsules B:13 parts of chitosans and 11 parts of sodium carboxymethylcellulose mixed solutions are added in reaction kettle, are added
Enter 1.5 part of 0.06% clothianidin, 1 part of herbicide, 20min stirred under 800r/min speed, adjust pH to 8, stirs 13min,
Through being separated by solid-liquid separation, drying, clothianidin and herbicide mixing microcapsule B is made；
Material mixes:15 parts of microcapsules A, 60 parts of biological organic fertilizers, 35 parts of packing materials are mixed to get mixture A, it will
B60 parts of biological organic fertilizers of 15 parts of microcapsules, 35 parts of packing materials are mixed to get mixture B；
It is prepared by medicine fertilizer:Granulated Cores are made by granulating disc in mixture A, in 15 parts of second of Granulated Cores surface spraying
The mixed liquor of base cellulose and lignin, again by wrapping up in comminutor, addition mixture B, 10 parts of binders are wrapped core
It wraps up in granulation and particle medicinal fertilizer is made.
Embodiment 3：
The preparation of organic fertilizer：8 parts of composite fermentation microbial inoculum is added after 63 parts of filter mud of sugar refinery carry out fermentation maturities, then with urea
18 parts, 10 parts of monoammonium phosphate, 23 parts of potassium chloride, modified 13 parts of poly-aspartic-acid resin, 3 parts of composite functional bacterial agent be mixed to prepare
Biological organic fertilizer.
It is prepared by microcapsules A:10 parts of poly butylene succinate solution are put into reaction kettle, it is mixed that 12 parts of emulsifiers are added
It closes, 1.2 part of 0.06% clothianidin solution is added in reaction kettle, 25min is stirred at 40 DEG C of temperature rotating speed 600r/min, stirs
It mixes and utricule is allowed fully to adsorb drug, it is 9 to adjust pH, under conditions of temperature is 60 DEG C, shearing dispersion reaction 65 minutes, encystation
Afterwards, through being separated by solid-liquid separation, drying, clothianidin microcapsules A is made；
It is prepared by microcapsules B:10 parts of chitosans and 12 parts of sodium carboxymethylcellulose mixed solutions are added in reaction kettle, are added
Enter 2 part of 0.06% clothianidin, 3 parts of herbicides, 10min is stirred under 850r/min speed, adjust pH to 8, stirs 11min, warp
It is separated by solid-liquid separation, is dry, clothianidin and herbicide mixing microcapsule B is made；
Material mixes:10 parts of microcapsules A, 62 parts of biological organic fertilizers, 25 parts of packing materials are mixed to get mixture A, it will
10 parts of microcapsules B, 62 parts of biological organic fertilizers, 25 parts of packing materials are mixed to get mixture B；
It is prepared by medicine fertilizer:Granulated Cores are made by granulating disc in mixture A, in 10 parts of second of Granulated Cores surface spraying
The mixed liquor of base cellulose and lignin, again by wrapping up in comminutor, addition mixture B, 13 parts of binders are wrapped core
It wraps up in granulation and particle medicinal fertilizer is made.
Embodiment 4：
The preparation of organic fertilizer：7 parts of composite fermentation microbial inoculum is added after 65 parts of filter mud of sugar refinery carry out fermentation maturities, then with urea
30 parts, 12 parts of monoammonium phosphate, 25 parts of potassium chloride, modified 10 parts of poly-aspartic-acid resin, 4 parts of composite functional bacterial agent be mixed to prepare
Biological organic fertilizer.
It is prepared by microcapsules A:12 parts of poly butylene succinates and polycaprolactone acid mixed solution are put into reaction kettle, are added
Enter 15 parts of emulsifier mixing, 1.8 part of 0.06% clothianidin solution is added in reaction kettle, in 50 DEG C of temperature rotating speed 700r/min
Lower stirring 23min, stirring allow utricule fully to adsorb drug, and it is 8 to adjust pH, and under conditions of temperature is 50 DEG C, shearing dispersion is anti-
It answers 80 minutes, after encystation, through being separated by solid-liquid separation, drying, 0.06% clothianidin microcapsules A is made；
It is prepared by microcapsules B:15 parts of chitosans and 10 parts of sodium carboxymethylcellulose mixed solutions are added in reaction kettle, are added
Enter 1 part of 0.06% clothianidin, 1.2 herbicide of part, 12min stirred under 950r/min speed, adjust pH to 9, stirs 15min,
Through being separated by solid-liquid separation, drying, clothianidin and herbicide mixing microcapsule B is made；
Material mixes:13 parts of microcapsules A, 65 parts of biological organic fertilizers, 28 parts of packing materials are mixed to get mixture A, it will
13 parts of microcapsules B, 65 parts of biological organic fertilizers, 28 parts of packing materials are mixed to get mixture B；
It is prepared by medicine fertilizer:Granulated Cores are made by granulating disc in mixture A, in 12 parts of second of Granulated Cores surface spraying
The mixed liquor of base cellulose and lignin, again by wrapping up in comminutor, addition mixture B, 15 parts of binders are wrapped core
It wraps up in granulation and particle medicinal fertilizer is made.
Embodiment 5：
The preparation of organic fertilizer：6 parts of composite fermentation microbial inoculum is added after 68 parts of filter mud of sugar refinery carry out fermentation maturities, then with urea
17 parts, 5 parts of monoammonium phosphate, 20 parts of potassium chloride, modified 15 parts of poly-aspartic-acid resin, 4 parts of composite functional bacterial agent be mixed to prepare
Biological organic fertilizer.
It is prepared by microcapsules A:14 parts of polycaprolactone acid solutions are put into reaction kettle, 11 parts of emulsifier mixing are added, by 2 parts
0.06% clothianidin solution is added in reaction kettle, and 28min is stirred at 60 DEG C of temperature rotating speed 750r/min, and stirring allows utricule to fill
Divide absorption drug, it is 9 to adjust pH, under conditions of temperature is 55 DEG C, dispersion reaction 60 minutes is sheared, after encystation, through solid-liquid point
From, it is dry, clothianidin microcapsules A is made；
It is prepared by microcapsules B:14 parts of chitosans and 15 parts of sodium carboxymethylcellulose mixed solutions are added in reaction kettle, are added
Enter 1.2 part of 0.06% clothianidin, 1.8 herbicide of part, 18min is stirred under 900r/min speed, adjusts pH to 10, stirring
Clothianidin and herbicide mixing microcapsule B is made through being separated by solid-liquid separation, drying in 10min；
Material mixes:14 parts of microcapsules A, 68 parts of biological organic fertilizers, 30 parts of packing materials are mixed to get mixture A, it will
14 parts of microcapsules B, 68 parts of biological organic fertilizers, 30 parts of packing materials are mixed to get mixture B；
It is prepared by medicine fertilizer:Granulated Cores are made by granulating disc in mixture A, in 13 parts of second of Granulated Cores surface spraying
The mixed liquor of base cellulose and lignin, again by wrapping up in comminutor, addition mixture B, 14 parts of binders are wrapped core
It wraps up in granulation and particle medicinal fertilizer is made.
The medicine fertilizer and commercially available Common compound fertilizer being prepared by embodiment compare, the sugarcane field in Nanning area
It is tested, medicine fertilizer particle is applied before sugarcane is sowed, investigating pest and disease damage during the growth of sugarcane, a situation arises and in sugarcane
Yield is measured when harvest, test result is as shown in the table：
1 sugarcane prevention and control of plant diseases, pest control effect table of table
2 sugarcane mature condition table of table
The above embodiment of the present invention scheme is only the description of the invention and cannot limit the present invention, is pointed out in claim
The range of product form ingredient of the present invention, component ratio, preparation method parameter, and above-mentioned explanation does not point out ginseng of the present invention
Therefore several ranges any change within the meaning and scope equivalent to the claims of the present invention, is all considered to be
It is included within the scope of the claims.
The present invention is by multidigit fertilizer processing staff's long-term work experience accumulation, and by creative work is created
Go out, medicine fertilizer of the invention can effectively prevent the generation of sugarcane production period pest and disease damage, additionally it is possible to provide each breeding to sugarcane
Point, promote absorption and utilization of the sugarcane to various nutriments, relatively for conventional composite fertilizer, medicine fertilizer of the invention is being reduced
In the case of 10% dosage, moreover it is possible to make 10% or more sugarcane production-increasing, improve utilization rate of fertilizer, medicine fertilizer of the invention is entire in sugarcane
The season of growth need to only use pesticide-fertilizer product twice, can control the pest of entire season sugarcane, be not in the sugarcane production later stage
De- fertilizer phenomenon.
Claims (4)
1. a kind of organic fertilizer, characterized in that the organic fertilizer constituent and its quality parts ratio are：Filter mud of sugar refinery 60~70
Part, 15~30 parts of urea, 5~12 parts of monoammonium phosphate, 15~25 parts of potassium chloride, modified 10~15 parts of poly-aspartic-acid resin,
5~8 parts of composite fermentation microbial inoculum, 2~4 parts of composite functional bacterial agent.
2. organic fertilizer according to claim 1, characterized in that the modification poly-aspartic-acid resin is poly- lucid asparagus
Propylhomoserin resin chelates calcium, magnesium, sulphur, boron, manganese, zinc, molybdenum element.
3. organic fertilizer according to claim 1, characterized in that the composite zymocyte is saccharomycete, lichens gemma bar
The mixing of bacterium, bacillus subtilis, Thermophilic Bacteria, bacillus pumilus；The composite functional bacterial agent be phosphate solubilizing bacteria, potassium solubilizing bacteria,
The mixing of nitrogen-fixing bacteria.
4. a kind of preparation method of organic fertilizer, characterized in that the preparation method of the organic fertilizer is by composite fermentation microbial inoculum 5~8
Part be added after 60~70 parts of filter mud of sugar refinery carries out fermentation maturities, then with 15~30 parts of urea, 5~12 parts of monoammonium phosphate, potassium chloride
15~25 parts, modified 10~15 parts of poly-aspartic-acid resin, 2~4 parts of composite functional bacterial agent be mixed to prepare biological organic fertilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810710548.3A CN108794175A (en) | 2017-09-27 | 2017-09-27 | A kind of organic fertilizer and preparation method thereof |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810710548.3A CN108794175A (en) | 2017-09-27 | 2017-09-27 | A kind of organic fertilizer and preparation method thereof |
| CN201710890803.2A CN107500915B (en) | 2017-09-27 | 2017-09-27 | A kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and preparation method thereof |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710890803.2A Division CN107500915B (en) | 2017-09-27 | 2017-09-27 | A kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108794175A true CN108794175A (en) | 2018-11-13 |
Family
ID=60699295
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710890803.2A Active CN107500915B (en) | 2017-09-27 | 2017-09-27 | A kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and preparation method thereof |
| CN201810710548.3A Withdrawn CN108794175A (en) | 2017-09-27 | 2017-09-27 | A kind of organic fertilizer and preparation method thereof |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710890803.2A Active CN107500915B (en) | 2017-09-27 | 2017-09-27 | A kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN107500915B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109553478A (en) * | 2018-12-29 | 2019-04-02 | 云南云之叶生物科技有限公司 | A kind of biological organic fertilizer and preparation method thereof using the rape stalk exploitation dedicated biological and ecological methods to prevent plant disease, pests, and erosion function of rape |
| CN113508738A (en) * | 2021-05-31 | 2021-10-19 | 潍坊郭牌农业科技有限公司 | Nutrient soil for small potted watermelons and preparation method of nutrient soil |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111484129A (en) * | 2019-01-25 | 2020-08-04 | 宝山钢铁股份有限公司 | Sulfur autotrophic denitrification filler, preparation method and application thereof |
| CN111763125A (en) * | 2020-06-02 | 2020-10-13 | 广西金裕隆农药化工有限公司 | Rice slow-release pesticide fertilizer containing tetrachlorantraniliprole and mefenacet and preparation method thereof |
| CN112624871A (en) * | 2021-01-07 | 2021-04-09 | 中诚国联（河南）生物科技有限公司 | High-tower pesticide-fertilizer containing clothianidin and chlorfenapyr and preparation method thereof |
| CN112573964A (en) * | 2021-01-08 | 2021-03-30 | 中诚国联（河南）生物科技有限公司 | High-tower pesticide-fertilizer containing clothianidin and cyfluthrin and preparation method thereof |
| CN115197025A (en) * | 2022-08-01 | 2022-10-18 | 赤天化科技集团有限公司 | Preparation method and application of insecticide-fertilizer granules containing clothianidin and imidacloprid |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
| CN103159558A (en) * | 2013-04-17 | 2013-06-19 | 广西新方向化学工业有限公司 | Novel long-lasting special fertilizer for sugarcane and preparation method thereof |
| CN103804092A (en) * | 2014-02-24 | 2014-05-21 | 华强化工集团股份有限公司 | Special fertilizer for sugarcane and preparation method of fertilizer |
| CN104230529A (en) * | 2014-08-22 | 2014-12-24 | 合肥四方磷复肥有限责任公司 | Special higher-utilization-ratio environment-friendly coated fertilizer for blueberries and preparation method thereof |
| CN104557269A (en) * | 2014-12-18 | 2015-04-29 | 广西大学 | Sugarcane efficient fertilizer and preparation method thereof |
| WO2016183511A1 (en) * | 2015-05-13 | 2016-11-17 | Mcknight Gary David | Non-aqueous organo liquid delivery systems containing dispersed poly (organic acids) that improve availability of macro & micro-nutrients to plants |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875257B (en) * | 2012-10-23 | 2014-11-05 | 广西田园生化股份有限公司 | Chemical fertilizer granula for preventing sugarcane moth borer |
| CN103449921B (en) * | 2013-08-31 | 2015-06-10 | 红河蔗保科技有限责任公司 | Formula and production method for disease-preventing and insect-killing pesticide-fertilizer for sugarcane |
| CN103641657A (en) * | 2013-11-06 | 2014-03-19 | 马鞍山科邦生态肥有限公司 | A fertilizer used for killing pests and weeding and a preparation method thereof |
| CN203582757U (en) * | 2013-12-03 | 2014-05-07 | 河北国东化工科技有限公司 | Pesticide fertilizer |
| CN105777406A (en) * | 2016-05-25 | 2016-07-20 | 广西金穗农药有限公司 | Pesticide and fertilizer mixture containing clothianidin |
| CN106719631A (en) * | 2016-11-30 | 2017-05-31 | 重庆市江津区森德家庭农场 | A kind of support type long-acting solid weeding and pest-killing agent and preparation method thereof of seedling growth |
-
2017
- 2017-09-27 CN CN201710890803.2A patent/CN107500915B/en active Active
- 2017-09-27 CN CN201810710548.3A patent/CN108794175A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
| CN103159558A (en) * | 2013-04-17 | 2013-06-19 | 广西新方向化学工业有限公司 | Novel long-lasting special fertilizer for sugarcane and preparation method thereof |
| CN103804092A (en) * | 2014-02-24 | 2014-05-21 | 华强化工集团股份有限公司 | Special fertilizer for sugarcane and preparation method of fertilizer |
| CN104230529A (en) * | 2014-08-22 | 2014-12-24 | 合肥四方磷复肥有限责任公司 | Special higher-utilization-ratio environment-friendly coated fertilizer for blueberries and preparation method thereof |
| CN104557269A (en) * | 2014-12-18 | 2015-04-29 | 广西大学 | Sugarcane efficient fertilizer and preparation method thereof |
| WO2016183511A1 (en) * | 2015-05-13 | 2016-11-17 | Mcknight Gary David | Non-aqueous organo liquid delivery systems containing dispersed poly (organic acids) that improve availability of macro & micro-nutrients to plants |
Non-Patent Citations (1)
| Title |
|---|
| 张宝文: "《新阶段中国农业科技发展战略研究》", 30 April 2004, 中国农业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109553478A (en) * | 2018-12-29 | 2019-04-02 | 云南云之叶生物科技有限公司 | A kind of biological organic fertilizer and preparation method thereof using the rape stalk exploitation dedicated biological and ecological methods to prevent plant disease, pests, and erosion function of rape |
| CN113508738A (en) * | 2021-05-31 | 2021-10-19 | 潍坊郭牌农业科技有限公司 | Nutrient soil for small potted watermelons and preparation method of nutrient soil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107500915A (en) | 2017-12-22 |
| CN107500915B (en) | 2018-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107500915B (en) | A kind of clothianidin-containing prevention pest and disease damage new drug fertilizer and preparation method thereof | |
| CN102344309B (en) | Throwing applying agent and preparation method thereof | |
| CN101709016B (en) | Sugarcane insecticide fertilizer and production method thereof | |
| CN105777329B (en) | A kind of solid union biology controls water conservation moisturizing fertilizer and the preparation method and application thereof | |
| CN106220391A (en) | Paddy rice-dedicated fertilizer | |
| CN103073355B (en) | Pyrazosulfuron-mefenacet-containing weeding and insecticidal fertilizer and producing method thereof | |
| CN101647384A (en) | Horticultural long-acting and slow-release straw nutritional soil as well as preparation method and using method of nutritional soil substrate | |
| CN110452056A (en) | A kind of coated release-controlled Synergistic type herbicide fertilizer granules of multilayer and its preparation and method of administration | |
| CN107628898A (en) | One kind is containing Diacloden preventing and treating pest and disease damage new drug fertilizer and preparation method thereof | |
| CN101473843B (en) | Composite type corn seed coating agent | |
| CN104163726A (en) | Pesticide fertilizer slow-release preparation, and preparation method and application method thereof | |
| AU2018101439A4 (en) | Special film-coated controlled release pesticide for peanut and preparation process thereof | |
| CN104193540A (en) | Pesticidal disease protecting and nutrient pesticide fertilizer and application thereof, and pesticidal disease protecting and nutrient pesticide fertilizer slow release formulation and application thereof | |
| CN104522045A (en) | Pesticide composition, sustained-release pesticidal fertilizer, and preparation methods thereof | |
| CN106857653A (en) | Soluble granule and its application process for preventing and treating root disease | |
| CN104151088A (en) | Pesticide fertilizer slow release preparation, as well as preparation method and application method thereof | |
| CN105367199A (en) | Production process and use method of green fertilizer with effects of insect disinfestation, sterilization and rooting promoting | |
| CN102134174A (en) | Organic insecticide envelope pesticide fertilizer and manufacturing technique | |
| CN104446703B (en) | Organic matter composite granulated fertilizer | |
| CN107382496A (en) | A kind of artificial soil for strengthening crop anti-adversity and the method for strengthening crop anti-adversity | |
| CN110357734A (en) | A kind of Nano fertilizer and preparation method thereof of dedicated prevention and treatment sugarcane insect pest | |
| CN105541506A (en) | Paddy-field pesticide-fertilizer sustained release granules and preparing method and application method thereof | |
| CN1910978A (en) | Plant source, Wet-keeping dressing agent contg. pesticide and fertilizer | |
| CN102584476A (en) | Complex liquid coated medical fertilizer for organically preventing and curing root diseases and manufacture process thereof | |
| CN101326918A (en) | Water-soluble granular formulation containing Imidacloprid, and preparation and use thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181113 |
|
| WW01 | Invention patent application withdrawn after publication |