CN108690425A - A kind of glazed tiles water paint and preparation method thereof - Google Patents
A kind of glazed tiles water paint and preparation method thereof Download PDFInfo
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- CN108690425A CN108690425A CN201810159718.3A CN201810159718A CN108690425A CN 108690425 A CN108690425 A CN 108690425A CN 201810159718 A CN201810159718 A CN 201810159718A CN 108690425 A CN108690425 A CN 108690425A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention relates to technical field of coatings, specifically disclose a kind of glazed tiles water paint and preparation method thereof.The glazed tiles water paint, including component that mass fraction is following:15-25 parts of acrylic emulsion;25-50 parts of water-based hydroxyl acrylic emulsion;5-20 parts of curing agent;2-5 parts of cosolvent;1-5 parts of organic silicone powder;1-5 parts of nano aluminium oxide;0.5-2 parts of nano zircite;0.1-3 parts of nanometer anion powder;0.01-0.05 parts of ultra-violet absorber;0.05-0.5 parts of nano zine oxide;0.1 part -1 part of Ludox;0-5 parts of pigment;0.1-0.2 parts of pH adjusting agent;0.1-0.2 parts of antifoaming agent;2-5 parts of coalescents;0.3-0.5 parts of dispersant;0.3-0.5 parts of substrate wetting agents;5-10 parts of deionized water;0.5-1.0 parts of thickener.Glazed tiles water paint provided by the invention, VOC≤60g/L is more environmentally-friendly, and smell is very low, and paint film has good water-fast, resistant effect and automatically cleaning, scrub performance, hardness, adhesive force, pollution resistance and weatherability.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of glazed tiles water paint and preparation method thereof.
Background technology
Glazed tiles develop by the successive dynasties, have formed the series of products that wide in variety, type system is particular about, assembling is strong, commonly
Common watt of part has:Semicircular tile, pan tile, sentence head watt, drip-tile, arched watt, bow watt, beast, choose angle, positive kiss, close angle kiss, beast of hanging down,
Money beast, Bao Ding etc..It is increasingly used widely in modern architecture.Glazed tiles preparation process is about at 850 DEG C -1000 DEG C
It is burnt into temperature.Bullion lead glaze with toner content how much, directly affect the variation of the glaze colours depth, can get the abundant color of level.Mesh
Preceding since technique is relative complex, calcining aberration is larger, and it is a kind of higher means of cost performance to carry out colouring to it using coating, together
When can modulate different colors as needed, not only saved processing cost, but also shorten production efficiency.
And common coating is solvent reducible coatings, can release a variety of volatility such as toluene, benzene, dimethylbenzene under room temperature has
Machine compound pollutes environment, aggravates the compound dirts of air such as photochemical pollution, region gray haze, acid rain, and bring health to people
Harm.In recent years, environment increasingly deteriorates, and haze is increasingly severe, and requirement of the society to environmental protection is higher and higher, develops environmental protection
Coating has become the common recognition of people.Wherein coating Water-borne modification is as a kind of effective approach, but even water paint, appoints
So contain a certain amount of VOC, and adhesive force, impact resistance and weather resistance are insufficient, so it is super to develop function admirable, VOC content
Low coating becomes the developing direction of coating industry.
Invention content
For VOC content content height and adhesive force, impact resistance and weather resistance difference etc. existing for existing glazed tiles coating
Problem, a kind of glazed tiles water paint of present invention offer and preparation method thereof.
To achieve the above object of the invention, the embodiment of the present invention uses the following technical solution:
A kind of glazed tiles water paint, including component that mass fraction is following:
Compared with the existing technology, glazed tiles water paint provided by the invention, using acrylic emulsion, water-based hydroxyl third
Olefin(e) acid lotion is used cooperatively with environment-friendly type coalescents, makes coating VOC≤60g/L, more environmentally-friendly, smell is very low, and makes paint
Film has high glaze, high-decoration, high hydrophobicity;The addition of organic silicone powder makes paint film have good water-fast, resistant effect
And automatically cleaning, scrub performance;Nano zircite, nano aluminium oxide improve the hardness of paint film, adhesive force, anti-pollution as filler
Property and weatherability;Nano zine oxide makes paint film have effects that persistently, mildly to sterilize;Nanometer anion powder can make paint film lasting
Anion is discharged, air purification is contributed to.
Further, the present invention also provides the preparation methods of the glazed tiles water paint.The preparation method, including with
Lower step:
(1) each component is weighed according to the raw material proportioning of glazed tiles water paint;
(2) by the organic silicone powder, nano aluminium oxide, nano zircite, nano zine oxide, nanometer anion powder, silicon
Colloidal sol, pigment, dispersant, the deionized water of ultra-violet absorber and 40%-60%, the pH adjusting agent of 40%-60%,
The antifoaming agent of 40%-60% carries out mixing treatment, obtains the first mixed material;
(3) by the acrylic emulsion, water-based hydroxyl acrylic emulsion, coalescents, substrate wetting agents, remaining pH value
Conditioning agent, remaining antifoaming agent, remaining deionized water carry out mixing treatment, obtain the second mixed material;
(4) first mixed material and the second mixed material are subjected to mixing treatment, thickener, agitated place is added
Reason, obtains component A;
(5) curing agent and cosolvent are subjected to mixing treatment, obtain B component, with mass ratio be 5-7 by A, B component:
1 is mixed, and glazed tiles water paint is obtained.
Compared with the existing technology, the preparation method of glazed tiles water paint provided by the invention, simple for process, operation side
Just, environmentally protective, securely and reliably, convenient for construction.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
The embodiment of the present invention provides a kind of glazed tiles water paint.The glazed tiles water paint, including mass fraction
Following component:
Preferably, the acrylic emulsion is pure-acrylic emulsion, has excellent appearance durability and good wearability, together
When also have good scrub resistance and resistance to blocking, improve the wear-resisting and scrub performance of paint film.
Preferably, the water-based hydroxyl acrylic emulsion is hydroxy polyacrylate dispersion, keeps the paint film after solidification hard
Degree is high, and flexibility is good, and gloss is high, and richness is high, and has good weatherability, ultraviolet resistance and excellent acid rain resistance.
Preferably, the organic silicone powder is polymethylsilsesquioxane, and high-performance organic-inorganic hybrid material has not
Molten insoluble thermosetting property, the advantages of integrating inorganic particle and organic powder, have good lubricity, moreover it is possible to promote pigment
Dispersion, prevents pigment and particle agglomerate, the temperature in use of coating can be made to increase, the mechanical property of coating is improved, prevent metal
Or the sedimentations such as metal oxide powder are reunited, and paint film is made to have good water-fast, resistant effect and automatically cleaning and scrub performance.Energy
Enough improve hydrophobic film, oleophobic stain, anti-slide mark, anti-fingerprint marking and other effects.
Specifically, the nano aluminium oxide has the performances such as excellent wear-resisting, hardening, high temperature resistant and insulation, as filler
Improve hardness, adhesive force, pollution resistance and the weatherability of paint film.
Specifically, the nano zircite performance is better than nano aluminium oxide, and effect is similar, improves hardness of paint film, fire resisting resistance
Performance, wear-resisting property, corrosion resistance etc. are fired, collocation nano aluminium oxide makes coating have higher hardness and shock resistance.
Specifically, the nano zine oxide volume is fluffy, grain size is small, large specific surface area, and antibacterial sterilization ability is excellent, nanometer
Zinc oxide not only has effects that contact sterilization, and good antibacterial sterilization effect can be still played under conditions of Guang Heshui,
Enhance the antibacterial sterilization ability of paint film.
Specifically, the ingredient in the nanometer anion powder has thermoelectricity and piezoelectric effect, when external condition changes,
When temperature, psychrometric difference, friction, the potential difference between nano-negative ion meal component crystal can be caused, to make sky
Gas ionizes, and that is hit is electronically attached to neighbouring water and oxygen molecule and it is made to be converted into negative aeroion, i.e., negative oxygen
Ion contributes to air purification.
Specifically, the Ludox is a kind of water base inorganic silicon compound, have good against weather, water proofing property,
Fire resisting, washable, resistance tocrocking, can improve the weather resistance of paint film.
Preferably, the pigment is aqueous light-resistant pigment, is used for the tone of adjusting coating.
Preferably, the curing agent is the hydrophilic aliphatic polyisocyanate based on two isocyanide ester of hexa-methylene, makes painting
Material has the characteristics that quick-drying, hardening are quick, and the paint film of formation has the characteristics that final hardness height and splendid chemical-resistant and Zhuo
Gloss retention more and outstanding mechanical performance.
Preferably, the cosolvent is propylene glycol methyl ether acetate, is mainly used for dissolving cured dose, forms B component.
Preferably, the ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone, can strong absorbing wavelength 300-
375nm ultraviolet lights make paint film have good efficient anti ageing property.
Preferably, the pH adjusting agent is one or both of dimethylethanolamine, AMP-95, the acid of regulation system
Alkalinity, while coating can be assisted to form a film.
Preferably, the dispersant is polyester modification polyphosphoric acid esters dispersant, improves the dispersion performance of system, and have
It is catalyzed the effect of reaction.
Preferably, it is 1 that the antifoaming agent, which is mass ratio,:The phosphate ester foam inhibitor of 0.8-1.2 and organic silicon antifoaming agent
Mixture, the generation of bubble in elimination or inhibition system.
Preferably, it is 1 that the coalescents, which are mass ratio,:The propylene glycol phenyl ethers coalescents of 1-2 form a film with alcohol ester-12
The mixture of auxiliary agent is environmentally friendly auxiliary agent, can effectively reduce the minimum film formation temperature of emulsion paint, improve the scrub resistance of paint film
And film quality, improve glossiness, intensity and the weatherability and color developing of paint film.
Preferably, the substrate wetting agents are Siloxane-Oxyalkylene Copolymers class wetting agent, improve the wettability of system.
Preferably, the thickener is polyurethane-type thickener, adjusting coating viscosity.
Glazed tiles water paint provided in an embodiment of the present invention, using acrylic emulsion, water-based hydroxyl acrylic emulsion
It is used cooperatively with environment-friendly type coalescents, makes coating VOC≤60g/L, more environmentally-friendly, smell is very low, and paint film is made to have height
Gloss, high-decoration, high hydrophobicity;The addition of organic silicone powder makes paint film have good water-fast, resistant effect and from clearly
Clean, scrub performance;Nano zircite, nano aluminium oxide improve the hardness of paint film, adhesive force, pollution resistance and resistance to as filler
Hou Xing;Nano zine oxide makes paint film have effects that persistently, mildly to sterilize;It is negative that nanometer anion powder can be such that paint film persistently discharges
Ion contributes to air purification.
The present invention still further provides the glazed tiles with aqueous painting under the premise of providing the glazed tiles water paint
The preparation method of material.
In one embodiment, which includes the following steps:
(1) each component is weighed according to the raw material proportioning of glazed tiles water paint;
(2) by the organic silicone powder, nano aluminium oxide, nano zircite, nano zine oxide, nanometer anion powder, silicon
Colloidal sol, pigment, dispersant, the deionized water of ultra-violet absorber and 40%-60%, the pH adjusting agent of 40%-60%,
The antifoaming agent of 40%-60% carries out mixing treatment, obtains the first mixed material;
(3) by the acrylic emulsion, water-based hydroxyl acrylic emulsion, coalescents, substrate wetting agents, remaining pH value
Conditioning agent, remaining antifoaming agent, remaining deionized water carry out mixing treatment, obtain the second mixed material;
(4) first mixed material and the second mixed material are subjected to mixing treatment, thickener, agitated place is added
Reason, obtains component A;
(5) curing agent and cosolvent are subjected to mixing treatment, obtain B component, with mass ratio be 5-7 by A, B component:
1 is mixed, and glazed tiles water paint is obtained.
Explanation is further explained to above-mentioned preparation method below:
Preferably, in step (2), (3), the mixing speed of the mixing treatment is 900-1100r/min, and mixing time is
10-15min;In step (4), the mixing speed of the mixing treatment is 500-700r/min, mixing time 8-10min;It stirs
The mixing speed for mixing processing is 400-600r/min, mixing time 5-10min, and it is to generate to avoid bubble in system, ensures to apply
The homogeneity of material system.
This method preparation process is simple, easy to operate, environmentally protective, securely and reliably, convenient for construction.
In order to better illustrate glazed tiles water paint provided in an embodiment of the present invention and preparation method thereof, below by
Embodiment is further to be illustrated.
Embodiment 1
A kind of glazed tiles water paint, including mass fraction component as shown in Table 1:
Table 1
The preparation method of the glazed tiles water paint includes the following steps:
(1) each component is weighed according to the raw material proportioning of glazed tiles water paint;
(2) by the organic silicone powder, nano aluminium oxide, nano zircite, nano zine oxide, nanometer anion powder, silicon
Colloidal sol, pigment, dispersant, ultra-violet absorber and 50% deionized water, 50% pH adjusting agent, 50% defoaming
Agent carries out mixing treatment 10min with 1000r/min, obtains the first mixed material;
(3) by the acrylic emulsion, water-based hydroxyl acrylic emulsion, coalescents, substrate wetting agents, remaining pH value
Conditioning agent, remaining antifoaming agent, remaining deionized water carry out mixing treatment 10min with 1000r/min, obtain the second mixture
Material;
(4) first mixed material and the second mixed material are subjected to mixing treatment 10min with 600r/min, are added and increase
Thick dose, it is 5min with 500r/min stir process, obtains component A;
(5) curing agent and cosolvent are subjected to mixing treatment, obtain B component, by A, B component with mass ratio for 6:1
It is mixed, obtains glazed tiles water paint.
Embodiment 2
A kind of glazed tiles water paint, including mass fraction component as shown in Table 2:
Table 2
The preparation method of the glazed tiles water paint includes the following steps:
(1) each component is weighed according to the raw material proportioning of glazed tiles water paint;
(2) by the organic silicone powder, nano aluminium oxide, nano zircite, nano zine oxide, nanometer anion powder, silicon
Colloidal sol, pigment, dispersant, ultra-violet absorber and 60% deionized water, 60% pH adjusting agent, 60% defoaming
Agent carries out mixing treatment 10min with 1100r/min, obtains the first mixed material;
(3) by the acrylic emulsion, water-based hydroxyl acrylic emulsion, coalescents, substrate wetting agents, remaining pH value
Conditioning agent, remaining antifoaming agent, remaining deionized water carry out mixing treatment 10min with 1100r/min, obtain the second mixture
Material;
(4) first mixed material and the second mixed material are subjected to mixing treatment 10min with 500r/min, are added and increase
Thick dose, it is 10min with 400r/min stir process, obtains component A;
(5) curing agent and cosolvent are subjected to mixing treatment, obtain B component, by A, B component with mass ratio for 7:1
It is mixed, obtains glazed tiles water paint.
Embodiment 3
A kind of glazed tiles water paint, including component that mass fraction is as shown in table 3:
Table 3
The preparation method of the glazed tiles water paint includes the following steps:
(1) each component is weighed according to the raw material proportioning of glazed tiles water paint;
(2) by the organic silicone powder, nano aluminium oxide, nano zircite, nano zine oxide, nanometer anion powder, silicon
Colloidal sol, pigment, dispersant, ultra-violet absorber and 40% deionized water, 40% pH adjusting agent, 40% defoaming
Agent carries out mixing treatment 15min with 900r/min, obtains the first mixed material;
(3) by the acrylic emulsion, water-based hydroxyl acrylic emulsion, coalescents, substrate wetting agents, remaining pH value
Conditioning agent, remaining antifoaming agent, remaining deionized water carry out mixing treatment 15min with 900r/min, obtain the second mixture
Material;
(4) first mixed material and the second mixed material are subjected to mixing treatment 8min with 700r/min, are added and increase
Thick dose, it is 5min with 600r/min stir process, obtains component A;
(5) curing agent and cosolvent are subjected to mixing treatment, obtain B component, by A, B component with mass ratio for 5:1
It is mixed, obtains glazed tiles water paint.
In order to better illustrate the characteristic of glazed tiles water paint provided in an embodiment of the present invention, below by embodiment 1,
2,3 glazed tiles prepared carry out the test of respective performances with water paint, and test result is as shown in table 4.
Table 4
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| (Chinese pencil) hardness | 2H | 2H | 3H |
| Flexibility (diameter D/mm) | 1 | 1 | 1 |
| Adhesive force | 0 | 0 | 0 |
| It impacts (cm) | 50 | 50 | 50 |
| Weatherability (artificial acceleration) h | 5000h is without exception | 5000h is without exception | 5000h is without exception |
| Flow time (min) | 5-10 | 5-10 | 5-10 |
| Suitable for film thickness (μm) | 10-30 | 10-30 | 10-30 |
It can be obtained by data above, the glazed tiles water paint provided in the embodiment of the present invention, paint film has higher
Hardness adhesive force, have excellent flexibility, impact resistance, weatherability.In addition, the glazed tiles are suitable for burning with water paint
System watt, pottery surface, have smooth feel, gorgeous appearance, and have certain automatically cleaning effect, the prints such as stain resistant
Note, holding surface are bright and clean.And has the effect of persistently sterilizing, discharges anion.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.
Claims (10)
1. a kind of glazed tiles water paint, it is characterised in that:Including the following component of mass fraction:
2. glazed tiles water paint as described in claim 1, it is characterised in that:The acrylic emulsion is pure-acrylic emulsion.
3. glazed tiles water paint as described in claim 1, it is characterised in that:The water-based hydroxyl acrylic emulsion is hydroxyl
Based polyacrylic acid ester dispersion.
4. glazed tiles water paint as described in claim 1, it is characterised in that:The organic silicone powder is poly- methyl silicon times
Half oxygen alkane.
5. glazed tiles water paint as described in claim 1, it is characterised in that:The pigment is aqueous light-resistant pigment.
6. glazed tiles water paint as described in claim 1, it is characterised in that:The curing agent is based on hexa-methylene two
The hydrophilic aliphatic polyisocyanate of isocyanide ester, and/or
The cosolvent is propylene glycol methyl ether acetate, and/or
The ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone.
7. glazed tiles water paint as described in claim 1, it is characterised in that:The pH adjusting agent is dimethyl ethanol
One or both of amine, AMP-95, and/or
The dispersant is polyester modification polyphosphoric acid esters dispersant, and/or
The antifoaming agent is that mass ratio is 1:The mixture of the phosphate ester foam inhibitor and organic silicon antifoaming agent of 0.8-1.2.
8. glazed tiles water paint as described in claim 1, it is characterised in that:The coalescents are that mass ratio is 1:1-
The mixture of 2 propylene glycol phenyl ethers coalescents and alcohol ester-12 coalescents, and/or
The substrate wetting agents are Siloxane-Oxyalkylene Copolymers class wetting agent, and/or
The thickener is polyurethane-type thickener.
9. a kind of preparation method of glazed tiles water paint, it is characterised in that:It at least includes the following steps:
(1) each component is weighed according to the raw material proportioning of the glazed tiles water paint as described in any one of claim 1~8;
(2) by the organic silicone powder, nano aluminium oxide, nano zircite, nano zine oxide, nanometer anion powder, Ludox,
Pigment, dispersant, ultra-violet absorber and the deionized water of 40%-60%, the pH adjusting agent of 40%-60%, 40%-
60% antifoaming agent carries out mixing treatment, obtains the first mixed material;
(3) acrylic emulsion, water-based hydroxyl acrylic emulsion, coalescents, substrate wetting agents, remaining pH value are adjusted
Agent, remaining antifoaming agent, remaining deionized water carry out mixing treatment, obtain the second mixed material;
(4) first mixed material and the second mixed material are subjected to mixing treatment, thickener is added, agitated processing obtains
To component A;
(5) curing agent and cosolvent are subjected to mixing treatment, obtain B component, with mass ratio be 5-7 by A, B component:1 into
Row mixing, obtains glazed tiles water paint.
10. the preparation method of glazed tiles water paint as claimed in claim 9, it is characterised in that:In step (2), (3),
The mixing speed of the mixing treatment be 900-1100r/min, mixing time 10-15min, and/or
In step (4), the mixing speed of the mixing treatment is 500-700r/min, mixing time 8-10min;Stir process
Mixing speed be 400-600r/min, mixing time 5-10min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810159718.3A CN108690425A (en) | 2018-02-26 | 2018-02-26 | A kind of glazed tiles water paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810159718.3A CN108690425A (en) | 2018-02-26 | 2018-02-26 | A kind of glazed tiles water paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108690425A true CN108690425A (en) | 2018-10-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810159718.3A Pending CN108690425A (en) | 2018-02-26 | 2018-02-26 | A kind of glazed tiles water paint and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109554040A (en) * | 2018-12-20 | 2019-04-02 | 惠州市银海涂料有限公司 | A kind of self-drying aqueous dumb light glass lacquer and preparation method thereof |
| CN110240857A (en) * | 2019-05-31 | 2019-09-17 | 江苏晶联水漆有限公司 | A kind of aqueous double-component polyurethane coating and preparation method thereof |
| CN111944113A (en) * | 2020-07-08 | 2020-11-17 | 华南理工大学 | Photoreaction type polyurethane associative thickener with benzophenone side group at end, preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1916093A (en) * | 2005-08-17 | 2007-02-21 | 厦门东顺涂料有限公司 | Dope with negative ion function for air purification, and prepartion method |
| CN107353758A (en) * | 2017-07-05 | 2017-11-17 | 河北晨阳工贸集团有限公司 | Tempering film water-based anti-blue light coating of sterilization and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1916093A (en) * | 2005-08-17 | 2007-02-21 | 厦门东顺涂料有限公司 | Dope with negative ion function for air purification, and prepartion method |
| CN107353758A (en) * | 2017-07-05 | 2017-11-17 | 河北晨阳工贸集团有限公司 | Tempering film water-based anti-blue light coating of sterilization and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109554040A (en) * | 2018-12-20 | 2019-04-02 | 惠州市银海涂料有限公司 | A kind of self-drying aqueous dumb light glass lacquer and preparation method thereof |
| CN110240857A (en) * | 2019-05-31 | 2019-09-17 | 江苏晶联水漆有限公司 | A kind of aqueous double-component polyurethane coating and preparation method thereof |
| CN111944113A (en) * | 2020-07-08 | 2020-11-17 | 华南理工大学 | Photoreaction type polyurethane associative thickener with benzophenone side group at end, preparation method and application thereof |
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Application publication date: 20181023 |