Summary of the invention
In order to adopt renewable resources as far as possible, reduce pollution to physical environment, the present inventor finds that after through analysis and research for many years kendir is as the raw-material optimal selection of natural paint compsn.Characteristics such as it is short that kendir has growth cycle, strong to the soil adaptive faculty, and output is high, and planting range is wide.At present, kendir is mainly used in textile industry and pharmaceutical industry, and its by product is for being mainly kendir natural gum, and apocynum fibre.The present inventor finds, gummy and apocynum fibre is used for coating with its by product kendir of textile industry and pharmaceutical industry, not only can turn waste into wealth, and the coating itself that contains mentioned component has the multiple advantage that existing coating does not have.
Therefore, the invention provides a kind of natural paint compsn, it is characterized in that, this natural paint compsn comprises kendir natural gum, apocynum fibre and tourmaline powder.
Natural paint compsn provided by the invention has the following advantages:
1, the surface is smooth, and natural silk or natural fiber texture are arranged.
2, moisture absorption is anti-dry, regulates the humidity of indoor environment automatically, satisfies the optimum environment that is fit to human living.There is more wetting ability hydroxyl in natural fiber in this product, and also there is pore in coating structure, has stronger water absorbability, can absorb the moisture of own vol 20%; If during dry air, water molecules can distribute, and regulates the humidity in room automatically.
3, discharge negative ion lastingly, purify air, toxic gases such as the formaldehyde that removing house decorative material etc. can send, ammonia, and the harmful gas of stink peculiar smell in the daily life.Tourmalinite is the natural mineral of multielement, and main chemical compositions is SiO
2TiO
2CaO K
2O Li
2O Al
2O
3B
2O
3MgO Na
2O Fe
2O
3FeOMnO P
2O
5, because it is the special polarity xln of a kind of structure, self can produce negative ion for a long time.Apocynum fibre also can produce purification ions such as negative ion in addition.Above-mentioned two kinds of compositions reasonably combined; Can excite and produce collaborative scale effect each other; Produce a large amount of negative ion (suitable) with the negative ion generation in the forest of occurring in nature, waterfall zone; These negative ions form ionic cloud on the one hand in the extremely short time, with harmful dusty gass such as formaldehyde, ammonia, peculiar smell harmless material of final generation after a series of Kettenreaktion; On the other hand can efficient sterilizing, reduce indoor bacteria concentration, prevent viral cross infection.And negative ion can also adsorb the suspended particle greater than tens times of own wts, settles down by deadweight, and suspensoid reaches the purpose that purifies air in the air thereby remove.For killing anti-microbial effect, according to research, kendir natural gum is all inhibited to intestinal bacteria, Candida albicans and gold-coloured staphylococci.
4, natural far-infrared transmitting function, anti-hypolipemia reduces cardiovascular and cerebrovascular diseases such as cerebral arteriosclerosis, improves microcirculation in human body.Apocynum fibre and tourmalinite can be launched far infrared light wave, can infiltrate skin and subcutis, with the water molecules generation resonant absorption effects in the histocyte.Reduce blood fat quantity, reduce fat, the generation of cardiovascular disordeies such as minimizing cerebral arteriosclerosis can improve microcirculation in human body.
5, solar heat protection insulation, cool in summer and warm in winter, energy-saving and cost-reducing.Have a large amount of microvoid structures owing to natural fiber material with in filming,, make this product can eliminate noise according to the sound-absorbing principle of micropore; In addition, the low thermal conductivity of microvoid structure and fiber makes this product have the heat-insulation and heat-preservation effect, makes the room cool in summer and warm in winter.
6, natural materials uses the back biodegradable, is converted into the nutritious fertilizer of plant.
7,3-D solid structure, good toughness, strong adhesion, shock resistance, intensity is high, the anti-tiny crack of mending.Kendir natural gum and apocynum fibre are compound, the coating good toughness of formation, cracking resistance, strong adhesion, consistency of performance.
Embodiment
The invention provides a kind of natural paint compsn, it is characterized in that, this natural paint compsn comprises kendir natural gum, apocynum fibre and tourmaline powder.
In natural paint compsn provided by the invention; To kendir natural gum; The ratio of apocynum fibre and tourmaline powder has no particular limits; But in order to obtain better health-care effect, said kendir is gummy, and the weight ratio of said apocynum fibre and said tourmaline powder is preferably 1: 0.1-1: 0.02-0.2.In a kind of preferred embodiment, said kendir natural gum, the weight ratio of said apocynum fibre and said tourmaline powder further is preferably 1: 0.2-0.5: 0.05-0.1; In this embodiment, because the ratio of said apocynum fibre and said tourmaline powder is more suitable, they can work in coordination with the release negative oxygen ion, and health-care effect will be more obvious.According to research, in the city and household sealed area, city and cold dim air-conditioned room, negative ion concentration is very low, is unfavorable for health; And in physical environment, negative ion concentration is higher.Result of study is as shown in the table
Environment |
Negative ion concentration (individual/cm3) |
Effect |
Forest, waterfall district |
100000-500000 |
Has spontaneous recovery power |
High mountain, seashore |
50000-100000 |
Antibacterial, minimizing disease propagation |
Countryside, field |
5000-50000 |
Increase body immunity and antimicrbial power |
The town park |
1000-2000 |
Keep healthy basic need |
The street greening district |
100-200 |
Bring out the physiological barrier performance |
Household sealed area, city |
40-50 |
Bring out headache, insomnia, anaphylactic disease etc. |
Indoor cold dim air-conditioned room |
0-20 |
Cause the air conditioning disease symptom |
Any crude tourmaline powder that said tourmaline powder can adopt for this area; But in order to obtain better health properties; The particle size of said tourmaline powder is preferably the 100-4000 order; And 800-3000 purpose tourmaline powder more preferably is like the tourmaline powder that is provided by Lingshi County health care stone source mill.
The colloid material that said kendir natural gum among the present invention extracts from kendir exactly, it can be directly from kendir, directly to extract.In weaving and pharmaceutical industries, produced a large amount of kendir natural gum sub products, this sub product generally can not be made other purposes.Taking cost into account, preferred these sub product kendir natural gum that adopts of the said kendir natural gum among the present invention.
Said apocynum fibre among the present invention can be directly from kendir, directly to extract.In weaving and pharmaceutical industries, produced a large amount of apocynum fibre sub products.Taking cost into account, the said apocynum fibre among the present invention preferably adopts these sub product apocynum fibres.
The present invention has no particular limits the size of said kendir natural gum and said apocynum fibre, and in order further to increase the surface-area of apocynum fibre, so that regulate humidity and other health-care effect better, said apocynum fibre is of a size of nano level.
Said apocynum fibre and said kendir natural gum can adopt primary colors apocynum fibre and kendir natural gum, and they all can be available from Heze kendir products factory.In preferred embodiment, described primary colors apocynum fibre carries out break process before use.Said broken method for processing can be the method for any broken fiber material, adopts HJ lumber fibre crusher (great lucky heavy-duty machinery) to carry out fragmentation but be preferably, and the staple length of acquisition is 0.5~3 millimeter.
In order further to improve the various performances of natural paint provided by the invention, for example prevent the pigment deposition, increase luminance brightness, avoid layering, increase and cover rate, leveling characteristics, dispersiveness, wettability; Improve ADHESION OF PAINTS power, abrasion resistance, contamination resistance improves intensity; Improve abrasion resistance, protection paint film, be difficult for efflorescence, bubble, peel off, the crack; Cover or increase color; Further enriched health care effect; A kind of preferred embodiment in, natural paint compsn of the present invention also comprises one or more in magnetized water, Yelkin TTS, plants essential oil, natural white pigment, color soil, lime powder, talcum powder, kaolin, marble flour and the guar gum.In another preferred embodiment, said natural paint compsn comprises magnetized water, Yelkin TTS, plants essential oil, natural white pigment, color soil, lime powder, talcum powder, kaolin, marble flour and guar gum.
Said natural white pigment can be natural white pigment any in this area, for example, and zinc white, lithopone powder, white titanium pigment, but be preferably white titanium pigment and/or zinc white.
The various combinations of compsn provided by the invention can be placed apart, also can be modulated at together.When being modulated at a time-out, should pack; Perhaps the part component may be combined in together, and for example, natural white pigment, color soil, lime powder, talcum powder, kaolin and marble flour may be combined in together.But a kind of preferred embodiment in, each component is placed apart.
Magnetized water has the effect of multiple mystery in industry, for example, a spot of BW of magnetic field treatment can reduce incrustation scale; Magnetized water is used for the cooling system of various High Temperature Furnaces Heating Apparatuss, has play a part very important for raising evaporation efficiency, prolongation furnace campaign; Magnetized water can be accelerated chemical reaction velocity, improves output.In the present invention, the unexpected magnetized water of finding of contriver can improve the cohesive strength of coating greatly.Said magnetized water can magnetize the water of handling for any warp that adopt this area, for example can select river, the lake water handled through magnetization for use, and drinking public water supply, magnetizes Qin County Zhang Heshui but be preferably.Magnetized water can be through being purchased acquisition, also can oneself preparation, for example with ortho-water through magnetized water machine (for example, the ancient Henkel magnetized water of purple light machine) handle get final product magnetized water.The content of said magnetized water has no particular limits, and its maximum level is when using coating composition provided by the invention, to modulate other component of compsn provided by the invention and do not need to add other water or solvent again with said magnetized water.A kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 30-150 weight part, is preferably the 40-80 weight part.
Any Yelkin TTS that said Yelkin TTS can adopt for this area, but be preferably soybean lecithin, Ovum Gallus domesticus Flavus lecithin, like soybean lecithin (LLF, Beijing Hua Qingmei is permanent), Ovum Gallus domesticus Flavus lecithin (PL-60, Beijing Hua Qingmei is permanent); The content of said natural phosphatidyl choline has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-25 weight part, is preferably the 5-10 weight part.Yelkin TTS has the surfactivity effect, shortens heat-up time, prevents the pigment deposition, increases luminance brightness, avoids layering, increases to cover rate and leveling characteristics, dispersiveness, wettability.
Said plants essential oil can be any plants essential oil, folk prescription essential oil for example, as eucalyptus globolus, tea tree, Rosmarinus officinalis, lavandula angustifolia etc. has strong sterilization effect, perhaps has the santal essential oil of static determinacy effect, perhaps has lemon quintessence oil that purifies air or the like; Compound essential oil, like enhancing immunity system essential oil (BJ9, the green face in Beijing is emerald green to be revealed), conditioning internal secretion essential oil (BJ8-1, the green face in Beijing is emerald green to be revealed).The kind of essential oil can be selected to add according to user's demand.Essential oil must lucifuge be packed separately before use, when using coating composition provided by the present invention, just essential oil is added, and mixes.The content of said plants essential oil has no particular limits; But from cost and effect consider, a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-25 weight part, is preferably the 5-10 weight part.
Any white titanium pigment that said white titanium pigment can adopt for this area, but be preferably sharp titanium white titanium pigment, like HA-100 (Yumen, Gansu), ATA-125 (Anhui An Nada); The content of said white titanium pigment has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 25-100 weight part, is preferably the 30-60 weight part.
The natural zinc white that said zinc white can adopt for this area, but be preferably zinc sulfide white, like good luck source board B301 zinc sulfide white (Shanghai face titanium industry), zinc sulfide white B311 (Shijiazhuang BHP magnesium zinc); The content of said natural zinc white has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-25 weight part, is preferably the 5-10 weight part.
Any natural color scholar that said color soil can adopt for this area, but be preferably the natural color soil in Tibet, like Gangdise active earths (the purple nation in Shanghai chemical industry); The content of said color soil has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-50 weight part, is preferably the 10-20 weight part.
Any natural magnesium calcium powder that said lime powder can adopt for this area, but be preferably the lime rock dust, like 1250 order dicalcium powders (Da Ding mountain, Lishu County); The content of said natural stone ashes has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-25 weight part, is preferably the 5-10 weight part.Lime powder can improve the thixotropy of system greatly, can significantly improve ADHESION OF PAINTS power, abrasion resistance, and contamination resistance improves intensity and surface smoothness, and has the effect of good anti-settling do.
The natural talcum powder that said talcum powder can adopt for this area, but be preferably 1250 order talcum powder, like 1250 order talcum powder (Qixia Hua You); The content of said natural talcum powder has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-25 weight part, is preferably the 5-10 weight part.Talcum powder can play skeleton function as filler, reduces the hardness of paint film that manufacturing cost improves coating simultaneously.
Any kaolin that said kaolin can adopt for this area, but be preferably 1250 order kaolin, like 1250 order kaolin (the emerging industry of Shijiazhuang occasion); Said kaolinic content has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 12-75 weight part, is preferably the 20-30 weight part.Kaolin can improve thixotropy and resistance to settling.
Any Paris white that said marble flour can adopt for this area, but be preferably marble flour is like marble flour (Lingshou County converge prosperous mining industry); The content of said marble flour has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 30-150 weight part, is preferably the 40-80 weight part.Marble flour mainly acts on and serves as packing material.
Any guar gum that said guar gum can adopt for this area, but be preferably cation guar gum, like cation guar gum (Shanghai Sheng Xuan); The content of said guar gum has no particular limits; But a kind of preferred embodiment in, the said kendir natural gum with respect to 100 weight parts can be the 2-25 weight part, is preferably the 5-10 weight part.Consistence, the levelling that guar gum can strengthen coating is capable, abrasion resistance and protect paint film, is difficult for efflorescence, bubble, peels off, the crack.
In order to improve the over-all properties of said coating, a kind of preferred embodiment in, with respect to the said kendir natural gum of 100 weight parts, said Yelkin TTS can be preferably the 5-10 weight part for content is the 2-25 weight part; The content of said lime powder is the 2-25 weight part, is preferably the 5-10 weight part; Said talcous content is the 2-25 weight part, is preferably the 5-10 weight part; Said kaolinic content is the 12-75 weight part, is preferably the 20-30 weight part; The content of said marble flour is the 30-150 weight part, is preferably the 40-80 weight part; The content of said guar gum is the 2-25 weight part, is preferably the 5-10 weight part.
In order further to improve the over-all properties of said coating, in another preferred embodiment, with respect to the said kendir natural gum of 100 weight parts, the content of said magnetized water is the 30-150 weight part, is preferably the 40-80 weight part; The content of said plants essential oil is the 2-25 weight part, is preferably the 5-10 weight part; The content of said white titanium pigment is the 25-100 weight part, is preferably the 30-60 weight part; The content of said zinc white part is the 2-25 weight part, is preferably the 5-10 weight part; The content of said color soil is the 2-50 weight part, is preferably the 10-20 weight part; The content of said Yelkin TTS is the 2-25 weight part, is preferably the 5-10 weight part; The content of said lime powder is the 2-25 weight part, is preferably the 5-10 weight part; Said talcous content is the 2-25 weight part, is preferably the 5-10 weight part; Said kaolinic content is the 12-75 weight part, is preferably the 20-30 weight part; The content of said marble flour is the 30-150 weight part, is preferably the 40-80 weight part; The content of said guar gum is the 2-25 weight part, is preferably the 5-10 weight part;
Compsn provided by the invention can prepare according to prior art, is about to each component and mixes.In use, if the quantity not sufficient that said compsn does not contain magnetized water or the magnetized water that contains when being modulated into slurries, adds entry, said compsn is modulated into slurries.The amount of the magnetized water that contains when said compsn is enough, just directly becomes slurries to get final product other compositional modulation of said compsn with magnetized water.Then with this slurries with surfaces such as brush, cylinder or spray gun brushing plaster, gypsum, planks.
To further specify the present invention through embodiment below, in all embodiment, the apocynum fibre that is adopted is available from the kendir products factory, and passes through break process before use.Broken working method is: apocynum fibre is carried out fragmentation with crusher (HJ lumber fibre crusher, great lucky heavy-duty machinery), and the staple length of acquisition is 0.5~3 millimeter.
Embodiment 1
Kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 50 weight parts and tourmaline powder (150 orders, Lingshi County health care stone source mill) 30 weight parts are mixed, form compsn 1.
Embodiment 2
Kendir natural gum (Heze kendir products factory) 100 weight parts, apocynum fibre (Heze kendir products factory) 100 weight parts and tourmaline powder (3000 orders, Lingshi County health care stone source mill) 20 weight parts are mixed, form compsn 2.
Embodiment 3
With kendir natural gum (Heze kendir products factory) 100 weight parts; Apocynum fibre (Heze kendir products factory) 10 weight parts and tourmaline powder (1250 orders; Lingshi County health care stone source mill) 2 weight, soybean lecithin (LLF; Beijing Hua Qingmei perseverance) 2 weight parts, lime powder (1250 order dicalcium powders, Da Ding mountain, Lishu County) 2 weight parts, talcum powder (1250 order talcum powder, Qixia Hua You) 2 weight parts, kaolin (1250 order kaolin; The emerging industry of Shijiazhuang occasion) 12 weight parts, marble flour (Lingshou County converge prosperous mining industry) 30 weight parts and guar gum (Shanghai Sheng Xuan) 2 weight parts mix, and form compsn 3.
Embodiment 4
With kendir natural gum (Heze kendir products factory) 100 weight parts; Apocynum fibre (Heze kendir products factory) 50 weight parts and tourmaline powder (1250 orders; Lingshi County health care stone source mill) 10 weight parts, soybean lecithin (LLF, Beijing Hua Qingmei is permanent) 25 weight parts, lime powder (1250 order dicalcium powders, Da Ding mountain, Lishu County) 25 weight parts, talcum powder (1250 order talcum powder; Qixia Hua You) 25 weight parts, kaolin (1250 order kaolin; The emerging industry of Shijiazhuang occasion) 75 weight parts, marble flour (Lingshou County converge prosperous mining industry) 150 weight parts and guar gum (Shanghai Sheng Xuan) 25 weight parts, white titanium pigment (HA-100, Yumen, Gansu) 25 weight parts, zinc white (good luck source board B301 zinc sulfide white, Shanghai face titanium industry) 2 weight parts, color soil (Gangdise active earths; The purple nation in Shanghai chemical industry) 2 weight parts mix, and form compsn 4.
Embodiment 5
With kendir natural gum (Heze kendir products factory) 100 weight parts; Apocynum fibre (Heze kendir products factory) 40 weight parts and tourmaline powder (1250 orders; Lingshi County health care stone source mill) 6 weight parts, soybean lecithin (LLF, Beijing Hua Qingmei is permanent) 5 weight parts, lime powder (1250 order dicalcium powders, Da Ding mountain, Lishu County) 10 weight parts, talcum powder (1250 order talcum powder; Qixia Hua You) 5 weight parts, kaolin (1250 order kaolin; The emerging industry of Shijiazhuang occasion) 20 weight parts, marble flour (Lingshou County converge prosperous mining industry) 40 weight parts and guar gum (Shanghai Sheng Xuan) 5 weight parts, white titanium pigment (HA-100, Yumen, Gansu) 100 weight parts, zinc white (good luck source board B301 zinc sulfide white, Shanghai face titanium industry) 25 weight parts, color soil (Gangdise active earths; The purple nation in Shanghai chemical industry) 50 weight parts, magnetized water (Qin County Zhang Heshui; Picking up from the ancient Henkel magnetized water of purple light machine handles) 30 weight parts, enhancing immunity system essential oil (BJ9, the green face in Beijing is emerald green to be revealed) 25 weight parts mix, and form compsn 5.
Embodiment 6
With kendir natural gum (Heze kendir products factory) 100 weight parts; Apocynum fibre (Heze kendir products factory) 20 weight parts and tourmaline powder (1250 orders; Lingshi County health care stone source mill) 2 weight parts, soybean lecithin (LLF, Beijing Hua Qingmei is permanent) 10 weight parts, lime powder (1250 order dicalcium powders, Da Ding mountain, Lishu County) 5 weight parts, talcum powder (1250 order talcum powder; Qixia Hua You) 10 weight parts, kaolin (1250 order kaolin; The emerging industry of Shijiazhuang occasion) 30 weight parts, marble flour (Lingshou County converge prosperous mining industry) 55 weight parts and guar gum (Shanghai Sheng Xuan) 10 weight parts, white titanium pigment (HA-100, Yumen, Gansu) 50 weight parts, zinc white (good luck source board B301 zinc sulfide white, Shanghai face titanium industry) 15 weight parts, color soil (Gangdise active earths; The purple nation in Shanghai chemical industry) 30 weight parts, magnetized water (Qin County Zhang Heshui; Picking up from the ancient Henkel magnetized water of purple light machine handles) 150 weight parts, conditioning internal secretion essential oil (BJ8-1, the green face in Beijing is emerald green to be revealed) 2 weight parts mix, and form compsn 6.
Comparative Examples 1
With water 240 weight parts, EBS451 (Aksu) 2 weight parts, NXZ (Nuo Puke) 1.5 weight parts; Ammoniacal liquor (supporting chemical industry in Jinzhong City) 1.5 weight parts, terepthaloyl moietie (supporting chemical industry in Jinzhong City) 10 weight parts, alcohol ester 12 (Yi Shiman) 5 weight parts; ORATAN1288 (ROHM AND HAAS) 7.5 weight parts, Triton CF-10 (Tao Shi) 2 weight parts, HA-100 white titanium pigment (Yumen, Gansu) 50 weight parts; 1250 order coarse whitings (Baima, Jincheng), 350 weight parts, 1250 order kaolin (sky, Shanghai, Hepu), 137.5 weight parts, 1250 order talcum powder (Jin Yuan peak, Laizhou), 75 weight parts; AS-2010 (ROHM AND HAAS) 100 weight parts, NXZ (Nuo Puke) 1.5 weight parts, HF (Sol) 1.5 weight parts; It is even that TRM203 (Dalian gold ancient cooking vessel auspicious) 5 weight parts (use 2: 1 dilution backs of water) carry out dispersing and mixing, forms comparative composition 1.
Performance test
Compsn to above-mentioned 100 gram embodiment 1-4 is allocated with 200 gram water; 100 gram embodiment 5 restrain water with 6 compsn with 50 and allocate; And the comparative composition 1 of the Comparative Examples 1 of 100 grams; Requirement according to following testing method requires to process model then, carries out the test of splitting resistance performance, the bounding force with base material, thermal conductivity, negative ion concentration, normal direction total emissivity.Splitting resistance and cohesive strength are according to 6.15 carrying out among the JG/T 157-2009; Thermal conductivity is carried out according to GB/T 10294-2008; Negative ion concentration is detected by the negative ion detector; Infrared emittance is carried out according to GB7287.10-87., and the result is as shown in table 1.
Table 1
Annotate: the testing method of negative ion concentration:
With the sample brushing on 0.5 centimetre of cement of 15 cm x, 7 cm x, one week of maintenance, place then in the lens of 30 centimetres of 30 cm x, 30 cm x, leave standstill 1 hour after, with negative ion detector detectable level.
The result of table 1 shows: natural paint compsn provided by the invention is compared with bounding force, resistance to cleavage and the back dope layer that in basic unit, forms of existing coating composition curing between the base material at the coating that forms after the curing; Its bounding force improves 30% at least, and the splitting resistance performance improves 50% at least.In addition, the coating that natural paint compsn provided by the invention forms after curing has lower heat-conduction coefficient, is 50% of general coating, therefore has obvious heat insulation and preservation effect; In a kind of preferred embodiment (coating composition that embodiment 4,5 provides), the negative ion burst size of the coating that coating composition forms after curing reaches the level in countryside, field, can increase human immunological competence and antimicrbial power.