CN108677553A - 一种变色合成革及其生产工艺 - Google Patents

一种变色合成革及其生产工艺 Download PDF

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CN108677553A
CN108677553A CN201810367113.3A CN201810367113A CN108677553A CN 108677553 A CN108677553 A CN 108677553A CN 201810367113 A CN201810367113 A CN 201810367113A CN 108677553 A CN108677553 A CN 108677553A
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synthetic leather
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陈尚文
陈尚明
陈尚德
陈池光
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FOSHAN GAOMING SHANG-ANG TECHNOLOGY Co Ltd
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Abstract

本发明所述一种变色合成革，包括面层、变色层和发泡层，变色层原料按照重量份包括：聚氨酯100份，碳酸氢钙50‑60份，热稳定剂1‑3份，PVC色浆4‑6份，应力变色革蜡粉1‑2份，感温变色粉5‑20份，石墨烯粉2‑4份，银粉2‑5份，纳米二氧化钛1‑3份，本发明可以不仅可以随着温度变化，而且当踩在上面，或者制作成鞋，走路时也会产生变化，颜色多变，而且颜色鲜亮。

Description

一种变色合成革及其生产工艺
技术领域
本发明涉及一种合成革，具体地说，涉及一种变色合成革及其生产工艺。
背景技术
皮革在包括汽车工业、沙发等在内的多种领域中被广泛应用，皮革通常包括天然皮革和合成革，其中，合成革由于造价相比天然皮革便宜且容易批量生产。
合成革是一种外观、手感似皮革并可代替其使用的塑料制品，主要有PVC合成革、PU合成革和PU合成革三类。合成革领域大多数采用以100％化学合成纤维(涤纶、尼龙)的无纺布作为底基，涂覆合成树脂及各种塑料添加制成。
目前，给皮革制品带来更多的变化，是现阶段业界着重研发的因素之一，现有变色人造革随着温度的变化产生不同的颜色，但是其仍然存在变色速度慢，颜色亮度不够的缺点。
发明内容
本发明克服了现有技术中的缺点，提供了一种变色合成革及其生产工艺，其变色速度快，颜色鲜亮，变化彻底。
为了解决上述技术问题，本发明是通过以下技术方案实现的：
一种变色合成革，包括面层、变色层和发泡层，变色层原料按照重量份包括：聚氨酯100份，碳酸氢钙50-60份，热稳定剂1-3份，PVC色浆4-6份，应力变色革蜡粉1-2份，感温变色粉5-20份，石墨烯粉2-4份，银粉2-5份，纳米二氧化钛1-3份。
进一步，还加入3-6份的蛋白质粉。
进一步，还加入1-3份的琥珀辛酯磺酸钠。
进一步，还加入1-3份的琥珀酸锌。
进一步，所述面层为PU面层。
进一步，所述发泡层包括PVC树脂90-100份，增塑剂25-35份，稳定剂2-4份，银粉2-5份，发泡剂4-6份。
一种变色合成革的生产工艺，包括以下步骤：
1)制备面层，将所述面层浆料涂覆在离型纸上，于120-140℃条件下烘干60-70S；
2)制备变色层，将变色层浆料涂敷于烘干后的面层浆料上，于140-160℃条件下烘干70-80S；
3)制备发泡层；将发泡层浆料涂敷于烘干后的变色层浆料上，于140-160℃条件下进行发泡反应，发泡反应时间为80-90S，然后于发泡层浆料上涂覆聚氨酯粘合剂，将发泡层通过聚氨酯粘合剂与基布粘合，于130-160℃下烘干80-90S，将离型纸抽离，得到变色合成革。
与现有技术相比，本发明的有益效果是：
本发明所述一种变色合成革，包括面层、变色层和发泡层，变色层原料按照重量份包括：聚氨酯100份，碳酸氢钙50-60份，热稳定剂1-3份，PVC色浆4-6份，应力变色革蜡粉1-2份，感温变色粉5-20份，石墨烯粉2-4份，银粉2-5份，纳米二氧化钛1-3份，本发明可以不仅可以随着温度变化，而且当踩在上面，或者制作成鞋，走路时也会产生变化，颜色多变，而且颜色鲜亮。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
实施例1：
本发明所述一种变色合成革，包括面层、变色层和发泡层，变色层原料按照重量份包括：聚氨酯100份，碳酸氢钙55份，热稳定剂2份，PVC色浆5份，应力变色革蜡粉1.5份，感温变色粉7份，石墨烯粉3份，银粉3份，纳米二氧化钛2份，还加入4份的蛋白质粉，2份的琥珀辛酯磺酸钠，2份的琥珀酸锌，石墨烯粉加快了变色的速度，蛋白质粉、琥珀辛酯磺酸钠和琥珀酸锌使人造革的颜色变得更细腻，银粉使颜色鲜亮。
面层为PU面层。
发泡层包括PVC树脂92份，增塑剂28份，稳定剂3份，银粉3份，发泡剂5份。
一种变色合成革的生产工艺，包括以下步骤：
1)制备面层，将所述面层浆料涂覆在离型纸上，于120-140℃条件下烘干60-70S；
2)制备变色层，将变色层浆料涂敷于烘干后的面层浆料上，于140-160℃条件下烘干70-80S；
3)制备发泡层；将发泡层浆料涂敷于烘干后的变色层浆料上，于140-160℃条件下进行发泡反应，发泡反应时间为80-90S，然后于发泡层浆料上涂覆聚氨酯粘合剂，将发泡层通过聚氨酯粘合剂与基布粘合，于130-160℃下烘干80-90S，将离型纸抽离，得到变色合成革。
本发明的人造革能随着受到外力变化，其形变部位就会呈现不同颜色。
实施例2：
本实施例与实施例1的技术方案基本相同，相同之处不再赘述，其区别在于：
本发明所述一种变色合成革，包括面层、变色层和发泡层，变色层原料按照重量份包括：聚氨酯100份，碳酸氢钙58份，热稳定剂2.5份，PVC色浆5.5份，应力变色革蜡粉1.8份，感温变色粉12份，石墨烯粉3.5份，银粉4份，纳米二氧化钛2.5份，还加入5份的蛋白质粉，2.8份的琥珀辛酯磺酸钠，2.8份的琥珀酸锌。
面层为PU面层。
发泡层包括PVC树脂97份，增塑剂32份，稳定剂3.5份，银粉4份，发泡剂5.5份。
最后应说明的是：以上仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，但是凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (7)

1.一种变色合成革，其特征在于，包括面层、变色层和发泡层，变色层原料按照重量份包括：聚氨酯100份，碳酸氢钙50-60份，热稳定剂1-3份，PVC色浆4-6份，应力变色革蜡粉1-2份，感温变色粉5-20份，石墨烯粉2-4份，银粉2-5份，纳米二氧化钛1-3份。
2.根据权利要求1所述一种变色合成革，其特征在于，还加入3-6份的蛋白质粉。
3.根据权利要求1所述一种变色合成革，其特征在于，还加入1-3份的琥珀辛酯磺酸钠。
4.根据权利要求1所述一种变色合成革，其特征在于，还加入1-3份的琥珀酸锌。
5.根据权利要求1所述一种变色合成革，其特征在于，所述面层为PU面层。
6.根据权利要求1所述一种变色合成革，其特征在于，所述发泡层包括PVC树脂90-100份，增塑剂25-35份，稳定剂2-4份，银粉2-5份，发泡剂4-6份。
7.根据权利要求1所述一种变色合成革的生产工艺，其特征在于，包括以下步骤：
1)制备面层，将所述面层浆料涂覆在离型纸上，于120-140℃条件下烘干60-70S；
2)制备变色层，将变色层浆料涂敷于烘干后的面层浆料上，于140-160℃条件下烘干70-80S；
3)制备发泡层；将发泡层浆料涂敷于烘干后的变色层浆料上，于140-160℃条件下进行发泡反应，发泡反应时间为80-90S，然后于发泡层浆料上涂覆聚氨酯粘合剂，将发泡层通过聚氨酯粘合剂与基布粘合，于130-160℃下烘干80-90S，将离型纸抽离，得到变色合成革。
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109385908A (zh) * 2018-12-10 2019-02-26 无锡市曼优丽新型复合材料有限公司 一种变色人造革
CN109851741A (zh) * 2018-12-29 2019-06-07 东莞市康诚鞋材有限公司 一种感温变色tpu鞋配件用材料及其制备方法
CN109851742A (zh) * 2018-12-29 2019-06-07 东莞市康诚鞋材有限公司 一种具有珠光及感温变色效果的tpu材料及其制备方法
CN110525003A (zh) * 2019-08-27 2019-12-03 江苏尚科聚合新材料有限公司 一种pu基车用变色人工皮革及其制备方法

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