CN108690753A - 一种渔网去腥清洗剂 - Google Patents
一种渔网去腥清洗剂 Download PDFInfo
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract
本发明属于渔网清洗技术领域，具体涉及一种渔网去腥清洗剂，包括以下原料：氯化钠、纳米碳酸钙、竹醋粉、羧甲基壳聚糖、生姜精油、消泡剂、十二烷基二甲基甜菜碱、复合酶、乙醇、水。本发明相比现有技术具有以下优点：本发明中清洗剂不包括有机溶剂，环保安全，复合酶与生姜精油配合，能有效降解醛、酮、含硫化合物等大分子，纳米碳酸钙、竹醋粉、羧甲基壳聚糖对小分子物质有吸附或结合作用，乙醇的适当蒸发，能带走部分气味分子，十二烷基二甲基甜菜碱与羧甲基壳聚糖协调作用，能保护渔网不被腐蚀，在清洗后进行浸胶，保证渔网的力学性能，增强清洁效果。
Description
技术领域
本发明属于渔网清洗技术领域，具体涉及一种渔网去腥清洗剂。
背景技术
渔网通是捕鱼专用的机构材料，99%以上用合成纤维加工而成，主要由尼龙6或改性尼龙的单丝、复丝或复单丝，也可以用聚乙烯、聚酯、聚偏氯乙烯等纤维，要求有高透明度（部分尼龙网）和强度，好的耐冲击性、耐磨性、网目尺寸稳定性和柔软性，适当的断裂伸长率（22-25%），由单丝、复丝捻线（有结网）或单丝经编织（无结网）、一次热处理（固定结节）、染色和二次热处理（固定网目尺寸）加工而成，在渔网长时间使用后，在其表面会累积大量的污垢层，这样在捕鱼使其中的腥气会影响成鱼上网，对渔网也有严重的腐蚀，从而形成渔网的破损，现有技术中有专门用于渔网去腥涂胶的装置，在使用时，由前清洗轮进行清洗后，进入浸胶池进行浸胶，在清洗和浸胶过程中由于发热管加热，产生的水蒸气和油烟气通过排风机排出，吹风冷却完成；虽然该装置在一定程度上能对渔网起到清洗作用，但是渔网表面的附着的很多污迹很难用热水直接清洗掉，因此，需要研究对渔网去腥去污的清洗液。
发明内容
本发明的目的是针对现有的问题，提供了一种渔网去腥清洗剂。
本发明是通过以下技术方案实现的：一种渔网去腥清洗剂，包括以下重量份的原料：氯化钠14-16份、纳米碳酸钙3-8份、竹醋粉6-10份、羧甲基壳聚糖2-6份、生姜精油0.2-0.4份、消泡剂0.8-1.6份、十二烷基二甲基甜菜碱2-4份、复合酶4-6份、乙醇10-20份、水800-1000份；
所述复合酶由脱水酶和中温α-淀粉酶以重量比6:1混合得到。
作为对上述方案的进一步改进，所述纳米碳酸钙的粒径为20-80nm。
作为对上述方案的进一步改进，所述竹醋粉由竹醋液喷雾干燥得到，所述竹醋粉的pH值为2.6-2.8，溶解焦油含量小于0.05%，汞含量小于0.1ppm，铅含量小于0.6ppm，砷含量小于0.1ppm，醋酸含量大于12%，醛类含量大于3%，醇类含量大于2%，脂类含量大于1%。
作为对上述方案的进一步改进，所述十二烷基二甲基甜菜碱的pH值为6.4-7.2，固含量为36-40%，其中氯化钠含量小于等于4%。
作为对上述方案的进一步改进，所述生姜精油的制备方法为：将新鲜生姜洗净后破碎匀浆，得到生姜浆固含量为42-46%；将互米花草在质量浓度为20%的乙醇溶液中，互米花草与乙醇溶液的质量比为6-10:100，在100℃的条件下保持12-18分钟，然后过滤，所得滤液经蒸馏、静置，得到提取液；将生姜浆和提取液以重量比4-6:1混合，得到混合浆在避光条件下静置1-2小时；将静置后的混合浆进行抽滤、分离出滤液与残渣；按混合浆滤液与石油醚的料液比为1:3g/ml的量加入石油醚，在30℃的水浴中萃取3h，之后分离出水层和油层，将油层在50-60℃下进行蒸馏，即得。
作为对上述方案的进一步改进，所述脱水酶为柠檬酸脱水酶和磷酸葡萄糖脱水酶以任意比例混合。
作为对上述方案的进一步改进，所述消泡剂由甘油三羟基聚醚和磷酸三丁酯以重量比4-6:1混合得到。
作为对上述方案的进一步改进，所述清洗剂在使用时的温度为55-60℃。
本发明相比现有技术具有以下优点：本发明中清洗剂不包括有机溶剂，环保安全，在55-60℃的使用条件下，复合酶具有较好的活性，与生姜精油配合，能有效降解醛、酮、含硫化合物等大分子，纳米碳酸钙、竹醋粉、羧甲基壳聚糖对小分子物质有吸附或结合作用，乙醇的适当蒸发，能带走部分气味分子，十二烷基二甲基甜菜碱与羧甲基壳聚糖协调作用，能保护渔网不被腐蚀，在清洗后进行浸胶，保证渔网的力学性能，增强清洁效果。
具体实施方式
实施例1
一种渔网去腥清洗剂，包括以下重量份的原料：氯化钠15份、纳米碳酸钙5份、竹醋粉8份、羧甲基壳聚糖4份、生姜精油0.3份、消泡剂1.2份、十二烷基二甲基甜菜碱3份、复合酶5份、乙醇15份、水900份；
所述复合酶由脱水酶和中温α-淀粉酶以重量比6:1混合得到。
其中，所述纳米碳酸钙的粒径为20-80nm；所述竹醋粉由竹醋液喷雾干燥得到，所述竹醋粉的pH值为2.7，溶解焦油含量小于0.05%，汞含量小于0.1ppm，铅含量小于0.6ppm，砷含量小于0.1ppm，醋酸含量大于12%，醛类含量大于3%，醇类含量大于2%，脂类含量大于1%；所述十二烷基二甲基甜菜碱的pH值为6.8，固含量为38%，其中氯化钠含量小于等于4%。
其中，所述生姜精油的制备方法为：将新鲜生姜洗净后破碎匀浆，得到生姜浆固含量为44%；将互米花草在质量浓度为20%的乙醇溶液中，互米花草与乙醇溶液的质量比为8:100，在100℃的条件下保持15分钟，然后过滤，所得滤液经蒸馏、静置，得到提取液；将生姜浆和提取液以重量比5:1混合，得到混合浆在避光条件下静置1.5小时；将静置后的混合浆进行抽滤、分离出滤液与残渣；按混合浆滤液与石油醚的料液比为1:3g/ml的量加入石油醚，在30℃的水浴中萃取3h，之后分离出水层和油层，将油层在55℃下进行蒸馏，即得。
其中，所述脱水酶为柠檬酸脱水酶和磷酸葡萄糖脱水酶以重量比2:1混合；所述消泡剂由甘油三羟基聚醚和磷酸三丁酯以重量比5:1混合得到。
实施例2
一种渔网去腥清洗剂，包括以下重量份的原料：氯化钠14份、纳米碳酸钙8份、竹醋粉6份、羧甲基壳聚糖2份、生姜精油0.2份、消泡剂1.6份、十二烷基二甲基甜菜碱2份、复合酶6份、乙醇20份、水1000份；
所述复合酶由脱水酶和中温α-淀粉酶以重量比6:1混合得到。
其中，所述纳米碳酸钙的粒径为20-80nm；所述竹醋粉由竹醋液喷雾干燥得到，所述竹醋粉的pH值为2.8，溶解焦油含量小于0.05%，汞含量小于0.1ppm，铅含量小于0.6ppm，砷含量小于0.1ppm，醋酸含量大于12%，醛类含量大于3%，醇类含量大于2%，脂类含量大于1%；所述十二烷基二甲基甜菜碱的pH值为7.2，固含量为40%，其中氯化钠含量小于等于4%。
其中，所述生姜精油的制备方法为：将新鲜生姜洗净后破碎匀浆，得到生姜浆固含量为42%；将互米花草在质量浓度为20%的乙醇溶液中，互米花草与乙醇溶液的质量比为10:100，在100℃的条件下保持18分钟，然后过滤，所得滤液经蒸馏、静置，得到提取液；将生姜浆和提取液以重量比4:1混合，得到混合浆在避光条件下静置1小时；将静置后的混合浆进行抽滤、分离出滤液与残渣；按混合浆滤液与石油醚的料液比为1:3g/ml的量加入石油醚，在30℃的水浴中萃取3h，之后分离出水层和油层，将油层在60℃下进行蒸馏，即得。
其中，所述脱水酶为柠檬酸脱水酶和磷酸葡萄糖脱水酶以重量比3:2混合；所述消泡剂由甘油三羟基聚醚和磷酸三丁酯以重量比4:1混合得到。
实施例3
一种渔网去腥清洗剂，包括以下重量份的原料：氯化钠16份、纳米碳酸钙3份、竹醋粉10份、羧甲基壳聚糖6份、生姜精油0.4份、消泡剂0.8份、十二烷基二甲基甜菜碱4份、复合酶4份、乙醇10份、水800份；
所述复合酶由脱水酶和中温α-淀粉酶以重量比6:1混合得到。
其中，所述纳米碳酸钙的粒径为20-80nm；所述竹醋粉由竹醋液喷雾干燥得到，所述竹醋粉的pH值为2.6，溶解焦油含量小于0.05%，汞含量小于0.1ppm，铅含量小于0.6ppm，砷含量小于0.1ppm，醋酸含量大于12%，醛类含量大于3%，醇类含量大于2%，脂类含量大于1%；所述十二烷基二甲基甜菜碱的pH值为6.4，固含量为36%，其中氯化钠含量小于等于4%。
其中，所述生姜精油的制备方法为：将新鲜生姜洗净后破碎匀浆，得到生姜浆固含量为46%；将互米花草在质量浓度为20%的乙醇溶液中，互米花草与乙醇溶液的质量比为6:100，在100℃的条件下保持12分钟，然后过滤，所得滤液经蒸馏、静置，得到提取液；将生姜浆和提取液以重量比6:1混合，得到混合浆在避光条件下静置2小时；将静置后的混合浆进行抽滤、分离出滤液与残渣；按混合浆滤液与石油醚的料液比为1:3g/ml的量加入石油醚，在30℃的水浴中萃取3h，之后分离出水层和油层，将油层在50-60℃下进行蒸馏，即得。
其中，所述脱水酶为柠檬酸脱水酶和磷酸葡萄糖脱水酶以重量比6:1混合；所述消泡剂由甘油三羟基聚醚和磷酸三丁酯以重量比6:1混合得到。
设置实验，以巢湖市渔网生产厂商制备的聚酰胺渔网线作为实验基材，根据GB/T21032-2007《聚酰胺单丝》中规定的1mm的聚酰胺渔网线的断裂强度为395MPa，单线结断裂强度为220MPa，参照国家标准GB/T5370-2007进行挂网，在连云港水产研究所海上实验基地，渔网浸泡深度为1.5m，浸泡时间为一周，选取生物附着率为75-80%的渔网，用申请号为2017112931690中提供的用于渔网去腥涂胶装置进行清洗，清洗时间为15分钟，对照组中清洗部分用温度为58℃的热水由前清洗轮进行清洗，实验组中将热水分别替换成实施例1-3中提供的清洗剂，在清洗完成后浸胶前，再次检测污染面积，聚酰胺渔网线的力学性能，并对其气味进行评测；
表1
通过表1中数据可以看出，本发明中相比对照组，清洁程度大大提高，同时力学性能保持较好，清洗效果明显，易于推广。
Claims (8)
1.一种渔网去腥清洗剂，其特征在于，包括以下重量份的原料：氯化钠14-16份、纳米碳酸钙3-8份、竹醋粉6-10份、羧甲基壳聚糖2-6份、生姜精油0.2-0.4份、消泡剂0.8-1.6份、十二烷基二甲基甜菜碱2-4份、复合酶4-6份、乙醇10-20份、水800-1000份；
所述复合酶由脱水酶和中温α-淀粉酶以重量比6:1混合得到。
2.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述纳米碳酸钙的粒径为20-80nm。
3.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述竹醋粉由竹醋液喷雾干燥得到，所述竹醋粉的pH值为2.6-2.8，溶解焦油含量小于0.05%，汞含量小于0.1ppm，铅含量小于0.6ppm，砷含量小于0.1ppm，醋酸含量大于12%，醛类含量大于3%，醇类含量大于2%，脂类含量大于1%。
4.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述十二烷基二甲基甜菜碱的pH值为6.4-7.2，固含量为36-40%，其中氯化钠含量小于等于4%。
5.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述生姜精油的制备方法为：将新鲜生姜洗净后破碎匀浆，得到生姜浆固含量为42-46%；将互米花草在质量浓度为20%的乙醇溶液中，互米花草与乙醇溶液的质量比为6-10:100，在100℃的条件下保持12-18分钟，然后过滤，所得滤液经蒸馏、静置，得到提取液；将生姜浆和提取液以重量比4-6:1混合，得到混合浆在避光条件下静置1-2小时；将静置后的混合浆进行抽滤、分离出滤液与残渣；按混合浆滤液与石油醚的料液比为1:3g/ml的量加入石油醚，在30℃的水浴中萃取3h，之后分离出水层和油层，将油层在50-60℃下进行蒸馏，即得。
6.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述脱水酶为柠檬酸脱水酶和磷酸葡萄糖脱水酶以任意比例混合。
7.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述消泡剂由甘油三羟基聚醚和磷酸三丁酯以重量比4-6:1混合得到。
8.如权利要求1所述一种渔网去腥清洗剂，其特征在于，所述清洗剂在使用时的温度为55-60℃。
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| CN105838521A (zh) * | 2016-04-14 | 2016-08-10 | 巢湖市荷花渔网有限公司 | 一种渔网除污剂 |
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