CN108794070B - Energy material and preparation method and application, energy ceramic tile and preparation method - Google Patents
Energy material and preparation method and application, energy ceramic tile and preparation method Download PDFInfo
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- CN108794070B CN108794070B CN201810660026.7A CN201810660026A CN108794070B CN 108794070 B CN108794070 B CN 108794070B CN 201810660026 A CN201810660026 A CN 201810660026A CN 108794070 B CN108794070 B CN 108794070B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The present invention provides a kind of energy material and preparation method and application, energy ceramic tile and preparation method, are related to field of material technology, energy material provided by the invention, including potassium albite in powder, kaolin, grey feldspar powder, porcelain sand, functional powders and optional auxiliary agent.Effective health-care effect can be played, so that the function of sub-health state is avoided, thus with health role to human body so that energy material provided by the invention has on the basis of environment friendly and pollution-free by the coordinated between each specific components and proportion.The preparation method of above-mentioned energy material provided by the invention, easy to operate, the energy material being prepared can effectively generate health-care effect.The present invention also provides a kind of energy ceramic tile, which includes energy material provided by the invention.Have the function of permanently generating health-care effect, while having both the environmentally friendly effects such as absorption peculiar smell removal formaldehyde.
Description
Technical field
The present invention relates to field of material technology, more particularly, to a kind of energy material and preparation method and application, energy porcelain
Brick and preparation method.
Background technique
With social city, technicalization, hommization development, people increasingly pay attention to quality of life, household are built
The making material of material etc. requires also opposite improve, it is desirable to which it can health-care effect with higher.Currently, house, office
The decorations of ceramic tile are also limited to raw material and are mostly mixed by clay, quartz sand etc., due in above-mentioned ornament materials not
It is evitable containing substances such as benzene, formaldehyde, particulate pollutant, biological pollutant, household chemical product, radon and its daughters, then plus
Upper indoor ventilation function is poor, generates a large amount of interior decoration pollution syndrome therefrom.
Therefore, it develops a kind of on the basis of will not bring the environmental protection of indoor pollution, additionally it is possible to have both the production of health-care effect
Product are particularly important.
In view of this, the present invention is specifically proposed.
Summary of the invention
The first purpose of this invention is to provide a kind of energy material, which has and can generate negative oxygen ion
Effective health-care effect can be played on the basis of environment friendly and pollution-free with the function of far infrared.
Second object of the present invention is to provide the preparation method of above-mentioned energy material, this method simple process, operation
It is convenient, a large amount of man power and material can be saved, production efficiency is effectively improved, and the energy material being prepared can be effectively
Generate health-care effect.
Third object of the present invention is to provide the application of above-mentioned energy material.
Fourth object of the present invention is to provide a kind of energy ceramic tile, which has and can generate negative oxygen ion
Effective health-care effect can be played on the basis of environment friendly and pollution-free with the function of far infrared, to avoid inferior health shape
State.
Of the invention the 5th is designed to provide the preparation method of above-mentioned energy ceramic tile, this method simple process, operation
It is convenient, a large amount of man power and material can be saved, production efficiency is effectively improved, and the energy ceramic tile being prepared can be effectively
Generate health-care effect.
The present invention provides a kind of energy material, the energy material is mainly made of the raw material of following parts by weight:
40-80 parts of potassium albite in powder, 5-20 parts of kaolin, grey 0.5-5 parts of feldspar powder, 1-10 parts of porcelain sand, functional powders 5-
15 parts and optional auxiliary agent；
The functional powders include negative ion powder, one of the dilute powder of graphite or magnet powder or a variety of.
Further, the energy material is mainly made of the raw material of following parts by weight:
50-70 parts of potassium albite in powder, 8-18 parts of kaolin, grey 1-4 parts of feldspar, 2-8 parts of porcelain sand, 6-14 parts of functional powders and
Optional auxiliary agent；
Preferably, the energy material is mainly made of the raw material of following parts by weight:
55-65 parts of potassium albite in powder, 10-15 parts of kaolin, grey 2-4 parts of feldspar, 3-7 parts of porcelain sand, 8-12 parts of functional powders
With optional auxiliary agent.
Further, the energy material further includes 0.1-2 parts of auxiliary agent, preferably 0.2-1.8 parts, more preferably 0.5-
1.2 part；
Preferably, the auxiliary agent includes diluent and/or binder；
Preferably, the auxiliary agent includes diluent and binder；
Preferably, the weight ratio of the diluent and binder is 1-10:1-5, preferably 2-8:1-4, more preferably 3-
7:1-3；
Preferably, the diluent is selected from hydroxy-ethyl acrylate, hydroxy propyl methacrylate, isobornyl acrylate or season
One of penta tetrol triacrylate is a variety of；
Preferably, the binder includes waterglass.
Further, it is preferable to ground, the functional powders include negative ion powder, the dilute powder of graphite and magnet powder；
Preferably, the mass ratio of the negative ion powder, the dilute powder of graphite and magnet powder is 0.1-2:0.1-2:0.1-2, preferably
For 0.5:1.5-0.5:1.5-0.5:1.5, more preferably 0.8:1.2-0.8:1.2-0.8:1.2.
Further, the partial size of the raw material is 0.5-1.5 μm, preferably 0.6-0.2 μm, more preferably 0.8-1.0 μm.
The present invention also provides the preparation method of above-mentioned energy material, the preparation method includes:
It takes each raw material of formulation weight part to be uniformly mixed, obtains the energy material；
Preferably, each raw material for taking formulation weight part after mixing, auxiliary agent is added into mixed-powder and mixes, obtains
The energy material；
Preferably, the water content of the energy material is 30%-40%, preferably 30%-35%；
Preferably, the slurry viscosity of the energy material is 25-55 ', preferably 30-50 '.
Exist the present invention also provides above-mentioned energy material or using the energy material that above-mentioned preparation method is prepared
Prepare the application in health product；
Preferably, the health product includes health care building materials or health textile；
Preferably, the health care building materials are selected from health tile, health care floor, health care wallpaper or health paint；
Preferably, the health textile is selected from health care curtain, health towel or health care underwear.
The present invention also provides a kind of energy ceramic tile, the energy ceramic tile includes ceramic body and glaze layer；
The glaze layer includes the energy material that above-mentioned energy material or the above-mentioned preparation method of use are prepared.
In addition, the present invention also provides the preparation method of above-mentioned energy ceramic tile, the preparation method includes:
Glaze is sprayed to one side surface of ceramic body, the first glaze layer is obtained after dry, sprays and be mixed in the first glaze layer
The glaze of above-mentioned energy material or the energy material being prepared using above-mentioned preparation method, obtains energy layer after dry,
It sprays glaze again in energy layer, obtains the second glaze layer after dry, the second glaze layer is processed by shot blasting, the energy porcelain is obtained
Brick.
Further, the mass ratio of the energy material and glaze be 5-20:100, preferably 10-20:100, more preferably
For 10-15:100.
Energy material provided by the invention, including potassium albite in powder, kaolin, grey feldspar powder, porcelain sand, functional powders and appoint
The auxiliary agent of choosing.Wherein, potassium albite can make energy material become soft, reduce melting temperature when preparation, save the cost；It is high
Ridge soil has plasticity, and wet soil can be moulded into various shape and will not be crushed, and can remain unchanged for a long time, makes energy material convenient for storage
It deposits, is unlikely to deteriorate；Grey feldspar has higher compression strength and stronger chemical stability, can not only make energy material have compared with
Strong compression strength equally also ensures the stability of energy material, easily stores；Porcelain sand good toughness, non-breakable, service life
It is long, energy consumption can be reduced, reduces cost, in functional powders, graphene can release the far infrared beneficial to human body, and promote
Negative ion powder in raw material discharges negative oxygen ion largely beneficial to human body, and magnetite can generate magnetic field, and magnetic field is adjustable
Vivo biodistribution magnetic field generates induction micro-current.Above-mentioned each component compatibility is good, passes through the association between each specific components and proportion
With cooperation, so that energy material provided by the invention has on the basis of environment friendly and pollution-free, effective health care can be played and made
With to avoid the function of sub-health state.
The preparation method of above-mentioned energy material provided by the invention, this method simple process is easy to operate, can save big
The energy material that the man power and material of amount effectively improves production efficiency, and is prepared can play effective health-care effect.
The present invention also provides a kind of energy ceramic tile, which includes energy material provided by the invention.The energy
Ceramic tile has on the basis of environment friendly and pollution-free, effective health-care effect can be played, to avoid the function of sub-health state.
In addition, also having both the advantages of improving air quality.
The present invention also provides the preparation methods of above-mentioned energy ceramic tile, and this method simple process is easy to operate, can save
A large amount of man power and material effectively improves production efficiency, and the energy ceramic tile being prepared is with health role to human body, also simultaneous
Tool improves the advantages of air quality.
Detailed description of the invention
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art
Embodiment or attached drawing needed to be used in the description of the prior art be briefly described, it should be apparent that, it is described below
Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor
It puts, is also possible to obtain other drawings based on these drawings.
Fig. 1 is the structural schematic diagram of energy ceramic tile provided by the invention.
Icon: 1- ceramic body；The first glaze layer of 2-；3- energy layer；The second glaze layer of 4-.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
Applying example is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention provides a kind of energy materials, are mainly made of the raw material of following parts by weight:
40-80 parts of potassium albite in powder, 5-20 parts of kaolin, grey 0.5-5 parts of feldspar powder, 1-10 parts of porcelain sand, functional powders 5-
15 parts and optional auxiliary agent；
Functional powders include negative ion powder, one of the dilute powder of graphite or magnet powder or a variety of.
Wherein, potassium albite is the aluminium silicate mineral of the alkali or alkaline earth metals such as potassium, sodium, is a kind of common feldspar
Mineral are also feldspar race mineral.In the present invention, energy material can be made to become soft using potassium albite in powder, reduces preparation
When melting temperature, reduce the dry of material and shrink and deformation, save the cost.Its content for example can be, but be not limited to 40 parts,
45 parts, 50 parts, 55 parts, 60 parts, 65 parts, 70 parts, 75 parts or 80 parts.
Kaolin is a kind of nonmetallic minerals, is a kind of clay and clay rock based on kaolinite race clay mineral.It is high
The crystal-chemical formula of ridge stone is 2SiO2·Al2O3·2H2O, theoretical chemistry group become 46.54% SiO2, 39.5%
Al2O3, 13.96% H2O., with plasticity, wet soil can be moulded into various shape and will not be crushed, and can remain unchanged for a long time for it.
In the present invention, energy material can be made convenient for storage using kaolin, be unlikely to deteriorate.Its content for example can be, but unlimited
In 5 parts, 10 parts, 15 parts or 20 parts.
Grey feldspar is the aluminium silicate mineral of the alkali or alkaline earth metals such as potassium, sodium, calcium, barium, main component SiO2、
Al2O3、K2O、Na2O, CaO etc., crystal structure category rack-like structure, has higher compression strength and stronger chemical stability, is
One of important rock-forming mineral.In the present invention, it can not only make energy material that there is stronger compression strength using grey feldspar,
It equally also ensures the stability of energy material, easily stores.Its content for example can be, but be not limited to 0.5 part, 1 part, 2 parts, 3
Part, 4 parts or 5 parts.
Porcelain sand is that have corrosion-resistant, oxidation resistant characteristic, stable chemical performance, tool made of porous ceramics raw material
There are certain filtration, effect good, and good toughness, non-breakable, service life is longer.In the present invention, using porcelain sand energy
Energy consumption is enough reduced, reduces cost, and energy material provided by the invention can be made to have both purification air by its filtration
Function.Its content for example can be, but be not limited to 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts.
Functional powders include negative ion powder, one of the dilute powder of graphite or magnet powder or a variety of, and content for example can be,
But it is not limited to 5 parts, 8 parts, 10 parts, 12 parts or 15 parts.
Negative ion powder is the principle that human use's nature generates anion, a kind of artificial synthesized or proportion grandidierite
Object has the function of generation negative oxygen ion, and negative oxygen ion also has other other effects, as removed the nocuousness in dissociated air
Other and peculiar smell, antibacterial bacteriostatic etc..If negative ion powder is added in the feed, energy material release can be made largely to have to human body
The negative oxygen ion of benefit, health care human body while, purify air.Negative ion powder includes tourmaline powder, Mt. Mountain medical stone powder, Guiyang stone
Powder, volcanic rock powder, Strange ice stone powder, six ring mountain flours, salt mountain flour, radium mountain flour, stone needle powder, sea-gull mountain flour, albumen mountain flour, hornblend
One of powder, microcline powder or water-soluble negative ion powder are a variety of.
Graphene is a kind of Two-dimensional Carbon nanometer material for forming hexangle type in honeycomb lattice with sp2 hybridized orbit by carbon atom
Material.Its far infrared that can generate 70% or so carrys out radiations heat energy, and infra red radiation band is 5-15 μm of optimum human body
Life light wave, the light of this section of wavelength is close with the wavelength of far infrared that human-body emitting comes out, can be with organism inner cell
Hydrone generate most effective " resonance ".If graphene is added in the feed can effectively activate soma nucleic acid protein etc.
Biomolecule, improves blood circulation, and enhancing metabolism has the health physical therapies effects such as good anti-inflammatory, analgesia.
Magnetite can generate magnetic field, and the adjustable vivo biodistribution magnetic field in magnetic field generates induction micro-current.If adding in the feed
Enter magnet powder, the induction micro-current that can be generated by it changes permeability of cell membrane, the activity for changing certain enzymes and expansion blood
Pipe accelerates blood flow, to reach health-care effect.
Energy material provided by the invention, feed components compatibility is good, by between each specific components and proportion
Coordinated so that energy material provided by the invention have on the basis of environment friendly and pollution-free, can generate negative oxygen ion and
Far infrared effectively increases microcirculation in human body, plays a role in health care, to avoid sub-health state.
In one preferred embodiment, energy material is mainly made of the raw material of following parts by weight:
50-70 parts of potassium albite in powder, 8-18 parts of kaolin, grey 1-4 parts of feldspar, 2-8 parts of porcelain sand, 6-14 parts of functional powders and
Optional auxiliary agent.
Preferably, energy material is mainly made of the raw material of following parts by weight:
55-65 parts of potassium albite in powder, 10-15 parts of kaolin, grey 2-4 parts of feldspar, 3-7 parts of porcelain sand, 8-12 parts of functional powders
With optional auxiliary agent.
It is further adjusted and is optimized by the proportion to each component, so that energy material provided by the invention has
Preferably generate the function of health care.
In one preferred embodiment, energy material further includes 0.1-2 parts of auxiliary agent, such as can be, but be not limited to
0.1 part, 0.2 part, 0.5 part, 0.8 part, 1 part, 1.2 parts, 1.5 parts, 1.8 parts or 2 parts.Preferably 0.2-1.8 parts, more preferably
0.5-1.2 parts.
In the industrial production, to improve production process, improving product quality and yield, or certain is peculiar for imparting product
Application performance added by auxiliaryization, auxiliary agent can be added.But as the important component of product matrix, auxiliary agent to product form,
Properity will not generate significant impact again.In one preferred embodiment of the invention, auxiliary agent include diluent and/or
Binder.
Diluent be Raw material processing at pulvis when, or in order to make it easy to spray the inert material being diluted being added
Matter.In the present invention, if diluent is added as auxiliary agent, energy material can be made to be more convenient for subsequent processing.Of the invention
In one embodiment, diluent is selected from hydroxy-ethyl acrylate, hydroxy propyl methacrylate, isobornyl acrylate or Ji Wusi
One of alcohol triacrylate is a variety of.
Binder be intensity in order to improve material or prevent powder segregation and be added in powder can be in following process
The substance removed in preceding or process.In the present invention, if diluent is added as auxiliary agent, can guarantee material and matrix it
Between adhesion strength.In an embodiment of the invention, binder includes waterglass (Na2O·SiO2)。
Preferably, auxiliary agent includes diluent and binder.
Preferably, the weight ratio of diluent and binder is 1-10:1-5, such as can be, but be not limited to 1:1,1:3,1:
5,2:1,5:1,5:2 or 10:1, preferably 2-8:1-4, more preferably 3-7:1-3.
In one preferred embodiment, functional powders include negative ion powder, the dilute powder of graphite and magnet powder.
Preferably, the mass ratio of negative ion powder, the dilute powder of graphite and magnet powder is 0.1-2:0.1-2:0.1-2, such as can be with
For, but be not limited to 0.1:2:2,0.1:0.1:2,2:0.1:0.1,0.5:1.5:1.5,0.5:0.5:1.5,1.5:0.5:0.5,
0.8:1.2:1.2 or 1.2:1.2:0.8, preferably 0.5:1.5-0.5:1.5-0.5:1.5, more preferably 0.8:1.2-0.8:
1.2-0.8:1.2。
It is further adjusted and is optimized by the proportion to each functional powders, so that energy material provided by the invention
With better healthcare function.
In one preferred embodiment, the partial size of raw material is 0.5-1.5 μm, such as can be, but be not limited to 0.5 μ
M, 0.8 μm, 1 μm, 1.2 μm or 1.5 μm, preferably 0.6-0.2 μm, more preferably 0.8-1.0 μm.
The partial size of each raw material is limited in preferred scope, the compatibility of each raw material can be made more preferable, and Function is more
Comprehensively, so that energy material provided by the invention has better healthcare function.
The present invention also provides the preparation methods of above-mentioned energy material, comprising:
It takes each raw material of formulation weight part to be uniformly mixed, obtains energy material.
The preparation method of above-mentioned energy material provided by the invention, this method simple process is easy to operate, can save big
The energy material that the man power and material of amount effectively improves production efficiency, and is prepared can effectively generate healthcare function.
Preferably, each raw material for taking formulation weight part after mixing, auxiliary agent is added into mixed-powder and mixes, obtains
Energy material.
Auxiliary agent is added into powder, the quality for the energy material that can be improved, so that energy material provided by the invention
Material has better healthcare function.
Preferably, the water content of energy material is 30%-40%, such as can be, but be not limited to 30%, 31%, 32%,
33%, 34%, 35%, 36%, 37%, 38%, 39% or 40%, preferably 30%-35%.
When controlling the water content of energy material of the invention in preferred scope, so that energy material is easier to prepare,
And the compatibility of wherein each raw material is more preferable, so that energy material provided by the invention has better healthcare function.
Preferably, the slurry viscosity of energy material is 25-55 ', such as can be, but be not limited to 25 ', 30 ', 35 ', 40 ',
45 ', 50 ' or 55 ', preferably 30-50 '.
When controlling the slurry viscosity of energy material of the invention in preferred scope, so that energy material is easier to make
Standby, wherein the compatibility of each raw material is more preferable, and obtained energy material application range is wider.
Exist the present invention also provides above-mentioned energy material or using the energy material that above-mentioned preparation method is prepared
Prepare the application in health product.
Preferably, health product includes health care building materials or health textile.
Preferably, health care building materials are selected from health tile, health care floor, health care wallpaper or health paint.
Preferably, health textile is selected from health care curtain, health towel or health care underwear.
The present invention also provides a kind of energy ceramic tiles, including ceramic body 1 and glaze layer；
Wherein, glaze layer includes the energy material that above-mentioned energy material or the above-mentioned preparation method of use are prepared.
The energy ceramic tile has the function of permanently generating health care, while releasing negative oxygen ion, avoids sub-health state.
In addition, also having both the advantages of improving air quality.
In one preferred embodiment, the glaze layer of the energy ceramic tile includes three layers, from the inside to the outside respectively the first glaze
Layer 2, energy layer 3 and the second glaze layer 4, wherein energy layer 3 includes energy material provided by the invention.
In addition, the present invention also provides the preparation methods of above-mentioned energy ceramic tile, comprising:
Glaze is sprayed to 1 one side surface of ceramic body, the first glaze layer 2 is obtained after dry, mixing is sprayed in the first glaze layer 2
There is the glaze of energy material, obtain energy layer 3 after dry, sprays glaze again in energy layer 3, obtain the second glaze layer 4 after dry,
Second glaze layer 4 is processed by shot blasting, energy ceramic tile is obtained.
This method simple process, it is easy to operate, a large amount of man power and material can be saved, production efficiency is effectively improved, and
The energy ceramic tile being prepared is with health role to human body, also has both the advantages of improving air quality.
Glaze is divided into three-layer set, and the first glaze layer 2 is first arranged in billet surface and sprays energy layer 3 again, can make energy layer 3
It is higher with the degree of adhesion of ceramic body 1, the damage that falls off is avoided, is polished after spraying the second glaze layer 4 again outside energy layer 3, this
When polishing operation energy ceramic tile can be made still to have the function of health care by 4 jettisoning of the second glaze layer without failure energy layer 3, thus
Achieve the purpose that saving energy material uses, save the cost.
In one preferred embodiment, the mass ratio of energy material and glaze is 5-20:100, such as can be, but
It is not limited to 5:100,10:100,15:100 or 20:100, preferably 10-20:100, more preferably 10-15:100.
It is further adjusted and is optimized by the mass ratio to energy material and glaze, so that energy provided by the invention
Ceramic tile is measured on the basis of save the cost, there is better healthcare function.
Combined with specific embodiments below and comparative example, the invention will be further described.
Embodiment 1
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
40 parts of potassium albite in powder, 5 parts of kaolin, grey 5 parts of feldspar powder, 1 part of porcelain sand, 2 parts of negative ion powder, 2 parts of Graphene powder
With 1 part of magnet powder.
Embodiment 2
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
80 parts of potassium albite in powder, 20 parts of kaolin, grey 0.5 part of feldspar powder, 10 parts of porcelain sand, 5 parts of negative ion powder, Graphene powder
5 parts and 5 parts of magnet powder.
Embodiment 3
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
50 parts of potassium albite in powder, 8 parts of kaolin, grey 4 parts of feldspar powder, 2 parts of porcelain sand, 5 parts of negative ion powder, 5 parts of Graphene powder
With 4 parts of magnet powder.
Embodiment 4
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
70 parts of potassium albite in powder, 18 parts of kaolin, grey 1 part of feldspar powder, 8 parts of porcelain sand, 2 parts of negative ion powder, 2 parts of Graphene powder
With 2 parts of magnet powder.
Embodiment 5
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
59 parts of potassium albite in powder, 13 parts of kaolin, grey 3 parts of feldspar, 5 parts of porcelain sand, 3 parts of negative ion powder, 3 parts of Graphene powder and
3 parts of magnet powder.
Embodiment 6
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
59 parts of potassium albite in powder, 13 parts of kaolin, grey 3 parts of feldspar, 5 parts of porcelain sand, 3 parts of negative ion powder, 3 parts of Graphene powder,
3 parts of magnet powder, 0.05 part of hydroxy-ethyl acrylate and 0.05 part of waterglass.
Embodiment 7
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
59 parts of potassium albite in powder, 13 parts of kaolin, grey 3 parts of feldspar, 5 parts of porcelain sand, 3 parts of negative ion powder, 3 parts of Graphene powder,
3 parts of magnet powder, 1 part of hydroxy-ethyl acrylate and 1 part of waterglass.
Embodiment 8
A kind of energy material is present embodiments provided, is mainly made of the raw material of following parts by weight:
59 parts of potassium albite in powder, 13 parts of kaolin, grey 3 parts of feldspar, 5 parts of porcelain sand, 3 parts of negative ion powder, 3 parts of Graphene powder,
3 parts of magnet powder, 1 part of hydroxy-ethyl acrylate and 0.5 part of waterglass.
Embodiment 9-13
A kind of energy material is present embodiments provided, is prepared by following methods:
(a) raw material of formulation weight part is crushed in Example 1-5 respectively, makes the partial size 0.5- of raw material powder
1.5μm；
(b) smashed raw material is uniformly mixed, obtains energy material.
Embodiment 14-16
A kind of energy material is present embodiments provided, is prepared by following methods:
(a) raw material of formulation weight part is crushed in Example 6-8 respectively, makes the partial size 0.5- of raw material powder
1.5μm；
(b) after mixing by the smashed raw material in addition to auxiliary agent, auxiliary agent is added into mixed-powder and mixes, obtains
Energy material.
Embodiment 17
A kind of energy material is present embodiments provided, is prepared by following methods:
(a) raw material of formulation weight part is crushed in Example 8；
(b) after mixing by the smashed raw material in addition to auxiliary agent, auxiliary agent is added into mixed-powder and mixes, obtains
Energy material.
Comparative example 1
This comparative example provides a kind of energy material, is mainly made of the raw material of following parts by weight:
35 parts of potassium albite in powder, 3 parts of kaolin, grey 8 parts of feldspar powder, 0.5 part of porcelain sand, 5 parts of negative ion powder, Graphene powder 1
Part and 0.1 part of magnet powder.
Comparative example 2
This comparative example provides a kind of energy material, is mainly made of the raw material of following parts by weight:
40 parts of potassium albite in powder, grey 5 parts of feldspar powder, 1 part of porcelain sand, 2 parts of negative ion powder, 2 parts of Graphene powder and magnet powder 1
Part.
Comparative example 3
This comparative example provides a kind of energy material, is mainly made of the raw material of following parts by weight:
40 parts of potassium albite in powder, 5 parts of kaolin, grey 5 parts and 1 part of porcelain sand of feldspar powder.
Comparative example 4
This comparative example provides a kind of energy material, is mainly made of the raw material of following parts by weight:
59 parts of potassium albite in powder, 13 parts of kaolin, grey 3 parts of feldspar, 5 parts of porcelain sand, 3 parts of negative ion powder, 3 parts of Graphene powder,
3 parts of magnet powder, 2 parts of hydroxy-ethyl acrylate and 2 parts of waterglass.
Comparative example 5-7
This comparative example provides a kind of energy material, is prepared by following methods:
(a) it takes the raw material of formulation weight part in comparative example 1-3 to be crushed respectively, makes the partial size 0.5- of raw material powder
1.5μm；
(b) smashed raw material is uniformly mixed, obtains energy material.
Comparative example 8
A kind of energy material is present embodiments provided, is prepared by following methods:
(a) it takes the raw material of formulation weight part in comparative example example 4 to be crushed, makes 0.5-1.5 μm of partial size of raw material powder；
(b) after mixing by the smashed raw material in addition to auxiliary agent, auxiliary agent is added into mixed-powder and mixes, obtains
Energy material.
Embodiment 18-26
A kind of energy ceramic tile is present embodiments provided, which includes:
Ceramic Tiles green body and glaze layer, glaze layer respectively include the energy material of embodiment 9-17 offer.
Embodiment 27
A kind of energy ceramic tile is present embodiments provided, the energy ceramic tile by being prepared following preparation method:
Glaze is sprayed to Ceramic Tiles green body side surface, obtains the first glaze layer 2 after dry, is sprayed in the first glaze layer 2 mixed
The glaze for the energy material for having embodiment 16 to provide is closed, is polished after dry, is obtained energy layer 3, spray glaze again in energy layer 3
Material obtains the second glaze layer 4 after dry, is processed by shot blasting to the second glaze layer 4, obtains energy ceramic tile.
Embodiment 28
A kind of energy ceramic tile is present embodiments provided, the energy ceramic tile by being prepared following preparation method:
Glaze is sprayed to Ceramic Tiles green body side surface, obtains the first glaze layer 2 after dry, is sprayed in the first glaze layer 2 mixed
The glaze for the energy material for having embodiment 16 to provide is closed, is polished after dry, is obtained energy layer 3, spray glaze again in energy layer 3
Material obtains the second glaze layer 4 after dry, is processed by shot blasting to the second glaze layer 4, obtains energy ceramic tile.
Wherein, the water content for controlling energy material is 35%, and slurry viscosity is 40 ', energy material and glaze in energy layer
Ratio be 10:100.
Embodiment 29
A kind of energy ceramic tile is present embodiments provided, the energy ceramic tile by being prepared following preparation method:
Glaze is sprayed to Ceramic Tiles green body side surface, obtains the first glaze layer 2 after dry, is sprayed in the first glaze layer 2 mixed
The glaze for the energy material for having embodiment 16 to provide is closed, is polished after dry, is obtained energy layer 3, spray glaze again in energy layer 3
Material obtains the second glaze layer 4 after dry, is processed by shot blasting to the second glaze layer 4, obtains energy ceramic tile.
Wherein, the water content for controlling energy material is 25%, and slurry viscosity is 20 ', energy material and glaze in energy layer 3
Ratio be 2:100.
Comparative example 9-12
This comparative example provides a kind of energy ceramic tile, which includes:
Ceramic Tiles green body and glaze layer, glaze layer respectively include the energy material of comparative example 5-8 offer.
Comparative example 13
This comparative example provides a kind of energy ceramic tile, and the energy ceramic tile by being prepared following preparation method:
Glaze is sprayed to Ceramic Tiles green body side surface, the first glaze layer 2 is obtained after dry, is directly sprayed in the first glaze layer 2
The glaze that the energy material of the offer of embodiment 16 is provided is applied, is polished after dry, obtains energy ceramic tile.
In order to be tested as follows to energy ceramic tile row further instruction provided by the invention:
1 energy ceramic tile of experimental example tests the change of molecular structure water
The present embodiment uses17It is as shown in table 1 below that half breadth of O nuclear magnetic resonance does testing result:
Table 117Half breadth testing result of O nuclear magnetic resonance
It can be seen that the general 10-13 water clusters of tap water from the result of upper table, the water clusters of embodiment are about in 5-6
Between a water clusters, the standard of activated water (small molecule water i.e. activated water, water clusters general 5-6) is reached, and has compared
Activated water molecule standard is not achieved in example.Illustrate the energy ceramic tile that 18-29 of the embodiment of the present invention is provided, by each specific components and matches
Coordinated than between, activated water can be played the role of by all having, and thus illustrate that energy ceramic tile has the function of cutting water clusters
Can, can also by water pesticide, chemical fertilizer, hormone strand cut and degrade.And the energy ceramic tile that comparative example 9-13 is provided, In
The aspect of activated water, effect are far below the level of embodiment.
Wherein, the energy material that the energy ceramic tile that embodiment 18-22 is provided includes, raw material components are identical, only match
Than difference.But the energy ceramic tile that embodiment 22 provides is no matter in terms of activated water molecule or degradation harmful substance, effect
It is above the level of embodiment 18-21, equally, no matter the energy ceramic tile that embodiment 20 and 21 provides is in activated water molecule or drop
The aspect of harmful substance is solved, effect is above the level of embodiment 18 and 19.Illustrate to carry out by the proportion to each component into
The adjustment and optimization of one step, so that energy material provided by the invention has better healthcare function.
Similarly, the energy material that the energy ceramic tile that embodiment 23-25 is provided includes, raw material components and added auxiliary agent
Type is identical, and only auxiliary agent proportion is different.But no matter the energy ceramic tile that embodiment 25 provides is in activated water molecule or degradation
The aspect of harmful substance, effect are above the level of embodiment 23 and 24.Illustrate to carry out by the proportion to each auxiliary agent into one
The adjustment and optimization of step, so that energy material provided by the invention has better healthcare function.
The energy ceramic tile packet that the energy material and embodiment 23-26 that the energy ceramic tile that embodiment 18-22 is provided includes provide
The energy material contained, raw material components are identical, but no matter the energy ceramic tile that embodiment 23-26 is provided is in activated water molecule or drop
The aspect of harmful substance is solved, effect is above the level of embodiment 18-22.Illustrate in the identical situation of raw material, by adding
Adding assistant can make the energy material being prepared have stronger health-care effect, can effectively avoid sub-health state.
The energy material that the energy ceramic tile that embodiment 22 and comparative example 9 provide includes, raw material components are identical, but comparative example 9
In each raw material proportion not in ratio range of the invention, no matter the energy ceramic tile that embodiment 22 provides is in activated water molecule
Or the aspect of degradation harmful substance, effect are above the level of comparative example 9.Illustrate in the identical situation of raw material, at this
Energy material in invention proportion has stronger health-care effect, can effectively avoid sub-health state.
The energy material that the energy ceramic tile that embodiment 22 and comparative example 10 and 11 provide includes, the proportion of same materials component
It is identical, but lack kaolin in comparative example 10, functional powders are lacked in comparative example 11, the energy ceramic tile that embodiment 22 provides is no matter
In terms of activated water molecule or degradation harmful substance, effect is above the level of comparative example 10 and 11.Illustrate identical
In the identical situation of the proportion of raw material components, only by the coordinated between each raw material specific components, obtained energy material
Material just has stronger health-care effect, can effectively avoid sub-health state.
The energy material that the energy ceramic tile that embodiment 25 and comparative example 12 provide includes, raw material components are identical, and remove auxiliary agent
Outer raw material proportioning is also identical, and not in ratio range of the invention, embodiment 25 mentions the proportion of each auxiliary agent in comparative example 12
For the energy ceramic tile of confession no matter in terms of activated water molecule or degradation harmful substance, effect is above the level of comparative example 12.
Illustrate in the identical situation of raw material, energy material of the auxiliary dosage in present invention proportion has stronger health-care effect, energy
It is enough effectively to avoid sub-health state.
The energy material that the energy ceramic tile that embodiment 25 and embodiment 26 provide includes, raw material components and proportion are all the same,
But during the preparation process, not in the preferred range, no matter energy ceramic tile is activating the partial size of raw material in embodiment 26
The aspect of hydrone or harmful substance of degrading, effect are below the level of embodiment 25.Illustrate the situation identical in raw material
Under, the energy material of raw material particle size in the preferred range has stronger health-care effect, can effectively avoid inferior health
State.
The energy material that the energy ceramic tile that embodiment 27 and comparative example 13 provide includes, raw material components and proportion are all the same,
But during the preparation process, comparative example 13 does not spray the second glaze layer 4, and no matter energy ceramic tile has in activated water molecule or degradation
The aspect of evil substance, effect are below the level of embodiment 27.Illustrate to spray three in preparation process in the identical situation of raw material
The energy ceramic tile of layer glaze has stronger health-care effect, can effectively avoid sub-health state.
The energy material that the energy ceramic tile that embodiment 28 and embodiment 29 provide includes, raw material components and proportion are all the same,
But during the preparation process, the parameters index of the energy material in embodiment 29 not in the preferred range, energy
Ceramic tile is measured no matter in terms of activated water molecule or degradation harmful substance, effect is below the level of embodiment 28.Illustrate
In the identical situation of raw material, the energy porcelain of the parameter index of energy material used in preparation process in the preferred range
Brick has stronger health-care effect, can effectively avoid sub-health state.
Experimental example 2 changes the pH value test of water
For save the cost, the preferable embodiment 22,25 and 28 of result provides in choice experiment example 1 energy ceramic tile and right
The energy ceramic tile that ratio 11 provides is changed the test of the pH value of water.
Appropriate amount of purified water and tap water are put into the energy ceramic tile that embodiment 22,25 and 28 and comparative example 11 provide respectively
On, PH reagent is instilled, PH variation in 2 hours is observed.The results are shown in Table 2 for it.
2 pH of table changes comparing result figure
From Table 2, it can be seen that the embodiment of the present invention 28 provide energy ceramic tile in 2 minutes can by tap water PH by
7.0, which rise to 8.0, becomes alkalescent water.And comparative example provide energy ceramic tile after 2 hours pH still without significant changes.Together
Sample, the energy ceramic tile observation that slant acidity pure water comparative example provides 2 hours unchanged, cannot change the pH value of pure water.And this
The pure water of slant acidity is become alkalescent after 30 minutes by the energy ceramic tile that inventive embodiments 28 provide, and demonstrates again that the present invention
Alkalescent can be presented by macromolecular mass Water Cutting at small-micelle water in the energy ceramic tile of offer, with health role to human body.
Observation of the experimental example 3 to microcirculation change
Tool: medical microcirculation detector
Object: 12 health adult's Microcirculation of Nailfold variations of observation: male 9, it is female 3, the age 20-32 years old, 25 years old average；
Height: 158cm-180cm is averaged 168cm, weight, and: 48Kg-79Kg is averaged 67Kg.
Method: after subject rests 30 minutes, excluding ambient enviroment interference, takes seat, and right ring finger sets somascope survey
It in prospect hole, brings into focus, finds blood vessel button loop top, 1 minute intravascular white adipose particle of observation is done by the quantity at top to be referred to
Mark.The right hand is laid flat into 10cm respectively again2Energy ceramic tile, the 10cm of the offer of embodiment 252Embodiment 28 provide energy ceramic tile and
10cm2Above the energy ceramic tile that comparative example 11 provides, it is as shown in table 3 below to obtain numerical value:
The quantity that the intravascular white adipose particle of table 3 passes through top
4 microcirculation detection statistics table of table
Show that the energy ceramic tile that the embodiment of the present invention 25 provides can accelerate microcirculation, the energy that embodiment 28 provides by upper table
Then the more obvious energy ceramic tile provided than comparative example 11 averagely increases 22% to ceramic tile, thus highest speedup may be used up to 29%
The energy ceramic tile improving micro_circulation effect for seeing that embodiment 28 provides is powerful and lasting, and it is fast (only 20 seconds) to start the time.
4 environmental protection tests of experimental example
In order to verify the environment protecting of energy ceramic tile provided by the invention, special commission holds in the palm the analysis Chemical Engineering Technology research of BeiJing ZhongKe's light
To the embodiment of the present invention 28 provide energy ceramic tile detect, as a result as shown in table 5 below:
Table 5 studies examining report
| Detection project | Testing result | Unit |
| Except benzene eliminates the unusual smell purifying rate | 89.8 | % |
| Except purifying formaldehyde rate | 88.6 | % |
| Staphylococcus aureus antibiotic rate | 99.23 | % |
| Hemolytic streptococcus antibiotic rate | 99.89 | % |
| Anti-radiation detection | 98 | % |
| Normal emittance | 0.86 | - |
| Anion | 852 | A/cm2 |
Can be seen that energy ceramic tile provided by the invention from the result of upper table it is necessary to adsorb peculiar smell, purification air, antibacterial,
It is anti-radiation, have superpower far infrared transmissivity, a large amount of negative oxygen ions of release and other effects.To sum up, judged according to every test data, it should
Product has certain health-care efficacy to human health, environmentally protective.
It should be noted that in the present invention, the application of energy material is not limited to ceramic tile, may also refer to pvc floor glue,
The fields such as wallpaper, curtain, underpants underwear, energy tableware, energy paint and energy machine oil are all contained in the art.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (6)
1. a kind of energy ceramic tile is applied in the product that preparation accelerates microcirculation, the energy ceramic tile includes ceramic body and glaze
Layer；
The preparation method of the energy ceramic tile includes:
Glaze is sprayed to one side surface of ceramic body, obtains the first glaze layer after dry, spraying is mixed with energy in the first glaze layer
The glaze of material obtains energy layer after dry, sprays glaze again in energy layer, the second glaze layer is obtained after dry, to the second glaze
Layer is processed by shot blasting, obtains the energy ceramic tile；
The energy material is made of the raw material of following parts by weight:
59 parts of potassium albite in powder, 13 parts of kaolin, grey 3 parts of feldspar powder, 5 parts of porcelain sand, 3 parts of negative ion powder, 3 parts of Graphene powder, magnetic
3 parts of mountain flour, 1 part of hydroxy-ethyl acrylate and 0.5 part of waterglass；
The energy material is prepared via a method which to obtain:
(a) each raw material is crushed, makes 0.5-1.5 μm of partial size of raw material powder；
(b) potassium albite in powder, kaolin, grey feldspar powder, porcelain sand, negative ion powder, Graphene powder, magnet powder are uniformly mixed and are obtained
Then hydroxy-ethyl acrylate and waterglass is added in mixed-powder into the mixed-powder.
2. application according to claim 1, which is characterized in that the water content of the energy material is 35%.
3. application according to claim 1, which is characterized in that the slurry viscosity of the energy material is 40 '.
4. application according to claim 1, which is characterized in that the mass ratio of the energy material and glaze is 5-20:
100。
5. application according to claim 4, which is characterized in that the mass ratio of the energy material and glaze is 10-20:
100。
6. application according to claim 5, which is characterized in that the mass ratio of the energy material and glaze is 10-15:
100。
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