Summary of the invention
In order to adopt as far as possible renewable resources, reduce pollution to physical environment, present inventor finding after analysis and research for many years, kendir is as the raw-material optimal selection of natural paint composition.The features such as it is short that kendir has growth cycle, adaptable to soil, and output is high, and planting range is wide.At present, kendir is mainly used in textile industry and pharmaceutical industry, and its by product is for being mainly kendir natural gum, and apocynum fibre.Present inventor finds, its by product kendir natural gum and the apocynum fibre of textile industry and pharmaceutical industry are used for to coating, not only can turn waste into wealth, and the coating that contains mentioned component itself has the multiple advantage that existing coating does not have.
Therefore, the invention provides a kind of natural paint composition, it is characterized in that, this natural paint composition comprises kendir natural gum, apocynum fibre and tourmaline powder.
Natural paint composition provided by the invention has the following advantages:
1, surface is smooth, has natural silk or natural fiber texture.
2, moisture absorption is anti-dry, and the humidity of adjusting indoor environment automatically, meets the optimum environment that is applicable to human living.There is more wetting ability hydroxyl in the natural fiber in this product, coating structure also exists pore, has stronger water absorbability, can absorb the moisture of own vol 20%; If when dry air, water molecules can distribute, and automatically regulates the humidity in room.
3, lasting anion releasing, purifies air, and removes the toxic gas such as formaldehyde, ammonia that house decorative material etc. can send, and the harmful gas of stink peculiar smell in daily life.Tourmalinite is the natural mineral of multielement, and main chemical compositions is SiO
2tiO
2caO K
2o Li
2o Al
2o
3b
2o
3mgO Na
2o Fe
2o
3feOMnO P
2o
5, because it is the special polarity xln of a kind of structure, self can produce negative ion for a long time.In addition apocynum fibre also can produce the purification ions such as negative ion.Above-mentioned two kinds of compositions reasonably combined, can mutually excite and produce collaborative scale effect, produce a large amount of negative ion (suitable with the negative ion generation in the forest of occurring in nature, waterfall region), these negative ions form ionic cloud on the one hand within the extremely short time, generate harmless material with harmful dusty gas such as formaldehyde, ammonia, peculiar smell is final after a series of chain reaction; On the other hand can efficient sterilizing, reduce indoor bacteria concentration, prevent viral cross infection.And negative ion can also adsorb the suspended particle that is greater than tens times of own wts, settle down by deadweight, reach thereby remove suspensoid in air the object purifying air.For killing anti-microbial effect, according to the study, kendir natural gum is all inhibited to intestinal bacteria, Candida albicans and gold-coloured staphylococci.
4, natural far-infrared transmitting function, anti-hypolipemia, reduces the cardiovascular and cerebrovascular diseases such as cerebral arteriosclerosis, improves microcirculation in human body.Apocynum fibre and tourmalinite, can launch far infrared light wave, can infiltrate skin and subcutis, produces resonant absorption effects with the water molecules in histocyte.Reduce blood fat quantity, reduce blood fat, reduce the generation of the cardiovascular disordeies such as cerebral arteriosclerosis, can improve microcirculation in human body.
5, solar heat protection insulation, cool in summer and warm in winter, energy-saving and cost-reducing.Owing to thering is a large amount of microvoid structures in natural fiber material and film, according to the sound-absorbing principle of micropore, make this product can eliminate noise; In addition, the low thermal conductivity of microvoid structure and fiber, makes this product have thermal insulation function, makes room cool in summer and warm in winter.
6, natural materials, use is rear biodegradable, is converted into the nutritious fertilizer of plant.
7,3-D solid structure, good toughness, strong adhesion, shock resistance, intensity is high, anti-benefit tiny crack.Kendir natural gum and apocynum fibre are compound, the coating good toughness of formation, cracking resistance, strong adhesion, consistency of performance.
Embodiment
The invention provides a kind of natural paint composition, it is characterized in that, this natural paint composition comprises kendir natural gum, apocynum fibre and tourmaline powder.
In natural paint composition provided by the invention, to kendir natural gum, the ratio of apocynum fibre and tourmaline powder has no particular limits, but in order to obtain better health-care effect, described kendir natural gum, the weight ratio of described apocynum fibre and described tourmaline powder is preferably 1: 0.1-1: 0.02-0.2.In the preferred embodiment of one, described kendir natural gum, the weight ratio of described apocynum fibre and described tourmaline powder more preferably 1: 0.2-0.5: 0.05-0.1; In this embodiment, because the ratio of described apocynum fibre and described tourmaline powder is more suitable, they can work in coordination with releasing negative oxygen ion, and health-care effect will be more obvious.According to the study, in city and household sealed area, city and cold dim air-conditioned room, negative ion concentration is very low, is unfavorable for health; And in physical environment, negative ion concentration is higher.Result of study is as shown in the table
Environment |
Negative ion concentration (individual/cm3) |
Effect |
Forest, waterfall district |
100000-500000 |
There is spontaneous recovery power |
High mountain, seashore |
50000-100000 |
Antibacterial, minimizing disease propagation |
Countryside, field |
5000-50000 |
Increase body immunity and antimicrbial power |
Town park |
1000-2000 |
Maintain healthy basic need |
Street greening district |
100-200 |
Bring out physiological barrier performance |
Household sealed area, city |
40-50 |
Bring out headache, insomnia, anaphylactic disease etc. |
Indoor cold dim air-conditioned room |
0-20 |
Cause air conditioning disease symptom |
Any crude tourmaline powder that described tourmaline powder can adopt for this area, but in order to obtain better health properties, the granular size of described tourmaline powder is preferably 100-4000 order, and more preferably 800-3000 object tourmaline powder, as the tourmaline powder being provided by Lingshi County health care stone source mill.
The colloidal substance that described kendir natural gum in the present invention extracts exactly from kendir, it can be directly from kendir, directly to extract.In weaving and pharmaceutical industries, produce a large amount of kendir natural gum byproducts, this byproduct generally can not be made other purposes.Taking cost into account, the described kendir natural gum in the present invention preferably adopts these byproduct kendir natural gum.
Described apocynum fibre in the present invention can be directly from kendir, directly to extract.In weaving and pharmaceutical industries, produce a large amount of apocynum fibre byproducts.Taking cost into account, the described apocynum fibre in the present invention preferably adopts these byproduct apocynum fibres.
The present invention has no particular limits the size of described kendir natural gum and described apocynum fibre, and in order further to increase the surface-area of apocynum fibre, to regulate better humidity and other health-care effect, described apocynum fibre is of a size of nano level.
Described apocynum fibre and described kendir natural gum can adopt primary colors apocynum fibre and kendir natural gum, and they all can be purchased from Heze kendir products factory.In a preferred embodiment, described primary colors apocynum fibre carries out break process before use.The method of described broken processing can be the method for any broken fiber material, adopts HJ lumber fibre crusher (great lucky heavy-duty machinery) to carry out fragmentation but be preferably, and the staple length of acquisition is 0.5~3 millimeter.
In order further to improve the various performances of natural paint provided by the invention, for example prevent pigment precipitation, increase luminance brightness, avoid layering, increase and cover rate, levelling property, dispersiveness, wettability; Improve the sticking power of coating, abrasion resistance, contamination resistance, improves intensity; Improve abrasion resistance, protection paint film, be difficult for efflorescence, bubble, peel off, crack; Cover or increase color; Further enriched health care effect; One preferred embodiment in, natural paint composition of the present invention also comprises one or more in magnetized water, Yelkin TTS, plants essential oil, natural white pigment, color soil, lime powder, talcum powder, kaolin, marble flour and guar gum.In another preferred embodiment, described natural paint composition comprises magnetized water, Yelkin TTS, plants essential oil, natural white pigment, color soil, lime powder, talcum powder, kaolin, marble flour and guar gum.
Described natural white pigment can be natural white pigment any in this area, for example, and zinc white, lithopone powder, titanium dioxide, but be preferably titanium dioxide and/or zinc white.
The various combinations of composition provided by the invention can be separated, also can be modulated at together.In the time being modulated at together, should pack; Or part component may be mixed together, for example, natural white pigment, color soil, lime powder, talcum powder, kaolin and marble flour may be mixed together.But one preferred embodiment in, each component is separated.
Magnetized water has the effect of multiple mystery in industry, and for example, the boiler feed water that magnetic field treatment is a small amount of, can reduce incrustation scale; Magnetized water, for the cooling system of various High Temperature Furnaces Heating Apparatuss, has play a part very important for raising cooling efficiency, prolongation furnace campaign; Magnetized water can be accelerated chemical reaction velocity, improves output.In the present invention, contriver surprisingly finds that magnetized water can improve the cohesive strength of coating greatly.Any water of processing through magnetization that described magnetized water can adopt for this area, for example, can select river, the lake water processed through magnetization, and drinking public water supply, but be preferably magnetization Qin County Zhang Heshui.Magnetized water can, by commercially available, also can oneself be prepared, for example, ortho-water for example, is processed and got final product to obtain magnetized water by water magnetizing machine (, the ancient Henkel water magnetizing machine of purple light).The content of described magnetized water, has no particular limits, and its maximum level is, in the time using coating composition provided by the invention, modulates other component of composition provided by the invention and does not need to add other water or solvent again with described magnetized water.One preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 30-150 weight part, be preferably 40-80 weight part.
Any Yelkin TTS that described Yelkin TTS can adopt for this area, but be preferably soybean lecithin, Ovum Gallus domesticus Flavus lecithin, as soybean lecithin (LLF, Beijing Hua Qingmei perseverance), Ovum Gallus domesticus Flavus lecithin (PL-60, Beijing Hua Qingmei perseverance); The content of described natural phosphatidyl choline has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-25 weight part, be preferably 5-10 weight part.Yelkin TTS has surface-active action, shortens heat-up time, prevents pigment precipitation, increases luminance brightness, avoids layering, increases and covers rate and levelling property, dispersiveness, wettability.
Described plants essential oil can be any plants essential oil, for example folk prescription essential oil, as eucalyptus globolus, tea tree, Rosmarinus officinalis, lavandula angustifolia etc. has stronger sterilization effect, or has the santal essential oil of static determinacy effect, or has lemon quintessence oil purifying air etc.; Compound essential oil, as strengthened immunity system essential oil (BJ9, the green face in Beijing is emerald green to be revealed), conditioning internal secretion essential oil (BJ8-1, the green face in Beijing is emerald green to be revealed).The kind of essential oil can be selected to add according to user's demand.Essential oil before use, must lucifuge be packed separately, in the time using coating composition provided by the present invention, just essential oil is added, and mixes.The content of described plants essential oil has no particular limits; But from cost and effect consider, one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-25 weight part, be preferably 5-10 weight part.
Any titanium dioxide that described titanium dioxide can adopt for this area, but be preferably sharp titanium titanium dioxide, as HA-100 (Yumen, Gansu), ATA-125 (Anhui An Nada); The content of described titanium dioxide has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 25-100 weight part, be preferably 30-60 weight part.
The natural zinc white that described zinc white can adopt for this area, but be preferably zinc sulfide white, as good luck source board B301 zinc sulfide white (Shanghai face titanium industry), zinc sulfide white B311 (Shijiazhuang BHP magnesium zinc); The content of described natural zinc white has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-25 weight part, be preferably 5-10 weight part.
Any natural color scholar that described color soil can adopt for this area, but be preferably Tibet natural color soil, as Gangdise active earths (the purple nation in Shanghai chemical industry); The content of described color soil has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-50 weight part, be preferably 10-20 weight part.
Any natural magnesium calcium powder that described lime powder can adopt for this area, but be preferably limestone powder, as 1250 order dicalcium powders (great Ding mountain, Lishu County); The content of described natural stone ashes has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-25 weight part, be preferably 5-10 weight part.Lime powder can improve the thixotropy of system greatly, can significantly improve the sticking power of coating, abrasion resistance, and contamination resistance, improves intensity and surface smoothness, and has good anti-settling effect.
The natural talcum powder that described talcum powder can adopt for this area, but be preferably 1250 order talcum powder, as 1250 order talcum powder (Qixia Hua You); The content of described natural talcum powder has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-25 weight part, be preferably 5-10 weight part.Talcum powder, as filler, can play skeleton function, and reduction manufacturing cost improves the hardness of paint film of coating simultaneously.
Any kaolin that described kaolin can adopt for this area, but be preferably 1250 order kaolin, as 1250 order kaolin (the emerging industry of Shijiazhuang occasion); Described kaolinic content has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 12-75 weight part, be preferably 20-30 weight part.Kaolin can improve thixotropy and resistance to settling.
Any Paris white that described marble flour can adopt for this area, but be preferably marble flour, as marble flour (Lingshou County converge prosperous mining industry); The content of described marble flour has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 30-150 weight part, be preferably 40-80 weight part.Marble flour Main Function serves as packing material.
Any guar gum that described guar gum can adopt for this area, but be preferably cation guar gum, as cation guar gum (Shanghai Sheng Xuan); The content of described guar gum has no particular limits; But one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, can be 2-25 weight part, be preferably 5-10 weight part.Consistence, levelling that guar gum can strengthen coating are capable, abrasion resistance protect paint film, are difficult for efflorescence, bubble, peel off, crack.
In order to improve the over-all properties of described coating, one preferred embodiment in, with respect to the described kendir natural gum of 100 weight parts, described Yelkin TTS can, for content is 2-25 weight part, be preferably 5-10 weight part; The content of described lime powder is 2-25 weight part, is preferably 5-10 weight part; Described talcous content is 2-25 weight part, is preferably 5-10 weight part; Described kaolinic content is 12-75 weight part, is preferably 20-30 weight part; The content of described marble flour is 30-150 weight part, is preferably 40-80 weight part; The content of described guar gum is 2-25 weight part, is preferably 5-10 weight part.
In order further to improve the over-all properties of described coating, in another preferred embodiment, with respect to the described kendir natural gum of 100 weight parts, the content of described magnetized water is 30-150 weight part, is preferably 40-80 weight part; The content of described plants essential oil is 2-25 weight part, is preferably 5-10 weight part; The content of described titanium dioxide is 25-100 weight part, is preferably 30-60 weight part; The content of described zinc white part is 2-25 weight part, is preferably 5-10 weight part; The content of described color soil is 2-50 weight part, is preferably 10-20 weight part; The content of described Yelkin TTS is 2-25 weight part, is preferably 5-10 weight part; The content of described lime powder is 2-25 weight part, is preferably 5-10 weight part; Described talcous content is 2-25 weight part, is preferably 5-10 weight part; Described kaolinic content is 12-75 weight part, is preferably 20-30 weight part; The content of described marble flour is 30-150 weight part, is preferably 40-80 weight part; The content of described guar gum is 2-25 weight part, is preferably 5-10 weight part;
Composition provided by the invention can be prepared according to prior art, mixes by each component.In use, if described composition does not contain magnetized water or the quantity not sufficient of the magnetized water that contains when being modulated into slurries, add water, described composition is modulated into slurries.The amount of the magnetized water containing when described composition is enough, just directly with magnetized water, other compositional modulation of described composition is become to slurries.Then by this surface such as brush, cylinder or spray gun brushing plaster, gypsum, plank for slurries.
To further illustrate the present invention by embodiment below, in all embodiment, the apocynum fibre adopting is purchased from kendir products factory, and passes through before use break process.Broken working method is: crusher for apocynum fibre (HJ lumber fibre crusher, great lucky heavy-duty machinery) is carried out to fragmentation, and the staple length of acquisition is 0.5~3 millimeter.
Embodiment 1
By kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 50 weight parts and tourmaline powder (150 orders, Lingshi County health care stone source mill) 30 weight parts mix, and form composition 1.
Embodiment 2
By kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 100 weight parts and tourmaline powder (3000 orders, Lingshi County health care stone source mill) 20 weight parts mix, and form composition 2.
Embodiment 3
By kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 10 weight parts and tourmaline powder (1250 orders, Lingshi County health care stone source mill) 2 weight, soybean lecithin (LLF, Beijing Hua Qingmei perseverance) 2 weight parts, lime powder (1250 order dicalcium powders, great Ding mountain, Lishu County) 2 weight parts, talcum powder (1250 order talcum powder, Qixia Hua You) 2 weight parts, kaolin (1250 order kaolin, the emerging industry of Shijiazhuang occasion) 12 weight parts, marble flour (Lingshou County converge prosperous mining industry) 30 weight parts and guar gum (Shanghai Sheng Xuan) 2 weight parts mix, form composition 3.
Embodiment 4
By kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 50 weight parts and tourmaline powder (1250 orders, Lingshi County health care stone source mill) 10 weight parts, soybean lecithin (LLF, Beijing Hua Qingmei perseverance) 25 weight parts, lime powder (1250 order dicalcium powders, great Ding mountain, Lishu County) 25 weight parts, talcum powder (1250 order talcum powder, Qixia Hua You) 25 weight parts, kaolin (1250 order kaolin, the emerging industry of Shijiazhuang occasion) 75 weight parts, marble flour (Lingshou County converge prosperous mining industry) 150 weight parts and guar gum (Shanghai Sheng Xuan) 25 weight parts, titanium dioxide (HA-100, Yumen, Gansu) 25 weight parts, zinc white (good luck source board B301 zinc sulfide white, Shanghai face titanium industry) 2 weight parts, color soil (Gangdise active earths, the purple nation in Shanghai chemical industry) 2 weight parts mix, form composition 4.
Embodiment 5
By kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 40 weight parts and tourmaline powder (1250 orders, Lingshi County health care stone source mill) 6 weight parts, soybean lecithin (LLF, Beijing Hua Qingmei perseverance) 5 weight parts, lime powder (1250 order dicalcium powders, great Ding mountain, Lishu County) 10 weight parts, talcum powder (1250 order talcum powder, Qixia Hua You) 5 weight parts, kaolin (1250 order kaolin, the emerging industry of Shijiazhuang occasion) 20 weight parts, marble flour (Lingshou County converge prosperous mining industry) 40 weight parts and guar gum (Shanghai Sheng Xuan) 5 weight parts, titanium dioxide (HA-100, Yumen, Gansu) 100 weight parts, zinc white (good luck source board B301 zinc sulfide white, Shanghai face titanium industry) 25 weight parts, color soil (Gangdise active earths, the purple nation in Shanghai chemical industry) 50 weight parts, magnetized water (Qin County Zhang Heshui, pick up from the processing of the ancient Henkel water magnetizing machine of purple light) 30 weight parts, strengthen immunity system essential oil (BJ9, the green face in Beijing is emerald green to be revealed) 25 weight parts mix, form composition 5.
Embodiment 6
By kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 20 weight parts and tourmaline powder (1250 orders, Lingshi County health care stone source mill) 2 weight parts, soybean lecithin (LLF, Beijing Hua Qingmei perseverance) 10 weight parts, lime powder (1250 order dicalcium powders, great Ding mountain, Lishu County) 5 weight parts, talcum powder (1250 order talcum powder, Qixia Hua You) 10 weight parts, kaolin (1250 order kaolin, the emerging industry of Shijiazhuang occasion) 30 weight parts, marble flour (Lingshou County converge prosperous mining industry) 55 weight parts and guar gum (Shanghai Sheng Xuan) 10 weight parts, titanium dioxide (HA-100, Yumen, Gansu) 50 weight parts, zinc white (good luck source board B301 zinc sulfide white, Shanghai face titanium industry) 15 weight parts, color soil (Gangdise active earths, the purple nation in Shanghai chemical industry) 30 weight parts, magnetized water (Qin County Zhang Heshui, pick up from the processing of the ancient Henkel water magnetizing machine of purple light) 150 weight parts, conditioning internal secretion essential oil (BJ8-1, the green face in Beijing is emerald green to be revealed) 2 weight parts mix, form composition 6.
Comparative example 1
By water 240 weight parts, EBS451 (Aksu) 2 weight parts, NXZ (Nuo Puke) 1.5 weight parts, ammoniacal liquor (providing chemical industry in Jinzhong City) 1.5 weight parts, ethylene glycol (providing chemical industry in Jinzhong City) 10 weight parts, alcohol ester 12 (Yi Shiman) 5 weight parts, ORATAN1288 (ROHM AND HAAS) 7.5 weight parts, Triton CF-10 (Tao Shi) 2 weight parts, HA-100 titanium dioxide (Yumen, Gansu) 50 weight parts, 1250 order coarse whitings (Baima, Jincheng), 350 weight parts, 1250 order kaolin (sky, Shanghai, Hepu), 137.5 weight parts, 1250 order talcum powder (Jin Yuan peak, Laizhou), 75 weight parts, AS-2010 (ROHM AND HAAS) 100 weight parts, NXZ (Nuo Puke) 1.5 weight parts, HF (Sol) 1.5 weight parts, it is even that TRM203 (Dalian gold ancient cooking vessel auspicious) 5 weight parts (using after water dilution in 2: 1) carry out dispersing and mixing, form Comparative composition 1.
Performance test
The composition of above-mentioned 100 grams of embodiment 1-4 is allocated with 200 grams of water, the composition of 100 grams of embodiment 5 and 6 is allocated with 50 grams of water, and the Comparative composition 1 of the comparative example 1 of 100 grams, then require to make model according to the requirement of following testing method, carry out the test of splitting resistance performance, bounding force with base material, thermal conductivity, negative ion concentration, normal direction total emissivity.Splitting resistance and cohesive strength are according to 6.15 carrying out in JG/T 157-2009; Thermal conductivity is carried out according to GB/T 10294-2008; Negative ion concentration is detected by negative ion detector; Infrared emittance is carried out according to GB7287.10-87., and result is as shown in table 1.
Table 1
Note: the testing method of negative ion concentration:
By sample brushing, on 0.5 centimetre of cement of 15 cm x 7 cm x, maintenance one week, is then placed in the lens of 30 centimetres of 30 cm x 30 cm x, leaves standstill after 1 hour, with negative ion detector detectable level.
The result of table 1 shows: compared with the bounding force between coating and base material that natural paint composition provided by the invention forms after solidifying, the dope layer that resistance to cleavage forms after solidifying with existing coating composition in basic unit, its bounding force at least improves 30%, and splitting resistance performance at least improves 50%.In addition, the coating that natural paint composition provided by the invention forms after solidifying has lower heat-conduction coefficient, is 50% of general coating, therefore has obvious heat insulation and preservation effect; In one, preferred embodiment in (coating composition that embodiment 4,5 provides), the negative ion burst size of the coating that coating composition forms after solidifying reaches the level in countryside, field, can increase human immunological competence and antimicrbial power.