CN108719341A - Efficiently solve the preparation method of the conditioning agent of plant droop - Google Patents

Efficiently solve the preparation method of the conditioning agent of plant droop Download PDF

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CN108719341A
CN108719341A CN201810401871.2A CN201810401871A CN108719341A CN 108719341 A CN108719341 A CN 108719341A CN 201810401871 A CN201810401871 A CN 201810401871A CN 108719341 A CN108719341 A CN 108719341A
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conditioning agent
preparation
plant
parts
added
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汪珂
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Jinhua Jing He Technology Co Ltd
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Jinhua Jing He Technology Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/10—Apiaceae or Umbelliferae [Carrot family], e.g. parsley, caraway, dill, lovage, fennel or snakebed
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C9/00—Fertilisers containing urea or urea compounds
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Abstract

The invention discloses the preparation methods of the efficient conditioning agent for solving plant droop, organic phase and water phase are prepared respectively, mix to obtain lotion, potassium peroxydisulfate is added and reacts to obtain microgel, separately triacontanol, 6- benzylaminopurines, heteroauxin, compound sodium nitrophenolate, thiocarbamide, celery root extract, peptide ferrous chelate compound, Bravo, avermectin, the basic element of cell division, gibberellin, urea, fulvic acid solution, compound amino acid is taken to mix to obtain conditioning agent, microgel is added in conditioning agent, obtains the conditioning agent for efficiently solving plant droop.It has the beneficial effect that：Conditioning agent sprays, be applied to plant surface after, one layer of conditioning agent hydrogel thin film can be formed in plant surface, transpiration can not only be prevented, also there is slow releasing function, the content of celery root extract and purity are higher in conditioning agent, the bactericidal effect of conditioning agent is significantly increased, peptide ferrous chelate compound can provide source of iron and amino acid for plant.

Description

Efficiently solve the preparation method of the conditioning agent of plant droop
Technical field
The present invention relates to plant modifying agent fields, more particularly, to the preparation side of the efficient conditioning agent for solving plant droop Method.
Technical background
Droop（blight）Also known as epidemic disease, the plant disease being led to by fungi or bacterium, morbidity is unexpected, and symptom includes tight The death of the stigma, wilting or leaf, flower, fruit, stem or whole plant of weight.Rapid tender tissue is grown often to be invaded.It is most of Important Economic crop is infected by one or more epidemic diseases.Epidemic disease can influence flower, leaf, bud packet, seedling, sprig, stem (rattan) and top The tip.Temperature is most sensitive one of the environmental condition of crop growth, and temperature is to influence crop production, limit its Regional Distribution Main Factors.Global greenhouse effects constantly aggravate in recent years, it is predicted that China various regions heat amplitude and will be apparently higher than entirely Ball, entire planting industry will face severe challenge.Late 1980s, south China citrus producing region are subjected to 3 times a wide range of high Warm tide causes huge economic loss.Pathogenic bacteria cause withered wither with hyperthermia induced to threaten the growth of plant simultaneously, rapid, The efficient plant droop that solves becomes particularly important.
Invention content
The purpose of the present invention is to provide the preparation method of the efficient conditioning agent for solving plant droop, conditioning agent sprays, After being applied to plant surface, one layer of conditioning agent hydrogel thin film can be formed in plant surface, can not only prevent transpiration, also have Slow releasing function, the content of celery root extract is higher with purity in conditioning agent, significantly increases the bactericidal effect of conditioning agent, and peptide is ferrous Chelate can provide source of iron and amino acid for plant.
The present invention is directed to the problem of being mentioned in background technology, and the technical solution taken is：
The preparation method for efficiently solving the conditioning agent of plant droop, specifically includes following steps：
S1：Take 0.18~0.20 part of Span-80,0.05~0.08 part of Tween-85, the double propyl acyls of 1.5~1.8 parts of N-N dimethyl Amine and 55~59 portions of normal heptanes are added in container, are persistently blasted nitrogen, are stirred under 1200~1300r/min rotating speeds Organic phase；Separately 2~5 parts of sodium alginates is taken to be added in 95~98 parts of distilled water, 14~15 parts of acryloyls are added after mixing Amine forms uniform water phase；Water phase is slowly added into organic phase, stirring 30~45min with 800~1000r/min obtains One lotion；Stopping is passed through nitrogen, and emulsion system is placed in 38~42 DEG C of water-bath system, and 1~1.2 ‰ parts of over cure is added Sour potassium stirs 2~4h of polymerization with 280~300r/min rotating speeds, 1.5~2 ‰ hydroquinone is added to terminate polymerisation；Add Enter isometric acetone, after being slowly stirred mixing, 5~8min is centrifuged with 5000~5800r/min speed, successively uses acetone, second Alcohol washs to obtain microgel；The microgel uniformity is good, and its water solubility, gelling, promotees permeability, biocompatibility and to drop Xie Xingjun is more excellent, can be as the carrier of growth regulator, and hydrogel can absorb a large amount of moisture content, in plant table Skin formed one layer of diaphragm, substantially reduce the transpiration on plant leaf blade surface, be effectively relieved plant water shortage, evaporation and caused by Dehydration wilt phenomenon；
S2：Weigh 0.2~0.4 part of triacontanol, 0.02~0.03 part of 6- benzylaminopurine, 0.01~0.012 part of indoles second Acid, 1.5~1.8 parts of compound sodium nitrophenolates, 0.5~0.8 part of thiocarbamide, 5~10 parts of celery root extracts, 0.2~2.0 part of peptide ferrous iron chelating Object, 0.2~0.5 part of Bravo, 0.2~0.6 part of avermectin, 0.3~0.5 part of basic element of cell division, 0.04~0.08 part it is red mould Above-mentioned substance, is dissolved in 300~380 part 5.8~7.0% of fulvic acid solution, then again by element and 3~10 parts of urea successively 2~10 parts of compound amino acids are added, stir and are uniformly mixed up to conditioning agent；It causes a disease containing efficiently inhibition droop in conditioning agent The effectiveness ingredient of bacterium can carry out pathogenic bacteria rapid, efficient killing, can not only reduce cell wall secreted by pathogenic bacteria and drop The activity for solving enzyme can also destroy the balance of pathogenic bacteria protection enzyme system, so that pathogen is damaged and is destroyed, substantially reduce withered The pathogenecity of disease of withering pathogen；Conditioning agent can also reduce Stomatal complexes, reduce moisture transpiration, make plant and soil conservation compared with More moisture forms pesticide-fulvic acid compound by physics chemical action and pesticide, can both reduce toxicity of pesticide, reduce agriculture Survival dose improves pesticide efficacy, improves the safety to people and animals, and can reduce environmental pollution, and complexing trace element improves plant Absorption to trace element and running ability, while cell growth can be also effectively facilitated, accelerate cell division, chlorophyll is promoted to close At the extension yellow time avoids plant withered；
S3：Under half-light, 1~2 DEG C of temperature condition, growth regulator is poured slowly into microgel, growth regulator is coagulated with micro- The mass ratio of glue is 1:2.5~3.5, microgel is stirred with the slow-speed of revolution of 200~250r/min when pouring into, is after mixing Obtain the conditioning agent for efficiently solving plant droop；By conditioning agent by spraying, being applied to plant surface after, can in plant surface shape At one layer of conditioning agent hydrogel thin film, film not only has water proof, anti-steaming effect to plant surface, reduces the moisture content on plant surface Evaporation, while can also make the growth regulator slow release in conditioning agent hydrogel thin film, the performance for keeping conditioning agent lasting subtracts steaming Effect and sterilization functions, while the effect for the cell growth that can also effectively accelerate the failure accelerate cell division, avoid cell bad Dead phenomenon is continuous worsening, can efficiently and rapidly kill droop pathogenic bacteria, solves plant droop, promotes plant failure thin Born of the same parents' fast-growth.
Preferably, the extracting method of celery root extract is：In 8~10 leaf phase of celery, celery is randomly selected, fresh quench is taken to wash Only, it is cut into after the segment that length is 1~1.5cm according to 1g:The amount of 2~5mL is soaked into absolute ethyl alcohol, and oscillation 18 under room temperature~ For 24 hours, it is then crossed with crocus cloth and filters out residue, then fungi is filtered off up to mother liquor with sterilizing filter；Using absolute ethyl alcohol as eluent Leaching liquor mother liquor is detached using silica gel column chromatography, it is 100~150 μm that stationary phase, which selects silica gel, silica gel grain size, chromatography Obtain celery root extract；Celery root extract can inhibit the activity of the cell wall degrading enzyme secreted by Pathogen of Fusarium Wilt, to drop Low pathogen decomposes the ability of cell wall, and it is original that celery root extract can also break Pathogen of Fusarium Wilt internal protection enzyme system Equilibrium state, so that it is reduced the Scavenging activity of active oxygen, Free-radical ring opening polymerization caused obstacle, H occur2O2A large amount of accumulation, Somatic cells film is destroyed, pathogen is made to be damaged and destroy, substantially reduces the pathogenecity of Pathogen of Fusarium Wilt.
Contain 1~1.2% in absolute ethyl alcohol during extracting celery root extract as to present invention further optimization 2- amino-5-fluorines pyridine and 0.3~0.4 ‰ (-)-sparteine；During extracting celery root extract, micro and special proportioning 2- amino-5-fluorines pyridine and (-)-sparteine can effectively destroy the cell wall of celery rhizosphere cell, celery root can be made The protein of border cell wall crosslinks degradation, to destroy cell wall, makes dissolution of cellular content, greatly increases content The extraction rate of effective antibacterial substance in object, while extraction time can also be shortened, extraction power consumption is reduced, effective bateriostatics are improved The content and purity of matter, to enhance control effect of the conditioning agent to plant droop.
Preferably, the preparation method of peptide ferrous chelate compound is：By the collagen peptide solution after enzymolysis through low The peptide liquid that solid content is 25~30% is obtained after temperature is dry, adjusts pH value to 7.1~7.15, and 2.0~2.3 times a concentration of is added The FeCl of 0.3~0.5mol/L2Solution adds the compound auxiliary of collagen peptide solution dry matter amount 0.1~0.15 ‰, 1~2h of concussion chelating at a temperature of 20~22 DEG C, chelating liquid is centrifuged at a temperature of 1~2 DEG C with 12000~12500r/min rotating speeds 15~20min is concentrated, supernatant is taken to be concentrated in vacuo, up to peptide ferrous chelate compound after freeze-drying；Collagen peptide chelates Ferrous chelation percent is higher, and chelate is relatively stablized, and the disadvantages such as inorganic molysite stability is poor, bioavailability is low are not only avoided, It is easy to be absorbed by plant, stable ferrous ion is provided for plant, the synthesis of plant chlorophyll, while fish-skin can be accelerated Collagen peptide can supplement amino acid needed for body, be a kind of efficient ferrous tonic and amino acid supplements.
It is advanced optimized as to the present invention, the substance of following content is contained in compound auxiliary：70~80% Vitamin C Acid, 20~30% malic acid and D- amphetamines mixture, the mass ratio of malic acid and D- amphetamines is 10~12:1；Chelating In reaction process, D- amphetamines can largely react with the oxidant in chelating systems with ascorbic acid, from And reduce the accounting that oxidant is precipitated oxidation of ferrous iron to brown di-iron trioxide, keep chelating systems in ferrous iron from The sufficient content of son；In addition, under the conditions of existing for malic acid, D- amphetamines can be with the S in chelating environment2-Ion generation is matched Position is complexed and generates stable complex, reduces the S in chelating environment2-Content avoids S2-With the Fe in stable chelate2 +It reacts, to prevent the dissociation of stable chelate, contributes to the generation of the chelating ferrous compound of collagen peptide, The content and purity for improving the chelating ferrous compound of collagen peptide, it is the ferrous iron for the stabilization that plant provides to increase The amount of ion greatly speeds up the synthesis of plant chlorophyll, promotes plant failure cell fast-growth.
Compared with the prior art, the advantages of the present invention are as follows：
1）During extracting celery root extract, the 2- amino-5-fluorines pyridine of micro and special proportioning and (-)-sparteine can be with So that the protein of celery rhizosphere cell wall is crosslinked degradation, to destroy cell wall, makes dissolution of cellular content, significantly Increase the extraction rate of effective antibacterial substance, shorten extraction time, reduce extraction power consumption, improve the content of effective antibacterial substance with Purity, to enhance control effect of the conditioning agent to plant droop；
2）The chelating ferrous chelation percent of collagen peptide is higher, and chelate is relatively stablized, and not only avoids inorganic molysite stabilization The disadvantages such as property is poor, bioavailability is low, are easy to be absorbed by plant, stable ferrous ion are provided for plant, can accelerate to plant The synthesis of object chlorophyll, while collagen peptide can supplement amino acid needed for body；
3）In the preparation process of peptide ferrous chelate compound, D- amphetamines and ascorbic acid can largely in chelating systems Oxidant react, to reduce the accounting that oxidant is precipitated oxidation of ferrous iron to brown di-iron trioxide, protect Hold the sufficient content of ferrous ion in chelating systems；
4）Under the conditions of existing for malic acid, D- amphetamines can reduce the S in chelating environment2-Content avoids S2-With Fe2+ It reacts, to prevent the dissociation of stable chelate, contributes to the generation of the chelating ferrous compound of collagen peptide, carry Its high content and purity, greatly speed up the synthesis of plant chlorophyll, promote plant failure cell fast-growth.
Specific implementation mode
The present invention program is described further below by embodiment：
Embodiment 1：
The preparation method for efficiently solving the conditioning agent of plant droop, specifically includes following steps：
S1：0.18 part of Span-80,0.05 part of Tween-85, the double propyl amides of 1.5 parts of N-N dimethyl and 55 portions of normal heptanes are taken to be added Into container, nitrogen is persistently blasted, organic phase is stirred to obtain under 1200r/min rotating speeds；Separately 2 parts of sodium alginates is taken to be added to In 95 parts of distilled water, 14 parts of acrylamides are added after mixing, form uniform water phase；Water phase is slowly added into organic phase In, uniform lotion is obtained with 800r/min stirrings 30min；Stopping is passed through nitrogen, emulsion system is placed in 38 DEG C of water-bath system In, 1 ‰ parts of potassium peroxydisulfate is added, polymerization 2h is stirred with 280r/min rotating speeds, 1.5 ‰ hydroquinone is added to terminate polymerization Reaction；Isometric acetone is added, after being slowly stirred mixing, 5min is centrifuged with 5000r/min speed, successively uses acetone, ethyl alcohol Wash to obtain microgel；
S2：Weigh 0.2 part of triacontanol, 0.02 part of 6- benzylaminopurine, 0.01 part of heteroauxin, 1.5 parts of compound sodium nitrophenolates, 0.5 part of thiocarbamide, 5 parts of celery root extracts, 0.2 part of peptide ferrous chelate compound, 0.2~0.5 part of Bravo, 0.2 part of avermectin, 0.3 Above-mentioned substance, is dissolved in 300 part 5.8% of fulvic acid solution by part basic element of cell division, 0.04 part of gibberellin and 3 parts of urea successively In, 2 parts of compound amino acids are then added, stirs and is uniformly mixed up to conditioning agent；
S3：Under half-light, 1 DEG C of temperature condition, growth regulator is poured slowly into microgel, growth regulator and microgel Mass ratio is 1:2.5, microgel is stirred with the slow-speed of revolution of 200r/min when pouring into, after mixing up to efficiently solution plant The conditioning agent of droop；By conditioning agent by spraying, being applied to plant surface after, can plant surface formed one layer of conditioning agent water Gel film, film not only have water proof, anti-steaming effect to plant surface, reduce the moisture evaporation on plant surface, while may be used also The growth regulator slow release in conditioning agent hydrogel thin film, the performance for keeping conditioning agent lasting is set to subtract steaming effect and make with sterilizing With, while the effect for the cell growth that can also effectively accelerate the failure, accelerate cell division, cell necrosis phenomenon is avoided persistently to dislike Change, can efficiently and rapidly kill droop pathogenic bacteria, solve plant droop, promotes plant failure cell fast-growth.
Embodiment 2：
The preparation method for efficiently solving the conditioning agent of plant droop, specifically includes following steps：
S1：0.20 part of Span-80,0.08 part of Tween-85, the double propyl amides of 1.8 parts of N-N dimethyl and 59 portions of normal heptanes are taken to be added Into container, nitrogen is persistently blasted, organic phase is stirred to obtain under 1300r/min rotating speeds；Separately 5 parts of sodium alginates is taken to be added to In 98 parts of distilled water, 15 parts of acrylamides are added after mixing, form uniform water phase；Water phase is slowly added into organic phase In, uniform lotion is obtained with 1000r/min stirrings 45min；Stopping is passed through nitrogen, emulsion system is placed in 42 DEG C of water-bath system In, 1.2 ‰ parts of potassium peroxydisulfate is added, polymerization 4h is stirred with 300r/min rotating speeds, 2 ‰ hydroquinone is added to terminate polymerization Reaction；Isometric acetone is added, after being slowly stirred mixing, 8min is centrifuged with 5800r/min speed, successively uses acetone, ethyl alcohol Wash to obtain microgel；The microgel uniformity is good, and its water solubility, gelling, promotees permeability, biocompatibility and degradable Property is more excellent, can be as the carrier of growth regulator, and hydrogel can absorb a large amount of moisture content, in plant epidermis Formed one layer of diaphragm, substantially reduce the transpiration on plant leaf blade surface, be effectively relieved plant water shortage, evaporation and caused by lose Water wilt phenomenon；
S2：In the 10 leaf phase of celery, celery is randomly selected, fresh quench is taken to clean, is cut into after the segment that length is 1.5cm according to 1g:5mL Amount be soaked into absolute ethyl alcohol, vibrated under room temperature for 24 hours, then crossed with crocus cloth and filter out residue, then filtered off with sterilizing filter true Bacterium is up to mother liquor；Leaching liquor mother liquor is detached using silica gel column chromatography using absolute ethyl alcohol as eluent, stationary phase is selected Silica gel, silica gel grain size are 150 μm, chromatograph to obtain celery root extract；Celery root extract can inhibit secreted by Pathogen of Fusarium Wilt The activity of cell wall degrading enzyme, to reduce the ability that pathogen decomposes cell wall, celery root extract can also be broken withered The sick original equilibrium state of pathogen internal protection enzyme system makes it reduce the Scavenging activity of active oxygen, causes free radical clear Except there is obstacle, H in system2O2A large amount of accumulation, destroy somatic cells film, pathogen are made to be damaged and destroy, substantially reduce withered The pathogenecity of disease of withering pathogen；
S3：Weigh 0.4 part of triacontanol, 0.03 part of 6- benzylaminopurine, 0.012 part of heteroauxin, 1.8 parts of compound sodium nitrophenolates, 0.8 part of thiocarbamide, 10 parts of celery root extracts, 2 parts of peptide ferrous chelate compounds, 0.5 part of Bravo, 0.6 part of avermectin, 0.5 part of cell Above-mentioned substance, is dissolved in 380 part 7.0% of fulvic acid solution, so by mitogen, 0.08 part of gibberellin and 10 parts of urea successively After add 10 parts of compound amino acids, stir and be simultaneously uniformly mixed up to conditioning agent；It is caused containing efficiently inhibition droop in conditioning agent The effectiveness ingredient of germ can carry out pathogenic bacteria rapid, efficient killing, can not only reduce cell wall secreted by pathogenic bacteria The activity of degrading enzyme can also destroy the balance of pathogenic bacteria protection enzyme system, so that pathogen is damaged and is destroyed, substantially reduce The pathogenecity of Pathogen of Fusarium Wilt；Conditioning agent can also reduce Stomatal complexes, reduce moisture transpiration, make plant and soil conservation More moisture forms pesticide-fulvic acid compound by physics chemical action and pesticide, can both reduce toxicity of pesticide, reduce Pesticide dosage improves pesticide efficacy, improves the safety to people and animals, and can reduce environmental pollution, and complexing trace element is improved and planted Absorption and running ability of the object to trace element, while cell growth can be also effectively facilitated, accelerate cell division, promotes chlorophyll Synthesis extends the yellow time, avoids plant withered；
S4：Under half-light, 2 DEG C of temperature conditions, growth regulator is poured slowly into microgel, growth regulator and microgel Mass ratio is 1:3.5, microgel is stirred with the slow-speed of revolution of 250r/min when pouring into, after mixing up to efficiently solution plant The conditioning agent of droop；By conditioning agent by spraying, being applied to plant surface after, can plant surface formed one layer of conditioning agent water Gel film, film not only have water proof, anti-steaming effect to plant surface, reduce the moisture evaporation on plant surface, while may be used also The growth regulator slow release in conditioning agent hydrogel thin film, the performance for keeping conditioning agent lasting is set to subtract steaming effect and make with sterilizing With, while the effect for the cell growth that can also effectively accelerate the failure, accelerate cell division, cell necrosis phenomenon is avoided persistently to dislike Change, can efficiently and rapidly kill droop pathogenic bacteria, solve plant droop, promotes plant failure cell fast-growth.
Embodiment 3：
The preparation method for efficiently solving the conditioning agent of plant droop, specifically includes following steps：
S1：0.2 part of Span-80,0.05 part of Tween-85, the double propyl amides of 1.5 parts of N-N dimethyl and 58 portions of normal heptanes are taken to be added Into container, nitrogen is persistently blasted, organic phase is stirred to obtain under 1200r/min rotating speeds；Separately 4 parts of sodium alginates is taken to be added to In 95 parts of distilled water, 14 parts of acrylamides are added after mixing, form uniform water phase；Water phase is slowly added into organic phase In, uniform lotion is obtained with 900r/min stirrings 30min；Stopping is passed through nitrogen, emulsion system is placed in 40 DEG C of water-bath system In, 1.1 ‰ parts of potassium peroxydisulfate is added, polyase 13 h is stirred with 280r/min rotating speeds, the hydroquinone of addition 1.5 ‰ is poly- to terminate Close reaction；Isometric acetone is added, after being slowly stirred mixing, 6min is centrifuged with 5500r/min speed, successively uses acetone, second Alcohol washs to obtain microgel；The microgel uniformity is good, and its water solubility, gelling, promotees permeability, biocompatibility and to drop Xie Xingjun is more excellent, can be as the carrier of growth regulator, and hydrogel can absorb a large amount of moisture content, in plant table Skin formed one layer of diaphragm, substantially reduce the transpiration on plant leaf blade surface, be effectively relieved plant water shortage, evaporation and caused by Dehydration wilt phenomenon；
S2：Weigh 0.3 part of triacontanol, 0.02 part of 6- benzylaminopurine, 0.01 part of heteroauxin, 1.8 parts of compound sodium nitrophenolates, 0.6 part of thiocarbamide, 8 parts of celery root extracts, 1.5 parts of peptide ferrous chelate compounds, 0.4 part of Bravo, 0.5 part of avermectin, 0.4 part of cell Above-mentioned substance, is dissolved in 350 part 6% of fulvic acid solution, then again by mitogen, 0.06 part of gibberellin and 6 parts of urea successively 6 parts of compound amino acids are added, stir and are uniformly mixed up to conditioning agent；Contain efficiently inhibition droop pathogenic bacteria in conditioning agent Effectiveness ingredient can carry out pathogenic bacteria rapid, efficient killing, can not only reduce cell wall degrading enzyme secreted by pathogenic bacteria Activity, can also destroy pathogenic bacteria protection enzyme system balance, so that pathogen is damaged and is destroyed, substantially reduce droop The pathogenecity of pathogen；Conditioning agent can also reduce Stomatal complexes, reduce moisture transpiration, keep plant and soil conservation more Moisture forms pesticide-fulvic acid compound by physics chemical action and pesticide, can both reduce toxicity of pesticide, reduce pesticide use Amount improves pesticide efficacy, improves the safety to people and animals, and can reduce environmental pollution, and complexing trace element improves plant to micro- The absorption of secondary element and running ability, while cell growth can be also effectively facilitated, accelerate cell division, promote Chlorophyll synthesis, Extend the yellow time, avoids plant withered；
S3：Under half-light, 1 DEG C of temperature condition, growth regulator is poured slowly into microgel, growth regulator and microgel Mass ratio is 1:3, microgel is stirred with the slow-speed of revolution of 240r/min when pouring into, it is withered up to plant is efficiently solved after mixing The conditioning agent for disease of withering；By conditioning agent by spraying, being applied to plant surface after, can plant surface formed one layer of conditioning agent water-setting Glue film, film not only have water proof, anti-steaming effect to plant surface, reduce the moisture evaporation on plant surface, while can also make Growth regulator slow release in conditioning agent hydrogel thin film, the performance for keeping conditioning agent lasting subtract steaming effect and sterilization functions, The effect for the cell growth that can also effectively accelerate the failure simultaneously accelerates cell division, avoids cell necrosis phenomenon continuous worsening, Droop pathogenic bacteria can be efficiently and rapidly killed, plant droop is solved, promote plant failure cell fast-growth.
The extracting method of celery root extract is：In the 8 leaf phase of celery, celery is randomly selected, takes fresh quench to clean, being cut into length is According to 1g after the segment of 1cm:The amount of 3mL is soaked into absolute ethyl alcohol, and 20h is vibrated under room temperature, is then crossed with crocus cloth and filters out residue, Fungi is filtered off up to mother liquor with sterilizing filter again；Utilize silica gel column chromatography to leaching liquor mother liquor by eluent of absolute ethyl alcohol It is detached, it is 100 μm that stationary phase, which selects silica gel, silica gel grain size, chromatographs to obtain celery root extract；Celery root extract can inhibit withered The activity of cell wall degrading enzyme secreted by disease of withering pathogen, to reduce the ability that pathogen decomposes cell wall, celery root Extract can also break the original equilibrium state of Pathogen of Fusarium Wilt internal protection enzyme system, make its Scavenging activity to active oxygen It reduces, Free-radical ring opening polymerization is caused obstacle, H occur2O2A large amount of accumulation, destroy somatic cells film, pathogen are made to be damaged And destruction, substantially reduce the pathogenecity of Pathogen of Fusarium Wilt.
During extracting celery root extract, (-)-gold containing 1% 2- amino-5-fluorines pyridine and 0.3 ‰ in absolute ethyl alcohol Sparrow spends alkali；During extracting celery root extract, 2- amino-5-fluorines pyridine and (-)-sparteine energy of micro and special proportioning The effective cell wall for destroying celery rhizosphere cell, can make the protein of celery rhizosphere cell wall crosslink degradation, To destroy cell wall, make dissolution of cellular content, greatly increase the extraction rate of effective antibacterial substance in content, simultaneously also Extraction time can be shortened, extraction power consumption is reduced, improve the content and purity of effective antibacterial substance, to enhance conditioning agent to planting The control effect of object droop.
The preparation method of peptide ferrous chelate compound is：By the collagen peptide solution after enzymolysis after low temperature drying The peptide liquid for being 25% to solid content adjusts pH value to 7.12, the FeCl of 2.2 times of a concentration of 0.5mol/L is added2Solution, then add The compound auxiliary for entering collagen peptide solution dry matter amount 0.12 ‰, concussion chelating 1h at a temperature of 21 DEG C, by chelating liquid in 1 DEG C At a temperature of with 12000r/min rotating speed centrifugal concentrating 15min, take supernatant to be concentrated in vacuo, after freeze-drying up to peptide ferrous iron chelate Object；The chelating ferrous chelation percent of collagen peptide is higher, and chelate is relatively stablized, and inorganic molysite stability is not only avoided Difference, the disadvantages such as bioavailability is low, are easy to be absorbed by plant, stable ferrous ion are provided for plant, can accelerate plant The synthesis of body chlorophyll, while collagen peptide can supplement amino acid needed for body, be a kind of efficient ferrous tonic With amino acid supplements.
Contain the substance of following content in compound auxiliary：74% ascorbic acid, 24% malic acid and 2% D- amphetamines； During chelatropic reaction, D- amphetamines can largely occur with the oxidant in chelating systems anti-with ascorbic acid It answers, to reduce the accounting that oxidant is precipitated oxidation of ferrous iron to brown di-iron trioxide, keeps two in chelating systems The sufficient content of valence iron ion；In addition, under the conditions of existing for malic acid, D- amphetamines can be with the S in chelating environment2-Ion It generates ligand complex and generates stable complex, reduce the S in chelating environment2-Content avoids S2-With stable chelate In Fe2+It reacts, to prevent the dissociation of stable chelate, contributes to the chelating ferrous compound of collagen peptide It generates, improves the content and purity of the chelating ferrous compound of collagen peptide, it can be the stabilization that provides of plant to increase Ferrous ion amount, greatly speed up the synthesis of plant chlorophyll, promote plant failure cell fast-growth.
Routine operation in operating procedure of the present invention is well known to those skilled in the art, herein without repeating.
Technical scheme of the present invention is described in detail in embodiment described above, it should be understood that the above is only For specific embodiments of the present invention, it is not intended to restrict the invention, all any modifications made in the spirit of the present invention, Supplement or similar fashion replacement etc., should all be included in the protection scope of the present invention.

Claims (9)

1. efficiently solving the preparation method of the conditioning agent of plant droop, it is characterised in that：The preparation method includes：
S1：It takes the double propyl amides of N-N dimethyl to be stirred to obtain organic phase with normal heptane, separately takes sodium alginate and acrylamide system Standby water phase, water phase is slowly added into organic phase, lotion is stirred to obtain；Emulsion system is placed in 38~42 DEG C of water-bath system In, potassium peroxydisulfate is added, hydroquinone is added to terminate polymerisation after stirring polymerization；Equal-volume acetone is added, is slowly stirred After mixing, centrifugation successively washs to obtain microgel with acetone, ethyl alcohol；
S2：Weigh triacontanol, 6- benzylaminopurines, heteroauxin, compound sodium nitrophenolate, thiocarbamide, celery root extract, peptide ferrous iron chela It closes object, Bravo, avermectin, the basic element of cell division, gibberellin and urea to be dissolved in fulvic acid solution, then add compound Amino acid stirs and is uniformly mixed to obtain conditioning agent；
S3：Conditioning agent is poured slowly into microgel, microgel is stirred with the slow-speed of revolution when pouring into, after mixing up to efficiently Solve the conditioning agent of plant droop.
2. the preparation method of the efficient conditioning agent for solving plant droop according to claim 1, it is characterised in that：It is described In S1 steps, the preparation method of organic phase is：Take 0.18~0.20 part of Span-80,0.05~0.08 part of Tween-85,1.5~ 1.8 parts of double propyl amides of N-N dimethyl and 55~59 portions of normal heptanes are added in container, persistently blast nitrogen, 1200~ Organic phase is stirred to obtain under 1300r/min rotating speeds；The preparation method of water phase is：2~5 parts of sodium alginates are taken to be added to 95~98 In part distilled water, 14~15 parts of acrylamides are added after mixing, form uniform water phase.
3. the preparation method of the efficient conditioning agent for solving plant droop according to claim 1, it is characterised in that：It is described In S1 steps, the additive amount of potassium peroxydisulfate is 1~1.2 ‰ parts, and the additive amount of hydroquinone is 1.5~2 ‰.
4. the preparation method of the efficient conditioning agent for solving plant droop according to claim 1, it is characterised in that：It is described In S2 steps, the parts by weight of triacontanol are 0.2~0.4 part, and 6- benzylaminopurines are 0.02~0.03 part, and heteroauxin is 0.01~0.012 part, compound sodium nitrophenolate is 1.5~1.8 parts, and thiocarbamide is 0.5~0.8 part, and celery root extract is 5~10 parts, and peptide is sub- Iron chelate is 0.2~2.0 part, and Bravo is 0.2~0.5 part, and avermectin is 0.2~0.6 part, the basic element of cell division 0.3 ~0.5 part, gibberellin is 0.04~0.08 part, and urea is 3~10 parts, and compound amino acid is 2~10 parts, and fulvic acid solution is 300~380 parts, mass fraction is 5.8~7.0%.
5. the preparation method of the efficient conditioning agent for solving plant droop according to claim 1 or 4, it is characterised in that： In the S2 steps, the extracting method of celery root extract is：In 8~10 leaf phase of celery, celery is randomly selected, fresh quench is taken to clean, It is cut into after segment according to 1g:The amount of 2~5mL is soaked into absolute ethyl alcohol, room temperature oscillation, successively with crocus cloth, sterilizing filter mistake It filters up to mother liquor；Using absolute ethyl alcohol as eluent, leaching liquor mother liquor is detached using silica gel column chromatography, stationary phase is selected Silica gel chromatographs to obtain celery root extract.
6. the preparation method of the efficient conditioning agent for solving plant droop according to claim 5, it is characterised in that：It is described In S2 steps, extract in the absolute ethyl alcohol during celery root extract containing 1~1.2% 2- amino-5-fluorines pyridine and 0.3~ 0.4 ‰ (-)-sparteine.
7. the preparation method of the efficient conditioning agent for solving plant droop according to claim 1 or 4, it is characterised in that： In the S2 steps, the preparation method of peptide ferrous chelate compound is：Collagen peptide solution after enzymolysis is done through low temperature Peptide liquid is obtained after dry, adjusts pH value to 7.1~7.15, FeCl is added2Solution adds collagen peptide solution dry matter amount 0.1~0.15 ‰ compound auxiliary concussion chelating, centrifuging and taking supernatant are concentrated in vacuo, are chelated up to peptide ferrous iron after freeze-drying Object.
8. the preparation method of the efficient conditioning agent for solving plant droop according to claim 7, it is characterised in that：It is described In S2 steps, the substance of following content is contained in the compound auxiliary in the preparation process of peptide ferrous chelate compound：70~80% it is anti-bad Hematic acid, 20~30% malic acid and D- amphetamines mixture, the mass ratio of malic acid and D- amphetamines is 10~12:1.
9. the preparation method of the efficient conditioning agent for solving plant droop according to claim 1, it is characterised in that：It is described In S3 steps, the mass ratio of growth regulator and microgel is 1:2.5~3.5.
CN201810401871.2A 2018-04-28 2018-04-28 Efficiently solve the preparation method of the conditioning agent of plant droop Pending CN108719341A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110078553A (en) * 2019-04-11 2019-08-02 山东农大腐植酸高效利用工程技术研发有限公司 A kind of economic benefits and social benefits chelated iron boron foliar fertilizer and preparation method thereof for preventing and treating fruit tree yellowtop
EP4005385A4 (en) * 2019-06-05 2023-10-18 In Kook Chang Composition comprising n6-benzylaminopurine for controlling plant growth, preparation method therefor, and use thereof

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CN1509606A (en) * 2002-12-20 2004-07-07 北京绿色奇点科技发展有限公司 Multifunctional water-retaining nutritious sustained release agent
CN105504166A (en) * 2016-01-20 2016-04-20 武汉理工大学 Sodium alginate-acrylamide composite aquagel, and preparation method and application thereof

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CN1509606A (en) * 2002-12-20 2004-07-07 北京绿色奇点科技发展有限公司 Multifunctional water-retaining nutritious sustained release agent
CN105504166A (en) * 2016-01-20 2016-04-20 武汉理工大学 Sodium alginate-acrylamide composite aquagel, and preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110078553A (en) * 2019-04-11 2019-08-02 山东农大腐植酸高效利用工程技术研发有限公司 A kind of economic benefits and social benefits chelated iron boron foliar fertilizer and preparation method thereof for preventing and treating fruit tree yellowtop
EP4005385A4 (en) * 2019-06-05 2023-10-18 In Kook Chang Composition comprising n6-benzylaminopurine for controlling plant growth, preparation method therefor, and use thereof

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Application publication date: 20181102