CN108659849A - Overcome the composition that soil acidification is hardened - Google Patents
Overcome the composition that soil acidification is hardened Download PDFInfo
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- CN108659849A CN108659849A CN201810459639.4A CN201810459639A CN108659849A CN 108659849 A CN108659849 A CN 108659849A CN 201810459639 A CN201810459639 A CN 201810459639A CN 108659849 A CN108659849 A CN 108659849A
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- potassium
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- soil
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- 239000002689 soil Substances 0.000 title claims abstract description 60
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 230000020477 pH reduction Effects 0.000 title claims abstract description 24
- 239000000126 substance Substances 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 29
- 239000004111 Potassium silicate Substances 0.000 claims abstract description 26
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical group [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052913 potassium silicate Inorganic materials 0.000 claims abstract description 26
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 22
- 229930195725 Mannitol Natural products 0.000 claims abstract description 22
- 235000010355 mannitol Nutrition 0.000 claims abstract description 22
- 239000000594 mannitol Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 9
- HBYKUCARMGQRCF-UHFFFAOYSA-N [K].C(CCC)(=O)O Chemical group [K].C(CCC)(=O)O HBYKUCARMGQRCF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005260 corrosion Methods 0.000 claims abstract description 9
- 239000002738 chelating agent Substances 0.000 claims abstract description 8
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 7
- 229940075582 sorbic acid Drugs 0.000 claims abstract description 5
- 235000010199 sorbic acid Nutrition 0.000 claims abstract description 5
- 239000004334 sorbic acid Substances 0.000 claims abstract description 5
- WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 claims abstract description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 12
- 229910052700 potassium Inorganic materials 0.000 claims description 12
- 239000011591 potassium Substances 0.000 claims description 12
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical group C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 5
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- RWMKSKOZLCXHOK-UHFFFAOYSA-M potassium;butanoate Chemical compound [K+].CCCC([O-])=O RWMKSKOZLCXHOK-UHFFFAOYSA-M 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000003672 processing method Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 19
- 230000008901 benefit Effects 0.000 abstract description 2
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- 238000012545 processing Methods 0.000 description 23
- 238000012360 testing method Methods 0.000 description 20
- 241000196324 Embryophyta Species 0.000 description 13
- 235000013399 edible fruits Nutrition 0.000 description 12
- 238000004080 punching Methods 0.000 description 10
- 240000008067 Cucumis sativus Species 0.000 description 9
- 240000003768 Solanum lycopersicum Species 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 8
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 4
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 4
- 241000219112 Cucumis Species 0.000 description 4
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 4
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 4
- 238000003306 harvesting Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
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- 238000005516 engineering process Methods 0.000 description 3
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- 238000003466 welding Methods 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- LPTWEDZIPSKWDG-UHFFFAOYSA-N benzenesulfonic acid;dodecane Chemical compound OS(=O)(=O)C1=CC=CC=C1.CCCCCCCCCCCC LPTWEDZIPSKWDG-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
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- 206010023126 Jaundice Diseases 0.000 description 1
- 241001274660 Modulus Species 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 241001290762 Pratia Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- DIFFLMNDXWOKQJ-UHFFFAOYSA-N [K].O[Si](O)(O)O Chemical compound [K].O[Si](O)(O)O DIFFLMNDXWOKQJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000013005 condensation curing Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- JTEDVYBZBROSJT-UHFFFAOYSA-N indole-3-butyric acid Chemical compound C1=CC=C2C(CCCC(=O)O)=CNC2=C1 JTEDVYBZBROSJT-UHFFFAOYSA-N 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- 208000000509 infertility Diseases 0.000 description 1
- 231100000535 infertility Toxicity 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of compositions for overcoming soil acidification hardened, with silicate and root-growing agent and anti-corrosion chelating agent, homogenizing agent, anatonosis antifoaming agent and water are composed, it is characterized in that silicate is potassium silicate, root-growing agent is butyric acid potassium, anti-corrosion chelating agent is sorbic acid and/or mannitol, homogenizing agent is neopelex, anatonosis antifoaming agent is organosilicon, each substance is according to potassium silicate: butyric acid potassium: sorbierite and/or mannitol: neopelex: organosilicon: water is uniformly mixed according to 1000: 0~2: 0~2: 0~2: 0~2: 0~100 mass ratio.Its advantage is that using the silicate used in industry and building, especially water-soluble metasilicate and potassium silicate, add suitable chemical substance, it realizes and is improved to being acidified hardened soil, so that soil is quickly recovered to the high-quality soil scope for substantially conforming to planting conditions requirement, achieves unexpected effect.
Description
Technical field
The invention belongs to agricultural use chemical engineering scope, be related to using Chemical composition that the soil of acidification carry out improvement and
The technology for promoting plant growth is specifically the composition for overcoming soil acidification hardened and promoting plant growth.
Background technology
At present since China's agricultural and peasant largely apply chemical fertilizer, although greatly improving the yield of various crops,
It has ensured the basic living needs of people, still, has applied chemical fertilizer due to excessive for many years, many soils is caused to produce acid
The bad problem such as change, hardened, and thus bring crop and be not easy to take root, grow the problems such as difficulty.By investigation, the pH value of soil
Be reduced to 5.5 hereinafter, soil acidification, it is hardened just very serious, need timely processing.In order to overcome the problems, such as these, take
Many methods, it is currently used to have applying organic manure, addition beneficial bacterium fertilizer, using various conditioners and catalyst to soil
Implement improvement, also achieves good effect.It is entitled such as Chinese patent application 201510253794.7：《A kind of conditioned soil
The element silicon alkaline fertilizer and preparation method thereof of earth acidification》Disclose a kind of mixed fertilizer containing a small amount of potassium silicate, but its
In silicic acid potassium content it is less, 15~20 parts are only accounted in entire component concentration ranges 91.4~117, and be organic and inorganic fertilizer
The existing mixed fertilizer of material, complex process, effect is slow, and after 1 year, the pH value of soil is just restored to neutrality.Moreover,
From the element silicon being also only described in its patent document in the acid soil for being the scarce silicon of supplement, silicon is not described or proved
Sour potassium has the function of overcoming soil acidity or acidification hardened, according to interrelated between soil and fertilizer and crop and
In the invention specific ingredient effect description, it can be seen that in the fertilizer to soil acidity improvement play a major role be make
For the matured compost of organic fertilizer.And for agricultural land soil due to excessive hardened using acidification caused by chemical fertilizer, without definite
Illustrate and describe by the scientific research personnel of our company look for another way the study found that the P in soil H value models of optimum plant growth
Within the scope of enclosing ＞ 6.0~7.5.Therefore, use suitable compound to acidification is hardened caused by chemical fertilizer excessively application can be with
It quickly corrects, it is made to be restored to the soil acidity or alkalinity condition for being suitable for plantation, be a simple and direct effective fast quick-recovery soil
Earth plants the road for development of ability.The goal of the invention of the present invention is proposed thus.
Invention content
The goal of the invention of the present invention is to solve current agricultural land soil due to excessive acidification caused by applying chemical fertilizer
Hardened problem and put forward.A kind of composition for overcoming soil acidification hardened is provided.
Technical solution of the invention is achieved in that the composition for overcoming soil acidification hardened, has silicate
It is composed with substance and anti-corrosion chelating agent, homogenizing agent, anatonosis antifoaming agent and water, it is characterized in that silicate is potassium silicate, it is raw
Root agent is butyric acid potassium, and anti-corrosion chelating agent is sorbic acid and/or mannitol, and homogenizing agent is neopelex, anatonosis
Antifoaming agent is organosilicon, and each substance is according to potassium silicate: butyric acid potassium: sorbierite and/or mannitol: neopelex
: organosilicon: water is uniformly mixed according to 1000: 0~2: 0~2: 0~2: 0~2: 0~100 mass ratio.
The beneficial of the present invention has the technical effect that：Using the silicate used in industry and building, especially water-soluble silicon
Sour sodium and potassium silicate, it is modified to add suitable chemical substance, and industrial potassium silicate is exclusively used in agricultural improvement soil.Realization pair
It is acidified hardened soil to be improved, so that acidified hardened soil has been quickly recovered to and substantially conform to planting conditions requirement
High-quality soil scope achieves unexpected effect.Other substances wherein compounded can be occurred with the potassium silicate of modified synergic
Effect improves the improving effect to soil, while stimulating and improving absorption and utilization of the crops to various nutritional ingredients.And
And substance used in the present invention is safe from harm to soil and crops, also without heavy metal component, do not remain with it is difficult to degrade
Substance can meet primary demand of the current planting industry to soil change amount completely, be a kind of rare soil conditioner.
Common potassium silicate in a reservoir natural storage when, surface solidification is generated due to moisture evaporation and is lost flowability.Through overtesting,
Natural storage in common worn-out mouth container under the room temperature of 25 DEG C or so of general spring and summer autumn indoor temperature, approximately passes through 20 hours just
Can be in the condensed layer of surface about 0.5mm thickness, and condensed layer is not easy to be broken through, and influences its mobility.Continue storage one week, then container
Interior liquid potassium silicate surface layer condensation cure, loses flowability completely.And the combination substance of the potassium silicate of the present invention, by examination
It tests, under condition of storage identical with common potassium silicate liquid, after 20 hours, there is no surface to condense phenomenon, mobility
Do not change, after open storage in one week, surface generates the condensed layer of about 0.5 millimeters thick, and the condensed layer is due to existing
The crosslinked action of organosilicon and neopelex, is not cured, therefore is influenced on mobility minimum.
Specific implementation mode
Specific embodiment is given below.
Embodiment 1.
Potassium silicate：1000 kilograms；Butyric acid potassium：2 kilograms；Sorbierite and mannitol：Each 1 kilogram；Detergent alkylate sulphur
Sour sodium：2 kilograms；Organosilicon：2 kilograms；Water：100 kilograms, above-mentioned whole is put into 1000 liters of reaction kettle and is stirred evenly.
Embodiment 2
Potassium silicate：1000 kilograms；Butyric acid potassium：1 kilogram；Sorbierite or mannitol：1 kilogram；Dodecyl benzene sulfonic acid
Sodium：1 kilogram；Organosilicon：1 kilogram；Water：50 kilograms, above-mentioned whole is put into 1000 liters of reaction kettle and is stirred evenly.
Embodiment 3
Potassium silicate：1000 kilograms；0.5 kilogram of heteroauxin potassium；Sorbierite and mannitol：Each 0.5 kilogram；Detergent alkylate
Sodium sulfonate：1 kilogram；Organosilicon：1 kilogram；Water：10 kilograms；Above-mentioned whole is put into 1000 liters of reaction kettle and is stirred evenly.
Embodiment 4
Sodium metasilicate：1000 kilograms；Butyric acid potassium：1 kilogram；Sorbierite or mannitol：1 kilogram；Dodecyl benzene sulfonic acid
Sodium：1 kilogram；Organosilicon：1 kilogram；Water：50 kilograms, above-mentioned whole is put into 1000 liters of reaction kettle and is stirred evenly.
Embodiment 5
The production method of the composition for overcoming soil acidification hardened of each substance combination in above-described embodiment：Indolebutyric acid
Potassium or heteroauxin potassium are added to the water and stir；Anti-corrosion chelating agent sorbic acid and mannitol are added to the water again and stirred
It mixes uniformly, stirs；Neopelex is added to the water and is stirred evenly；By the above-mentioned each substance stirred evenly
It is added in reaction kettle with together with potassium silicate, then plus water is to defined amount, and organosilicon is added and stirs.Through precipitating,
After filtering, finished product metering packing.
Root-growing agent butyric acid potassium in above example can use heteroauxin potassium to substitute.It is not extremely serious in acidification
Area, effect is substantially without what difference.
Sorbierite and mannitol in embodiment can be according to sorbierites 0~1: the mass ratio range of mannitol 1~0 is appointed
Meaning mixing.Either sorbierite and mannitol are used alone or both sorbierite and mannitol are used in mixed way according to arbitrary proportion,
Effect is essentially identical.
When pH value in the hardened less serious plot of acidification, such as soil is more than 5.5 less than 6.0, potassium silicate can be used
Sodium metasilicate replaces.
In general, compare the P in soil H values of suitable for crop growth within the scope of 5.5~7.5 ＞.
Soil plants experiment effect citing
Experiment 1
Test place：Anqiu City of Weifang City of Shandong Province towns Jin Zhongzi.
Trial crops：Great Jiang.Test period：On May 12nd, 2016 to May 17.
Test 667 square metres of block area.Compare 667 square metres of block area.
It is averaged pH value using preceding soil：5.5.Application method：Punching is applied.Dosage：Every 667 square metres with the embodiment of the present invention 4
10 kilograms of the composition of manufacture, does not use comparatively.It is tested within 5 days after use, experimental field soil is averaged pH value 6.5, control
Ground is still 5.5.Experimental field big ginger leaves piece is unfolded, blackish green.Comparatively leaf rolling is wilted.
Experiment 2
Test place：The Hebei province Gucheng County villages Zang Zhuan.
Trial crops：Cauliflower, also known as cauliflower.Test period：On July 20th, 2016 to July 25.
Test 667 square metres of block area.Compare 667 square metres of block area.
It is averaged pH value using preceding soil：5.2.Application method：Punching is applied.Dosage：Every 667 square metres with the embodiment of the present invention 4
10 kilograms of the composition of manufacture, does not use comparatively.It is tested within 6 days after use, experimental field soil is averaged pH value 6.5, control
Ground is still 5.2.Experimental field cauliflower blade caused by soil acidification is withered, is changed into normal.Comparatively cauliflower blade it is withered,
Jaundice.
Experiment 3
Test place：The Liaocheng of Shandong Province Shenxian County position village town villages Ming Gongji.
Trial crops：Eggplant.Test period：August in 2016 3 days was to August 9 days.
Test 667 square metres of block area.Compare 667 square metres of block area.
It is averaged pH value using preceding soil：5.2.Application method：Punching is applied.Dosage：Every 667 square metres with the embodiment of the present invention 4
10 kilograms of the composition of manufacture, does not use comparatively.It is tested within 5 days after use, experimental field soil is averaged pH value 6.5, control
Ground is still 5.2.Experiment common pratia fruit grows fine, and plant is sturdy, and flowers and fruits number obviously increases.Comparatively eggplant rice shoot is short and small, blade
Dispirited curling, number of blooming are considerably less than experimental field.
Experiment 4
In order to further verify the effect of the present invention, our company specially establishes one in the original material storage yard of intra-company
The winter warm type protecting field greenhouse of a top grade plants excellent No. 1 cucumber in Tianjin, carries out effect test.The area 666m of greenhouse2(one
Mu), soil regime is former fertilizer material stockyard, pH value 5.2.
Date of test：On July 25,22 days to 2017 March in 2017.
If 2 processing：
Processing is 1.：Clear water compares (CK), area 133.2m2(0.2 mu).It is applied with the punching of 2 equivalent clear water of same processing, number is applied in punching
With the time with processing 2.
Processing is 2.：Use the composition of the present invention, area 532.8m2(0.8 mu), per acre every time using the combination of the present invention
Object 5kg, in cucumber at seedling stage (April 15), growth medium (April 27), the best fruiting period (May 20), punching is applied 3 times altogether.
Experimentation：
It is broadcast live using high ridge zanjon, plastic film mulching cultivation, furrow wide 80cm, furrow width 40cm, 2 rows of field planting per furrow, line-spacing 60cm,
Spacing in the rows 35cm.April 22 was sowed；Final singling between May 3, it is 3180 plants/acre that a seedling, plantation density are stayed per cave；May 24 bloomed,
1 day-June 13 May harvest time.
Experimental plot base manure applies organic commercial fertilizer 500kg, 40% composite fertilizer (N-P per acre2O5-K2O=18-10-12) 50kg,
Urea 10kg；September 10 days, September each top dressing on the 22nd 1 time, apply 10kg/ mus of urea every time.The time of infertility prevents downy mildew, aphid etc.
2 times.
The cucumber yield of trial zone and check plot is weighed after picking, is recorded in time.
As a result with analysis
Influence of the different disposal to cucumber plant character
During the test, each 20 plants of processing positioning investigation measures base portion stem thickness, average melon length, percentage of fertile fruit, single melon
Weight, economical characters and the structure of output (referring to table 1) such as record single plant number of results.
It is applied from table 1 it follows that carrying out punching using the composition of the present invention during cucumber growth, to improving the agriculture of cucumber
Skill character and structure of output have positive effect, effect of increasing production apparent.Punching applies the composition (processing is 2.) of the present invention than clear water pair
According to (processing is 1.)：The long 38.9cm of average melon, increases 3.2cm, increases 8.96%；Base portion stem thickness 0.72cm increases 0.07cm, increases
10.8%；Average list melon weight 214.3g, increases 11.7g, increases 5.78%；Average per plant number 7.05, increases by 0.7, increases
11.02%；4804.1kg/ mus of theoretical yield increases 713.3kg/ mus, increases 17.4%, difference reaches the pole level of signifiance.
Influence of composition of the application of table 1 containing the present invention to cucumber economical character and structure of output
Influence of the different disposal to cucumber yield
During the test, to accomplish accurate, easy, scientific algorithm yield, each processing randomly selects 5 points, each
Point area 10m2, individually harvest, individually meter production, finally calculate total yield, equivalent per mu yield.
As can be seen from Table 2, using the compositions-treated of the present invention, it is 4782.4kg/ mus to convert into yield, is compareed than clear water
3948.6kg/ mus, increase 833.8kg/ mu, increasing 21.1%, obvious effect of increasing production.
Influence unit of composition of the application of table 2 containing the present invention to cucumber yield result：Kg/ mus
Experiment 5
In order to further verify the effect of the present invention, our company specially establishes one in the original material storage yard of intra-company
The winter warm type protecting field greenhouse of a top grade plants tomato, and tomato variety is tested using Provence tomato as material, and effect is carried out
Experiment.The area 666m of greenhouse2(one mu), soil regime are former fertilizer material stockyard, pH value 5.2.
Date of test：3~July in 2017.
If 2 processing：
Processing is 1.：Use Ba Fute composite fertilizers (N: P2O5∶K2O=15: 15: 15), and area 133.2m2(0.2 mu).With same
It handles the punching of 2 equivalent clear water to apply, punching applies number and time with processing 2.
Processing is 2.：Use Ba Fute composite fertilizers (N: P2O5∶K2O=15: 15: 15) and invention composition, area
532.8m2(0.8 mu).
Experimentation：
Experiment is cultivated using furrow, duplicate rows field planting.65 centimetres of line-spacing, 40 centimetres of spacing in the rows.It is applied per acre before field planting when ploughing
Enter 3000 kilograms of organic commercial fertilizer.March 18 be colonized, after field planting, respectively at March 31,12 mesh in April, April 23, May 3,
May 14 and May 24, according to 18 kilogram of fertilizer are imposed per acre, 8 public affairs of substance of the primary present invention are applied in the independent bath of processing 2
Jin.Four fringe fruits are stayed to pinch.May, 23 start to harvest, and experimental investigation handles cell production, single fruit weight, the hardness of fruit and solvable
Property solid content.Other management conditions such as water and prevention and control of plant diseases, pest control are consistent in entire growth course.
Data analysis：
Test data analyzer arranges.Statistics is as follows.With the tomato per mu yield of processing 2 for 8564.07 kilograms；Handle 1 tomato
Per mu yield be 7781.16 kilograms.
| Processing | 1 | 2 |
| Yield (kg) | 7781.16 | 8564.0 |
In terms of single fruit weight, 2 tomato single fruit weight maximum is handled, is 216.52 grams, processing 1 is minimum.
| Processing | 1 | 2 |
| Mean fruit weight (gram) | 187.6 | 216.52 |
In terms of tamato fruit hardness, the tomato hardness for handling 2 is 0.7Mp, and processing 1 is 0.5Mp.
| Processing | 1 | 2 |
| Average hardness (Mp) | 0.5 | 0.7 |
In terms of tamato fruit soluble solid, the content highest of 2 tomato is handled, is 4.80%；It is minimum to handle 1.
| Processing | 1 | 2 |
| Soluble solid (%) | 4.40% | 4.80% |
Test result shows that the yield that applied the tomato of substance of the present invention is high, and the hardness of fruit is maximum, soluble solid
Also significantly greater than other soil fertility qualities.
In addition the 2 plot soil ph value of test process of substance of the present invention has been used to be increased to 6.3 by original 5.2, it is right
P in soil H values than 1 plot of test process do not change, and therefore, the substance of the present invention is combined improved it can be seen from testing above
Soil, promotes the good harvest of crop.
By being tested above as can be seen that the composition of the present invention is improving soil acidification, raising crop growth environment
It is at low cost with markedly fast, the outstanding features such as easy to operate, it can also improving the yield and economic benefit of crops.It achieves
Unexpected effect.
Analysis：Potassium silicate, commonly referred to as potassium water glass.Appearance：Colourless or yellowish transparent or semitransparent thick liquid
Body.Molecular formula：K2O·nSiO2.For n moduluses in 2-14, pH value is about 11~13, density 1.1~1.45.Generally it is often used
I types in I class I liquid Is specified in HGT4131-2010 standards and II types, the industrial potassium silicate that modulus is 2.20~3.40.
Under the precondition for not considering cost, II classes (solid) potassium silicate can also be used to carry out complex treatment.
Modulus：2.35-2.5 purposes：Inorganic coating adhesive etc..Modulus：3.25-3.35 purposes：Welding rod binder
Deng.
Sodium metasilicate, aqueous solution are commonly called as waterglass, are a kind of binders.Its chemical formula is Na2O·nSiO2, n is known as water glass
The number that rubs of glass.Common waterglass is sodium metasilicate (Na in building2O·nSiO2) aqueous solution.
Potassium silicate aqueous solution, generally as industry and building on use, be commonly used to manufacture welding rod, welding electrode,
Reducing dye, fireproof agent.Also serve as fluorescent screen dope layer and soap filler, casting binder etc..The present inventor passes through
Substance appropriate is added, by potassium silicate by modified and decentralized processing, is applied to agricultural acid as main central role substance
Change soil improvement, reduces the acidity that soil generates due to the use of chemical fertilizer, and pass through certain verification experimental verification, achieve imaginary
Less than effect.With significant progress and substantive distinguishing features outstanding.
Sorbierite is also known as D-sorbite, and mannitol is also known as mannitol.Mannitol is the isomer of D-sorbite,
For hydroxyl towards difference, molecular formula is C on No. two carbon atoms of two kinds of substances6H14O6, there is extremely strong permeability and improve plant
Resistance.On the one hand, sugar alcohol is the important substance for participating in intracellular penetration and adjusting.Plant is in adverse circumstances such as salt damage, arid, waterflooding
Under stress, sorbierite, mannitol can make plant adapt to adverse growth by adjusting cell permeability；On the other hand, sugar alcohol can be with
It improves to the resistance of active oxygen, avoids burning ultraviolet light day, plant-active oxygen damage caused by due to arid, disease, anoxic etc.
Wound.Meanwhile also playing the role of anti-corrosion and anti-metamorphic and ion chelating to the solution of the composition of the present invention.
Butyric acid potassium is a kind of growth-promoting root class plant growth regulator.It induces crop to form adventitious root, is sprayed via blade face
It spills, the modes such as root dipping are passed into plant by positions such as blade seeds, and concentrate on growing point position, promote cell division,
Induced synthesis adventitious root, it is more to show as root, rough, and root hair is more.It is soluble easily in water, it is stored under dark conditions, molecular structure stabilized.
In the present compositions, which plays the role of coordinating potassium silicate to soil modification.The property of heteroauxin potassium with
Butyric acid potassium is similar, and effect is essentially identical.
Organosilicon：Ethyoxyl is modified poly- trisiloxanes, has superpower spreadability and outstanding permeability, can significantly reduce
The surface tension of spray solution.It is therefore used in the compositions of the present invention as antifoaming agent, together for nonionic form under normality
Interpenetrating property between each substances of Shi Zengjia makes the solution of the present invention be uniformly mixed.
Neopelex, white or faint yellow powdery or chip solid.Hardly possible volatilization, it is soluble easily in water, be dissolved in water and
At translucent solution.Play the role of uniform liquid property as anionic surfactant in the present compositions.
Substance used in the present invention, by mutually it is compatible, all have good water solubility, without heavy metal and other
Harmful substance.Under the premise of quality control is rational, water-insoluble therein only has 0.2-0.3% by detection, well beyond
Now widely used Ministry of Agriculture's a great number of elements (NY 1107-2010) and moderate-element (NY 2266-2012) Water soluble fertilizer standard
Specified in water-insoluble less than or equal to 5% standard requirement, also comply with chemical industry water soluble fertilizer standard (HGT/4365-
2012) requirement of the water-insoluble less than or equal to 0.5% in standard.Fully meet wanting for current agricultural technology field water-fertilizer integral
It asks.It is a kind of rare pure water soluble agromelioration agent.Solve at present be agriculturally badly in need of solve because largely making
The soil acidification caused by chemical fertilizer is hardened and thus caused, soil quality, quality reduce, and what crop yield declined asks
Topic.
Claims (5)
1. a kind of composition for overcoming soil acidification hardened, there is silicate and root-growing agent substance and anti-corrosion chelating agent, uniformly
Agent, anatonosis antifoaming agent and water are composed, it is characterized in that silicate is potassium silicate, root-growing agent substance is butyric acid potassium, anti-corrosion
Chelating agent is sorbic acid and/or mannitol, and homogenizing agent is neopelex, and anatonosis antifoaming agent is organosilicon, each substance
According to potassium silicate: butyric acid potassium: sorbierite and/or mannitol: neopelex: organosilicon: water is according to 1000: 0
~2: 1~2: 0~2: 0~2: 10~100 mass ratio uniformly mixes.
2. a kind of composition for overcoming soil acidification hardened described in accordance with the claim 1, it is characterised in that described root-growing agent
It is heteroauxin potassium.
3. one kind described in accordance with the claim 1 overcomes the hardened composition of soil acidification, it is characterised in that described sorbierite and
Mannitol is according to sorbierite 0~1: mannitol: 1~0 mass ratio mixing.
4. a kind of composition for overcoming soil acidification hardened described in accordance with the claim 1, it is characterised in that described silicate
It is sodium metasilicate, described organosilicon is that ethyoxyl is modified poly- trisiloxanes.
5. a kind of processing method of composition for overcoming soil acidification hardened described in accordance with the claim 1, it is characterised in that Yin
Diindyl potassium butyrate or heteroauxin potassium are added to the water and stir；Water is added in anti-corrosion chelating agent sorbic acid and mannitol again
In stir；Neopelex is added to the water and is stirred evenly；By the above-mentioned each substance and silicon stirred evenly
Sour potassium is added in reaction kettle together, and then plus water, addition organosilicon stir, through precipitation, filtering, finished product metering packet
Dress.
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| CN108424256A (en) * | 2018-05-09 | 2018-08-21 | 巴夫特（潍坊）化工有限公司 | Overcome soil acidification hardened and promotes the composition of plant growth |
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