CN108746174A - A kind of ecological elution circuit administered for heavy-metal contaminated soil or slag - Google Patents

A kind of ecological elution circuit administered for heavy-metal contaminated soil or slag Download PDF

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Publication number
CN108746174A
CN108746174A CN201810590079.6A CN201810590079A CN108746174A CN 108746174 A CN108746174 A CN 108746174A CN 201810590079 A CN201810590079 A CN 201810590079A CN 108746174 A CN108746174 A CN 108746174A
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China
Prior art keywords
ecological
slag
contaminated soil
water
soil
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Withdrawn
Application number
CN201810590079.6A
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Chinese (zh)
Inventor
杨崎峰
刘彬
和利钊
郑子健
张海鸥
韩丽杰
覃当麟
赖文学
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Guangxi Bossco Environmental Protection Technology Co Ltd
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Guangxi Bossco Environmental Protection Technology Co Ltd
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Priority to CN201810590079.6A priority Critical patent/CN108746174A/en
Publication of CN108746174A publication Critical patent/CN108746174A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/02Extraction using liquids, e.g. washing, leaching, flotation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/002Reclamation of contaminated soil involving in-situ ground water treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/288Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Soil Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of ecological elution circuit administered for heavy-metal contaminated soil or slag, which is made of irrigation leaching system and biological water purification system, connects to form closed loop through pipeline between irrigation leaching system and biological water purification system;The irrigation leaching system mainly extracts well by pollution-free mellow soil layer, contaminated soil or slag layer and leacheate and constitutes, and pollution-free mellow soil layer is located at the upper surface of contaminated soil or slag layer, and the leacheate extraction well for stretching out outside is provided in contaminated soil or slag layer;The biological water purification system is made of the sedimentation basin, ecological water channel and biological pond being sequentially connected through pipeline, and the water outlet that leacheate extracts well connects with sedimentation basin, the pollution-free mellow soil layer of the outlet end connection irrigation leaching system of biological pond.Low energy consumption for ecology elution circuit processing of the invention, and operation and maintenance are convenient, of low cost, non-secondary pollution.

Description

A kind of ecological elution circuit administered for heavy-metal contaminated soil or slag
Technical field
The invention belongs to environment remediation field, specifically a kind of ecology leaching administered for heavy-metal contaminated soil or slag Wash system.
Background technology
With the continuous quickening of industrialization and urbanization process, China once greatly developed mining, process hides, smelting, plating, burning The industries such as alkali manufacture, waste incineration, sewage irrigation, but the blowdown supervisory system and not perfect, green technology in China during this period It is relatively backward, efficient circulation utilization ratio it is low etc. situations, so as to cause plurality of heavy metal with waste water,waste gas and industrial residue into burying Earth causes the serious heavy metal pollution of soil in China.Heavy metal pollution of soil have concealment, refractory organics, chronicity, can not The characteristics of inverse property, not only results in soil degradation, pollution hydrological environment, and can constantly be accumulated in the ecosystem, reduces agriculture Crop yield and quality threaten health by food chain, or even generate serious Ecological Environment Risk.Therefore, how to have The removing heavy metal-polluted soil of effect by be heavy-metal contaminated soil reparation difficult point.
The restorative procedure of heavy-metal contaminated soil is broadly divided into physical-chemical process and biological restoration, there are commonly solidification/ The technologies such as stabilisation, elution, electro reclamation, thermodynamics reparation, phytoremediation, microorganism remediation.Compared with other recovery techniques, Soil leaching be it is a kind of can be by physical-chemical restorative procedure that heavy metal is removed from soil.Soil leaching refers in fluid Under effect, the pollutant in solid phase of soil is transferred in liquid phase of soil by the desorption dissolution of eluent, then containing dirt Contaminate the technology of the waste water recycling device of object.Soil leaching recovery technique is that an application is strong, can thoroughly remove pollutant, processing Fireballing soil restoring technology, and control expense relative moderate have been widely used in soil remediation improvement, especially suitable In the improvement of heavy-metal contaminated soil.The key of elution technique is to select remediation efficiency high, at low cost and non-secondary pollution Eluent and ELUTION METHOD, at present elution technique have the following problems in the application:
Elution method can neatly use the repair mode of original position or dystopy in practical applications.Dystopy elution is clear first to cut the earth Earth backfills after contaminated soil scrubbed equipment processing, and this method has that strong to the perturbation of soil, quantities is big, pair sets It is standby to require the problems such as high, of high cost.Original position for traditional mode and dystopy elution technique, generally use in lessivation The eluents such as water, acid, alkali, salt, chelating agent, surfactant and compound eluent, can cause soil texture to destroy, and be unfavorable for planting Object is grown, or even causes soil degradation and the secondary pollution of soil;Lessivation generates a large amount of waste liquid simultaneously, increases post-processing Cost.
Invention content
Technical problem to be solved by the invention is to provide a kind of ecologies administered for heavy-metal contaminated soil or slag Elution circuit, the system can make full use of natural precipitation and irrigate water wash contaminated soil, reduce heavy metal in soil content, Achieve the purpose that soil remediation, and does not destroy the soil texture and soil fertility of the pollution-free mellow soil layer on upper layer again.
The present invention solves above-mentioned technical problem with following technical solution:
The ecological elution circuit that the present invention is administered for heavy-metal contaminated soil or slag, it is by irrigation leaching system and life Object water cleaning systems are constituted, and connect to form closed loop through pipeline between irrigation leaching system and biological water purification system;It is described Irrigation leaching system mainly extracts well by pollution-free mellow soil layer, contaminated soil or slag layer and leacheate and constitutes, pollution-free mellow soil Layer is located at the upper surface of contaminated soil or slag layer, and the leacheate extraction well for stretching out outside is provided in contaminated soil or slag layer; The biological water purification system is made of the sedimentation basin, ecological water channel and biological pond being sequentially connected, sedimentation basin, ecological water channel and biology It is connected by pipeline between the pool, the water outlet that leacheate extracts well connects with sedimentation basin, and leaching is irrigated in the water outlet connection of biological pond Wash the pollution-free mellow soil layer of system.
The side wall of pollution-free mellow soil layer of the present invention, the side wall of soil or slag layer and bottom are equipped with HDPE antiseepages Film, the surrounding of the ecology water channel and bottom are equipped with HDPE antiseepage films.
Leacheate of the present invention extracts between the water outlet and sedimentation basin of well, between sedimentation basin and ecological water channel, biology It is separately installed with water pump in connecting pipe between the pool and pollution-free mellow soil layer.
Leacheate extracts in well and sets water level monitor in irrigation leaching system of the present invention.
Being covered with counterweight metal in the HDPE antiseepage films of ecology water channel bottom of the present invention has the clay mineral of adsorption effect Matrix.
Kind, which is implanted with counterweight metal, in ecology water channel and biological pond of the present invention the water plant of suction-operated, ecological water The side slope kind of canal and biological pond is implanted with heavy metal super-enriched plant.
Compared with prior art, the present invention having the advantages that:
1. the principle that ecology elution circuit of the invention is combined using elution in situ and restoration of the ecosystem, can make full use of nature Precipitation and irrigation water wash contaminated soil, reduce heavy metal in soil content, achieve the purpose that soil remediation, and do not destroy The soil texture and soil fertility of the pollution-free mellow soil layer of layer.
2. ecology elution circuit of the invention monitors water level in real time during repairing and treating, avoid water level higher than pollution soil layer Or slag layer, prevent leacheate from polluting mellow soil layer;It is anti-in the surrounding and bottom laying HDPE of pollution soil layer and ecological water channel simultaneously Film is oozed, leacheate soil mobility around is prevented, does not generate secondary pollution.
3. ecology elution circuit of the invention is equipped with bed mud-clay by the ecological water channel bottom in biological water purification system Mineral substrate achievees the effect that purifying water body heavy metal by physics chemical action or surface precipitation;Ecological water channel and life The water plants such as heavy metal super-enriched plant, reed are planted in the object pool, are reduced the effects that plant extract, microorganism are fixed in water Content of beary metal, while revegetation promotes the harmony with periphery ecoscape, in ecology improvement, beautification of landscape etc. hair Wave important function.
4. ecology elution circuit of the invention, using original hollow landform, is not take up additional in implementing operating process Disposal field reduces the perturbation to soil, simplifies construction, and scale of investment is small, economizes the land resource, and restores topography and geomorphology;Ground Shape land restoration and recirculated water make original region for being unfavorable for cultivation restore agricultural productivity on the basis of irrigating;In ecological ditch Canal coordinates biological pond, and is rationally utilized to biological pond, and fishery cultivating or aquatic agricultural are carried out, with good economic efficiency And environmental benefit.
5. the leacheate of ecology elution circuit of the invention by ecological water channel, biological pond purification after recharge to irrigation leaching System realizes recycling.
Description of the drawings
Fig. 1 is the structural schematic diagram for the ecological elution circuit that the present invention is administered for heavy-metal contaminated soil or slag.
In figure:1- is pollution-free mellow soil layer, 2- contaminated soils layer, 3- leacheates extract well, 4-HDPE antiseepage films, 5- water pumps One, 6- sedimentation basins, 7- water pumps two, 8- ecologies water channel, 9- biological ponds, 10- clay minerals matrix, 11- water plants, a 12- huge sum of moneys Belong to super enriching plant, 13- water pumps three.
Specific implementation mode
Technical solution of the present invention is further described below in conjunction with the accompanying drawings.
As shown in Figure 1, the present invention for the ecological elution circuit that heavy-metal contaminated soil or slag are administered is drenched by irrigating System and biological water purification system composition are washed, connects to form closed circulation through pipeline between irrigation leaching system and biological water purification system Circuit.The irrigation leaching system is mainly extracted by pollution-free mellow soil layer 1, contaminated soil layer 2 (or being slag layer) and leacheate Well 3 is constituted, and pollution-free mellow soil layer 1 is located at the upper surface of contaminated soil layer 2, and the elution for stretching out outside is provided in contaminated soil layer 2 Liquid extracts well 3.The biological water purification system is made of sedimentation basin 6, ecological water channel 8 and biological pond 9, sedimentation basin 6, ecological water channel 8 It is connected by pipeline with biological pond 9, the water outlet that leacheate extracts well 3 is connected with sedimentation basin 6, the outlet end of biological pond 9 Pollution-free mellow soil layer 1 is connected, to realize that purification Water Spreading utilizes.
The side wall of pollution-free mellow soil layer 1 of the present invention, the side wall of contaminated soil layer 2 and bottom are equipped with HDPE antiseepage films 4, the surrounding of ecological water channel 8 and bottom are equipped with HDPE antiseepage films 4.
Leacheate of the present invention extracts and is equipped with water pump one in the connecting pipe between the water outlet and sedimentation basin 6 of well 3 5, water pump 27 is installed in the connecting pipe between sedimentation basin 6 and ecological water channel 8, the water outlet of biological pond 9 is connected through pipeline to be filled The pollution-free mellow soil layer 1 for irrigating elution circuit is equipped with water pump 3 13 on the pipeline, handled in biological pond 9 it is up to standard after water it is logical Water pump 3 13 is crossed through pipeline recharge to pollution-free mellow soil layer 1, forms closed loop system.
Leacheate of the present invention extracts in well 3 and sets water level monitor, for monitoring level of ground water in real time, to avoid water level It is excessively high to influence pollution-free mellow soil layer 1.
Being covered with counterweight metal in the HDPE antiseepage films of 8 bottom of ecology water channel of the present invention has the clay mineral of adsorption effect Matrix 10, the clay mineral matrix 10 are one or more in zeolite, concave convex rod, montmorillonite, illite etc..
Kind, which is implanted with counterweight metal, in ecology water channel 8 and biological pond 9 of the present invention the water plant 11 of suction-operated, such as The water plants such as reed.In the side slope of ecological water channel 8 and biological pond 9 kind be implanted with heavy metal super-enriched plant 12, as Viola baoshanensis, The heavy metal super-enriched plants such as roundleaf penny cress, Phytolacca acinosa, ciliate desert-grass, Sedum alfredii Hance, glossy privet.
The course of work of the present invention for the ecological elution circuit that heavy-metal contaminated soil or slag are administered is as follows:
(1) after natural precipitation or irrigation water enter pollution-free mellow soil layer 1, undergoing hydrodynamic action will be in contaminated soil layer 2 Pollutant is eluted out;When monitoring water level close to before pollution-free mellow soil layer 1, by controlling water pump 1, by leacheate from extraction Extraction enters sedimentation basin 6 in well 3;
(2) leacheate enters ecological water channel 8, ecological water by sedimentation basin 6, the water pump 27 in biological water purification system successively Purification of water quality reaches in canal 8《Water environment quality standard》(GB 3838-2002) enters biological pond 9 afterwards;
(3) water outlet of biological pond 9 reaches《Agricultural irrigation water quality standard》(GB 5084-2005) passes through the water in recharge system Pump 3 13 and pipeline recharge to irrigation leaching system pollution-free mellow soil layer 1;
(4) system operation for a period of time after, by through purification it is up to standard after irrigation water extract out, by recharge system for again Secondary irrigation;
(5) step (1), (2), (3), (4) are repeated.
The present invention makes leacheate reduce particle content in leacheate through precipitation by the way that sedimentation basin 6 is arranged;Pass through life The absorption of the clay mineral matrix counterweight physical chemistry of metal of state water channel 10, and pass through water plant 11 and heavy metal super-enriched Plant 12 reaches the effect to purify water to heavy metal in the plant absorption effect of heavy metal and rhizosphere microbial effect trap water Fruit.
Biological pond 9 of the present invention can carry out aquaculture or aquatic agricultural;It is raw in the ecology water channel 8, biological pond 9 Long reed and heavy metal super-enriched plant need to gather in storage in time;The plant tissue of collection and ecological water channel midsole mud are according to ring Guarantor portion requires to do harmless treatment.
Using the application example of ecological elution circuit of the invention:
Heavy metal in soil cadmium content 45.67mg/kg, heavy metal zinc content 587.21mg/kg, heavy metal lead contain before processing Measure 2541.35mg/kg, heavy metal chromium content 78.36mg/kg.After cycling elution system of the present invention processing, heavy metal in soil Cadmium content 3.93mg/kg, heavy metal zinc content 54.61mg/kg, content of heavy metal lead 190.60mg/kg, heavy metal chromium content 5.41mg/kg, heavy metal cadmium, zinc, lead, chromium removal rate be respectively 91.4%, 90.7%, 92.5%, 93.1%.
As it can be seen that after carrying out cycling elution using the ecological elution circuit of the present invention, containing for pollutant in soil is significantly reduced Amount;Pollution-free mellow soil layer can plant the plants such as vegetation simultaneously, and reed and Phytolacca acinosa, red-spotted stonecrop etc. are planted in ecological water channel and biological pond Heavy metal super-enriched plant can cultivate aquatic animal in ecological water channel and biological pond, increase vegetation coverage and biology be more Sample is beneficial to beautify local landscape and improve the ecological environment.

Claims (6)

1. a kind of ecological elution circuit administered for heavy-metal contaminated soil or slag, it is characterised in that:It is by irrigation leaching System and biological water purification system are constituted, and connect to form closed circulation time through pipeline between irrigation leaching system and biological water purification system Road;The irrigation leaching system mainly extracts well by pollution-free mellow soil layer, contaminated soil or slag layer and leacheate and constitutes, no dirt Dye mellow soil layer is located at the upper surface of contaminated soil or slag layer, and the leacheate pumping for stretching out outside is provided in contaminated soil or slag layer Take well;The biological water purification system is made of the sedimentation basin, ecological water channel and biological pond being sequentially connected, sedimentation basin, ecological water channel It is connected by pipeline between biological pond, the water outlet that leacheate extracts well connects with sedimentation basin, the water outlet connection of biological pond The pollution-free mellow soil layer of irrigation leaching system.
2. being used for the ecological elution circuit that heavy-metal contaminated soil or slag are administered according to claim 1, it is characterised in that: The side wall of the pollution-free mellow soil layer, the side wall of soil or slag layer and bottom are equipped with HDPE antiseepage films, the ecology water channel Surrounding and bottom be equipped with HDPE antiseepage films.
3. the ecological elution circuit according to claim 1 or claim 2 administered for heavy-metal contaminated soil or slag, feature exist In:The leacheate extracts between the water outlet and sedimentation basin of well, between sedimentation basin and ecological water channel, biological pond with it is pollution-free ripe It is separately installed with water pump in connecting pipe between soil layer.
4. the ecological elution circuit according to claim 1 or claim 2 administered for heavy-metal contaminated soil or slag, feature exist In:Leacheate extracts in well and sets water level monitor in the irrigation leaching system.
5. being used for the ecological elution circuit that heavy-metal contaminated soil or slag are administered according to claim 2, it is characterised in that: Being covered with counterweight metal in the HDPE antiseepage films of the ecology water channel bottom has the clay mineral matrix of adsorption effect.
6. the ecological elution circuit according to claim 1 or claim 2 administered for heavy-metal contaminated soil or slag, feature exist In:Kind, which is implanted with counterweight metal, in the ecology water channel and biological pond the water plant of suction-operated, ecological water channel and biological pond Side slope kind be implanted with heavy metal super-enriched plant.
CN201810590079.6A 2018-06-08 2018-06-08 A kind of ecological elution circuit administered for heavy-metal contaminated soil or slag Withdrawn CN108746174A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110883080A (en) * 2019-12-20 2020-03-17 河北工业大学 Soil heavy metal in-situ sensing monitoring, adsorption transfer and precipitation recovery system
CN111204902A (en) * 2020-02-21 2020-05-29 广西博世科环保科技股份有限公司 Closed tailing pond and pollution prevention and control ecological system and control method thereof
CN111346913A (en) * 2020-03-31 2020-06-30 山东省环境保护科学研究设计院有限公司 Plant-microorganism comprehensive remediation system for polluted soil and underground water
CN115846397A (en) * 2022-12-30 2023-03-28 中铁环境科技工程有限公司 Mine soil remediation method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110883080A (en) * 2019-12-20 2020-03-17 河北工业大学 Soil heavy metal in-situ sensing monitoring, adsorption transfer and precipitation recovery system
CN111204902A (en) * 2020-02-21 2020-05-29 广西博世科环保科技股份有限公司 Closed tailing pond and pollution prevention and control ecological system and control method thereof
CN111346913A (en) * 2020-03-31 2020-06-30 山东省环境保护科学研究设计院有限公司 Plant-microorganism comprehensive remediation system for polluted soil and underground water
CN115846397A (en) * 2022-12-30 2023-03-28 中铁环境科技工程有限公司 Mine soil remediation method
CN115846397B (en) * 2022-12-30 2023-09-08 中铁环境科技工程有限公司 Mine soil restoration method

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